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Paper - 1: Physics, Chemistry & Mathematics: This Booklet Contains 24 Printed Pages
Paper - 1: Physics, Chemistry & Mathematics: This Booklet Contains 24 Printed Pages
MRF No. :
: in words
2. Invigilator’s Signature :
PART A — PHYSICS 3. Two masses m 1=5 kg and m 2=10 kg,
ALL THE GRAPHS/DIAGRAMS GIVEN ARE connected by an inextensible string over a
SCHEMATIC AND NOT DRAWN TO SCALE. frictionless pulley, are moving as shown
1. The density of a material in the shape of a in the figure. The coefficient of friction of
cube is determined by measuring three horizontal surface is 0.15. The minimum
sides of the cube and its mass. If the weight m that should be put on top of m2
relative errors in measuring the mass and to stop the motion is :
length are respectively 1.5% and 1%, the
maximum error in determining the density
is :
(1) 2.5%
(2) 3.5%
(3) 4.5%
(4) 6%
2. All the graphs below are intended to
represent the same motion. One of them
does it incorrectly. Pick it up. (1) 18.3 kg
(2) 27.3 kg
(3) 43.3 kg
(1)
(4) 10.3 kg
k
(1) −
(3) 4 a2
k
(2)
2 a2
(3) Zero
(4)
3 k
(4) −
2 a2
37
(4) MR 2
9
10. Two moles of an ideal monoatomic gas 13. A granite rod of 60 cm length is clamped
occupies a volume V at 278C. The gas at its middle point and is set into
expands adiabatically to a volume 2 V. longitudinal vibrations. The density of
Calculate (a) the final temperature of the granite is 2.7×103 kg/m3 and its Young’s
gas and (b) change in its internal energy. modulus is 9.27×1010 Pa. What will be
the fundamental frequency of the
(1) (a) 189 K (b) 2.7 kJ
longitudinal vibrations ?
(2) (a) 195 K (b) −2.7 kJ (1) 5 kHz
(2) 2.5 kHz
(3) (a) 189 K (b) −2.7 kJ
(3) 10 kHz
(4) (a) 195 K (b) 2.7 kJ
(4) 7.5 kHz
σ a 2 − b2
(2)
1000
, 10
(2) + c 2
o b
50
(3) ,0
2
σ b2 − c2
(3) + a (4) 50, 0
o b
B
(1) Λn ≈ A + 2
λn
(2) Λn ≈ A +B λn (1) 0
(2) 15 mA
(3) Λ2n ≈ A+B λn2
(3) 11.5 mA
(4) Λn2 ≈λ (4) 13.5 mA
(1) C 3H6O 3
29. In a potentiometer experiment, it is found
that no current passes through the (2) C 2H 4O
galvanometer when the terminals of the (3) C 3H4O 2
cell are connected across 52 cm of the (4) C 2H4O 3
potentiometer wire. If the cell is shunted
by a resistance of 5 Ω, a balance is found
when the cell is connected across 40 cm of 32. Which type of ‘defect’ has the presence of
the wire. Find the internal resistance of cations in the interstitial sites ?
the cell. (1) Schottky defect
(1) 1Ω
(2) Vacancy defect
(2) 1.5 Ω
(3) Frenkel defect
(3) 2Ω
(4) 2.5 Ω (4) Metal deficiency defect
30. On interchanging the resistances, the 33. According to molecular orbital theory,
balance point of a meter bridge shifts to which of the following will not be a viable
the left by 10 cm. The resistance of their molecule ?
series combination is 1 kΩ. How much was
2+
the resistance on the left slot before (1) He2
interchanging the resistances ?
