Professional Documents
Culture Documents
GROUP 5
Fenol, Khing
Manalo, Jhane
Manuel, Princess
Marti, Benedick
Rubio, Athena
Taladua, Lica
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Abstract
and aluminium. This material is subjected to a separation process which includes heating,
shearing, and electrostatic separation. The separated components then undergo incineration with
energy recovery. The fuel gases produced are then tested for presence of harmful components. If
no harmful components are present, the gases are safe to be released back into the atmosphere.
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CHAPTER 1
INTRODUCTION
Plastic is almost everywhere, and the growing rate of plastic pollution is even
worsened due to the rising consumption and population growth. Plastic pollution has
increasingly becoming a major nuisance and poses significant threats to the entire
environment leading to land, air, and water pollution. Plastics also impacts the natural
environment and has grave consequences for humans, wildlife, and plants since they
Plastic is a polymeric materialthat is, a material whose molecules are very large,
links. No one exactly knows how long plastic takes to break down, but it is believed to take
hundreds or even thousands of years. It is not just the accumulation of plastics that harms
the environmentit is also the fragments and toxins released during photo-decomposition
Plastics are used as packaging materials such as plastic sachets. Unilever, the
consumer goods giant behind brands that are using plastic sachets in their products. The
company sells billions of products in single-use sachets each year, including cosmetics
and food products, particularly in developing and emerging markets. From shampoo and
toothpaste to detergent powder and instant coffee, plastic sachets are a common form of
packaging in developing countries that have made household goods affordable for people
with limited disposable income. But with hundreds of billions of them thrown away every
year, these lightweight plastic sachets have become an environmental nuisance, clogging
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drains and polluting public spaces. It also contributes a great amount in municipal wastes.
And is difficult to recycle because sachets are fabricated out of thin film of plastics and
aluminum in a sandwich laminate form for longer shelf life and leakage counteract.
To tackle this problem, our group focuses on how to dispose plastic sachets without
harming our environment. In line with this, our group has come up with a step by step
procedure. The first step is separation of each plastic component by heating, shredding
and electrostatic separation, after the separation of plastic components of sachets; the
second step is incineration of each component with energy recovery. In past, incineration
Incineration comes with a number of benefits in specific areas like medical wastes and
other life risking waste. In this process, toxins are destroyed when waste is treated with
high temperature.
Based on these problems, the paper aims to dispose completely the plastic
sachets by incineration with energy recovery without harming our environment and at the
same time to produce energy that will help the people in the community.
sachets produced by Unilever that does not violates any laws regarding the proper
General Objective: To develop a way to dispose the plastic sachets that does harm
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Specific Objectives:
8749 (The Philippine Clean Air Act of 1999), RA 9003 (The Ecological Solid Waste
Management Act of 2000) and RA 6969 (Toxic Substances and Hazardous Waste Act
of 1990).
The discovery of plastics has tremendously changed lives from around the world.
It has been the greatest achievement of mankind. But as the newly-found packaging
technique granted convenient life to both the consumer and the producer since profitable
economy has been made possible for the manufacturing industries just by repacking their
products into tiny parcels, sachets are observed of be a major contributor to the
Unilever Philippines, Inc. that can be used to solve the plastic problem. The beneficiaries
The researchers will become a better individual after achieving the goal of this
study. They will be recognized for having a study that would help the community.
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This study will help the government to reduce or to fully unravel the problems with
plastics. The benefits of this research study to the government include the reduction of the
amount of solid wastes and pollution due to inadequate solid waste management. This
study will also benefit them by minimizing the area allotted to a landfill that can be used for
a different purpose.
There is no question that sachets have brought better quality products to different
communities but the problem is that waste volumes are projected to grow worldwide as
adoption of these sachet products increases. However, with the help of this study, they
will not worry anymore about the clogging of creeks and canals that will be a reason of
flood.
