Professional Documents
Culture Documents
02 Industrial Waste Management PDF
02 Industrial Waste Management PDF
Industrial Waste
Management
Protecting
Land
Ground Water
Surface Water
Air
Building
Partnerships
Introduction
vii.
Introduction
viii.
Introduction
The electronic version of the Guide, which can be obtained either on CD-ROM or from EPA’s
Web site <www.epa.gov/epaoswer/non-hw/industd/index.htm>, contains a large collection of
additional resources. These include an audio-visual tutorial for each main topic of the Guide;
the IWEM and IWAIR models developed by EPA for the Guide; other models, including the
HELP (Hydrologic Evaluation of Landfill Performance) Model for calculating infiltration rates;
and a large collection of reference materials to complement the information provided in each of
the main chapters, including chemical fact sheets from the Agency for Toxic Substances and
Disease Registry, links to Web sites, books on pertinent topics, copies of applicable rules and
regulations, and lists of contacts and resources for additional information. The purpose of the
audio-visual tutorials is to familiarize users with the fundamentals of industrial waste manage-
ment and potentially expand the audience to include students and international users.
The IWEM and IWAIR models that come with the electronic version of the Guide are critical
to its purpose. These models assess potential risks associated with constituents in wastes and
make recommendations regarding unit design and control of volatile organic compounds to
help mitigate those risks. To operate, the models must first be downloaded from the Web site or
the CD-ROM to the user’s personal computer.
ix.
Introduction
Furthermore, while the Guide provides many tools for assessing appropriate industrial waste
management, the information provided is not intended for use as a replacement for other exist-
ing EPA programs. For example, Tier 1 ground-water risk criteria can be a useful conservative
screening tool for certain industrial wastes that are to be disposed in new landfills, surface
impoundments, waste piles, or land application units, as intended by the Guide. These
ground-water risk criteria, however, cannot be used as a replacement for sewage sludge stan-
dards, hazardous waste identification exit criteria, hazardous waste treatment standards, MCL
drinking water standards, or toxicity characteristics to identify when a waste is hazardous—all
of which are legally binding and enforceable. In a similar manner, the air quality tool in this
Guide does not and cannot replace Clean Air Act Title V permit conditions that may apply to
industrial waste disposal units. The purpose of this Guide is to help industry, state, tribal, and
environmental representatives by providing a wealth of information that relays and defers to
existing legal requirements.
x.
Part I
Getting Started
Chapter 1
Understanding Risk and Building Partnerships
Contents
Resources ....................................................................................................................................................1 - 20
Appendix ....................................................................................................................................................1 - 22
Tables:
Table 1: Effective Methods for Public Notification ....................................................................................1- 14
Figures:
Figure 1: Multiple Exposure Pathways/Routes............................................................................................1 - 7
Getting Started—Understanding Risk and Building Partnerships
R
esidents located near waste man- A. Introduction to Risk
agement units want to understand Assessment
the management activities taking This Guide provides simple-to-use risk
place in their neighborhoods. They assessment tools that can assist in determining
want to know that waste is being the appropriate waste management practices
managed safely, without danger to public for surface impoundments, landfills, waste
health or the environment. This requires an piles, and land application units. The tools
understanding of the basic principles of risk estimate potential human health impacts from
assessment and the science behind it. a waste management unit by modeling two
Opportunities for dialogue between facilities, possible exposure pathways: releases through
states, tribes, and concerned citizens, includ- volatile air emissions and contaminant migra-
ing a discussion of risk factors, should take tion into ground water. Although using the
place before decisions are made. Remember, tools is simple, it is still essential to under-
successful partnerships are an ongoing activity. stand the basic concepts of risk assessment to
be able to interpret the results and understand
the nature of any uncertainties associated with
I. Understanding the analysis. This section provides a general
overview of the scientific principles underly-
Risk Assessment ing the methods for quantifying cancer and
Environmental risk communication skills
are critical to successful partnerships between This chapter will help address the fol-
companies, state regulators, the public, and lowing questions.
other stakeholders. As more environmental
management decisions are made on the basis • What is risk and how is it assessed?
of risk, it is increasingly important for all inter- • What are the benefits of building
ested parties to understand the science behind partnerships?
risk assessment. Encouraging public participa-
tion in environmental decision-making means • What methods have been successful
ensuring that all interested parties understand in building partnerships?
the basic principles of risk assessment and can • What is involved in preparing a
converse equally on the development of stakeholder meeting?
assumptions that underlie the analysis.
1-1
Getting Started—Understanding Risk and Building Partnerships
noncancer risk. Ultimately, understanding the Noncancer risk encompasses a diverse set of
scientific principles will lead to more effective effects or endpoints, such as weight loss,
use of the provided tools. enzyme changes, reproductive and develop-
mental abnormalities, and respiratory reac-
tions. Noncancer risk is generally assessed by
B. Types of Risk comparing the exposure or average intake of a
Risk is a concept used to describe situa- chemical with a corresponding reference (a
tions or circumstances that pose a hazard to health benchmark), thereby creating a ratio.
people or things they value. People encounter The ratio so generated is referred to as the
a myriad of risks during common everyday hazard quotient (HQ). An HQ that is greater
activities, such as driving a car, investing than 1 indicates that the exposure level is
money, and undergoing certain medical pro- above the protective level of the health bench-
cedures. By definition, risk is comprised of mark, whereas, an HQ less than 1 indicates
two components: the probability that an that the exposure is below the protective level
adverse event will occur and the magnitude established by the health benchmark.
of the consequences of that adverse event. In It is important to understand that exposure
capturing these two components, risk is typi- to a chemical does not necessarily result in an
cally stated in terms of the probability (e.g., adverse health effect. A chemical’s ability to
one chance in one million) of a specific initiate a harmful health effect depends on
harmful “endpoint” (e.g., accident, fatality, the toxicity of the chemical as well as the
cancer). route (e.g., ingestion, inhalation) and dose
In the context of environmental manage- (the amount that a human intakes) of the
ment and this section in the Guide, risk is exposure. Health benchmark values are used
defined as the probability or likelihood that to quantify a chemical’s possible toxicity and
public health might be unacceptably impact- ability to induce a health effect, and are
ed from exposure to chemicals contained in derived from toxicity data. They represent a
waste management units. The risk endpoints “dose-response”1 estimate that relates the like-
resulting from the exposure are typically lihood and severity of adverse health effects
grouped into two major consequence cate- to exposure and dose. The health benchmark
gories: cancer risk and noncancer risk. is used in combination with an individual’s
exposure level to determine if there is a risk.
The cancer risk category captures risks
Because individual chemicals generate differ-
associated with exposure to chemicals that
ent health effects at different doses, bench-
might initiate cancer. To determine a cancer
marks are chemical specific; additionally,
risk, one must calculate the probability of an
since health effects are related to the route of
individual developing any type of cancer dur-
exposure and the timing of the exposure,
ing his or her lifetime from exposure to car-
health benchmarks are specific to the route
cinogenic hazards. Cancer risk is generally
and the duration (acute, subchronic, or
expressed in scientific notation; in this nota-
chronic) of the exposure. The definitions of
tion, the chance of 1 person in 1,000,000 of
acute, subchronic, and chronic exposures
developing cancer would be expressed as 1 x
vary, but acute typically implies an exposure
10-6 or 1E-6.
of less than one day, subchronic generally
The noncancer risk category is essentially a indicates an exposure of a few weeks to a few
catch-all category for the remaining health months, and chronic exposure can span peri-
effects resulting from chemical exposure. ods of several months to several years.
1
Dose-response is the correlative relationship between the dose of a chemical received by a subject and the
degree of response to that exposure.
1-2
Getting Started—Understanding Risk and Building Partnerships
2
Upper-bound is a number that is greater than or equal to any number in a set.
1-3
Getting Started—Understanding Risk and Building Partnerships
guidance for making management decisions by and identifying the extent of exposure for indi-
providing one of the inputs to the decision viduals or populations at risk.
making process. Risk assessment furnishes ben-
Performing a risk assessment is complex and
eficial information for a variety of situations,
requires knowledge in a number of scientific
such as determining the appropriate pollution
disciplines. Experts in several areas, such as
control systems for an industrial site, predicting
toxicology, geochemistry, environmental engi-
the appropriateness of different waste manage-
neering, and meteorology, can be involved in
ment options or alternative waste management
performing a risk assessment. For the purpose
unit configurations, or identifying exposures
of this section, and for brevity, the basic com-
that might require additional attention.
ponents important to consider when assessing
The risk assessment process involves data risk are summarized in three main categories
collection activities, such as identifying and listed below. A more extensive discussion of
characterizing the source of the environmental these components can be found in the refer-
pollutant, determining the transport of the pol- ences listed at the end of this section. The
lutant once it is released into the environment, three main categories are:
determining the pathways of human exposure,
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Getting Started—Understanding Risk and Building Partnerships
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Getting Started—Understanding Risk and Building Partnerships
A probabilistic risk assessment is per- different types of media which are considered
formed by running the equations that exposure pathways: air, soil, ground water,
describe each distribution in a program in surface water, and biota (Figure 1). As a result
conjunction with a Monte Carlo program. of this movement, a chemical can be present
The Monte Carlo program randomly selects a in various environmental media, and human
value from the designated distribution and exposure often results from multiple sources.
mathematically treats it with numbers ran- The relative importance of an exposure path-
domly selected from distributions for other way depends on the concentration of a chemi-
parameters. This process is repeated a num- cal in the relevant medium and the rate of
ber of times (e.g., 10,000 times) to generate a intake by the exposed individual. In a com-
distribution of theoretical values. The person prehensive risk assessment, the risk assessor
assessing risk then uses his or her judgement identifies all possible site-specific pathways
to select the risk value (e.g., 50th or 90th through which a chemical could move and
percentile). reach a receptor. The Guide provides tools to
model the transport and movement of chemi-
The output of the exposure assessment is a
cals through two environmental pathways: air
numerical estimate of exposure and intake of
and ground water.
a chemical by an individual. The intake infor-
mation is then used in concert with chemical- The transport of a chemical in the environ-
specific health benchmarks to quantify risks ment is facilitated by natural forces: wind and
to human health. water are the primary physical processes for
distributing contaminants. For example,
Before gathering these data, it is important
atmospheric transport is frequently caused by
to understand what information is necessary
ambient wind. The direction and speed of the
for conducting an adequate exposure assess-
wind determine where a chemical can be
ment and what type of work might be
found. Similarly, chemicals found in surface
required. Exposures are commonly deter-
water and ground water are carried by water
mined by using mathematical models of
currents or sediments suspended in the water.
chemical fate and transport to determine
chemical movement in the environment in The chemistry of the contaminants and of
conjunction with models of human activity the surrounding environment, often referred
patterns. The information required for per- to as the “system,” also plays a significant role
forming the exposure assessment includes in determining the ultimate distribution of
site-specific data such as soil type, meteoro- pollutants in the various types of media.
logical conditions, ground-water pH, and Physical-chemical processes, including disso-
location of the nearest receptor. Information lution/precipitation, volatilization, photolytic
must be gathered for the two components of and hydrolytic degradation, sorption, and
exposure assessment: exposure complexation, can influence the distribution
pathways/routes and exposure quantifica- of chemicals among the different environ-
tion/estimation. mental media and the transformation from
one chemical form to another3. An important
a. Exposure Pathways/Routes component of creating a conceptual model
for performing a risk assessment is the identi-
An exposure pathway is the course the fication of the relevant processes that occur in
chemical takes from its source to the individ- a system. These complex processes depend
ual or population it reaches. Chemicals cycle on the conditions at the site and specific
in the environment by crossing through the chemical properties.
3
Kolluru, Rao (1996).
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Getting Started—Understanding Risk and Building Partnerships
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1-8
Getting Started—Understanding Risk and Building Partnerships
trations) and the results of the exposure assess- ment unit might be underestimated. The EPA
ment (estimated intake or dose by potentially has developed guidance outlined in the Risk
exposed populations) are integrated to arrive at Assessment Guidance for Superfund, Volume I
quantitative estimates of cancer and noncancer (U.S. EPA, 1989b) to assess the overall poten-
risks. To characterize the potential noncarcino- tial for cancer and noncancer effects posed by
genic effects, comparisons are made between multiple chemicals. The risk assessor, facility
projected intake levels of substances and refer- manager, and other interested parties should
ence dose or reference concentration values. To determine the appropriateness of adding the
characterize potential carcinogenic effects, risk contribution of each chemical for each
probabilities that an individual will develop pathway to calculate a cumulative cancer risk
cancer over a lifetime are estimated from pro- or noncancer risk. The procedures for adding
jected intake levels and the chemical-specific risks differ for carcinogenic and noncarcino-
cancer slope factor value. This procedure is the genic effects.
final calculation step. This step determines who
The cancer-risk equation described in the
is likely to be affected and what the likely
adjacent box estimates the incremental indi-
effects are. Because of all the assumptions
vidual lifetime cancer risk for simultaneous
inherent in calculating a risk, a risk characteri-
exposure to several carcinogens and is based
zation cannot be considered complete unless
on EPA (1989a) guidance. The equation com-
the numerical expressions of risk are accompa-
bines risks by summing the risks to a recep-
nied by explanatory text interpreting and quali-
tor from each of the carcinogenic chemicals.
fying the results. As shown in the text box, the
risk characterization step is different for car-
cinogens and noncarcinogens. Cancer Risk Equation for
Multiple Substances
Calculating Risk RiskT = ⌺Riski
Cancer Risks: where:
Incremental risk of cancer = average RiskT = the total cancer risk,
daily dose (mg/kg-day) * slope factor expressed as a unitless probability.
(mg/kg-day)
⌺Riski = the sum of the risk estimates
Non-Cancer Risks: for all of the chemical risks.
Hazard quotient = exposure or intake
(mg/kg-day) or (mg/m3)/ RfD (mg/kg-
day) or RfC (mg/m3) Assessing cumulative effects from noncar-
cinogens is more difficult and contains a
greater amount of uncertainty than an assess-
Another consideration during the risk-
ment for carcinogens. As discussed earlier,
characterization phase is the cumulative
noncarcinogenic risk covers a diverse set of
effects of multiple exposures. A given popula-
health effects and different chemicals will
tion can be exposed to multiple chemicals
have different effects. To assess the overall
from several exposure routes and sources.
potential for noncarcinogenic effects posed by
Multiple constituents might be managed in a
more than one chemical, EPA developed a
single waste management unit, for example,
hazard index (HI) approach. The approach
and by considering one chemical at a time,
assumes that the magnitude of an adverse
the risks associated with the waste manage-
1-9
Getting Started—Understanding Risk and Building Partnerships
health effect is proportional to the sum of the using conservative, non-site specific
hazard quotients of each of the chemicals assumptions provided by EPA. The
investigated. In keeping with EPA’s Risk values are provided in “look-up
Assessment Guidance, hazard quotients should tables” that serve as a quick and
only be added for chemicals that have the straightforward means for assessing
same critical effect (e.g., both chemicals affect risk. These values are calculated to be
the liver or both initiate respiratory distress). protective over a broad range of con-
As a result, an extensive knowledge of toxi- ditions and situations and are by
cology is needed to sum the hazard quotients design very conservative.
to produce a hazard index. Segregation of Tier 2 Evaluation
hazard indices by effect and mechanism of
• Represents a higher level of complex-
action can be complex, time-consuming, and
ity.
will have some degree of uncertainty associat-
ed with it. This analysis is not simple and • Moderate cost.
should be performed by a toxicologist.
• Provides the ability to input some
site-specific data into the risk assess-
4. Tiers for Assessing Risk ment and thus provides a more accu-
As part of the Guide, EPA has used a 3- rate representation of site risk.
tiered approach for assessing risk associated • Uses relatively simplistic fate and
with air and water releases from waste man- transport models.
agement units. Under this approach, an Tier 3 Evaluation
acceptable level of protection is provided
across all tiers, but with each progressive tier • Provides a sophisticated risk assess-
the level of uncertainty in the risk analysis is ment.
reduced. Reducing the level of uncertainty in • Higher cost.
the risk analysis might reduce the level of
• Provides the maximum use of site-
control required by a waste management unit
specific data and thus provides the
(if appropriate for the site), while maintaining
most accurate representation of site
an acceptable level of protection. The facility
risk.
performing the risk assessment accepts the
higher costs associated with a more complex • Uses more complex fate-and-trans-
risk assessment in return for greater certainty port models and analyses.
and potentially reduced construction and
operating costs.
D. Results
The advantages and relative costs of each
tier are outlined below. The results of a risk assessment provide a
basis for making decisions but are only one
Tier 1 Evaluation element of input into the process of designing
• Allows for a rapid but conservative a waste management unit. The risk assess-
assessment. ment does not constitute the only basis for
• Lower cost. management action. Other factors are also
important, such as technical feasibility of
• Requires minimal site data. options, public values, and economics.
• Contaminant fate-and-transport and Understanding and interpreting the results
exposure assumptions are developed for the purpose of making decisions also
requires a thorough knowledge of the
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Getting Started—Understanding Risk and Building Partnerships
assumptions that were applied during the operators might wish to include TRI data in
risk assessment. Ample documentation the facility’s information repository. TRI data,
should be assembled to describe the scenarios however, are merely raw data. When estimat-
that were evaluated for the risk assessment ing risk, other considerations need to be
and any uncertainty associated with the esti- examined and understood too, such as the
mate. Information that should be considered nature and characteristics of the specific facil-
for inclusion in the risk assessment documen- ity and surrounding community.
tation include: a description of the contami-
In 1999, EPA promulgated a final rule that
nants that were evaluated; a description of
established alternate thresholds for several
the risks that are present (i.e., cancer, non-
persistent, bioaccumulative, and toxic (PBT)
cancer); the level of confidence in the infor-
chemicals (see 64 FR 58665; October 29,
mation used in the assessment; the major
1999). In this rule, EPA has added seven
factors driving the site risks; and the charac-
chemicals to the EPCRA Section 313 list of
teristics of the exposed population. The
TRI chemicals and lowered the reporting
results of a risk assessment are essentially
thresholds for another 18 PBT chemicals and
meaningless without the information on how
chemical categories. For these 18 chemicals,
they were generated.
the alternate thresholds are significantly lower
than the standard reporting thresholds of
25,000 pounds manufactured or processed,
II. Information on and 10,000 pounds otherwise used.
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Getting Started—Understanding Risk and Building Partnerships
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Getting Started—Understanding Risk and Building Partnerships
ronmental organizations, and any individuals person who is available within the facility to
in the community who have expressed inter- answer questions.
est in the facility’s operations.
What is involved in preparing a
Using the information gathered during the
interviews, facility representatives can devel- meeting with industry, community,
op a list of the community’s concerns regard- and state representatives?
ing the facility’s waste management activities.
They can then begin to engage the communi- Meetings can be an effective means of giv-
ty in discussions about how to address those ing and receiving comments and addressing
concerns. These discussions can form the concerns. To publicize a meeting, the date,
basis of a partnership plan. time, and location of the meeting should be
placed in a local newspaper and/or advertised
on the radio. To help ensure a successful dia-
B. Inform the State and logue, meetings should be at times conve-
Public About New nient for members of the community, such as
early in the evenings during the week, or on
Facilities or Significant weekends. An interpreter might need to be
Changes in Facility obtained if the local community includes resi-
Operating Plans dents whose primary language is not English.
A facility’s decision to change its opera- Prior to a meeting, the facility representa-
tions provides a valuable opportunity for tive should develop a waste management plan
involvement. Notifying the state and public or come to the meeting prepared to describe
of new units and proposed changes at exist- how the industrial waste from the facility will
ing facilities gives these groups the opportu- be managed. A waste management plan pro-
nity to identify applicable state requirements vides a starting point for public comment and
and comment on matters that apply to them. input. Keep data presentations simple and
provide information relevant to the audience.
What are examples of effective Public speakers should be able to respond to
methods for notifying the public? both general and technical questions. Also,
the facility representative should review and
Table 1 presents examples of effective
be familiar with the concerns of groups or cit-
methods for public notification and associat-
izens who have
ed advantages and disadvantages. The
previously
method used at a particular facility, and
expressed an
within a particular community, will depend
interest in the
on the type of information or issues that
facility’s opera-
need to be communicated and addressed.
tions. In addi-
Public notices usually provide the name and
tion, it is
address of the facility representative and a
important to
brief description of the change being consid-
anticipate ques-
ered. After a public notice is issued, a facility
tions and plan
can develop informative fact sheets to
how best to
explain proposed changes in more detail.
respond to these
Fact sheets and public notices can include
questions at a
the name and telephone number of a contact
meeting.
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Getting Started—Understanding Risk and Building Partnerships
Table 1
Effective Methods for Public Notification
Methods Features Advantages Disadvantages
Briefings Personal visit or phone call to Provides background information. Requires time.
key officials or group leaders to Determines reactions before an issue
announce a decision, provide “goes public.” Alerts key people to
background information, or issues that might affect them.
answer questions.
Mailing of key Mailing technical studies or Provides full and detailed information Costs money to print and
technical reports or environmental reports to other to people who are most interested. mail. Some people might not
environmental agencies, leaders of organized Often increases the credibility of read the reports.
documents groups, or other interested parties. studies because they are fully visible.
News conferences Brief presentation to reporters, Stimulates media interest in a story. Reporters will only come if
followed by a question-and- Direct quotations often appear in the announcement or presen-
answer period, often television and radio. Might draw tation is newsworthy. Cannot
accompanied by handouts of attention to an announcement or control how the story is pre-
presenter’s comments. generate interest in public meetings. sented, although some direct
quotations are likely.
Newsletters Brief description of what is going Provides more information than can Requires staff time. Costs
on, usually issued at key intervals be presented through the media to money to prepare, print, and
for all people who have shown those who are most interested. Often mail. Stories must be objec-
interest. used to provide information prior to tive and credible, or people
public meetings or key decision points. will react to the newsletters
Helps to maintain visibility during as if they were propaganda.
extended technical studies.
Newspaper inserts Much like a newsletter, but Reaches the entire community with Requires staff time to prepare
distributed as an insert in a important information. Is one of the the insert, and distribution
newspaper. few mechanisms for reaching everyone costs money. Must be pre-
in the community through which you pared to newspaper’s layout
can tell the story your way. specifications.
Paid advertisements Advertising space purchased in Effective for announcing meetings or Advertising space can be
newspapers or on the radio or key decisions or as background costly. Radio and television
television. material for future media stories. can entail expensive produc-
tion costs to prepare the ad.
News releases A short announcement or news Might stimulate interest from the Might be ignored or not
story issued to the media to get media. Useful for announcing read. Cannot control how
interest in media coverage of the meetings or major decisions or as the information is used.
story. background material for future media
stories.
Presentations to civic Deliver presentations, enhanced Stimulates communication with key Few disadvantages, except
and technical groups with slides or overheads, to key community groups. Can also provide some groups can be hostile.
community groups. in-depth responses.
Press kits A packet of information Stimulates media interest in the story. Few disadvantages, except
distributed to reporters. Provides background information that cannot control how the
reporters can use for future stories. information is used and
might not be read.
Advisory groups and A group of representatives of key Promotes communication between Potential for controversy
task forces interested parties is established. key constituencies. Anticipates public exists if “advisory” recom-
Possibly a policy, technical, or reaction to publications or decisions. mendations are not followed.
citizen advisory group. Provides a forum for reaching Requires substantial commit-
consensus. ment of staff time to provide
support to committees.
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Getting Started—Understanding Risk and Building Partnerships
Table 1
Effective Methods for Public Notification (cont.)
Methods Features Advantages Disadvantages
Focus groups Small discussion groups Provides in-depth reaction to ideas or Gets reactions, but no
established to give “typical” decisions. Good for predicting knowledge of how many
reactions of the public. emotional reactions people share those reactions.
Conducted by a professional Might be perceived as an
facilitator. Several sessions can be effort to manipulate the
conducted with different groups. public.
Telephone line Widely advertised phone number Gives people a sense that they know Is only as effective as the
that handles questions or provides whom to call. Provides a one-step person answering the tele-
centralized source of information. service of information. Can handle phone. Can be expensive.
two-way communication.
Meetings Less formal meetings for people Highly legitimate forum for the public Unless a small-group discus-
to present positions, ask to be heard on issues. Can be sion format is used, it permits
questions, and so forth. structured to permit small group only limited dialogue. Can
interaction— anyone can speak. get exaggerated positions or
grandstanding. Requires staff
time to prepare for meetings.
U.S. EPA 1990. Sites for Our Solid Waste: A Guidebook for Effective Public Involvement.
State representatives also should antici- • What are the construction plans for
pate and be prepared to answer questions any proposed containment facilities?
raised during the meeting. State representa-
• What are the intended methods for
tives should be prepared to answer ques-
monitoring and detecting emissions
tions on specific regulatory or compliance
or potential releases?
issues, as well as to address how the facility
has been working in cooperation with the • What are the plans to address acci-
state agency. The following are some ques- dental releases of chemicals or wastes
tions that are often asked at meetings. at the site?
• What are the risks to me associated • What are the plans for financial
with the operations? assurance, closure, and post-closure
care?
• Who should I contact at the facility if
I have a question or concern? • What are the applicable state regula-
tions?
• How will having the facility nearby
benefit the area? • How long will it take to issue the
permit?
• Will there be any noticeable day-to-
day effects on the community? • How will the permit be issued?
• Which processes generate industrial • Who should I contact at the state
waste, and what types of waste are agency if I have questions or con-
generated? cerns about the facility?
• How will the waste streams be treat- At the meeting, the facility representative
ed or managed? should invite public and state comments on
the proposed change(s), and tell community
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Getting Started—Understanding Risk and Building Partnerships
members where, and to whom, they should one-to-one. Similarly, workshops and briefin-
send written comments. A facility can choose gs enable community members, state officials,
to respond to comments in several ways. For and facility representatives to interact, ask
example, telephone calls, additional fact questions, and learn about the activities at the
sheets, or additional meetings can all be used facility. Web sites can also serve as a useful
to address comments. Responding promptly tool for facility, state, and community repre-
to residents’ comments and concerns demon- sentatives to share information and ask ques-
strates an honest attempt to address them. tions.
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Getting Started—Understanding Risk and Building Partnerships
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Getting Started—Understanding Risk and Building Partnerships
Resources
American Chemistry Council. Revised 2001. Environmental Justice and Your Community: A Plant
Manager’s Introduction.
Council in Health and Environmental Science, ENVIRON Corporation. 1986. Elements of Toxicology
and Chemical Risk Assessment.
Executive Order 12898. 1994. Federal Actions to Address Environmental Justice in Minority
Populations and Low-income Populations. February.
Holland, C.D., and R.S. Sielken, Jr. 1993. Quantitative Cancer Modeling and Risk Assessment.
Kolluru, Rao, Steven Bartell, et al. 1996. Risk Assessment and Management Handbook: For
Environmental, Health, and Safety Professionals.
Louisiana Department of Environmental Quality. 1994. Final Report to the Louisiana Legislature on
Environmental Justice.
Lu, Frank C. 1996. Basic Toxicology: Fundamentals, Target Organs, and Risk Assessment.
National Research Council. 1983. Risk Assessment in the Federal Government: Managing the Process.
Public Participation and Accountability Subcommittee of the National Environmental Justice Advisory
Council (A Federal Advisory Committee to the U.S. EPA). 1996. The Model Plan for Public
Participation. November.
Texas Natural Resource Conservation Commission. 1993. Texas Environmental Equity and Justice Task
Force Report: Recommendations to the Texas Natural Resource Conservation Commission.
1-20
Getting Started—Understanding Risk and Building Partnerships
Resources (cont.)
U.S. EPA. 1996b. 1994 Toxics Release Inventory: Public Data Release, Executive Summary. EPA745-S-
96-001.
U.S. EPA. 1995a. Decision-maker’s Guide to Solid Waste Management, Second Edition. EPA530-R-95-
023.
U.S. EPA. 1992. Environmental Equity: Reducing Risk for all Communities. EPA230-R-92-008A.
U.S. EPA. 1990. Sites for our Solid Waste: A Guidebook for Effective Public Involvement. EPA530-
SW-90-019.
U.S. EPA. 1989a. Chemical Releases and Chemical Risks: A Citizen’s Guide to Risk Screening. EPA560-
2-89-003.
U.S. Government Accounting Office. 1995. Hazardous and Nonhazardous Waste: Demographics of
People Living Near Waste Facilities. GAO/RCED-95-84.
Western Center for Environmental Decision-Making. 1996. Public Involvement in Comparative Risk
Projects: Principles and Best Practices: A Source Book for Project Managers.
1-21
Getting Started—Understanding Risk and Building Partnerships
Appendix
1-22
Getting Started—Understanding Risk and Building Partnerships
1-23
Part I
Getting Started
Chapter 2
Characterizing Waste
Contents
Resources ....................................................................................................................................................2 - 16
Appendix ....................................................................................................................................................2 - 18
Getting Started—Characterizing Waste
Characterizing Waste
This chapter will help you:
• Understand the industrial processes that generate a waste.
• Determine the waste’s physical and chemical properties.
• Estimate constituent leaching to facilitate ground-water risk analysis.
• Quantify total constituent concentrations to facilitate air emissions
analysis.
ing, or some combination of the two to esti-
U
nderstanding the physical and
mate waste generation rates and waste con-
chemical properties of a waste
stituent concentrations. To the extent that the
using sampling and analysis
waste is not highly variable, the use of process
techniques is the cornerstone
knowledge can be a sound approach to waste
upon which subsequent steps in
characterization and can prove more reason-
the Guide are built. It is necessary for gauging
able and cost effective than frequent sampling
what risks a waste might pose to surface water,
of the waste. It is important to note, however,
ground water, and air and drives waste man-
that owners or operators using process knowl-
agement unit design and operating decisions.
edge to characterize a waste in lieu of testing
Knowing the composition of the waste is also
are still responsible for the accuracy of their
necessary when determining the constituents
determinations. No matter what approach is
for which to test. And, as discussed in Chapter
used in characterizing a waste, the goal is to
3–Integrating Pollution Prevention, knowledge
maximize the available knowledge that is nec-
of the physical and chemical properties of the
essary to make the important decisions
waste is crucial in identifying pollution pre-
described in later chapters of the Guide. Also,
vention opportunities.
as changes are made to the industrial process-
In many instances, you can use knowledge es or waste management practices, it might be
of waste generation processes, analytical test- necessary to recharacterize a waste in order to
accurately make waste management decisions
and evaluate risk.
This chapter will help you address the In considering the use of process knowl-
following questions: edge or analytical testing, it is important to
• How can process knowledge be used note that the ground water and air emissions
to characterize a waste? models that accompany the Guide use con-
stituent concentrations to estimate risk. Input
• Which constituent concentrations
requires specific concentrations which cannot
should be quantified?
be precisely estimated solely by knowledge of
• Which type of leachate test should be the processes that generate the waste. Further,
used? when wastes are placed in a waste manage-
ment unit, such as a landfill or surface
2-1
Getting Started—Characterizing Waste
impoundment, they are subjected to various waste characteristics such as the physical
physical, chemical, and biological processes state of the waste, the volume of waste pro-
that can result in the creation of new com- duced, and the general composition of the
pounds in the waste, changes in the mass and waste. In addition, many industries have
volume of the waste, and the creation of dif- thoroughly tested and characterized their
ferent phases within the waste and within the wastes over time, therefore it might be benefi-
landfill or impoundment. In order to accu- cial to contact your trade association to deter-
rately predict the concentration of the conta- mine if waste characterizations have already
minants in the leachate, these changes must been performed and are available for process-
be accounted for. es similar to yours. Additional resources can
assist in waste characterization by providing
Accurate waste management unit con-
information on waste constituents and poten-
stituent characterization is also necessary for
tial concentrations. Some examples include:
input to the modeling tools provided in the
Guide. Because model input requires specific • Chemical engineering designs or
data, model output will be based on the accu- plans for the process, showing
racy of the data input. Process knowledge process input chemicals, expected
alone (unless based on previous testing) might primary and secondary chemical
not be sufficiently accurate to yield reliable reactions, and products.
results. Leachate testing (discussed later in
• Material Safety Data Sheets (MSDSs)
this chapter), for example, will likely give you
for materials involved. (Note that not
a more precise assessment of waste con-
all MSDSs contain information on all
stituent concentrations than process knowl-
constituents found in a product.)
edge. Also note that whether you are using
process knowledge, testing, or a combination • Manufacturer’s literature.
of both, sources of model input data must be • Previous waste analyses.
well documented so that an individual evalu-
ating the modeling results understands the • Literature on similar processes.
background supporting the assessment. • Preliminary testing results, if available.
