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Neshat Et Al 2014 MUY BUENO PDF
Neshat Et Al 2014 MUY BUENO PDF
DOI 10.1007/s12665-013-2690-7
ORIGINAL ARTICLE
Received: 14 February 2013 / Accepted: 20 July 2013 / Published online: 2 August 2013
Ó Springer-Verlag Berlin Heidelberg 2013
Abstract Groundwater contamination from intensive modified through the sensitivity analysis. Subsequently, the
fertilizer application affects conservation areas in a plain. rates and weights were computed. The results of the study
The DRASTIC model can be applied in the evaluation of revealed that the modified DRASTIC model performs more
groundwater vulnerability to such pollution. The main efficiently than the traditional method for nonpoint source
purpose of using the DRASTIC model is to map ground- pollution, particularly in agricultural areas. The regression
water susceptibility to pollution in different areas. How- coefficients showed that the relationship between the vul-
ever, this method has been used in various areas without nerability index and the nitrate concentration was 82 %
modification, thereby disregarding the effects of pollution after modification and 44 % before modification. This
types and their characteristics. Thus, this technique must be comparison indicated that the results of the modified
standardized and be approved for applications in aquifers DRASTIC of this region are better than those of the ori-
and particular types of pollution. In this study, the potential ginal method.
for the more accurate assessment of vulnerability to pol-
lution is achieved by correcting the rates of the DRASTIC Keywords Modified DRASTIC GIS
parameters. The new rates were calculated by identifying Groundwater Hydrogeology Sensitivity analysis
the relationships among the parameters with respect to the Kerman plain Vulnerability
nitrate concentration in groundwater. The methodology
was implemented in the Kerman plain in the southeastern
region of Iran. The nitrate concentration in water from Introduction
underground wells was tested and analyzed in 27 different
locations. The measured nitrate concentrations were used Groundwater is an important and prominent resource in
to associate and correlate the pollution in the aquifer to the most countries, particularly for those in arid and semi-arid
DRASTIC index. The Wilcoxon rank-sum nonparametric areas. Water quality has been given more emphasis in
statistical test was applied to determine the relationship groundwater management (Pradhan 2009; Ayazi et al.
between the index and the measured pollution in Kerman 2010; Manap et al. 2012, 2013). Aquifers are usually
plain. Also, the weights of the DRASTIC parameters were unconfined and highly permeable, thereby causing their
high susceptibility to surface contamination (Javadi et al.
2011a, b). The potential groundwater pollution by human
A. Neshat B. Pradhan (&) H. Z. M. Shafri activities at or near the surface has been considered the
Department of Civil Engineering, Faculty of Engineering,
primary basis for the management of this major resource by
University Putra Malaysia, 43400 Serdang, Selangor, Malaysia
e-mail: biswajeet@mailcity.com; biswajeet24@gmail.com; implementing preventive policies.
biswajeet@lycos.com The introduction of potential contaminants to a location
on top of an aquifer at a specified position in an under-
S. Pirasteh
ground system is defined as groundwater vulnerability
Department of Geography and Environmental Management,
Faculty of Environment, University of Waterloo, Waterloo, (National Research Council 1993). Vulnerability assess-
Canada ment must be based on scientific, accurate, and objective
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3120 Environ Earth Sci (2014) 71:3119–3131
evidence. Various methods have been introduced to esti- (2009), Nobre et al. (2007), Pathak and Hiratsuka (2011),
mate groundwater vulnerability with high accuracy (Javadi Remesan and Panda (2008), Saidi et al. (2011), and Hailin
et al. 2011a, b). In most cases, these procedures consist of et al. (2011). Several groups attempted to correlate the vul-
analytical tools intended to correlate groundwater con- nerability index using chemical or contaminant parameters
tamination with land activities. There are three categories (Kalinski et al. 1994; Rupert 1999; McLay et al. 2001).
of assessment processes and procedures: the process-based Certain index methods modified the DRASTIC model by
simulation models, the statistical methods (Harbaugh et al. varying the factors and respective weights or by incorpo-
2000), and the overlay and index methods (Dixon 2004). rating alternative data on human activities, such as land use
Process-based models generally require a large amount and contaminant loading. Al-Hanbali and Kondoh (2008)
of primary and secondary data to apply the mathematical combined a human activity impact index derived from land
models for creating the principal tool. Such methods seem use or cover data using the DRASTIC model. Their work
more complex and difficult to use on a regional scale. demonstrated that human activities affect the groundwater
Statistical methods use data on the known areal contami- quality and increase the risk of pollution in the Dead Sea
nant distribution and describe the contamination potential groundwater basin in Jordan.
