PHY./INO.

CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 51

This DPP is to be discussed in the week (02.11.2015 to 07.11.2015)

DPP No. # 51 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

ANSWER KEY
DPP No. # 51 (JEE-MAIN)
1. (C) 2. (B) 3. (C) 4. (D) 5. (D) 6. (C) 7. (A)
8. (D) 9. (D) 10. (C) 11. (C) 12. (C) 13. (D) 14. (B)
15. (D) 16. (C) 17. (A) 18. (C) 19. (A) 20. (C

1. Two first order reaction have half-lives in the ratio 8 : 1. Calculate the ratio of time intervals t 1 : t2. The time t1
th th
 1 3
and t2 are the time period for   completion of 1st reaction and   2nd completion rxn repectively..
 4  4
(A) 1 : 0.301 (B) 0.125 : 0.602 (C*) 1 : 0.62 (D) none of these
nks çFke dksfV dh vfHkfØ;kvksa ds fy, v)Z vk;qdky dk vuqikr 8 : 1 gS] rks le;kUrjky ds vuqikr t1 : t2 dh x.kuk dhft,A
th th
 1 3
t1 rFkk t2 le; og le;kUrjky gS] tc Øe'k%   rFkk   vfHkfØ;k iw.kZ gks pqdh gSA
 4 4
(A) 1 : 0.301 (B) 0.125 : 0.602 (C*) 1 : 0.62 (D) buesa ls dksbZ ughaA
( t 1/ 2 )1  1 
Sol. (C) t1 = ln  1 – (1/ 4) 
0.693  

( t1 / 2 ) 2  1 
t2 = ln  1 – 3 / 4 
0.693  

t1 8 ln ( 4 / 3)
t2 = × ln ( 4) = 1 : 0.62.
1

2. The order of a reaction A  product in which half the reagent is reacted is half an hour, three quarters in one
hour and seven - eighth in one and half hours is
1
A  mRikn vfHkfØ;k ds fy;s ftldk vk/kk vfHkdeZd 1/2 ?k.Vs esa fØ;k djrk gS o 3/4 Hkkx 1 ?k.Vs esa] o 7/8 Hkkx 1
2
?k.Vs esa fØ;k djrk gS rks vfHkfØ;k dh dksfV D;k gksxhA
(A) 2 (B*) 1 (C) zero 'kwU; (D) – 1
Sol. A  product
30 min a 60 min a 90 min a
a   
2 4 8
So, Order is 1. ¼blfy, izFke dksfV gS½

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3. For a first order reaction, nA B whose concentration vs time curve is as shown in the figure. If half life for
the reaction is 24 minutes . Find out the value of n.
nA B izFke dksfV dh vfHkfØ;k ds fy, lkanzrk rFkk le; ds e/; oØ fuEu izdkj ls iznf'kZr fd;k x;k gSA ;fn vfHkfØ;k
ds fy, v)Zvk;qdky 24 feuV gS] rks n dk eku Kkr dhft;sA

(A) 1 (B) 2 (C*) 3 (D) 4

Sol. nA B
a
x
a–x t½ = 24 min
n
x
at t = 48 a–x =
n
(1  n) x na
a= ; =x
n 1 n

n2 1 a
 n
24 48 na
a
(1  n)

a(1  n)
4=  n = 3.
a

4. Consider the plots for the types of reaction nA  B + C

d [A ] 1
– [A]
dt [A ]

These plots respectively correspond to the reaction orders :

nA  B + C vfHkfØ;k ds fofHkUu çdkjksa ds fy, fuEu vkjs[kks ij fopkj dhft, %

d [A ] 1
– [A]
dt [A ]

