Luyn Thi & Bi Dng Kin Thc

Gio vin - Th.S Ng Xun Qunh - T: 0979.817.885 Mn Ha Hc: T Ha 8 => Ha 12

S GD&T VNH PHC KIM TRA CHT LNG CHUYN MN GIO VIN
NM HC 2015 - 2016
CHNH THC MN HA HC; CP THCS
Thi gian lm bi: 180 pht, khng k thi gian giao
( thi gm 02 trang)
Cho nguyn t khi ca mt s nguyn t: H=1; C=12; N=14; O=16; Na=23; Mg=24; S=32;
Cl=35,5; K=39; Ca=40; Fe=56; Cu=64; Ag=108; Ba=137.
Cu 1 (1,0 im)
Trnh by cch pha ch:
a) 150 gam dung dch CuSO4 2% t dung dch CuSO4 10% (coi khi lng ring ca nc bng 1 g/ml).
b) 250 ml dung dch KOH 0,5M t dung dch KOH 2M.
Cu 2 (1,0 im)
Trn 50 ml dung dch CaCl2 0,4M vi 150 ml dung dch c cha 5,1 gam AgNO3.
a) Nu hin tng quan st c v vit phng trnh ha hc.
b) Tnh khi lng kt ta thu c.
c) Tnh nng mol/l ca cc cht trong dung dch sau phn ng.
Bit th tch ca dung dch thay i khng ng k.
Cu 3 (1,0 im)
Hirocacbon X mch h, l cht kh nhit phng (250C). Nhit phn hon ton X (trong iu kin
khng c oxi) thu c sn phm l C v H2, trong th tch kh H2 thu c gp i th tch kh X
(o cng iu kin). Vit cng thc cu to cc cht X tha mn.
Cu 4 (1,0 im)
Metan b ln mt t tp cht l: CO2, C2H4, C2H2. Trnh by phng php ho hc loi ht tp cht
khi metan.
Cu 5 (1,0 im)
Khng dng thm thuc th no khc, hy nhn bit cc dung dch sau: NaHCO3, CaCl2, Na2CO3,
Ca(HCO3)2.
Cu 6 (1,0 im)
Ngi ta iu ch poli(vinyl clorua) t CaC2 theo s sau:
CaC2
C2H2
CH2=CHCl
(-CH2-CHCl-)n
a) Vit cc phng trnh phn ng theo s trn.
b) Tnh khi lng poli(vinyl clorua) thu c khi dng 800 kg t n ( tinh khit ca CaC2 l 80%)
v hiu sut chung ca c qu trnh iu ch l 75%.
Cu 7 (1,0 im)
a) Vit cng thc ca este sinh ra t phn ng ca glixerol v axit panmitic (C15H31COOH) theo t l
mol tng ng l 1 : 3.

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b) phn ng hon ton vi 86,2 gam mt loi cht bo (l trieste ca glixerol vi axit bo) cn va
x gam NaOH, thu c 9,2 gam glixerol v y gam hn hp mui ca cc axit bo. Tnh x, y.
Cu 8 (1,0 im)
Ba cht hu c mch h A, B, D c cng thc phn t tng ng l: C 3H6O, C3H4O2, C6H8O2. Chng
c nhng tnh cht sau:
- Ch A v B tc dng vi Na gii phng kh H2.
- Ch B v D tc dng c vi dung dch NaOH.
- A tc dng vi B (trong iu kin xc tc, nhit thch hp) thu c sn phm l cht D.
Hy cho bit cng thc cu to ca A, B, D. Vit cc phng trnh phn ng xy ra.
Cu 9 (1,0 im)
Ha tan ht 15,3 gam BaO vo nc, thu c dung dch A. Cho 9,24 gam hn hp CaCO3 v MgCO3 tan
ht trong dung dch HCl d, thu c kh B. Nu cho dung dch A hp th ht lng kh B th c to ra
kt ta hay khng? Nu c, hy tnh khi lng kt ta thu c.
Cu 10 (1,0 im)
Ha tan ht hn hp A gm Fe v mt oxit st FexOy vo 300 ml dung dch H2SO4 1,8 M. Sau phn ng,
thu c dung dch B v 2,016 lt kh D ( ktc). Cho dung dch NaOH d vo dung dch B, thu c kt
ta E. Lc, sy kh v nung E trong khng kh n khi lng khng i, thu c 32 gam cht rn F.
Bit rng, lng axit dng d 20% so vi lng cn thit.
Tnh thnh phn phn trm theo khi lng ca oxit st trong hn hp A.

