EQUILIBRIO LIQUIDO-VAPOR

DIAGRAMA x -y
BENCENO(1)-TOLUENO(2)
760 mm Hg

0.9

0.8

0.7

0.6
Raoult
0.5 exp Gültekin
y

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x
 EQUILIBRIO LIQUIDO-VAPOR
DIAGRAMA x,y - T
BENCENO(1)- TOLUENO(2)
760 mm Hg
390

380

x-T Raoult
370 y - T Raoult

x - T exp. (Gültekin)

y - T exp. (Gültekin)

360
T

350

340

330
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x, y
 ELV BENCENO(1) - TOLUENO(2) IDEAL ISOBARICO
343 400
BENCENO(1) TOLUENO(2)
TC 562.2 591.8
PC 48.9 41
Tb 353.2 383.8
VpA -6.98273 -7.28607
VpB 1.33213 1.38091
VpC -2.62863 -2.83433
VpD -3.33399 -2.79468
EC. 1 1
Presión atmos 1.01325 bar
PHI 1
gamma 1

0 x1 x2 TOC TK alfa1 ln(Pvp/Pc)

1 0 1 110.7083883 383.8583883 0.317220939 -3.02348012
2 0.05 0.95 108.4211331 381.5711331 0.32128934 -3.08190846
3 0.1 0.9 106.2285977 379.3785977 0.325189261 -3.13867913
4 0.15 0.85 104.1576457 377.3076457 0.328872918 -3.19300111
5 0.2 0.8 102.1940919 375.3440919 0.332365543 -3.24514619
6 0.25 0.75 100.3272053 373.4772053 0.335686223 -3.29531312
7 0.3 0.7 98.54866789 371.6986679 0.338849755 -3.34364971
8 0.35 0.65 96.85201202 370.002012 0.341867641 -3.39026413
9 0.4 0.6 95.23142901 368.381429 0.344750215 -3.43525495
10 0.45 0.55 93.6816386 366.8316386 0.347506868 -3.47871358
11 0.5 0.5 92.17523066 365.3252307 0.350186356 -3.52136786
12 0.55 0.45 90.76482033 363.9148203 0.35269509 -3.56167769
13 0.6 0.4 89.40687059 362.5568706 0.355110511 -3.60083458
14 0.65 0.35 88.09885201 361.248852 0.357437118 -3.63887737
15 0.7 0.3 86.80959682 359.9595968 0.359730351 -3.67669131
16 0.75 0.25 85.6242692 358.7742692 0.361838724 -3.71173815
17 0.8 0.2 84.4245016 357.5745016 0.363972783 -3.74748956
18 0.85 0.15 83.3100865 356.4600865 0.365955022 -3.78095073
19 0.9 0.1 82.23012833 355.3801283 0.367875972 -3.8136126
20 0.95 0.05 81.18323278 354.3332328 0.369738113 -3.84549805
21 1 0 80.19616707 353.3461671 0.371493833 -3.8757649

X y TC T K
0 0 110.05 383.2
0.1 0.208 105.31 378.46
0.2 0.372 101.46 374.61
0.3 0.507 98 371.15
 0.4 0.619 95.05 368.2
0.5 0.713 92.3 365.45
0.6 0.791 89.74 362.89
0.7 0.857 87.29 360.44
0.8 0.912 84.99 358.14
0.9 0.959 82.68 355.83
0.95 0.98 81.43 354.58
1 1 80.13 353.28
OBARICO

pvp alfa2 ln(pvp/pc) pvp y1 y2 y1+y2

2.378089131 0.351371429 -3.70121662 1.012432095 0 0.999192791 0.999192791
2.243122649 0.355236341 -3.76661321 0.948340994 0.110689497 0.889142802 0.999832299
2.119326321 0.3589412 -3.83016514 0.889947261 0.209161246 0.790478693 0.999639938
2.007271394 0.362440612 -3.89098519 0.837433753 0.297153426 0.702510427 0.999663853
1.905284239 0.365758547 -3.94937598 0.789935555 0.376073869 0.623684623 0.999758491
1.812059923 0.368913137 -4.0055587 0.74677852 0.447091025 0.552759822 0.999850847
1.726554293 0.371918439 -4.05969773 0.707423587 0.511192981 0.488720958 0.999913939
1.64791898 0.37478538 -4.11191322 0.67143293 0.569229354 0.430724307 0.999953661
1.575420856 0.377523777 -4.16231474 0.638430364 0.621927799 0.378049068 0.999976867
1.508421608 0.380142551 -4.21100396 0.6080903 0.669913371 0.330076156 0.999989527
1.445433873 0.382688018 -4.25879574 0.579712104 0.71326616 0.286065682 0.999331842
1.388327387 0.385071274 -4.3039639 0.554110123 0.75359493 0.246088878 0.999683807
1.335015387 0.387365883 -4.34784297 0.530322004 0.790534648 0.20935485 0.999889498
1.285181598 0.38957612 -4.39047608 0.508187902 0.824444153 0.175539862 0.999984016
1.237491174 0.391754652 -4.43285503 0.487101398 0.854916183 0.144219511 0.999135694
1.194872215 0.393757571 -4.47213475 0.468339095 0.884435392 0.115553687 0.99998908
1.152908455 0.395784891 -4.51220592 0.449943232 0.910265743 0.088811889 0.999077632
1.114969072 0.397667985 -4.54971168 0.433380314 0.935330581 0.064156967 0.999487548
1.079140393 0.399492855 -4.58632287 0.417800679 0.958525886 0.041233721 0.999759607
1.045274312 0.401261857 -4.62206495 0.403131332 0.980025262 0.019892985 0.999918246
1.014111134 0.402929762 -4.6559937 0.389683023 1.000849873 0 1.000849873

DATOS EXPERIMENTAES DE GÜLTEKIN Benceno(1) + Tolueno(2)

PRESIÓN 1 atm = 1.01325 bar
x1 y1 T/K gamma1
0.008 0.018 383.9 1.098
0.022 0.051 383.17 1.076
0 0 0.077 0.17 380.45 1.069
1 1 0.088 0.191 379.95 1.068
 0.23 0.424 373.94 1.049
0.352 0.573 369.53 1.035
0.449 0.668 366.44 1.025
0.519 0.727 364.37 1.019
0.599 0.786 362.2 1.014
Benceno(1) + Tolueno(2)
25 bar
gamma2
1
1
1.001
1.001
1.004
1.01
1.017
1.022
1.03