;g vkjs[k Øe'k% fdl dksfV dh vfHkfØ;k ls lEcaf/kr gSA

(A) 0, 2, 1 (B) 0, 1, 2 (C) 1, 1, 2, (D*) 1, 0, 2
Sol. nA  B + C
d[ A ] 1
 [A] (Ist order) [A]t  t (zero order) [ A ]t  t (2nd order)
dt
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5. 'V1' ml of an aqueous urea solution having osmotic pressure as 2.4 atm is mixed with 'V2' ml of another
V1
aqueous urea solution having osmotic pressure as 4.6 atm at same temperature. What will be value of
V2
if resulting solution after mixing has osmotic pressure as 2.95 atm.
leku rki ij ,d tyh; ;wfj;k foy;u] ftldk ijklj.k nkc 2.4 atm gS] ds 'V1' ml vk;ru dks nwljs tyh; ;wfj;k foy;u
V1
ftldk ijklj.k nkc 4.6 atm gS] ds 'V2' ml esa feyk;k tkrk gS rks ifj.kkeh foy;u ds fy, dk eku Kkr dhft,A ;fn
V2
fefJr djus ij ifj.kkeh foy;u dk ijklj.k nkc 2.95 atm gks tkrk gSA
(A) 1 (B) 1.5 (C) 2 (D*) 3
2.4 V1  4.6 V2
Sol. R = V1  V2 = 2.95 atm (assume temperature constant) (ekuk rki fu;r gS)

V1
V2 = 3.

6. Two reactions A  products and B  products have rate constants kA and kB at temperature, T and
activation energies EA and EB respectively. If k A > kB and EA < EB and assuming that ‘A’ , pre-exponential
factor for both the reactions is same, then.
(A) at higher temperatures k B will be greater than kA
(B) at lower temperatures kA and kB will be close to each other in magnitude
(C*) as temperature rises kA and kB will be close to each other in magnitude.
(D) at lower temperature k B > kA
nks vfHkfØ;k;sa A  mRikn rFkk B  mRikn] rkieku T ij osx fu;rkad Øe'k% kA rFkk kB j[krh gSA rFkk budh
lfØ;.k ÅtkZ;sa Øe'k% EA rFkk EB ik;h tkrh gSA ;fn kA > kB rFkk EA < EB gSA ekuk fd ‘A’ nksuksa vfHkfØ;kvksa ds fy,
leku gS] rcµ
(A) mPp rki ij kB, kA dh rqyuk esa vf/kd gksxkA
(B) U;wu rki ij kA rFkk k B ifjek.k esa ijLij utnhd eku j[ksxsA
(C*) rki esa o`f) ds lkFk kA rFkk k B ifjek.k esa ijLij utnhd eku j[ksaxsA
(D) U;wu rki ij kB > kA .
Sol. As temperature increases, KA & KB tends to A.
So, they are equal in magnitude.
rki c<+us ij KA rFkk KB A dh rjQ tkrs gS blfy, ifjek.k esa leku gksrs gSA

7. S1 : The frequency factor has the same unit as the rate constant, k
S2 : A plot n rate vs n C for the nth order reaction gives a straight line with slope –n and intercept k n
S3 : The order of a reaction A  product in which half the reagent is reacted in half an hour, three quarters in
one hour and seven - eighth in one and half hours must be 1(unity).
S4 : The unit of rate constant for a second order reaction will be M–1s–1.( M is representing the molarity of
solution)
S1 : vko`fr xq.kkad nj fu;rkad k ds leku bdkbZ j[krk gSA
S2 : n dksfV dh vfHkfØ;k ds fy, n osx rFkk n C ds e/; oØ vkjsf[kr djus ij <+ky n rFkk vUr% [k.M kn ds lkFk
th

lh/kh js[kk esa izkIr gksrk gSA

S3 : A  mRikn] vfHkfØ;k ds fy;s ftldk vk/kk vfHkdeZd 1/2 ?k.Vs esa fØ;k djrk gS o 3/4 Hkkx 1 ?k.Vs esa] o 7/8 Hkkx
1
1 ?k.Vs esa fØ;k djrk gS] rks vfHkfØ;k dh dksfV 1 gksxhA
2
S4 : f}rh; dksfV dh vfHkfØ;k ds fy, osx fu;rkad dh bZdkbZ M–1s–1 gksxhA (;gk¡ M foy;u dh eksyjrk dks iznf'kZr djrk
gS)
(A*) T F T T (B) T T T T (C) F F T T (D) T F F T

