A B

CH4 1.702 CH4 0.009081 CH4

C2H6 1.131 C2H6 0.019225 C2H6
C3H8 1.213 C3H8 0.028785 C3H8
n-C4H10 1.935 n-C4H10 0.036915 n-C4H10
iso-C4H10 1.677 iso-C4H10 0.037853 iso-C4H10
C5H12 2.464 C5H12 0.045351 C5H12
C6H14 3.025 C6H14 0.053722 C6H14
C7H16 3.57 C7H16 0.062127 C7H16
C8H18 4.108 C8H18 0.070567 C8H18
C2H4 1.424 C2H4 0.014394 C2H4
C3H6 1.637 C3H6 0.022706 C3H6
C4H8 1.967 C4H8 0.03163 C4H8
C5H10 2.691 C5H10 0.039753 C5H10
C6H12 3.22 C6H12 0.048189 C6H12
C7H14 3.768 C7H14 0.056588 C7H14
C8H16 4.324 C8H16 0.06496 C8H16
Ac-C2H4O 1.693 Ac-C2H4O 0.017978 Ac-C2H4O
C2H2 6.132 C2H2 0.001952 C2H2
C6H6 -0.206 C6H6 0.039064 C6H6
C4H6 2.734 C4H6 0.026786 C4H6
C6H12 -3.876 C6H12 0.063249 C6H12
C2H6O 3.518 C2H6O 0.020001 C2H6O
C8H10 1.124 C8H10 0.05538 C8H10
Ox-C2H4O -0.385 Ox-C2H4O 0.023463 Ox-C2H4O
CH2O 2.264 CH2O 0.007022 CH2O
CH4O 2.211 CH4O 0.012216 CH4O
C8H8 2.05 C8H8 0.050192 C8H8
C7H8 0.29 C7H8 0.047052 C7H8
aire 3.355 aire 0.000575 aire
NH3 3.578 NH3 0.00302 NH3
BR2 4.493 BR2 0.000056 BR2
CO 3.376 CO 0.000557 CO
CO2 5.457 CO2 0.001045 CO2
CS2 6.311 CS2 0.000805 CS2
Cl2 4.442 Cl2 0.000089 Cl2
H2 3.249 H2 0.000422 H2
H2S 3.931 H2S 0.00149 H2S
HCl 3.156 HCl 0.000623 HCl
HCN 4.736 HCN 0.001359 HCN
N2 3.28 N2 0.000593 N2
N2O 5.328 N2O 0.001214 N2O
NO 3.387 NO 0.000629 NO
NO2 4.982 NO2 0.001195 NO2
N2O4 11.66 N2O4 0.002257 N2O4
O2 3.639 O2 0.000506 O2
SO2 5.699 SO2 0.000801 SO2
SO3 8.06 SO3 0.001056 SO3
H2O 3.47 H2O 0.00145 H2O
CaO 6.104 CaO 0.000443 CaO
CaCO3 12.572 CaCO3 0.002637 CaCO3
Ca(OH)2 9.597 Ca(OH)2 0.005435 Ca(OH)2
CaC2 8.254 CaC2 0.001429 CaC2
CaCl2 8.646 CaCl2 0.00153 CaCl2
C(grafito) 1.771 C(grafito) 0.000771 C(grafito)
Cu 2.677 Cu 0.000815 Cu
CuO 5.78 CuO 0.000973 CuO
Fe -0.111 Fe 0.006111 Fe
Fe2O3 11.812 Fe2O3 0.009697 Fe2O3
Fe3O4 9.594 Fe3O4 0.027112 Fe3O4
FeS 2.612 FeS 0.013286 FeS
I2 6.481 I2 0.001502 I2
LiCl 5.257 LiCl 0.002476 LiCl
NH4Cl 5.939 NH4Cl 0.016105 NH4Cl
Na 1.988 Na 0.004688 Na
NaCl 5.526 NaCl 0.001963 NaCl
NaOH 0.121 NaOH 0.016316 NaOH
NaHCO3 5.128 NaHCO3 0.018148 NaHCO3
S(rmbico) 4.114 S(rmbico) -0.001728 S(rmbico)
SiO2(cuarzo) 4.871 SiO2(cuarzo) 0.005365 SiO2(cuarzo)
Amoniaco 22.626 Amoniaco -0.10075 Amoniaco
Anilina 15.819 Anilina 0.02903 Anilina
