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logging equipment for gas data acquisition, along with (parts per million), separated and quantified by gas
inappropriate methods for interpretation in all kinds of chromatography using a Flame Ionization Detector (FID).
geological environments. It also seems that the potential
added-value of the current gas data within the formation • TG (Total Gas), expressed in ppm of equivalent methane
evaluation process seems to be relatively poorly known in air, and obtained through direct combustion of the gas
amongst the E&P community, both mud logging and oil flow in a FID device.
companies alike. The details of the method have already been published.10 In
For a long time, the attempts to construct rational the present paper we only give the main features of this
interpretation methods based on gas data were generally method. The global GWDTM method workflow is given in
restricted to use of the Pixler and/or Geoservices diagram (or Fig.1. The main steps are the following:
equivalents), wetness, balance, character, and gas
normalization. This first step towards a more radical analysis - data process: we stress the fact that drilling events as
of the fluids led to the emergence of an integrated well as the gas chain characteristics have a strong
interpretation method called GWDTM for “Gas While Drilling” influence on the gas data. At this stage, it is therefore of
which permitted TotalFinaElf and ENI AGIP to use the prime importance to collect all the geological and drilling
earliest reservoir information obtained on site in their global data available. The data needed for a GWDTM study are
evaluations and programs.7,10 This method has lead to given in Fig.2. The use of softwares specifically modified
numerous operational successes, either in real time, at the rig for these interpretations (ExcelTM, Geolog6TM, WinlogTM
site, at the well scale, or at the field scale, in multi-disciplinary or InfactTM) requires that the gas data is presented in a
integrated studies and reservoir modeling. certain manner, along with other data such as ROP, mud
In the same way, since J.T.Hayward initiated mud logging in flow and bit size. The latter are needed to calculate a
1931, equipment and methods involved in real-time drilling normalized total gas content (NTG). The main source of
surveillance have been dramatically improved. However, information at the well site is the litholog or masterlog,
despite some attempts from several pioneers such as which should contain the main geological and operational
Issenmann, Whittaker or Delaune11 among others, gas information needed for a correct interpretation of gas
measurement stayed pretty much the same for decades. It is shows. The data processing makes it possible to have
only a few years ago that the concept of “gas chain” appeared, specific gas ratios directly as well as logs and cross-plots
collating the device extracting the fluid from the mud (“the which will be used at the QC and analysis steps. The gas
degasser” or gas trap), the transport medium between the gas database must be recorded both versus time and depth.
trap and the Mud Logging Unit (“the gas line”) and the The mud logging company is responsible for such data
analyzer located inside the pressurized unit. Special attention storage. The depth-referenced data base, cleaned of
was given to an improved volumetric gas trap, associated with specific special events such as trip gas, connection gas,
a more “standardized” gas transport line, an efficient, fast, gas calibration, etc., is used for the GWDTM method
chromatographic device and appropriate gas (however, these special events must be recorded on a file
data management. for checking if necessary).
The main goal of this paper is to show that the added value of
gas data interpretation for early formation evaluation is linked - quality control : as for most of the techniques used in the
to the efficiency of the equipment used within the gas chain. In petroleum E&P process, the QC step is essential. QC for
fact, reducing uncertainties in formation evaluation at an early the GWDTM method is based on the following criteria:
stage, with gas while drilling data, will not be possible unless
the equipment used for the acquisition follows precise C1 < saturation threshold of the chromatograph
specifications, some of which are described in this paper. C1/C2 ratio < maximum value defined for a given
chromatograph work with %(C1+C2) instead of
%C1 if C1/C2 > specification
The GWDTM Method
In order to understand the technical requirements for an C1, C2, C3, iC4, nC4, iC5, nC5 > quantification
efficient gas chain, as well as the added value of gas data for threshold (depends on the tool characteristics);
formation evaluation, it is necessary to explain the basic generally a minimum value of 10 ppm is adopted
principles of the GWDTM method. TG/ΣCcor = 1 +/- 20%, where
The GWDTM method was first developed in 1997 as a joint Elf
/ Agip research program. It is now a trademarked method by ΣCcor =C1+2xC2+3xC3+4x(iC4+nC4)+5x(iC5+nC5)
Total and ENI in France, the United Kingdom, Italy and the This is to check the consistency between the TG
USA. It is based on a very systematic and rational approach to detector and the gas chromatograph results (a value
gas shows in conjunction with drilling and mud logging other than 1 can be considered as long as the ratio
events, and integrated with other techniques such as electric remains more or less constant).
logs, PVT/thermodynamics and geochemistry.
TG/ΣCcor = 1 good calibration
The raw gas data used in the GWDTM method are:
TG/ΣCcor <1 calibration problem:
• C1, C2, C3, iC4, nC4, iC5 and nC5 expressed in ppm corresponding data are suspect
SPE 84383 3
efficient gas chain. In order to appreciate the performance of if no care is taken as regards the transport line, it can act as a
the gas chain it is described here after. chromatographic column and separate the different
hydrocarbons before they arrive at the analyzer itself. For this
The “Gas Chain” : technical specifications reason the construction material for the line has to be selected
The gas chain is composed of three different parts: with care.