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Sol. S 1 k = Ae –Ea/RT
S 2 rate = kn [C] n  ln rate = ln k n + n lnC
S 3 A  product ¼mRikn½

1 1 1
hr hr hr
2  a 2  a
2  a 
a    Ist order reaction.¼izFke dksfV vfHkfØ;k½
2 4 8

8. Among the following select the correct the statements :

(I) PH 5 do not exist.
(II) p-d bond is present in SO 2.
(III) SeF4 and CH4 have the same shape.

(IV) I3 has a bent shape.
fuEu esa ls lgh dFkuksa dk p;u dhft, %
(I) PH5 ugha ik;k tkrk gSA
(II) SO 2 esa p-d ca/k mifLFkr gSA
(III) SeF4 o CH 4 dh vkd`fr leku gksr h gSA

(IV) I3 dh eqM +h gqb Z vkd`fr ¼lajpuk½ gksrh gSA
(A) II, III (B) I, II (C) I, IV (D*) I, II, IV

Sol.


SeF4 has sp3d hybridisation and see-saw shape I3 has sp 3 hybridisation and bent shape.

Sol.

SeF4 dk ladj.k sp3d o <s+dqyh vkÑfr (see-saw shape) gksrh gSA I3 dk ladj.k sp3 o eqM+h gqb Z vkd`fr (bent
shape) gksr h gS A

9. In the process of extraction of silver,

Identify the complexes [P] and [Q]

flYoj ds fu"d"kZ.k izØe esa]

ladqy [P] o [Q] dks igpkfu;s \

(A) P = [Ag(CN)4]–, Q = [Zn(CN)4]2– (B) P = [Ag(CN)4]–, Q = [Zn(CN)6]4–
(C) P = [Ag(CN)4]3–, Q = [Zn(CN)4]2– (D*) P = [Ag(CN)2]–, Q = [Zn(CN)4]2–
1
Sol. 2Ag + 4CN – + H 2O + O  2[Ag(CN) 2] – + 2OH –
2 2

2[Ag(CN)2]– + Zn  [Zn(CN) 4]2– + 2Ag

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10. If r 0 be the radius of first Bohr's orbit of H-atom, the de-Broglie's wavelength of an electron revolving in
the third Bohr's orbit will be :
;fn H-ijek.kq ds izFke cksg j d{kk dh f=kT;k r0 gS] rc r`rh; cksg j d{kk esa pDdj yxkus okys ,d bysDVªkWu dh
Mh&czksXyh rjaxnS/;Z gksxh %
(A) 2r0 (B) 4r0 (C*) 6r0 (D) r0
nh
Sol. mvr = ...(1)
2
h
p= = mv ...(2)

Placing the value of mv from Eq. (2) into Eq. (1) for 3 rd orbit
3rd d{kk ds fy, lehdj.k (2) ls mv dk eku lehdj.k (1) es a j[kus ij
h 3h
r =
 3 2
2 r3
=
3
2
r 3 = n r 0 = 9r 0
2 .9r0
So blfy, = = 6r 0
3

11. A 5.0 cm 3 solution of H 2O 2 liberates 0.508 g of l2 from an acidified Kl solution. The strength of H 2O2
solution in terms of volume strength at STP is :
5.0 cm 3 H2O2 foy;u] vEyh;d`r KI foy;u ls 0.508 g, l2 eqDr djrk gSA STP ij H 2O 2 foy;u dh lkeF;Z vk;ru
lkeF;Z ds inksa esa gS %
(A) 2.24 V (B) 1.12 V (C*) 4.48 V (D) 8.96 V
Sol. meq H 2O2 = meq l2
0.508  2
N5=  1000 or Normality = 0.8 N
254
Volume strength = 5.6  N
= 5.6  .8
= 4.48 V.
Sol. feyhrqY;kad H2O2 = feyhrqY;kad l2
0.508  2
N5=  1000 ;k ukeZyrk = 0.8 N
254
vk;ru lkeF;Z = 5.6  N
= 5.6  .8
= 4.48 V.

