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Langmuir and Freundlich Isotherm Analysis

The document contains data for Ci (initial concentration) and Ce (equilibrium concentration) values. It then plots the Langmuir and Freundlich isotherm models from the data. For the Langmuir model, it calculates the maximum monolayer capacity qm as 39.0625 mg/g and the Langmuir constant KL as 0.21 L/mg. For the Freundlich model, it calculates the Freundlich constant KF as 27.233 and the heterogeneity factor n as 15.822. It determines that the Langmuir model fits the data better based on its regression coefficient being closer to 1.

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Maharghya Biswas
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32 views2 pages

Langmuir and Freundlich Isotherm Analysis

The document contains data for Ci (initial concentration) and Ce (equilibrium concentration) values. It then plots the Langmuir and Freundlich isotherm models from the data. For the Langmuir model, it calculates the maximum monolayer capacity qm as 39.0625 mg/g and the Langmuir constant KL as 0.21 L/mg. For the Freundlich model, it calculates the Freundlich constant KF as 27.233 and the heterogeneity factor n as 15.822. It determines that the Langmuir model fits the data better based on its regression coefficient being closer to 1.

Uploaded by

Maharghya Biswas
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd

Ci Ce qe 1/Ce 1/qe logCe logqe

151 22 32.25 0.045455 0.031008 1.342423 1.50853


199 56.5 35.625 0.017699 0.02807 1.752048 1.551755
245 95 37.5 0.010526 0.026667 1.977724 1.574031
300 150 37.5 0.006667 0.026667 2.176091 1.574031
353 200 38.25 0.005 0.026144 2.30103 1.582631
400 246 38.5 0.004065 0.025974 2.390935 1.585461
446 290 39 0.003448 0.025641 2.462398 1.591065
493 340 38.25 0.002941 0.026144 2.531479 1.582631

Plot of Langmuir Isotherm


0.035
0.03
f(x) = 0.1214012532x + 0.0255854395
0.025 R² = 0.9806995504
0.02
1/qe

0.015
0.01
0.005
0
0 0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.05
1/Ce

For Langmuir Isotherm, 1/qe = (1/qm* KL)*Ce + 1/qm


So, 1/qm = 0.0256 (Intercept)

Therefore, qm = 39.0625

(1/qm*KL) =0.1214 so, KL = 0.21

Therefore, the value of Langmuir Isotherm constant, KL = 0.21


Plot of Freundlisch Isotherm
1.6
f(x) = 0.0631612148x + 1.4350694058
R² = 0.8983563646
1.58

1.56

1.54
logqe

1.52

1.5

1.48

1.46
1.2 1.4 1.6 1.8
logCe 2 2.2 2.4 2.6

For Freundlich Isotherm, LOG (qe) = (1/n)* LOG (Ce) + LOG (KF)

So, LOG (KF) = 1.4351 (Intercept) and (1/n) = 0.0632 so, n=15.822
Therefore, KF = 10^(1.4351) = 27.233

So, the value of Freundlich Isotherm constant, KF = 27.233

For langmuir isotherm,


the regression coefficient value is 0.9807
which is more closer to 1
while regression coefficient
for Freundlisch isotherm is 0.8984.
Hence, langmuir isotherm is more
appropriate for the given set
of values of Ci and Ce.

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