Benceno -0.747 Benceno 0.06796 Benceno
1,3-Butadien 22.711 1,3-Butadien -0.08796 1,3-Butadien
Tetracloruro 21.155 Tetracloruro -0.04828 Tetracloruro
Clorobencen 11.278 Clorobencen 0.03286 Clorobencen
Cloroformo 19.215 Cloroformo -0.04289 Cloroformo
Ciclohexano -9.048 Ciclohexano 0.14138 Ciclohexano
Etanol 33.866 Etanol -0.1726 Etanol
xido de etil 21.039 xido de etil -0.08641 xido de etil
Metanol 13.431 Metanol -0.05128 Metanol
n-Propanol 41.653 n-Propanol -0.21032 n-Propanol
Trixido de a -2.93 Trixido de a 0.13708 Trixido de a
Tolueno 15.133 Tolueno 0.00679 Tolueno
Agua 8.712 Agua 0.00125 Agua
C D
-2.164E-06 CH4 0
-5.561E-06 C2H6 0
-8.824E-06 C3H8 0
-1.1402E-05 n-C4H10 0
-1.1945E-05 iso-C4H10 0
-1.4111E-05 C5H12 0
-1.6791E-05 C6H14 0
-1.9486E-05 C7H16 0
-2.2208E-05 C8H18 0
-4.392E-06 C2H4 0
-6.915E-06 C3H6 0
-9.873E-06 C4H8 0
-1.2447E-05 C5H10 0
-1.5157E-05 C6H12 0
-1.7847E-05 C7H14 0
-2.0521E-05 C8H16 0
-6.158E-06 Ac-C2H4O 0
0 C2H2 -129900
-1.3301E-05 C6H6 0
-8.882E-06 C4H6 0
-2.0928E-05 C6H12 0
-6.002E-06 C2H6O 0
-1.8476E-05 C8H10 0
-9.296E-06 Ox-C2H4O 0
-1.877E-06 CH2O 0
-3.45E-06 CH4O 0
-1.6662E-05 C8H8 0
-1.5716E-05 C7H8 0
0 aire -1600
0 NH3 -18600
0 BR2 -15400
0 CO -3100
0 CO2 -115700
0 CS2 -90600
0 Cl2 -34400
0 H2 8300
0 H2S -23200
0 HCl 15100
0 HCN -72500
0 N2 4000
0 N2O -92800
 0 NO 1400
0 NO2 -79200
0 N2O4 -278700
0 O2 -22700
0 SO2 -101500
0 SO3 -202800
0 H2O 12100
CaO -104700
CaCO3 -312000
Ca(OH)2
CaC2 -104200
CaCl2 -30200
C(grafito) -86700
Cu 3500
CuO -87400
Fe 115000
Fe2O3 -197600
Fe3O4 40900
FeS
I2
LiCl -19300
NH4Cl
Na
NaCl
NaOH 194800
NaHCO3
S(rmbico) -78300
iO2(cuarzo) SiO2(cuarzo) -100100
0.00019271 Amoniaco 0
-0.0000158 Anilina 0
-3.778E-05 Benceno 0
0.00020579 1,3-Butadien 0
0.00010114 Tetracloruro 0
-0.0000319 Clorobencen 0
0.00008301 Cloroformo 0
-0.0001616 Ciclohexano 0
0.00034917 Etanol 0
0.00017228 xido de etil 0
0.00013113 Metanol 0
0.0004272 n-Propanol 0
-8.473E-05 Trixido de a 0
0.00001635 Tolueno 0
-1.8E-07 Agua 0
Especies qumicas Estado Hf 298 Gf 298 Tabla C.1: Capacidades calorficas de gases
Inorgnicos diversos: Constantes de la ecuacin:
Amoniaco NH3 (g) -46110 -16450 (_^)( )=++^2+^(2)
Amoniaco NH3 (ac) -26500
Carburo de caCaC2 (s) -59800 -64900