The students could get further information regarding the disposal of plastic sachets
that can eliminate pollution. It also inform the students about the advancement of the
technology of modern days. Lastly, this study can encourage them to perform a study that
The development of this method of plastic sachet disposal will be able to make the
environment cleaner and greener, prevent break out of health diseases, avoid flooding,
and reduce the uses of the land for other, more useful purposes.
The main focus of this project was the ecological disposal of plastic sachets
produced by the company, Unilever, in the Philippines. These sachets are composed of
three layers: the Polyethylene, aluminum, and Polyethylene terephthalate (PET). Factors
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such as the chemical properties of the layers and the inks printed on its packaging were
considered for this certain process of disposal. Essentially, the environmental legislations
such as RA 8749 (The Philippine Clean Air Act of 1999) and RA 9003 (The Ecological
Solid Waste Management Act of 2000) declared by the government were a huge influence
to the leading of this project. As for the method, plastic sachets are first subjected to
undergo layer separation whereas the material is heated and shredded to produce
delamination. Subsequently, materials will undergo a reactor for pyrolysis for energy
recovery. This proposed method is exclusive for plastic sachet produced by Unilever
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CHAPTER 2
THEORETICAL FRAMEWORK
Products from companies such as Unilever are readily available to the public since
the introduction of sachet containers. Small markets and stores sell these small packs of
both food and non-food products instead of the larger variety to accommodate to a wider
market range. In a third world country, like the Philippines, these small packs of goods are
more patronized as majority of the people cannot afford to buy the larger ones. However,
when these goods get used up, the discarded sachet becomes a major problem when it
comes to municipal solid waste. According to the National Solid Waste Management
Status Report (2008-2014) done by the Environmental Management Bureau under the
10.55% by weight to the total municipal solid waste. Also, according to a study conducted
by the World Bank, municipal solid wastes generated in the Philippine cities will go up by
165 percent to 77,776 tons per day from 29,315 tons (2012) as a consequence of a
With these numbers, several studies and programs have been done to promote
utilization and disposal of plastic products. Unilever Philippines developed their Sachet
Recovery Program which collects and makes use of empty sachets which are then
converted to cement pavers for landscape and pathway purposes (Dinglasan, 2015).
invented a three-step process which was able to separate a base plastic from another
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plastic separated by a layer of an adhesive plastic. After washing, the material is first
which is within 67 80 C, and TC 20 C. This can be carried out by any known means
such as lamps or resistances emitting infrared radiation. The material is then shredded by
being subjected to shearing at the same temperature as the first stage. This starts the
delamination and converts the materials into particles of small dimensions of two types:
one is mostly the base plastic, and the other is the secondary plastic with the adhesive
plastic. The particles are then charged, for example, by corona discharge or by subjecting
them to friction. They can now then be separated by letting them pass through two
With the components of sachet now separated, individual disposal methods for
article posted 2009, incineration was conducted without separating materials causes harm
to environment. This un-separated waste was not free from bulky and recyclable materials,
even. This resulted in risk for plant workers health and environment.
Polyethylene, when subjected to pyrolysis, was able to produce gases which are suitable
for feedstock and as fuel (Ademiluyi, et al., 2007). Also, in incineration of LDPE, only water
and carbon dioxide are produced. However common additives like UV-stabilizators (e.g.
carbon black), dyeing agents and fire protectors can produce other waste products.
