WA AP Chemistry - Review of lectures 1-5, part B Acl— ard vie Name: Key Ag Week Guo Be Nah ~heatty 4 Week Base 1. Consider a solution formed by mixing 100.0 mL of 0.10 M HA (Ka = 1. x10" BL ix? 100.0 mL of 0.10 M NaA and 100.0 mL of 0.10 M HCL. In calculating the pH for the final solution, you would make some assumptions about the orderin == (X10 which various reactions occur to simplify the calculations. State these ae -8 assumptions. Does it matter whether the reactions actually occur in the hw assumed order? ‘ oa has HE ito ‘Aci, onal i dominnk pH Cortifecotoue, be atime Hel H ful digiverato % seg jo E Ua dees art Cribibike rch PLE) Ar-*Se An dbves ook pH 2—leylo.t) = 1.0 loose (ince. a>! Oeper NWT YRG: 2. Consider two solutions of the salts NaX (aq) and NaY (aq) at equal concentrations. What would you need to know to determine which solution has the higher pH? Explain how you would decide (perhaps even provide a samplecalculation). y™ ye ~~ (Moth weok Bases) need Kh valves : The highe Kb vala will be te hanger Bate ¢ the higher pH 3. Aweak acid, HA, dissociates 10.0 % in solution. Draw a representation of what a solution of this acid would look like at equilibrium. Draw a second beaker demonstrating the behavior of HCl, using the same number of L Derrertin Emote : ieee ony . TA ws AA eel - We elo Bree Bt elo BARA Hea teen ane” ¢ BANA, Lee EE eer é veel a, de 1F te wolecde! iy = Mee eee * i |) 4. Astudent makes a solution by dissolving 20.0 grams of NazCOs in enough Rola water to make 400. ml of solution. What is the pH of the solution? > 2oy Ne2Os 2 pile O«432M ons Wo= Heoy +o Kbit ree + gs, tomglonl CO Toy ve +e iD | Meco. a. E DHI-X x * | Rar 2 4,300, Prssuere, EID —X VY ONE Ken = s-bx0 -4 “4 Xe [av-) = TPG (O47) = 0004 | \xto tts = Fs Chek: Rouge = Saget 33 Gets Ad Fan Sec. ET 2 2nd awe vas BKIG make Ken 27 tee canbe HQNeked,FoR Ye raed Rails one rave > Ce He Al ClO~R pln POE ws = No Sie Comparer We Ka where the Woo a v8 os =foxe a MepH Vala, Soe Eath Kesptetive ron. Kobe Cetigthe nears” yey Ll Kae UNO g graype ene eel. eves WEHR gee rade kal SeeOK ee vsry S's. ‘The pl of 0.0100 M solution of yamteacd (HOCN) is 2.77 ata certain x temperature, Calculate Ka for HOCN, based on this data. ¢ LH) 0.00199 Hoey Ht Den xt = ® Fs 0.0100 2 Kq= perk E phon OF ORK = noo) Lass © .9110 —0.00 F790 6. Codeine (CisH21NOs) is a derivative of morphine that is used as an analgesic, narcotic, or antitussive. It was once commonly used in cough syrups, but is now only available only by prescription because of its addictive properties. If 2-959 poten the pH of a 0.0017 M solution of codeine is 9.59, calculate Kb. 4 hoe caddie ee oie Petre = 8.2% 44) Cocke + Gee 10 8.0019 ne . = 3, ond SM anes x . 7 Gor, B.SOIF a 3A a Som Aciorc "65 xi! Sao” 8. Whatis the pH ot Oe Mae sain Ae Kaz 19X10 nee a-~+Aho et + oW- - -s Hesy Z dyn hes outs Kee i? g.guni 0.0s0-K ve] te ie ary > 0.050 é ow~ Owolol Kelot= V2. Festa) = 0:00, = Seem. See xin 9. What is the pH ofa 0.400 MW ee i g OOD 2h KE ME |.BD perp . > pills 70 GH=)-0) iD. + yatic. My * <2 1h + ant * S00" 5. Sxeni ov ound & ar eae te Aitume ontto—x 20d = 44 A ter to make 125 L of P2S42 10.A 2.14 g sample of sodium hypoiodite is dissolved in wa solution. The solution pH is 11,32. What is the Kb for the hypoiodite fon? Lor +Moes oe ae y= Q.mery™ (0.90209) * ee He : cree ee 0.0103 — dons = 0.00209 | pol = WH-thoae 248 ouaia-x 8 268 LoWex= 10” 2 e.gpz0nm