The second essential factor to consider is the inside diameter
- the gas trap of the line. It must be perfectly suited to both the pumping rate
- the gas line or transport line of the mud degassed and that of the extracted gas to the
analyzer. It must be big enough to let all the gas and air flow
- the analyzer in the line but small enough to minimize the risk of dead
volumes, which are responsible for signal dampening.
The gas trap. Mud logging has suffered for many years from Last but not least, special training for the Mud Loggers
a lack of interpretation of its gas data, mainly due to the fact ensures that the line is installed correctly to avoid
that the real-time analysis very much depended on the method condensations or freezing in cold environments.
of extraction. All degassers or gas traps available on the
market were all dependant upon the good will of the operator The analyser. Two types of system are present in the
who needed to constantly adjust their position in the possum analyzer device:
belly tank in order to try to get stable recording conditions. - a Flame Ionization Detector (FID) which analyzes all the
Any variation in the flow rate lead to a change in the quantity gas flow to yield a Total Gas (TG) content; only
of gas extracted and carried to the analyzer. Several attempts hydrocarbon compounds can be detected by FID, this is
were made to avoid the problem. SAMEGA developed the the reason why non hydrocarbon gases such as CO2 and
first prototype constant volume extractor but it never proved to H2S are not included in the TG content (some mud
be adapted to the market; TEXACO introduced the logging contractors use Catalytic and Thermal
“Quantitative Gas Measurement” gas trap (QGM) which was Combustion Detectors -respectively CCD and TCD, but
an excellent alternative to a real constant flow gas trap. Some they need to be evaluated prior their use for GWDTM) ;
other trials were performed on floating Gas traps, but an
original device was proposed by Geoservices12, which now - a gas chromatograph, equipped with FID, which separates
constitutes the most efficient constant volume gas trap and quantifies the different hydrocarbon compounds from
currently on the market (GZG, see Fig.6). the C1 to C5 range within 42 seconds; we will focus only
On many drilling rigs, especially these days of ultra deep on the gas chromatograph, which will be referred to as
water drilling ships, the possum belly tanks are at the end of a “the analyzer” in this paper.
complex chain of equipment, including the obvious flow line, Experience has shown that some points are absolutely critical
but also sometimes gumbo traps or in-line degassers. In for the analyzer, for obtaining really accurate added-value of
addition, height differences of a few meters can exist between GWDTM for formation evaluation.
the bell nipple and the shaker box. All these factors induce a • Perfect integration with the other parts of the gas
spontaneous degassing which badly affects the fluid analysis. chain
The first necessity was thus to be able to place the gas trap as
close as possible to the bell nipple. This has been achieved • High sensitivity
thanks to a probe that can be fitted to any closed flow line
• High accuracy
using special adaptation flanges (Fig.7).
It has been shown that placing the gas trap on the flow line • Possibility of integrating data from the flow line
increases the quantity of all gasses by a factor of 2 to 10 (Out) as well as data from the Mud pits (In)
(Fig.8). In deep or ultra deep offshore, this difference becomes • High speed chromatography
an essential factor in the interpretation process.
A constant volume pump has been added to the assembly. The
mud gets sucked through the probe located in the flow line, A perfect fit of the analyzer with the rest of the
and filtered from solids greater than 0.5 mm, at a constant rate. acquisition chain is mandatory in order to maximize the
This way, mud flow variations do not affect the measurements meaning of the gas data. In particular, this means that the
and the recorded gas quantities can be directly linked to the pumping rate of the gas/air mixture from the gas trap must be
geological environment for the interpretation process. In constant so that the ratio of mud degassed/gas mixture
addition, the special design of the mixing bowl associated with analyzed stays constant at all times.
the high tech profile of the degassing arm, allows the High sensitivity is most critical for heavy gases
extraction of the gaseous phase from the drilling fluid in a (butane and pentane). It allows an advanced interpretation of
constant manner, as well as with optimum efficiency. This is the compartments in the reservoir thanks to the differential
what makes it different from the other conventional types of distribution of the isomers of each component. Moreover,
gas trap. these isomers prove useful in the early indication of
biodegradation due to a preferential consumption of normal
The gas line. The molecules analyzed from methane to versus branched alkanes by bacteria.
pentane have very different sizes. This is the reason why they
can be separated through gas chromatography. In this respect,
SPE 84383 5
High accuracy is essential for detecting the subtle Case 1 – Field-A and Field-B. The geological environment of
evolution of fluids along the lithostatic column. For a Field-A and Field-B is shaley and sandy Tertiary deposits in a
homogeneous fluid drilled with a new uncontaminated mud, deltaic basin, in a shallow water offshore location. The main
the corresponding gas data, plotting a Cm vs. Cn diagram, will objective of the studies undertaken was to identify
follow a straight line passing through the origin. A lack of hydrocarbon-bearing reservoirs and possible lithological
accuracy would give a cloud of points contained within two barriers, and provide fluid sampling recommendations.
lines indicating the extent of the measurement error. This can Additionally, a request was made to attempt to identify
be observed for instance on Fig.9. depleted reservoirs and water flushed zones. Comparison of
interpretation with electric logs was done.