for a specified geographical region using the available data The existing literature reports a limited number of studies
in the regions of interest (National Research Council 1993). on groundwater vulnerability from specific contamination
Overlay and index methods emphasize the combination sources based on GIS and index methods. This lack of
of different regional maps by allocating a numerical index. information may be due to the previous definition of
Both methods are easy to apply in geographic information groundwater vulnerability for nonpoint sources. However,
systems (GIS), particularly on a regional scale. Therefore, the existing index methods may still be useful in evaluating
these techniques are the most popular methods used in the risk of groundwater pollution in local and larger scales
vulnerability evaluation. The most widely used among when it is combined with site-specific information, such as
these techniques include GOD (Foster 1987), IRISH (Daly the hydrogeology and contamination history (Alexander
and Drew 1999), AVI (van Stemproot et al. 1993), and et al. 1986). Recent studies have attempted to correlate the
DRASTIC (Aller et al. 1987). DRASTIC is widely applied vulnerability index with chemical or contaminant parame-
in various countries, including the USA (Plymale and ters (Kalinski et al. 1994; Rupert 1999; McLay et al. 2001),
Angle 2002; Fritch et al. 2000; Shukla et al. 2000), China whereas others correlate the nearby land to its vulnerability.
(Yuan et al. 2006; Huan et al. 2012; Yin et al. 2012), However, the rates or weights of the DRASTIC model could
Jordan (Naqa et al. 2006), Morocco (Ettazarini 2006), Iran not be used efficiently in these investigations.
(Javadi et al. 2011a, b), Palestine (Mimi et al. 2012), Nitrate is not naturally found in surface groundwater. This
Tunisia (Saidi et al. 2010, 2011), and Portugal (Pacheco compound is considered a good indicator of contaminant
and Sanches Fernandes 2012). movement from the surface to groundwater, particularly in
Despite its popularity, the DRASTIC method has some land allocated for agricultural use (Javadi et al. 2011a, b).
disadvantages. The DRASTIC model consists of seven Carvalho (2009) conducted pollution risk assessment by
hydrogeologic factors: depth of water, net recharge, aquifer integrating DRASTIC results with nitrate concentrations.
media, soil media, topography (slope), impact of vadose Subsequently, other researchers used nitrate to modify
zone, and hydraulic conductivity of the aquifer. DRASTIC (Panagopoulos et al. 2006; Javadi et al. 2011a, b).
This approach primarily uses the seven parameters to Pacheco and Sanches Fernandes (2012) used nitrates to
compute for the vulnerability index. Each parameter is perform a correspondence analysis. Panagopoulos et al.
allocated specific weights and rating values, as shown in (2006) and Javadi et al. (2011a, b) calibrated the model using
Table 1 (Aller et al. 1987). The DRASTIC model is con- nitrate before a correlation coefficient was obtained to
sidered one of the best index models for vulnerability map- describe the relationship of the vulnerability index and
ping since it was first introduced by Aller et al. (1985, 1987). nitrate concentration. In the current study, the rate of
This technique disregards the effects of regional character- DRASTIC parameters was calibrated for the study area by
istics. Therefore, uniform weights and rating values are used. measuring the nitrate concentration of groundwater. The
Moreover, this method does not use a standard validation test relationship between the vulnerability indicators and the
for the aquifer. Thus, several researchers have continued to parameters was statistically analyzed to calibrate the rates
develop this model using different methods. Some of the using the Wilcoxon rank-sum nonparametric statistical test
notable studies include those by Secunda et al. (1998), (Wilcoxon 1945). In addition, the single-parameter sensi-
Melloul and Collin (1998), Zhou et al. (1999), Thirumalai- tivity analysis was applied to compute the effective weight of
vasan et al. (2003), Dixon (2005), Antonakos and Lambrakis each parameter in the Kerman plain.
