SOAL-SOAL TERMODINAMIKA

 U  a
1. If dU = TdS – PdV and dA = -SdT – PdV, derive that    2 for a van der Waals gas
 V  T V
T V2 1  V  1  V 
2. Derive that CP - C V  if    ,    and
 V  T  P V  P  T

 P   V   T 
       -1
 T  V  P  T  V  P
 H   V 
3. If dH = T dS + V dP, derive that   V-T 
 P  T  T  P
 U 
4. Derive that    - V T   V P
 P  T
5. A real gas has a state equation of PV = R T + B P, determine W, U, q, S, dan H for reversibly
isothermal expansion of the gas.
6. One mol of an ideal gas is initially at 400 K and 1 atm. The gas then is expanded adiabatically at
a pressure of 5 atm to achieve an equilibrium. If CV = (18.8 + 0.021 T) J mol-1 K-1, determine U,
H and S for the process.
7. Derive that
 S  
a.   
 V  T 
 U   H 
b.    
 S  V  S  P
 H   G 
c.    
 P S  P  T