If an influx of contamination or recycling gas occurs The wells investigated are labeled Well-A1, Well-B1, Well-
over a time interval (supposed at a constant rate), the straight B2 and Well-B3. Only the main results within the scope of gas
line will be shifted from its origin. Therefore, the possibility of added value versus acquisition quality will be given.
integrating data from the flow line (Out) as well as data from
the Mud pits (In) allows evaluation of the recycling effect of Well-A1. Fig.11 shows a composite log of part of the well-
gas in mud. Although ignored for years, recycling of the A1. Besides electric and gas data, interpretation is reported on
drilled gas or contamination from mud are well-known the right part, in three distinct columns:
phenomena by all experts in gas logging. The fact of being - fluid interpretation mainly based on electric logs: proven
able to measure the gas In data on the same analyzer as the gas gas in red, possible gas in gray and water in blue
Out allows the same calibration for both analyses. It is then
- hydrocarbon-bearing reservoir identification based on
necessary to synchronize both measurements at the bit depth
GWDTM (red layers)
in order to be able to correlate them and to issue a relevant
differential value “Out – In”. - fluid units identification based on GWDTM (single fluid
behavior in yellow layers in that case)
High-speed chromatography becomes of prime
Pressure and equivalent density data are reported in an
importance. Due to cost constraints and improved procedures,
attempted correlation with gas data; but this has been
drilling always gets faster. In a multi-layer situation or when
relatively unconvincing so far in that case.
thin markers are being looked for, this becomes essential since
In the meantime, one can easily see the relatively high number
thin layers can be missed if the analyzing rate is not fast
of small reservoir layers. It can be seen from Fig.11 that,
enough. Some operational applications in real field cases will
though a rather good correlation exists at first sight between
be shown later on in this paper.
electric logs and gas data interpretation in terms of
hydrocarbon-bearing reservoir identification, red layers from
Gas data acquisition technical specifications for GWDTM GWDTM interpretation are more numerous than the ones
interpretation. In order to have the best possible gas data obtained from the usual log interpretation. Obviously, the gas
available to perform the GWDTM interpretation, data bring some additional information that helps in reducing
recommendations to Mud Logging companies were set up uncertainties and yields additional net pays.
jointly by Total and ENI in 2001. The following technical The use of a high quality level gas chain enables us, not only
specifications are considered as a minimum requirement. They to determine with a high level of confidence the existence of
take into account the whole gas data acquisition, from the gas hydrocarbon-bearing reservoirs (gas in this case), but also to
trap to data management. These specifications are reported in assess a differentiation between fluid behaviors, thus leading
Appendix A. to accurate sampling recommendations at an early stage. In the
Besides technical recommendations on the different parts of case of thin layers in a multi-layer situation as in Well-A1, this
the gas chain, special attention should be paid to data would not be possible without the use of a fast cycle time gas
management, in particular to the choice of gas data when the chromatograph coupled with a constant volume gas trap.
time database is converted into the depth data base. GWDTM As an example, a double gas acquisition was performed on
requires that, for a given depth interval, the highest value of Well-A1. The interpretation described above is based on a
C1 should be chosen, along with the associated corresponding high quality acquisition chain corresponding to the one
C2 to C5 values. described in chapter 3 (The “gas chain” technical
We also insist on the sampling rate, which should be at least specifications), whereas a conventional gas chain was also
50cm (recommended: every 20-25 cm). Fig.10 shows the used, characterized by a non-constant volume gas trap
difference for chromatographic data logs between a 20 cm associated with a gas chromatograph with a longer
depth sampling rate and a 1 m one. Some hydrocarbon-bearing chromatographic time cycle (Geo-FID: 190 seconds).
levels are likely to be missed or badly analyzed when the Fig.12 shows the log representation of gas composition and
depth sampling rate is too high. TG values for both gas chains. At first glance, the TG
evolutions seem to be parallel for both acquisitions ; however
CASE STUDIES the TG signal for the Geo-FID gas chain appears to be more
noisy and is likely to lead to wrong hydrocarbon-bearing
The case studies described in this paper deal with Total fields reservoir identification (numerous thin red layers without any
spread all over Asia. real significance). In this respect, the TG/ΣCcor quality
control ratio appears to be more noisy with the Geo-FID
compared to the Reserval data.
6 SPE 84383
A great difference is observed for the gas composition data: chain, since the quantity of data is far lower (low cycle time),
there are far less data with the Geo-FID, with a very noisy and randomly distributed (poor accuracy ).
distribution. Moreover, heavy components are rarely
quantified with the Geo-FID chain, whereas significant Case 2 – Field D. This case study, based on five wells from a
amounts are obtained with the ReservalTM chain. The single basin labeled Field-D, highlights a totally different
difference between both gas chains is spectacularly shown on approach from the previous case 1 fields. The geological
Fig.13. As a matter of fact, the cross-plot C1/C3 vs. C2/C3 environment for the Field-D is shaley and sandy deposits in an
clearly shows that the gas composition signature with the off-shore deltaic basin. Here again, special attention is paid to
ReservalTM chain enables 5 fluid units differentiation, while the impact of the quality of the acquisition chain on the gas
this assessment is impossible with the gas composition data data interpretation as well as operational considerations.
obtained with the Geo-FID system.
