ay @ ene, " 55 nee ® # o dow the posemtal energy inthe sable configuration, (oe issovation eneray sven by, We... 44 wbsttting for! ard fern equations (4) and (5), we get the eustion De minors energy as, Substicaing ie vale-ofr rom equation (4), an (0\ad Anse PA The meron energy of wo parses fn he fd of each aber nen by ww) +8 share nb ss a) Show vat the parses form esble compound Far vont (0) Show that in the stable configuration the energy of atracton is times the energy of repulsion, (6) Show thatthe potential enery'af dhe two particles inthe st configuration is Kar) (89) 2:2, Assume the energy af two parcies in the fell of each other is give bythe fancsion U(r) = = (a) +(e) where an are comnans +s the distance betwee the centres of he pach (a) Show hat ifthe pales are pled apr. the msc wil re 22] ssuse ws Wavamnscibcia wale smear tani ee (6) Also show that the minisnum force required ro beak the malecule a agli]Saunone fern Refer equation (23): re @) Referring equation (2): iS) |r = (4.5) Answer (a)) _ (> the aractve energy inthe sable cofigation Sue, ta epcveate. aye vel] ® aa [ % i faa de _[d'w]_ 20 7» -[Se]-3--0 % “ Ae) (©) Fmt be minimum when 147s poste. From eqution (3) & PF 60 TO a eee Now ering cation (I) minim force required trek the mk ‘cule is piven by er -[*] 4Sabsiiiwting the value of r fram equation (4), ene pets rand] Ls) Answer () 23. Astuming sn overlap interstion berweem newest neighbours of the ype qi) = B exp (op), where Mand p are constans calculate the cequiibium spacing rin ccoms-of B and 9. Sokation: Ai the equiibeium spacing, (0H, =0=8 exprdp) ie. Beapt-rdp)=0 P22 Develop « new form of equation forte force Between two atoms OF soecules forthe equation, P(r) = (A/F) ~ (Be, Obtain from this, squation expressions Fr the Following properties ofthe energy cure: (4) Se slope at r= ry: () the spacing 7, For which the force mani. ‘nur ad (c) the vale Of Fe 14 Develop a new form of the equation forthe posemal energy of a pair cof ators or moleciles frm the estion w= ne Determine from this eqation, expression fr the following properties oft ‘energy curve: fa) potential eoengy at r= F (Ua) (b)the spacing athe pai of election. Solution WW(o8,..,* simu av) ma (el. ma nb 7 = (bia) iat ie bela ry (mn) e ‘Thenew form of equations