A material balance exercise using process
knowledge can be useful in understanding
I. Waste where wastes are generated within a process
Characterization and in estimating concentrations of waste con-
stituents particularly where analytical test data
Through Process
Knowledge
A waste characterization begins with an
understanding of the industrial processes that
generate a waste. You must obtain enough
information about the process to enable
proper characterization of the waste, for
example, by reviewing process flow diagrams
or plans and determining all inputs and out-
puts. You should also be familiar with other
2-2
Getting Started—Characterizing Waste
2-3
Getting Started—Characterizing Waste
a sampling effort and how they will be per- itself. Reasons for obtaining samples from an
formed. This plan should be carefully thought existing unit include, characterizing the waste
out, well in advance of sampling. The more in the unit to determine if the new waste
detailed the sampling plan, the less opportu- being added is compatible, checking to see if
nity for error or misunderstanding during the composition of the waste is changing over
sampling, analysis, and data interpretation. time due to various chemical and biological
breakdown processes, or characterizing the
To ensure that the sampling plan is
waste in the unit or the leachate from the
designed properly, a wide range of personnel
unit to give an indication of expected concen-
should be consulted. It is important that the
trations in leachate from a new unit.
following individuals are involved in the
development of the sampling plan to ensure The sampling plan must be correctly
that the results of the sampling effort are pre- defined and organized in order to get an
cise and accurate enough to properly charac- accurate estimation of the characteristics of
terize the waste: the waste. Both an appropriate sample size
and proper sampling techniques are neces-
• An engineer who understands the
sary. If the sampling process is carried out
manufacturing processes.
correctly, the sample will be representative
• An experienced member of the sam- and the estimates it generates will be useful
pling team. for making decisions concerning proper man-
• The end user of the data. agement of the waste and for assessing risk.
2-5
Getting Started—Characterizing Waste
3
These and other EPA publications can be found at the National Environmental Publications Internet
site (NEPIS) at <www.epa.gov/ncepihom/nepishom/>.
2-6
Getting Started—Characterizing Waste
2-7
Getting Started—Characterizing Waste
or points in all batches of waste from which a If sampling is restricted, the sampling strat-
sample could be collected) are identified, and egy should, at a minimum, take sufficient
a suitable number of samples is randomly samples to address the potential vertical varia-
selected from the population. tions in the waste in order to be considered
representative. This is because contained
The appropriate number of samples to
wastes tend to display vertical, rather than
employ in a waste characterization is at least
horizontal, non-random heterogeneity due to
the minimum number of samples required to
settling or the layering of solids and denser
generate a precise estimate of the true mean
liquid phases. Also, care should be taken
concentration of a chemical contaminant in a
when performing representative sampling of a
waste. A number of mathematical formulas
landfill, waste pile, or surface impoundment
exist for determining the appropriate number
to minimize any potential to create hazardous
of samples depending on the statistical preci-
conditions. (It is possible that the improper
sion required. Further information on sam-
use of intrusive sampling techniques, such as
pling designs and methods for calculating
the use of augers, could accelerate leaching by
required sample sizes and optimal distribu-
creating pathways or tunnels that can acceler-
tion of samples can be found in Gilbert
ate leachate movement to ground water.)
(1987), Winer (1971), and Cochran (1977)
and Chapter 9 of EPA SW-846. To facilitate characterization efforts, consult
with state and local regulatory agencies and a
The type of sampling plan developed will
qualified professional to select a sampling plan
vary depending on the sampling location.
and determine the appropriate number of sam-
Solid wastes contained in a landfill or waste
ples, before beginning sampling efforts. You
pile can be best sampled using a three-
should also consider conducting a detailed
dimensional random sampling strategy. This
waste-stream specific characterization so that
involves establishing an imaginary three-
the information can be used to conduct waste
dimensional grid or sampling points in the
reduction and waste minimization activities.
waste and then using random-number tables
or random-number generators to select points Additional information concerning sam-
for sampling. Hollow-stem augers combined pling plans, strategies, methods, equipment,
with split-spoon samplers are frequently and sampling quality assurance and quality
appropriate for sampling landfills. control is available in Chapters 9 and 10 of the
SW-846 test methods document. Electronic
If the distribution of waste components is
versions of these chapters have been included
known or assumed for liquid or semi-solid
on the CD-ROM version of the Guide.
wastes in surface impoundments, then a two-
dimensional simple random sampling strategy
might be appropriate. In this strategy, the top 2. Representative Waste Analysis
surface of the waste is divided into an imagi- After a representative sample has been col-
nary grid and grid sections are selected using lected, it must be properly preserved to main-
random-number tables or random-number tain the physical and chemical properties that
generators. Each selected grid point is then it possessed at the time of collection. Sample
sampled in a vertical manner along the entire types, sample containers, container prepara-
length from top to bottom using a sampling tion, and sample preservation methods are
device such as a weighted bottle, a drum critical for maintaining the integrity of the
thief, or Coliwasa. sample and obtaining accurate results.
Preservation and holding times are also
2-8
Getting Started—Characterizing Waste
important factors to consider and will vary ommendations or requirements of your state
depending on the type of constituents being and local regulatory agencies.
measured (e.g., VOCs, heavy metals, hydro-
When selecting the most appropriate ana-
carbons) and the waste matrix (e.g., solid,
lytical tests, consider at a minimum the phys-
liquid, semi-solid).
ical state of the sample, the constituents to be
The analytical chemist then develops an analyzed, detection limits, and the specified
analytical plan which is appropriate for the holding times of the analytical methods.4 It
sample to be analyzed, the constituents to be might not be cost-effective or useful to con-
analyzed, and the end use of the information duct a test with detection limits at or greater
required. The laboratory should have standard than the constituent concentrations in a
operating procedures available for review for waste. Process knowledge can help you pre-
the various types of analyses to be performed dict whether the concentrations of certain
and for all associated methods needed to com- constituents are likely to fall below the detec-
plete each analysis, such as instrument main- tion limits for anticipated methods.
tenance procedures, sample handling
After assessing the state of the waste, assess
procedures, and sample documentation proce-
the environment of the waste management
dures. In addition, the laboratory should have
unit in which the waste will be placed. For
a laboratory quality assurance/quality control
example, an acidic environment might
statement available for review which includes
require a different test than a non-acidic envi-
all key personnel qualifications.
ronment in order to best reflect the condi-
The SW-846 document contains informa- tions under which the waste will actually
tion on analytical plans and methods. leach. If the waste management unit is a
Another useful source of information regard- monofill, then the characteristics of the waste
ing the selection of analytical methods and will determine most of the unit’s conditions.
quality assurance/quality control procedures Conversely, if many different wastes are being
for various compounds is the Office of Solid co-disposed, then the conditions created by
Waste Methods Team home page at
<www.epa.gov/sw-846/index.htm>.
Which leaching test is
appropriate?
B. Leachate Test Selection Selecting an appropriate leachate test
Leaching tests are used to estimate poten- can be summarized in the following four
tial concentration or amount of waste con- steps:
stituents that can leach from a waste to
ground water. Typical leaching tests use a 1. Assess the physical state of the waste
specified leaching fluid mixed with the solid using process knowledge.
portion of a waste for a specified time. Solids 2. Assess the environment in which the
are then separated from the leaching solution waste will be placed.
and the solution is tested for waste con-
3. Consult with your state and/or local
stituent concentrations. The type of leaching
regulatory agency.
test performed can vary depending on the
chemical, biological, and physical characteris- 4. Select an appropriate leachate test
tics of the waste; the environment in which based on the above information.
the waste will be placed; as well as the rec-
4
There are several general categories of phases in which samples can be categorized: solids, aqueous,
sludges, multiphase samples, ground water, and oil and organic liquid. You should select a test that is
designed for the specific sample type. 2-9
Getting Started—Characterizing Waste
the co-disposed wastes must be considered, sult with state and local regulatory agencies
including the constituents that can be leached and/or a laboratory that is familiar with
by the subject waste. leachate testing methods to identify the most
appropriate test and test method procedures
A qualified laboratory should always be used
for your waste and sample type.
when conducting analytical testing. The labora-
tory can be in-house or independent. When
using independent laboratories, ensure that 1. Toxicity Characteristic Leaching
they are qualified and competent to perform Procedure (TCLP)
the required tests. Some laboratories might be
The TCLP 6 is the test method used to deter-
proficient in one test but not another. You
mine whether a waste is hazardous due to its
should consult with the laboratory before final-
characteristics as defined in the Resource
izing your test selection to make certain that
Conservation and Recovery Act (RCRA), 40
the test can be performed. When using analyti-
CFR Part 261. The TCLP estimates the leacha-
cal tests that are not frequently performed,
bility of certain toxicity characteristic hazardous
additional quality assurance and quality control
constituents from solid waste under a defined
practices might need to be implemented to
set of laboratory conditions. It evaluates the
ensure that the tests are conducted correctly
leaching of metals, volatile and semi-volatile
and that the results are accurate.
organic compounds, and pesticides from
A brief summary of the TCLP and three wastes. The TCLP was developed to simulate
other commonly used leachate tests is provid- the leaching of constituents into ground water
ed below (procedures for the EPA test meth- under conditions found in municipal solid
ods are included in SW-846 and for the waste (MSW) landfills. The TCLP does not sim-
ASTM method in the Annual Book of ASTM ulate the release of contaminants to non-ground
Standards). These summaries are provided as water pathways. The TCLP is most commonly
background and are not meant to imply that used by EPA, state, and local agencies to classify
these are the only tests that can be used to waste. It is also used to determine compliance
accurately predict leachate potential. Other with some land disposal restrictions (LDRs) for
leachate tests have been developed and might hazardous wastes. The TCLP can be found as
be suitable for testing your waste. The table EPA Method 1311 in SW-846.7 A copy of
in the appendix at the end of this chapter Method 1311 has been included on the CD-
provides a summary of over 20 leachate tests ROM version of the Guide.
that have been designed to estimate the
For liquid wastes, (i.e., those containing
potential for contaminant release, including
less than 0.5 percent dry solid material) the
several developed by ASTM.5 You should con-
waste after filtration through a glass fiber fil-
5
EPA has only reviewed and evaluated those test methods found in SW-846. The EPA has not reviewed
or evaluated the other test methods and cannot recommend use of any test methods other than those
found in SW-846.
6
EPA is undertaking a review of the TCLP test and how it is used to evaluate waste leaching (described
in the Phase IV Land Disposal Restrictions rulemaking, 62 Federal Register 25997; May 26, 1998). EPA
anticipates that this review will examine the effects of a number of factors on leaching and on
approaches to estimating the likely leaching of a waste in the environment. These factors include pH,
liquid to solid ratios, matrix effects and physical form of the waste, effects of non-hazardous salts on
the leachability of hazardous metal salts, and others. The effects of these factors on leaching might or
might not be well reflected in the leaching tests currently available. At the conclusion of the TCLP
review, EPA is likely to issue revisions to this guidance that reflect a more complete understanding of
waste constituent leaching under a variety of management conditions.
2-10
7
The TCLP was developed to replace the Extraction Procedure Toxicity Test method which is designated
as EPA Method 1310 in SW-846.
Getting Started—Characterizing Waste
ter is defined as the TCLP extractant. The in a municipal landfill, this test might not be
concentrations of constituents in the liquid appropriate for your waste because the leach-
extract are then determined. ing potential for the same chemical can be
quite different depending on a number of fac-
For wastes containing greater than or equal
tors. These factors include the characteristics
to 0.5 percent solids, the liquid, if any, is sep-
of the leaching fluid, the form of the chemical
arated from the solid phase and stored for
in the solids, the waste matrix, and the dis-
later analysis. The solids must then be
posal conditions.
reduced to particle size, if necessary. The
solids are extracted with an acetate buffer Although the TCLP is the most commonly
solution. A liquid-to-solid ratio of 20:1 by used leachate test for estimating the actual
weight is used for an extraction period of 18 leaching potential of wastes, you should not
± 2 hours. After extraction, the solids are fil- automatically default to it in all situations or
tered from the liquid through a glass fiber fil- conditions and for all types of wastes. While
ter and the liquid extract is combined with the TCLP test might be conservative under
any original liquid fraction of the wastes. some conditions (i.e., overestimates leaching
Analyses are then conducted on the liquid fil- potential), it might underestimate leaching
trate/leachate to determine the constituent under other extreme conditions. In a landfill
concentrations. that has primarily alkaline conditions, the
TCLP is not likely to be the optimal method
To determine if a waste is hazardous
because the TCLP is designed to replicate
because it exhibits the toxicity characteristic
leaching in an acidic environment. For mate-
(TC), the TCLP method is used to generate
rials that pose their greatest hazard when
leachate under controlled conditions as dis-
exposed to alkaline conditions (e.g., metals
cussed above. If the TCLP liquid extract con-
such as arsenic and antimony), use of the
tains any of the constituents listed in Table 1
TCLP might underestimate the leaching
of 40 CFR Part 261 at a concentration equal
potential. When the conditions of your waste
to or greater than the respective value in the
management unit are very different from the
table, the waste is considered to be a TC haz-
conditions that the TCLP test simulates,
ardous waste, unless exempted or excluded
another test might be more appropriate.
under Part 261. Although the TCLP test was
Further, the TCLP might not be appropriate
designed to determine if a waste is hazardous,
for analyzing oily wastes. Oil phases can be
the importance of its use for waste characteri-
difficult to separate (e.g., it might be impossi-
zation as discussed in this chapter is to
ble to separate solids from oil), oily material
understand the parameters to be considered
can obstruct the filter (often resulting in an
in properly managing the wastes.
underestimation of constituents in the
You should check with state and local reg- leachate), and oily materials can yield both
ulatory agencies to determine whether the oil and aqueous leachate which must be ana-
TCLP is likely to be the best test for evaluat- lyzed separately.8
ing the leaching potential of a waste or if
another test might better predict leaching
under the anticipated waste management
2. Synthetic Precipitation
conditions. Because the test was developed by Leaching Procedure (SPLP)
EPA to determine if a waste is hazardous The SPLP (designated as EPA Method 1312
(according to 40 CFR 261.24) and focused in SW-846) is currently used by several state
on simulating leaching of solid wastes placed agencies to evaluate the leaching of con-
8
SW-846 specifies several procedures that should be followed when analyzing oily wastes.
2-11
Getting Started—Characterizing Waste
2-12
Getting Started—Characterizing Waste
leachate generation, in part, from acid rain. solid ratio of 20:1 by weight is used. After
This time a liquid-to-solid ratio of 20:1 by agitation the solids are filtered from the liquid
weight is used for an extraction period of 24 extract, and the liquid is analyzed.
hours. After extraction, the solids are once
The water extraction is meant to simulate
again filtered from the liquid extract, and the
conditions where the solid waste is the domi-
liquid extract is combined with any original
nant factor in determining the pH of the
liquid fraction of the waste.
extract. This test, however, has only been
These four steps are repeated eight addi- approved for certain inorganic constituents,
tional times. If the concentration of any con- and is not applicable to organic substances
stituent of concern increases from the 7th or and volatile organic compounds (VOCs). A
8th extraction to the 9th extraction, the pro- copy of this procedure can be ordered by
cedure is repeated until these concentrations calling ASTM at 610 832-9585 or online at
decrease. <www.astm.org>.
The MEP is intended to simulate 1,000
years of freeze and thaw cycles and prolonged
exposure to a leaching medium. One advan- III. Waste
tage of the MEP over the TCLP is that the
MEP gradually removes excess alkalinity in Characterization
the waste. Thus, the leaching behavior of
metal contaminants can be evaluated as a
of Volatile
function of decreasing pH, which increases
the solubility of most metals.
Organic
Emissions
4. Shake Extraction of Solid To determine whether volatile organic
emissions are of concern at a waste manage-
Waste with Water or Neutral ment unit, determine the concentration of the
Leaching Procedure VOCs that are reasonably expected to be
The Shake Extraction of Solid Waste with emitted. Process knowledge is likely to be
Water, or the Neutral Leaching Procedure, less accurate for determining VOCs than
was developed by the American Society for measured values. As discussed earlier in this
Testing and Materials (ASTM) to assess the chapter, modeling results for waste manage-
leaching potential of solid waste and has been ment units will only be as accurate as the
designated as ASTM D-3987-85. This test input data. Therefore, sampling and analytical
method provides for the shaking of an extrac- testing might be necessary if organic concen-
tant (e.g., water) and a known weight of trations cannot be estimated confidently
waste of specified composition to obtain an using process knowledge.
aqueous phase for analysis after separation.
Table 2 in Chapter 5–Protecting Air Quality
The intent of this test method is for the final
can be used as a starting point to help you
pH of the extract to reflect the interaction of
determine which air emissions constituents to
the liquid extractant with the buffering capac-
measure. It is not recommended that you
ity of the solid waste.
sample for all of the volatile organics listed in
The shake test is performed by mixing the Table 2, but rather use Table 2 as a guide in
solid sample with test water and agitating conjunction with process knowledge to nar-
continuously for 18±0.25 hours. A liquid-to- row the sampling effort and thereby minimize
2-13
Getting Started—Characterizing Waste
2-14
Getting Started—Characterizing Waste
2-15
Getting Started—Characterizing Waste
Resources
ASTM. D-3987-85. Standard Test Method for Shake Extraction of Solid Waste with Water
California EPA. 1995. Preliminary Proposal to Require the TCLP in Lieu of the Waste Extraction
Test. Memorandum to James Carlisle, Department of Toxics Substances Control, from Jon
Marshack, California Regional Water Quality Control Board. December 18.
California EPA. 1994. Regulation Guidance: When Extraction Tests are Not Necessary.
Cochran, W.G. 1977. Sampling Techniques. Third Edition. New York: John Wiley and Sons.
Dusing, D.C., Bishop, P.L., and Keener, T.C. 1992. Effect of Redox Potential on Leaching from
Stabilized/Solidified Waste Materials. Journal of Air and Waste Management Association. 42:56.
January.
Gilbert, R.O. 1987. Statistical Methods for Environmental Pollution Monitoring. New York: Van
Nostrand Reinhold Company.
Kosson, D.S., H.A. van der Sloot, F. Sanchez, and A.C. Garrabrants. 2002. An Integrated
Framework for Evaluating Leaching in Waste Management and Utilization of Secondary Materials.
Environmental Engineering Science, In-press.
New Jersey Department of Environmental Protection. 1996. Industrial Pollution Prevention Trends
in New Jersey.
2-16
Getting Started—Characterizing Waste
Resources (cont.)
Northwestern University. 1995. Chapter 4—Evaluation of Procedures for Analysis and Disposal of
Lead- Based Paint-Removal Debris. Issues Impacting Bridge Painting: An Overview. Infrastructure
Technology Institute. FHWA/RD/94/098. August.
U.S. EPA 2002. Industrial Waste Managment Evaluation (IWEM) Technical Background Document.
EPA530-R-02-012.
U.S. EPA. 1998a. Guidance on Quality Assurance Project Plans: EPA QA/G-5. EPA600-R-98-018.
U.S. EPA. 1998b. Guidance on Sampling Designs to Support QA Project Plans. QA/G-5S
U.S. EPA. 1996a. Guidance for the Data Quality Assessment: Practical Methods for Data Analysis:
EPAQA/G-9. EPA600-R-96-084.
U.S. EPA. 1996b. Guidance for the Data Quality Objectives Process: EPA QA/G-4. EPA600-R-96-055.
U.S. EPA. 1996d. National Exposure Research Laboratory (NERL)-Las Vegas: Site Characterization
Library, Volume 2.
U.S. EPA. 1996e. Test Methods for Evaluating Solid Waste Physical/Chemical Methods—SW846. Third
Edition.
U.S. EPA. 1995. State Requirements for Non-Hazardous Industrial Waste Management Facilities.
U.S. EPA. 1993. Identifying Higher-Risk Wastestreams in the Industrial D Universe: The State
Experience. Draft.
U.S. EPA Science Advisory Board. 1991. Leachability Phenomena: Recommendations and Rationale for
Analysis of Contaminant Release by the Environmental Engineering Committee. EPA-SAB-EEC-92-003.
Winer, B.J. 1971. Statistical Principles in Experimental Design. New York: McGraw-Hill.
2-17
Getting Started—Characterizing Waste
I. Static Tests
Toxicity 0.1 N acetic acid solution, 20:1 9.5 mm 1 18 ±2 hours Co-disposal scenario might
Characteristic pH 2.9, for alkaline wastes not be appropriate; no
Leaching 0.1 N sodium acetate allowance for structural
Procedure (1311) buffer solution, pH 5.0, integrity testing of
for non-alkaline wastes monolithic samples
Extraction 0.5 N acetic acid (pH-5.0) 16:1 during 9.5 mm 1 24 hours High alkalinity samples can
Procedure extraction result in variable data
Toxicity Test (1310) 20:1 final
dilution
ASTM D3987-85 ASTM IV reagent water 20:1 As in 1 18 hours Not validated for organics
Shake Extraction environment
of Solid Waste (as received)
with Water
California WET 0.2 M sodium citrate 10:1 2.0 mm 1 48 hours Similar to EP, but sodium
(pH- 5.0) citrate makes test more
aggressive
Alternative TCLP TCLP acetic acid solutions 20:1 <9.5 1 8 hours Uses heat to decrease
for Construction, extraction time
Demolition and
Lead Paint
Abatement Debris10
Synthetic #1 Reagent water to pH 4.2 20:1 9.5 mm 1 18±2 hours ZHE option for organics
Precipitation with nitric and sulfuric
Leaching Procedure acids (60/40)
(1312) #2 Regent water to pH 5.0
with nitric and sulfuric
acids (60/40)
9
Bisson, D.L.; Jackson D.R.; Williams K.R.; and Grube W.E. J. Air Waste Manage. Assoc., 41: 1348-1354.
10
Olcrest, R. A Representative Sampling and Alternative Analytical Toxic Characteristic Leachate Procedure
2-18 Method for Construction, Demolition, and Lead Paint Abatement Debris Suspected of Containing Leachable
Lead, Appl. Occup. Environ. Hyg. 11(1), January 1996.
Getting Started—Characterizing Waste
Static Leach Test Can be site specific, 3 VOL/surface 40 mm2 1 >7 days Series of optional steps
Method (material standard leachates: water, 10 cm surface area increasing complexity of
characteristic brine, silicate/bicarbonate analysis
centre- 1)
High Temperature Same as MCC-1 (conducted VOL/Surface 40 mm2 1 >7 Days Series of optional steps
Static Leach Tests at 100°C) 10 cm Surface Area increasing complexity of
Method (material analysis
characterization
centre-2)
Standard Leach DI water SYN Landfill 10:1, 5:1, As in 3 3 or 14 days Sample discarded after each
Test, Procedure C 7.5:1 environment leach, new sample added to
(Wisconsin) existing leachate
Multiple Extraction Same as EP TOX, then 20:1 9.5 mm 9 (or more) 24 hours per
Procedure (1320) with synthetic acid rain extraction
(sulfuric acid, nitric acid
in 60:40% mixture)
Graded Serial Batch Distilled water Increases N/A >7 Until steady
(U.S. Army) from 2:1 to state
96:1
2-19
Getting Started—Characterizing Waste
Use of Chelating Demineralized water with 50 or 100 <300 µm 1 18, 24, or Experimental test based on
Agent to Determine EDTA, sample to a final 48 hours Method 7341
the Metal pH of 7±0.5
Availability for
Leaching Soils and
Wastes11
IAEA Dynamic DI water/site water N/A One face >19 >6 months
Leach Test prepared
(International
Atomic Energy
Agency)
Leaching Tests on 0.1N acetic acid 20:1 0.6 µm-70µm 1 24 hours S/S technologies most valid
Solidified Products12 (Procedure A) when applied to wastes
2:1 (6 hrs.) contaminated by inorganic
& 10:1 pollutants
(18 hrs.)
(Procedure B)
Generalized Acid Acetic acid 20:1 Able to pass 1 48 hours Quantifies the alkalinity of
Neutralization through an binder and characterizes
Capacity Test14 ASTM No. 40 buffering chemistry
sieve
11
Garrabrants, A.C. and Koson, D.S.; Use of Chelating Agent to Determine the Metal Availability for Leaching
from Soils and Wastes, unpublished.
12
Leaching Tests on Solidified Products; Gavasci, R., Lombardi, F., Polettine, A., and Sirini, P.
13
C1308-95 Accelerated Leach Test for Diffusive Releases from Solidified Waste and a Computer Program to
Model Diffusive, Fractional Leaching from Cylindrical Wastes.
2-20 14
Generalized Acid Neutralization capacity Test; Isenburg, J. and Moore, M.
Part I
Getting Started
Chapter 3
Integrating Pollution Prevention
Contents
III. Where to Find Out More: Technical and Financial Assistance ..............................................................3 - 10
Resources ....................................................................................................................................................3 - 15
P
ollution prevention describes a vari-
agencies. It can also reduce liabilities and risks
ety of practices that go beyond tra-
associated with releases from waste manage-
ditional environmental compliance
ment units and closure and post-closure care
or single media permits for water,
of waste management units.
air, or land disposal and begin to
address the concept of sustainability in the Pollution prevention is comprehensive.
use and reuse of natural resources. Adopting It emphasizes a life-cycle approach to assess-
pollution prevention policies and integrating ing a facility’s physical plant, production
pollution prevention into operations provide processes, and products to identify the best
opportunities to reduce the volume and toxic- opportunities to minimize environmental
ity of wastes, reduce waste disposal needs, impacts across all media. This approach also
and recycle and reuse materials formerly han- ensures that actions taken in one area will not
dled as wastes. In addition to potential sav- increase environmental problems in another
ings on waste management costs, pollution area, such as reducing wastewater discharges
prevention can help improve the interactions but increasing airborne emissions of volatile
organic compounds. Pollution prevention
requires creative problem solving by a broad
This chapter will help address the fol- cross section of employees to help achieve
lowing questions. environmental goals. In addition to the envi-
ronmental benefits, implementing pollution
• What are some of the benefits of pol- prevention can often benefit a company in
lution prevention? many other ways. For example, redesigning
• Where can assistance in identifying production processes or finding alternative
and implementing specific pollution material inputs can also improve product
prevention options be obtained? quality, increase efficiency, and conserve raw
materials. Some common examples of pollu-
tion prevention activities include: redesigning
3-1
Getting Started—Intregrating Pollution Prevention
processes or products to reduce raw material ated with the release of such substances, pol-
needs and the volume of waste generated; lutants, or contaminants.
replacing solvent based cleaners with aqueous
Recycling requires an examination of
based cleaners or mechanical cleaning sys-
waste streams and production processes to
tems; and instituting a reverse distribution
identify opportunities. Recycling and benefi-
system where shipping packaging is returned
cially reusing wastes can help reduce disposal
to the supplier for reuse rather than discard.
costs, while using or reusing recycled materi-
The Pollution Prevention Act of 1990 als as substitutes for feedstocks can reduce
established a national policy to first, prevent raw materials costs. Materials exchange pro-
or reduce waste at the point of generation grams can assist in finding uses for recycled
(source reduction); second, recycle or reuse materials and in identifying effective substi-
waste materials; third, treat waste; and finally, tutes for raw materials. Recycling not only
dispose of remaining waste in an environ- helps reduce the overall amount of waste sent
mentally protective manner (see Figure 1). for disposal, but also helps conserve natural
Some states and many local governments resources by replacing the need for virgin
have adopted similar policies, often with materials.
more specific and measurable goals.
Treatment can reduce the volume and
Source Reduction means any practice toxicity of a waste. Reducing a waste’s volume
which (i) reduces the amount of any sub- and toxicity prior to final disposal can result
stance, pollutant, or contaminant entering in long-term cost savings. There are a consid-
any wastestream or otherwise released into erable number of levels and types of treat-
the environment, prior to recycling, treat- ment from which to choose. Selecting the
ment, or disposal; and (ii) reduces the risks right treatment option can help simplify dis-
to public health and the environment associ- posal options and limit future liability.
3-2
Getting Started—Integrating Pollution Prevention
Over the past 10 years, interest in all aspects to land application can provide the flexibility to
of pollution prevention has blossomed, and use land application and ensure that the prac-
governments, businesses, academic and tice will be protective of human health and the
research institutions, and individual citizens environment and limit future liabilities.
have dedicated greater resources to it. Many
industries are adapting pollution prevention
practices to fit their individual operations.
Pollution prevention can be successful when
I. Benefits of
flexible problem-solving approaches and solu-
tions are implemented. Fitting these steps into
Pollution
your operation’s business and environmental Prevention
goals will help ensure your program’s success. Pollution prevention activities benefit
Throughout the Guide several key steps are industry, states, and the public by protecting
highlighted that are ideal points for imple- the environment and reducing health risks,
menting pollution prevention to help reduce and also provide businesses with financial and
waste management costs, increase options, or strategic benefits.
reduce potential liabilities by reducing risks Protecting human health and the envi-
that the wastes might pose. For example: ronment. By reducing the amount of contami-
Waste characterization is a key compo- nants released into the environment and the
nent of the Guide. It is also a key component volume of waste requiring disposal, pollution
of a pollution prevention opportunity assess- prevention activities protect human health and
ment. An opportunity assessment, however, is the environment. Decreasing the volume or
more comprehensive since it also covers mate- toxicity of process materials and wastes can
rial inputs, production processes, operating reduce worker exposure to potentially harmful
practices, and potentially other areas such as constituents. Preventing the release and dis-
inventory control. When characterizing a posal of waste constituents to the environment
waste, consider expanding the opportunity also reduces human and wildlife exposure and
assessment to cover these aspects of the busi- habitat degradation. Reduced consumption of
ness. An opportunity assessment can help raw materials and energy conserves precious
identify the most efficient, cost-effective, and natural resources. Finally reducing the volume
environmentally friendly combination of of waste generated decreases the need for con-
options, especially when planning new prod- struction of new waste management facilities,
ucts, new or changed waste management prac- preserving land for other uses such as recre-
tices, or facility expansions. ation or wildlife habitat.
Land application of waste might be a pre- Cost savings. Many pollution prevention
ferred waste management option because land activities make industrial processes and equip-
application units can manage wastes with high ment more resource-efficient. This increased
liquid content, treat wastes through biodegra- production efficiency saves raw material and
dation, and improve soils due to the organic labor costs, lowers maintenance costs due to
material in the waste. Concentrations of con- newer equipment, and potentially lowers over-
stituents might limit the ability to take full sight costs due to process simplification. When
advantage of land application. Reducing the planning pollution prevention activities, con-
concentrations of constituents in the waste sider the cost of the initial investment for
before it is generated or treating the waste prior audits, equipment, and labor. This cost will
3-3
Getting Started—Intregrating Pollution Prevention
3-4
Getting Started—Integrating Pollution Prevention
3-5
Getting Started—Intregrating Pollution Prevention
tion of waste and risk reduction, adopting waste reduction program, especially one fea-
new procedures or upgrading equipment can turing good housekeeping procedures. Case
reduce waste volume, toxicity, and manage- study data indicate that effective employee
ment costs. Some examples include redesign- training programs can reduce waste disposal
ing equipment to cut losses during batch volumes by 10 to 40 percent.1
changes or during cleaning and maintenance,
Regularly scheduled maintenance and
changing to mechanical cleaning devices to
plant inspections are also useful. Maintenance
avoid solvent use, and installing more energy-
helps avoid the large cleanups and disposal
and material-efficient equipment. State tech-
operations that can result from equipment
nical assistance centers, trade associations,
failure. Routine maintenance also ensures that
and other organizations listed in this chapter
equipment is operating at peak efficiency, sav-
can help evaluate the potential advantages
ing energy, time, and materials. Regularly
and savings of such improvements.
scheduled or random, unscheduled plant
In-process recycling (reuse). In-process inspections help identify potential problems
recycling involves the reuse of materials, such before they cause waste management prob-
as cutting scraps, as inputs to the same lems. They also help identify areas where
process from which they came, or uses them improving the efficiency of materials manage-
in other processes or for other uses in the ment and handling practices is possible. If
facility. This furthers waste reduction goals by possible, plant inspections, periodically per-
reducing the need for treatment or disposal formed by outside inspectors who are less
and by conserving energy and resources. A familiar with day-to-day plant operations, can
common example of in-process recycling is bring attention to areas for improvement that
the reuse of wastewater. are overlooked by employees accustomed to
the plant’s routine practices.
Good housekeeping procedures. Some of
the easiest, most cost-effective, and most wide- Storing large volumes of raw materials
ly used waste reduction techniques are simple increases the risk of an accidental spill and
improvements in housekeeping. Accidents and the likelihood that the materials will not be
spills generate avoidable disposal hazards and used due to changes in production schedules,
expenses. They are less likely to occur in new product formulations, or material degra-
clean, neatly organized facilities. dation. Companies are sometimes forced to
dispose of materials whose expiration dates
Good housekeeping techniques that reduce
have passed or that are no longer needed.
the likelihood of accidents and spills include
Efficient inventory control allows a facility to
training employees to manage waste and
avoid stocking materials in excess of its abili-
materials properly; keeping aisles wide and
ty to use them, thereby decreasing disposal
free of obstructions; clearly labeling contain-
volume and cost. Many companies have suc-
ers with content, handling, storage, expira-
cessfully implemented “just-in-time” manu-
tion, and health and safety information;
facturing systems to avoid the costs and risks
spacing stored materials to allow easy access;
associated with maintaining a large onsite
surrounding storage areas with containment
inventory. In a “just-in-time” manufacturing
berms to control leaks or spills; and segregat-
system, raw materials arrive as they are need-
ing stored materials to avoid cross-contami-
ed and only minimal inventories are main-
nation, mixing of incompatible materials, and
tained on site.
unwanted reactions. Proper employee train-
ing is crucial to implementing a successful
1
Freeman, Harry. 1995. Industrial Pollution Prevention Handbook. McGraw-Hill, Inc. p. 13.
