Professional Documents
Culture Documents
CONTENT:
EXPERIMENT 1 PAGE
a) USE OF pH METER 1
b) DETERMINATION OF ACIDITY 8
OF WATER SAMPLES
c) DETERMINATION OF 14
ALKALINITY OF WATER
SAMPLES
EXPERIMENT 2
a) DETERMINATION OF SOLIDS IN 21
WATER
b) DETERMINATION OF HARDNESS 28
IN WATER
REFERENCE 37
DECLARATION 38
APPENDIX 39
GROUP 24 1 1
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
OBJECTIVES:
The objective of this test is determined pH of the given water samples by using pH
meter and pH paper.
THEORY:
pH
pH is a numerical representation of acidic or basic nature of solutions.
Water ionizes to a small degree. The ionization is represented by:
H2O H + + OH -
p Notation
pX = -log10 X
GROUP 24 2 2
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
pH = -log [H+]
pH < 7 ; acidic solution
pH = 7 ; neutral solution
pH > 7 ; alkaline solution
In general,
pH + pOH = 14
APPARATUS:
o pH Meter,
o Volumetric Cone and
o Cylindrical
pH METER
PROCEDURES:
GROUP 24 3 3
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
a) At first we calibrate the pH meter with buffer solutions (pH 4.01 and
7.01).
b) We have rinsed the electrode of the pH meter with distilled water and dry
it with a piece of tissue paper.
c) Then we determine the pH value for the following water samples by
immersing the pH meter electrode into them.
i) Distilled water
ii) Laboratory tap water
iii) Untreated sewage sample
Notes: Rinse your electrode with distilled water and dry it with a piece of tissue
paper before measuring each samples pH
GROUP 24 4 4
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
RESULTS:
pH meter reading
Sample
I II III Average
(b ) Untreated sewage
sample 6.87 6.94 6.97 6.93
GROUP 24 5 5
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
DISCUSSION:
Use of pH meter
GROUP 24 6 6
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
CONCLUSION:
GROUP 24 7 7
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
laboratory tab water and untreated sewage sample are acidic. The standard value for
wastewater is 5.5 to 9 (standard A) and 5.0 to 9.0 (standard B) respectively.
OBJECTIVE:
To determine various forms of acidity in the given water samples.
THEORY:
Acidity
Both CO2 and mineral acidity can be measured by titration with a standard alkaline
solution. Mineral acids are measured by titration to a pH of 4.5. Titration to the pH 8.3
end point measures total acidity i.e. both mineral acidity as well as due to weak acids.
APPARATUS:
o pH Meter,
o Volumetric Cone,
o Cylindrical,
o Retort Stand and
o Burette.
GROUP 24 8 8
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
PROCEDURES:
a) For samples with pH 0 4.5 (i.e. mineral acidity), we take 50ml sample and
titrate it using N/50 NaOH and methyl orange as indicator (colour change from
red to orange).
b) For samples with pH 4.5 8.3 (i.e. CO2 acidity), we take 50ml sample and titrate
it using N/50 NaOH and phenolphthalein as indicator (colour change from
colourless to pink).
c) We have recorded the concentration and type of acidity.
RESULT:
Experiment 1b: Determination of Acidity Water Samples
Sample Volume = 50 ml
pH value = 2.96
Burrete Reading
Type of Acidity
Volume of NaOH
Start ( 0.05 ml) End ( 0.05 ml)
(ml)
Carbon Dioxide
Acidity 27.60 40.10 12.50
GROUP 24 9 9
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
Sample Volume = 50 ml
pH value = 6.93
Burrete Reading
Type of Acidity
Volume of N/50
Start ( 0.05 ml) End ( 0.05 ml)
NaOH (ml)
CALCULATION:
GROUP 24 10 10
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
1000
Total acidity = ml of N/50 NaOH x mlsample
1000
= 12.50 x
50
= 250.00 mol/l
DISCUSSION:
GROUP 24 11 11
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
Acidity
pH is a measure of a water sample's deviation from a neutral value of 7.00, it
provides little information about a water sample's ability to neutralize acids or bases.
The standard procedures for "acidity" and "alkalinity", which have been modified here
to fit the time and equipment requirements of a student laboratory,
quantitatively provide that information.