Well-D1, Well-D1-T and Well-D2.Well-D1 is a horizontal
Well-B1. Fig.14 gives a general overview of the whole drain. It perforated the main target reservoir twice.
Well-B1, in the same way as previously. Additionally, water Additionally, a technical side-track was also drilled, labeled
levels identified with GWDTM are also indicated (in blue). Well-D1-T, which also perforated the same reservoir twice.
Fig.14 shows the very high number of thin reservoir levels in The ReservalTM chain was used for gas data acquisition for
this case. It also gives the location of lithological these wells. Another similar horizontal drain was drilled
heterogeneities as seen by GWDTM, as well as the hydrocarbon (labeled Well-D2), still in the same reservoir, using
fluid behavior differentiation, five different fluid units in conventional gas acquisition chain.
this case. Fig.17 shows the log data for Well-D1 and Well-D1-T. The
A more detailed view of well-B1 is given in Fig.15. It shows, GWDTM method applied in this case led to assessing a change
on the one hand, an example of good agreement between in fluid behavior at the same vertical depth (x925m TVD),
electric logs and gas data interpretation for the identification which corresponds to x625m MD for Well-D1 and x680 for
of hydrocarbon levels and, on the other hand, the identification Well-D1-T). This is particularly well seen on Fig.18 which
of a hydrocarbon-bearing level and a water-bearing level with represents the C1/C3 vs. C2/C3 cross-plots for the two wells ;
GWDTM while logs were doubtful. This example shows the two fluid families are clearly defined, with a break
added-value of good quality gas data for reducing formation corresponding to x625 m TVD. Is not well known yet whether
evaluation uncertainties. this fluid change corresponds to a GOC or a transition zone
Fig.15 also gives the opportunity to show the potential of gas between two oil phases. Further investigation by
data for the identification of flushed zones. Supposed water PVT/thermodynamic studies will help for a final assessment.
flushed levels have been indicated in green on the log In comparison, the same plots for Well-D2 (Fig.19) clearly
interpretation column. In fact, distinction between original show that a less sophisticated system leads to poor quality data
aquifer and real flushed zones can be done with the gas data, which prevent us from any accurate interpretation as regards
the former corresponding to a real water level with GWDTM fluid units, fluid contacts or transition zones.
(low TG, low %C1) whereas the latter exhibits gas signature
typical of a hydrocarbon-bearing level which could be Well-D3 and Well-D3-T. Other wells were drilled in the
interpreted as the presence of residual hydrocarbons. same previous structure, Well-D3 and its side-track Well-D3-
As for Well-A1, the ability to clearly define numerous fluid T. As for wells Well-D1 and D1-T, the Well-D3 and D3-T
differentiated hydrocarbon-bearing reservoirs in thin layers is perforated the reservoir twice. A ReservalTM chain was used
possible thanks to a high quality gas acquisition system. for the gas data acquisition.
The main interesting zones are located at the same vertical
Well-B2. Fig.16 gives a general overview of the whole depth intervals (Fig.20) even though the well diameter (hence
Well-B2. Sure gas levels identified with logs are labeled in the volume of rock drilled) was different.
red, possible in pink, water in blue and flushed zones in green. The composition analysis, processed with various plots, leads
Sure hydrocarbon levels identified with GWDTM are indicated to the determination of four different fluid units that the two
in black, possible in gray, water in blue. As for Well-B1, wells share in common (Fig.20).
Well-B2 exhibits a very large number of thin layers. Fig.16 The gas analysis confirms good connectivity between the
shows that, while there is no clear relationship between the formations encountered in the two wells.
presence of a flushed zone and the composition of the gas, it is Some barrier identification and characterization has been
possible to differentiate real flushed zones (with significant carried out between the hydrocarbon-bearing zones. The
gas signature) and original aquifers (water levels abrupt change in the C1/C3 ratio (at the exit/entrance of the
with GWDTM). reservoirs) indicates that the barrier presents a good efficiency,
which explains that different fluids units have been identified
Well-B3. A double gas chain acquisition was also used for during the fluid composition analysis. Fig.21 shows one of
Well-B3, as for Well-A1. Fig.9 shows the difference between these barriers.
the results obtained by both acquisitions. The cross-plots on
Fig.9 (C3 vs C1, C3 vs C2, iC4 vs C1 and nC4 vs iC4) enable Technical evolution : FLAIR
us to differentiate four fluid units shown by the different To reduce the current mud logging gas system uncertainties
slopes on the cross-plots. It seems obvious that this and enhance gas data potential, the three components of the
interpretation cannot be assessed with the conventional gas gas chain – gas trap, transport line and detection system
SPE 84383 7
(analyzer) - had to be improved all together. This has led to the extractor and analyzer have been designed. With this new
the development of a completely new kind of gas line, absorption of paraffinic or aromatic hydrocarbons, a
chromatograph coupled to a mass spectrometer (GC-MS), able known problem with standard transfer lines, is negligible.