3-6
Getting Started—Integrating Pollution Prevention
Segregating waste streams is another good simply publish lists of generators, materials,
housekeeping procedure that enables a facili- and buyers. Some waste exchanges also spon-
ty to avoid contaminating lower risk wastes sor workshops and conferences to discuss
with hazardous constituents from another waste-related regulations and to exchange
source. Based on a waste characterization information. More than 60 waste and materials
study, it might be more efficient and cost- exchanges operate in North America. Below
effective to manage wastes separately by recy- are four examples of national, state, and local
cling some, and treating or disposing of exchange programs. Each program’s Web site
others. Waste segregation can also help also provides links to other regional, national,
reduce the risks associated with handling and international materials exchange net-
waste. Separating waste streams allows some works.
materials to be reused, resulting in additional
• EPA’s Jobs Through Recycling (JTR)
cost savings. Emerging markets for recovered
Web site <www.epa.gov/jtr/comm/
industrial waste materials are creating new
exchange.htm> provides descriptions
economic incentives to segregate waste
of and links to international, national,
streams. Recovered materials are more attrac-
and state-specific materials exchange
tive to potential buyers if it can be ensured
programs and organizations.
that they are not tainted with other waste
materials. For example, if wastes from metal- • Recycler’s World <www.recycle.net/
finishing facilities are segregated by type, exch/index.html> is a world-wide
metal-specific-bearing sludge can be recov- materials trading site with links to
ered more economically and the segregated dozens of state and regional exchange
solvents and waste oils can be recycled. networks.
• CalMAX (California Materials
B. Recycling Exchange) <www.ciwmb.ca.gov/
calmax> is maintained by the
Recycling involves col- California Integrated Waste
lecting, processing, and Management Board and facilitates
reusing materials that waste exchanges in California and
would otherwise be han- provides links to other local and
dled as wastes. The fol- national exchange programs.
lowing discussion highlights a few of the
ways to begin this process. • King County, Washington’s IMEX
<www.metrokc.gov/hazwaste/imex/
Materials exchange programs. Many local exchanges.html/> is a local industri-
governments and states have established mate- al materials exchange program that
rials exchange programs to facilitate transac- also provides an extensive list of
tions between waste generators and industries state, regional, national, and interna-
that can use wastes as raw materials. Materials tional exchange programs.
exchanges are an effective and inexpensive way
to find new users and uses for a waste. Most Beneficial use. Beneficial use involves
are publicly funded, nonprofit organizations, substituting a waste material for another
although some charge a nominal fee to be list- material with similar properties. Utility com-
ed with them or to access their online databas- panies, for example, often use coal combus-
es. Some actively work to promote exchanges tion ash as a construction material, road base,
between generators and users, while others or soil stabilizer. The ash replaces other, non-
3-7
Getting Started—Intregrating Pollution Prevention
recycled materials, such as fill or Portland est recovered material content level practica-
cement, not only avoiding disposal costs but ble. As of January 2001, EPA has designated
also generating revenue. Other examples of 54 items within eight product categories
beneficial use include using wastewaters and including items such as retread tires, cement
sludges as soil amendments (see Chapter 7, and concrete containing coal fly ash and
Section C–Designing a Land Application ground granulated blast furnace slag, traffic
Program) and using foundry sand in asphalt, barricades, playground surfaces, landscaping
concrete, and roadbed construction. products, and nonpaper office products like
binders and toner cartridges. While directed
Many regulatory agencies require approval
primarily at federal, state, and local procuring
of planned beneficial use activities and may
agencies, CPG information is helpful to every-
require testing of the materials to be reused.
one interested in purchasing recycled-content
Others may allow certain wastes to be desig-
products. For further information on the CPG
nated for beneficial use, as long as the required
program, visit: <www.epa.gov/cpg>.
analyses are completed. Pennsylvania, for
example, allows application of a “coproduct”
designation to, and exemption from waste reg- C. Treatment
ulations for “materials which are essentially
equivalent to and used in place of an inten- Treatment of non-hazardous industrial
tionally manufactured product or produced waste is not a federal requirement, however,
raw material and... [which present] no greater it can help to reduce the volume and toxicity
risk to the public or the environment.” of waste prior to disposal. Treatment can also
Generally, regulatory agencies want to ensure make a waste amenable for reuse or recycling.
that any beneficially used materials are free Consequently, a facility managing non-haz-
from significantly increased levels of con- ardous industrial waste might elect to apply
stituents that might pose a greater risk than treatment. For example, treatment might be
the materials they are replacing. Consult with incorporated to address volatile organic com-
the state agency for criteria and regulations pound (VOC) emissions from a waste manag-
governing beneficial use. ment unit, or a facility might elect to treat a
waste so that a less stringent waste manage-
In a continuing effort to promote the use of ment system design could be used. Treatment
materials recovered from solid waste, the involves changing a waste’s physical, chemi-
Environmental Protection Agency (EPA) has cal, or biological character or composition
instituted the Comprehensive Procurement through designed techniques or processes.
Guideline (CPG) program. Using recycled-con- There are three primary categories of treat-
tent products ensures that materials collected ment—physical, chemical, and biological.
in recycling programs will be used again in the
manufacture of new products. The CPG pro- Physical treatment involves changing the
gram is authorized by Congress under Section waste’s physical properties such as its size,
6002 of the Resource Conservation and shape, density, or state (i.e., gas, liquid, solid).
Recovery Act (RCRA) and Executive Order Physical treatment does not change a waste’s
13101. Under the CPG program, EPA is chemical composition. One form of physical
required to designate products that are or can treatment, immobilization, involves encapsu-
be made with recovered materials and to rec- lating waste in other materials, such as plastic,
ommend practices for buying these products. resin, or cement, to prevent constituents from
Once a product is designated, procuring agen- volatilizing or leaching. Listed below are a few
cies are required to purchase it with the high- examples of physical treatment.
3-8
Getting Started—Integrating Pollution Prevention
• Immobilization: • Stabilization
Encapsulation
• Vitrification
Thermoplastic binding
• Extraction:
• Carbon absorption:
Solvent extraction
Granular activated carbon (GAC)
Critical extraction
Powdered activated carbon (PAC)
• High temperature metal recovery
• Distillation:
(HTMR)
Batch distillation
Fractionation Biological treatment can be divided into two
Thin film extraction categories–aerobic and anaerobic. Aerobic bio-
Steam stripping logical treatment uses oxygen-requiring
Thermal drying microorganisms to decompose organic and
non-metallic constituents into carbon dioxide,
• Filtration
water, nitrates, sulfates, simpler organic prod-
• Evaporation/volatilization ucts, and cellular biomass (i.e., cellular growth
and reproduction). Anaerobic biological treat-
• Grinding
ment uses microorganisms, in the absence of
• Shredding oxygen, to transform organic constituents and
• Compacting nitrogen-containing compounds into oxygen
and methane gas (CH4(g)). Anaerobic biologi-
• Solidification/addition of absorbent cal treatment typically is performed in an
material enclosed digestor unit. Listed below are a few
Chemical treatment involves altering a examples of biological treatment.
waste’s chemical composition, structure, and • Aerobic:
properties through chemical reactions. Activated sludge
Chemical treatment can consist of mixing the Aerated lagoon
waste with other materials (reagents), heating Trickling filter
the waste to high temperatures, or a combi- Rotating biological contactor (RBC)
nation of both. Through chemical treatment,
waste constituents can be recovered or • Anaerobic digestion
destroyed. Listed below are a few examples of The range of treatment methods from
chemical treatment. which to choose is as diverse as the range of
• Neutralization wastes to be treated. More advanced treat-
ment will generally be more expensive, but
• Oxidation by reducing the quantity and risk level of the
• Reduction waste, costs might be reduced in the long
run. Savings could come from not only lower
• Precipitation disposal costs, but also lower closure and
• Acid leaching post-closure care costs. Treatment and post-
treatment waste management methods can be
• Ion exchange
selected to minimize both total cost and envi-
• Incineration ronmental impact, keeping in mind that treat-
ment residuals, such as sludges, are wastes
• Thermal desorption
themselves that will need to be managed.
3-9
Getting Started—Intregrating Pollution Prevention
3-10
Getting Started—Integrating Pollution Prevention
3-11
Getting Started—Intregrating Pollution Prevention
3-12
Getting Started—Integrating Pollution Prevention
3-13
Getting Started—Intregrating Pollution Prevention
Integrating Pollution
Prevention Activity List
To address pollution prevention you should:
■ Make waste management decisions by considering the priorities set by the full range of pollution
prevention options—first, source reduction; second, reuse and recycling; third, treatment; last, dis-
posal.
■ Explore the cost savings and other benefits available through activities that integrate pollution pre-
vention.
■ Develop a waste reduction policy.
■ Conduct a pollution prevention opportunity assessment of facility processes.
■ Research potential pollution prevention activities.
■ Consult with public and private agencies and organizations providing technical and financial assis-
tance for pollution prevention activities.
■ Plan and implement activities that integrate pollution prevention.
3-14
Getting Started—Integrating Pollution Prevention
Resources
Erickson, S. and King, B. 1999. Fundamentals of Environmental Management. John Wiley and Sons,
Inc.
“Green Consumerism: Commitment Remains Strong Despite Economic Pessimism.” 1992. Cambridge
Reports. Research International. (October).
Habicht, F. Henry. 1992. U.S. EPA Memorandum on EPA Definition of Pollution Prevention (May).
Higgins, Thomas E., ed. 1995. Pollution Prevention Handbook. CRC-Lewis Publishers.
National Pollution Prevention Roundtable. 1995. The Pollution Prevention Yellow Pages.
Pollution Prevention Act of 1990. (42 U.S.C. 13101 et seq., Pub.L. 101-508, November 5, 1990).
Rossiter, Alan P., ed. 1995. Waste Minimization Through Process Design. McGraw-Hill, Inc.
U.S. EPA. 2001. Pollution Prevention Clearinghouse: Quarterly List of Pollution Prevention
Publications, Winter 2001. EPA742-F-01-004.
U.S. EPA. 1998. Project XL: Good for the Environment, Good for Business, Good for Communities.
EPA100–F-98-008.
U.S. EPA. 1997. Developing and Using Production Adjusted Measurements of Pollution Prevention.
EPA600-R-97-048.
U.S. EPA. 1997. Guide to Accessing Pollution Prevention Information Electronically. EPA742-B-97-003
U.S. EPA. 1997. Pollution Prevention 1997: A National Progress Report. EPA742-R-97-001.
U.S. EPA. 1997. Technical Support Document for Best Management Practices Programs—Spent
Pulping Liquor Management, Spill Prevention, and Control.
U.S. EPA. 1996. Environmental Accounting Project: Quick Reference Fact Sheet. EPA742-F-96-001.
3-15
Getting Started—Intregrating Pollution Prevention
Resources (cont.)
U.S. EPA. 1996. Profiting from Waste Reduction in Your Small Business. EPA742-B-88-100.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Paints and Coatings. EPA600-S-95-009.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Bourbon Whiskey. EPA600-S-95-010.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Automotive Battery Separators. EPA600-S-95-011.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Automotive Lighting Equipment and Accessories. EPA600-S-95-012.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Locking Devices. EPA600-S-95-013.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Combustion Engine Piston Rings. EPA600-S-95-015.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Metal Fasteners.EPA600-S-95-016.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Stainless Steel Pipes and Fittings. EPA600-S-95-017.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Outboard Motors. EPA600-S-95-018.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Electroplated Truck Bumpers. EPA600-S-95-019.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Printed Circuit
Board Plant.EPA600-S-95-020.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Folding Paperboard Cartons. EPA600-S-95-021.
3-16
Getting Started—Integrating Pollution Prevention
Resources (cont.)
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Rebuilt Industrial Crankshafts. EPA600-S-95-022.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Pressure-sensitive Adhesive Tape. EPA600-S-95-023.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Wooden Cabinets. EPA600-S-95-024.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Power Supplies. EPA600-S-95-025.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Food Service Equipment. EPA600-S-95-026.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Metal Parts
Coater. EPA600-S-95-027.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Gear Cases for Outboard Motors. EPA600-S-95-028.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Electrical Load Centers. EPA600-S-95-029.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Pharmaceuticals. EPA600-S-95-030.
U.S. EPA. 1995. Environmental Research Brief: Pollution Prevention Assessment for a Manufacturer of
Aircraft Landing Gear. EPA600-S-95-032.
U.S. EPA. 1995. EPA Standards Network Fact Sheet: Role of Voluntary Standards. EPA741-F-95-005.
U.S. EPA. 1995. Recent Experience in Encouraging the Use of Pollution Prevention in Enforcement
Settlements: Final Report. EPA300-R-95-006.
3-17
Getting Started—Intregrating Pollution Prevention
Resources (cont.)
U.S. EPA. 1994. Final Best Demonstrated Available Technology (BDAT) Background Document for
Universal Standards, Volume B: Universal Standards for Wastewater forms of Listed Hazardous Wastes,
Section 5, Treatment Performance Database. EPA530-R-95-033.
U.S. EPA. 1993. Guidance Manual for Developing Best Management Practices. EPA833-B-93-004.
U.S. EPA. 1993. Primer for Financial Analysis of Pollution Prevention Projects. EPA600-R-93-059.
U.S. EPA. 1992. Practical Guide to Pollution Prevention Planning for the Iron and Steel Industries.
EPA742-B-92-100
U.S. EPA. 1991. Treatment Technology Background Document; Third Third; Final. EPA530-SW-90-
059Z.
U.S. EPA. 1990. Guide to Pollution Prevention: Printed Circuit Board Manufacturing Industry. EPA625-
7-90-007
U.S. EPA. 1990. Waste Minimization: Environmental Quality with Economic Benefits. EPA530-SW-90-
044.
U.S. EPA. 1989. Treatment Technology Background Document; Second Third; Final. EPA530-SW-89-
048A.
3-18
Part I
Getting Started
Chapter 4
Considering the Site
Contents
Resources ....................................................................................................................................................4 - 27
Tables:
Table 1: Examples of Improvement Techniques for Liquefiable Soil Foundation Conditions ..................4 - 12
Getting Started—Considering the Site
M
earthquake zones, unstable soils, and areas at
any hydrologic and geologic
risk for subsurface movement need to be
settings can be effectively uti-
taken into account just as they would be
lized for protective waste
when siting and constructing a manufactur-
management. There are,
ing plant or home. Catastrophic events asso-
however, some hydrologic
ciated with these locations could seriously
and geologic conditions that are best avoided
damage or destroy a waste management unit,
all together if possible. If they cannot be
release contaminants into the environment,
avoided, special design and construction pre-
and add substantial expenses for cleanup,
cautions can minimize risks. Floodplains,
repair, or reconstruction. If problematic site
conditions cannot be avoided, engineering
This chapter will help address the follow- design and construction techniques can
ing questions: address some of the concerns raised by locat-
• What types of sites need special consid- ing a unit in these areas.
eration? Many state, local, and tribal governments
• How will I know whether my waste require buffer zones between waste manage-
management unit is in an area requir- ment units and other nearby land uses. Even
ing special consideration? if buffer zones are not required, they can still
provide benefits now and in the future. Buffer
• Why should I be concerned about sit- zones provide time and space to contain and
ing a waste management unit in such remediate accidental releases before they
areas? reach sensitive environments or sensitive
• What actions can I take if I plan to site populations. Buffer zones also help maintain
a unit in these areas? good community relations by reducing dis-
ruptions associated with noise, traffic, and
4-1
Getting Started—Considering the Site
wind-blown dust, often the source of serious be required prior to the disturbance of any
neighborhood concerns. land area or before property titles are trans-
ferred. An ESA is the process of determining
In considering impacts on the surrounding
whether contamination is present on a parcel
community, it is important to understand
of property. You should check with the EPA
whether the community, especially one with a
regional office and state or local authorities to
large minority and low income population,
determine if there are any ESA requirements
already faces significant environmental
prior to siting a new unit or expanding an
impacts from existing industrial activities. You
existing unit. If there are no requirements,
should develop an understanding of the com-
you might want to consider performing an
munity’s current environmental problems and
ESA in order to ensure that there are no cont-
work together to develop plans that can
amination problems at the site.
improve and benefit the environment, the
community, the state, and the company. Many companies specialize in site screening,
characterization, and sampling of different
How should a waste environmental media (i.e., air, water, soil) for
management unit site potential contamination. A basic ESA (often
assessment begin? referred to as the Phase I Environmental Site
In considering whether to site a new waste Assessment process) typically involves
management unit or laterally expand an exist- researching prior land use, deciding if sam-
ing unit, certain factors will influence the sit- pling of environmental media is necessary
ing process. These factors include land based on the prior activities, and determining
availability, distance from waste generation contaminate fate and transport if contamina-
points, ease of access, local climatic condi- tion has occurred. Liability issues can arise if
tions, economics, environmental considera- the site had contamination problems prior to
tions, local zoning requirements, and potential construction or expansion of the waste man-
impacts on the community. As prospective agement unit. Information on the extent of
sites are identified, you should become famil- contamination is needed to quantify cleanup
iar with the siting considerations raised in this costs and determine the cleanup approach.
chapter. Determine how to address concerns at Cleanup costs can represent an additional,
each site to minimize a unit’s adverse impacts possibly significant, project cost when siting a
on the environment in addition to the environ- waste management unit.
ment’s adverse impacts on the unit. You should As discussed later in this chapter, you will
choose the site that best balances protection of also need to consider other federal laws and
human health and the environment with oper- regulations that could affect siting. For exam-
ational goals. In addition to considering the ple, the Endangered Species Act (16 USC
issues raised in this chapter, you should check Sections 1531 et seq.) provides for the desig-
with state and local regulatory agencies early nation and protection of threatened or endan-
in the siting process to identify other issues gered wildlife, fish, and plant species, and
and applicable restrictions. ensures the conservation of the ecosystems on
Another factor to consider is whether there which such species depend. It is the responsi-
are any previous or current contamination bility of the facility manager to check with
problems at the site. It is recommended that and obtain a Section 10 permit from the
potential sites for new waste management Secretary of the Interior if the construction or
units be free of any contamination problems. operation of a waste management unit might
An environmental site assessment (ESA) may potentially impact any endangered or threat-
4-2
Getting Started—Considering the Site
ened species or its critical habitat. Thus, you water supplies, toxic and air releases, haz-
might not be able to site a new waste man- ardous waste sites, water discharge permits,
agement unit in an area where endangered or and Superfund sites at the national, state, and
threatened species live, or expand an existing county levels.
unit into such an area. As another example,
EPA’s Waste Management—Facility Siting
the National Historic Preservation Act (16
Application is a powerful new Web-based
USC Sections 470 et seq.) protects historic
tool that provides assistance in locating waste
sites and archaeological resources. The facility
management facilities. The tool allows the
manager of a waste management unit should
user to enter a ZIP code; city and state; or lat-
be aware of the properties listed on the
itude and longitude to identify the location of
National Register of Historic Properties. The
fault lines, flood planes, wetlands, and karst
facility manager should consult with the state
terrain in the selected area. The user also can
historic preservation office to ensure that the
use the tool to display other EPA regulated
property to be used for a new unit or lateral
facilities, monitoring sites, water bodies, and
expansion of an existing unit will not impact
community demographics. The Facility Siting
listed historic properties, or sites with archeo-
Application can be found at <www.epa.gov/
logical significance. Other federal laws or
epaoswer/non-hw/industd/index.htm>.
statutes might also require consideration. It is
the ultimate responsibility of the facility
owner or manager to comply with the
requirements of all applicable federal and I. General Siting
state statutes when siting a waste manage-
ment unit. Considerations
Examining the topography of a site is the
Additional factors, such as proximity to
first step in siting a unit. Topographic infor-
other activities or sites that affect the environ-
mation is available from the U.S. Geological
ment, also might influence siting decisions.
Survey (USGS), the Natural Resources
To determine your unit’s proximity to other
Conservation Service (NRCS)1, the state’s geo-
facilities or industrial sites, you can utilize
logical survey office or environmental regula-
EPA’s Envirofacts Warehouse. The Envirofacts
tory agency, or local colleges and universities.
Web site at <www.epa.gov/enviro/index_
Remote sensing data or maps from these orga-
java.html> provides users with access to sev-
nizations can help you determine whether
eral EPA databases that will provide you with
your prospective site is located in any of the
information about various environmental
areas of concern discussed in this section.
activities including toxic chemical releases,
USGS maps can be downloaded or ordered
water discharges, hazardous waste handling
from their Web site at <mapping.usgs.gov>.
processes, Superfund status, and air releases.
Also, the University of Missouri-Rolla main-
The Web site allows you to search one data-
tains a current list of state geological survey
base or several databases at a time about a
offices on its library’s Web site at
specific location or facility. You can also cre-
<www.umr.edu/~library/geol/geoloff.html>.
ate maps that display environmental informa-
tion using the “Enviromapper” application
located at <www.epa.gov/enviro/html/mod/ A. Floodplains
index.html>. Enviromapper allows users to
A floodplain is a relatively flat, lowland
map different types of environmental infor-
area adjoining inland and coastal waters. The
mation, including the location of drinking
1
This agency of the U.S. Department of Agriculture was formerly known as the Soil Conservation
Service (SCS).
4-3
Getting Started—Considering the Site
How is it determined if a
prospective site is in a 100-year
floodplain?
The first step in determining whether a
prospective site is located in a 100-year flood-
plain is to consult with the Federal Emergency
Management Agency (FEMA). FEMA has pre-
pared flood hazard boundary maps for most
regions. If a prospective site does not appear
to be located in a floodplain, further explo-
Flood waters overflowed from the ration is not necessary. If uncertainty exists as
Mississippi River (center) into its floodplain to whether the prospective site might be in a
(foreground) at Quincy, Illinois in the 1993 floodplain, several sources of information are
floods that exceeded 100-year levels in parts available to help make this determination.
of the Midwest. More detailed flood insurance rate maps
(FIRMs) can be obtained from FEMA. FIRMs
100-year floodplain—the area susceptible to divide floodplain areas into three zones: A, B,
inundation during a large magnitude flood and C. Class A zones are the most susceptible
with a 1 percent chance of recurring in any to flooding while class C zones are the least
given year—is usually the floodplain of con- susceptible. FIRMs can be obtained from
cern for waste management units. You should FEMA’s Web site at <msc.fema.gov/MSC/
determine whether a candidate site is in a hardcopy.htm>.
100-year floodplain. Siting a waste manage-
ment unit in a 100-year floodplain increases Additional information can be found on
the likelihood of floods inundating the unit, flood insurance rate maps in FEMA’s publica-
increases the potential for damage to liner sys- tion How to Read a Flood Insurance Rate Map
tems and support components (e.g., leachate (visit: <www.fema.gov/nfip/ readmap.htm>).
collection and removal systems or other unit FEMA also publishes The National Flood
structures), and presents operational concerns. Insurance Program Community Status Book
This, in turn, creates environmental and which lists communities with flood insurance
human health and safety concerns, as well as rate maps or floodway maps. Floodplain maps
legal liabilities. It can also be very costly to can also be obtained through the US
build a unit to withstand a 100-year flood Geological Survey (USGS); National Resources
without washout of waste or damage to the Conservation Service (NRCS); the Bureau of
unit, or to reconstruct a unit after such a Land Management; the Tennessee Valley
flood. Further, locating your unit in a flood- Authority; and state, local, and tribal agencies.2
plain can exacerbate the damaging effects of a Note that river channels shown in flood-
flood, both upstream and downstream, by plain maps can change due to hydropower or
reducing the temporary water storage capacity flood control projects. As a result, some flood-
of the floodplain. As such, it is preferable to plain boundaries might be inaccurate. If you
locate potential sites outside the 100-year suspect this to be the case, consult recent aeri-
floodplain. al photographs to determine how river chan-
nels have been modified.
2
Copies of flood maps from FEMA are available at Map Service Center, P.O. Box 1038, Jessup, MD 20794-
1038, by phone 800 358-9616, or the Internet at <www.fema.gov/nfip/readmap.htm>.
4-4
Getting Started—Considering the Site
B. Wetlands
Wetlands, which include swamps, marshes,
and bogs, are vital and delicate ecosystems.
They are among the most productive biologi-
cal communities on earth and provide habitat
for many plants and animals. The U.S. Fish
Knowing the behavior of waters at their and Wildlife Service estimates that up to 43
peak flood level is important for determin- percent of all endangered or threatened
ing whether waste will wash out. species rely on wetlands for their survival.5
Riprap (rock cover) reduces stream channel erosion (left) and gabions (crushed rock encased
in wire mesh) help stabilize erodible slopes (right).
Sources: U.S. Department of the Interior, Office of Surface Mining (left); The Construction
Site—A Directory To The Construction Industry (right).
5
From EPA’s Wetlands Web site, Values and Functions of Wetlands factsheet, <www.epa.gov/owow/
wetlands/facts/fact2.html>.
4-6
Getting Started—Considering the Site
Different types of wetlands: spruce bog (left) and eco pond in the Florida Everglades (right).
6
For the full text of the Clean Water Act, including Section 404, visit the U.S. House of Representatives
Internet Law Library Web site at <uscode.house.gov/download.htm>, under Title 33, Chapter 26.
4-7
Getting Started—Considering the Site
compliance with the guidelines established state, or local permits would be a violation of
under Section 404, all permit applicants must: many laws. It might be possible to learn the
extent of wetlands without performing a new
• Take steps to avoid wetland impacts
delineation, since many wetlands have previ-
where practicable.
ously been mapped. The first step, therefore,
• Minimize impacts to wetlands where should be to determine whether wetlands
they are unavoidable. information is available for your area.
• Compensate for any remaining, At the federal level, four agencies are prin-
unavoidable impacts by restoring or cipally involved with wetlands identification
creating wetlands. and delineation: USACE, EPA, the U.S. Fish
The EPA and USACE jointly administer a and Wildlife Service (FWS), and National
review process to issue permits for regulated Resource Conservation Service (NRCS). EPA
activities. For projects with potentially signifi- also has a Wetlands Information Hotline (800
cant impacts, an individual permit is usually 832-7828) and a wetlands Web site at <www.
required. For most discharges with only mini- epa.gov/owow/wetlands> which provides
mal adverse effects, USACE may allow appli- information about EPA’s wetlands program;
cants to comply with existing general facts about wetlands; the laws, regulations,
permits, which are issued on a nationwide, and guidance affecting wetlands; and science,
regional, or statewide basis for particular education, and information resources for wet-
activity categories as a means to expedite the lands. The local offices of NRCS (in agricul-
permitting process. In making permitting tural areas) or regional USACE Engineer
decisions, the agencies will consider other Divisions and Districts <www.usace.army.
federal laws that might restrict placement of mil/divdistmap.html> might know whether
waste management units in wetlands. These wetlands in the vicinity of the potential site
include the Endangered Species Act; the have already been delineated.
Migratory Bird Conservation Act; the Coastal Additionally, FWS maintains the National
Zone Management Act; the Wild and Scenic Wetlands Inventory (NWI) Center,7 from
Rivers Act; the Marine Protection, Research which you can obtain wetlands mapping for
and Sanctuaries Act; and the National much of the United States. This mapping,
Historic Preservation Act. however, is based on aerial photography,
which is not reliable for specific field deter-
How is it determined if a minations. If you have recently purchased
prospective site is in a wetland? your site, you also might be able to find out
As a first step, determine if the prospective from the previous property owner whether
site meets the definition of a wetland. If the any delineation has been completed that
prospective site does not appear to be a wet- might not be on file with these agencies. Even
land, then no further exploration is necessary. if existing delineation information for the site
If it is uncertain whether the prospective site is found, it might still be prudent to contact a
is a wetland, then several sources are avail- qualified wetlands consultant to verify the
able to help you make this determination and wetland boundaries, especially if the delin-
define the boundaries of the wetland. eation is not a field determination or is more
Although this can be a challenging process, it than a few years old.
will help you avoid future liability since fill- If the existence of a wetland is uncertain,
ing a wetland without the appropriate federal, you should obtain a wetlands delineation.
7
To contact NWI, write to National Wetlands Inventory Center, 9720 Executive Center Drive, Suite 101,
Monroe Building, St. Petersburg, FL 33702, call 727 570-5400, or fax 727 570-5420. For additional
4-8 information online or to search for maps of your area, visit: <www.nwi.fws.gov>.
Getting Started—Considering the Site
This procedure should be performed only by ing the presence and location of hydrophytic
an individual with experience in performing a vegetation (i.e., plants that are adapted for life
wetlands delineation8 using standard delin- in saturated soils), wetland hydrology, and
eation procedures or applicable state or local hydric soils is discussed.
delineation standards. The delineation proce-
dure, with which you should become familiar What can be done if a
before hiring a delineator, involves collecting prospective site is in a wetland?
maps, aerial photographs, plant data, soil sur- Before constructing a waste management
veys, stream gauge data, land use data, and unit in a wetland area, consider whether you
other information. Note that it is mandatory can locate the unit elsewhere. If an alternative
that wetlands delineation for CWA Section location can be identified, strongly consider
404 permitting purposes be conducted in pursuing such an option, as required by
accordance with the 1987 U.S. Army Corps of Section 404 of the CWA. Because wetlands
Engineers Wetlands Delineation Manual9 are important ecosystems that should be pro-
(USACE, 1991). The manual provides guide- tected, identification of practicable location
lines and methods for determining whether alternatives is a necessary first step in the sit-
an area is a wetland for purposes of Section ing process. Even if no viable alternative loca-
404. A three-parameter approach for assess-
NWI wetland resource maps like this one show the locations of various different types of
wetlands and are available for many areas.
Source: NWI web site, sample GIS Think Tank maps page, <wetlands.fws.gov/>.
8
Currently, there is no federal certification program. In March 1995, USACE proposed standards for a
Wetlands Delineator Certification Program (WDCP), but the standards have not been finalized. If the
WDCP standards are finalized and implemented, you should use WDCP-certified wetland consultants.
9
The 1987 manual can be ordered from the National Technical Information Service (NTIS) at 703 605-
6000 or obtained online at <www.wes.army.mil/el/wetlands/wlpubs.html>. 4-9
Getting Started—Considering the Site
tions are identified, it might be beneficial to the grains are saturated, the saturated granu-
keep a record of the alternatives investigated, lar material turns into a viscous fluid, a
noting why they were not acceptable. Such process referred to as liquefaction. This
records might be useful during the interac- diminishes the bearing capacity of the soils
tion between facilities, states, and members of and can lead to foundation and slope failures.
the community.
To avoid these hazards, do not build or
If no alternatives are available, you should expand a unit within 200 feet of an active
consult with state and local regulatory agen- fault. If it is not possible to site a unit more
cies concerning wetland permits. Most states than 200 feet from an active fault, you should
operate permitting programs under the CWA, design the unit to withstand the potential
and state authorities can guide you through ground movement associated with the fault
the permitting process. To obtain a permit, area. A fault is considered active if there has
the state might require that the unit facility been movement along it within the last 10,000
manager assess wetland impacts and then: to 12,000 years.
• Prevent contamination from leachate How is it determined if a
and runoff.
prospective site is in a fault area?
• Minimize dewatering effects. A series of USGS maps, Preliminary Young
• Reduce the loss of wetland acreage. Fault Maps, Miscellaneous Field Investigation
916, identifies active faults.10 These maps,
• Protect the waste management unit however, might not be completely accurate
against settling. due to recent shifts in fault lines. If a prospec-
tive site is well outside the 200 foot area of
C. Active Fault Areas concern, no fault area considerations exist. If
it is unclear how close a prospective site is to
Faults occur when stresses in a geologic an active fault, further evaluation will be nec-
material exceed its ability to withstand these essary. A geologic reconnaissance of the site
forces. Areas surrounding faults are subject to and surrounding areas can be useful in verify-
earthquakes and ground failures, such as ing that active faults do not exist at the site.
landslides or soil liquefaction. Fault move-
ment can directly weaken or destroy struc- If a prospective site is in an area known or
tures, or seismic activity associated with suspected to be prone to faulting, you should
faulting can cause damage to structures conduct a fault characterization to determine
through vibrations. Structural damage to the if the site is near a fault. A characterization
waste management unit could result in the includes identifying linear features that sug-
release of contaminants. In addition, fault gest the presence of faults within a 3,000-foot
movement might create avenues to ground- radius of the site. Such features might be
water supplies, increasing the risk of ground- shown or described on maps, aerial pho-
water contamination. tographs,11 logs, reports, scientific literature,
or insurance claim reports, or identified by a
Liquefaction is another common problem detailed field reconnaissance of the area.
encountered in areas of seismic activity. The
vibrating motions caused by an earthquake If the characterization study reveals faults
tend to rearrange the sand grains in soils. If within 3,000 feet of the proposed unit or lat-
10
Information about ordering these maps is available by calling 888 ASK-USGS or 703 648-6045.
11
The National Aerial Photographic Program (NAPP) and the National High Altitude Program (NHAP),
both administered by USGS, are sources of aerial photographs. To order from USGS, call 605 594-
6151. For more information, see <edc.usgs.gov/nappmap.html>. Local aerial photography firms and
4-10
surveyors are also good sources of information.
Getting Started—Considering the Site
4-11
Getting Started—Considering the Site
Table 1
Examples of Improvement Techniques for Liquefiable Soil Foundation Conditions
Method Principle Most Suitable Soil Applications
Conditions/Types
Blasting Shock waves and vibrations cause Saturated, clean sands; partly Induce liquefaction in controlled and
limited liquefaction, displacement, saturated sands and silts after limited stages and increase relative density
remolding, and settlement to higher flooding. to potentially nonliquefiable range.
density.