12. For the equilibrium, CuSO 4 . 5H 2O(s) CuSO 4 . 3H 2O(s) + 2H 2O(g), K p = 1.086  10 –4 atm –2 at
25C. The efflorescent nature of CuSO 4 . 5H 2O(s) can be noticed when the vapour pressure of water in
the atmosphere is (in mm Hg) :
25C ij lkE; CuSO4.5H 2O(s) CuSO 4.3H 2O(s) + 2H 2O(g) ds fy, Kp = 1.086  10–4 atm –2 gS A
CuSO 4.5H 2O(s) mRQqYyu izo `fr (efflorescent nature) n'kkZrk gS tc okrkoj.k esa ty dk ok"i nkc (mm Hg es a)
fuEu gS %
(A) 10.92 (B) 7.90 (C*) < 7.90 (D) > 7.90
Sol. Kp = PH22O = 1.086  10 –4 atm 2

PH2O = 1.04  10–2  760 = 7.90 mm Hg

If the vapour pressure of water in air is less than 7.90 mm Hg, water of crystallization is given out.
;fn ok;q esa ty dk ok"i nkc 7.90 mm Hg ls de gksxk rks fØLVyu ty fudysxkA

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13. The reaction of XeF 6 with silica (SiO 2) gives :
(A) XeO3 and SiF4 (B) XeF4 and SiF4
(C) XeOF2 and SiF4 (D*) XeOF4 and SiF4
XeF6 dh flfydk (SiO2) ds lkFk vfHkfØ;k ij iz kIr gksrk gS %
(A) XeO3 rFkk SiF4 (B) XeF4 rFkk SiF4
(C) XeOF 2 rFkk SiF4 (D*) XeOF4 rFkk SiF4

Sol. 2XeF6 + SiO2  2XeOF 4 + SiF 4

14. In FCC lattice A, B, C, D atoms are arranged at corners, face centres, octahedral voids and tetrahedral
voids respectively, then the body diagonal contains :
FCC tkyd esa A, B, C, D ijek.kq Øe'k% dks us ] Qyd dsUnz] v"VQydh; fNnz o prq "Qydh; fNnz esa O;ofLFkr gS
rks dk; fod.kZ ij fuEu fLFkr gksxsa %
(A) 2A, 2D (B*) 2A, C, 2D (C) 2A, 2B, D (D) 2A, 2B, 2C
Sol. Body diagonal contain two atoms at corners (1), one octahedral void (3) and two tetrahedral voids (4).
Sol. dksus ds nks ijek.kq (1), ,d v"VQydh; fNnz (3) o nks prq"Qydh; fNnz (4) dk; fod.kZ ij fLFkr gksxsaA

15. (I) [ Co(EDTA)] – has two optical isomers.