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Th sinh khng c s dng ti liu, k c bng tun hon cc nguyn t ha hc.
Cn b coi thi khng gii thch g thm.
H v tn th sinh: S bo danh:

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 Luyn Thi & Bi Dng Kin Thc
Gio vin - Th.S Ng Xun Qunh - T: 0979.817.885 Mn Ha Hc: T Ha 8 => Ha 12

S GD&T VNH PHC P N V HNG DN CHM

MN HA HC; CP THCS
(Hng dn chm c 04 trang)

Cu p n im
1 a) 150 gam dung dch CuSO4 2% c 0,25
(1,0) mCuSO4 150.2 /100 3g mddCuSO4 10% 3.100 /10 30 g
Khi lng nc cn dng l 150 30 = 120g.
Cch pha: Cn 30 gam dung dch CuSO4 10% v 120 gam nc (hoc ong 120 ml nc) 0,25
ri trn vo nhau c 150 gam dung dch CuSO4 2%
b) nKOH = 0,25.0,5 = 0,125 (mol) VddKOH 2M = 0,125/2 = 0,0625 (lt) 0,25
Cch pha: ong 62,5 ml dung dch KOH 2M ri cho vo ng ong 500 ml. Thm t t 0,25
nc ct vo ng ong n th tch 250 ml thu c dung dch KOH 0,5M

2 a) Hin tng: to kt ta trng 0,25

(1,0) Phng trnh phn ng: CaCl2 + 2AgNO3 Ca(NO3)2 + 2AgCl
5,1 0,25
b) n CaCl2 = 0,05.0,4 = 0,02 mol; n AgNO3 = = 0,03 mol
170
Theo ptp: nAgCl = nAgNO3 = 0,03 mol mAgCl = 0,03.143,5 = 4,305 g
c) Dung dch sau phn ng c CaCl2 d v Ca(NO3)2, trong : 0,5
0, 03
n Ca(NO3 )2 = = 0,015 mol; n CaCl2 = 0,02 - 0,015 = 0,005 mol;
2
Vdd sau p = 50 + 150 = 200 ml = 0,2 lt
0, 015 0, 005
C M/Ca(NO3 )2 = = 0,075M; C M/CaCl2 = = 0,025M.
0, 2 0, 2

3 Gi cng thc phn t ca X : CxHy ( x 4) Mi

(1,0) CxHy t0
xC + y/2 H2 CTCT
Theo bi ra ta c y/2 = 2 y= 4. c
0,25
Vy X c dng CxH4. cc cng thc phn t tha mn iu kin X l:
CH4, C2H4, C3H4, C4H4.
Cc CTCT: CH4; CH2=CH2; CH C-CH3 (v CH2=C=CH2); CH C-CH=CH2.

4 Cho hn hp kh ln lt i qua bnh nc Brm d, lc loi ht C2H4, C2H2 nh phn 0,5

(1,0) ng:
C2H4 + Br2 C2H4Br2
C2H2 + 2Br2 C2H2Br4
Kh thot ra dn qua bnh ng dung dch kim d (NaOH, Ca(OH)2,v.v), lc CO2 b 0,5
hp th ht do phn ng:
2NaOH + CO2 Na2CO3 + H2O
Kh cn li l CH4 nguyn cht.

