P (kPa) x1 y1

29.819 0 0
31.957 0.0455 0.1056
33.553 0.094 0.1818
35.285 0.1829 0.2783
36.457 0.2909 0.3607
36.996 0.398 0.4274
37.608 0.5069 0.4885
36.978 0.5458 0.5098
36.778 0.5946 0.5375
35.792 0.7206 0.6157
34.372 0.8145 0.6913
32.331 0.8972 0.7869
30.038 0.9573 0.8916
27.778 1 1

P1s = 27.778
P2s = 29.819

Tabel 1
P (kPa) x1 y1 x2 y2 1 2 ln 1 ln 2 GE/RT (GE/RT)/x1x2
29.819 0 0 1 1 1 0 0
31.957 0.0455 0.1056 0.9545 0.8944 2.67004 1.00422 0.98209295 0.00421 0.048705 1.1214563
33.553 0.094 0.1818 0.906 0.8182 2.33613 1.01618 0.84849434 0.01605 0.094298 1.1072514
35.285 0.1829 0.2783 0.8171 0.7217 1.93281 1.04515 0.65897372 0.04416 0.15661 1.0479233
36.457 0.2909 0.3607 0.7091 0.6393 1.62736 1.10226 0.48695617 0.09736 0.210697 1.0214268
36.996 0.398 0.4274 0.602 0.5726 1.43023 1.18009 0.3578338 0.16559 0.242105 1.0104736
37.608 0.5069 0.4885 0.4931 0.5115 1.30473 1.30827 0.26599818 0.26871 0.267334 1.0695385
36.978 0.5458 0.5098 0.4542 0.4902 1.24339 1.33837 0.21784468 0.29145 0.251278 1.0136155
36.778 0.5946 0.5375 0.4054 0.4625 1.19685 1.40709 0.17969535 0.34153 0.245302 1.0176345
35.792 0.7206 0.6157 0.2794 0.3843 1.10093 1.65096 0.0961557 0.50136 0.209369 1.039901
34.372 0.8145 0.6913 0.1855 0.3087 1.05022 1.91825 0.04899739 0.65141 0.160745 1.0639055
32.331 0.8972 0.7869 0.1028 0.2131 1.02082 2.24759 0.02060455 0.80986 0.10174 1.1030827
30.038 0.9573 0.8916 0.0427 0.1084 1.00715 2.55729 0.00711969 0.93895 0.046909 1.1475654
1 1 0 0 0 0

A12 = a= 1.0552
A21 = b= 1.0719
Tabel 2
x1 y1 x2 y2 ln 1* ln 2* GE/RT* (GE/RT)/x1x2* 1* 2* Pcalc (kPa)
0 0 1 1 1.0552 0 0 1.0552 2.87255 1 29.819
0.0455 0.1056 0.9545 0.8944 0.96275 0.00215 0.04586 1.05595985 2.61888 1.002155 31.833581
0.094 0.1818 0.906 0.8182 0.86872 0.0092 0.09 1.0567698 2.38387 1.009246 33.490402
0.1829 0.2783 0.8171 0.7217 0.70859 0.03494 0.15815 1.05825443 2.03112 1.035562 35.550868
0.2909 0.3607 0.7091 0.6393 0.53546 0.0887 0.21867 1.06005803 1.70824 1.092756 36.909593
0.398 0.4274 0.602 0.5726 0.38723 0.16661 0.25441 1.0618466 1.47289 1.181291 37.48915
0.5069 0.4885 0.4931 0.5115 0.26069 0.27119 0.26587 1.06366523 1.29782 1.311525 37.558503
0.5458 0.5098 0.4542 0.4902 0.22145 0.3148 0.26385 1.06431486 1.24788 1.369982 37.474139
0.5946 0.5375 0.4054 0.4625 0.17669 0.37418 0.25675 1.06512982 1.19326 1.453802 37.283221
0.7206 0.6157 0.2794 0.3843 0.08425 0.55175 0.21487 1.06723402 1.0879 1.736295 36.242195
0.8145 0.6913 0.1855 0.3087 0.03725 0.707 0.16149 1.06880215 1.03795 2.027897 34.700922
0.8972 0.7869 0.1028 0.2131 0.01147 0.86008 0.09871 1.07018324 1.01153 2.363352 32.454478
0.9573 0.8916 0.0427 0.1084 0.00198 0.98101 0.04379 1.07118691 1.00198 2.667141 30.040637
1 1 0 0 0 1.0719 0 1.0719 1 2.920924 27.778
 40

35

30
14; 27.778
25
P (KPa)

20
x1
15 y1

10

0
0 0.2 0.4 0.6 0.8 1 1.2

x1, y1

1.2
(GE/RT)/x1x2

1.15

1.1

f(x) = 0.0166809885x + 1.0552403767

1.05 R = 0.0122328803

(GE/RT)/x1
x2
1 Li near
((GE/RT)/x
1x2)

0.95

0.9
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1

1.4

1.2

0.8
 1.4

1.2

y1calc 1

0
0.8
0.103978 40
0.185862
35 0.6
0.290268
0.373985 30
0.4
0.434359
P (kPa)

25
0.486552 0.2
0.504865 20
0.528623 0
15 0 0.2 0.4 0.6 0.8 1 1.2
0.600857
0.676748 10
0.776776 x1
5 l n 1 l n 2 GE/RT (GE/RT)/x1x2
0.886953
l n 1* l n 2* GE/RT* (GE/RT)/x1x2*
1 0
0 0.2 0.4 0.6 0.8 1 1.2

x1, y1

P-x1 P-y1 Pcal c-x1 Pcal c-y1cal c

r
1.2