to work at the rig site. This new system includes a new heated To minimize the transit time and avoid any condensation in
gas extractor, a new transport line, and a new compact the line, transport of the sample is performed under non-
analyzer situated in the mud logging unit. The heated gas atmospheric conditions. This procedure provides a new
extractor provides significantly better extraction from drilling standard set of working conditions for the extraction system
mud, especially in cold muds in deep water drilling and the line. Performed under these new conditions, response
environments. The new non-condensing gas transfer line from an injection of toluene proves there is absolutely no
eliminates absorption of aromatic and paraffin hydrocarbons. condensation of heavy compounds in the transportation line.13
The GC-MS analyzer continuously measures a greatly
increased range of components at a rate of 60 to 90 seconds. Analyzer: The GC-MS. Detection systems placed in mud
This new gas chain is able to continuously analyze gas and logging units must be designed to perform under severe well
hydrocarbon vapors from C1 to the heavier hydrocarbons C6 site conditions. Despite the drilling conditions, they must be
to C8, the light aromatics (benzene, toluene, xylenes), and the able to detect very low concentrations and produce repeatable
non-hydrocarbon or sour gases such as He, H2, Acetic Acid, data that are accurate enough to be interpreted. Furthermore,
CO2 and H2S, by mass spectrometry, even in severe analyzed gas data have to be automatically inserted in a time
conditions. The innovative aspect of this technology is the use or depth database and available for an on-demand, real-time
at the rig site of a mass spectrometer used as a detector log, combining ROP, lithology, etc.
coupled to a gas chromatograph, instead of the classical flame The chromatographs equipped with flame ionization detectors
ionization detector, allowing simultaneous qualitative and that are currently used can detect C1 to C5 quickly (less than
quantitative detection of components of interest. Only recent one minute). However, it takes too long for them to analyze
advances in mass spectrometry design have made the use of the heavier hydrocarbons (C6-C8) and they cannot measure
this tool possible at well sites, often in critically the non hydrocarbons or sour gases at all. Furthermore, they
severe conditions. very often provide a relatively limited C1/C2 discriminating
This brand new gas chain has been called FLAIR, for Fluid ratio (this ratio is generally up to 350, therefore the detection
Logging &Analysis in Real time13,14. of C2 when the quantity of C1 is 350 times greater is
very difficult).
FLAIR equipment description. To overcome these limitations and obtain universal detection
Gas Trap: The C1-C8 FLEX extractor. A constant flow of the components leaving the chromatographic column, a
and volume extraction by mechanical agitation is used to specific mass spectrometer has been designed to be used as a
produce a representative sampling of components of interest detector, since it can detect non-hydrocarbon and sour gases as
from the drilling fluid, from C1 to C8 including the aromatic well as hydrocarbons. With the addition of the mass
compounds and sour gases. spectrometer, this analyzer can detect co-eluting peaks since
Features of the FLEX (C1-C8 Fluid Extractor) include: each different ion current is measured. The maximum allowed
C1/C2 ratio is thus dramatically improved and can be as high
• A specific sampling device which can be placed close as 8500.
to the bell nipple to reduce gas losses during To get an analyzing cycle up to C8 in 90 seconds and up to C7
surface circulation. in less than 60 seconds, an electronic pressure control device
• A volumetric pump used to suck the mud into the has been introduced into the analyzer, allowing a variation in
degassing chamber to avoid the effects of variations the flow rate of the carrier gas versus the cycle time. Thus the
in the mud level. lighter components such as C1 or C2, with lower flow rates,
are retained more than the heavier components such as
• A second pump, located in the Mud Logging unit, benzene to octane which are intentionally accelerated. Another
maintained at a specific rate to keep a constant ratio innovative feature of the GC-MS analyzer is a device that
between the pumped mud volume and the volume of allows injection into the chromatographic part of the analyzer
gas to be analyzed: extracted gas and additional of a constant volume of sample taken from the transfer line
carrier gas such as air, nitrogen or helium. under particular temperature and pressure conditions.
• A pre-extraction mud heating system to extract heavy A specific pneumatic module permits the use of two different
components usually found in liquid state at ambient C1-C8 extractors with the same analyzer. Two complete and
conditions, such as hydrocarbons like C8. independent gas circuits allow real-time comparison between
Moreover, a specific effort has been made to enhance Gas OUT (mud taken close to the bell nipple) and Gas IN
extraction efficiency mechanically by increasing the amount (mud taken at the pit). This equipment is stacked in two 19-in
of energy available at the extractor and optimizing the ratio of racks and can be easily installed in a mud logging unit. After a
gas and mud volumes. complete cycle, which takes 90 seconds up to C8, results are
sent automatically to the computerized mud logging system
Transport Line. A mud-logging unit can be placed up to for real-time monitoring, storage and interpretation. A new
100m from the sampling point. To minimize sample loss cycle then begins. The process thus ensures continuous
during transport, a new transfer line and specific couplings to measurement of gases while drilling.