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 Hc bit, hc lm, hc chung sng, hc lm ngi v t khng nh mnh !
5 nh s cc l dung dch, ly mi l mt t ha cht cho vo ng nghim cng s lm Nhn
(1,0) mu th. bit
Trn ln cc mu th tng i mt c kt qu theo bng sau: c 1
NaHCO3 CaCl2 Na2CO3 Ca(HCO3)2 cht
NaHCO3 Khng ht Khng ht Khng ht Khng ht c
CaCl2 Khng ht Khng ht Kt ta trng Khng ht 0,25
Na2CO3 Khng ht Kt ta trng Khng ht Kt ta trng
Ca(HCO3)2 Khng ht Khng ht Kt ta trng Khng ht
Mu to hai kt ta trng khi trn vi cc mu khc l Na2CO3
Mu khng gy hin tng g khi trn vi cc mu khc l NaHCO3.
Hai mu to mt kt ta trng vi Na2CO3 l CaCl2 v Ca(HCO3)2. em un nng hai mu
ny, mu to kt ta trng v c kh bay ra l Ca(HCO3)2, mu khng hin tng g l CaCl2.
Ca(HCO3)2 + Na2CO3 CaCO3 + 2NaHCO3
CaCl2 + Na2CO3 CaCO3 + 2NaCl
Ca(HCO3)2 CaCO3 + CO2 + H2O
o
t

Ca(HCO3)2 + Na2CO3 CaCO3 + 2NaHCO3

6 a) Cc ptp: 0,5
(1,0) CaC2 + 2H2O C2H2 + Ca(OH)2
C2H2 + HCl CH2=CHCl
0
xt , t

nCH2=CHCl (-CH2-CHCl-)n
0
xt , t , p

b) Khi lng CaC2 = 800. 80% = 640 kg 0,5

S mol C2H2 = s mol CaC2 = 640: 64 = 10 kmol
S mol C2H3Cl phn ng = 10. 75% = 7,5 kmol
Khi lng PVC thu c = 7,5. 62,5 = 468,75 kg
7 a) Cng thc ca este (C15H31COO)3C3H5 0,25
(1,0) b) Gi cht bo c dng: (RCOO)3C3H5, s phn ng: 0,25
(RCOO)3C3H5 + 3NaOH C3H5(OH)3 + 3RCOONa
9, 2
S mol NaOH = 3.s mol glixerol = 3. 0,3 mol
92 025
Khi lng NaOH: x = 0,3. 40 = 12 gam
p dng nh lut bo ton khi lng:
Khi lng cht bo + khi lng NaOH = khi lng glixerol + khi lng hn hp mui 0,25
Khi lng hn hp mui: y = 86,2 + 12 9,2 = 89 gam
8 - A tc dng vi Na gii phng kh H2. Vy A l ancol, Cng thc cu to ca A l: 0,25
(1,0) CH2=CH-CH2-OH.
- B tc dng vi Na gii phng kh H2, B tc dng c vi dung dch NaOH. Vy B l axit 0,25
c cng thc cu to l: : CH2=CH-COOH
- D tc dng c vi dung dch NaOH, khng tc dng vi Na v l sn phm phn ng 0,25
gia A v B. Vy D l este c cng thc cu to l:
CH2=CH-COOCH2-CH=CH2
Cc phng trnh phn ng xy ra l: 0,25
CH2=CH-CH2-OH + Na CH2=CH-CH2-ONa + 1/2H2

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 Luyn Thi & Bi Dng Kin Thc
Gio vin - Th.S Ng Xun Qunh - T: 0979.817.885 Mn Ha Hc: T Ha 8 => Ha 12

