MIXING TANK

Neraca energy mixer steady:

(1) MT-01 KONDISI OPERASI:

(2) 0 = Q + W +Hin - Hout Q = 0, W = 0

T = 32,0754 oC
(3) 0 = Hin - Hout
P = 1 atm
Hin = Hout
(4)

NERACA MASA MIXER MT-01

Input (Kg) Output (Kg)

Komponen
Aliran 1 Aliran 2 Aliran 3 Aliran 4

p-xylene 21781,77 21781,7679

Asam Asetat 56008,66 56008,6595

HBr 34772,04 34772,0428

m-xylene 15,2472 15,2472

O-xylene 4,3564 4,3564

Toluene 0,2178 0,2178

Water 22403,46 21906,39 44309,8508

21801,59 78412,12 56678,43 156892,1423

Total 156892,1423 156892,1423

 INPUT

Komponen BM Input Input Tleleh Tdidih T Tproses Pproses P uap Fase ∫ Cp dT ∆Hfus ∆Hvap Entalpi (kJ)
(Kg) (mol) ( K) (K) masuk (K) (Atm) (atm) (kJ/mol) (cal/mol) (cal/mol) (Tref = 303 K)
(K)

p-xylene 106.16 21781,77 205.1787 286.2 411.5 303 305 1 Cair 912.4990 187212.9910

Asam Asetat 60.05 56008,66 932.7004 289.7 391.1 303 305 1 Cair 620.4639 0.777 578.677,9890

HBr 80.92 34772,04 429.7088 187 206 303 305 1 Gas 303.4822 575 4210 130.408,9863

m-xylene 106.16 15,2472 1.436247 225.6 412.3 303 305 1 Cair 314.9869 45.2358

O-xylene 106.16 4,3564 0.410362 248 417 303 305 1 Cair 753.1046 30.9013

Toluene 92.13 0,2178 0.002364 178 383.8 303 305 1 0.047 Cair 753,1046 1.7803

18 44309.85 273 373 303 305 1 0.04 Cair 1436 9729 927000

Water 08 2461.658 376,7380

156892,1

TOTAL 423 186.966.877,6113

 OUPUT

Komponen BM Input Input Tleleh Tdidih T Tproses Pproses P uap Fase ∫ Cp dT ∆Hfus ∆Hvap Entalpi (kJ)
(Kg) (mol) ( K) (K) masuk (K) (Atm) (atm) (kJ/mol.) (cal/mol) (cal/mol) (Tref = 303 K)
(K)

106.16 21781,767 205,16 286. 411. 305 305 1 Cair

p-xylene 9 51 2 5 912.4990 187212.9910
Asam 60.05 56008,659 932,65 289. 391. 305 305 1 Cair 0.777
Asetat 5 38 7 1 620.4639 578.677,9890
80.92 34772,042 429,70 187 206 305 305 1 Gas 575 4210
HBr 8 89 303.4822 130.408,9863
106.16 225. 412. 305 305 1 Cair
m-xylene 15,2472 0.1436 6 3 314.9869 45.2358
O-xylene 106.16 4,3564 0.0410 248 417 305 305 1 Cair 753.1046 30.9013
92.13 178 383. 305 305 1 0.05 Cair
Toluene 0,2178 0.0024 8 753,1046 1.7803
18 44309,850 2459,6 273 373 305 305 1 0.045 Cair 1436 9729 927000
Water 8 087 376,7380

156892,14 186.966.877,611
TOTAL 23 3
 PERSAMAAN ENTALPI

NO KOMPONEN PERSAMAAN ENTALPI

1 H1 = n1 ∫ (-3.55.10-4 + 1.2872. 103 T -2.599 T2 + 2.426. 10-3 T3) dT

p-xylene 305
= n1 (-3.55.10-4 T +0.6436.103 T2 – 0.866 T3 + 0.664.10-3 T4 ) 303
2 Asam Asetat
3 HBr
4 m-xylene
5 O-xylene
6 Toluene
7 Water
 LAMPIRAN

DATA Hvap (Perry’s Chemical Engineering Handbook, Perry dkk, 1999)

DATA Cp Hvap (Perry’s Chemical Engineering Handbook, Perry dkk, 1999)

 REAKTOR

Kondisi Operasi Reaktor

(7) Neraca energi steady untuk reaktor:
P = 10.6 atm
R-01 0 = Q + W + Hin + Hout Q = ∆Hreaksi,W = 0
T = 190 C = 463 K (4)
0 = ∆Hreaksi + Hin + Hout
(5)
(6)

(8)
 INPUT
Komponen BM Input Input Tleleh Tdidih T Tproses Pproses P uap Fase ∫ Cp dT ∆Hfus ∆Hvap Entalpi (kJ)
(Kg) (mol) ( K) (K) masuk (K) (Atm) (atm) (kJ/mol.) (cal/mol) (cal/mol (Tref = 303
(K) ) K)

106.1 286.2 411.5 463 463 10.6 Cair

p-xylene 6 21781,7679 10.59 3,2841 912.4990
60.05 289.7 391.1 328 463 10.6 327765,9 Gas 0.777
Oksigen 4790,2503 1865.0041 828 620.4639
80.92 18020.465 187 206 328 463 10.6 2211090 Gas 575 4210
Nitrogen 18020,4654 4 69,6899 303.4822
Asam 106.1 225.6 412.3 463 463 10.6 Cair
Asetat 6 56008,6595 56000 6,4114 314.9869
Tetrahydrate 106.1 248 417 303 463 10.6 Padat
d Co-Asetat 6 1166,8471 1166,8471 - 753.1046
Tetrahydrate 92.13 178 383.8 303 463 10.6 Padat
d Mn-Asetat 1166,8471 1166,8471 - 753,1046
asam 18 34772,042 273 373 463 463 10.6 Gas 1436 9729
Bromida 34772,0428 8 441,1803 376,7380
asam p- 13574,232 463 463 10.6 Cair
toluat 1 0,0764
463 463 10.6 Cair
m-xylene 15,2472 3,3026
463 463 10.6 Cair
O-xylene 4,3564 2,9027
463 463 10.6 Cair
Toluene 0,2178 6,1654
463 463 10.6 Uap
Air 44309,8508 12,3860

182036,552
TOTAL 2
 OUTPUT

Komponen BM Input Input Tleleh Tdidih T Tproses Pproses P uap Fase ∫ Cp dT ∆Hfus ∆Hvap
(Kg) (mol) ( K) (K) masuk (K) (Atm) (atm) (kJ/mol.) (cal/mol) (cal/mol)
(K)

p-xylene 106.16 10.59 286.2 411.5 305 1 Cair 912.4990 187212.9910

oksigen 60.05 1865.0041 289.7 391.1 305 1 Cair 620.4639 0.777 578.677,9890
nitrogen 80.92 18020.4654 187 206 305 1 Gas 303.4822 575 4210 130.408,9863
Asam Asetat 106.16 56000 225.6 412.3 305 1 Cair 314.9869 45.2358
Tetrahydrated 106.16 248 417 305 1 Cair
Co-Asetat 1166,8471 753.1046 30.9013
Tetrahydrated 92.13 178 383.8 305 1 Cair
Mn-Asetat 1166,8471 753,1046 1.7803
asam 18 273 373 305 1 Cair 1436 9729 927000
Bromida 34772,0428 376,7380
asam p-
toluat 13574,2321
186.966.877,6113
m-xylene 15,2472
O-xylene 4,3564
Toluene 0,2178
Air 55400

TOTAL 182036,5522