Vibrocompaction Densification by vibration and Cohesionless soils with less Induce liquefaction in controlled and
compaction of backfill material of sand than 20 percent fines. limited stages and increase relative density
or gravel. to nonliquefiable condition. The dense
column of backfill provides (a) vertical
support, (b) drainage to relieve pore water
pressure, and (c) shear resistance in hori-
zontal and inclined directions. Used to
stabilize slopes and strengthen potential
failure surfaces.
Compaction piles Densification by displacement of pile Loose sandy soils; partly Useful in soils with fines. Increases relative
volume and by vibration during driving; saturated clayey soils; loess. density to nonliquefiable condition.
increase in lateral effective earth Provides shear resistance in horizontal and
pressure. inclined directions. Used to stabilize
slopes and strengthen potential failure
surfaces.
Displacement and Highly viscous grout acts as radial All soils. Increase in soil relative density and
compaction grout hydraulic jack when pumped in under horizontal effective stress. Reduce
high pressure. liquefaction potential. Stabilize the ground
against movement.
Mix-in-place piles Lime, cement, or asphalt introduced Sand, silts, and clays; all soft Slope stabilization by providing shear
and walls through rotating auger or special in- or loose inorganic soils. resistance in horizontal and inclined
place mixer. directions, which strengthens potential
failure surfaces or slip circles. A wall could
be used to confine an area of liquefiable
soil.
Heavy tamping Repeated application of high- intensity Cohesionless soils best; other Suitable for some soils with fines; usable
(dynamic impacts at surface. types can also be improved. above and below water. In cohesionless
compaction) soils, induces liquefaction in controlled
and limited stages and increases relative
density to potentially nonliquefiable range.
Source: RCRA Subtitle D (258) Seismic Design Guidance for Municipal Solid Waste Landfill Facilities. (EPA, 1995c).
12
Loess is a wind-deposited, moisture-deficient silt that tends to compact when wet.
4-12
Getting Started—Considering the Site
loess and saturated sand as well, because seis- of ground motion at your site. This can help
mic shocks can liquefy them, causing sudden you determine if the structural integrity of the
collapse of structures. Similar effects are possi- unit is susceptible to damage from ground
ble in sensitive cohesive soils when natural motion.
moisture exceeds the soil’s liquid limit. For a
For waste management unit siting purpos-
discussion of liquid limits, refer to the “Soil
es, use USGS’ recently revised Peak
Properties” discussion in Chapter 7, Section B
Acceleration (%g) with 2 % Probability of
– Designing and Installing Liners. Earthquake-
Exceedance in 50 Years maps available at
induced ground vibrations can also compact
<geohazards.cr.usgs.gov/eq/hazmapsdoc/
loose granular soils. This could result in large
junecover.html>. It is important to note that
uniform or differential settlements at the
ground motion values having a 2 percent
ground surface.
probability of exceedance in 50 years are
How is it determined if a approximately the same as those having 10
percent probability of being exceeded in 250
prospective site is in a seismic years. According to USGS calculations, the
impact zone? annual exceedance probabilities of these two
If a prospective site is in an area with no differ by about 4 percent (for a more complete
history of earthquakes, then seismic impact discussion visit: <geohazards.cr.usgs.
zone considerations might not exist. If it is gov/eq/faq/parm08.html>).
unclear whether the area has a history of seis-
If a site is or might be in a seismic impact
mic activity, then further evaluation will be
zone, it is useful to analyze the effects of seis-
necessary. As a first step, consult the USGS
mic activity on soils in and under the unit.
field study map series MF-2120, Probabilistic
Computer software programs are available that
Earthquake Acceleration and Velocity Maps for
can evaluate soil liquefaction potential
the United States and Puerto Rico.13 These maps
(defined in Section C of this chapter). LIQ-
provide state- and county-specific information
UFAC, a software program developed by the
about seismic impact zones. Additional infor-
Naval Facilities Engineering Command in
mation is available from the USGS National
Washington, DC, can calculate safety factors
Earthquake Information Center (NEIC),14
for each soil layer in a given soil profile and
which maintains a database of known earth-
the corresponding one dimensional settle-
quake and fault zones. Further information
ments due to earthquake loading.
concerning the USGS National Seismic Hazard
Mapping Project can be accessed at <geohaz- What can be done if a
ards.cr.usgs.gov/eq>. USGS’s Web site also prospective site is in a seismic
allows you to find ground motion hazard
parameters (including peak ground accelera- impact zone?
tion and spectra acceleration) for your site by If a waste management unit cannot be sited
entering a 5 digit ZIP code outside a seismic impact zone, structural com-
<eqint.cr.usgs.gov/eq/html/zipcode. ponents of the unit—including liners, leachate
shtml>, or a latitude-longitude coordinate collection and removal systems, and surface-
pair <eqint.cr.usgs.gov/eq/html/lookup. water control systems—should be designed to
shtml>. The USGS Web site explains how resist the earthquake-related stresses expected
these values can be used to determine the in the local soil. You should consult profes-
probability of excedance for a particular level sionals experienced in seismic analysis and
13
For information on ordering these maps, call 888 ASK-USGS, write to USGS Information Services, Box
25286, Denver, CO 80225, or fax 303 202-4693. Online information is available at
<ask.usgs.gov/products.html>.
14
To contact NEIC, call 303 273-8500, write to United States Geological Survey, National Earthquake
Information Center, Box 25046, DFC, MS 967, Denver, CO 80225, fax 303 273-8450, or e-mail
sedas@neic.cr.usgs.gov. For online information, visit: <neic.usgs.gov>. 4-13
Getting Started—Considering the Site
design to ensure that your unit is designed the foundation components. Placing too
appropriately. To determine the potential much waste in one area of the unit can lead
effects of seismic activity on a structure, the to catastrophic shifting during an earthquake
seismic design specialist should evaluate soil or heavy seismic activity. Shifting of this
behavior with respect to earthquake intensity. nature can cause failure of crucial system
This evaluation should account for soil components or of the unit in general.
strength, degree of compaction, sorting (orga-
In addition, seismic impact zones have
nization of the soil particles), saturation, and
design issues in common with fault areas,
peak acceleration of the potential earthquake.
especially concerning soil liquefaction and
After conducting an evaluation of soil earthquake-related stresses. To address lique-
behavior, choose appropriate earthquake pro- faction, consider employing the soil improve-
tection measures. These might include shal- ment techniques described in Table 1.
lower slopes, dike and runoff control designs Treating liquefiable soils in the vicinity of the
using conservative safety factors, and contin- unit will improve foundation stability and
gency plans or backup systems for leachate help prevent uneven settling or possible col-
collection if primary systems are disrupted. lapse of heavily saturated soils underneath or
Unit components should be able to withstand near the unit.
the additional forces imposed by an earth-
To protect against earthquake-related
quake within acceptable margins of safety.
stresses, consider installing redundant liners
Additionally, well-compacted, cohesionless and special leachate collection and removal
embankments or reasonably flat slopes in system components, such as secondary liner
insensitive clay (clay that maintains its com- systems, composite liners, and leak detection
pression strength when remolded) are less systems combined with a low permeability
likely to fail under moderate seismic shocks soil layer. These measures function as back-
(up to 0.15 g - 0.20 g). Embankments made ups to the primary containment and collec-
of insensitive, cohesive soils founded on tion systems and provide a greater margin of
cohesive soils or rock can withstand even safety for units during possible seismic stress-
greater seismic shocks. For earthen embank- es. Examples of special leachate systems
ments in seismic regions, consider designing include high-strength, flexible materials for
the unit with internal drainage and core leachate containment systems; geomembrane
materials resistant to fracturing. Also, prior to liner systems underlying leachate contain-
or during unit construction in a seismic ment systems; and perforated polyvinyl chlo-
impact zone, you should evaluate excavation ride or high-density polyethylene piping in a
slope stability to determine the appropriate bed of gravel or other permeable material.
grade of slopes to minimize potential slip.
For landfills and waste piles, using shal- E. Unstable Areas
lower waste side slopes is recommended, as
steep slopes are more vulnerable to slides Siting in unstable areas should be avoided
and collapse during earthquakes. Use fill because these locations are susceptible to nat-
sequencing techniques that avoid concentrat- urally occurring or human-induced events or
ing waste in one area of the unit for an forces capable of impairing the integrity of a
extended period of time. This prevents waste waste management unit. Naturally occurring
pile side slopes from becoming too steep and unstable areas include regions with poor soil
unstable and alleviates differential loading of foundations, regions susceptible to mass
movement, or regions containing karst ter-
4-14
Getting Started—Considering the Site
rain, which can include hidden sinkholes. overlying caverns can collapse suddenly,
Unstable areas caused by human activity can resulting in sinkholes that can be more than
include areas near cut or fill slopes, areas 100 feet deep and 300 feet wide.
with excessive drawdown of ground water,
and areas where significant quantities of oil How is it determined if a
or natural gas have been extracted. If it is prospective site is in an
necessary to site a waste management unit in unstable area?
an unstable area, technical and construction If a stability assessment has not been per-
techniques should be considered to mitigate formed on a potential site, you should have a
against potential damage. qualified professional conduct one before
The three primary types of failure that can designing a waste management unit on the
occur in an unstable area are settlement, loss prospective site. The qualified professional
of bearing strength, and sinkhole collapse. should assess natural conditions, such as soil
Settlement can result from soil compression if geology and geomorphology, as well as
your unit is, or will be located in, an unstable human-induced surface and subsurface fea-
area over a thick, extensive clay layer. The tures or events that could cause differential
unit’s weight can force water from the com- ground settlement. Naturally unstable condi-
pressible clay, compacting it and allowing the tions can become more unpredictable and
unit to settle. Settlement can increase as destructive if amplified by human-induced
waste volume increases and can result in changes to the environment. If a unit is to be
structural failure of the unit if it was not built at an assessed site that exhibits stability
properly engineered. Settlement beneath a problems, tailor the design to account for any
waste management unit should be assessed instability detected. A stability assessment
and compared to the elongation strength and typically includes the following steps:
flexibility properties of the liner and leachate Screen for expansive soils. Expansive
collection pipe system. Even small amounts soils can lose their ability to support a foun-
of settlement can seriously damage leachate dation when subjected to certain natural or
collection piping and sumps. A unit should human-induced events, such as heavy rain or
be engineered to minimize the impacts of set- explosions. Expansive soils usually are clay-
tlement if it is, or will be in an unstable area. rich and, because of their molecular struc-
Loss of bearing strength is a failure mode ture, tend to swell and shrink by taking up
that occurs in soils that tend to expand and and releasing water. Such soils include smec-
rapidly settle or liquefy. Soil contractions and tite (montmorillonite group) and vermiculite
expansions can increase the risk of leachate or clays. In addition, soils rich in white alkali
waste release. Another example of loss of bear- (sodium sulfate), anhydrite (calcium sulfate),
ing strength occurs when excavation near the or pyrite (iron sulfide) can also swell as water
unit reduces the mass of soil at the toe of the content increases. These soils are more com-
slope, thereby reducing the overall strength mon in the arid western states.
(resisting force) of the foundation soil. Check for soil subsidence. Soils subject
Catastrophic collapse in the form of sink- to rapid subsidence include loesses, uncon-
holes can occur in karst terrain. As water, solidated clays, and wetland soils. Unconsol-
especially acidic water, percolates through idated clays can undergo considerable
limestone, the soluble carbonate material dis- compaction when oil or water is removed.
solves, leaving cavities and caverns. Land Similarly, wetland soils, which by their
4-15
Getting Started—Considering the Site
Sinkholes, like this one that occurred just north of Orlando, Florida in 1981, are a risk of
development in Karst terrain. Left: aerial view (note baseball diamond for scale); right:
ground-level view. Photos courtesy of City of Winter Park, Florida public relations office.
nature are water-bearing, are also subject to the USGS15 and state specific geological maps
subsidence when water is withdrawn. can be reviewed to identify karst areas.
Look for areas subject to mass move- Scan for evidence of excessive ground-
ment or slippage. Such areas are often situ- water drawdown or oil and gas extraction.
ated on slopes and tend to have rock or soil Removing underground water can increase
conditions conducive to downhill sliding. the effective overburden on the foundation
Examples of mass movements include soils underneath the unit. Excessive draw-
avalanches, landslides, and rock slides. Some down of water might cause settlement or
sites might require cutting or filling slopes bearing capacity
during construction. Such activities can cause failure on the
existing soil or rock to slip. foundation soils.
Extraction of oil
Search for karst terrain. Karst features
or natural gas
are areas containing soluble bedrock, such as
can have similar
limestone or dolomite, that have been dis-
effects.
solved and eroded by water, leaving charac-
teristic physiographic features including Investigate
sinkholes, sinking streams, caves, large the geotechnical
springs, and blind valleys. The principal con- and geological
cern with karst terrains is progressive or cata- characteristics
strophic subsurface failure due to the of the site. It is
presence of sinkholes, solution cavities, and important to
subterranean caverns. Karst features can also establish soil
hamper detection and control of leachate, strengths and
which can move rapidly through hidden con- other engineer-
Subsidence, slippage, and
duits beneath the unit. Karst maps, such as ing properties. A
other kinds of slope failure
Engineering Aspects of Karst, Scale 1:7,500,000, geotechnical
can damage structures.
Map No. 38077-AW-NA-07M-00, produced by engineering con-
15 For information on ordering this map, call 888 ASK-USGS, write USGS Information Services,
Box 25286, Denver, CO 80255, or fax 303 202-4693. Online information is available at
4-16 <www-atlas.usgs.gov/atlasmap.html>.
Getting Started—Considering the Site
For example, to safeguard the structural You should incorporate adequate engineer-
integrity of side slopes in an unstable area, ing controls into any waste management unit
reduce slope height, flatten slope angle, exca- located in a karst terrain. In areas where karst
vate a bench in the upper portion of the slope, development is minor, loose soils overlying
or buttress slopes with compacted earth or rock the limestone can be excavated or heavily
fill. Alternatively, build retaining structures, compacted to achieve the needed stability.
such as retaining walls or slabs and piles. Other Similarly, in areas where the karst voids are
approaches include the use of geotextiles and relatively small, the voids can be filled with
geogrids to provide additional strength, wick slurry cement grout or other material.
and toe drains to relieve excess pore pressures, Engineering solutions can compensate for
grouting, and vacuum and wellpoint pumping the weak geologic structures by providing
to lower ground- water levels. In addition, sur- ground supports. For example, ground modi-
face drainage can be controlled to decrease fications, such as grouting or reinforced raft
infiltration, thereby reducing the potential for foundations, could compensate for a lack of
mud and debris slides. ground strength in some karst areas. Raft
Additional engineering concerns arise in constructions, which are floating foundations
the case of waste management units in areas consisting of a concrete footing extending
containing karst terrain. The principal con- over a very large area, reduce and evenly dis-
cern with karst terrains is progressive or cata- tribute waste loads where soils have a low
strophic subsurface failure due to the bearing capacity or where soil conditions are
presence of sinkholes, solution cavities, and variable and erratic. Note, however, that raft
foundations might not always prevent the
4-17
Getting Started—Considering the Site
4-18
Getting Started—Considering the Site
Topographic maps available from USGS are the disposal and storage areas when practical
also suitable for determining airport locations. or technically feasible.
If necessary, FAA can provide information on
the location of all public-use airports. In accor-
dance with FAA guidance, if a new unit or an G. Wellhead Protection
expansion of an existing unit will be within 5 Areas
miles of the end of a public-use airport run- Wellhead protection involves protecting
way, the affected airport and the regional FAA the ground-water resources that supply pub-
office should be notified to provide them an lic drinking water systems. A wellhead pro-
opportunity for review and comment. tection area (WHPA) is the area most
What can be done if a susceptible to contamination surrounding a
wellhead. WHPAs are designated and often
prospective site is in an regulated to prevent public drinking water
airport vicinity? sources from becoming contaminated. The
If a proposed waste management unit or a technical definition, delineation, and regula-
lateral expansion is to be located within tion of WHPAs vary from state to state. You
10,000 feet of an airport used by jet aircraft should contact your state or local regulatory
or within 5,000 feet of an airport used only agency to determine what wellhead protec-
by piston-type aircraft, design and operate tion measures are in place near prospective
your unit so it does not pose a bird hazard to sites. Section II of this chapter provides
aircraft. For above-ground units, design and examples of how some states specify mini-
operate your unit so it does not interfere mum allowable distances between waste
with flight patterns. If it appears that height management units and public water supplies,
is a potential concern, consider entrenching as well as drinking water wells. Locating a
the unit or choosing a site outside the air- waste management unit in a WHPA can cre-
port’s flight patterns. Most nonhazardous ate a potential avenue for drinking water con-
industrial waste management units do not tamination through accidental release of
usually manage wastes that are attractive leachate, contaminated runoff, or waste. In
food sources for birds, but if your unit han- addition, some states might have additional
dles waste that potentially attracts birds, take restrictions for areas in designated “sole
precautions to prevent birds from becoming source aquifier” systems.
an aircraft hazard. Discourage congregation
of birds near your unit by preventing water
How is it determined if a
from collecting on site; eliminating or cover- prospective site is in a wellhead
ing wastes that might serve as a source of protection area?
food; using visual deterrents, including real- A list of state wellhead protection program
istic models of the expected scavenger birds’ contacts is available on EPA’s Web site at
natural predators; employing sound deter- <www.epa.gov/ogwdw/safewater/source/
rents, such as cannon sounds, distress calls contacts.html>. Also, USGS, NRCS, local
of scavenger birds, or the sounds of the water authorities, and universities can pro-
birds’ natural predators; removing nesting vide maps and further expertise that can help
and roosting areas (unless such removal is you to identify WHPAs. If there is uncertainty
prohibited by the Endangered Species Act); regarding the proximity of the prospective
or constructing physical barriers, such as a site to a WHPA, contact the appropriate state
canopy of fine wires or nets strung around or local regulatory agency.
4-19
Getting Started—Considering the Site
4-20
Getting Started—Considering the Site
A. Recommended Buffer
Zones
You should check with state and local offi-
cials to determine what buffer zones might
apply to your waste management unit. Areas
Many nearby areas and land uses, such as for which buffer zones are recommended
schools, call for consideration of buffer zones. include property boundaries, drinking water
wells, other sources of water, and adjacent
management unit’s design, you select a site houses or buildings.
where an adequate distance separates the bot- Property boundaries. To minimize
tom of a unit from the ground-water table. adverse effects on adjacent properties, consid-
(See the appendix for a summary of these er incorporating a buffer zone or separation
minimum separation distances.)16 In the event distance into unit design. You should consid-
of a release, this separation distance will er planting trees or bushes to provide a nat-
allow for corrective action and natural attenu- ural buffer between your unit and adjacent
ation to protect ground water.17 properties.
Additionally, in the event of an unplanned Drinking water wells, surface-water
release, an adequate buffer zone will allow bodies, and public water supplies. Locating
time for remediation activities to control con- a unit near or within the recharge area for
taminants before they reach sensitive areas. sole source aquifers and major aquifers,
Buffer zones also provide additional protec- coastal areas, surface-water bodies, or public
tion for drinking water supplies. Drinking water supplies, such as a community well or
water supplies include ground water, individ- water treatment facility, also raises concerns.
ual and community wells, lakes, reservoirs, Releases from a waste management unit can
and municipal water treatment facilities. pose serious threats to human health not only
Finally, buffer zones help maintain good where water is used for drinking, but also
relations with the surrounding community by where surface waters are used for recreation.
16
A detailed discussion of technical considerations concerning the design and installation of liner sys-
tems, both in situ soil liners and synthetic liners, is included in Chapter 7, Section B – Designing and
Installing Liners.
17
Natural attenuation can be defined as chemical and biological processes that reduce contaminant con- 4-21
centrations.
Getting Started—Considering the Site
Houses or buildings. Waste management Park lands. A buffer between your unit
units can present noise, odor, and dust prob- and park boundaries helps maintain the aes-
lems for residents or businesses located on thetics of the park land. Park lands provide
adjacent property, thereby diminishing prop- recreational opportunities and a natural
erty values. Additionally, proximity to proper- refuge for wildlife. Locating a unit too close
ty boundaries can invite increased to these areas can disrupt recreational quali-
trespassing, vandalism, and scavenging. ties and natural wildlife patterns.
Public roads. A buffer zone will help
B. Additional Buffer Zones reduce unauthorized access to the unit,
reduce potential odor concerns, and improve
There are several other areas for which to aesthetics for travelers on the nearby road.
consider establishing buffer zones, including
critical habitats, park lands, public roads, and Historic or archaeological sites. A waste
historic or archaeological sites. management unit located in close proximity
to one of these sites can adversely impact the
Critical habitats. These are geographical aesthetic quality of the site. These areas
areas occupied by endangered or threatened include historic settlements, battlegrounds,
species. These areas contain physical or bio- cemeteries, and Indian burial grounds. Also
logical features essential to the proliferation of check whether a prospective site itself has
the species. When designing a unit near a historical or archaeological significance.
critical habitat, it is imperative that the criti-
cal habitat be conserved. A buffer zone can
help prevent the destruction or adverse modi-
fication of a critical habitat and minimize
harm to endangered or threatened species.18
18
For the full text of the Endangered Species Act, visit the U.S. House of Representatives Internet Law
Library Web site at <uscode.house.gov/download.htm>, under Title 16, Chapter 35.
4-22
Getting Started—Considering the Site
regulations that specify buffer zones for your be brought by local authorities or nearby
unit. For units located near any sensitive property owners.
areas as described in this section, consider
In situations where land use and zoning
measures to minimize any possible health,
restrictions might cause difficulties in expand-
environmental, and nuisance impacts.
ing or siting a unit, work closely with local
authorities to learn about local land use and
zoning restrictions and minimize potential
III. Local Land Use problems. Misinterpreting or ignoring such
restrictions can cause complications with
and Zoning intended development schedules or designs.
Considerations In many cases, the use of vegetation, fences,
or walls to screen your activities can reduce
In addition to location and buffer zone impacts on nearby properties. In addition, it
considerations, become familiar with any might be possible to request amendments,
local land use and zoning requirements. Local rezonings, special exceptions, or variances to
governments often classify the land within restrictions. These administrative mechanisms
their communities into areas, districts, or allow for flexibility in use and development of
zones. These zones can represent different land. Learning about local requirements as
use categories, such as residential, commer- early as possible in the process will maximize
cial, industrial, or agricultural. You should the time available to apply for variances or
consider the compatibility of a planned new rezoning permits, or to incorporate screening
unit or a planned lateral expansion with near- into the plans for your unit.
by existing and future land use, and contact
local authorities early in the siting process.
Local planning, zoning, or public works offi-
cials can discuss with you the development of IV. Environmental
a unit, compliance with local regulations, and
available options. Local authorities might
Justice
impose conditions for protecting adjacent
properties from potential adverse impacts
Considerations
In the past several years, there has been
from the unit.
growing recognition from communities and
Addressing local land use and zoning federal and state governments that some
issues during the siting process can prevent socioeconomic and racial groups might bear a
these issues from becoming prominent con- disproportionate burden of adverse environ-
cerns later. Land use and zoning restrictions mental effects from waste management activi-
often address impacts on community and ties. President Clinton issued Executive Order
recreational areas, historical areas, and other 12898, Federal Actions to Address
critical areas. You should consider the prox- Environmental Justice in Minority
imity of a new unit or lateral expansion to Populations and Low-Income Populations, on
such areas and evaluate any potential adverse February 11, 1994.19 To be consistent with
effects it might have on these areas. For the definition of environmental justice in this
example, noise, dust, fumes, and odors from executive order, you should identify and
construction and operation of a unit could be address, as appropriate, disproportionately
considered a nuisance and legal action could high and adverse human health or environ-
mental effects of waste management pro-
19
For the full text of Presidential Executive Order No. 12898 and additional information concerning
environmental justice issues go to EPA’s Web site at <es.epa.gov/program/iniative/justice/
justice.html>. 4-23
Getting Started—Considering the Site
grams, policies, and activities on minority Tailor the public involvement activities
and low-income populations. to the specific needs. Good public involve-
ment programs are site-specific—they take
One of the criticisms made by advocates of
into account the needs of the facility, neigh-
environmental justice is that local communi-
borhood, and state. There is no such thing
ties endure the potential health and safety
as a “one-size-fits-all” public involvement
risks associated with waste management
program. Listening to each other carefully
units without enjoying any of the economic
will identify the specific environmental jus-
benefits. During unit siting or expansion,
tice concerns and determine the involve-
address environmental justice concerns in a
ment activities most appropriate to address
manner that is most appropriate for the oper-
those needs.
ations, the community, and the state or tribal
government. Provide interpreters for public meetings.
Interpreters can be used to ensure the infor-
You should look for opportunities to mini-
mation is exchanged. Provide interpreters, as
mize environmental impacts, improve the
needed, for the hearing impaired and for any
surrounding environment, and pursue
languages, other than English, spoken by a
opportunities to make the waste management
significant percentage of the audience.
Provide multilingual fact sheets and
other information. Public notices and fact
sheets should be distributed in as many lan-
guages as necessary to ensure that all inter-
ested parties receive necessary information.
Fact sheets should be available for the visual-
ly impaired in the community on tape, in
large print, or braille.
Promote the formation of a community/
state advisory panel to serve as the voice of
the community. The Louisiana Department
of Environmental Quality, for example,
facility an asset to the community. When
encourages the creation of environmental jus-
planning these opportunities, it is beneficial
tice panels comprised of community mem-
to maintain a relationship with all involved
bers, industry, and state representatives. The
parties based on honesty and integrity, utilize
panels meet monthly to discuss environmen-
cross-cultural formats and exchanges, and
tal justice issues and find solutions to any
recognize industry, state, and local knowl-
concerns identified by the group.
edge of the issues. It is also important to take
advantage of all potential opportunities for
developing partnerships.
Examples of activities that incorporate
environmental justice issues include tailoring
activities to specific needs; providing inter-
preters, if appropriate; providing multilingual
materials; and promoting the formation of a
community/state advisory panel.
4-24
Getting Started—Considering the Site
4-25
Getting Started—Considering the Site
4-26
Getting Started—Considering the Site
Resources
Bagchi, A. 1994. Design, Construction, and Monitoring of Landfills. John Wiley & Sons Inc.
Das, B. M. 1990. Principles of Geotechnical Engineering. 2nd ed. Boston: PWS-Kent Publishing Co.
Federal Emergency Management Agency. How to Read a Flood Insurance Map. Web Site:
<www.fema.gov/nfip/readmap.htm>
Federal Emergency Management Agency. The National Flood Insurance Program Community Status Book.
Web Site: <www.fema.gov/nfip/>
Federal Emergency Management Agency. 1995. The Zone A Manual: Managing Floodplain Development in
Approximate Zone A Areas. FEMA 265.
Illinois Department of Energy and Natural Resources. 1990. Municipal Solid Waste Management Options:
Volume II: Landfills.
Law, J., C. Leung, P. Mandeville, and A. H. Wu. 1996. A Case Study of Determining Liquefaction Potential of
a New Landfill Site in Virginia by Using Computer Modeling. Presented at WasteTech ’95, New Orleans, LA
(January).
Noble, George. 1992. Siting Landfills and Other LULUs. Technomic Publications.
Oregon Department of Environmental Quality. 1996. Wellhead Protection Facts. Web Site:
<www.deq.state.or.us/wq/groundwa/gwwell.htm>.
Texas Natural Resource Conservation Commission. 1983. Industrial Solid Waste Landfill Site Selection.
U.S. Army Corps of Engineers. 1995. Engineering and Design: Design and Construction of Conventionally
Reinforced Ribbed Mat Slabs (RRMS). ETL 1110-3-471.
U.S. Army Corps of Engineers. 1995. Engineering and Design: Geomembranes for Waste Containment
Applications. ETL 1110-1-172.
U.S. Army Corps of Engineers. 1992. Engineering and Design: Bearing Capacity of Soils. EM 1110-1-1905.
U.S. Army Corps of Engineers. 1992. Engineering and Design: Design and Construction of Grouted Riprap.
ETL 1110-2-334.
4-27
Getting Started—Considering the Site
Resources (cont.)
U.S. Army Corps of Engineers. 1991. 1987 U.S. Army Corps of Engineers Wetlands Delineation Manual.
HQUSACE.
U.S. Army Corps of Engineers. 1984. Engineering and Design: Use of Geotextiles Under Riprap. ETL
1110-2-286.
U.S. EPA. 2000a. Social Aspects of Siting RCRA Hazardous Waste Facilities. EPA530-K-00-005.
U.S. EPA. 2000b. Siting of Hazardous Waste Management Facilities and Public Opposition. EPAOSW-0-00-809.
U.S. EPA. 1997. Sensitive Environments and the Siting of Hazardous Waste Management Facilities.
EPA530-K-97-003.
U.S. EPA. 1995b. Decision-Maker’s Guide to Solid Waste Management, 2nd Ed. EPA530-R-95-023.
U.S. EPA. 1995c. RCRA Subtitle D (258) Seismic Design Guidance for Municipal Solid Waste Landfill
Facilities. EPA600-R-95-051.
U.S. EPA. 1995d. Why Do Wellhead Protection? Issues and Answers in Protecting Public Drinking Water
Supply Systems. EPA813-K-95-001.
U.S. EPA. 1993b. Solid Waste Disposal Facility Criteria: Technical Manual. EPA530-R-93-017.
U. S. EPA. 1992. Final Comprehensive State Ground-Water Protection Program Guidance. EPA100-R-93-001.
U. S. EPA. 1991. Protecting Local Ground-Water Supplies Through Wellhead Protection. EPA570-09-91-007.
U. S. EPA. 1988. Developing a State Wellhead Protection Program: A User’s Guide to Assist State Agencies
Under the Safe Drinking Water Act. EPA440-6-88-003.
U.S. Geological Survey. Preliminary Young Fault Maps, Miscellaneous Field Investigation 916.
4-28
Getting Started—Considering the Site
Resources (cont.)
U.S. Geological Survey. Probabilistic Acceleration and Velocity Maps for the United States and Puerto Rico.
Map Series MF-2120.
U.S. House of Representatives. 1996. Endangered Species Act. Internet Law Library. Web Site:
<uscode.house.gov/title_16.htm>.
University of Illinois Center for Solid Waste Management and Research, Office of Technology Transfer. 1990.
Municipal solid waste landfills: Volume II: Technical issues.
University of Illinois Center for Solid Waste Management and Research, Office of Technology Transfer. 1989.
Municipal Solid Waste Landfills: Vol. I: General Issues.
White House. Executive Order 12898 Federal Actions to Address Environmental Justice in Minority
Populations and Low-Income Populations.
4-29
Getting Started—Considering the Site
Table 1
State Buffer Zone Restrictions for Surface Impoundments
Buffer Zone Category Range of Values—minimum Most Common Value (number of
distance (number of states states with this common value)
with this common value)
Drinking Water Wells 1,200 to 1,320 feet (2) 1,200 feet (1)
1,320 feet (1)
Public Water Supply 500 to 1,320 feet (4) 1,320 feet (2)
Surface Water Body 100 to 1,320 feet (4) 100 feet (2)
4-30
Getting Started—Considering the Site
• Landfills. Table 2 presents the range of values and the most common state buffer zone
restrictions for landfills.
Table 2
State Buffer Zone Restrictions for Landfills
Buffer Zone Category Range of Values—minimum Most Common Value (number of
distance (number of states with states with this common value)
this common value)
Drinking Water Wells 500 to 1,320 feet (9) 500 feet (2)
600 feet (2)
1,200 feet (2)
Public Water Supply 400 to 5,280 feet (13) 1,200 feet (3)
Surface Water Body 100 to 2,000 feet (20) 100 feet (5)
1,000 feet (5)
4-31
Getting Started—Considering the Site
• Waste Piles. Table 3 presents the state buffer zone restrictions for waste piles. Of the
four states with buffer zone restrictions, only two states specified minimum distances.
Table 3
State Buffer Zone Restrictions for Waste Piles
Buffer Zone Category Range of Values-minimum Most Common Value (number of
distance (number of states states with this common value)
with this common value)
* If no liner or storage pad is used, then this state requires four feet between the waste and
the seasonal high water table.
4-32
Getting Started—Considering the Site
• Land Application.20 Table 4 presents the range of values and the most common state
buffer zone restrictions for land application.
Table 4
State Buffer Zone Restrictions for Land Application
Buffer Zone Category Range of Values-minimum Most Common Value (number of
distance (number of states with states with this common value)
this common value)
Drinking Water Wells 200 to 500 feet (2) 200 feet (1)
500 feet (1)
Public Water Supply 300 to 5,280 feet (3) 300 feet (1)
1,000 feet (1)
5,280 feet (1)
Surface Water Body 100 to 1,000 feet (5) 100 feet (2)
Critical Habitat No minimum distance set (2) No minimum distance set (2)
Soil Conditions Not on frozen, ice or snow (1) Not on frozen, ice or snow (1)
covered, or water saturated soils covered, or water saturated soils
20
In the review of state regulations performed to develop Table 5, it was not possible to distinguish
between units used for treatment and units where wastes are added as a soil amendment. It is recom-
mended that you consult applicable state agencies to determine which buffer zone restrictions are rele-
vant to your land application unit.
4-33
Getting Started—Considering the Site
Based on the review of state requirements, Table 5 presents the most common buffer zones
restrictions across all four unit types.