(II) [Co(NH3)4 (NO2)2 ]+ show linkage isomers.
(III) For [ Pt (py)(NH3)(NO2) Cl BrI], theoretically fifteen different geometrical isomers are possible.
(IV) [ Cr(H2O)4Cl2 ] Cl2. 2H2O can show hydrate as well as ionisation isomerism.
Amongs the following correct statements are :
(I) [ Co(EDTA)] – nks izdk'kh; leko;oh j[krk gSA
(II) [Co(NH3)4 (NO2)2 ]+ fyadst leko;oh n'kkZrk gSA
(III) [ Pt (py)(NH3)(NO2) Cl BrI], ds lS)kfUrd :i ls iUnzg T;kferh; leko;oh lEHko gSaA
(IV) [ Cr(H2O)4Cl2 ] Cl2. 2H2O gkbMªsV ds lkFk&lkFk vk;uu leko;ork çnf'kZr djrk gSaA
fuEu esa ls lgh dFku gSa %
(A) II, III (B) III (C) I, III (D*) I, II & III
Sol. (I), (II) and (III) are correct statements.
(IV) It is an example of only hydrate isomerism not ionisation isomerism because ionisation isomerism
occurs owing to exchange of ions between coordination and ionisation spheres.
Sol. (I), (II) rFkk (III) lgh gSaA
(IV) ;g dsoy gkbMsªV leko;ork dk mnkgj.k gS] vk;uu leko;ork dk ugha] D;ksafd vk;uu leko;ork leUo; xksyd
rFkk vk;uu xksyd ds chp vk;uksa ds ifjorZu ls izkIr gksrh gSA
16. The vander W aals' constant 'a' for the gases CH 4, N 2, NH 3 and O 2 are 2.25 , 1.39, 4.17 and 1.3 L 2 atm-
mol–2 respectively. The gas which shows highest critical temperature is :
xSlksa CH4, N2, NH3 o O2 ds fy, ok.MjokWy fu;rkad 'a' Øe'k% 2.25 , 1.39, 4.17 o 1.3 L 2 atm-mol –2 gSA xSl ftlds
fy, vf/kdre Økafrd rki gksxk %
(A) CH4 (B) N 2 (C*) NH3 (D) O2
Sol. The gas which shows higher value of 'a' will have higher value of critical temperature as vander W aals'
8a
constant 'a' is directly proportional to critical temperature i.e., T C = 27 Rb .
Sol. xSl ftlds fy, ok.MjokWy fu;rkad 'a' vf/kd gksxk] mlds fy, Økafrd rki Hkh vf/kd gksxk D;ksafd ok.MjokWy fu;rkad 'a'
8a
Økafrd rki ds lekuqikrh gksrk gSA vFkkZr~ T C = 27 Rb .

17. In the formation of HBr from H2 & Br2, following mechanism is observed.
(1) Br2 2Br Equilibrium step

(2) H2 + Br  HBr + H Slow step

(3) H + Br2  HBr + Br Fast step
Calculate the rate of reaction, if concentration of hydrogen is twice that of bromine and the rate constant is
equal to 1 M–1/2 Sec –1. Concentration of bromine is 1 M.

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 H2 rFkk Br2 ls HBr ds fuekZ.k esa] fuEu fØ;kfof/k izsf{kr dh x;h &
(1) Br2 2Br lkE; in
(2) H2 + Br  HBr + H /khek in
(3) H + Br2  HBr + Br rhoz in
vfHkfØ;k dh nj@osx ifjdfyr dhft,] ;fn H2 dh lkUnzrk czksehu dh rqyuk esa nqxuh gSa rFkk nj fu;rkad
1 M–1/2 Sec–1 ds cjkcj gSA czksehu dh lkUnzrk 1 M gSaA
(A*) 2 M Sec–1 (B) 3 M Sec–1 (C) 4 M Sec–1 (D) 5 M Sec–1
Sol. (1)
Rate = K[H2]1 [Br2]1/2
Rate = 1 [2]1 [1]1/2 = 2 M Sec–1
Sol. (1)
nj = K[H2]1 [Br2]1/2
nj = 1 [2]1 [1]1/2 = 2 M Sec–1