The acidity of a water sample is its capacity to neutralize hydroxide ions.
Acidity may be caused by mineral acids such as sulfuric acid or hydrochloric acid or by
dissolved carbon dioxide. Most commonly in drinking water, carbon dioxide is the
principal cause of acidity. Acidity increases the corrosive behavior of water. Drinking
water with a high acidity is likely to be corrosive to copper water pipes and to the solder
which joins those pipes. High levels of copper and lead in drinking water often occur
when acidic water stands in pipes for extended periods of time (such as over night). In
addition to creating a possible health hazard due to dissolved metal ions, acidity in
water can cause copper plumbing to develop pin hole leaks after a few years.
Acidity is generally measured by titration with sodium hydroxide to an accepted
pH value. Phenolphthalein is an acid-base indicator which changes from colourless to a
pink (magenta) at a pH of about 8.3.
Generally, acidity is measured by titration of a water sample to pH 8.3 with
NaOH titrant. Metacresol purple also changes color at pH 8.3, but gives a sharper color
change than phenolphthalein. If available, its use is recommended over phenolphthalein.
If a water sample is at the alkaline color of the indicator before any titrant is added, then
the acidity is zero and the alkalinity of the water should be tested.
Because CO2 is the most likely cause of acidity in water, the water sample
should be collected within a few hours of the time of analysis. The container used to
collect the water should be filled completely and closed with an air-tight seal. A clean
plastic soft drink bottle with screw cap is suitable for water samples tested in this
procedure.
GROUP 24 12 12
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
GROUP 24 13 13
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
CONCLUSION:
From the calculation based on the information we obtained, the result we get for
laboratory tap water sample:
Mineral acidity = 230 mol/l
Total acidity = 250 mol/l
Carbon Dioxide acidity = 20 mol/l
The acidity is quite high if we refer the data above, so the treatment is required upon the
water.
OBJECTIVE:
THEORY:
Alkalinity
Alkalinity is measured by titration with a standard acid solution. The end points of
importance for the titration are those of pH 8.3 and 4.5.
GROUP 24 14 14
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
APPARATUS:
o pH Meter,
o Volumetric Cone,
o Cylindrical,
o Retort Stand and
o Burette.
PROCEDURES:
a) We have taken 50ml of untreated sewage and add it with the appropriate
indicator.
b) (i) The pH of the sample is greater than 8.3, hence we titrate the sample by using
N/50 H2SO4 and phenolphthalein as indicator (colour change from pink
to colourless).
To the same sample add methyl orange indicator to find total alkalinity (colour change
from orange to red).
GROUP 24 15 15
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
(ii) For the sample pH lies between 4.5 and 8.3 that means only bicarbonate
alkalinity is present. We titrate the sample with N/50 H2SO4 using methyl orange as
indicator (colour change from orange to red).
c) We have determine various forms of alkalinity with the help of following guide :
RESULT:
Experiment 1c : Determination of Alkalinity Water Samples
Burrete Reading
Type of Acidity
Volume of N/50
Start ( 0.05 ml) End ( 0.05 ml)
NaOH (ml)
GROUP 24 16 16
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
Burrete Reading
Type of Acidity
Volume of N/50
Start ( 0.05 ml) End ( 0.05 ml)
NaOH (ml)
CALCULATION:
Experiment 1c: Determination of Alkalinity Water Samples
ii) Untreated sewage sample
Sample volume = 50 ml
pH value = 6.43
Total H2SO4 = 8.7 ml
Phenolftalein alkalinity (P) = 0
Total alkalinity (M) = total ml H2SO4 x 1000
ml sample
= 8.7 x 1000 / 50
= 174 mol/l
GROUP 24 17 17
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
Types of alkalinity = HCO3- alkalinity (4.5 < pH < 8.3; all alkalinity is HCO3-)
DISCUSSION:
Alkalinity
GROUP 24 18 18
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
Since the total alkalinity = 174 mg/l as CaCO 3 and P = 0 and M = 8.7 ml. Therefore the
predominant species are bbicarbonate, HCO3-. Type of alkalinity is acid.
GROUP 24 19 19
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
1.Which ions other than hydroxide (OH-), carbonate (CO32-) and bicarbonate
(HCO3-)can cause alkalinity in water?