Heating value is equivalent to 3/4 kg of oil (Lenau, 2003). HDPE is considered one of the
safest plastics because it is very non-reactive. According to the EPA, it burns into carbon
dioxide and water vapor, and leaves no toxic waste. Any film additives also become simple
oxides, just like HDPE. Generally speaking, the CO2 production from HDPE incineration is
considered minor as it partially offsets CO2 production of fuel oil plants. The consumption
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of crude oil, natural gas, and pit coal, normally used in district heating plants can be
substantially lowered by the incineration of plastic waste. According to the EPA, some
plastics may emit nitrous oxide with incomplete combustion; however, since HDPE doesnt
contain nitrogen, there are no NO2 emissions. HDPE usually has a higher energy value
than other materials commonly found in the waste stream and fewer pollutants. Pound for
pound, it generates about twice the energy as Wyoming coal and almost as much energy
as fuel oil. When processed in modern waste-to-energy facilities, the HDPE helps other
recovery of energy from the incineration of waste is the accepted practice, aluminum foil
becomes a useful source of heat energy. Under the furnace conditions of an incineration
plant, foil releases its latent energy by combining with oxygen to release heat. Although
aluminum foil is a tiny proportion of the total waste stream, it is nonetheless a positive fuel
substitute, helping to reduce the amount of fossil fuel needed to sustain the incineration
process. During oxidation, aluminum gives off no polluting or green house gas and the
resulting residue represents the return of the metal to aluminum oxide, an inert compound
similar to that from which the metal was originally extracted. In less pure forms, aluminum
oxide occurs in most soils, and disposal of this residue is therefore totally safe. (2002)
incineration. Aluminum does not burn during incineration but its surface oxidizes partly into
its oxide Al2O3, releasing a quantity of energy, 31.6 MJ/kg, equivalent to that resulting
from the combustion of plastic, paper and even oil. The outer alumina layer offers a major
advantage as it prevents the aluminum substrate from further oxidation. This property is
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highly valued and widely used in some industrial processes, especially for the controlled
voluntary deep oxidation (anodization) applied to aluminum extrusions for windows and
doors. Due to this surface treatment, these building products are well protected against
weather influences and do not need any additional maintenance for a considerable period
Plastics Inc.). However, the incinerator used must be capable of scrubbing out acidic
combustion products.
Extension, plastics, which include contaminated LDPE film, have a higher energy
value and heat content than most municipal solid waste materials. While taking up
seven percent of the waste stream by weight and 20 percent by volume, plastics
provide incinerators with 25 percent of the recoverable MSW energy. For example, a
pound of polyethylene supplies 19,000 Btu, but corrugated paper packaging provides
only 7,000 Btu. Because of their high Btu content, plastics can be incinerated as a
municipal solid waste or used as a supplement with other municipal solid wastes to
its very low biodegradability and presence in large quantities. Therefore, finding alternative
methods of disposing waste by using friendly methods are becoming a major research
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issue. Preferred options for disposal are recycling, incineration with energy recovery, and
landfill. The high value of this product makes incineration with energy recovery very
desirable for material that cannot be recycled, but incineration must be capable of
scrubbing out acidic combustion products that affects the environment, so producing
method/s that could help regulates its acidic combustion products can help the study. The
study plastic sachet disposal methods are: Separation of plastic sachet components then
For proper disposal of the sachet, it is recommended to first separate each component
polymer before individual disposal methods are employed. Vandenhende and Yernaux of
adhesive plastic. The sachet used in Unilever products fall on this category as it has HDPE
as its base plastic, PET as its second plastic which are attached to the foil by a polymer
adhesive resin which is mostly ethylene acid. The multilayer plastic is subjected to the
Procedure of Incineration:
Combustion in a furnace, producing hot gases and a bottom ash residue for
disposal.
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Gas temperature reduction, frequently involving heat recovery via steam
generation.
Treatment of the cooled gas to remove air pollutants, and disposal of residuals
PET, as with many plastics, is also an excellent candidate for thermal disposal
(incineration), as it is composed of carbon, hydrogen, and oxygen, with only trace amounts
of catalyst elements (but no sulfur). PET has the energy content of soft coal.
When recycling polyethylene terephthalate or PET or polyester, in general two ways have
to be differentiated:
1. The chemical recycling back to the initial raw materials purified terephthalic acid
(PTA) or dimethyl terephthalate (DMT) and ethylene glycol (EG) where the
hydroxyethyl) terephthalate
2. The mechanical recycling where the original polymer properties are being
maintained or reconstituted.