8 SPE 84383
By way of example, Fig.22 shows the gas log versus depth could help in assessing the origin of oils and condensates
obtain with the FLAIR system. This log proves the extremely (marine, terrigenous or lacustrine).21 Thus, the data obtained
good consistency of heavy components data compared to with the new FLAIR gas acquisition chain, associated with the
regular C1 to C5 measurements. This example comes from an improved interpretation method from GWDTM, will give birth
oil base mud taken at the shale shakers, with temperature of to real geochemical logs while drilling which will be
the mud around 15°C in a deep offshore situation. integrated in formation evaluation and reservoir modeling at a
very early stage of the petroleum E&P process. However, this
FLAIR potential for GWDTM. We have demonstrated that raises the question of the differential bottom to surface transfer
C1 to C5 hydrocarbon mud logging gas data can provide function for these different molecules.
essential information for formation evaluation, i.e. net pay,
water saturation, porosity, fluid contacts or lithological Conclusions
changes for example, similar to the aims of electric logging. Thanks to great improvements in both the gas chain equipment
To this end, crosscheck any of results obtained from mud- and the interpretation method, the gas data obtained while
logging gas data with interpretation of electric logs needs to be drilling proves to be very useful in early formation evaluation.
done. However, once the validation is done, a scenario can be Special emphasis is laid upon the need for the gas chain to
envisaged where the formation evaluation by mud logging gas comply with minimum technical specifications in order to
data with just a minimal suite of electric logs will be sufficient ensure good quality gas data. If these specifications are
for the development of an oil/gas field. correctly taken into account, the GWDTM method is able to
Extending the range of components classically measured at the bring important added-value within the petroleum E&P
well site opens new prospectd with respect to the identification process, for instance in reducing uncertainties for
and interpretation of formation while drilling, such as : hydrocarbon-bearing reservoir identification where electric
logs remains doubtful, or even in yielding additional pay zones
CO2. CO2 quantification while drilling is of prime interest. not seen by logs. This is particularly the case in multi-layered
The ability to log CO2 gas with such surface equipment would environment, associated with thin beds.
help to eliminate wire-line RFT sampling runs. This could Furthermore, a good quality gas chain (from gas trap to the gas
provide significant savings during the course of an extensive chromatograph) is essential for hydrocarbon fluid behavior
drilling program particularly when the inability of supercombo differentiation. It is impossible to get a valid interpretation for
and RFT logging runs to reach bottom can become a frequent thin hydrocarbon-bearing reservoir identification with
occurrence. Nevertheless, to be able to mud log the CO2 determination of fluid units if the gas chain does not comply
correctly, a lime-free drilling fluid system is recommended15 with the technical specifications required by GWDTM. Not
since lime reacts strongly with CO2 and inhibits only does the gas chromatograph needs to combine fast cycle
surface logging. time, sensitivity and accuracy, but the gas trap has also to be a
real of the constant volume type. This is of prime importance
for providing accurate fluid sampling recommendations.
C6s and aromatics compounds. C6s (or C6+) and The use at the rig site of a GC-MS instead of the current GC
aromatic hydrocarbon logging is a new measurement which analyzers, is a major technical evolution for the gas chain
will need to be deeply understood to be interpreted. acquisition within the scope of added-value interpretation for
Comparison between two different hydrocarbon chemical formation evaluation. Preliminary results show the great
series such as alkanes and aromatics will certainly point out potential of this new way of monitoring the mud gases while
new interpretation aspects in mud logging gas data analysis. drilling. Fundamental understanding of thermodynamic and
This can be noted for instance on Fig.23 where the C6H6/C6s geochemical behaviors of light hydrocarbons will lead to the
log presents some differences (trend, peaks) compared to the emergence of an innovative geochemical log at the well site.
C1/C6s log.
Furthermore, the difference in their solubility in water could Acknowledgements
help in the characterization of fluid contacts or may be used in The authors wish to thank the management of Total as well as
conjunction with other water soluble compounds such as the Total operating subsidiaries for permission to publish this
acetic acid to better estimate the type of fluid in place, or paper and the data it contains. We would also like to extend
evaluate distance of a given level from the water zone. our appreciation to Carlo Carugo, Gianfranco Bagnoli and
other ENI people, as well as to Denis Kandel from Total, for
In any case, it seems obvious that these new measurements their contribution to the construction of the GWDTM method as
should involve not only geologists but also geochemists and well as to the gas chain technical specifications, within the
PVT specialists. The use of light hydrocarbons is well known joint Elf EP / ENI Agip Div. well data project. Special thanks
in organic geochemistry. 16-21 For instance, the different to Bernard Barraud and Gérard Ségalini from Total for their
molecules of the C7 family (e.g. n-heptane, toluene and contribution to the construction of the GWDTM method, their
methyl-cyclohexane) proves useful for the assessment of an involvement in the field cases treated as well as fruitful
oil’s geochemical history in terms of maturity level, diffusion, discusions. Lastly, thanks to Yves Kerbart who initiated the
water washing, evaporative fractionation or biodegradation.18 cross-plot interpretation method at Geoservices.
