Mw of pollutan 409 g/mole Langmuir Freundlish

Amount Equilibrium qe
Ce
adsorbed aqueous-phase (mol/g 1/qe 1/Ce log qe log Ce
(mol/L)
(mg/g Carbon)
87 conc. (mg/L) adsorb) 4701.15 3098485 -3.6722 -6.49115
0.132 3.227E-07 0.000213
79 0.061 1.491E-07 0.000193 5177.22 6704918 -3.7141 -6.82639
64 0.026 6.357E-08 0.000156 6390.6315730769 -3.80554 -7.19675
53 0.0071 1.736E-08 0.00013 7716.9857605634 -3.88745 -7.76046
43 0.0032 7.824E-09 0.000105 9511.631.28E+08 -3.97825 -8.10657
31 0.0029 7.09E-09 7.58E-05 13193.51.41E+08 -4.12036 -8.14933
22 0.0021 5.134E-09 5.38E-05 18590.91.95E+08 -4.2693 -8.2895
18 0.0016 3.912E-09 4.4E-05 22722.22.56E+08 -4.35645 -8.4076
12 0.0006 1.467E-09 2.93E-05 34083.36.82E+08 -4.53254 -8.83357
11 0.0005 1.222E-09 2.69E-05 37181.88.18E+08 -4.57033 -8.91275

Langmuir Isotherm -10 -9 -8

40000
f(x) = 4.02738821123743E-05x + 6655.7327788915
30000
R = 0.9441596004

20000

10000
f(x) = 0.380

0 R = 0.8970
0 200000000 400000000 600000000 800000000 1000000000

Intercept 1/qmax
6655
qmax 0.0001503
slope 1/KL qmax
4.02738821E-05
KL ###

Intercept Log KF
-1.0821
KF 0.0827752
slope 1/n
0.380954646
n 2.6249844
 Langmuir Freundlish

1/qe qe log qe qe Ce
La ngmui r Fre
6779.79 0.00015 -3.554934 0.00028 3.23E-07 0.0003
6925.03 0.00014 -3.682646 0.00021 1.49E-07
0.00025
7288.54 0.00014 -3.823735 0.00015 6.36E-08
8975 0.00011 -4.038485 9.15E-05 1.74E-08 0.0002

11802.5 8.47E-05 -4.170337 6.76E-05 7.82E-09

0.00015
12335 8.11E-05 -4.186623 6.51E-05 7.09E-09
14498.8 6.9E-05 -4.240025 5.75E-05 5.13E-09 0.0001

16950 5.9E-05 -4.285016 5.19E-05 3.91E-09

0.00005
34108.4 2.93E-05 -4.44729 3.57E-05 1.47E-09
39599 2.53E-05 -4.477455 3.33E-05 1.22E-09 0
0 0.00000005 0.0000001 0.0000001

0
0 -9 -8 -7 -6 -5 -4 -3

-1

-2

-3

f(x) = 0.380954646x - 1.0820985467 -4

R = 0.8970092162
-5
 La ngmui r Freundl i sh experi ment

0.00000005 0.0000001 0.00000015 0.0000002 0.00000025 0.0000003 0.00000035

 Initial Conc. Amount adsorbed Eq Conc. 1/Ce 1/qe log Ce log qe
(mg/l) (mg/g adsorbent) (mg/l)

140 13.09 1.51 0.66 0.08 0.18 1.12

160 14.04 8.41 0.12 0.07 0.92 1.15
180 15.08 26.25 0.04 0.07 1.42 1.18
200 15.44 43.5 0.02 0.06 1.64 1.19
220 15.84 54.49 0.02 0.06 1.74 1.20

Time (min) qt (mg/g adsorbent) ln (qe-qt) t/qt t/2 Pseudo Second order
0 0 2.57 #DIV/0! 0 8.00
5 9.86 1.17 0.51 2.5 7.00
f(x) = 0.0750153187x + 0.0984678838
10 11.44 0.50 0.87 5 6.00 R = 0.9998240693
15 12.45 -0.45 1.20 7.5 5.00
30 13.05 -3.22 2.30 15 4.00
60 13.09 Err:502 4.58 30 3.00
90 13.09 Err:502 6.88 45 2.00
1.00
qe = 13.09 0.00
0 10 20 30 40 50 60 70 80 90 1