Alkalinity is defined as the ability of water to resist a change in pH when acid is
added; it relates to the pH buffering capacity of the water. Almost all natural
waters have some alkalinity. This is natures mean keeping the pH neutral, and
stable, so that life can exist there. Three major ions contribute to total alkalinity.
However other ions such as organic nitrogen, ammonia nitrogen, nitrite nitrogen,
nitrate nitrogen, phosphate PO42- , sulphate SO42- , chloride Cl- , fluoride F- , and
cyanide CN- can also cause alkalinity in water.
CONCLUSION:
Relative to the pH scale the various type of alkalinities reside. In other words,
these ions have the capacity to hold to the pH of the water at these ranges, depending on
how much of each is represent. Now picture titrating with an acid into a water with
carbonate alkalinity. By the time pH 8.3 is reached, exactly half the carbonate alkalinity
has been neutralized. This is always the case. One of the reasons that phenolphthalein
GROUP 24 20 20
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
was chosen as a useful indicator for this method was that it does visually show this
point.
The total alkalinity of the effluent sample obtained from the experiment is 174
mg/l as CaCO3 with P = 0 and M = 8.7 ml. Therefore the only predominant species is
bicarbonate ions (HCO3-). Since the pH of the effluent sample is only 6.43 which does
not exceed 8.3, therefore the effluent alkalinity is at its required standards for alum to
react with suspended solid and settle as sludge. The alkalinity in water plays an
important role in waste water treatment especially in the lumping and flocking process.
OBJECTIVES:
To determine the amount of total solids (TS), suspended solids (SS) and
volatile suspended solids (VSS) in the given wastewater samples.
THEORY:
Solids in wastewater
Solids - Water normally contain solid material, both in dissolved and suspended forms.
Solids are also further classified as fixed or volatile. Fixed solids are basically the ash
GROUP 24 21 21
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
left over after burning the dried solids; volatile solids are those that are lost in this
procedure. The sum of the two is referred to as total. Volatile solids are often used as an
estimate of the organic matter present.
Suspended material can decrease the depth of the body of water. If there is a lot of
biodegradable organic material in the sediment, it will become anaerobic and contribute
to oxygen depletion. Toxic materials can also accumulate in the sediment and affect the
organisms which live there and can build up in fish that feed on them, and so be passed
up the food chain, causing problems all along the way . Also, some of the particulate
matter may be grease-- or be coated with grease, which is lighter than water, and float to
the top, creating an aesthetic nuisance.
APPARATUS:
o Volumetric Cone,
o Cylindrical,
o Filtration Unit,
o Vicar and
o Heat Bowl
PROCEDURE:
GROUP 24 22 22
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
(ii) Cool the crucible in a desiccator and weight on an analytical balance to the
nearest 0.1 mg. (X)
(iii) Pour a suitable volume of sample into the crucible and evaporate the contents to
dryness on a steam bath.
(iv) Transfer to an oven at 104 C and dry to a constant weight (about 30 minutes).
(v) Cool the crucible in a desiccator and weight on an analytical balance to the
nearest 0.1 mg. (Y)
GROUP 24 23 23
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
RESULT:
GROUP 24 24 24
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
CALCULATION:
Suspended solids
Y X 1000
Suspended solids (SS) (mg/l) =
volumeofsample ml
= (0.3368 - 0.3027) x 1000
100
= 341.0000mg/l
Total Solids
Y X 1000
Total solids (TS) (mg/l) =
volumeofsample ml
= 21.0000mg/l
GROUP 24 25 25
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
DISCUSSION:
There are few types of solids in water. Total Dissolved Solids (TDS) consist mainly of
carbonates, bicarbonates, chlorides, sulfates, phosphates, nitrates, calcium, magnesium,
sodium, potassium, iron, manganese, and a few others. Total Suspended Solids (TSS) is
comprised of organic and mineral particles that are transported in the water column.
Total suspended solids (TSS) gives a measure of the turbidity of the water.
Solids in water are harmless to people, unless they exist in high amounts. Small
amounts of chlorides are necessary for normal cell functions in plant and animal life.
However, fish and aquatic animals can not live in high levels of chlorides. Phosphorus
is a necessity for all plant life, and nearly all fertilizers contain phosphates.
