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SET−1
Roll No.
General Instructions
(i) This test consists of 30 question.
(ii) Each question is allotted 4 marks for correct response.
(iii) Candidates will be awarded marks as stated above in instruction no. 2 for correct
response of each question. 1 mark will be deducted for indicating incorrect response
of each question. No deduction from the total score will be made if no response is
indicated for an item in the answer sheet.
(iv) There is only one correct response for each question. Filling up more than one
response in any question will be treated as wrong response and marks for wrong
response will be deducted according as per instructions.
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2.
KHC2O4. 3NaHC2O4
v.f = 2×3 = 6
v.f = 2
over all v.f = 6+2 = 8
M M
E
vf
3. Root mean square velocity (urms) = RT
M
Also p M = dRT
Substituting for RT/M in urms expression gives,
p
rms ⇒ rms ∝
d
d
4. Gives, ⇒
Also from first law : dq = CvdT + pdV
For one mole of an ideal gas : pV = RT
⇒ pdV + Vdp = RdT
From (i) pdV = Vdp
Substituting in Eq. (ii) gives
2pdV = RdT
⇒ ⇒
⇒
5. nFEFe
Fe
nEFFe
Fe
nEFFe
Fe
× × EFe
Fe
×
EFe
Fe ×
6. R and R
∞
∴ and ∴
R
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× × ×
⇒ T × ∘C
11.
6
5
4
3
2
n=1
Maximum number of lines produced = = 15 out of these 15 lines,
5 lines belong to ultra violet region and 4 lines are in visible region and rest are in
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infrared region.
13. Graphite has a two-dimensional sheet like structure and each carbon atom makes a use
of sp2 hybridisation. The above layer structure of graphite is less compact than that of
diamond. Further, since the bonding between the layers involving only van der Waal’s
forces is weak, these layers can slide over each other. This gives softness, greasiness
and lubricating character of graphite.
14. Ozone layer acts as a shield and does not allow ultraviolet radiation from sun to reach
earth. It does not prevent infra-read radiation from sun to reach earth, thus option (4)
is wrong statement and so it is the correct answer.
O
O O
15.
N N
N
where, O = given mass of O N = given mass of N O = molecular mass of
O N = molecular mass of N N = molecular mass of N O = number of
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(c) Transition n → 1 to n → 3 For He+ sample
(d) Transition n → 1 to n → ∞ For H-atom sample
17.
∧m
∧∞ b
c
∧m = Molar conductivity at conc. c
∧∞ = Molar conductivity at infinite dilution
c = concentration
b = constant
23.
O O
|| ||
C C
KOH ClCH2COOEt
N-H N-K+
C C
|| ||
O O
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O
|| COOH
C
H2O NH2–CH2–COOH +
N–CH2COOEt.
C COOH
||
O
24.
O O
Br2 (1.0 mol)
CH3COONa + CHBr3 +
Na+OH- CH3
CH3 CH3 CH3
Reaction I: (Unreacted)
(1.0 mol)
(In basic medium complete haloform reaction takes place since the rate of reaction
increases with each α-halogenation)
O O
Br2 (1.0 mol)
CH3COOH
CH3 CH3 CH3
CH3
Reaction II:
(1.0 mol)
(In acidic medium monohalogenation takes place with 1-mol of halogen)
O O
|| || -
OH
25. CH3-C-CH2-CH2-CH2-CH2-C-H
⊝
O
O
|| ⊝ C–CH3
CH3-C-CH-CH2-CH2-CH2-C-H
|| O
O (i) H+
(ii) ⧍
C–CH3
O
26.
O
PBr3 CH2-CH2
CH3-CH-CH3 CH3-CH-Br Mg/ether CH3-CH-MgBr C
OH CH3 CH3
H2 O CH3-CH-CH2CH2OH
CH3-CH-CH2CH2OMgBr
CH3 CH3
6
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27.
(a) Gas dispersed in liquid (p) Foam
(b) Liquid dispersed in gas (q) Aerosol
(c) Liquid dispersed in solid (r) Gel
(d) Liquid dispersed in liquid (s) Emulsion
5 3 1
6 Cl 4 2
29.
H+/Hg2+
CH3-C≡ CH + H2O CH3-C = CH2 CH3-C = CH3
OH O
enol keto
30.
H+ RCH2OH
-H+
O + O
O Acetal
OCH2R
H
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