It has also been proposed that relative proportions of
isoalkanes, cyclo-pentanes and cyclo-hexanes (+ toluene)
SPE 84383 9
9- Ten Haven, H.L., Simon, B.S., Brevière, J. and Le Cann, J.P.: Jérôme BREVIERE is at present Head of the Fluids
“Applications and Limitations of Mudlogging Gas Data in Formation Department in Geoservices, France. He is a graduate physicist
Evaluation and Hydrocarbon Detection” AAPG International and his research work focuses on PVT, gas chromatography
Conference & Exhibition (2000)
and mass spectrometry, adapted to well site applications.
10- Kandel, D., Quagliori, R. Segalini, G. and Barraud, B.:
“Improved Integrated Reservoir Interpretation Using Gas While Francis LARAN is a reservoir engineer in the GWD team for
Drilling Data”, paper SPE65176 first presented at the 2000 SPE
Total in Pau. He joined Elf EP in 1975 and worked in
European Petroleum Conference, Paris, France, 24-25 October,
published by SPE Reservoir Evaluation & Engineering, (December reservoir department in different subsidiaries in France,
2001), 489. Netherlands, Congo and Cameroon for formation evaluation
and field monitoring mainly and performed reservoir
11- Wright A.C., Hanson S. A. & De Laune P. L.: “A New simulation in head quarter. He holds a diploma of Physical
Quantitative Technique for Surface Gas Measurements”, SPWLA
measures from IUT in Toulouse, France.
34th Annual Logging Symposium (1993).
12- De Pazzis, L.L., Delahaye, T.R., Besson, L.J. and Lombez, J.P.: Hervé CHAUVIN is currently the Head of Mud Logging
“New Gas Logging System Improves Gas Shows Analysis and interpretation products for Geoservices in Paris, France since
Interpretation,” paper SPE 19605 presented at the 1989 SPE Annual 2002. After graduating in geology from the University of
Technical Conference and Exhibition, San Antonio, Texas, 8-11
Rennes, France, in 1985, he joined Geoservices in 1988. His
October.
career with Geoservices started as mud logger. He then
13- Brevière, J., Herzaft, B. and Mueller, N.: “Gas Chromatography – worked as head of training and head of Operation Assistance.
Mass Spectrometry (GCMS) – A New Wellsite Tool for Continuous He joined the Research and Development Department in
C1-C8 Gas Measurement in Drilling Mud – Including Original September 2001.
Extractor and Gas Line Concepts. First Results and Potential”,
SPWLA 43rd Annual Logging Symposium (June 2-5, 2002), 1.
Claudine BOEHM is a senior operation geologist in Pau, in
14- Brevière, J., Evrard, J.F. and Duriez, G.: “Enhanced, Continuous charge of well preparation process. She is a PhD graduate in
C1-C8 Data from Mud Logging : Deep Offshore Results and Structural Geology with a specialization at the Ecole Nationale
Potential”, OWA-03 Conference and Exhibition (2003). Supérieure des Pétroles et Moteurs. She joined Elf EP in 1983
15- Harrison, J.R, Stansbury, M., Patel, J., Cross, T. and Kilburn, M.: as a log analyst. She currently manages a project concerning
“Novel Lime-Free During Fluid System Applied Successfully in Gulf advanced interpretation of mud logging data.
of Thailand”, SPE/IADC 52817 (1999).
10 SPE 84383
• The gas trap should be located near the bell-nipple, taking (Relative error between observed values and true values)
into account the safety (equipment) and its accessibility (see glossary)
(maintenance) • Resolution: 10 ppm
• Mud outlet below the mud level (Smallest variation in the gas composition which produces
Gas line a detectable change in the signal)(see glossary)
• 2 independent gas lines (one active and one spare) • Transit Time from gas trap to TG detector to be checked
preferably with continuous purge capability routinely
• Kept to a minimum length; thus, no loops or twists at • Visual and audible alarms set on TG inside the unit
anytime (alarms threshold to be fixed according to company
request).
• Condensation collector on each gas line
• The systematic computation of NTG (Normalized Total
• No polyethylene (to avoid segregation effects of the gas Gas) uses the following formula:
components) or steel allowed for gas lines. PVC gas line
Normalized Gas (m3/m3) = 14.71*(TG*Flow
is recommended.
Rate*0.2642)/((ROP*3.281)*(Bit Size 2))
• Gas line should be available for extreme temperatures (i.e.
where :
5 - 40°C).
TG = Raw Total Gas (%)
• Use an insulation system.
ROP = Rate of Penetration (m/h)
• Air inlet far from any pollution sources (such as
rig engines) Flow Rate = l/min
• ‘Gas mixture + Air vector’: pressure and suction flow Bit size = inch
should be constant, according to the specification of the Calibration
equipment, with a visual control into ML unit.
