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Pollution
TYPICAL AIR POLLUTION SCENARIO
Air & Its Pollution
A person needs per
day about
0.7 kg of food
1.4 kg of water
14 kg of air
Air Pollution
Air pollution may be defined as the presence
in the air (outdoor atmosphere) of one or
more contaminants or combinations there
of in such quantities and of such durations
as may be or tend to be injurious to
human, animal or plant life, or property,
or which unreasonably interferes with
the comfortable enjoyment of life or
property or conduct of business.
Air Pollutants
A pollutant can be solid (large or sub-molecular),
liquid or gas .
It may originate from a natural or anthropogenic
sources or both.
It is estimated that anthropogenic sources have
changed the composition of global air by less
than 0.01%.
However, it is widely accepted that even a small
change can have a significant adverse effect
on the climate, ecosystem and species on the
planet.
Examples of these are CO, SOx, NOx, SPM,
PM10, PM2.5, CO2, ozone in the lower
atmosphere, and photochemical smog.
Air Pollution and Public Opinion
Not a new phenomena: Smoke from Burning of
Coal
Problems in many urban areas in late 1800s and
early 1900 due to coal use
1000s of deaths attributed to air pollution
episodes in London
large number of pollution sources
restricted air volume
failure to recognize problem
CO presence: lethal
Photochemical smog
Sources of Air Pollution
Why Air Quality?
1.Point sources
Stacks of thermal power plants, brick kilns, lime kilns, boilers etc.
2. Area sources
Cluster of point sources, spill of chemicals, crude/product spills in ocean etc.
3. Line sources
Car, scooter, train, aircraft: white line in sky behind a jet plane?
Types of Pollutants
Why Air Quality?
1. Primary pollutants
Pollutants which are being emitted into the air directly by point/area/line
sources.
Examples: CO, NOx, SOx, Pb, PM, PM10, PM2.5, VOCs etc.
2. Secondary pollutants
Pollutants which are getting formed from primary pollutants in the
atmosphere. Some of the reactions are catalyzed by sun light.
Examples: acid rains, smog, O3, H2O2, formaldehyde,
peroxy acetyl nitrate (PAN) etc.
Why Air Pollution?
Main cause: Combustion
Fuel (C,H,S,N,Pb,Hg,ash) + Air (N2 + O2)
CO2, CO, NOx, SOx, Pb, Hg, SPM,
PM10,PM2.5, VOCs
Fuel consumption (Annual)
Coal: 450 MT
Crude based products: 120 MT
Natural gas: 60 NBCM
Biomass: 350-400 MT
Why Air Pollution contd..
Usage/handling of Chemicals: paint,
varnishes, perfumes, CFCs, petrol
pumps, etc.
Fuel MW %age
Total Thermal 1,91,664 69.5
Coal 167,708 60.8
Sector Gas MW
22,962 %age8.3
State Sector Oil 96,015
994 34.80.4
Central Sector 73,671 26.7
Hydro 41,997 15.2
Private Sector 1,06,226 38.5
Nuclear 5,780 2.1
Total 2,75,912
RES 36,471 13.2
Total 2,75,912
Pollutants generation
Fuel Combustion
PM10
23%
S in coals:0.5-2.5%
Sox
43%
Sox
CO
VOC Pb
1%
Nox
VOC
PM10
Nox
25%
N2+O2=NOx
Pb CO
5% 3%
Transport
PM10 Sox
10% 1%
Sox
VOC
17% CO
Pb
CO Nox
36%
VOC
PM10
Nox
21%
VOC
51%
Agencies responsible for monitoring
state of air pollution in India
18.11.2009
Particulate Matter
Suspended Particulate Matter
Fine Particulate Matter
What is Particulate Matter?
Particulate matter, or PM, is
the term for particles found
in the air, including dust, dirt,
soot, smoke, and liquid
droplets.
These small particles can
remain suspended in the air
for long periods of time.
Some particles are large or
dark enough to be seen as
soot or smoke. Others are
so small that individually
they can only be detected
with an electron microscope.
Types of Fine Particulate Matter
Primary Particles
These particles are emitted directly
from air pollution sources such as
power plants, factories, automobile
exhaust, construction sites, unpaved
roads, wood burning etc.