Pseudo Fist order in

3.00 14
12 f(x) = 0.1552030075x + 8.0976691729
2.00 f(x) = - 0.1874523295x + 2.3654165699 R = 0.2961436684
1.00 R = 0.9941481156 10
0.00 8
0 10 20 30 40 50 60 70 80 90 100 6
-1.00
4
-2.00
2
-3.00
0
-4.00 0 5 10 15 20 25 30 35 40 45 50

4.00

Temperature Amout of adsorbed Eq conc. f(x) = 9947.6042

Temp (K) qe/Ce ln qe/ce 1/T 3.00 R = 0.21308010
(C) (mg/g adsorbent ) (mg/L)

30 7.24 0.554 303 13.06859 2.57 0.00330 2.00

40 7.26 0.357 313 20.33613 3.01 0.00319

1.00
45 7.74 0.326 318 23.74233 3.17 0.00314
50 7.73 0.318 323 24.30818 3.19 0.00310
0.00
53 7.74 31.68 326 0.244318 -1.41 0.00307 0.00305 0.00310

-1.00
slope
-2.00
0.00
0.00305 0.00310

-1.00

-2.00
 Fr
1.22

1.20
Langmuir Isotherm
f(x) = 0.0523058427x + 1.1
0.09 1.18 R = 0.986407969
0.08 1.16
0.07 f(x) = 0.0175933987x + 0.0653379303
R = 0.8105724126 1.14
0.06
0.05 1.12
cond order 0.04
0.03 1.10
0.02
1.08
0984678838 0.01
0.00 1.06
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.00 0.20 0.40 0.60 0.80

50 60 70 80 90 100

Thermodynamic
4.00

f(x) = 9947.6042483705x - 29.3347789779

3.00 R = 0.2130801018

2.00

1.00

0.00
0.00305 0.00310 0.00315 0.00320 0.00325 0.00330 0.00335

-1.00

-2.00
0.00
0.00305 0.00310 0.00315 0.00320 0.00325 0.00330 0.00335

-1.00

-2.00
 Freundlish
22

20
f(x) = 0.0523058427x + 1.1045251931
18 R = 0.986407969

16

14

12

10

08

06
0.00 0.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00
 Adsorbent A
time 100 150 200 Pseudo Frist Oder
qe 75.08 86.32 96.85 ln(qe-qt)100 ln(qe-qt)150
0 0 0 0 4.31855421 4.45806132
5 62.0335339 62.7903258 75.7228082 2.5685173 3.15826236
10 69.3461998 75.754275 86.627186 1.74637852 2.35761527
15 70.9573679 77.2908387 87.8832054 1.41649182 2.20045948
30 73.4480071 81.9693954 88.9872675 0.48980191 1.47031482
60 74.0161483 81.0009729 91.10345 0.061896 1.67129041
90 74.0563199 83.0884614 92.567 0.02340408 1.17295837
120 74.1538795 84.086 92.683 -0.07675092 0.8037937

Pseudo Second Oder

t/qe (100) t/qe (150)
0 0
k100 0 0.06659563 0.057924
k150 0 0.13319126 0.11584801
k200 1.066107E+12 0.19978689 0.17377201
0.39957379 0.34754402
0.79914758 0.69508804
1.19872136 1.04263207
1.59829515 1.39017609

Intra Panticle Diffusion model

t1/2 qt (100) qt (150)
0 0 0
2.5 62.0335339 62.7903258
5 69.3461998 75.754275
7.5 70.9573679 77.2908387
15 73.4480071 81.9693954
30 74.0161483 81.0009729
45 74.0563199 83.0884614
60 74.1538795 84.086
o Frist Oder
ln(qe-qt)200
4.57316339 Pseudo Frist Oder
3.05056092
5
2.32462189
2.19352827 4

2.06213419 3
1.74859967 0.0172198042x + 3.0460288506
f(x) = - 0.0214408335x 3.0646242202
ln(qe-qt)

2 f(x)
R ==0.6413817325
- 0.0270980353x + 2.4363305714
0.5391048997
1.4546537
R = 0.6060250115
1.42719635 1

0
Second Oder 0 20 40 60 80 100 120 140
-1
t/qe (200)
0 time
0.05162623
0.10325245 ln(qe-qt)100 Linear (ln(qe-qt)100)

0.15487868 ln(qe-qt)150 Linear (ln(qe-qt)150)

0.30975736 ln(qe-qt)200 Linear (ln(qe-qt)200)
0.61951471
0.92927207
1.23902943

e Diffusion model Pseudo Second Oder

qt (200)
2
0
75.7228082 1.5
f(x) = 0.0133191263x + 1.57009245868378E-16
86.627186 f(x)
R ==10.0115848007x - 2.35513868802566E-16
87.8832054 1 f(x) = 0.0103252452x + 2.35513868802566E-16
R = 1
t/qe