Polyethylene
The high density polyethylene (HDPE) used in the production of NOAXE reusable
bags is made from a natural gas feed stock. It is a hydrocarbon consisting primarily of
oxygen, hydrogen, and carbon. HDPE is considered one of the safest plastics because it is
very non-reactive.1 According to the EPA, it burns into carbon dioxide and water vapor,
and leaves no toxic waste. Any film additives also become simple oxides, just like HDPE.2
Generally speaking, the CO2 production from HDPE incineration is considered minor as it
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partially offsets CO2 production of fuel oil plants.3 The consumption of crude oil, natural
gas, and pit coal, normally used in district heating plants can be substantially lowered by
the incineration of plastic waste.4 According to the EPA, some plastics may emit nitrous
oxide with incomplete combustion, however, since HDPE doesnt contain nitrogen, there
are no NO2 emissions. 5 HDPE usually has a higher energy value than other materials
commonly found in the waste stream and fewer pollutants. Pound for pound it generates
about twice the energy as Wyoming coal and almost as much energy as fuel oil. 6 When
processed in modern waste-to-energy facilities, the HDPE helps other waste materials
Aluminum
In countries where the recovery of energy from the incineration of waste is the
accepted practice, aluminum foil becomes a useful source of heat energy. Under the
furnace conditions of an incineration plant, foil releases its latent energy by combining with
oxygen to release heat. Although aluminum foil is a tiny proportion of the total waste
stream, it is nonetheless a positive fuel substitute, helping to reduce the amount of fossil
During oxidation, aluminum gives off no polluting or green house gas and the resulting
residue represents the return of the metal to aluminum oxide, an inert compound similar to
that from which the metal was originally extracted. In less pure forms, aluminum oxide
occurs in most soils, and disposal of this residue is therefore totally safe.
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VII. RESEARCH PARADIGM
Input Process
Fuel gases
Evaluation of Acceptability Energy
For better understanding of the study and to help the readers understand it, the following
Aluminum Foil. In this study, it is the innermost layer or component of the plastic sachet.
Plastic Sachet. It refers to the packaging material with components made up of multi-
layered films.
Polyethylene Terephthalate. It refers to the next layer of sachet covering aluminum foil.
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Cleaning/
Collection Separation Disposal
Drying
CHAPTER 3
sachets, that also includes the segregation of food-grade and non-food-grade plastic
sachets, then it will undergo cleaning process to remove the remaining contents.
Subsequently, these sachets will be dried and then will be subjected to a process for
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Figure 2. Project Design Flow
X. PROJECT DEVELOPMENT
This project development relates to the separation of a multilayer material based on plastic
separation of constituents of a multilayer material including a base plastic and a layer of a barrier
Such multilayer materials are commonly employed in diverse industries, for example in the
These sachets, although economical and does provide low-price products for the
consumers, have contributed to the countrys heavy unmanageable solid waste since the
constituents of these sachet has a low rate of degradation. Studies are being done to efficiently
and ecologically dispose these materials. However, In the case of multilayer materials the
grind the multilayer material into particles and to reemploy them in the manufacture of a new
product, the latter runs the risk of exhibiting mediocre mechanical performance and therefore the
quantities of material thus recycled must be greatly restricted. It is therefore desirable to have
available a simple and effective method enabling the constituents of multilayer materials to be
separated with a view to being able to reemploy them in a manner which is comparable with virgin
constituents, without affecting the performance of the new product manufactured from constituents
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1. COLLECTION
The initiation step for this research study is the collection of used Unilevers plastic sachets
within a barangay. It also includes the segregation of food grade and non-food grade plastic
sachets.