CH2=CH-COOH + Na CH2=CH-COONa + 1/2H2

CH2=CH-COOH + NaOH CH2=CH-COONa + H2O
CH2=CH-COOCH2-CH=CH2 + NaOHCH2=CH-COONa + CH2=CH-CH2-OH

CH2=CH-COOCH2-CH=CH2+ H2O
CH2=CH-COOH + CH2=CH-CH2-OH

xt,t 0

9 15,3 0,25
n BaO = = 0,1 (mol)
(1,0) 153
9,24 9,24
= 0,0924 (mol) < n hh(CaCO3 ,MgCO3 ) < = 0,11 (mol)
100 84
Cc phng trnh phn ng:
BaO + H 2 O Ba(OH)2
0,1(mol) 0,1 (mol)
CaCO3 + 2HCl CaCl2 + CO2 + H2O
MgCO3 + 2HCl MgCl2 + CO2 + H2O
CO2 + Ba(OH)2 BaCO3 + H2O
CO2 + BaCO3 + H2O Ba(HCO3)2
0,0924 (mol) < n CO2 = n hh(CaCO3 ,MgCO3 ) < 0,11 (mol) < 2n Ba(OH)2 0, 2 (mol) 0,25
Vy nu cho dd A hp th ht lng kh B th c to ra kt ta
Xt on 0,0924 (mol) < n CO2 n Ba(OH)2 0,1 (mol) ch xy ra phn ng to kt ta 0,25
0,0924 (mol) < n CO2 = n BaCO3 0,1 (mol)
Xt khong n Ba(OH)2 0,1 (mol) < n CO2 < 0,11 (mol) c phn ng ha tan mt phn kt
ta 0,09 (mol) < 2n Ba(OH)2 - n CO2 = n BaCO3 < 0,1 (mol)
0,09 (mol) < n BaCO3 0,1 (mol) 0,25
Vy
0,09.197 = 17,73 (gam) < n BaCO3 0,1.197 19,7 (gam)
10 0,54.100 0,25
n H2SO4 0,54 (mol) n H2SO4 p = = 0,45 mol ; nD = 0,09 mol
(1,0) 120
FeSO 4
Fe
hh A +H 2SO 4 dd B Fe 2 (SO 4 )3 + D (H 2 )
Fe x O y H SO
2 4
Fe(OH) 2 +O2 ,t o
ddB
+NaOH
E F (Fe2 O3 )
Fe(OH)3
n Fe2O3 = 0,2 mol nion st/ddB = 0,4 mol;
n SO2- /mui 0,45 3
n SO2- /mui = n H2 SO4 = 0,45 mol 1< 4
= < Dung dch B cha c mui st
4
n ion st 0,4 2
(II) v st (III).
t s mol Fe2+ v Fe3+ ln lt l a, b (mol) a + b = 0,4 (1)
p dng bo ton in tch: 2a + 3b = 0,45.2 = 0,9 (2)

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"Life is a race, if you don't run fast, you will get trampled"
 Hc bit, hc lm, hc chung sng, hc lm ngi v t khng nh mnh !

a = 0,3
Gii h phng trnh (1) v (2) c
b = 0,1
Ta c: n H2SO4p- = n H2 + n O/oxit = 0,45 mol n O/oxit = 0,45 - 0,09 = 0,36 (mol)
n Fe c/A n H2 = 0,09 mol n Fe/oxit 0,31 mol 0,25
nO 0,36
trong oxit c Vy oxit st c th l Fe2O3 hoc Fe3O4
n Fe 0,31
TH1: Nu oxit st l Fe2O3 0,25
0,36
n Fe2O3 = = 0,12 mol n Fe = 0,4 - 0,12.2 = 0,16 mol
3
0,12.160
%Fe2 O3 = .100 = 68,18%
0,12.160+0,16.56
TH2: Nu oxit st l Fe3O4 0,25
0,36
n Fe3O4 = = 0,09 mol n Fe = 0,4 - 0,09.3 = 0,13 mol
4
0,09.232
%Fe3O4 = .100 = 74,15%
0,09.232+0,13.56

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Th sinh lm bi theo cch khc ng vn tnh im bnh thng

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