Carbonato deCaCO3 (s) -1206920 -1128790 Especies qumicas
Cloruro de caCaCl2 (s) -795800 -748100 Parafinas:
Cloruro de caCaCl2 (ac) -8101900 Metano CH4
Cloruro de caCaCl2 6H2O (s) -2607900 Etano C2H6
Hidrxido de Ca(OH)2 (s) -986090 -898490 Propano C3H8
Hidrxido de Ca(OH)2 (ac) -868070 n-Butano C4H10
xido de calcCaO (s) -635090 -604030 iso-Butano C4H10
Dixido de c CO2 (g) -393509 -394359 n-Pentano C5H12
Monxido deCO (g) -110525 -137169 n-Hexano C6H14
cido clorhdHCl (g) -92307 -95299 n-Heptano C7H16
Cianuro de h HCN (g) 135100 124700 n-Octano C8H18
Sulfuro de hi H2S (g) -20630 -33560
xido de hierFeO (s) -272000 1-Alquenos:
xido de hierFe2O3 (s) -824200 -742200 Etileno C2H4
xido de hierFe3O4 (s) -1118400 -1015400 Propileno C3H6
Sulfuro de hieFeS2 (s) -178200 -166900 1-Buteno C4H8
Cloruro de litLiCl (s) -408610 1-Penteno C5H10
Cloruro de lit LiCl H2O (s) -712580 1-Hexeno C6H12
Cloruro de lit LiCl 2H2O (s) -1012650 1-Hepteno C7H14
Cloruro de lit LiCl 3H2O (s) -1311300 1-Octeno C8H16
cido ntrico HNO3 (l) -174100 -80710
cido ntrico HNO3 (ac) -111250 Orgnicos diversos:
xidos de ni NO (g) 90250 86550 AcetaldehdoC2H4O
NO2 (g) 33180 51310 Acetileno C2H2
N2 O (g) 82050 104200 Benceno C6H6
N2 O 4 (g) 9160 97540 1,3-ButadienC4H6
Carbonato deNa2CO3 (s) -1130680 -1044440 Ciclohexano C6H12
Carbonato deNa2CO3 10H2O (s) -4081320 Etanol C2H6O
Cloruro de soNaCl (s) -411153 -384138 Etilbenceno C8H10
Cloruro de soNaCl (ac) -393133 xido de etil C2H4O
Hidrxido de NaOH (s) -425609 -379494 Formaldehd CH2O
Hidrxido de NaOH (ac) -419150 Metanol CH4O
Dixido de azSO2 (g) -296830 -300194 Estireno C8H8
Trixido de a SO3 (g) -395720 -371060 Tolueno C7H8
Trixido de a SO3 (l) -441040
cido Sulfri H2SO4 (l) -813989 -690003 Inorgnicos diversos:
cido Sulfri H2SO4 (ac) -744530 Aire
Agua H2O (g) -241818 -228572 Amoniaco NH3
Agua H2O (l) -285830 -237129 Bromo BR2
Monxido deCO
Dixido de c CO2
Disulfuro de CS2
Cloro Cl2
Hidrgeno H2
Sulfuro de hi H2S
Cloruro de h HCl
Cianuro de h HCN
Nitrgeno N2
xido nitrosoN2O
xido ntrico NO
Dixido de niNO2
Tetraxido deN2O4
Oxgeno O2
Dixido de azSO2
Trixido de a SO3
Agua H2O
: Capacidades calorficas de gases en el estado de gas ideal
onstantes de la ecuacin:
)=++^2+^(2)
() desde 298 hasta _

