CL324 Lecture 11 11 8 21

Parallelre actions
A R
A s

Xylene production
methylation of toulene ZSM Zeolite

s
CH OH H2o

H2o
Ei m xylem
L
p xylene
used as
precursor for terephthalicacid
Polyethylene terephthalate PET

o xylene phthalic anhydride

dyes quinizangolventfeens
A R Both are first order reactions
A s

ra I doff doff k.cat Rafa

If CR.tk CI XD
ha xa Kitkat
Need to estimate both k k
Need to measure some other quantity
Ganesh Viswanathan, Department of Chemical Engineering, IIT Bombay
CL324: Autumn 2021-22
 re IIE off Rica

Ms d R2Ca

day Yz
Ro 0 Go 0

SIR der
Ik
k Cs
des

Rack
Cro 0 Go 0 Ra G Cro k Cs Cso

Go Cro O

Cao Cat Cat Cs Cs Go Ca Cr

cone of any one of the twofstpecies

Measuring

man
I me
qhgff.ge
S Kit R2 S
th
Reversibleffchopatet
2rad Calls
Narco Call
Ganesh Viswanathan, Department of Chemical Engineering, IIT Bombay
CL324: Autumn 2021-22
 A
In R first order

ra 1,4 4h Cao
4 K G Ker

Wtf k.SI Xa REAM Xa

Egg

Rifa
Equilibrium constant Kc I
Dae the evil conversion

If Xae is known
Kc K MII Kits is known

Estimate Xae from Kc thermodynamics

ke
Rimff
kill
If
Xa
Kim Mta

en
f Fae Mfa kit

Estimating k Ike fr
reversible first order
ME Ik mus

Ganesh Viswanathan, Department of Chemical Engineering, IIT Bombay

CL324: Autumn 2021-22
 Reactionaries
R G R GoCI Xa
Ta Go
If
en fi ta kit Estimate R

Mr I date off RG R.de G

exptk df

k GoexptRit Ker

exp at off k Go exp kat expl k.tl KexpRAG

day expat Cp K Caoexp Ra Rst

Bk th
Ek
t o G o

exp Rat exp Kent G

ftp.I.ca
Dynamics of different species
when at the maxima

It Imax
CR max

Ganesh Viswanathan, Department of Chemical Engineering, IIT Bombay

CL324: Autumn 2021-22
 M
tax
1 g mean

Ye ki
Gif E

Ganesh Viswanathan, Department of Chemical Engineering, IIT Bombay

CL324: Autumn 2021-22