Table 5
Common Buffer Zone Restrictions Across All Four Unit Types
Buffer Zone Category Most Common Values
(total number of states for all unit types) (number of states with this common value)
4-34
Part II
Protecting Air Quality
Chapter 5
Protecting Air Quality
Contents
Resources ......................................................................................................................................................5-40
Figures:
Figure 1. Evaluating VOC Emission Risk ..................................................................................................5-13
Figure 2. Conceptual Site Diagram ............................................................................................................5-18
Figure 3. Emissions from WMU ................................................................................................................5-19
Figure 4. Forces That Affect Contaminant Plumes......................................................................................5-20
Figure 5. IWAIR Approach for Developing Risk or Protective Waste Concentrations ................................5-24
Figure 6. Screen 1, Method, Met Station, WMU ........................................................................................5-25
Figure 7. Screen 2, Wastes Managed ..........................................................................................................5-25
Tables:
Table 1. Industries for Which NSPSs Have Been Established ......................................................................5-5
Table 2. HAPs Defined in Section 112 of the CAA Amendments of 1990 ....................................................5-6
Table 3. Source Categories With MACT Standards ......................................................................................5-8
Table 4. Major Source Determination in Nonattainment Areas ..................................................................5-15
Table 5. Constituents Included in IWAIR ..................................................................................................5-22
Table 6. Source Characterization Models....................................................................................................5-29
Table 7. Example List of Chemical Suppressants ........................................................................................5-34
Protecting Air Quality—Protecting Air Quality
H
ealth effects from airborne pol-
include particulates or wind-blown dust and
lutants can be minor and
gaseous emissions from volatile compounds
reversible (such as eye irrita-
tion), debilitating (such as It is recommended that every facility
asthma), or chronic and poten- implement controls to address emissions of
tially fatal (such as cancer). Potential health airborne particulates. Particulates have imme-
impacts depend on many factors, including diate and highly visible impacts on surround-
the quantity of air pollution to which people ing neighborhoods. They can affect human
are exposed, the duration of exposures, and health and can carry constituents off site as
the toxicity associated with specific pollu- well. Generally, controls are achieved through
tants. An air risk assessment takes these fac- good operating practices.
tors into account to predict the risk or
For air releases from industrial waste man-
hazards posed at a particular site or facility.
agement units, you need to know what regula-
tory requirements under the Clean Air Act
This chapter will help you address the fol- (CAA) apply to your facility, and whether those
lowing questions. requirements address waste management units.
• Is a particular facility subject to CAA The followup question for facilities whose
requirements? waste management units are not addressed by
CAA requirements, is “are there risks from air
• What is an air risk assessment? releases that should be controlled?”
• Do waste management units pose risks This Guide provides two tools to help you
from volatile air emissions? answer these questions. First, this chapter
• What controls will reduce particulate includes an overview of the major emission
and volatile emissions from a facility? control requirements under the CAA and a
decision guide to evaluate which of these
5-1
Protecting Air Quality—Protecting Air Quality
might apply to a facility. The steps of the deci- two-tiered approach to this assessment is rec-
sion guide are summarized in Figure 1. Each ommended, depending on the complexity and
facility subject to any of these requirements amount of site specific data you have.
will most likely be required to obtain a CAA
Limited Site-Specific Air Assessment:
Title V operating permit. The decision guide
The CD-ROM version of the Guide contains
will help you clarify some of the key facility
the Industrial Waste Air Model (IWAIR). If a
information you need to identify applicable
waste contains any of the 95 constituents
CAA requirements.
included in the model, you can use this risk
If your answers in the decision guide indi- model to assess whether VOC emissions pose
cate that the facility is or might be subject to a risk that warrants additional emission con-
specific regulatory obligations, the next step is trols or that could be addressed more effec-
to consult with EPA, state, or local air quality tively with pollution prevention or waste
program staff. Some CAA regulations are treatment before placement in the waste man-
industry-specific and operation-specific within agement unit. The IWAIR model allows users
an industry, while others are pollutant specific to supply inputs for an emission estimate and
or specific to a geographic area. EPA, state, or for a dispersion factor for the unit.
local air quality managers can help you pre-
Comprehensive Risk Assessment: This
cisely determine applicable requirements and
assessment relies on a comprehensive analysis
whether waste management units are
of waste and site-specific data and use of mod-
addressed by those requirements.
els designed to assess multi-pathway exposures
You might find that waste management to airborne contaminants. There are a number
units are not addressed or that a specific facili- of modeling tools available for this analysis.
ty clearly does not fit into any regulatory cate- You should consult closely with your air quali-
gory under the CAA. It is then prudent to ty management agency as you proceed.
look beyond immediate permit requirements
to assess risks associated with volatile organic
compounds (VOCs) released from the unit. A
Airborne emissions are responsible for the loss of visibility between the left and right pho-
tographs of the Grand Canyon. Source: National Park Service, Air Resources Division.
5-2
Protecting Air Quality—Protecting Air Quality
1
42 U.S.C. § 7409
2
For a discussion of the history of the litigation over the revised ozone standard and EPA’s plan for
implementing it, including possible revisions to 40 CFR 50.9(b), see 67 FR 48896 (July 26, 2002). 5-3
Protecting Air Quality—Protecting Air Quality
tion that can reasonably be anticipated to least 10 tons per year (tpy) of any single HAP
endanger public health or welfare. For indus- or at least 25 tpy of any combination of HAPs.
try categories, NSPSs establish national tech- All fugitive emissions of HAPs, including emis-
nology-based emission limits for air pollutants, sions from waste management units, are to be
such as particulate matter (PM) or VOCs. taken into account in determining whether a
States have primary responsibility for assuring stationary source is a major source. Each
that the NSPSs are followed. These standards MACT standard might limit specific opera-
are distinct from NAAQS because they estab- tions, processes, or wastes that are covered.
lish direct national emission limits for speci- Some MACT standards specifically cover waste
fied sources, while NAAQS establish air management units, while others do not. If a
quality targets that states meet using a variety facility is covered by a MACT standard, it
of measures that include emission limits. Table must be permitted under Title V (see below).
1 lists industries for which NSPSs have been
EPA has identified approximately 170 indus-
established and locations of the NSPSs in the
trial categories and subcategories that are or will
Code of Federal Regulations. You should
be subject to MACT standards. Table 3 lists the
check to see if any of the 74 New Source
categories for which standards have been final-
Performance Standards (NSPSs)3 apply to the
ized, proposed, or are expected. The CAA calls
facility.4 Any facility subject to a NSPS must
for EPA to promulgate the standards in four
obtain a Title V permit (see Section D below.).
phases. EPA is currently in the fourth and final
phase of developing proposed regulations.
C. National Emission CAA also requires EPA to assess the risk to
Standards for Hazardous public health remaining after the implementa-
Air Pollutants tion of NESHAPs and MACT standards. EPA
must determine if more stringent standards are
Section 112 of the CAA Amendments of necessary to protect public health with an
19905 requires EPA to establish national stan- ample margin of safety or to prevent an
dards to reduce emissions from a set of certain adverse environmental effect. As a first step in
pollutants called hazardous air pollutants this process the CAA requires EPA to submit a
(HAPs). Section 112(b) contains a list of 188 Report to Congress on its methods for making
HAPs (see Table 2) to be regulated by National the health risks from residual emissions deter-
Emission Standards for Hazardous Air mination. The final report, Residual Risk
Pollutants (NESHAPs) referred to as Maximum Report to Congress (U.S. EPA, 1997b), was
Achievable Control Technology (MACT) stan- signed on March 3, 1999 and is available from
dards, that are generally set on an industry-by- EPA’s Web site at <www.epa.gov/ttn/oarpg/
industry basis. t3/reports/risk_rep.pdf>. If significant resid-
MACT standards typically apply to major ual risk exists after application of a MACT,
sources in specified industries; however, in EPA must promulgate health-based standards
some instances, non-major sources also can be for that source category to further reduce HAP
subject to MACT standards. A major source is emissions. EPA must set residual risk stan-
defined as any stationary source or group of dards within 8 years after promulgation of
stationary sources that (1) is located within a each NESHAP.
contiguous area and under common control,
and (2) emits or has the potential to emit at
3
40 CFR Part 60.
4
While NSPSs apply to new facilities, EPA also established emission guidelines for existing facilities.
5-4
5
42 U.S.C. § 7412.
Protecting Air Quality—Protecting Air Quality
5-5
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Table 2
HAPs Defined in Section 112 of the CAA Amendments of 1990
CAS# CHEMICAL NAME CAS# CHEMICAL NAME CAS# CHEMICAL NAME
5-6
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Table 2
HAPs Defined in Section 112 of the CAA Amendments of 1990 (cont)
CAS# CHEMICAL NAME CAS# CHEMICAL NAME CAS# CHEMICAL NAME
96-09-3 Styrene oxide 593-60-2 Vinyl bromide [none] Fine mineral fibersc
NOTE: For all listings above which contain the word “compounds” and for glycol ethers, the following applies: Unless otherwise specified,
these listings are defined as including any unique chemical substance that contains the named chemical (i.e., antimony, arsenic, etc.) as part
of that chemical’s infrastructure.
a X’CN where X = H’ or any other group where a formal dissociation can occur. For example KCN or Ca(CN)2.
b On January 12, 1999 (64 FR 1780), EPA proposed to modify the definition of glycol ethers to exclude surfactant alcohol ethoxylates and
their derivatives (SAED). On August 2, 2000 (65 FR 47342), EPA published the final action. This action deletes each individual com-
pound in a group called the surfactant alcohol ethoxylates and their derivatives (SAED) from the glycol ethers category in the list of haz-
ardous air pollutants (HAP) established by section 112(b)(1) of the Clean Air Act (CAA). EPA also made conforming changes in the
definition of glycol ethers with respect to the designation of hazardous substances under the Comprehensive Environmental Response,
Compensation, and Liability Act (CERCLA).
“The following definition of the glycol ethers category of hazardous air pollutants applies instead of the definition set forth in 42 U.S.C.
7412(b)(1), footnote 2: Glycol ethers include mono- and di-ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-
(OCH2CH2)n-OR’
Where:
n= 1, 2, or 3
R= alkyl C7 or less, or phenyl or alkyl substituted phenyl
R’= H, or alkyl C7 or less, or carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate.
c Includes mineral fiber emissions from facilities manufacturing or processing glass, rock, or slag fibers (or other mineral derived fibers) of
average diameter 1 micrometer or less. (Currently under review.)
d Includes organic compounds with more than one benzene ring, and which have a boiling point greater than or equal to 100°C.
(Currently under review.)
e A type of atom which spontaneously undergoes radioactive decay.
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Table 3
Source Categories With MACT Standards
Source Category Federal Register Citation Source Category Federal Register Citation
5-8
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Table 3
Source Categories With MACT Standards (cont.)
Source Category Federal Register Citation Source Category Federal Register Citation
This table contains final rules (F), proposed rules (P), and notices (N) promulgated as of February 2002. It does
not identify corrections or clarifications to rules. An * denotes sources required by Section 112 of the CAA to have
MACT standards by 11/15/00 for which proposed rules are being prepared but have not yet been published.
5-9
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5-11
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9
61 FR 34139; July 1, 1996, as amended, 64 FR 38970 (July 20, 1999) and 66 FR 1266 (January 8,
2001).
10
OSWRO identified approximately 100 HAPs to be covered. This HAP list is a subset of the CAA
5-12 Section 112 list.
Protecting Air Quality—Protecting Air Quality
NO
Does
No further the waste
evaluation is NO contain any of the 95
indicated listed contaminants
in IWAIR?
YES
Conduct a risk evaluation using either:
5-13
Protecting Air Quality—Protecting Air Quality
11
EPA can designate additional source categories subject to Title V operating permit requirements.
12
Implementation of air emission controls can generate new residual waste. Ensure that these wastes are
5-14 managed appropriately, in compliance with state requirements and consistent with the Guide.
Protecting Air Quality—Protecting Air Quality
13
The nonattainment categories are based upon the severity of the area’s pollution problems. The four cate-
gories for VOCs and NOx range from Moderate to Extreme. Moderate areas are the closest to meeting the
attainment standard, and require the least amount of action. Nonattainment areas with more serious air
quality problems must implement various control measures. The worse the air quality, the more controls
areas will have to implement. PM-10 and CO have only two categories, Moderate and Serious. 5-15
Protecting Air Quality—Protecting Air Quality
14
OSWRO identified approximately 100 HAPs to be covered. This HAP list is a subset of the CAA
Section 112 list.
5-16
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5-17
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5-18
Protecting Air Quality—Protecting Air Quality
In addition to these factors affecting the distances of transport being considered are
diffusion and transport of a plume away from relatively short, the removal mechanisms
its point of release, the concentration of spe- shown in the figure are likely to have a rela-
cific chemicals in a plume can also be affect- tively minor effect on plume concentration
ed by depletion. As volatile chemicals are (both wet and dry deposition have significant-
transported away from the WMU, they can ly greater effects on airborne particulates).
be removed from the ambient air through a
Once the constituent’s ambient outdoor
number of depletion mechanisms including
concentration is determined, the receptor’s
wet deposition (the removal of chemicals due
extent of contact with the pollutant must be
to precipitation) and dry deposition (the
characterized. This step involves determining
removal of chemicals due to the forces of
the location and activity patterns relevant to
gravity and impacts of the plume on features
the receptor being considered. In IWAIR, the
such as vegetation). Chemicals can also be
receptors are defined as residents and work-
transformed chemically as they come in con-
ers located at fixed distances from the WMU,
tact with the sun’s rays (i.e., photochemical
and the only route of exposure considered
degradation). Figure 4 illustrates the forces
for these receptors is the inhalation of
acting to transport and deplete the contami-
volatiles. Typical activity patterns and body
nant plume.
physiology of workers and residents are used
Because the chemicals being considered in to determine the intake of the constituent.
IWAIR are volatiles and semi-volatiles and the Intake estimates quantify the extent to which
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5-21
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5-22
Protecting Air Quality—Protecting Air Quality
developed by ISCST3 for many separate sce- centrations managed in the unit or the waste
narios designed to cover a broad range of concentration (Cw) in the unit that should
unit characteristics, including: not be exceeded to protect human health. In
calculating either estimate, the model applies
• 60 meteorological stations, chosen to
default values for exposure factors, including
represent the 9 general climate
inhalation rate, body weight, exposure dura-
regions of the continental U.S.
tion, and exposure frequency. These default
• 4 unit types. values are based on data presented in the
• 17 surface area sizes for landfills, Exposure Factors Handbook (U.S. EPA, 1995a)
land application units and surface and represent average exposure conditions.
impoundments, and 11 surface area IWAIR maintains standard health benchmarks
sizes and 7 heights for waste piles. (CSFs for carcinogens and RfCs for noncar-
cinogens) for 95 constituents. These health
• 6 receptor distances from the unit benchmarks are from the Integrated Risk
(25, 50, 75, 150, 500, 1000 meters). Information System (IRIS) and the Health
• 16 directions in relation to the edge Effects Assessment Summary Tables (HEAST).
of the unit. IWAIR uses these data to perform either a for-
ward calculation to obtain risk estimates or a
The default dispersion factors were derived backward calculation to obtain protective
by modeling many scenarios with various waste concentration estimates.
combinations of parameters, then choosing as
the default the maximum dispersion factor
for each waste management unit/surface 4. Estimation Process
area/meteorological station/receptor distance Figure 5 provides an overview of the step-
combination. wise approach the user follows to calculate
Based on the size and location of a unit, as risk or protective waste concentration esti-
specified by a user, IWAIR selects an appro- mates with IWAIR. The seven steps of the
priate dispersion factor from the default dis- estimation process are shown down the right
persion factors in the model. If the user side of the figure, and the user specified
specifies a unit surface area that falls between inputs are listed to the left of each step. As
two of the sizes already modeled, a linear the user provides input data, the program
interpolation method will estimate dispersion proceeds to the next step. Each step of the
in relation to the two closest unit sizes. estimation process is discussed below.
Alternatively, a user can enter a site-specif- a. Select Calculation Method. The user
ic dispersion factor developed by conducting selects one of two calculation meth-
independent modeling with ISCST3 or with a ods. Use the forward calculation to
different model and proceed to the next step, arrive at chemical-specific and cumu-
the risk calculation. lative risk estimates if the user knows
the concentrations of constituents in
the waste. Use the backward calcula-
3. Risk Model tion method to estimate protective
The third component to the model com- waste concentrations not to be
bines the constituent’s air concentration with exceeded in new units. The screen
receptor exposure factors and toxicity bench- where this step is performed is shown
marks to calculate either the risk from con- in Figure 6.
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Protecting Air Quality—Protecting Air Quality
Identify WMU
User Specifies: Land application unit
WMU type Waste pile
WMU information (e.g., Surface impoundment, aerated
operating parameters) and quiescent
Landfill
Calculate Results
User Specifies:
Risk Calculation
Risk level for allowable concentration
1. Chemical-specific carcinogenic risk
calculation
2. Chemical-specific noncarcinogenic risk
3. Total cancer risk
or
Allowable Waste Concentration
(Cwaste) Calculation
Cwaste for wastewaters (mg/L)
Cwaste for solid wastes (mg/kg)
5-24
Protecting Air Quality—Protecting Air Quality
A. Select B. Select
calculation WMU type
method
C. Select met
station search
option
D. View
selected met
station
B. Select
sorting option
for identifying D. View
chemicals selected
chemicals
A. Add/
modify
chemicals E. Enter waste
concentrations
C. Identify
chemicals in
waste
5-25
Protecting Air Quality—Protecting Air Quality
b. Identify Waste Management Unit. DAT8 rates, a user can provide their
Four WMU types can be modeled: own site-specific emission rates
surface impoundments (SIs), land developed with a different model or
application units (LAUs), active land- based on emission measurements.
fills (LFs), and wastepiles (WPs). For
e. Determine Dispersion. The user can
each WMU, you will be asked to
provide site-specific unitized disper-
specify some design and operating
sion factors (µg/m3 per µg/m2-s) or
parameters such as surface area,
have the model develop dispersion
depth for surface impoundments and
factors based on user-specified WMU
landfills, height for wastepiles, and
information and the IWAIR default
tilling depth for LAUs. The amount
dispersion data. Because a number of
of unit specific data needed as input
assumptions were made in develop-
will vary depending on whether the
ing the IWAIR default dispersion
user elects to develop CHEMDAT8
data you can elect to provide site-
emission rates. IWAIR provides
specific dispersion factors which can
default values for several of the oper-
be developed by conducting inde-
ating parameters that the user can
pendent modeling with ISCST3 or
choose, if appropriate.
with a different model. Whether you
c. Define Waste Managed. Specify use IWAIR or provide dispersion fac-
constituents and concentrations in tors from another source, specify dis-
the waste if you choose a forward tance to the receptor from the edge
calculation to arrive at chemical spe- of the WMU and the receptor type
cific risk estimates. If you choose a (i.e., resident or worker). These data
backward calculation to estimate pro- are used to define points of exposure.
tective waste concentrations, then
f. Calculate Ambient Air
specify constituents of concern. The
Concentration. For each receptor,
screen where this step is performed
the model combines emission rates
is shown in Figure 7.
and dispersion data to estimate ambi-
d. Determine Emission Rates. You can ent air concentrations for all waste
elect to develop CHEMDAT8 emis- constituents of concern.
sion rates or provide your own site-
g. Calculate Results. The model calcu-
specific emission rates for use in
lates results by combining estimated
calculations. IWAIR will also ask for
ambient air concentrations at a speci-
facility location information to link
fied exposure point with receptor
the facility’s location to one of the 60
exposure factors and toxicity bench-
IWAIR meteorological stations. Data
marks. Presentation of results
from the meteorological stations pro-
depends on whether you chose a for-
vide wind speed and temperature
ward or backward calculation:
information needed to develop emis-
sion estimates. In some circum- Forward calculation: Results are estimates of
stances the user might already have cancer and non-cancer risks from inhalation
emissions information from monitor- exposure to volatilized constituents in the
ing or a previous modeling exercise. waste. If risks are too high, options are: 1)
As an alternative to using the CHEM- implement unit controls to reduce volatile air
emissions, 2) implement pollution preven-
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Protecting Air Quality—Protecting Air Quality
5-27
Protecting Air Quality—Protecting Air Quality
particulate emissions are not EPA, 1993) can assist users in deter-
accounted for in the model. mining whether a facility is in an
area of simple, intermediate, or com-
• Waste Management Practices. The
plex terrain.
user specifies a number of unit-spe-
cific parameters that significantly • Receptor Type and Location.
impact the inhalation pathway (e.g., IWAIR has predetermined adult
size, type, and location of WMU, worker and resident receptors, six
which is important in identifying receptor locations, and predeter-
meteorological conditions). However, mined exposure factors. The program
the model cannot accommodate cannot be used to characterize risk
information concerning control tech- for other possible exposure scenarios.
nologies such as covers that might For example, the model can not eval-
influence the degree of volatilization uate receptors that are closer to the
(e.g., whether a wastepile is covered unit than 25 meters or those that are
immediately after application of new further from the unit than 1,000
waste). In this case, it might be advis- meters. If the population of concern
able to generate site-specific emission for your facility is located beyond the
rates and enter those into IWAIR. limits used in IWAIR, consider using
a model that is more appropriate for
• Terrain and Meteorological
the risks posed from your facility.
Conditions. If a facility is located in
an area of intermediate or complex
terrain or with unusual meteorologi- C. Site-specific Risk
cal conditions, it might be advisable
to either 1) generate site-specific air
Analysis
dispersion modeling results for the IWAIR is not the only model that can be
site and enter those results into the applicable to a site. In some cases, a site-spe-
program, or 2) use a site-specific risk cific risk assessment might be more advanta-
modeling approach different from geous. A site-specific approach can be
IWAIR. The model will inform the tailored to accommodate the individual needs
user which of the 60 meteorological of a particular WMU. Such an approach
stations is used for a facility. If the would rely on site-specific data and on the
local meteorological conditions are application of existing fate and transport
very different from the site chosen by models. Table 6 summarizes available emis-
the model, it would be more accurate sions and/or dispersion models that can be
to choose a different model. applied in a site-specific analysis. Practical
considerations include the source of the
The terrain type surrounding a facili- model(s), the ease in obtaining the model(s),
ty can impact air dispersion model- and the nature of the model(s) (i.e., is it pro-
ing results and ultimately risk prietary), and the availability of site-specific
estimates. In performing air disper- data required for use of the model. Finally,
sion modeling to develop the IWAIR the model selection process should determine
default dispersion factors, the model whether or not the model has been verified
ISCST3 assumes the area around the against analytical solutions, other models,
WMU is of simple or flat terrain. The and/or field data. Proper models can be
Guideline on Air Quality Models (U.S. selected based on the physical and chemical
5-28
Protecting Air Quality—Protecting Air Quality
Table 6
Source Characterization Models
Model Name Summary
AP-42 The EPA’s Compilation of Air Pollutant Emission Factors, Volume I: Stationary
Point and Area Sources (AP-42), is a compilation of emission factors for a wide
variety of air emission sources, including fugitive dust sources (Section 13.2).
Emission factors are included for paved roads, unpaved roads, heavy construc-
tion operations, aggregate handling and storage piles, industrial wind erosion
(this is the 1988 Cowherd model), and abrasive blasting. These are simple emis-
sion factors or equations that relate emissions to inputs (e.g., silt loading or con-
tent, moisture content, mean vehicle weight, area, activity level, and wind
speed). Guidance is provided for most inputs, but the more site-specific the
input data used, the more accurate the results.
CHEMDAT8 The CHEMDAT8 model allows the user to conduct source and chemical specific
emissions modeling. CHEMDAT8 is a Lotus 1-2-3 spreadsheet that includes ana-
lytical models to estimate volatile organic compound emissions from treatment,
storage, and disposal facility processes under user-specified input parameters.
CHEMDAT8 calculates the fractions of waste constituents of interest that are dis-
tributed among pathways (partition fractions) applicable to the facility under
analysis.
The 1988 version of the model is available as part of AP-42, Section 13.2.5 (see
above).
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Protecting Air Quality—Protecting Air Quality
Table 6
Source Characterization Models
Model Name Summary
ISCLT3 The Industrial Source Complex Model-Long Term, ISCLT3, is a steady state
Gaussian plume dispersion model that can be used to model dispersion of con-
tinuous emissions from point or area sources over transport distances of less
than 50km. It can estimate air concentration for vapors and particles, and dry
deposition rates for particles (but not vapors), and can produce these outputs
averaged over seasonal, annual, or longer time frames. ISCLT3 inputs include
readily available meteorological data known as STAR (STability ARray) sum-
maries (these are joint frequency distributions of wind speed class by wind
direction sector and stability class, and are available from the National Climate
Data Center in Asheville, North Carolina), and information on source character-
istics (such as height, area, emission rate), receptor locations, and a variety of
modeling options (such as rural or urban). Limitations of ISCLT3 include inabili-
ty to model wet deposition, deposition of vapors, complex terrain, or shorter
averaging times than seasonal, all of which can be modeled by ISCST3. In addi-
tion, the area source algorithm used in ISCLT3 is less accurate than the one used
in ISCST3. The runtime for area sources, however, is significantly shorter for
ISCLT3 than for ISCST3.
ISCST3 A steady-state Gaussian plume dispersion model that can estimate concentration,
dry deposition rates (particles only), and wet deposition rates. Is applicable for
continuous emissions, industrial source complexes, rural or urban areas, simple
or complex terrain, transport distances of less than 50 km, and averaging times
from hourly to annual.
Available at <www.epa.gov/scram001/tt22.htm>.
Landfill Air Emissions Estimation Used to estimate emission rates for methane, carbon dioxide, nonmethane
Model (LAEEM) volatile organic compounds, and other hazardous air pollutants from municipal
solid waste landfills. The mathematical model is based on a first order decay
equation that can be run using site-specific data supplied by the user for the
parameters needed to estimate emissions or, if data are not available, using
default value sets included in the model.
Developed by the Clean Air Technology Center (CATC). Can be used to estimate
emission rates for methane, carbon dioxide, nonmethane organic compounds,
and individual air pollutants from landfills. Can also be used by landfill owners
and operators to determine if a landfill is subject to the control requirements of
the federal New Source Performance Standard (NSPS) for new municipal solid
waste (MSW) landfills (40 CFR 60 Subpart WWW) or the emission guidelines
for existing MSW landfills (40 CFR 60 Subpart CC).
Developed for municipal solid waste landfills; might not be appropriate for all
industrial waste management units.
Available at <www.epa.gov/ttn/chief/software/index.html>.
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Protecting Air Quality—Protecting Air Quality
Table 6
Source Characterization Models
Model Name Summary
Wastewater Treatment Compound WATER9 is a Windows based computer program and consists of analytical
Property Processor and Air Emissions expressions for estimating air emissions of individual waste constituents in
Estimator Program (WATER9) wastewater collection, storage, treatment, and disposal facilities; a database list-
ing many of the organic compounds; and procedures for obtaining reports of
constituent fates, including air emissions and treatment effectiveness.
WATER9 has the ability to use site-specific compound property information, and
the ability to estimate missing compound property values. Estimates of the total air
emissions from the wastes are obtained by summing the estimates for the individ-
ual compounds. The EPA document Air Emissions Models for Waste and Wastewater
(U.S. EPA, 1994a) includes the equations used in the WATER9 model.
Available at <www.epa.gov/ttnchie1/software/water/water9/index.html>.
Contact the Air Emissions Model Hotline at 919 541-5610 for support or more
information.
Toxic Modeling System Short Term An interactive PC-based system to analyze intermittent emissions from toxic
(TOXST) sources. Estimates the dispersion of toxic air pollutants from point, area, and
volume sources at a complex industrial site. This system uses a Monte Carlo sim-
ulation to allow the estimation of ambient concentration impacts for single and
multiple pollutants from continuous and intermittent sources. In addition, the
model estimates the average annual frequency with which user-specified concen-
tration thresholds are expected to be exceeded at receptor sites around the mod-
eled facility. TOXST requires the use of ISCT3 model input files for physical
source parameters.
Available at <www.epa.gov/rgytgrnj/programs/artd/toxics/arpp/etools.htm>.
Toxic Screening Model (TSCREEN) TSCREEN, a Model for Screening Toxic Air Pollutant Concentrations, should be
used in conjunction with the “Workbook of Screening Techniques for Assessing
Impacts of Toxic Air Pollutants.” The air toxics dispersion screening models
imbedded in TSCREEN that are used for the various scenarios are SCREEN2,
RVD, PUFF, and the Britter-McQuaid model. Using TSCREEN, a particular
release scenario is selected via input parameters, and TSCREEN model to simu-
late that scenario. The model to be used and the worst case meteorological con-
ditions are automatically selected based on criteria given in the workbook.
TSCREEN has a front-end control program to the models that also provides, by
use of interactive menus and data entry screen, the same steps as the workbook.
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Protecting Air Quality—Protecting Air Quality
attributes of the site in question. As with all should check to see if your state also has reg-
modeling, however, you should consult with ulations or guidance concerning dust or fugi-
your state prior to investing significant tive emission control.
resources in a site-specific analysis. The state
PM emissions at waste management units
might have preferred models or might be able
vary with the physical and chemical charac-
to help plan the analysis.
teristics of waste streams; the volume of waste
handled; the size of the unit, its location, and
associated climate; and waste transportation
III. Emission Control and placement practices. The subsections
below discuss the main PM-generating opera-
Techniques tions and identify emission control tech-
niques. The waste management units of main
A. Controlling Particulate concern for PM emissions include landfills,
waste piles, land application units, and closed
Matter surface impoundments.
Particulate matter (PM) consists of air-
borne solid and liquid particles. PM is easily
inhaled and can cause various health prob- 1. Vehicular Operations
lems. PM also impacts the environment by Waste and cover material are often trans-
decreasing visibility and harming plants as ported to units using trucks. If the waste has
well as transporting constituents off site. the potential for PM to escape to the atmos-
Constituents can sorb to particulate matter phere during transport, you should cover the
and, therefore, wind blown dust is a potential waste with tarps or place wastes in containers
pathway for constituents to leave the site. It is such as double bags or drums.17
recommended that facilities adopt controls to A unit can also use vehicles to construct
address emissions of airborne particulates. lifts in landfills, apply liquids to land applica-
Solid PM that becomes airborne directly or tion units, or dredge surface impoundments.
indirectly as a result of human activity, is Consider using “dedicated” equipment—vehi-
referred to as fugitive dust16 and it can be cles that operate only within the unit and are
generated from a number of different sources. not routinely removed from the unit to per-
The most common sources of fugitive dust at form other activities. This practice reduces
waste management units include vehicular the likelihood that equipment movement will
traffic on unpaved roads and land-based spread contaminated PM outside the unit. To
units, wind erosion from land-based units, control PM emissions when equipment must
and waste handling procedures. Developing a be removed from the landfill unit, such as for
fugitive dust control plan is an efficient way maintenance, a wash station can remove any
to tackle these problems. The plan should contaminated material from the equipment
include a description of all operations con- before it leaves the unit. You should ensure
ducted at the unit, a map, a list of all fugitive that this is done in a curbed wash area where
dust sources at the unit, and a description of wash water is captured and properly handled.
the control measures that will be used to To minimize PM emissions from all vehi-
minimize fugitive dust emissions. OSHA has cles, it is recommended that you construct
established standards for occupational expo- temporary roadways with gravel or other
sure to dust (see 29 CFR § 1910.1000). You
16
Fugitive emissions are defined as emissions not caught by a capture system and therefore exclude PM
emitted from exhaust stacks with control devices.
17
Containerizing wastes provides highly effective control of PM emissions, but, due to the large volume of
5-32 many industrial waste streams, containerizing waste might not always be feasible.
Protecting Air Quality—Protecting Air Quality
5-33
Protecting Air Quality—Protecting Air Quality
more effectively than water. When applied to efficiency varies, depending on the same fac-
a unit, suppressants cement loose material tors as water application, as well as spray
into a more impervious surface or form a sur- nozzle parameters, but generally falls
face which attracts and retains moisture. between 60 and 90 percent reduction in fugi-
Examples of chemical dust suppressants are tive dust emissions. Suppressant costs, how-
provided in Table 7. The degree of control ever, can be high.
achieved is a function of the application
At land application units, if wastes contain
intensity and frequency and the dilution ratio.
considerable moisture, PM can be suppressed
Chemical dust suppressants tend to require
through application of more waste rather
less frequent application than water, reducing
than water or chemical suppressants. This
the potential for leachate generation. Their
method, however, is only viable if it would
5-34
Protecting Air Quality—Protecting Air Quality
not cause an exceedence of a design waste the exposed surface. It can also shelter mate-
application rate or exceed the capacity of soil rials handling operations to reduce entrain-
and plants to assimilate waste. ment during load-in and loadout. Wind
fences or barriers can be portable and either
At surface impoundments, the liquid
man-made structures or vegetative barriers,
nature of the waste means PM is not a major
such as trees. A number of studies have
concern while the unit is operational. Inactive
attempted to determine the effectiveness of
or closed surface impoundments, however,
wind fences or barriers for the control of
can emit PM during scraping or bulldozing
windblown dust under field conditions.
operations to remove residual materials. The
Several of these studies have shown a
uppermost layer of the low permeability soils,
decrease in wind velocity, however, the
such as compacted clay, which can be used to
degree of emissions reduction varies signifi-
line a surface impoundment, contains the
cantly from study to study depending on test
highest contaminant concentrations.
conditions.