18. Zn Amalgam is prepared by electrolysis of aqueous ZnCl 2 using Hg cathode (9gm). How much current
is to be passed through ZnCl 2 solution for 1000 seconds to prepare a Zn Amalgam with 25% Zn by wt.
(Zn = 65.4)
Hg dS FkksM (9gm) dk mi;ksx djrs gq, tyh; ZnCl2 ds oS|qr vi?kV~u }kjk Zn veyxe rS;kj fd;k tkrk gSA
ZnCl2 foy;u esa 1000 lS d.M ds fy, fdruh fo|qr /kkjk izokfgr dh tk;s ftlls ,slk ftad veyxe cus ftlesa Zn
Hkkj ds vuql kj 25% gksA (Zn = 65.4)
(A) 5.6 amp (B) 7.2 amp (C*) 8.85 amp (D) 11.2 amp
Sol. (3)
Let x gm of Zn deposit on 9 gm of Hg
m Zn  100 x
% of Zn in Amalgam = m  m = x 100 = 25
Zn Hg 9x
 x = 3gm
3x2
Eq. of Zn =
65 .4
n Zn ne – Q it
  
1 2 2f 2f

6 96500
Current i = x = 8.85 amp.
65 .4 1000
Sol. ekuk 9 gm Hg ij Zn ds x gm fu{ksfir gksrs gSaA
m Zn  100 x
veyxe esa Zn dk % = m  m = x 100 = 25
Zn Hg 9x
 x = 3gm
3x2
Zn dk rqY;kad =
65 .4

n Zn ne – Q it
  
1 2 2f 2f

6 96500
/kkjk i = x = 8.85 amp.
65 .4 1000

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19. A certain acid-base indicator is red in acid solution and blue in basic solution. At pH = 5, 75% of the indicator
is present in the solution in its blue form. Calculate the pH at which the indicator shows 90% red form?
(Given 10–4.523 = 3  10–5)
,d fuf'pr vEyµ{kkj lwpd vEyh; foy;u esa yky rFkk {kkjh; foy;u esa uhyk gSaA pH = 5 ij foy;u esa lwpd dk 75%
blds uhys :i esa mifLFkr gksrk gSA ml pH dks Kkr dhft, ftl ij lwpd 90% yky :i n'kkZrk gS \
(fn;k x;k gSA 10–4.523 = 3  10–5)
(A*) 3.56 (B) 5.47 (7) 2.5 (4) 7.4
Sol. (1)

[I n– ]
pH = pK1 + log
[HI n]

75
5 = pK1 + log
25
 pK1 = 4.523
 K1 = 3 × 10–5
10
pH = 4.523 + log = 4.523 – 0.954 = 3.56
90

20. H2 gas diffuses 4 times as rapidly as a mixture of C2H4 and CO2. The molar ratio of C2H4 to CO2 in the mixture
is -
H2 xSl dk folj.k C2H4 vkSj CO2 ds feJ.k ls 4 xquk rsth ls gksrk gSA rks C 2H4 vkSj CO2 ds eksyj feJ.k dk vuqikr gksxk-
(A) 1 : 1 (B) 2 : 1 (C*) 3 : 1 (D) 3 : 2
rH2 Mmix Mmix
Ans. (C) r  or, 4=  Mmix = 32
mix mmix 2

Mmix = XC2H4 + XCO2 .MCO2

32 = (1 – X CO ) MC H + XCO .MCO = 28 + (44 – 27) X CO
2 2 4 2 2 2

X C2H4 3
X CO2 = 1/4
  X CO2 = 1

21. H2 gas diffuses 4 times as rapidly as a mixture of C2H4 and CO2. The molar ratio of C2H4 to CO2 in the mixture
is -
H2 xSl dk folj.k C2H4 vkSj CO2 ds feJ.k ls 4 xquk rsth ls gksrk gSA rks C 2H4 vkSj CO2 ds eksyj feJ.k dk vuqikr gksxk-
(A) 1 : 1 (B) 2 : 1 (C*) 3 : 1 (D) 3 : 2
rH2 Mmix Mmix
Ans. (C)  or, 4=  Mmix = 32
rmix mmix 2

Mmix = XC2H4 + XCO2 .MCO2

32 = (1 – X CO ) MC H + XCO .MCO = 28 + (44 – 27) X CO
2 2 4 2 2 2

X C2H4 3
X CO2 = 1/4
  X CO2 = 1

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