(2007), Bojórquez-Tapia et al. (2009), Ckakraborty et al. The main contribution of this research compared with
(2007), Denny et al. (2007), Hamza et al. (2007), Leone et al. previously published literature in Javadi et al. (2011a, b) is
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Environ Earth Sci (2014) 71:3119–3131 3121
Range Rating Range Rating Range Rating Range Rating Range Rating Range Rating Range Rating
the use of two nitrate samples in the same month, which in the study area was 108.3 mm in 2011. The vadose zone
makes more accurate correlation. Apart from that, the area consists of silt and clay, sand and gravel, or gravel and sand
of interest in this study is the Kerman plain which is with silt. The aquifer medium is composed of marlstone
located in the southeastern part of Iran. The Kerman plain and shale, silt and clay, massive sandstone, or sand and
is located in arid and semiarid regions, with groundwater as gravel. The total net recharge of the study area is 186.06
its only water source because of the scarcity of surface million cubic meters per year (MCM per year). The max-
water. Moreover, the Kerman plain experiences heavy imum electrical conductivity (EC) in this study area is
pumping of groundwater, which becomes a serious prob- 3,880 lmoh/cm (micromhos per centimeter), and the
lem because it continuously lowers the water table. The average EC is 2,700 lmoh/cm. The minimum EC is
majority of the study area is covered with agricultural 1,100 lmoh/cm. In addition, the southeastern regions of
lands, and the application of fertilizers is a common the plain have the maximum EC. The geology of Kerman
practice. The DRASTIC model can be used to demonstrate plain contains Cretaceous and Eocene conglomerates (PC),
the application of the proposed method and to provide a intrusive rocks (gp), Eocene and Neogene volcanism, and
basis for its environmental management. Neogene, or younger, sediments.
Study area
Materials and methods
The Kerman plain is an arid and semi-arid area; the
majority of the study area is composed of agricultural land. Data and DRASTIC method
Pistachio is the most economically important product in
this region. The Kerman plain has an area of 978 km2 in The data used to obtain the hydrogeological parameters of
the southeastern part of Iran (Fig. 1). The highest ground the DRASTIC model are listed in Table 2. This method
elevation in the area is 1,980 m, with the lowest point was established by the United States Environmental Pro-
being 1,633 m above sea level. The average annual rainfall tection Agency (USEPA) to classify the pollution potential
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Table 2 Sources of data used for creation of hydro-geological (Sinkevich et al. 2005; Werz and Hötzl 2007). The index
parameter for DRASTIC method consists of seven parameters with different weighting fac-
No data type Sources tors and is calculated by
Kerman
V¼ ðWi Ri Þ; ð1Þ
i¼1
2. Geology map Geological survey of IRAN
3. Soil map Soil and water research Institute of where V is the index value and Wi is the weighted coeffi-
Kerman cient for parameter i, with an associated rating value of Ri.
4. Topography Water organizations of Kerman The following physical parameters are included in the
5. Wells Water organizations of Kerman DRASTIC method:
6. Hydraulic Water organization of Kerman
conductivity D Depth to water table from the soil surface
7. Geological profile Water organization of Kerman
R net recharge
8. Groundwater balance Water organization of Kerman
A Aquifer media
of Kerman plain S Soil media
9. Sample wells Surveyed in my study area and took two T Topography
times samples using GSP technique I Impact of the vadose zone media
C Conductivity (hydraulics) of the aquifer
of aquifers (Aller et al. 1987). Vulnerability to contami-
nation is defined as a dimensionless index function of Each of these hydrogeological factors is given a rating
hydrogeological factors, contamination sources, and from ‘‘1’’ to ‘‘10’’, and the DRASTIC parameters are
anthropogenic effects in any specific area (Plymale and weighted from ‘‘1’’ to ‘‘5’’ according to their relative
Angle 2002). Groundwater vulnerability commonly refers contribution to the potential contamination (Aller et al.
to the potential contamination from nonpoint sources or 1987). The resulting index is a relative measure of vul-
distributed point sources of pollution, such as pesticides or nerability to contamination. Areas with a higher index
nitrates from fertilizers in agricultural practices. Since the value are more vulnerable, as compared with those with a
development of the DRASTIC model (Aller et al. 1987) for lower index. The rates and weights of the original
groundwater vulnerability assessment by USEPA in the DRASTIC model parameters are presented by Aller et al.
late 1980s, this type of indexing method has become (1987). The seven layers of the DRASTIC model are pre-
popular, and widely used in the US, and worldwide sented in Fig. 2.
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Fig. 2 Seven layers of DRASTIC model (a depth of water, b recharge, c aquifer media, d soil, e topography (slope %), f impact of vadose zone,
g hydraulic conductivity)
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DRASTIC data layers clay, sand, sandy loam, and silty loam. Aller et al. (1987)
stated that the maximum rate belonged to gravel, sand, and
The assigned layers for the seven DRASTIC parameters sandy loam. Based on the observed soil media layer, sand
were constructed in raster GIS, based on Table 1. with high permeability was located in the northern and
southern regions of the study area.
