[𝐻2 𝑂2 ] mol

tiempo/ms ORDEN CERO

dm-3 LN 1/[𝐻2𝑂2]
7
2 6.23 1.82937633 0.16051364
4 4.48 1.49962305 0.22321429 6

6 3.76 1.32441896 0.26595745 5

8 3.2 1.16315081 0.3125 4
10 2.6 0.95551145 0.38461538
3
12 2.16 0.77010822 0.46296296
14 1.85 0.61518564 0.54054054 2

16 1.49 0.39877612 0.67114094 1

18 1.27 0.2390169 0.78740157 0
20 1.01 0.00995033 0.99009901 0 5 10

tiempo/ms LN PRIMER ORDEN

2 1.82937633
2
4 1.49962305
1.8
6 1.32441896 1.6
8 1.16315081 1.4
10 0.95551145 1.2
12 0.77010822 1
14 0.61518564 0.8

16 0.39877612 0.6
0.4
18 0.2390169
0.2
20 0.00995033 0
0 5

tiempo/ms 1/[𝐻2𝑂2]
2 0.16051364 SEGUNDO ORDEN
4 0.22321429
1.2
6 0.26595745
8 0.3125 1
10 0.38461538
0.8
12 0.46296296
14 0.54054054 0.6
16 0.67114094
18 0.78740157 0.4
20 0.99009901
0.2

0
0 5
ORDEN CERO

y = -0.2585x + 5.648
R² = 0.9078

10 15 20 25

PRIMER ORDEN

y = -0.0959x + 1.9357
R² = 0.9956

10 15 20 25

SEGUNDO ORDEN

y = 0.043x + 0.0064
R² = 0.9462

10 15 20 25
 Rapidez
Presión NO2 /
inicial / Torr
Torr
min-1 LOGr LNGa
4.7 0.98 1.54756251 -0.0202027
11 2.35 2.39789527 0.85441533
15.3 3.16 2.72785283 1.15057203
20.3 3.96 3.01062089 1.37624403
26.1 5.56 3.26193531 1.71559811
34.1 6.77 3.52929738 1.91250109

LN(r) VS LN(A)
2.5

1.5

0.5

0
0 0.5 1 1.5
-0.5

T (ºC) 5 15 25 35
T (°K) 278.15 288.15 298.15 308.15
1/T 0.003595182 0.003470415 0.003354016 0.003245173
-1
k (s ) 1.50E-06 8.00E-06 4.10E-05 2.00E-04
LN K -13.410045 -11.736069 -10.101938 -8.5171932

LN K
0
0.0032 0.00325 0.0033 0.00335 0.0034 0.00345 0.0035 0.00355 0.0036 0.00365

-2
m=-13977
b=36.808
-4
Despejand
Ea=-mR = -
-6
 -8
Ea=-116204
-10 y = -13977x + 36.808
R² = 0.9997 A=exp(b)
-12
A =exp(36.
-14

-16
LN(r) VS LN(A)

y = 0.9788x - 1.5227
R² = 0.9976

1.5 2 2.5 3 3.5 4

1/T LN K
0.00359518 -13.410045
0.00347041 -11.736069
0.00335402 -10.101938
0.00324517 -8.5171932

m=-13977
b=36.808
Despejando Ea y A
Ea=-mR = -13977 K*8.314 J/mol K
Ea=-116204.778 J/mol=-116.204 KJ/mol
A=exp(b)
A =exp(36.808)=9.671 x1015 s-1