_ _(_298)^/R
A B C D

1500 4.217 1.702 0.009081 -2.164E-06 0

1500 6.369 1.131 0.019225 -5.561E-06 0
1500 9.011 1.213 0.028785 -8.824E-06 0
1500 11.928 1.935 0.036915 -1.1402E-05 0
1500 11.901 1.677 0.037853 -1.1945E-05 0
1500 14.731 2.464 0.045351 -1.4111E-05 0
1500 17.55 3.025 0.053722 -1.6791E-05 0
1500 20.361 3.57 0.062127 -1.9486E-05 0
1500 23.174 4.108 0.070567 -2.2208E-05 0

1500 5.325 1.424 0.014394 -4.392E-06 0

1500 7.792 1.637 0.022706 -6.915E-06 0
1500 10.52 1.967 0.03163 -9.873E-06 0
1500 13.437 2.691 0.039753 -1.2447E-05 0
1500 16.24 3.22 0.048189 -1.5157E-05 0
1500 19.053 3.768 0.056588 -1.7847E-05 0
1500 21.868 4.324 0.06496 -2.0521E-05 0

rsos:
1000 6.506 1.693 0.017978 -6.158E-06 0
1500 5.253 6.132 0.001952 0 129900
1500 10.259 -0.206 0.039064 -1.3301E-05 0
1500 10.72 2.734 0.026786 -8.882E-06 0
1500 13.121 -3.876 0.063249 -2.0928E-05 0
1500 8.948 3.518 0.020001 -6.002E-06 0
1500 15.993 1.124 0.05538 -1.8476E-05 0
1000 5.784 -0.385 0.023463 -9.296E-06 0
1500 4.191 2.264 0.007022 -1.877E-06 0
1500 5.547 2.211 0.012216 -3.45E-06 0
1500 15.534 2.05 0.050192 -1.6662E-05 0
1500 12.922 0.29 0.047052 -1.5716E-05 0

versos:
2000 3.509 3.355 0.000575 0 -1600
1800 4.269 3.578 0.00302 0 -18600
3000 4.337 4.493 0.000056 0 -15400
2500 3.507 3.376 0.000557 0 -3100
2000 4.467 5.457 0.001045 0 -115700
1800 5.532 6.311 0.000805 0 -90600
3000 4.082 4.442 0.000089 0 -34400
3000 3.468 3.249 0.000422 0 8300
2300 4.114 3.931 0.00149 0 -23200
2000 3.512 3.156 0.000623 0 15100
2500 4.326 4.736 0.001359 0 -72500
2000 3.502 3.28 0.000593 0 4000
2000 4.646 5.328 0.001214 0 -92800
2000 3.59 3.387 0.000629 0 1400
2000 4.447 4.982 0.001195 0 -79200
2000 9.198 11.66 0.002257 0 -278700
2000 3.535 3.639 0.000506 0 -22700
2000 4.796 5.699 0.000801 0 -101500
2000 6.094 8.06 0.001056 0 -202800
2000 4.038 3.47 0.00145 0 12100
 Temperatura (K) a calcular el Hrxn 1073.15
CALOR DE RE -801444.66 J H 298 = -802625
Ai = 3.417
Bi = -0.006148
Ci = 2.164E-06
Di = -46100
Para constantes ABCD
Para Hf 298
Reactivos/Productos i Hf 298 Ai Bi Ci Di
ch4 ch4(g) -1 -74520 1.702 0.009081 -2.16E-06 0
o2 o2(g) -2 0 3.639 0.000506 0 -22700
co2 co2(g) 1 -393509 5.457 0.001045 0 -115700
h2o h2o(g) 2 -241818 3.47 0.00145 0 12100
n2 n2(g) 0 0 3.28 0.000593 0 4000
(g) 0 0 0 0 0
(g) 0 0 0 0 0
(g) 0 0 0 0 0
(g) 0 0 0 0 0
(g) 0 0 0 0 0
0 0 0 0
TEMPERATURA FINAL

Calor al que se desea igual37 21 = 1526994.79

Temperatura (K) inicial= 533.15

Numero de moles= 25

Temperatura Final = 1413 K

TEMPERATURA A LA FLA

HT = 0 = H298rxn + Hp 22702.678 0
H298rxn = -802625
Ap= 45.0154 Temperatura a la flama= 2066.265 K
Bp= 0.00950219
Cp= 0
Dp= -64460
Hp= 825327.678
 DELTA DE ENTALPIA
HT = 0 = H298rxn + Hp+ Haire
22702.678 0
HAire 0 n= 21.42 T= 773.15
T= 298.15

CALOR SENSIBLE Q

Q= 800645.81
A= 1.702
B= 0.009081
C= -2.164E-06
D= 0
T= 523.15
T= 1473.15
n= 12
Q (dado)= 422000000 800645.81

H reactivos -2136.2249

T= 600
T= 298.15
iAi iBi i C i iDi iHf np (moles) npAp npBp
-1.702 -0.009081 2.164E-06 0 74520 0 1 0
-7.278 -0.001012 0 45400 0 0.4 2 0.0002024
5.457 0.001045 0 -115700 -393509 1 5.457 0.001045
6.94 0.0029 0 24200 -483636 2 6.94 0.0029
0 0 0 0 0 9.03 29.6184 0.00535479
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
npCp npDp
0 0
0 -9080
0 -115700
0 24200
0 36120
0 0
0 0
0 0
0 0
0 0