Depth of water
Topography (T)
The water table depths were measured from 28 observation
wells. The ArcGIS Geostatistical Analyst extension by Topography in the DRASTIC model displays the slope of
Krigging interpolation was applied to interpolate the points the land surface. The topography was derived from the
and to develop the raster map with a pixel size of 100 m. digital elevation model using a topographic map
Krigging was previously used to obtain significant results (1:25,000). The topography of the area was divided into
in groundwater level analysis (Kumar 2007; Gundogdu and five classes (Aller et al. 1987), which were mostly found in
Guney 2007; Theodossiou 1999). The methodology for areas with slopes ranging from 0 to 2 % and from 2 to 6 %.
groundwater vulnerability measures the water table depth
from the surface as the parameter of interest. This param-
eter represents the distance that a contaminant must travel Impact of the vadose zone (I)
from the surface to reach the groundwater. A deeper water
level indicates a longer time for contamination (Aller et al. The impact of the vadose zone was classified based on the
1987). The depths to the water levels for the Kerman plain drilling logs for each well. The most significant part of the
are classified into three classes: 15–23 m, 23–30 m, and area included gravel and sand with silt and clay (15–30 %)
[30 m, with depth to water rates (Dr) of 3, 2, and 1, in the western region. A small section located in the
respectively. Given that the study area is located in arid and northeastern region of the study area exclusively contains
semi arid regions, two classes less than 30 m were defined gravel and sand.
to represent the area of irrigation return flow.
Hydraulic conductivity (H)
Net recharge (R)
The hydraulic conductivity of the aquifer was computed
The net recharge is considered the result of rainfall infil- according to the following equation: k ¼ Tb , where k is the
tration, irrigation return flow, and absorption wells in the hydraulic conductivity of the aquifer (m/s), T is the trans-
study area. The total net recharge was computed by the missivity (m2/s), and b is the thickness of the aquifer (m).
Kerrman Water Authorities. The hydraulic conductivity distribution map was generated
using pumping test results and a geoelectrical study of the
Aquifer media (A) area. Regions with maximum hydraulic conductivity
exhibited higher chances of distribution contamination.
Classification of this area was based on the drilling logs for Hydraulic conductivity was derived by measurement, and
each well. Two sections of the aquifer rock are basically the GIS-ArcView was applied to interpolate the hydraulic
composed of marl and conglomerate rocks in the southern conductivity and create the raster layer. Hydraulic con-
regions and a small area in the northwestern region. The ductivity could be divided into three classes.
extensive sand deposits with a very low percentage of fine- All required layers were created; each layer was classified
grained material were identified as gravel and sand. Deposits of using the different rating scales The DRASTIC index was then
fine to coarse sand (fine-medium sand) extended across the determined by multiplying the obtained values with the weight
northern and northeastern regions of the study area. Deposits of factor. The obtained index was divided into seven groups
silt and clay were located exclusively in the middle region of (Aller et al. 1987). The vulnerability indices and the corre-
the study area. According to Aller et al. (1987) and Rahman sponding area percentages are presented in Figs. 3 and 4.
(2008), glacial till is a mixture of gravel, sand, silt, and clay.
Nitrate measurements
Soil media (S)
The nitrate concentration was selected as the main
The soil map of the Soil and Water Institute of Kerman was parameter of the initial contamination to calibrate the
used. The soil media layer indicated the recharge rate that DRASTIC model. A total of 27 agricultural wells were
could infiltrate into the pollution. The soil map consists of chosen for the analysis and sampling, with two nitrate
clay loam, gravel, loam, non-shrinking and non-aggregated samples obtained from each well. The first nitrate sample
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Environ Earth Sci (2014) 71:3119–3131 3125
The rates of DRASTIC were initially modified using the Wil- According to Babiker et al. (2005), Saidi et al. (2011), the
coxon rank-sum nonparametric statistical test. Subsequently, applied weights for calculating the vulnerability index
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Table 5 Single-parameter
Parameter DRASTIC weight Theoretical weight (%) Effective weight (%)
sensitivity analysis on modified
DRASTIC Minimum Mean Maximum SD
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Environ Earth Sci (2014) 71:3119–3131 3129
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