Rate changein cone

of Reaction time taken If always ve

Average Rate

InstantaneousRate

I units of Rate Md the

conc

am


Measuring the reaction Rate

Concentration

change

colour

change

Titration

Pressure vol change

Conductivitychange

Rotation

of planeofpolarizedlight

Time

Rateof disappearanceof A x Rate

offormation of B

for a hypotheticalreaction a A t bB e et d D

Rate
of Rin
atdft I dig todig dtd

eg NzLg t 3111g 2MHz g

Rateof Ren

Idiot

Rate
of rn phrasehas no
meaning if a balanced equation isn'tgiven

Factors altecting rate

of reaction

1 Concentration Pressure

2 Physical state

3 Temperature

4 Presence absence

of catalyst
5 Nature

of reactants products

6 Radiation

7 pH of medium

8 Dielectric const

ofmedium

Rate Law

For a ryn aA t bB Products

Rate K A IBM order at b

of an

Order be tve ve zero

may integer or fraction

K rateconst velocityconst specific rn rate

units time
of K

conc

zero order molest

Ist order s

2nd order mot's

eg Haig By19 2hr19 R

14,41144ft

Holy Idg 211119 R K Hal IT

20319 30219 R K103710,7

43410 Hy t O R k fat 407

Rate of rx

may depend on species other than reactants

K depends on t

only

Zero Order Reaction

Reverse Haber process

eg 2144,1g Mlg 37219

Photochemical reaction

Haig 421g 2nd g

For Ryn na Products Rate KIAT K

Qual drop in

conc in
Slope k
wi dog

intervalsof

time

tis

to

First Order Reaction

21420519 4140219 0219

NO Ig COlg NOlg 6219

Radioactivedecays

Decomposition
of 420 at hook to 4 and Oz

Decomposition

of 1102

I t

Into Ince Inco Kt

I
y c me
4

slope k

bet slopes k life

t t

equal to drops in equal intervalsoftime

Second Order Reaction

Glock Iz ClycoafI Htt I R K acetone Ht

Hat Iz ZHI R K11271127

A Product ATB Product

it I

Gas phase reactions

21420519 4NO g 0219

to Po O O

Et

Arrhenius Equation

1 Sufficient Energy

An effective collision needs Is 2 Proper orientation

No Collisionfree X Energyfactor x Prob factor

of effective collisions

e Ealrt

tk

FRIMK rg.LI lnA

AE

af

tT
plk.tk

1nA
ftp

slope

Ink

Temp Coefficient

KII

2 3