Particulate emissions from this uppermost
layer, therefore, are the chief contributor to Other wind erosion control measures
contaminant emissions. When removing include passive enclosures such as three-
residuals from active units, you should ensure sided bunkers for the storage of bulk materi-
that equipment scrapes only the residuals, als, storage silos for various types of aggregate
avoiding the liner below. material, and open-ended buildings. Such
enclosures are most easily used with small,
temporary waste piles. At land application
3. Wind Erosion
units that use spray application, further wind
Wind erosion occurs when a dry surface is erosion control can be achieved simply by
exposed to the atmosphere. The effect is most not spraying waste on windy days.
pronounced with bare surfaces of small parti-
cles, such as silty soil; heavier or better Windblown PM emissions from a waste
anchored material, such as stones or clumps pile depend on how frequently the pile is dis-
of vegetation, has limited erosion potential turbed, the moisture content of the waste, the
and requires higher wind speeds before ero- proportion of aggregate fines, and the height
sion can begin. of the pile. When small-particle wastes are
loaded onto a waste pile, the potential for
Compacted clay and in-situ soil liners tend dust emissions is at a maximum, as small
to form crusts as their surfaces dry. Crusted particles are easily disaggregated and picked
surfaces usually have little or no erosion up by wind. This tends to occur when mater-
potential. Examine the crust thickness and ial is either added to or removed from the
strength during site inspections. If the crust pile or when the pile is otherwise reshaped.
does not crumble easily the erosion potential On the other hand, when the waste remains
might be minimal. undisturbed for long periods and is weath-
Wind fences or barriers are effective means ered, its potential for dust emissions can be
by which to control fugitive dust emissions greatly reduced. This occurs when moisture
from open dust sources. The wind fence or from precipitation and condensation causes
barrier reduces wind velocity and turbulence aggregation and cementation of fine particles
in an area whose length is many times the to the surface of larger particles, and when
height of the fence. This allows settling of vegetation grows on the pile, shielding the
large particles and reduces emissions from surface and strengthening it with roots.
5-35
Protecting Air Quality—Protecting Air Quality
Finally, limiting the height of the pile can Removal of the volatiles near the point of
reduce PM emissions, as wind velocities gen- generation can obviate the need for controls
erally increase with distance from the on your subsequent process units and can
ground. facilitate recycling the recovered organics
back to the process.
5-36
Protecting Air Quality—Protecting Air Quality
include water, mineral oils, or other non- incinerators provide oxidation at tempera-
volatile petroleum oils. Absorption efficien- tures lower than those required by thermal
cies of 60 to 96 percent have been reported incinerators. Design considerations are
for organics. The material removed from the important because the catalyst can be
absorber can present a disposal or separation adversely affected by high temperatures, high
problem. For example, organics must be concentrations of organics, fouling from par-
removed from the water or nonvolatile oil ticulate matter or polymers, and deactivation
without losing them as emissions during the by halogens or certain metals.
solvent recovery or treatment process.
5. Special Considerations for
d. Vapor Combustion Land Application Units
Vapor combustion is another control tech- Since spraying wastes increases contact
nique for vented vapors. The destruction of between waste and air and promotes VOC
organics can be accomplished in flares; ther- emissions, if the waste contains volatile
mal oxidizers, such as incinerators, boilers, organics you might want to choose another
or process heaters; and in catalytic oxidizers. application method, such as subsurface injec-
Flares are an open combustion process in tion. During subsurface injection, waste is
which oxygen is supplied by the air sur- supplied to the injection unit directly from a
rounding the flame. Flares are either operated remote holding tank and injected approxi-
at ground level or elevated. Properly operated mately 6 inches into the soil; hence, the
flares can achieve destruction efficiencies of waste is not exposed to the atmosphere. In
at least 98 percent. Thermal vapor incinera- addition, you should consider pretreating the
tors can also achieve destruction efficiencies waste to remove the organics before placing
of at least 98 percent with adequately high it in the land application unit.
temperature, good mixing, sufficient oxygen,
and an adequate residence time. Catalytic
5-38
Protecting Air Quality—Protecting Air Quality
5-39
Protecting Air Quality—Protecting Air Quality
Resources
American Conference of Governmental Industrial Hygienists. 1997. Threshold Limit Values for Chemical
Substances and Physical Agents and Biological Exposure Indices.
Christensen, T.H., R. Cossu, and R. Stegmann. 1995. Siting, Lining Drainage & Landfill Mechanics,
Proceeding from Sardinia 95 Fifth International Landfill Symposium, Volume II.
Finn, L., and R. Spencer. 1987. Managing Biofilters for Consistent Odor and VOC Treatment. BioCycle.
January.
Hazardous Waste Treatment, Storage and Disposal Facilities and Hazardous Waste Generators; Organic Air
Emission Standards for Tanks, Surface Impoundments, and Containers; Final Rule. Federal Register. Volume
59, Number 233, December 6, 1994. pp. 62896 - 62953.
Mycock, J.C., J.D. McKenna, and L. Theodore. 1995. Handbook of Air Pollution Control Engineering and
Technology.
National Ambient Air Quality Standards for Particulate Matter. Federal Register. Volume 62, Number 138, July
18, 1997. pp. 38651 - 38701.
Orlemann, J.A., T.J. Kalman, J.A. Cummings, E.Y. Lin. 1983. Fugitive Dust Control Technology.
Texas Center for Policy Studies. 1995. Texas Environmental Almanac, Chapter 6, Air Quality. <www.tec.org>
U.S. EPA. 2002a. Industrial Waste Air Model Technical Background Document. EPA530-R-02-010.
U.S. EPA. 2002b. Industrial Waste Air Model (IWAIR) User’s Guide. EPA530-R-02-011.
U.S. EPA. 1998. Taking Toxics out of the Air: Progress in Setting “Maximum Achievable Control Technology”
Standards Under the Clean Air Act. EPA451-K-98-001.
U.S. EPA. 1997a. Best Management Practices (BMPs) for Soil Treatment Technologies: Suggested Operational
Guidelines to Prevent Cross-Media Transfer of Contaminants During Clean-Up Activities. EPA530-R-97-007.
U.S. EPA. 1996. Test Methods for Evaluating Solid Waste Physical/Chemical Methods—SW846. Third
Edition.
5-40
Protecting Air Quality—Protecting Air Quality
Resources (cont.)
U.S. EPA. 1995a. Exposure Factors Handbook: Volumes 1-3. EPA600-P-95-002FA-C.
U.S. EPA. 1995b. Survey of Control Technologies for Low Concentration Organic Vapor Gas Streams.
EPA456-R-95-003.
U.S. EPA. 1995c. User’s Guide for the Industrial Source Complex (ISC3) Dispersion Models: Volume I.
EPA454-B-95-003a.
U.S. EPA. 1995d. User’s Guide for the Industrial Source Complex (ISC3) Dispersion Models: Volume II-
Description of Model Algorithms. EPA454-B-95-003b.
U.S. EPA. 1994a. Air Emissions Models for Waste and Wastewater. EPA453-R-94-080A.
U.S. EPA. 1994b. Handbook: Control Techniques for Fugitive VOC Emissions from Chemical Process
Facilities. EPA625-R-93-005.
U.S. EPA. 1994c. Toxic Modeling System Short-Term (TOXST) User’s Guide: Volume I. EPA454-R-94-058A.
U.S. EPA. 1992a. Control of Air Emissions from Superfund Sites. EPA625-R-92-012.
U.S. EPA. 1992b. Protocol for Determining the Best Performing Model. EPA454-R-92-025.
U.S. EPA. 1992c. Seminar Publication: Organic Air Emissions from Waste Management Facilities. EPA625-
R-92-003.
U.S. EPA. 1991. Control Technologies for Hazardous Air Pollutants. EPA625-6-91-014.
U.S. EPA. 1989. Hazardous Waste TSDF—Fugitive Particulate Matter Air Emissions Guidance Document.
EPA450-3-89-019.
U.S. EPA. 1985. Rapid Assessment of Exposures to Particulate Emissions form Surface Contamination
Sites.
Viessman, W., and M. Hammer. 1985. Water Supply and Pollution Control.
5-41
Part III
Protecting Surface Water
Chapter 6
Protecting Surface Water
Contents
Resources ....................................................................................................................................................6 - 34
Figures:
Figure 1. BMP Identification and Selection Flow Chart............................................................................6 - 17
Figure 2. Coverings..................................................................................................................................6 - 22
Figure 3. Silt Fence ..................................................................................................................................6 - 24
Contents (cont.)
Tables:
Table 1. Biological and Chemical Processes Occurring in Surface Water Bodies ......................................6 - 14
Table 2. Priority Pollutants ......................................................................................................................6 - 15
Protecting Surface Water—Protecting Surface Water
O
water is such a valuable commodity, the pro-
ver 70 percent of the Earth’s
tection of our surface waters should be every-
surface is water. Of all the
one’s goal. Pollutants1 associated with waste
Earth’s water, 97 percent is
management units and storm-water dis-
found in the oceans and seas,
charges must be controlled.
while 3 percent is fresh water.
This fresh water is found in glaciers, lakes, This chapter summarizes how EPA and
ground water, wetlands, and rivers. Because states determine the quality of surface waters
and subsequently describes the existing sur-
This chapter will help you address the face-water protection programs for ensuring
following questions: the health and integrity of waterbodies. The
fate and transport of pollutants in the surface-
• What surface-water protection pro- water environment is also discussed. Finally,
grams are applicable to my waste various methods that are used to control pollu-
management unit? tant discharges to surface waters are described.
• What are the objectives of run-on and
runoff control systems?
• What should be considered in design- I. Determining the
ing surface-water protection systems?
Quality and
• What BMPs should be implemented
to protect surface waters from pollu- Health of
tants associated with waste manage-
ment units?
Surface Waters
The protection of aquatic resources is gov-
• What are some of the engineering and erned by the Clean Water Act (CWA). The
physical mechanisms available to con- objective of the CWA is to “restore and main-
trol storm water? tain the chemical, physical, and biological
1
To be consistent with the terminology used in the Clean Water Act, the term pollutant is used in this
chapter in place of the term constituent. In this chapter, pollutant means an effluent or condition intro-
duced to surface waters that results in degradation. Water pollutants include human and animal wastes, 6-1
nutrients, soil and sediments, toxics, sewage, garbage, chemical wastes, and heat.
Protecting Surface Water—Protecting Surface Water
6-2
Protecting Surface Water—Protecting Surface Water
uses cited in the CWA. The states may differ- the total maximum daily load (TMDL) pro-
entiate and subcategorize the types of uses gram, under which the states establish the
that are to be protected, such as cold-water or allowable pollutant loadings for impaired
warm-water fisheries, or specific species that waterbodies (i.e., waterbodies not meeting
are to be protected (e.g., trout, salmon, bass). state water quality standards) based on their
States may also designate special uses to pro- “waste assimilative capacity.” EPA must
tect sensitive or valuable aquatic life or habi- approve or disapprove TMDLs established by
tat. In addition, the water quality criteria the states. If EPA disapproves a state TMDL,
adopted into a state water quality standard EPA must establish a federal TMDL.
may or may not be the same number pub-
A TMDL is a calculation of the maximum
lished by EPA under section 304. States have
amount of a pollutant that a waterbody can
the discretion to adjust the EPA’s criteria to
receive and still meet water quality standards.
reflect local environmental conditions and
The calculation must include a margin of
human exposure patterns.
safety to ensure that the waterbody can be
The CWA requires that the states review used for the purposes the state has designat-
their standards at least once every three years ed. The calculation must also account for sea-
and submit the results to EPA for review. EPA sonal variation in water quality.
is required to either approve or disapprove
The quantity of pollutants that can be dis-
the standards, depending on whether they
charged into a surface-water body without
meet the requirements of the CWA. When
use impairment (also taking into account nat-
EPA disapproves a standard, and the state
ural inputs such as erosion) is known as the
does not revise the standard to meet EPA’s
“assimilative capacity.” The assimilative capac-
objection, the CWA requires the Agency to
ity is the range of concentrations of a sub-
propose substitute federal standards.
stance or a mixture of substances that will
not impair attainment of water quality stan-
C. Total Maximum Daily dards. Typically, the assimilative capacity of
surface-water bodies might be higher for
Load (TMDL) Program biodegradable organic matter, but it can be
Lasting solutions to water quality problems very low for some toxic chemicals that accu-
and pollution control can be best achieved by mulative in the tissues of aquatic organisms
looking at the fate of all pollutants in a water- and become injurious to animals and people
shed. The CWA requires EPA to administer using them as food.
6-3
Protecting Surface Water—Protecting Surface Water
A. National Pollutant
What is a watershed? Discharge Elimination
Watersheds are areas of land that drain to System (NPDES) Permit
surface-waterbodies. A watershed general-
ly includes lakes, rivers, estuaries, wet-
Program
lands, streams, and the surrounding The CWA requires most “point sources”
landscape. Ground-water recharge areas (i.e., entities that discharge pollutants of any
are also considered part of a watershed. kind into waters of the United States) to have
Because watersheds are defined by natur- a permit establishing pollution limits, and
al hydrology, they represent the most log- specifying monitoring and reporting require-
ical basis for managing surface-water ments. This permitting process is known as
resources. Managing the watershed as a the National Pollutant Discharge Elimination
whole allows state and local authorities to System (NPDES). Permits are issued for three
gain a more complete understanding of types of wastes that are collected in sewers
overall conditions in an area and the and treated at municipal wastewater treat-
cumulative stressors which affect the sur- ment plants or that discharge directly into
face-water body. Information on EPA’s receiving waters: process wastewater, non-
strategy to protect and restore water qual- process wastewater, and storm water. Most
ity and aquatic ecosystems at the water- discharges of municipal and industrial storm
shed level can be found at <www.epa. water require NPDES permits, but some
gov/owow/watershed/index2.html> other storm water discharges do not require
permits. To protect public health and aquatic
life and assure that every facility treats waste-
II. Surface-Water water, NPDES permits include the following
terms and conditions.
Protection • Site-specific effluent (or discharge)
Programs limitations.
• Standard and site-specific compliance
Applicable to monitoring and reporting require-
Waste ments.
6-4
Protecting Surface Water—Protecting Surface Water
2
Initially, a group application option was available for facilities with similar activities to jointly submit a
single application for permit coverage. A multi-sector general permit was then issued based upon infor-
mation provided in the group applications. The group application option was only used during the ini-
tial stages of the program and is no longer available. 6-5
Protecting Surface Water—Protecting Surface Water
6-6
Protecting Surface Water—Protecting Surface Water
6-7
Protecting Surface Water—Protecting Surface Water
ment requirements, are subject to the general established both mass- and concentration-
and specific prohibitions identified in 40 CFR based standards. Generally, both a daily maxi-
Part 403.5 (a) and (b), respectively. General mum limitation and a long-term average
prohibitions forbid the discharge of any pol- limitation (e.g., average daily values in a cal-
lutant to a POTW that can pass through or endar month) are established for each regu-
cause interference. Specific prohibitions for- lated pollutant.
bid the discharge of pollutants that pose fire
Local Limits. Federal regulations located
or explosion hazards; corrosives; solid or vis-
at 40 CFR Parts 403.8 (f) (4) and 122.21 (j)
cous pollutants in amounts that will obstruct
(4) require authorities to evaluate the need
system flows; quantities of pollutants that will
for local limits and, if necessary, implement
interfere with POTW operations; heat that
and enforce specific limits protective of that
inhibits biological activity; specific oils; pollu-
POTW. Local limits might be developed for
tants that can cause the release of toxic gases;
pollutants such as metals, cyanide, BOD, TSS,
and pollutants that are hauled to the POTW
oil & grease, and organics that can interfere
(except as authorized by the POTW).
with or pass through the treatment works,
Categorical Standards. Categorical pre- cause sludge contamination, or cause worker
treatment standards are national, uniform, health and safety problems if discharged at
technology-based standards that apply to dis- excess levels.
charges to POTWs from specific industrial
All POTWs designed to accommodate
categories (e.g., battery manufacturing, coil
flows of more than 5 million gallons per day
coating, grain mills, metal finishing, petrole-
and smaller POTWs with significant industri-
um refining, rubber manufacturing) and limit
al discharges are required to establish pre-
the discharge of specific pollutants. These
treatment programs. The EPA Regions and
standards are described in 40 CFR Parts 405
states with approved pretreatment programs
through 471.
serve as approval authorities for the National
Categorical pretreatment standards can be Pretreatment Program. In that capacity, they
concentration-based or mass-based. review and approve requests for POTW pre-
Concentration- based standards are expressed treatment program approval or modification,
as milligrams of pollutant allowed per liter of oversee POTW program implementation,
wastewater discharged (mg/l) and are issued review requested modifications to categorical
where production rates for the particular pretreatment standards, provide technical
industrial category do not necessarily corre- guidance to POTWs and IUs, and initiate
late with pollutant discharges. Mass-based enforcement actions against noncompliant
standards are generally expressed as a mass POTWs and IUs.
per unit of production (e.g., milligrams of
pollutant per kilogram of product produced)
2. Treatment of Waste at POTW
and are issued where production rates do
correlate with pollutant discharges. Thus, Plants
limiting the amount of water discharge (i.e., A waste treatment works’ basic function is
water conservation) is important to reducing to speed up the natural processes by which
the pollutant load to the POTW. For a few water is purified and returned to receiving
categories where reducing a facility’s flow vol- lakes and streams. There are two basic stages
ume does not provide a significant difference in the treatment of wastes, primary and sec-
in the pollutant load discharged, EPA has ondary. In the primary stage, solids are
6-8
Protecting Surface Water—Protecting Surface Water
allowed to settle and are removed from which the sewage passes. More recently, inter-
wastewater. The secondary stage uses biologi- locking pieces of corrugated plastic or other
cal processes to further purify wastewater. synthetic media have also been used in trick-
Sometimes, these stages are combined into ling beds. Bacteria gather and multiply on
one operation. POTWs can also perform these stones until they can consume most of
other “advanced treatment” operations to the organic matter in the sewage. The cleaner
remove ammonia, phosphorus, pathogens water trickles out through pipes for further
and other pollutants in order to meet effluent treatment. From a trickling filter, the sewage
discharge requirements. flows to another sedimentation tank to
remove excess bacteria. Disinfection of the
Primary treatment. As sewage enters a
effluent with chlorine is generally used to
plant for treatment, it flows through a screen,
complete the secondary stage. Ultraviolet
which removes large floating objects such as
light or ozone are also sometimes used in sit-
rags and sticks that can clog pipes or damage
uations where residual chlorine would be
equipment. After sewage has been screened, it
harmful to fish and other aquatic life.
passes into a grit chamber, where cinders,
sand, and small stones settle to the bottom. At Activated sludge. The activated sludge treat-
this point, the sewage still contains organic ment process speeds up the work of the bac-
and inorganic matter along with other sus- teria by bringing air and sludge, heavily laden
pended solids. These solids are minute parti- with bacteria, into close contact with sewage.
cles that can be removed from sewage by After the sewage leaves the settling tank in
treatment in a sedimentation tank. When the the primary stage, it is pumped into an aera-
speed of the flow of sewage through one of tion tank, where it is mixed with air and
these tanks is reduced, the suspended solids sludge loaded with bacteria and allowed to
will gradually sink to the bottom, where they remain for several hours. During this time,
form a mass of solids called raw primary the bacteria break down the organic matter
sludge. Sludge is usually removed from tanks into harmless by-products. The sludge, now
by pumping, after which it can be further activated with additional millions of bacteria
treated for use as fertilizer, or disposed of and other tiny organisms, can be used again
through incineration if necessary. To complete by returning it to the aeration tank for mixing
primary treatment, effluent from the sedimen- with new sewage and ample amounts of air.
tation tank is usually disinfected with chlorine From the aeration tank, the sewage flows to
before being discharged into receiving waters. another sedimentation tank to remove excess
Sometimes chlorine is fed into the water to bacteria. The final step is generally the addi-
kill pathogenic bacteria and to reduce tion of chlorine to the effluent.
unpleasant odors.
Advanced treatment. New pollution
Secondary treatment. The secondary stage problems have created additional treatment
of treatment removes about 85 percent of the needs on wastewater treatment systems. Some
organic matter in sewage by making use of the pollutants can be more difficult to remove
bacteria in it. The two principal techniques from water. Increased demands on the water
used in secondary treatment are trickling fil- supply only aggravate the problem. These
ters and the activated sludge process. challenges are being met through better and
more complete methods of removing pollu-
Trickling filters. A trickling filter is a bed of
tants at treatment plants, or through preven-
stones from three to six feet deep through
tion of pollution at the source (refer to
6-9
Protecting Surface Water—Protecting Surface Water
A. How Do Pollutants
Move From Waste What is “runoff?”
Management Units To Runoff is water or leachate that drains
Surface Water? or flows over the land from any part of a
waste management unit.
1. Overland Flow
The primary means by which pollutants What is “run-on?”
are transported to surface-water bodies is via Run-on is water from outside a waste
overland flow or “runoff.” Runoff to surface management unit that flows into the
water is the amount of precipitation after all unit. Run-on includes storm water from
“losses” have been subtracted. Losses include rainfall or the melting of snow or ice
infiltration into soils, interception by vegeta- that falls directly on the unit, as well as
tion, depression storage and ponding, and the water that drains from adjoining
evapotranspiration (i.e., evaporation from the areas.
soil and transpiration by plants).
6-10
Protecting Surface Water—Protecting Surface Water
solves atmospheric carbon dioxide and sulfur reaches the land surface at a spring or
and nitrogen oxides, and acts as a weak acid through a seep in the side or bottom of a
after it hits the ground, reacting with soil and river bed, lake, wetland, or other surface-
limestone formations. Overland flow begins water body. Ground water can also leave the
after rain particles reach the earth’s surface aquifer via the pumping of a well. The
(note that during winter months runoff for- process of ground water outflowing into a
mation can be delayed by snowpack forma- surface-water body or leaving the aquifer
tion and subsequent melting). Rain hitting an through pumping is called discharge.
exposed waste management unit will liberate
Discharge from confined aquifers occurs in
and pick up particulates and pollutants from
much the same way except that pressure,
the unit and can also dissolve other chemicals
rather than gravity, is the driving force in
it comes in contact with. Precipitation that
moving ground water to the surface. When
flows into a waste management unit, called
the intersection between the aquifer and the
“run-on,” can also free-up and subsequently
land’s surface is natural, the pathway is called
transport pollutants out of the unit. Runoff
a spring. If discharge occurs through a well,
carries the pollutants from the waste manage-
that well is a “flowing artesian well.”
ment unit as it flows downgradient following
the natural contours of the watershed to
nearby lakes, rivers, or wetland areas. 3. Air to Surface Water
Pollutants released into the air are carried
2. Ground Water to Surface by wind patterns away from their place of
origin. Depending on weather conditions and
Water
the chemical and physical properties of the
Ground water and surface water are funda- pollutants, pollutants can be carried signifi-
mentally interconnected. In fact, it is often cant distances from their source and can
difficult to separate the two because they undergo physical and chemical changes as
“feed” each other. As a result, pollutants can they travel. Some of these chemical changes
move from one media to another. Shallow include the formation of new pollutants such
water table aquifers interact closely with as ozone, which is formed from nitrogen
streams, sometimes discharging water into a oxides (NOx) and hydrocarbons.
stream or lake and sometimes receiving water
from the stream or lake. Many rivers, lakes, Atmospheric deposition occurs when pol-
and wetlands rely heavily on ground-water lutants in the air fall on the land or surface
discharge as a source of water. During times waters. When pollutants are deposited in
of low precipitation, some bodies of water snow, fog, or rain, the process is called wet
would not contain any water at all if it were deposition, while the deposition of pollutants
not for ground-water discharge. as dry particles or gases is called dry deposi-
tion. Pollutants can be deposited into water
An unconfined aquifer that feeds a stream bodies either directly from the air onto the
is said to provide the stream’s “baseflow.” surface of the water, or through indirect
Gravity is the dominant driving force in deposition, where the pollutants settle on the
ground-water movement in unconfined land and are then carried into a water body
aquifers. As such, under natural conditions, by runoff.
ground water moves “downhill” until it
6-11
Protecting Surface Water—Protecting Surface Water
6-12
Protecting Surface Water—Protecting Surface Water
stream will be deposited on the bottom of the human population or to aquatic organisms,
streambed as the particles fall out of the such as fish). Priority pollutants of particular
water column. In this manner, pollutants can concern for surface-water bodies include:
accumulate in areas of low flow. Thus, it is
• Metals, such as cadmium, copper,
obvious that the hydrodynamical, biological,
chromium, lead, mercury, nickel, and
and chemical processes in aquatic systems
zinc, that arise from industrial opera-
cannot be separated and must be addressed
tions, mining, transportation, and
simultaneously when considering pollutant
agricultural use.
loads and impacts to surface water. Table 1
presents some additional information on the • Organic compounds, such as pesti-
biological and chemical processes that occur cides, PCBs, solvents, petroleum
in water bodies. hydrocarbons, organometallic com-
pounds, phenols, formaldehyde, and
biochemical methylation of metals in
C. Pollutants Of Concern aquatic sediments.
As you assess the different types of best • Dissolved gases, such as chlorine and
management practices (BMPs) that can be ammonium.
used at waste management units to protect
surface waters (discussed in Section IV of this • Anions, such as cyanides, fluorides,
chapter), you should also identify the pollu- sulfides, and sulphates.
tants in the unit that pose the greatest threats • Acids and alkalis.
to surface water. Factors to consider include
the solubility of the constituents in the waste
management unit, how easily these potential
pollutants can be mobilized, degradation IV. Protecting
rates, vapor pressures, and biochemical decay
coefficients of the pollutants and any other
Surface Waters
factors that could encourage their release into
the environment. A. Controls to Address
While all pollutants can become toxic at Surface-Water
high enough levels, there are a number of Contamination from
compounds that are toxic at relatively low Overland Flow
levels. These pollutants have been designated
Protecting surface water entails preventing
by the EPA as priority pollutants. The list of
storm-water contamination during both the
priority pollutants is included in Table 2. The
construction of a waste management unit and
list of priority pollutants is continuously
the operational life of the unit. During con-
under review by EPA and is periodically
struction the primary concern is sediment
updated. The majority of pollutants on the
eroding from exposed soil surfaces.
list are classified as organic chemicals. Others
Temporary sediment and erosion control
are heavy metals which are being mobilized
measures, such as silt fences around con-
into the environment by human activities at
struction perimeters, straw bales around
rates greatly exceeding those of natural geo-
storm-water inlets, and seeding or straw cov-
logical processes. Several of the priority pol-
ering of exposed slopes, are typically used to
lutants are also considered carcinogenic (i.e.,
limit and manage erosion. States or local
they can increase the risk of cancer to the
6-13
Protecting Surface Water—Protecting Surface Water
6-14
Protecting Surface Water—Protecting Surface Water
3
The list of pollutants is current as of the Federal Register dated April 2, 2001.
6-15
Protecting Surface Water—Protecting Surface Water
municipalities often require the use of sedi- from active areas of a landfill or waste pile
ment and erosion controls at any construc- should be managed as leachate. You should
tion site disturbing greater than a certain design a leachate collection and removal sys-
number of acres, and can have additional tem to handle the potentially contaminated
requirements in especially sensitive water- runoff, in addition to the leachate that might
sheds. You should consult with the state and be generated by the unit. You should segre-
local regulatory agencies to determine the gate noncontact runoff to reduce the volume
sediment and erosion control requirements that will need to be treated as leachate. The
for construction. Multi-Sector General Permit does not autho-
rize discharges of leachate which includes
Once a waste management unit has been
storm water that comes in contact with
constructed, permanent run-on and runoff
waste. The discharge of leachate would be
controls are necessary to protect surface
regulated under either an individually drafted
water. Run-on controls are designed to pre-
NPDES permit with site- specific discharge
vent storm water from entering the active
limitations, or an alternative NPDES general
areas of units. If run-on is not prevented
permit if one is available. Note that for land
from entering active areas, it can seep into
application sites, runoff from the site can also
the waste and increase the amount of
adversely affect nearby surface water if pollu-
leachate that must be managed. It can also
tants are picked up and carried overland.
deposit pollutants from nearby sites, such as
pesticides from adjoining farms, further bur- BMPs are measures used to reduce or
dening treatment systems. Excessive run-on eliminate pollutant releases to surface waters
can also damage earthen containment sys- via overland flow. They fall into three cate-
tems, such as dikes and berms. Run-on that gories, baseline, activity-specific, and site-
contacts the waste can carry pollutants into specific, and can take the form of a process,
receiving waters through overland runoff or activity, or physical structure. The use of
into ground water through infiltration. You
can divert run-on to the waste management
unit by taking advantage of natural contours Why are “run-on” controls necessary?
in the land or by constructing ditches or Run-on controls are designed to pre-
berms designed to intercept and drain storm vent: 1) contamination of storm water,
water away from the unit. Run-on diversion 2) erosion that can damage the physical
systems should be designed to handle the structure of units, 3) surface discharge
peak discharge of a design storm event (e.g., of waste constituents, 4) creation of
a 24-hour, 25-year storm4). Also note that leachate, and 5) already contaminated
surface impoundments should be designed surface water from entering the unit.
with sufficient freeboard and adequate capac-
ity to accommodate not only waste, but also
What is the purpose of a “runoff”
precipitation and run-on.
control system?
Runoff controls can channel, divert, and Runoff control systems are designed
convey storm water to treatment facilities or, to collect and control at a minimum the
if appropriate, to other intended discharge water flow resulting from a storm event
points. Runoff from landfills, land treatment of a specified duration, such as a 24-
units, or waste piles should be managed as a hour, 25-year storm event.
potentially contaminated material. The runoff
4
This discharge is the amount of water resulting from a 24-hour rainfall event of a magnitude with a 4
percent statistical likelihood of occurring in any given year (i.e, once every 25 years). Such an event
6-16 might not occur in a given 25-year period, or might occur more than once during a single year.
Protecting Surface Water—Protecting Surface Water
BMPs to protect surface water should be con- while designing and constructing a new waste
sidered in both the design and operation of a management unit to ensure that the proper
waste management unit. Before identifying baseline, activity-specific, and site-specific
and implementing BMPs, you should assess BMPs are implemented and installed from the
the potential sources of storm-water contami- start of operations. After assessing the poten-
nation including possible erosion and sedi- tial and existing sources of storm-water conta-
ment discharges caused by storm events. A mination, the next step is to select appropriate
thorough assessment of a waste management BMPs to address these contamination sources.
unit involves several steps including creating
a map of the waste management
unit area; considering the design Figure 1. BMP Identification and Selection Flow Chart
of the unit; identifying areas
Recommended Steps
where spills, leaks, or discharges
could or do occur; inventorying
the types of wastes contained in Assessment Phase
the unit; and reviewing current Develop a site map
Inventory and describe exposed materials
operating practices (refer to
List significant spills and leaks
Chapter 8–Operating the Waste Identify areas associated with industrial activity
Management System for more Test for nonstorm-water discharges
information). Figure 1 illustrates Evaluate monitoring/sampling data if appropriate
the process of identifying and (see Chapter 9–Monitoring Performance)
selecting the most appropriate
BMPs.
Designing a storm-water BMP Identification Phase
management system to protect Operational BMPs
surface water involves knowl- Source control BMPs
edge of local precipitation pat- Erosion and sediment control BMPs
terns, surrounding topographic Treatment BMPs
Innovative BMPs
features, and geologic condi-
tions. You should consider sam-
pling runoff to ascertain the
quantity and concentration of Implementation Phase
pollutants being discharged. Implement BMPs
(Refer to the Chapter 9– Train employees
Monitoring Performance for
more information). Collecting
and evaluating this type of infor- Evaluation/Monitoring Phase
mation can help you to select Conduct semiannual inspection/BMP evaluation (see
the most appropriate BMPs to Chapter 8–Operating the Waste Management System)
prevent or control pollutant dis- Conduct recordkeeping
charges. The same considera- Monitor surface water if appropriate
tions (e.g., types of wastes to be Review and revise plan
contained in the unit, precipita-
tion patterns, local topography Adapted from U.S. EPA, 1992e.
and geology) should be made
6-17
Protecting Surface Water—Protecting Surface Water
6-18
Protecting Surface Water—Protecting Surface Water
are relevant to waste management are sum- sion, exposure minimization, erosion and
marized below. sedimentation prevention, infiltration, and
other prevention practices. For many of the
Preventing waste leaks and dust emis-
surface-water protection measures described
sions due to vehicular travel. To prevent
in this section, it is important to design for an
leaks, you should ensure that trucks moving
appropriate storm event (i.e., structures that
waste into and around a waste management
control run-on and runoff should be designed
unit have baffles (if they carry liquid waste)
for the discharge of a 24-hour, 25-year storm
or sealed gates, spill guards, or tarpaulin cov-
event).
ers (if the waste is solid or semisolid). To
minimize tracking dust off site where it can When selecting and designing surface-
be picked up by storm water, wash trucks in water protection measures or systems, you
a curbed truck wash area where wash water should consult state, regional, and local
is captured and properly handled. For more watershed management organizations. Some
information on these topics, consult Chapter of these organizations maintain management
8–Operating the Waste Management System . plans devised at the overall watershed level
You should be aware that washwater from that address storm-water control. Thus, these
vehicle and equipment cleaning is considered agencies might be able to offer guidance in
to be “process wastewater,” and is not eligible developing surface-water protection systems
for discharge under the Multi-Sector General for optimal coordination with other dis-
Permit program for industrial storm-water charges in the watershed. Again, after site-
discharges. Such discharges would require specific BMPs have been installed, you should
coverage under either a site-specific individ- evaluate the effectiveness of the selected
ual NPDES permit or an NPDES general BMPs on a regular basis to ensure that they
storm-water permit. are functioning properly .