Secondary Particles
Formed in the atmosphere indirectly
when gases from burning fuels react
with sunlight and water vapor and
are chemically transformed into
particles, secondary pollutants:
solid/liquid
A few definitions
Solid or liquid particles with sizes from
0.001 100 m may be in air
General term for these is aerosols
Dust originates from grinding or crushing
Fumes are solid particles formed when
vapors condense
Smoke describes particles released in
combustion processes
Smog is used to describe air pollution and
is a combination of smoke+fog
Hukka
Stokes Law
Where,
1991Norms 14 3.5 18
Bharat
4.0 1.1 7.0 0.15
stage-II
Bharat
2.1 1.6 5.0 0.10
Stage-III
Bharat
1.5 0.96 3.5 0.02
Stage-IV
Data of 1014
TREND OF PM10 LEVELS IN DELHI
Reason: CNG
40
20
Health Effects of Particulate Matter
Impact depends on particle size, shape
and composition
Large particles trapped in nose
Particles >10 m removed in
tracheobronchial system
Particles <0.5 m reach lungs but are
exhaled with air
Particles 2 4 m most effectively get
deposited in lungs
Health Effects from Particulate Matter
Many scientific studies have
linked breathing PM to a
series of significant health
problems, including:
aggravated asthma
increase in respiratory symptoms
like coughing and difficult or
painful breathing
chronic bronchitis
decreased lung function
premature death
Other Effects of PM
Visibility Impairment
PM is the major cause of
reduced visibility (haze).
Aesthetic Damage
Soot, a type of PM, stains and
damages stone and other
materials, including objects
such as monuments and
statues.
Plant Damage
PM can form a film on plant
leaves interfering with
photosynthesis and plant
growth
Particulate Matter and Taj
The deposition of
PM on the
shimmering
white marble of
the Taj Mahal
imparts yellow
tinge to the
marble surface
Carbon Monoxide
Most abundant air
pollutant
Produced by incomplete
combustion
insufficient O2
low temperature
short residence time
poor mixing
Major source (~ 77%) is
motor vehicle exhaust
Carbon Monoxide
Misc
10%
Industrial
7%
Fuel Combustion
6%
Misc
Industrial
Fuel Combustion
Transport
Transport
77%
Carbon Monoxide
Colorless and odorless
When inhaled, binds to hemoglobin in blood to form
carboxyhemoglobin, reducing the oxygen carrying capacity
brain function reduced, heart rate increased at lower levels
asphyxiation occurs at higher levels
Concentration Source
0.1 ppm Natural atmosphere level
0.5 to 5 ppm Average level in homes
1991Norms 14 3.5 18
Misc
Transport
45% Industrial
Fuel Combustion
Transport
Fuel Combustion
50%
Emission norms (NOx) for Heavy Diesel Vehicles
Norms CO( g/km) HC (g/km) NOx (g/km) PM(g/km)
1991Norms 14 3.5 18
Bharat
4.0 1.1 7.0 0.15
stage-II
Bharat
2.1 1.6 5.0 0.10
Stage-III
Bharat
1.5 0.96 3.5 0.02
Stage-IV
Oxides of Nitrogen (NOx)
primary
oxidants
produced:
ozone (O3)
formaldehyde
peroxyacetyl
nitrate (PAN)
Ozone and Ultraviolet Radiation (UVR)
Ultra-violet radiation (UVR) high energy electromagnetic wave emitted from the
sun. It is made up of wavelengths ranging from 100nm to 400nm.
UV radiation includes UV-A, the least dangerous form of UV radiation, with a
wavelength range between 315nm to 400nm, UV-B with a wavelength range
between 280nm to 315nm, and UV-C which is the most dangerous between 100nm
to 280nm. UV-C is unable to reach Earths surface due to stratospheric ozones
ability to absorb it.
Sun Protection Factor
Sunscreens: 4, 8, 15, 30, 45
The SPF of a sunscreen indicates the time period you can stay in the sun without burning based on your skin complexion.
Recommended SPF
Skin Type 1 hr 2 hr 3 hr 4 hr 5+ hr
Very Fair /
15 30 30 45 45
Extremely Sensitive
Fair / Sensitive 15 15 30 30 45
Fair 15 15 15 30 30
Medium 8 8 15 15 30
Dark 4 8 8 15 15
AQI
AQI categories and range
breathing discomfort to the people with lung disease such as asthma and
Moderate
discomfort to people with heart disease, children and older adults
respiratory effects even on healthy people and serious health impacts on people with
Severe
lung/heart diseases
The higher the AQI, greater the air pollution and health concerns