• Unit: compulsory in equivalent methane in air (EMA)
• Suction flow must be checked daily and each change must using calibration bottles with only methane (do not use
be reported on the Master (Mud) Log. multi-components mixtures).
• Gas line diameter as small as possible. • Type: master calibration using minimum of 3
• Transit time through gas line: maximum 2 min depending points at different methane concentration (C1= 1 000, 10
on gas line diameter & length 000 and 100 000 ppm).
• Desiccant product: silicagel not allowed. Calcium calibration check using 2 points at
Chloride is recommended. different methane concentration (C1= 1 000 and
100 000 ppm).
• Gas injection at gas trap location is only to check that the
line is not blocked, but not used for checking gas • Frequency: master calibration must be performed before
line efficiency the Spud In (in the Contractor’s base or laboratory or at
well-site). A master calibration chart has to be provided
• T-valve with hypodermic needle for vacutainer samples by the Contractor to the Company representative at well-
site for unit acceptance.
Gas detector
Calibration check must be performed 1 per trip to surface
• Type: FID for hydrocarbon gases (possibly TCD, but not or 1 per drilling phase. Minimum once a day. In case the
yet proven for GWDTM analysis) calibration check gives bad results (exceeding the required
accuracy range), a new master calibration must be
• Eventually TCD type for acid gases (CO2, H2S), not yet
performed at well-site.
proved for GWD analysis
12 SPE 84383
• Policy: no manual dilution allowed. Certified calibration Contractor to the Company representative at well-site for
gas bottles are compulsory. unit acceptance.
Calibration check must be performed 1 per trip to surface
Gas chromatography or 1 per drilling phase. Minimum once per day. In case the
calibration check gives bad results (exceeding the required
• Type: FID (possibly TCD type, but not yet proved accuracy range), a new master calibration must be
for GWDTM analysis) performed at well-site.
• Type of analysis: Chromatographic analysis from C1 • Policy: no manual dilution allowed. Certified calibration
to nC5. gas bottles are compulsory.
• Use high resolution gas chromatograph with a cycle time
maximum 90 sec (C1-nC5)..
• Measurement unit: ppm.
• Component values computed using peak areas (do not use
peak height).
• Accuracy: +/- 5 %
(Relative error between observed values and true values)
(see glossary)
• Resolution: 1 ppm
(Smallest variation in the gas composition which produces
a detectable change in the signal) ) (see glossary)
• Threshold of quantifiable value: 10 ppm (see glossary)
• Saturation limit must be clearly defined
• C1/C2 separation capacity: ratio minimum requested
value = 200, recommended = 500.
• Each tool (main and/or backup) has to be identified by
Contractors (serial number, technical specifications &
characteristics including software version used) before
well spuding
• Displayed on front panel: oven Temperature, sample
pressure and flow. It is recommended to insert these data
on the database.
• Type and version have to be recorded on database and
displayed on Master (Mud) Log document.
• No gas sample must be trapped into chromatograph for
later analysis to avoid possible gas
alteration/deterioration.
• It is required the possibility to display or print the
chromatograms on request.
Calibration:
• Type: master calibration: minimum 3 points using gas
mixture (C1-nC5) at known components concentration
(with C1= 100, 1 000, and 100 000 ppm,).
calibration check : 1 point using gas mixture
(C1-nC5) at known components concentration (with C1=
10 000 ppm).
• Frequency: master calibration must be performed before
spuding (in the Contractor’s base or laboratory or at well-
site). A master calibration chart must be provided by the
SPE 84383 13
Data management
• Compulsory: both time and depth database
Versus depth:
• Sampling rate : maximum every 50 cm, recommended
every 20-25 cm
• List of parameters compulsory to be recorded versus
depth (Table A-1).
• Depth database without gas events as: trip gas, PCG,
calibration, etc…).
Table A-1
14 SPE 84383
Versus time:
• Sampling rate optimized with Total Gas sampling rate
requirement
• List of parameters compulsory to be recorded versus time
(Table A-2).
TM
Fig. 2 Needed data for a GWD study
TM
Fig. 1 GWD interpretation method workflow
TM
Fig. 4 Typical gas data logs and cross-plots used in GWD
interpretation
Fig. 11 Composite log for well A1: uncertainty reduction on net pays
TM
identification with GWD
SPE 84383 17
TM
Fig. 12 Comparison of GWD interpretation for well A1 based on Reserval and GeoFID gas chains results
TM
Fig. 14 Synthetic Log for well B1: fluid and lithological interpretation from logs and GWD
18 SPE 84383
TM
Fig. 15 composite log for well B1: uncertainty reduction on net pays identification with GWD
TM
Fig. 16 Composite log for well B2: fluid interpretation from logs and GWD , an example of differentiation between water flushed
and original aquifer levels
Fig. 17 Comparison of reservoir gas logs for wells D1 and D1-T: change in gas composition
SPE 84383 19
Fig. 19 Composite log for well D2: reservoir gas log, C3 vs. C2
and C1/C3 vs. C2/C3 cross-plots