For land application, choosing appropri-
ate slopes. You should minimize runoff by
designing a waste management unit site with
slopes less than six percent. Moderate slopes
help reduce storm-water runoff velocity
which encourages infiltration and reduces BMP Maintenance
erosion and sedimentation. Note that storm- BMPs must be maintained on a regu-
water discharges from land application units lar basis to ensure adequate surface-
are regulated under the Multi-Sector General water protection. Maintenance is
Permit program. important because storms can damage
surface-water protection measures such
3. Site-Specific BMPs as storage basin embankments or spill-
In addition to baseline and activity-specific ways. Runoff can also cause sediments
BMPs, you should also consider site-specific to settle in storage basins or ditches and
BMPs, which are more advanced measures can carry floatables (i.e., tree branches,
tailored to specific pollutant sources at a par- lumber, leaves, litter) to the basin.
ticular waste management unit and usually Facilities might need to repair storm-
consist of the installation of structural or water controls and periodically remove
physical measures. These site-specific BMPs sediment and floatables.
can be grouped into five areas: flow diver-
6-19
Protecting Surface Water—Protecting Surface Water
a. Flow Diversion
What are some advantages of
Flow diversion can be used to protect sur-
face water in two ways. First, it can channel conveyances?
storm water away from waste management Conveyances direct storm-water flows
units to minimize contact of storm water around industrial areas, waste manage-
with waste. Second, it can carry polluted or ment units, or other waste containment
potentially polluted materials to treatment areas to prevent temporary flooding;
facilities. Flow diversion mechanisms include require little maintenance; and provide
storm-water conveyances and diversion long-term control of storm-water flows.
dikes.
What are some disadvantages of
Storm-Water Conveyances (Channels, Gutters, conveyances?
Drains, and Sewers) Conveyances require routing through
Storm-water conveyances, such as chan- stabilized structures to minimize erosion.
nels, gutters, drains, and sewers, can prevent They also can increase flow rates, might
storm-water run-on from entering a waste be impractical if there are space limita-
management unit or runoff from leaving a tions, and might not be economical.
unit untreated. Some conveyances collect
storm water and route it around waste man-
agement units or other waste containment veyances should be designed with a capacity
areas to prevent contact with the waste, to accept the estimated storm-water flow
which might otherwise contaminate storm associated with the selected design storm
water with pollutants. Other conveyances event. Section V of this chapter discusses
collect water that potentially came into con- methods for determining storm water flow.
tact with the waste management unit and
carry it to a treatment plant (or possibly back Diversion Dikes
to the unit for reapplication in the case of Diversion dikes, often made with compact-
land application units, some surface ed soil, direct run-on away from a waste man-
impoundments, and leachate-recirculating agement unit. Dikes are built uphill from a
landfills). Conveyances should not mix the unit and usually work with storm-water con-
stream of storm water diverted around the veyances to divert storm water from the unit.
unit with that of water that might have con- To minimize the potential for erosion, diver-
tacted waste. Remember, storm water that sion dikes are often constructed to redirect
contacts waste is considered leachate and can runoff at a shallow slope to minimize its
only be discharged in accordance with an velocity. A similar means of flow diversion is
NPDES permit other than the Multi-Sector grading the area around the waste manage-
General Permit. ment unit to keep storm water away from the
Storm-water conveyances can be con- area, instead of or in addition to using diver-
structed of or lined with materials such as sion dikes to redirect water that would other-
concrete, clay tile, asphalt, plastic, metal, wise flow into these areas. In planning for the
riprap, compacted soil, and vegetation. The installation of dikes, you should consider the
material used will vary depending on the use slope of the drainage area, the height of the
of the conveyance and the expected intensity dike, the size of the flow it will need to divert,
of storm-water flow. Storm-water con-
6-20
Protecting Surface Water—Protecting Surface Water
6-21
Protecting Surface Water—Protecting Surface Water
6-22
Protecting Surface Water—Protecting Surface Water
binder, or soil palliative) can hold the soil in to accommodate the design storm event and
place and protect against erosion by spraying are kept clear of clogs.
vinyl, asphalt, or rubber onto soil surfaces.
Erosion and sediment control is immediate Silt Fences, Straw Bales, and Brush Barriers
upon spraying and does not depend on cli-
Silt fences and straw bales (see Figures 3
mate or season. Stabilizer should be applied
and 4) are temporary measures designed to
according to manufacturer’s instructions to
capture sediment that has already eroded and
ensure that water quality is not affected.
reduce the velocity of storm water. Silt fences
Coating large areas with thick layers of stabi-
and straw bales should not be considered
lizer, however, can create an impervious sur-
permanent measures unless fences are main-
face and speed runoff to downgradient areas
tained on a routine basis and straw bales are
and should be avoided.
replaced regularly. They could be used, for
example, during construction of a waste man-
Interceptor Dikes and Swales agement unit or on a final cover before per-
Dikes (ridges of compacted soil) and manent grass growth is established.
swales (excavated depressions in which storm
Silt fences consist of geotextile fabric sup-
water flows) work together to prevent entry
ported by wooden posts. These fences slow
of run-on into erodible areas. A dike is built
the flow of storm water and retain sediment as
across a slope upgradient of an area to be
the water filters through the fabric. If properly
protected, such as a waste management unit,
installed, straw bales perform a similar func-
with a swale just above the dike. Water flows
tion. Straw bales should be placed end to end
down the slope, accumulates in the swale,
(with no gaps in between) in a shallow, exca-
and is blocked from exiting it by the dike.
vated trench and staked into place. Silt fences
The swale is graded to direct water slowly
and straw bales limit sediment from entering
downhill across the slope to a stabilized out-
receiving waters if properly maintained. Both
let structure. Since flows are concentrated in
measures require frequent inspection and
the swale, it is important to vegetate the
maintenance, including checking for channels
swale to prevent erosion of its channel and to
eroded beneath the fence or bales, removing
grade it so that predicted flows will not dam-
age the vegetation.
6-23
Protecting Surface Water—Protecting Surface Water
Storm Drain Inlet Protection Bottom: Perspective of silt fence. Top: Cross-
Filtering measures placed around inlets or section detail of base of silt fence.
drains to trap sediment are known as inlet
From U.S. EPA, 1992e.
protection (see Figure 5). These measures
prevent sediment from entering inlets or Figure 4. Straw Bale
drains and possibly making their way to the
receiving waters into which the storm
drainage system discharges. Keeping sediment
out of storm-water drainage systems also
serves to prevent clogging, loss of capacity,
and other problems associated with siltation
of drainage structures. Inlet protection meth-
ods include sod, excavated areas for settle-
ment of sediment, straw bales or filter fences,
and gravel or stone with wire mesh. These
measures are appropriate for inlets draining From U.S. EPA, 1992e.
small areas where soil will be disturbed. Some
state or local jurisdictions require installation enough to allow most of the sediment to set-
of these measures before disturbance of more tle out and accumulate on the bottom of the
than a certain acreage of land begins. Regular basin. Since many pollutants are attached to
maintenance to remove accumulated sedi- suspended solids, they will also settle out in
ment is important for proper operation. the basin with the sediment. The quantity of
sediment removed will depend on basin vol-
Collection and Sedimentation Basins ume, inlet and outlet configuration, basin
A collection or sedimentation basin (see depth and shape, and retention time. Regular
Figure 6) is an area that retains runoff long maintenance and dredging to remove accu-
6-24
Protecting Surface Water—Protecting Surface Water
6-25
Protecting Surface Water—Protecting Surface Water
6-26
Protecting Surface Water—Protecting Surface Water
or where wells, foundations, or septic fields feet deep. It is filled with stone to allow for
are nearby. temporary storage of storm water in the open
spaces between the stones. The water eventu-
Vegetated Filter Strips and Grassed Swales ally infiltrates the surrounding soil or is col-
lected by perforated pipes in the bottom of
Vegetated filter strips are gently sloped
the trench and conveyed to an outflow point.
areas of natural or planted vegetation. They
Such trenches can remove fine sediments and
allow water to pass over them in sheetflow
(runoff that flows in a thin, even layer), infil-
trate the soil, and drop sediment. Vegetated Figure 7. Outlet Protection
filter strips are appropriate where soils are
well draining and the ground-water table is
deep below the surface. They will not work
effectively on slopes of 15 percent or more
due to high runoff velocity. Strips should be
at least 20 feet wide and 50 to 75 feet long in
general, and longer on steeper slopes. If pos-
sible, it is best to leave existing natural vege-
tation in place as filter strips, rather than
planting new vegetation, which will not func-
tion to capture eroded particles until it
becomes established.
Grassed swales function similarly to non-
vegetated swales (discussed earlier in this
chapter) except that grass planted along the
swale bottom and sides will slow water flow
and filter out sediment. Permeable soil in
which the swale is cut encourages reduction
of water volume through infiltration. Check
dams (discussed earlier in this chapter) are
sometimes provided in grassed swales to fur-
ther slow runoff velocity, increasing the rate
of infiltration.
To optimize swale performance, it is best
to use a soil which is permeable but not
excessively so; very sandy soils will not hold
vegetation well and will not form a stable
channel structure. It is also recommended
that you grade the swale to a very gentle
slope to maximize infiltration.
Infiltration Trenches
An infiltration trench (see Figure 8) is a From U.S. EPA, 1992e.
long, narrow excavation ranging from 3 to 12
6-27
Protecting Surface Water—Protecting Surface Water
6-28
Protecting Surface Water—Protecting Surface Water
dled appropriately. Discharge of such waste provisions for a dry-weather flow to maintain
water requires an NPDES permit other than the wetlands, 3) measures to limit mosquito
the Multi-Sector General Permit. breeding, 4) structures to prevent escape of
floating wetland plants (such as water
Discharges to Wetlands hyacinths) into downstream areas where they
are undesirable, and 5) a program of harvest-
Discharge to constructed wetlands is a
ing and replacing plants.
method less frequently used and can involve
complicated designs. The discharge of storm
water into natural wetlands, or the modifica- B. Controls to Address
tion of wetlands to improve their treatment Surface-water
capacity, can damage a wetland ecosystem
and, therefore, is subject to federal, state, and Contamination from
local regulations. Ground Water to
Constructed wetlands provide an alterna- Surface Water
tive to natural wetlands. A specially designed Generally, the use of liners and ground-
pond or basin, which is lined in some cases, water monitoring systems will reduce poten-
is stocked with wetland plants that can con- tial contamination from ground water to
trol sedimentation and manage pollutants surface water. For more information on pro-
through biological uptake, microbial action, tecting ground water, refer to Chapter 7:
and other mechanisms. Together, these Sections A–Assessing Risk, Section
processes often result in better pollutant B–Designing and Installing Liners, and
removal than would be expected from sedi- Section C–Designing a Land Application
mentation alone. When designing construct- Program.
ed wetlands, you should consider 1) that
maintenance might include dredging, similar
to that required for sedimentation basins, 2) C. Controls to Address
Surface-water
Contamination from Air
What are some advantages of
constructed wetlands? to Surface Water
Provide aesthetic as well as water qual- Emission control techniques for volatile
ity benefits and areas for wildlife habitat. organic compounds (VOC) and particulates
can assist in reducing potential contamination
of surface water from air. Refer to Chapter
What are some disadvantages of 5–Protecting Air Quality, for more informa-
constructed wetlands? tion on air emission control techniques.
Discharges to wetlands might be sub-
ject to multiple federal, state, and local
regulations. In addition, constructed
wetlands might not be feasible if land is
not available and might not be effective
as a storm-water control measure until
time has been allowed for substantial
plant growth.
6-29
Protecting Surface Water—Protecting Surface Water
6-30
Protecting Surface Water—Protecting Surface Water
5
TR-55, Urban Hydrology for Small Watersheds Technical Release 55, presents simplified procedures to
calculate storm runoff volume, peak rate of discharge, hydrographs, and storage volumes required for
floodwater reservoirs. This software is suited for use in small and especially urbanizing watersheds. TR-
55 can be downloaded from the National Resource Conservation Service at
<www.wcc.nrcs.usda.gov/water/quality/common/tr55/tr55.html>. 6-31
Protecting Surface Water—Protecting Surface Water
6-32
Protecting Surface Water—Protecting Surface Water
6-33
Protecting Surface Water—Protecting Surface Water
Resources
Dingman, S. 1994. Physical Hydrology. Prentice Hall.
Florida Department of Environmental Regulation. Storm Water Management: A Guide for Floridians.
Novotny, V., and H. Olem. 1994. Water Quality: Prevention, Identification, and Management of Diffuse
Pollution. Van Nostrand Reinhold.
Pitt, R. 1988. Source Loading and Management Model: An Urban Nonpoint Source Water Quality Model
(SLAMM). University of Alabama at Birmingham.
McGhee, T. 1991. McGraw-Hill Series in Water Resources and Environmental Engineering. 6th Ed.
Urbonas, B., and P. Stahre. 1993. Storm Water: Best Management Practices and Detention for Water Quality,
Drainage, and CSO Management. PTR Prentice Hall.
U.S. EPA. 1998. Water Quality Criteria and Standards Plan–Priorities for the Future. EPA822-R-98-003.
U.S. EPA. 1995a. Process Design Manual: Land Application of Sewage Sludge and Domestic Septage. EPA625-
R-95-001.
U.S. EPA. 1995b. Process Design Manual: Surface Disposal of Sewage Sludge and Domestic Septage. EPA625-
R-95-002.
U.S. EPA. 1995c. NPDES Storm Water Multi-Sector General Permit Information Package.
U.S. EPA. 1995d. Storm Water Discharges Potentially Addressed by Phase II of the National Pollutant
Discharge Elimination System Storm Water Program. Report to Congress. EPA833-K-94-002.
U.S. EPA. 1994b. Project Summary: Potential Groundwater Contamination from Intentional and Non-
Intentional Storm Water Infiltration. EPA600-SR-94-061.
U.S. EPA. 1994c. Storm Water Pollution Abatement Technologies. EPA 600-R-94-129.
6-34
Protecting Surface Water—Protecting Surface Water
Resources (cont.)
U.S. EPA. 1993a. Overview of the Storm Water Program. EPA833-F-93-001.
U.S. EPA. 1993b. NPDES Storm Water Program: Question and Answer Document, Volume 2. EPA833-
F093-002B.
U.S. EPA. 1992a. An Approach to Improving Decision Making in Wetland Restoration and Creation.
EPA600-R-92-150.
U.S. EPA. 1992b. NPDES Storm Water Program: Question and Answer Document, Volume 1. EPA833-F-
93-002.
U.S. EPA. 1992c. NPDES Storm Water Sampling Guidance Document. EPA833-B-92-001.
U.S. EPA. 1992e. Storm Water Management for Industrial Activities: Developing Pollution Prevention Plans
and Best Management Practices. EPA832-R-92-006.
U.S. EPA. 1992f. Storm Water Management for Industrial Activities: Developing Pollution Prevention Plans
and Best Management Practices. Summary Guidance. EPA833-R-92-002.
Viessman Jr., W., and M.J. Hammer. 1985. Water Supply and Pollution Control. 4th Ed.
Washington State Department of Ecology. 1993. Storm Water Pollution Prevention Planning for Industrial
Facilities: Guidance for Developing Pollution Prevention Plans and Best Management Practices. Water
Quality Report. WQ-R-93-015. September.
6-35
Part IV
Protecting Ground-Water Quality
Chapter 7: Section A
Assessing Risk
Contents
Resources ....................................................................................................................................................7A-41
Tables:
Table 1. Earth’s Water Resources ................................................................................................................7A-1
Table 2. Examples of Attenuation Processes ............................................................................................7A-10
Table 3. List of Constituents in IWEM with Maximum Contaminant Levels (MCLs) ..............................7A-13
Contents
Table 4. Example of Tier 1 Summary Table for MCL-based LCTVs for Landfill - No Liner/In situ Soils ..7A-24
Table 5. Example of Tier 1 Summary Table for HBN-based LCTVs for Landfill - No Liner/In situ Soils 7A-25
Table 6. Example of Tier 1 Summary Table for MCL-based LCTVs for Landfill - Single Clay Liner ...... 7A-25
Table 7. Example of Tier 1 Summary Table for MCL-based LCTVs for Landfill - Composite Liner ........ 7A-25
Table 8. Input Parameters for Tier 2 ........................................................................................................7A-29
Table 9. A Sample Set of Site-Specific Data for Input to Tier 2 ................................................................7A-31
Table 10. Example of Tier 2 Detailed Summary Table - No Liner/In situ Soils ........................................7A-31
Table 11. Example of Tier 2 Detailed Summary Table - Single Clay Liner................................................7A-32
Table 12. Example Site-Specific Ground-water Fate and Transport Models..............................................7A-38
Table 13. ASTM Ground-Water Modeling Standards ..............................................................................7A-39
Figures:
Figure 1: Representation of Contaminant Plume Movement ......................................................................7A-5
Figure 2: Three Liner Scenarios Considered in the Tiered Modeling Approach for Industrial
Waste Guidelines ......................................................................................................................7A-22
Figure 3: Using Tier 1 Lookup Tables ......................................................................................................7A-27
Protecting Ground Water—Assessing Risk
Assessing Risk
This chapter will help you:
• Protect ground water by assessing risks associated with new waste
management units and tailoring management controls accordingly.
• Understand the three-tiered evaluation discussed in this chapter
that can be used to determine whether a liner system is necessary,
and if so, which liner system is recommended, or whether land
application is appropriate.
• Follow guidance on liner design and land application practices.
G
round water is Table 1.
the water found Earth’s Water Resources
in the soil and
rock that make Resource Percent of Percent of
Total Nonoceanic
up the Earth’s
surface. Although it com- Oceans 97.25 —
prises only about 0.69 per-
cent of the Earth’s water Ice caps and glaciers 2.05 74.65
resources, ground water is of Ground water and soil moisture 0.685 24.94
great importance. It repre-
Lakes and rivers 0.0101 0.37
sents about 25 percent of
fresh water resources, and Atmosphere 0.001 0.036
when the largely inaccessible Biosphere 0.00004 0.0015
fresh water in ice caps and
glaciers is discounted, Adapted from Berner, E.K. and R. Berner. 1987. The Global
ground water is the Earth’s
Water Cycle: Geochemistry and Environment
largest fresh water
resource—easily surpassing
percent of the total water used by industry.2
lakes and rivers, as shown in Table 1.
Ground water also has other important environ-
Statistics about the use of ground water as a
mental functions, such as providing recharge to
drinking water source underscore the impor-
lakes, rivers, wetlands, and estuaries.
tance of this resource. Ground water is a
source of drinking water for more than half of Water beneath the ground surface occurs in
the people in the United States. In rural
1
an upper unsaturated (vadose) zone and a
areas, 97 percent of households rely on deeper saturated zone. The unsaturated zone
ground water as their primary source of is the area above the water table where the
drinking water. soil pores are not filled with water, although
some water might be present. The subsurface
In addition to its importance as a domestic
area below the water table where the pores
water supply, ground water is heavily used by
and cracks are filled with water is called the
industry and agriculture. It provides approxi-
saturated zone. This chapter focuses on
mately 37 percent of the irrigation water and 18
1
Surface water, in the form of lakes and rivers, is the other major drinking water source. Speidel, D., L.
Ruedisili, and A. Agnew. 1988. Perspectives on Water: Uses and Abuses.
2
Excludes cooling water for steam-electric power plants. U.S. Geological Survey. 1998. Estimated Use of 7A-1
Water in the United States in 1995.
Protecting Ground Water—Assessing Risk
Runoff
potential threats to the quali- Saturated
Zone
ty of ground water exist,
Groundwater
such as the leaching of fertil- Lake
Groundwater flow
Flow
7A-2
Protecting Ground Water—Assessing Risk
this chapter is available in the companion in the future, and the likelihood that such
documents to the IWEM software: User’s contact will harm these people. This process
Guide for the Industrial Waste Management shows how great (or small) the risks might
Evaluation Model (U.S. EPA, 2002b), and be. It also points to who is at risk, what is
Industrial Waste Management Evaluation Model causing the risk, and how certain one can be
(IWEM) Technical Background Document (U.S. about the risks. A general overview of these
EPA, 2002a). steps is presented below to help explain how
the process is used in performing the assess-
ments associated with IWEM. The compo-
I. Assessing Risk nents of a risk assessment that are discussed
in this section are: problem formulation,
exposure assessment, toxicity assessment, and
A. General Overview of the risk characterization. Each of these steps is
Risk Assessment Process described as it specifically applies to risk
resulting from the release of chemical con-
Our ground-water resources are essential stituents from WMUs to ground water.
for biotic life on the planet. They also act as a
medium for the transport of contaminants
and, therefore, constitute an exposure path- 1. Problem Formulation
way of concern. Leachate from WMUs can be The first step in the risk assessment
a source of ground-water contamination. process is problem formulation. The purpose
Residents who live close to a WMU and who of this step is to clearly define the risk ques-
use wells for water supply can be directly tion to be answered and identify the objec-
exposed to waste constituents by drinking or tives, scope, and boundaries of the
bathing in contaminated ground water. assessment. This phase can be viewed as
Residents also can be exposed by inhaling developing the overall risk assessment study
volatile organic compounds (VOCs) and design for a specific problem. Activities that
semi-volatile organic compounds (SVOCs) might occur during this phase include:
that are released indoors while using ground
• Articulating a clear understanding of
water for showering or via soil gas migration
the purpose and intended use of the
from subsurface plumes.
risk assessment.
The purpose of this section is to provide
• Identifying the constituents of concern.
general information on the risk assessment
process and a specific description of how • Identifying potential release scenarios.
each of the areas of risk assessment is applied
• Identifying potential exposure path-
in performing ground-water risk analyses.
ways.
Greater detail on each of the steps in the
process as they relate to assessing ground- • Collecting and reviewing available
water risk is provided in later sections of this data.
chapter. • Identifying data gaps.
In any risk assessment, there are basic • Recommending data collection
steps that are necessary for gathering and efforts.
evaluating data. This Guide uses a four-part
process to estimate the likelihood of chemi- • Developing a conceptual model of
cals coming into contact with people now or what is occurring at the site.
7A-3
Protecting Ground Water—Assessing Risk
Although this step can be formal or infor- of data will be useful in determining the
mal, it is critical to the development of a suc- potential for exposure to and intake of con-
cessful assessment that fully addresses the stituents.
problem at hand. In addition, the develop-
The next step in this process includes
ment of a conceptual model helps direct the
identifying exposure pathways through
next phases of the assessment and provides a
ground water and estimating exposure con-
clear understanding of the scope and design
centrations at the well3. In modeling the
of the assessment.
movement of the constituents away from the
WMU, the Guide generally assumes that the
2. Exposure Assessment constituents behave as a plume (see Figure
The goals of an exposure assessment are 1), and the plume’s movement is modeled to
to: 1) characterize the source, 2) characterize produce estimated concentrations of con-
the physical setting of the area that contains stituents at points of interest. As shown in
the WMU, 3) identify potential exposure Figure 1, the unsaturated zone receives
pathways, 4) understand the fate and trans- leachate from the WMU. In general, the flow
port of constituents of concern, and 5) calcu- in the unsaturated zone tends to be gravity-
late constituent doses. driven, although other factors (e.g., soil
porosity, capillarity, moisture potential) can
Source characterization involves defining also influence downward flow.
certain key parameters for the WMU. The
accuracy of predicting risks improves as more Transport through the unsaturated zone
site-specific information is used in the char- delivers constituents to the saturated zone, or
acterization. In general, critical aspects of the aquifer. Once the contaminant arrives at the
source (e.g., type of WMU, size, location, water table, it will be transported downgradi-
potential for leachate generation, and expect- ent toward wells by the predominant flow
ed constituent concentrations in leachate) field in the saturated zone. The flow field is
should be obtained. Knowledge of the overall governed by a number of hydrogeologic and
composition of the waste deposited in the climate-driven factors, including regional
WMU and of any treatment processes occur- hydraulic gradient, hydraulic conductivity of
ring in the WMU is important to determine the saturated zone, saturated zone thickness,
the overall characteristics of the leachate that local recharge rate (which might already be
will be generated. accounted for in the regional hydraulic gradi-
ent), and infiltration rate through the WMU.
The second step in evaluating exposure is
to characterize the site with respect to its The next step in the process is to estimate
physical characteristics, as well as those of the exposure concentrations at a well. Many
the human populations near the site. processes can occur in the unsaturated zone
Important site characteristics include climate, and in the saturated zone that can influence
meteorology, geologic setting, and hydrogeol- the concentrations of constituents in leachate
ogy. Consultation with appropriate technical in a downgradient well. These processes
experts (e.g., hydrogeologists, modelers) include dilution and attenuation, partitioning
might be needed to characterize the site. to solid, hydrolysis, and degradation.
Characterizing the populations near the site Typically, these factors should be considered
with respect to proximity to the site, activity when estimating the expected constituent
patterns, and the presence of sensitive sub- concentrations at a receptor.
groups might also be appropriate. This group
3
In this discussion and in IWEM, the term “well” is used to represent an actual or hypothetical ground-
water monitoring well or drinking water well, located downgradient from a WMU.
7A-4
Protecting Ground Water—Assessing Risk
Well
C Land Surface
Leachate
Unsaturated
Zone
Water Table
DAF
Saturated
Zone Leachate Plume
The final step in this process is estimating exposed individuals. It is also meant to pro-
the dose. The dose is determined based on vide, where possible, an estimate of the rela-
the concentration of a constituent in a medi- tionship between the extent of exposure to a
um and the intake rate of that medium for constituent and the increased likelihood
the receptor. For example, the dose is depen- and/or severity of adverse effects. The intent
dent on the concentration of a constituent in is to establish a dose-response relationship
a well and the ingestion rate of ground water between a constituent concentration and the
from that well by the receptor. The intake incidence of an adverse effect. It is usually a
rate is dependent on many behavior patterns, five-step process that includes: 1) gathering
including ingestion rate, exposure duration, toxicity information for the substances being
and exposure frequency. In addition, a risk evaluated, 2) identifying the exposure periods
assessor should consider the various routes of for which toxicity values are necessary, 3)
exposure (e.g., ingestion, inhalation) to deter- determining the toxicity values for noncar-
mine a dose. cinogenic effects, 4) determining the toxicity
values for carcinogenic effects, and 5) sum-
After all of this information has been col-
marizing the toxicity information. The deriva-
lected, the exposure pathways at the site can
tion and interpretation of toxicity values
be characterized by identifying the potentially
requires toxicological expertise and should
exposed populations, exposure media, expo-
not be undertaken by those without training
sure points, and relevant exposure routes and
and experience. It is recommended that you
then calculating potential doses.
contact your state regulatory agency for more
specific guidance.
3. Toxicity Assessment
The purpose of a toxicity assessment is to 4. Risk Characterization
weigh available evidence regarding the poten-
This step involves summarizing and inte-
tial for constituents to cause adverse effects in
grating the toxicity and exposure assessments
7A-5
Protecting Ground Water—Assessing Risk
7A-6
Protecting Ground Water—Assessing Risk
of constituents among the aqueous, vapor, Information about constituent toxicity can be
and solid phases. Temperature, pH, pressure, collected from publicly available resources
chemical composition,4 and the presence of such as the Integrated Risk Information
microorganisms within WMUs may have sig- System (IRIS) <www.epa.gov/iris> or from
nificant effects on the concentration of con- detailed, chemical-specific literature searches.
stituents available for release in the leachate. The conceptual model should attempt to
Another waste characteristic that can influ- identify the toxicity data that are most rele-
ence leachate production is the presence of vant to likely routes of ground-water expo-
organic wastes as free liquids, also called sure and identify areas requiring additional
non-aqueous phase liquids (NAPLs). The research. The conceptual model should pro-
presence of NAPLs may affect the mobility of vide a draft plan of action for the next phases
constituents based on saturation and viscosi- of the risk assessment.
ty. Finally, characteristics such as acidity and
alkalinity can influence leachate generation
2. Exposure Assessment
by affecting the permeability of underlying
soil or clay. Exposure assessment is generally com-
prised of two components: characterization of
the exposure setting and identification of the
b. Development of a Conceptual exposure pathways. Characterization of the
Model exposure setting includes describing the
The development of a conceptual model is source characteristics and the site characteris-
important for defining what is needed for the tics. Identification of the exposure pathway
exposure assessment and the toxicity assess- involves understanding the process by which
ment. The conceptual model identifies the a constituent is released from a source, travels
major routes of exposure to be evaluated and to a receptor, and is taken up by the receptor.
presents the current understanding of the This section discusses the concepts of charac-
toxicity of the constituents of concern. terizing the source, characterizing the site set-
For the ground-water pathway, the concep- ting, understanding the general dynamics of
tual model identifies those pathways on contaminant fate and transport (or movement
which the risk assessor should focus. of harmful chemicals to a receptor), identify-
Potential pathways of interest include ground ing exposure pathways, and calculating the
water used as drinking water, ground water dose to (or uptake by) a receptor.
used for other domestic purposes that might
release volatile organics, ground-water releas- a. Source Characterization
es to surface water, vapor intrusion from The characteristics of a source greatly
ground-water gases to indoor air, and ground influence the release of leachate to ground
water used as irrigation water. The conceptu- water. Some factors to consider include the
al model should address the likelihood of type of WMU, the size of the unit, and the
various ground-water pathways under present design and management of the unit. The type
or future circumstances, provide insight to of WMU is important because each unit has
the likelihood of contact with receptors distinct characteristics that affect release.
through the various pathways, and identify Landfills, for example, tend to be permanent
areas requiring further information. in nature, which provides a long time period
The conceptual model should also address for leachate generation. Waste piles, on the
the toxicity of the constituents of concern. other hand, are temporary in design and
4
Generally, the model considers a high ratio of solids to leachate, and therefore, the user should consider
this before applying a 20 to 1 solids to leachate ratio.
7A-7
Protecting Ground Water—Assessing Risk
7A-8
Protecting Ground Water—Assessing Risk
areas that are designated as potential sources movement of waste constituents can be
of underground drinking water. expected through coarse-textured materials,
such as sand and gravel, than through fine-
c. Understanding Fate and Transport textured materials, such as silt and clay. Other
key flow and transport parameters include
In general, the flow in the unsaturated zone dispersivity (which determines how far a
tends to be gravity-driven. As shown in Figure plume will spread horizontally and vertically
1, the unsaturated zone receives leachate infil- as it moves away from the source) and porosi-
tration from the WMU. Therefore, the vertical ty (which determines the amount of pore
flow component accounts for most of the fluid space in the geologic materials in the unsatu-
flux between the base of the WMU and the rated and saturated zone used for flow and
water table. Water-borne constituents are car- transport and can affect transport velocity).
ried vertically downward toward the water
table by the advection process. Mixing and As waste constituents migrate through the
spreading occur as a result of hydrodynamic unsaturated and saturated zones, they can
dispersion and diffusion. Transport processes undergo a number of biochemical and
in the saturated zone include advection, physicochemical processes that can lead to a
hydrodynamic dispersion, and sorption. reduction in concentration of potential
Advection is the process by which con- ground-water contaminants. These processes
stituents are transported by the motion of the are collectively referred to as attenuation
flowing ground water. Hydrodynamic disper- processes. Attenuation processes can remove
sion is the tendency for some constituents to or degrade waste constituents through filtra-
spread out from the path that they would be tion, sorption, precipitation, hydrolysis, bio-
expected to flow. Sorption is the process by logical degradation, bio-uptake, and redox
which leachate molecules adhere to the sur- reactions. Some of these processes (e.g.,
face of individual clay, soil, or sediment parti- hydrolysis, biological degradation) can actual-
cles. Attenuation of some chemicals in the ly result in the formation of different chemi-
unsaturated zone is attributable to various cals and greater toxicity. Attenuation
biochemical or physicochemical processes, processes are dependent upon several factors,
such as degradation and sorption. including ground-water pH, ground-water
temperature, and the presence of other com-
The type of geological material below the pounds in the subsurface environment. Table
unit affects the rate of movement because of 2 provides additional information on attenua-
differences in hydraulic and transport proper- tion processes.
ties. One of the key parameters controlling
contaminant migration rates is hydraulic con-
ductivity. The larger the hydraulic conductivi- d. Exposure Pathways
ty, the greater the potential migration rate due A complete exposure pathway usually con-
to lower hydraulic resistance of the formation. sists of four elements: 1) a source and mecha-
Hydraulic conductivity values of some hydro- nism of chemical release, 2) a retention or
geologic environments, such as bedded sedi- transport medium (in this case, ground
mentary rock aquifers, might not be as large water), 3) a point of potential human contact
as those of other hydrogeologic environments, with the contaminated medium (often referred
such as sand and gravel or fractured lime- to as the exposure point), and 4) an exposure
stone. As a general principle, more rapid route (e.g., ingestion). Residents who live near
7A-9
Protecting Ground Water—Assessing Risk
Table 2:
Examples of Attenuation Processes
Biological degradation: Decomposition of a substance into more elementary compounds by action
of microorganisms such as bacteria. Sullivan. 1993. Environmental Regulatory Glossary, 6th Ed.