2. CLEANING
After the collection of sachets from the sources, it will undergo cleaning where the residue
The process in which we will be separating the multilayer material into two components
including a layer of base plastic (A) and a layer of plastic (B) separated by a layer of adhesive
plastic (C) was patented by Vandenhende and Yernaux of Belgium (1999). Plastic is intended to
denote any polymer or polymer mixtures. Evidently, the variable of this research which is the
sachet produced by the Unilever contains a layer of Polyethylene, Aluminum, and Polyethylene
terephthalate which are also thermoplastic and thus making it suitable for the process. However,
each of the plastics (A, B, C) may in addition optionally contain one or several conventional
According to the tests ran by Vandenhende and Yernaux, there are characteristics of each
Layer Description
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Base plastic (A) - represents more than 80% of the total
(HDPE).
conventional polymers
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in particular polyethylene or
anhydride.
essentially of polyethylene or of
With the knowledge of how compatible our variables are with the required or suggested
characteristics of each layer, the multilayer plastic is now subjected to the following process:
Heating
Before the heating begins, it may optionally include washing or else chopping at an ambient
temperature, intended to reduce the materials into medium dimension. The material is heated to a
temperature between the crystallization temperature (Tc) of the second plastic (B), which is within
67 80 C, and TC 20 C. This can be carried out by any known means such as lamps or
resistances emitting infrared radiation. The purpose of heating is to bring the material to a
Shredding
The material is then shredded by being subjected to shearing at the same temperature as
the first stage. Surprisingly, it has been found that the fact of subjecting the multilayer material to
shearing forces at a temperature slightly lower than the crystallization temperature of the plastic B
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makes it possible to effect the separation of, on the one hand, A and, on the other hand B+C. This
justifies the main goal of the process- to separate the base plastic from the other plastics.
The material is preferably shredded in an impeller mill. This type of equipment is well
known as such; it generally consists of a rotary drum provided with blades at its periphery, rotating
in a vessel to which blades are also secured. A model capable of producing particles from
to perform the separation with a high efficiency. This starts the delamination and converts the
materials into particles of small dimensions of two types: one is mostly the base plastic, which in
this case is the Polyethylene, and the other is the Aluminum film along with the adhesive plastic.
Electrostatic Separation
In this stage, the particles are charged at a temperature of at least 50 C, for example, by
corona discharge or by subjecting them to friction which may involve mutual friction, for example in
a fluidized bed, or else friction of the particles on a moving member (drum, belt or the like) of an
appropriate nature (glass, plastic, or the like). They can now then be separated by letting them
pass through two deflecting electrodes with continuous and high potential difference.
After separation of the particles X (A) and Y (B+C) the particles Y are advantageously subjected to
a subsequent stage (4) of separation making it possible to collect, on the one hand, the plastic B
and, on the other hand, the adhesive plastic. This time, recovering plastic B for further uses by
dissolving the Y particles in a water/alcohol solution with heating should the plastic B consists of
4. INCINERATON
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After the separation of components of plastic sachets, each component will undergo
incineration process with energy recovery and a scrubber where acidic substances are absorb in
Procedure of Incineration:
Combustion in a furnace, producing hot gases and a bottom ash residue for disposal.
Gas temperature reduction, frequently involving heat recovery via steam generation.
Treatment of the cooled gas to remove air pollutants, and disposal of residuals from
START
COLLECTION
CLEANING
SEPARATION
OF EACH
COMPONENT
INCINERATION
END
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XI. TESTING AND OPERATING PROCEDURE
The efficiency of the separation of each component of the sachet shall be tested by
manipulating the process. The electrostatic separation part of the separation involves trial
and error to work out the best combination of controlling factors. When the best
combination has been applied, the separating efficiency is very high. This results to a
After the separated components have been incinerated, the resulting gases
produced will undergo sanitary testing whether these gases can be allowed to be released
The energy recovered from incineration can be used to measure the amount of
XII. EVALUATION
components of plastic sachets and to test the concentration of treated gases produced
atmosphere.
gases to atmosphere)
PE 19,000 BTU/lb
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Aluminum 31.6 MJ/kg
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