+
(2) He2
(1) 990 Ω
(2) 505 Ω (3) H−
2
(3) 550 Ω
(4) 910 Ω (4) H22−
(1) 5×10 −8
(4) A and D
(2) 3×10 −20
35. The combustion of benzene (l) gives CO2(g) (4) 5×10 −19
and H2O(l). Given that heat of combustion
of benzene at constant volume is
38. An aqueous solution contains an unknown
−3263.9 kJ mol −1 at 258 C; heat of
concentration of Ba2+. When 50 mL of a
combustion (in kJ mol−1) of benzene at
1 M solution of Na2SO4 is added, BaSO4
constant pressure will be :
just begins to precipitate. The final volume
(R=8.314 JK−1 mol−1) is 500 mL. The solubility product of BaSO4
is 1×10 −10 . What is the original
(1) 4152.6 concentration of Ba2+ ?
(1) 5×10−9 M
(2) −452.46
(2) 2×10−9 M
(3) 3260
(3) 1.1×10−9 M
(4) −3267.6 (4) 1.0×10−10 M
(4) 0
43. Which of the following are Lewis acids ?
(3) 9
47. The oxidation states of 50. Consider the following reaction and
Cr in [Cr(H 2 O) 6 ]Cl 3 , [Cr(C 6 H 6 ) 2 ], and statements :
K2[Cr(CN) 2(O) 2(O 2)(NH 3)] respectively
[Co(NH3)4Br2]++Br−→[Co(NH3)3Br3]+NH3
are :
(I) Two isomers are produced if the
(1) +3, +4, and +6 reactant complex ion is a cis-isomer.
(2) +3, +2, and +4 (II) Two isomers are produced if the
reactant complex ion is a trans-
(3) +3, 0, and +6 isomer.
(4) 6-iodohexanal
(2) NaBH4
(4) Sn - HCl
(2)
(1)
(3)
(2)
(3)
(4)
(4)
(4)
56. The predominant form of histamine
present in human blood is (pK a ,
Histidine=6.0)
58. The increasing order of basicity of the
following compounds is :
(1) (a)
(b)
(2)
(c)
(d)
(3)
(1) (a) < (b) < (c) < (d)
(2) (b) < (a) < (c) < (d)
(3) (b) < (a) < (d) < (c)
(4)
(4) (d) < (b) < (a) < (c)
(1) (1)
(2) (2)
(3) (3)
(4) (4)
1 1
69. Let A be the sum of the first 20 terms and 73. Let f ( x ) = x 2 + and g( x ) = x − ,
2
x x
B be the sum of the first 40 terms of the
series f (x )
x e R−{−1, 0, 1}. If h( x ) = , then the
12+2⋅22+32+2⋅4 2+52+2⋅62+..... g(x )
If B−2A=100λ, then λ is equal to : local minimum value of h(x) is :
(1) 232 (1) 3
(2) 248 (2) −3
(3) 464 (3) −2 2
(4) 496
(4) 2 2
70. For each t e R, let [t] be the greatest integer
less than or equal to t. Then 74. The integral
sin x
dy
+ y cosx = 4x , x (0, π) . If
dx
π π
y = 0 , then y is equal to :
π 2 6
(1)
8 4
(1) π2
9 3
π −8 2
(2) (2) π
2 9 3
8 2
(3) − π
9
(3) 4π
4 2
(4) − π
9
π
(4)
4 78. A straight line through a fixed point (2, 3)
intersects the coordinate axes at distinct
points P and Q. If O is the origin and the
76. Let g(x)=cos x 2 , f (x) = x , and
rectangle OPRQ is completed, then the
α, β (α < β) be the roots of the quadratic
locus of R is :
equation 18x 2 −9πx+π 2 =0. Then the
(1) 3x+2y=6
area (in sq. units) bounded by the curve
(2) 2x+3y=xy
y=(gof )(x) and the lines x=α, x=β and
y=0, is : (3) 3x+2y=xy
(4) 3x+2y=6xy
1
(1)
2
( 3 −1 ) 79. Let the orthocentre and centroid of a
triangle be A(−3, 5) and B(3, 3)
respectively. If C is the circumcentre of
1 this triangle, then the radius of the circle
(2)
2
( 3 +1 ) having line segment AC as diameter, is :
(1) 10
1 (2) 2 10
(3)
2
( 3− 2 )
5
(3) 3
2
1 3 5
(4)
2
( 2 −1 ) (4)
2
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