Suspended solids (SS) cause the water to be milky or muddy looking due to the light
scattering from very small particles in the water. Sometimes it is mixed with color, but
colored waters can also be clear. Normally, we notice suspended solids before we notice
anything else.
GROUP 24 26 26
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
Suspended solids reduce light penetration and submersed plant productivity. Suspended
solids also affect organisms that live in the water. Those organisms that depend on
plants for food and predators that rely on their visual abilities to hunt are adversely
affected. Suspended solids in a body of water also accelerate the process of
eutrophication. Eutrophication is the process whereby bodies of water become
fertilized. This fertilization causes a significant increase in the growth rate of algae and
other aquatic plants. With continued eutrophication, dissolved oxygen levels become
depleted further accelerating the process of eutrophication leading to eventual aquatic
collapse.
High levels of total dissolved solids can adversely industrial applications requiring the
use of water such as cooling tower operations; boiler feed water, food and beverage
industries, and electronics manufacturers. High levels of chloride and sulfate will
accelerate corrosion of metals.
The main function of the desiccator is to remove all the moisture exist on the surface of
the filter paper. Therefore the ignited filter paper should be put into the desiccator
before we weighing it, as the moisture exist on the surface of the ignited filter paper
may bring significant affection to the final weighing result.
CONCLUSION:
From the experiment, the effluent sample solid component comprises of suspended
solid and volatile suspended solid. The suspended solid content must be acknowledged
to simplify the waste water treatment process. Parameter values from the experiments
are as below.
GROUP 24 27 27
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
The allowed suspended solid in waste water is only 100 mg/l as stated in Environmental
Quality Act 1974. This is because suspended solid contains organic substances that are
the main parameter of wastewater.
OBJECTIVES:
To determine total, Ca and Mg hardness in the given wastewater samples.
THEORY:
Hardness
Hardness is the presence of multivalent metallic cations in solution. Metal ions like Ca
2+
, Mg 2+, Fe 2+, Mn 2+, Sr 2+ and Al 3+ would all contribute hardness.
However, in natural waters the major hardness contributing ions are Ca2+
and Mg 2+. Thus, generally total hardness is taken as the sum of Ca and Mg hardness.
Hardness of a water sample is determined by titration with ethylenediaminetetraacetic
acid (EDTA).
The amount of dissolved calcium and magnesium in water determines its "hardness."
GROUP 24 28 28
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
Hardness (mg/l) = 2,5 [conc. of Ca2+ (mg/l)] + 4,1 [conc. of Mg2+ (mg/l)]
The most frequently used standard classifies water supplies is shown in the following
table.
Hardness Scale
APPARATUS:
o Volumetric Cone,
o Cylindrical, Vicar,
o Heat Bowl
GROUP 24 29 29
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
PROCEDURES:
a) Total hardness
i) We have measured 100 ml of sample diluted to 100ml with distilled water into a
250 ml conical flask (hardness between 10 200 mg/l as CaCO3).
ii) 2 ml of ammonia buffer solution added in sample to get pH 10.
iii) 1 drop of Eriochrome Black T (EBT) added as indicator and mix it with the
sample.
iv) Then we titrate the sample with M/100 EDTA (colour change from red to
blue/grey).
v) The total hardness calculated as:
b) Ca hardness
GROUP 24 30 30
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
c) Mg hardness;
The Mg hardness calculated as:
Mg hardness = Total hardness Ca hardness
RESULT:
Total Hardness
Burette Reading
Calcium Hardness
GROUP 24 31 31
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
Burette Reading
CALCULATION:
1000
Total hardness (mg/l as CaCO3) = mlEDTA
mlsample
= 4.60 x 1000
100
= 46.00 mg/l as CaCO3
1000
Calcium hardness (mg/l as CaCO3) = mlEDTA
mlsample
= 3.20 x 1000
100
GROUP 24 32 32
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
DISCUSSION:
Hardness
Hardness is defined as the sum of the concentrations of calcium and magnesium
ions dissolved in water. These two ions are the major hardness constituents, and though
some other metals contribute to hardness, their concentrations in natural waters are so
much smaller that their significance as hardness is negligible.