88.9872675 R = 1

91.10345 0.5

92.567
92.683 0
0 20 40 60 80 100 120 140

time

t/qe (100) Linear (t/qe (100))

t/qe (200) Linear (t/qe (200))

t/qe (150) Linear (t/qe (150))

 time

t/qe (100) Linear (t/qe (100))

t/qe (200) Linear (t/qe (200))

t/qe (150) Linear (t/qe (150))

Intra Panticle Diffusion model

100

80
qt

60

40

20

0
0 10 20 30 40 50 60 70

time/2

qt (100) qt (200) qt (150)

140
 Langmuir Freundlich
Ce (mg/L) qe (mg/g cat) temp 1/Ce 1/qe log Ce log qe
0.0000 0.5000 20 #DIV/0! 2 Err:502 -0.30103
0.2372 0.7628 4.21638 1.31091 -0.62494 -0.1175724
0.6368 0.8632 1.57035 1.15848 -0.196 -0.0638886
1.0315 0.9685 0.96946 1.03252 0.01347 -0.0139004
1.4500 1.0500 0.68966 0.95238 0.16137 0.0211893
1.9100 1.0900 0.52356 0.91743 0.28103 0.0374265
0.0000 0.5000 30 #DIV/0! 2 Err:502 -0.30103
0.2594 0.7406 3.8545 1.35032 -0.58597 -0.1304379
0.6539 0.8461 1.52923 1.18192 -0.18447 -0.0725895
1.0659 0.9341 0.93815 1.07058 0.02773 -0.0296183
1.5000 1.0000 0.66667 1 0.17609 0
1.9800 1.0200 0.50505 0.98039 0.29667 0.0086002
0.0000 0.5000 40 #DIV/0! 2 Err:502 -0.30103
0.2705 0.7000 3.69727 1.42857 -0.56788 -0.154902
0.7070 0.7500 1.41444 1.33333 -0.15059 -0.1249387
1.0893 0.8700 0.91799 1.14943 0.03716 -0.0604807
1.6000 0.9000 0.625 1.11111 0.20412 -0.0457575
2.0500 0.9500 0.4878 1.05263 0.31175 -0.0222764
0.0000 0.5000 50 #DIV/0! 2 Err:502 -0.30103
0.2735 0.6900 3.65616 1.44932 -0.56302 -0.1611648
0.7122 0.7186 1.40401 1.39163 -0.14737 -0.1435249
1.1317 0.7890 0.88359 1.26743 0.05375 -0.102923
1.6957 0.8043 0.58974 1.24327 0.22934 -0.0945657
2.1710 0.8290 0.46061 1.20629 0.33666 -0.0814512

(II)
Temp (C) qe (mg/g) Ce (mg/L)1/T (1/K) qe/Ce ln (qe/CeG
30 4.61 34.53 0.0033 0.13351 -2.0136 5070.7294 0
0.003
40 4.8 32.6 0.00319 0.14724 -1.9157 4922.5323
45 5.35 31.8 0.00314 0.16824 -1.78237 4848.4338
50 5.31 32.2 0.0031 0.16491 -1.80237 4774.3353 -0.5
55 5.63 31.6 0.00305 0.17816 -1.72505 4700.2368

-1
d
 -0.5

(II)
-1
Temp (C) qe (mg/g) Ce (mg/L)
30 0.554 7.24 0.0033 0.07652 -2.57021 3678.8535

ln kd
40 0.357 7.26 0.00319 0.04917 -3.0124 2669.7834
45 0.326 7.74 0.00314 0.04212 -3.16726 2165.2483 -1.5

50 0.318 7.73 0.0031 0.04114 -3.19081 1660.7132

53 31.68 7.74 0.00307 4.09302 1.40928 1357.9921
-2

H = 9561.1
S = 14.8197
-2.5

H = 34253.7
H = 100.907
 Thermodynamics

0
0.003 0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335

-0.5 f(x) = - 4119.9743322188x + 12.137001941

R = 0.9314280616

-1
d
 -0.5 f(x) = - 4119.9743322188x + 12.137001941
R = 0.9314280616

-1
ln kd

-1.5

f(x) = - 1149.9688749858x + 1.7825483753

R = 0.9283724966
-2

-2.5

1/T

(II)

Linear ( (II))

Linear ( (II))

(II)

Linear ( (II))