Vidyamandir Classes

SOLUTIONS
Joint Entrance Exam | IITJEE-2018
Paper Code - B
8th April 2017 | 9.30 AM – 12.30 PM

VMC/JEE Mains-2018 1 Solutions

 Vidyamandir Classes

PART-C CHEMISTRY

61.(1) I3 is - sp3 d hybridised

- linear shape

62.(4) CH3COOK is a salt of a weak acid and a strong base

 Most basic

63.(1)

64.(1) Amidines, are stronger organic bases.

65.(1) Methyl orange is used for titration of strong acid and weak base.

66.(1)

67.(2) Cx H y Oz has z oxygen atom

 y y
Cx H y   x   O2 
 x CO2  H 2O
 4 2
 y
O atoms required for combustion  2  x  
 4

1  y 
z 2  x  
2   4  
y
zx
4
68.(1) During reduction H 2O 2 
 H2O

During oxidation H 2 O2 
 O2

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69.(2)

Option (2) is correct [NCERT Class XII Part-II, Page No.-340]

70.(1) B2 H 6  3O2 
 B2 O 3  3 H 2 O
27.66
nB2 H 6  1
27.66
n O2 required = 3

2H 2O 
 2 H 2  O2
n-factor for O2 = 4
 Number of equivalent = 3  4  12F  12  96500 C
i  t  12  96500
12  96500 12  96500
t s  h  3.2 hr
100 100  3600
71.(3) G  H  TS
 RTnk  H  TS
H S
nk  
RT R
H
Slope is
R
Since H is  ve
 Slope is positive.
n
72.(3) r  k A 
n
1  k  363  0.95  ….(i)
n
0.5  k  363  0.67  ….(ii)
From (i) and (ii)
n2
73.(3)

Option (3) is correct [NCERT Class XII Part-II, Page No 405]

74.(4) Case - I

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 Vidyamandir Classes

Case - II

 Two isomers (fac and mer) are produced if reactant complex ion is a cis isomer.
Only one isomer (fac) is formed if reactant complex ion is a trans isomer.

75 (4).

76 (3).

OH OH

COOH
NaOH H3O +
+ CO 2

(X)

OH OCOCH3

COOH COOH
H2SO4
+ (CO3CO)2O + CH3 COOH
Cat

(X) Aspirin

[NCERT class XII part II/Page No. 330]

77.(1)  Ba 2  (aq)  SO42  (aq)

BaSO 4 (s)  Ksp  1010

Na 2SO4  2Na   SO 42 
50  1
Conc. of SO 24  in final solution   0.1M
500
For final solution
  Ba 2  SO24   1010   Ba 2   109 M
    
M i Vi  Mf Vf

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 Vidyamandir Classes

C  450  109  500  C  1.1 109 M

78.(4) Kjeldahl method is not applicable to compounds containing nitrogen in nitro (NO2) and azo (N = N –) groups
and nitrogen present in the ring (pyridine) as nitrogen of these compounds does not change to ammonium sulphate.
[NCERT Class XI part II/Page No. 358]
NaOH
79.(1)  Al  OH 3 
Al  NaOH   NaAlO2
(M)
white gel ppt
(X)

Al  OH 3  Al2 O3
Al2O3 is used in chromatography as an absorbent. (Refer NCERT Class XIth/Part-II, Page-352)

80.(4)  H   Cl
HCl 
0.2M 0.2 M

 H   HS
H 2 S  K1  107

 H   S2 
HS  K 2  1.2  1013

 2H   S2 
H 2 S  K  K1  K 2
 1.2 1020
2
H   S2 
K     H    0.2M ,  H 2S  0.1
 H 2S  

20
 0.22 S2  
1.2  10   S2    3  10 20 M
0.1  

81.(1) (Refer NCERT Class XIth Part-II, Page-407)

The F ions make the enamel on teeth much harder by converting hydroxyapatite, 3Ca  PO 4  2  Ca  OH 2  ,

into much harder fluorapatite i.e. 3Ca  PO4 2  CaF2 


82.(2) NH 4 NO 2  N 2  2H 2 O

 NH4 2 SO4   NH3  H 2SO 4

Ba  N3 2  Ba  3N 2

 NH 4 2 Cr2 O7   N 2  4H 2 O  Cr2 O3

83.(3) NCERT Class XII/Part-II, Page No. 443

84.(1) Cr  H 2 O   Cl3

 6
x 03  0
x  3
Cr  C6 H6  
 2
x0  0
x0

K 2 Cr  CN 2  O 2  O2  NH3 

2 x2420  0
x  6

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 Vidyamandir Classes

85.(1) Pressure of cation in interstitial sites is ‘Frenkel’ defect.

15
86.(2) C6 H 6 (  )   6CO 2 (g)  3H 2 O ( )
O 2 (g) 
2

3
n (g)  
2

H  U  n (g) RT

1.5  8.314  298

 3263.9   3267.6 kJ / mol
1000
87.(2) BCl3 and AlCl3 are e deficient and thus act as Lewis acid

88.(1) KCl exist as K  and Cl

89.(2) Depression in freezing pt

Tf  i K f m

Less the value of i,

Higher the value of freezing pt.

For (2) i = 1 (min)

90.(2) H 22  does not exist as Bond order is zero

Electronic configuration of H 22  : 1s

2 2
*1s
22
B.O  0
2

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