Calcium is the most abundant dissolved cationic constituent of natural fresh
waters, and is widely distributed in the minerals of rocks and soil. It is fifth most
abundant element on earth and is found in every major land area of the world.
Magnesium is also a major constituents of rocks, in abundance second to
calcium ( about fifth as much ), and is usually found in occurrence with calcium.
The carbonate salts of calcium are the major source of dissolved calcium and are
generally referred to as limestone or calcite. They include Iceland spar ( pure ), marble
and alabaster ( less pure and more compressed ), and chalk. They can be white or
colorless. Calcium carbonate is quite isoluble in pure water and dissolves only up to 15
mg/l, but if CO2, is represent, this natural acidity make the lime stones much more
soluble. This often occurs in groundwater; bacterial action in the soil release CO2,
GROUP 24 33 33
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
changing the carbonates to bicarbonates, and dissolving large amounts of calcium into
the water. Because of this, groundwater is generally harder waters than surfaces water.
Hard water typically contains high concentration of Ca , Mg (and other) cations
which interfere with the use of the water for many application .(For example the ions
diminish the effectiveness of soaps and detergens for cleansing operations , they
diminish the drinking quality of water and contribute to accumulation of insoluble salt
deposit in storage vessels or plumbing.)
GROUP 24 34 34
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
3.Why are samples adjusted to different pH values for total and Ca hardness
determination?
The unit of the hardness is stated in CaCO3 equivalent . The water is defined as
Hard water if the hardness of the water is more than 150 mg/l as CaCO3
equivalent.And the value of soft water have the hardness in between 50-60
mg/l as CaCO3 equivalent.
GROUP 24 35 35
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
Two basic methods of softening water are chemical precipitation and ion
exchange.Other methods can also be used to soften water such as
electrodialysis , distillation , freezing and reverse osmosis.
Chemical precipitation is one of the more common methods used to soften
water.The chemical normally used are lime ( calcium hydroxide , Ca(OH) 2 ) and
soda ash ( sodium carbonate , Na2CO3).
Lime is used to remove the chemical that cause the carbonate and magnesium
non-carbonate hardness.Soda ash is used to remove the chemical that cause the
non-carbonate hardness.
When the lime and soda ash are added , the hardness-causing minerals form
nearly insoluble precipitates.When calcium hardness is removed in a chemical
softener , it is precipitates as calcium carbonate (CaCO 3).When magnesium
hardness is removed is a chemical softener , it is precipitated as magnesium
hydroxide (Mg(OH)2.
CONCLUSION:
From our experiment, we discover that our sample is good for experiment. From
calculation, we got very high notes for effluent sample that we used for experiment. The
result is:
Weve learnt that from our syllabus, those water need to recycle to be drink or for
housework to be done. The data shows that the total hardness is more that it should be.
From books, we already know that total hardness for water is given the value of 500 and
below. So, the sample is totally can be drink daily as the experiment show. After all, we
just have to remove the colour and the water is ready to be drink. Weve refer to the
Malaysian Standard for water drinking to determine total hardness that the water should
GROUP 24 36 36
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
have. Finally, it is shown that hardness is a factor, besides other factor as pH, the colour
and minerals in the sample
REFERENCE:
3. Kejuruteraan Air Sisa, Kualiti Air dan Air Sisa, Hamidi Abdul Aziz (1999),
Utusan Publication & Distributors Sdn Bhd, ms 19-30
5. Bekalan Air, Pembetungan dan Pengiran, Nik Ahmad Fuaad Nik Abillah, ms 61-
74.
GROUP 24 37 37
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
DECLARATION
WE, hereby make the declaration that we have successfully carry out
the experiment with cooperation from each member in the group. In order
to complete this lab report we have equally divided the jobs to every
member in the group.
GROUP 24 38 38
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
ABDUL AZIZ
MARSHIDAH 70195 DISCUSSION,
MUSTAPA CONCLUSION
APPENDIX
GROUP 24 39 39
EAA305 ENVIRONMENTAL ENGINEERING LABORATORY
EXPERIMENT 1 USE OF pH METER, DETERMINATION OF ACIDITY AND ALKALINITY WATER SAMPLES
EXPERIMENT 2. DETERMINATION OF SOIL AND HARDNESS IN WATER
GROUP 24 40 40