Kg/dia 1 2 3 4 5 6

Pb° 250
PbSO4 804.090
PbO 107.700
PbO2 115.399
Inerte 162 162 162
H2SO4 22.727
H2O 53.030 3.849443 95.438 89214
Na3Cit 371.47737
Na2HCit 339.847524
Na4Pb(Cit)2 , 4073.14989
H2O2 40.902
N2H4 15.397772
N2 13.5
H2 1.0
O2
NaOH
Pb(OH)2
Na2SO4 408.938918

CORRIENTE 1
PESO MOLECULAR (Kg/kmol) 0.66m1=mPb°=1000Kg/d
Pb° 207.8
PbSO4 303.8 % KgPb/dia Kmol/dia
PbO 223.8 Pb° 25 250 1.203
PbO2 239.8 PbSO4 55 550 2.646
H2SO4 98.064 PbO 10 100 0.481
H2O 18 PbO2 10 100 0.481
Na3Cit 258.06 TOTAL 100 1000 4.811
Na2HCit 236.0872
Na4Pb(Cit)2 677.278
H2O2 34
N2H4 32.012 m1=1000/0.66 1515.15 Kg/d
N2 28.012
H2 2 5%Humedad 75.7575758 = H2SO4
O2 32 H2O
NaOH 39.999
Pb(OH)2 241.19 mPb1(total) 1352.9
Na2SO4 142.042
Cit (C6H5O7) 189.066

CORRIENTE 5
H2O = 2879 L
1M Na2SO4 = 1M(Na2SO4)(1mol/LH2O)
(1mol/L)(2879L) = 2879mol(Na2SO4) = 2.879 Kmol
= 408.938918 kg/d
Na3Cit 0.5M 0.5M(Na3Cit)(1mol/LH2O) = 1.4395
1M Na2HCit 0.5M 0.5M(Na2HCit)(1mol/LH2O) = 1.4395

6.014Kmol Na4Pb(Cit)2 = 100% (para la corriente 5 y 7)

CORRIENTE 11
La corriente es igual f por los moles dela corriente 10
f = Kmol H2O(11)/Kmol H2O (10)
f = 159.9Kmol/4951.5Kmol
f = 0.032

Kg/dia 1 2 3 4 5 6
Pb° 1.203
PbSO4 2.647
PbO 0.481
PbO2 0.481
Inerte 2.135 2.135 2.135
H2SO4 0.232
H2O 2.946 0.214 5.302 4956.33333
Na3Cit 1.4395
Na2HCit 1.4395
Na4Pb(Cit)2 6.014
H2O2 1.203
N2H4 0.481
N2 0.481
H2 0.481
O2
NaOH
Pb(OH)2
Na2SO4 2.879

CORRIENTE 1
Inerte
1000kgPb°/d 4.82648776 kmol 66%
mPb1(total) = 5.2 Kmol/d 5%humedad

Inerte = 2.135 Kmol/dia

1.203Kmol 1.203Kmol 2.406Kmol

RXN 1 Pb° + H2O2 + 2Na2HCit
0.481Kmol 0.481Kmol 0.481Kmol
RXN 2 PbO2 + N2H4 + 2Na2HCit
0.481Kmol 0.481Kmol 0.481Kmol
RXN 3 PbO + 2Na2HCit Na4Pb(Cit)2 +
2.647Kmol 5.294Kmol 2.647Kmol
RXN 4 PbSO4 + 2Na3Cit Na4Pb(Cit)2 +
0.232Kmol
RXN 5 H2SO4 + 2Na3Cit 2Na4Pb(Cit)2 +

RXN 6 Pb(OH)2 + 2Na2HCit Na4Pb(Cit)2 +

PRECIPITADO
1.203Kmol 2.406Kmol 1.203Kmol 1.203Kmol
Na4Pb(Cit)2 + 2NaOH Pb(OH)2 + 2Na3Cit

ELECTROGANADO
4.811Kmol 4.811Kmol 4.811Kmol 2.4055Kmol
Na4Pb(Cit)2 + H2O Pb° + (1/2)O2

Na4Pb(Cit)2 + 2e Pb° + 2Na2Cit

H2O (1/2)O2 + 2H
 7 8 9 10 11 12 13
1000

89214 89127 2878.2 2879

371.47737 371.47737 11.8872758 371.47737
339.847524 339.847524 10.8751208 339.847524
4073.14989 814.765434 26.0724939

76.976

408.938918 408.938918 13.0860454 408.938918

CORRIENTE 1

550 KgPb°/d 207.8 KmolPb°/d

804.1 KgPbSO4/d 303.8 KmolPbSO4/d

100 KgPb°/d 207.8 KmolPb°/d

107.7 KgPbO/d 223.8 KmolPbO/d

100 KgPb°/d 207.8 KmolPb°/d

115.4 KgPbO2/d 239.8 KmolPbO2/d
.

30% = 22.7272727 Kg/d

70% = 53.030303 Kg/d

Kg/d Inerte 162.20 Kg/d

Kmol
Kmol
 7 8 9 10 11 12 13
4.812

4956.3 4951.5 159.9 159.944444

1.4395 1.4395 0.046064 1.4395
1.4395 1.4395 0.046064 1.4395
6.014 1.203 0.038496

2.4055

2.879 2.879 0.092128 2.879

CORRIENTE 10
H2O 4956.3Kmol-4.8Kmol =
7.31286025
0.36564301 Na4Pb(Cit)2 80% Electrolisis =

1.203Kmol 2.406Kmol
Na4Pb(Cit)2 + 2H2O
0.481Kmol 0.962Kmol 0.481Kmol 0.481Kmol
Na4Pb(Cit)2 + 2H2O + N2 + H2
0.481Kmol
H2O
2.647Kmol
Na2SO4

Na2SO4

2H2O
 4.811Kmol
+ Na2HCit

cátodo
+ 2e ánodo
 14 15 16 17

2879 86274.936
371.47737 359.590094
328.972404
788.69294

290.15157
395.852873

CORRIENTE 2
(Utilizando la rxn 2)
NH4 80% 15.397772
H2O 20% 3.849443

CORRIENTE 3
(Utilizando la rxn 1)
H2O 70% 95.438
H2O2 30% 40.902

CORRIENTE 4
(Utilizando la rxn 2)
N2 15.397772 KgNH4/d 32.012 KmolNH4/d
13.5 KgN2/d 28.012 KmolN2/d

H2 15.397772 KgNH4/d 32.012 KmolPb°/d

1.0 KgN2/d 2 KmolPbSO4/d
14 15 16 17

159.944444 4793.052
1.4395 1.393436
1.393436
1.164504

1.203
2.786872

4951.5 Kmol

1.203 kmol