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CLD 10603
Fluid Characteristics and Behaviors
Universiti Kuala Lumpur
Malaysian Institute of Chemical and Bioengineering technology
Objectives
Student should be able to:
i. Define and determine the fluid properties
such as:
Weight, mass, density, specific gravity, specific
weight, specific volume, absolute viscosity,
kinematic viscosity.
ii. Understand the liquid behavior:
Surface tension and capillary effect.
Introduction
Any characteristic of a system is called a property.
o Familiar: pressure P, temperature T, volume V, and mass m.
o Less familiar: viscosity, thermal conductivity, surface tension.
Intensive properties are independent of the mass of the
system. Examples: temperature, pressure, and density.
Extensive properties are those whose value depends on
the size of the system. Examples: Total mass, total
volume, and total momentum.
Extensive properties per unit mass are called specific
properties. Examples include specific volume v = V/m
and specific total energy e=E/m.
Mass (m)
Weight (W)
The magnitude of the force acting on the
object due to Earth’s gravity field.
W mg
m = mass (kg)
g = standard earth gravity
= 9.81 m /s2 or 32.174 ft/s2
Density (ρ)
The quantity of matter contained in a unit
volume of the substance.
mass m
volume v
Density (ρ)
Density is highly variable in gases and is a
function of the gas composition, its
temperature and its pressure.
P
RT
P = pressure
T = temperature
R = gas constant
liquid liquid
SGliquid
water 998 kg / m3
Unit : None
Weight W
Volume V
g
Question 2
Although most modern thermometers contain alcohol, older
ones often contained mercury (Hg). During fabrication of a
certain thermometer, the Hg was inserted under standard
conditions so that it filled a reservoir of volume 50 mm3.
Given that Hg has a specific gravity of 13.6 and the density
of water is 1 g/cm3, calculate the weight and mass of the
Hg in the thermometer.
volume 1
mass
Viscosity ()
Viscosity is a property
that represents the
internal resistance of a
fluid to motion.
= absolute viscosity
xy = shear stress
xy du/dy = velocity /distance
du
( ) Unit : kg/m.s or Pa.s or N.s/m2 or lbf.s/ft2 or
dy poise
(1 poise = 0.1 Pa.s)
Cohesive force
Force which acts to hold together the like
atoms, ions, or molecules of a single body.
Surface Tension
Tendency of liquids to reduce their exposed
surface to the smallest possible area.
Small insects
walk on water
Soap bubble
Water beads on
flower petals
Water droplets
from rain
CLD 10603 20 Chapter 2: Fluid Characteristics and Behaviors
Universiti Kuala Lumpur
Malaysian Institute of Chemical and Bioengineering technology
Surface Tension
Liquids droplets behave like small spherical balloons
filled with liquid, and the surface of the liquid acts
like a stretched elastic membrane under tension.
The pulling force that causes this is
due to the attractive forces between molecules
called surface tension s.
Attractive force on surface molecule is not
symmetric.
Repulsive forces from interior molecules causes the
liquid to minimize its surface area and attain a
spherical shape.
Surface Tension
A molecule I in the interior
experience an attractive
force from neighboring
molecules which surround
on all sides.
I
Molecules on the surface
have neighboring molecules
only on one side (the side
facing the interior) and thus
experience an attractive
force which tends to pull
them into the interior .
CLD 10603 22 Chapter 2: Fluid Characteristics and Behaviors
Universiti Kuala Lumpur
Malaysian Institute of Chemical and Bioengineering technology
Surface Tension
The total energy of the fluid
system is minimized when each
molecule has the “correct” number
of neighbors.
The surface molecules of liquid do
not have identical molecules above
them, they will be more strongly
attracted to their neighbors below
and in the plane of the interface.
The result is a layer of surface
molecules that at the macroscopic
level behaves as an elastic
membrane.
Surface Tension
(A) The relevant force balance at the contact line. (B) Example
of a liquid wetting a solid as defined by a contact angle θc <
90◦. (C) In contrast, the liquid does not wet the solid, since θc >
90◦
CLD 10603 26 Chapter 2: Fluid Characteristics and Behaviors
Universiti Kuala Lumpur
Malaysian Institute of Chemical and Bioengineering technology
Capillary Effect
Capillary effect is the rise or
fall of a liquid in a small-
diameter tube.
The curved free surface in
the tube is call the
meniscus.
Water meniscus curves up
because water is a wetting
fluid.
Mercury meniscus curves
down because mercury is a
nonwetting fluid.
Force balance can describe
magnitude of capillary rise.
Capillary Effect
2 cos
h
gr
Where:
h = height capillary rise, m
= surface tension, N/m
= contact angle
= density of a liquid, kg/m3
g = gravitation force , 9.81 m/s2
r = radius of tube, m
Capillary Effect
Question 3
Capillary Effect
Question 4