Government Institutes.
Bio-uptake: The uptake and (at least temporary) storage of a chemical by an exposed organism. The
chemical can be retained in its original form and/or modified by enzymatic and non-enzymatic reac-
tions in the body. Typically, the concentrations of the substance in the organism exceed the concentra-
tions in the environment since the organism will store the substance and not excrete it. Sullivan. 1993.
Environmental Regulatory Glossary, 6th Ed. Government Institutes.
Filtration: Physical process whereby solid particles and large dissolved molecules suspended in a
fluid are entrapped or removed by the pore spaces of the soil and aquifer media. Boulding, R. 1995.
Soil, Vadose Zone, and Ground-Water Contamination: Assessment, Prevention, and Remediation.
Hydrolysis: A chemical process of decomposition in which the elements of water react with another
substance to yield one or more entirely new substances. This transformation process changes the chem-
ical structure of the substance. Sullivan. 1993. Environmental Regulatory Glossary, 6th Ed. Government
Institutes.
Oxidation/Reduction (Redox) reactions: Involve a transfer of electrons and, therefore, a change in
the oxidation state of elements. The chemical properties for elements can change substantially with
changes in the oxidation state. U.S. EPA. 1991. Site Characterization for Subsurface Remediation.
Precipitation: Chemical or physical change whereby a contaminant moves from a dissolved form in
a solution to a solid or insoluble form. It reduces the mobility of constituents, such as metals. Unlike
sorption, precipitation is not generally reversible. Boulding, R. 1995. Soil, Vadose Zone, and Ground-
Water Contamination: Assessment, Prevention, and Remediation.
Sorption: The ability of a chemical to partition between the liquid and solid phase by determining
its affinity for adhering to other solids in the system such as soils or sediments. The amount of chemi-
cal that "sorbs" to solids is dependent upon the characteristics of the chemical, the characteristics of the
surrounding soils and sediments, and the quantity of the chemical. Sorption generally is reversible.
Sorption often includes both adsorption and ion exchange.
a site might use ground water for their water beneath houses. This pathway is character-
supply, and thus, the exposure point would be ized by the vapors seeping into households
a well. Exposure routes typical of residential through the cracks and holes in basements
use of contaminated ground water include and concrete slabs. In some cases, concentra-
direct ingestion through drinking water, der- tions of constituents can reach levels that pre-
mal contact while bathing, and inhalation of sent chronic health hazards. Factors that can
VOCs during showering or from other house- contribute to the potential for vapor intrusion
hold water uses (e.g., dishwashers). include the types of constituents present in
the ground water, the presence of pavement
Another potential pathway of concern is
or frozen surface soils (which result in higher
exposure to ground-water constituents from
subsurface pressure gradients and greater
the intrusion of vapors of VOCs and SVOCs
transport), and the presence of subsurface
through the basements and concrete slabs
7A-10
Protecting Ground Water—Assessing Risk
gases such as methane that affect the rate of contaminants to cause adverse effects in
transport of other constituents. Because of the exposed individuals, and where possible, pro-
complexity of this pathway and the evolving vides an estimate of the increased likelihood
science regarding this pathway, IWEM focuses and severity of adverse effects as a result of
on the risks and pathways associated with exposure to a contaminant. IWEM uses two
residential exposures to contaminated ground different toxicity measures—maximum conta-
water. If exposure through this route is likely, minant levels (MCLs) and health-based num-
the user might consider Tier 3 modeling to bers (HBNs). Each of these measures is based
assess this pathway. EPA is planning to issue a on toxicity values reflecting a cancer or non-
reference document regarding the vapor cancer effect. Toxicity data are based on
intrusion pathway in the near future. human epidemiologic data, animal data, or
other supporting studies (e.g., laboratory
e. Dose Calculation studies). In general, data can be used to char-
acterize the potential adverse effect of a con-
The final element of the exposure assess- stituent as either carcinogenic or
ment is the dose calculation. The dose to a non-carcinogenic. For the carcinogenic effect,
receptor is a function of the concentration at EPA generally assumes there is a non-thresh-
the exposure point (i.e, the well) and the old effect and estimates a risk per unit dose.
intake rate by the receptor. The concentration For the noncarcinogenic effect, EPA generally
at the exposure point is based on the release assumes there is a threshold below which no
from the source and the fate and transport of adverse effects occur. The toxicity values used
the constituent. The intake rate is dependent in IWEM include:
on the exposure route, the frequency of expo-
sure, and the duration of exposure. • Oral cancer slope factors (CSFo) for
oral exposure to carcinogenic conta-
EPA produced the Exposure Factors minants.
Handbook (U.S. EPA, 1997a) as a reference for
providing a consistent set of exposure factors • Reference doses (RfD) for oral expo-
to calculate the dose. This reference is avail- sure to contaminants that cause non-
able from EPA’s National Center for cancer health effects.
Environmental Assessment Web site • Inhalation cancer slope factors (CSFi)
<www.epa.gov/ncea>. The purpose of the derived from Unit Risk Factors
handbook is to summarize data on human (URFs) for inhalation exposure to car-
behaviors and physical characteristics (e.g., cinogenic contaminants.
body weight) that affect exposure to environ-
mental contaminants and recommend values • Reference concentrations (RfC) for
to use for these factors. The result of a dose inhalation exposure to contaminants
calculation is expressed as a contaminant con- that cause noncancer health effects.
centration per unit body weight per unit time EPA defines the cancer slope factor (CSF)
that can then be used as the output of the as, “an upper bound, approximating a 95 per-
exposure assessment for the risk characteriza- cent confidence limit, on the increased cancer
tion phase of the analysis. risk from a lifetime exposure to an agent [con-
taminant].” Because the CSF is an upper
3. Toxicity Assessment bound estimate of increased risk, EPA is rea-
sonably confident that the “true risk” will not
A toxicity assessment weighs available evi-
exceed the risk estimate derived using the CSF
dence regarding the potential for particular
and that the “true risk” is likely to be less than
7A-11
Protecting Ground Water—Assessing Risk
predicted. CSFs are expressed in units of pro- million individuals exposed to the contami-
portion (of a population) affected per mil- nant. Lower concentrations of the contami-
ligram/kilogram-day (mg/kg-day). For nant are not likely to cause adverse health
noncancer health effects, the RfD and the RfC effects. Exceptions might occur, however, in
are used as health benchmarks for ingestion individuals exposed to multiple contaminants
and inhalation exposures, respectively. RfDs that produce the same health effect. Similarly,
and RfCs are estimates of daily oral exposure a higher incidence of cancer among sensitive
or of continuous inhalation exposure, respec- subgroups, highly exposed subpopulations, or
tively, that are likely to be without an appre- populations exposed to more than one cancer-
ciable risk of adverse effects in the general causing contaminant might be expected. As
population, including sensitive individuals, noted previously, the exposure factors used to
over a lifetime. The methodology used to calculate HBNs are described in the Exposure
develop RfDs and RfCs is expected to have an Factors Handbook (U.S. EPA, 1997a).
uncertainty spanning an order of magnitude.
4. Risk Characterization
a. Maximum Contaminant Levels Risk characterization is the integration of
(MCLs) the exposure assessment and the toxicity
MCLs are maximum permissible contami- assessment to generate qualitative and quan-
nant concentrations allowed in public drink- titative expressions of risk. For carcinogens,
ing water and are established under the Safe the target risk level used in IWEM to calcu-
Drinking Water Act. For each constituent to late the HBNs is 1 x 10-6. A risk of 1 x 10-6
be regulated, EPA first sets a Maximum describes an increased chance of one in a
Contaminant Level Goal (MCLG) as a level million of a person developing cancer over a
that protects against health risks. The MCL lifetime, due to chronic exposure to a specific
for each contaminant is then set as close to chemical. The target hazard quotient used to
its MCLG as possible. In developing MCLs, calculate the HBNs for noncarcinogens is 1.
EPA considers not only the health effects of A hazard quotient of 1 indicates that the esti-
the constituents, but also additional factors, mated dose is equal to the RfD (the level
such as the cost of treatment, available ana- below which no adverse effect is expected).
lytical and treatment technologies. Table 3 An HQ of 1, therefore, is frequently EPA’s
lists the 57 constituents that have MCLs that threshold of concern for noncancer effects.
are incorporated in IWEM. These targets are used to calculate unique
HBNs for each constituent of concern and
b. Health-based Numbers (HBNs). each exposure route of concern (i.e., inges-
tion or inhalation).
The parameters that describe a chemical’s
toxicity and a receptor’s exposure to the chem- Usually, doses less than the RfD (HQ = 1)
ical are considered in calculation of the are not likely to be associated with adverse
HBN(s) of that chemical. HBNs are the maxi- health effects and, therefore, are less likely to
mum contaminant concentrations in ground be of regulatory concern. As the frequency or
water that are not expected to cause adverse magnitude of the exposures exceeding the
noncancer health effects in the general popula- RfD increase (HQ > 1), the probability of
tion (including sensitive subgroups) or that adverse effects in a human population
will not result in an additional incidence of increases. However, it should not be categori-
cancer in more than approximately one in one cally concluded that all doses below the RfD
7A-12
Protecting Ground Water—Assessing Risk
Table 3.
List of Constituents in IWEM with Maximum Contaminant Levels (MCLs)
(States can have more stringent standards than federal MCLs.)
7A-13
Protecting Ground Water—Assessing Risk
are “acceptable’’ (or will be risk-free) and that screening. If the use of Tier 1 provides an
all doses in excess of the RfD are “unaccept- agreeable assessment, the conservative nature
able’’ (or will result in adverse effects). For of the model can be relied upon, and the
IWEM, the output from the risk characteriza- additional resources required for further
tion helps determine with 90 percent proba- analysis can be avoided. Of course, where
bility (i.e., with a confidence that for 90 there is concern with the results from Tier 1,
percent of the realizations) whether or not a a more precise assessment of risk at the
design system is protective (i.e., has a cancer planned unit location should be conducted.
risk of < 1 x 10-6, non-cancer hazard quotient The second approach is to try and accommo-
of < 1.0). IWEM does not address the cumu- date many of the most important site-specific
lative risk due to simultaneous exposure to factors in a simplified form, useable by indus-
multiple constituents. The results of the risk try, state, and environmental representatives.
assessment might encourage the user to con- This model, labeled Tier 2, is available as part
duct a more site-specific analysis, or consider of this Guide, and is a major new step in
opportunities for waste minimization or pol- moving EPA guidance away from national,
lution prevention. “one size fits all” approaches. Third, a site-
specific risk analysis can be conducted. This
approach should provide the most precise
II. The IWEM assessment of the risks posed by the planned
unit. Such an analysis, labeled Tier 3, should
Ground-Water be conducted by experts in ground-water
modeling, and can require significant
Risk Evaluation resources. This Guide identifies the benefits
This section takes the principles of risk and sources for selecting site-specific models,
assessment described in Part I and applies but does not provide such models as part of
them to evaluating industrial waste manage- this Guide. In many cases, corporations will
ment unit liner designs. This is accomplished go directly to conducting the more exacting
using IWEM and a three-tiered ground-water Tier 3 analysis, which EPA believes is accept-
modeling approach to make recommenda- able under the Guide. There is, however, still
tions regarding the liner design systems that a need for the Tier 2 tool. State and environ-
should be considered for a potential unit, if a mental representatives might have limited
liner design system is considered necessary. resources to conduct or examine a Tier 3
The tiered approach was chosen to provide assessment; Tier 2 can provide a point of
facility managers, the public, and state regu- comparison with the results of the Tier 3
lators flexibility in assessing the appropriate- analysis, narrow the technical discussion to
ness of particular WMU designs as the user those factors which are different in the mod-
moves from a national assessment to an els, and form a basis for a more informed dia-
assessment using site-specific parameters. logue on the reasonableness of the differences.
The three tiers allow for three possible IWEM is designed to address Tier 1 and
approaches. The first approach is a quick Tier 2 evaluations. Both tiers of the tool con-
screening tool, a set of lookup tables, which sider all portions of the risk assessment
provides conservative national criteria. While process (i.e., problem formulation, exposure
this approach, labeled Tier 1, does not take assessment, toxicity assessment, and risk
into account site- (or even state-) specific con- characterization) to generate results that vary
ditions, it does provide a rapid and easy from a national-level screening evaluation to
7A-14
Protecting Ground Water—Assessing Risk
a site-specific assessment. The Tier 3 evalua- of the Tier 2 evaluation with the appropriate
tion is a complex, site-specific hydrogeologic state regulatory agency before selecting a liner
investigation that would be performed with design for a new WMU.
other models such as those listed at the end
If the Tier 1 and Tier 2 modeling do not
of this chapter. Those models could be used
adequately simulate conditions at a proposed
to evaluate hydrogeological complexities that
site because the hydrogeology of the site is
are not addressed by IWEM. Brief outlines of
complex, or because the user believes Tier 2
the three tiers follow.
does not adequately address a particular site-
A Tier 1 evaluation involves comparing the specific parameter, the user is advised to con-
expected leachate concentrations of wastes sider a more in-depth, site-specific risk
being assessed against a set of pre-calculated assessment. This Tier 3 assessment involves a
maximum recommended leachate concentra- more detailed, site-specific ground-water fate
tions (or Leachate Concentration Threshold and transport analysis. The user should con-
Values—LCTVs). The Tier 1 LCTVs are sult with state officials and appropriate trade
nationwide, ground-water fate and transport associations to solicit recommendations for
modeling results from EPA’s Composite Model approaches for the analysis.
for Leachate Migration with Transformation
The remainder of this section discusses in
Products (EPACMTP). EPACMTP simulates
greater detail how to use IWEM to perform a
the fate and transport of leachate infiltrating
Tier 1 or Tier 2 evaluation. In addition, this
from the bottom of a WMU and predicts con-
section presents information concerning the
centrations of those contaminants in a well. In
use of Tier 3 models.
making these predictions, the model quantita-
tively accounts for many complex processes
that dilute and attenuate the concentrations of A. The Industrial Waste
waste constituents as they move through the
subsurface to the well. The results that are
Management Evaluation
generated show whether a liner system is con- Model (IWEM)
sidered necessary, and if so which liner sys- The IWEM is the ground-water modeling
tems will be protective for the constituents of component of the Guide for Industrial Waste
concern. Tier 1 results are designed to be pro- Management, used for recommending appro-
tective with 90 percent certainty at a 1x10-6 priate liner system designs, where they are
risk level for carcinogens or a noncancer haz- considered necessary, for the management of
ard quotient of < 1.0. RCRA Subtitle D industrial waste. IWEM
compares the expected leachate concentration
The Tier 2 evaluation incorporates a limit-
(entered by the user) for each waste con-
ed number of site-specific parameters to help
stituent with a protective level calculated by a
provide recommendations about which liner
ground-water fate and transport model to
system (if any is considered necessary) is pro-
determine whether a liner system is needed.
tective for constituents of concern in settings
When IWEM determines a liner system is
that are more reflective of your site. IWEM is
necessary, it then evaluates two standard liner
designed to facilitate site-specific simulations
types (i.e., single clay-liner and composite
without requiring the user to have any previ-
liner). This section discusses components of
ous ground-water modeling experience. As
the tool and important concepts whose under-
with any ground-water risk evaluation, how-
standing is necessary for its effective use. The
ever, the user is advised to discuss the results
user can refer to the User’s Guide for the
7A-15
Protecting Ground Water—Assessing Risk
Industrial Waste Management Evaluation Model processes that occur as waste constituents
(U.S. EPA, 2002b) for information necessary and their transformation products move to
to perform Tier 1 and Tier 2 analyses, and the and through ground water. As leachate carry-
Industrial Waste Management Evaluation Model ing waste constituents migrates through the
Technical Background Document (U.S. EPA, unsaturated zone to the water table, attenua-
2002a), for more information on the use and tion processes, such as adsorption and degra-
development of IWEM. dation, reduce constituent concentrations.
Ground-water transport in the saturated zone
further reduces leachate concentrations
1. Leachate Concentrations
through dilution and attenuation. The con-
The first step in determining a protective centration of constituents arriving at a well,
waste management unit design is to identify therefore, is lower than that in the leachate
the expected constituents in the waste and released from a WMU.
expected leachate concentrations from the
waste. In order to assess ground-water risks In the unsaturated zone, the model simu-
using either the Tier 1 or Tier 2 evaluations lates one-dimensional vertical migration with
provided in IWEM, the expected leachate steady infiltration of constituents from the
concentration for each individual constituent WMU. In the saturated zone, EPACMTP sim-
of interest must be entered into the model. ulates three-dimensional plume-movement
See Chapter 2—Characterizing Wastes, for a (i.e., horizontal as well as transverse and ver-
detailed discussion of the various approaches tical spreading of a contaminant plume). The
available to use in evaluating expected model considers not only the subsurface fate
leachate concentrations. and transport of constituents, but also the
formation and the fate and transport of trans-
formation (daughter and granddaughter)
2. Models Associated with IWEM products. The model also can simulate the
One of the highlights of IWEM is its abili- fate and transport of metals, taking into
ty to simulate the fate and transport of waste account geochemical influences on the
constituents at a WMU with a small number mobility of metals.
of site-specific inputs. To accomplish this
task, IWEM incorporates the outputs of three b. MINTEQA2
other models, specifically EPACMTP, MINTE-
QA2, and HELP. This section discusses these In the subsurface, metal contaminants can
three models. undergo reactions with other substances in
the ground water and with the solid aquifer
or soil matrix material. Reactions in which
a. EPACMTP the metal is bound to the solid matrix are
EPA’s Composite Model for Leachate referred to as sorption reactions, and the
Migration with Transformation Products metal bound to the solid is said to be sorbed.
(EPACMTP) is the backbone of IWEM. During contaminant transport, sorption to
EPACMTP is designed to simulate subsurface the solid matrix results in retardation (slower
fate and transport of contaminants leaching movement) of the contaminant front.
from the bottom of a WMU and predict con- Transport models such as EPACMTP incorpo-
centrations of those contaminants in a down- rate a retardation factor to account for sorp-
gradient well. In making these predictions, tion processes.
the model accounts for many complex
7A-16
Protecting Ground Water—Assessing Risk
The actual geochemical processes that con- For the application of HELP to IWEM, an
trol the sorption of metals can be quite com- existing database of infiltration and recharge
plex, and are influenced by factors such as rates was used for 97 climate stations in the
pH, the type and concentration of the metal lower 48 contiguous states. Five climate sta-
in the leachate plume, the presence and con- tions (located in Alaska, Hawaii, and Puerto
centrations of other constituents in the Rico) were added to ensure coverage
leachate plume, and other factors. The throughout all of the United States. These cli-
EPACMTP model is not capable of simulating matic data were then used along with data on
all these processes in detail. Another model, the soil type and WMU design characteristics,
MINTEQA25, is used to determine a sorption to calculate a water balance for each applica-
coefficient for each of the metals species. For ble liner design as a function of the amount
IWEM, distributions of variables (e.g., leach- of precipitation that reaches the surface of the
able organic matter, pH) were used to gener- unit, minus the amount of runoff and evapo-
ate a distribution of isotherms for each metal transpiration. The HELP model then comput-
species. EPACMTP, in turn, samples from ed the net amount of water that infiltrates
these calculated sorption coefficients and uses through the surface of the unit (accounting
the selected isotherm as a modeling input to for recharge), the waste, and the unit’s bottom
account for the effects of nationwide or layer (for unsaturated soil and clay liner sce-
aquifer-specific ground-water and leachate narios only), based on the initial moisture
geochemistry on the sorption and mobility of content and the hydraulic conductivity of
metals constituents. each layer.
Although data were collected for all 102
c. HELP sites, these data were only used for the
The Hydrologic Evaluation of Landfill unlined landfills, waste piles, and land appli-
Performance (HELP) model is a quasi-two- cation units. For the clay liner scenarios
dimensional hydrologic model for computing (landfills and waste piles only), EPA grouped
water balances of landfills, cover systems, and sites and ran the HELP model only for a sub-
other solid waste management facilities. The set of the facilities that were representative of
primary purpose of the model is to assist in the ranges of precipitation, evaporation, and
the comparison of design alternatives. HELP soil type. The grouping is discussed further in
uses weather, soil, and design data to com- the IWEM Technical Background Document
pute a water balance for landfill systems (U.S. EPA, 2002a).
accounting for the effects of surface storage; In addition to climate factors and the par-
snowmelt; runoff; infiltration; evapotranspira- ticular unit design, the infiltration rates calcu-
tion; vegetative growth; soil moisture storage; lated by HELP are affected by the landfill
lateral subsurface drainage; leachate recircula- cover design, the permeability of the waste
tion; unsaturated vertical drainage; and leak- material in waste piles, and the soil type of
age through soil, geomembrane, or composite the land application unit. For every climate
liners. The HELP model can simulate landfill station and WMU design, multiple HELP
systems consisting of various combinations of infiltration rates are calculated. In Tier 1, for
vegetation, cover soils, waste cells, lateral a selected WMU type and design, the
drain layers, low permeability barrier soils, EPACMTP Monte Carlo modeling process
and synthetic geomembrane liners. For fur- was used to randomly select from among the
ther information on the HELP model, visit: HELP-derived infiltration and recharge data.
<wes.army.mil/el/elmodels/helpinfo.html>.
5
MINTEQA2 is a geochemical equilibrium speciation model for computing equilibria among the dis-
solved, absorbed, solid, and gas phases in dilute aqueous solution.
7A-17
Protecting Ground Water—Assessing Risk
This process captured both the nationwide depending on the exposure duration of the
variation in climate conditions and variations reference ground-water concentration (RGC)
in soil type. In Tier 2, the WMU location is a of interest. For example, IWEM assumes a
required user input, and the climate factors 30-year exposure duration for carcinogens,
used in HELP are fixed. However, in Tier 2, and therefore, the maximum average concen-
the Monte Carlo process is still used to tration is the highest 30-year average across
account for local variability in the soil type, the modeling horizon. After calculating the
landfill cover design, and permeability of maximum average concentrations across the
waste placed in waste piles. 10,000 realizations, the concentrations are
arrayed from lowest to highest and the 90th
percentile of this distribution is selected as
3. Important Concepts for Use
the constituent concentration for IWEM.
of IWEM
Once the 90th percentile exposure con-
Several important concepts are critical to
centration is determined, it is used in one of
understanding how IWEM functions. These
two ways. For both the Tier 1 analysis and
concepts include 90th percentile exposure
the Tier 2 analysis, the 90th percentile expo-
concentration, dilution and attenuations fac-
sure concentration is compared with the
tors (DAFs), reference ground-water concen-
expected waste leachate concentration to
trations (RGCs), leachate concentration
generate a DAF. This calculation is discussed
threshold values (LCTVs), and units designs.
further in the following section. For Tier 2,
the 90th percentile exposure concentration is
a. 90th Percentile Exposure the concentration of interest for the analysis.
Concentration The 90th percentile exposure concentration
The 90th percentile exposure concentra- can be directly compared with the reference
tion was chosen to represent the estimated ground-water concentration to assist in waste
constituent concentration at a well for a management decision-making.
given leachate concentration. The 90th per-
centile exposure concentration was selected b. Dilution and Attenuation Factors
because this concentration is protective for
DAFs represent the expected reduction in
90 percent of the model simulations con-
waste constituent concentration resulting
ducted for a Tier 1 or Tier 2 analysis. In Tier
from fate and transport in the subsurface. A
1, the 90th percentile concentration is used
DAF is defined as the ratio of the constituent
to calculate a DAF, which is then used to gen-
concentration in the waste leachate to the
erate a leachate concentration threshold value
concentration at the well, or:
(LCTV). In Tier 2, the 90th percentile con-
centration is directly compared with a refer- CL
ence ground-water concentration to DAF = ———
determine whether a liner system is neces- CW
sary, and if so whether the particular liner
design is protective for a site. where: DAF is the dilution and attenua-
tion factor;
The 90th percentile exposure concentra-
tion is determined by running EPACMTP in a CL is the leachate concentration
Monte Carlo mode for 10,000 realizations. (mg/L); and
For each realization, EPACMTP calculates a CW is the ground-water well con-
maximum average concentration at a well, centration (mg/L).
7A-18
Protecting Ground Water—Assessing Risk
The magnitude of a DAF reflects the com- because the site-specific leachate concentra-
bined effect of all dilution and attenuation tion is used in the EPACMTP model runs, the
processes that occur in the unsaturated and 90th percentile exposure concentration can
saturated zones. The lowest possible value of be compared directly to the RGC.
a DAF is one. A DAF of 1 means that there is
no dilution or attenuation at all; the concen- c. Reference Ground-Water
tration at a well is the same as that in the Concentration (RGC)
waste leachate. High DAF values, on the
other hand, correspond to a high degree of As used in this Guide and by IWEM, a ref-
dilution and attenuation. This means that the erence ground-water concentration (RGC) is
expected concentration at the well will be defined as a constituent concentration thresh-
much lower than the concentration in the old in a well that is protective of human
leachate. For any specific site, the DAF health. RGCs have been developed based on
depends on the interaction of waste con- maximum contaminant levels (MCLs) and
stituent characteristics (e.g., whether or not health-based-numbers (HBN). Each con-
the constituent degrades or sorbs), site-specif- stituent can have up to five RGCs: 1) based
ic factors (e.g., depth to ground water, hydro- on an MCL, 2) based on carcinogenic effects
geology), and physical and chemical from ingestion, 3) based on carcinogenic
processes in the subsurface environment. In effects from inhalation while showering, 4)
addition, the DAF calculation does not take based on non-carcinogenic effects from inges-
into account when the exposure occurs, as tion, and 5) based on non-carcinogenic
long as it is within a 10,000-year time-frame effects from inhalation while showering.
following the initial release of leachate. Thus, The IWEM’s database includes 226 con-
if two constituents have different mobility, the stituents with at least one RGC. Of the 226
first might reach the well in 10 years, while constituents, 57 have MCLs (see Table 3),
the second constituent might not reach the 212 have ground-water ingestion HBNs, 139
well for several hundred years. EPACMTP, have inhalation HBNs, and 57 have both an
however, can calculate the same or very simi- MCL and HBN. The HBNs were developed
lar DAF values for both constituents. using standard EPA exposure assumptions for
For the Tier 1 analysis in IWEM, DAFs are residential receptors. For carcinogens, IWEM
based on the 90th percentile exposure con- used a target risk level equal to the probabili-
centration. EPACMTP was implemented by ty that there might be one increased cancer
randomly selecting one of the settings from case per one million exposed people (com-
the WMU database and assigning a unit monly referred to as a 1x10-6 cancer risk).
leachate concentration to each site until The target hazard quotient used to calculate
10,000 runs had been conducted for a WMU. the HBNs for noncarcinogens was 1 (unit-
The resulting 10,000 maximum well concen- less). A hazard quotient of 1 indicates that
trations based on the averaging period associ- the estimated dose is equal to the oral refer-
ated with the exposure duration of interest ence dose (RfD) or inhalation reference con-
(i.e., 1-year, 7-years, 30-years) were then centration (RfC). These targets were used to
arrayed from lowest to highest. The 90th per- calculate unique HBNs for each constituent of
centile concentration of this distribution is concern and each exposure route of concern
then used as the concentration in the ground- (ingestion or inhalation). For further informa-
water well (Cw) for calculating the DAF. The tion on the derivation of the IWEM RGCs,
DAF is similarly calculated for the Tier 2, but see the Industrial Waste Management
Evaluation Model Technical Background
7A-19
Protecting Ground Water—Assessing Risk
Document (U.S. EPA, 2002a). Users also can MCL is the maximum concentra-
add new constituents and RGCs can vary tion level
depending on the protective goal. For exam-
HBN is the health-based number
ple, states can impose more stringent drink-
ing water standards than federal MCLs.6 To The evaluation of whether a liner system is
keep the software developed for this Guide needed and subsequent liner system design
up-to-date, and to accommodate concerns at recommendations is determined by compar-
levels different from the current RGCs, the ing the expected waste constituent leachate
RGC values in the IWEM software tool can concentrations to the corresponding calculat-
be modified by the user of the software. ed LCTVs. LCTVs are calculated for all unit
types (i.e., landfills, waste piles, surface
impoundments, land application units) by
d. Leachate Concentration Threshold
type of design (i.e., no liner/in situ soils, sin-
Values (LCTVs)
gle liner, or composite liner).7 The Tier 1
The purpose of the Tier 1 analysis in evaluation is generally the most protective
IWEM is to determine whether a liner system and calculates LCTVs using data collected on
is needed, and if so, to recommend liner sys- WMUs throughout the United States.8 LCTVs
tem designs or determine the appropriateness used in Tier 1 are designed to be protective
of land application with minimal site-specific to a level of 1x10-6 for carcinogens or a non-
data. These recommendations are based on cancer hazard quotient of < 1.0 with a 90
LCTVs that were calculated to be protective percent certainty considering the range of
for each waste constituent in a unit. These variability associated with the waste sites
LCTVs are the maximum leachate concentra- across the United States. LCTVs from the Tier
tions for which water in a well is not likely to 1 analysis are generally applicable to sites
exceed the corresponding RGC. The LCTV across the country; users can determine
for each constituent accounts for dilution and whether a specific liner design for a WMU is
attenuation in the unsaturated and saturated protective by comparing expected leachate
zones prior to reaching a well. An LCTV has concentrations for constituents in their waste
been generated for a no liner/in situ soils sce- with the LCTVs for each liner design.
nario and for two standard liner types (i.e.,
single clay liner and composite liner) and The Tier 2 analysis differs from the Tier 1
each RGC developed for a constituent. analysis in that IWEM calculates a site-specif-
ic DAF in Tier 2. This allows the model to
The LCTV for a specific constituent is the calculate a site-specific 90th percentile expo-
product of the RGC and the DAF: sure concentration that can be compared
LCTV = DAF * MCL with an RGC to determine if a liner system is
needed and to recommend the appropriate
or LCTV = DAF * HBN liner system if necessary. The additional cal-
Where: LCTV is the leachate concentra- culation of an LCTV is not necessary. IWEM
tion threshold value continues to perform the calculation, howev-
er, to help users determine whether waste
DAF is the dilution and attenua-
minimization might be appropriate to meet a
tion factor
specific design. For example, a facility might
6
For example, a state can make secondary MCLs mandatory, which are not federally enforceable stan-
dards, or a state might use different exposure assumptions, which can result in a different HBN. In
addition, states can choose to use a different risk target than is used in this Guidance.
7
LCTVs are influenced by liner designs because of different infiltration rates.
7A-20
8
For additional information on the nationwide data used in the modeling, see the IWEM Technical
Background Document (U.S. EPA, 2002a).
Protecting Ground Water—Assessing Risk
find it more cost effective to reduce the con- a flexible membrane liner in contact with a
centration of constituents in its waste and clay liner. In Tier 2, users also can evaluate
design a clay-lined landfill than to dispose of other liner designs by providing a site-specific
the current waste in a composite landfill. The infiltration rate based on the liner design. For
LCTV calculated for the Tier 2 analysis is land applications units, only the no liner/in
based on the expected leachate concentration situ soils scenario is evaluated because liners
for a specific site and site-specific data for are not typically used at this type of facility.
several sensitive parameters. Because the Tier
To determine an appropriate design in Tier
2 analysis includes site-specific considera-
1, IWEM compares expected leachate con-
tions, LCTVs from this analysis are not
centrations for all of the constituents in the
applicable to other sites.
leachate to constituent-specific LCTVs and
then reports the minimum design system that
e. Determination of Liner Designs is protective for all constituents. If the expect-
The primary method of controlling the ed leachate concentrations of all waste con-
release of waste constituents to the subsurface stituents are lower than their respective no
is to install a low permeability liner at the liner/in situ soils LCTVs, the proposed WMU
base of a WMU. A liner generally consists of a does not need a liner to contain the waste.
layer of clay or other material with a low On the other hand, if the Tier 1 screening
hydraulic conductivity that is used to prevent evaluation indicates a liner is recommended,
or mitigate the flow of liquids from a WMU. a user can verify this recommendation with a
The type of liner that is appropriate for a spe- follow-up Tier 2 (or possibly Tier 3) analysis
cific WMU, however, is highly dependent for at least those constituents whose expected
upon a number of location-specific character- leachate concentrations exceed the Tier 1
istics, such as climate and hydrogeology. LCTV values.
These characteristics are critical in determin- If the user proceeds to a Tier 2 analysis,
ing the amount of liquid that migrates into IWEM will evaluate the three standard
the subsurface from a WMU and in predicting designs or it can evaluate a user-supplied
the release of contaminants to ground water. liner design. The user can supply a liner
The IWEM software is intended to assist design by providing a site-specific infiltration
the user in determining if a new industrial rate that reflects the expected infiltration rate
waste management unit can rely on a no through the user’s liner system. In the Tier 2
liner/in situ soils design, or whether one of analysis, IWEM conducts a location-adjusted
the two recommended liners designs, single Monte Carlo analysis based on user inputs to
clay liner or composite liner, should be used. generate a 90th percentile exposure concen-
The no liner/in situ soils design (Figure 2a) tration for the site. The 90th percentile expo-
represents a WMU that relies upon location- sure concentration is then compared with the
specific conditions, such as low permeability RGC to determine whether a liner is consid-
native soils beneath the unit or low annual ered necessary, and where appropriate, rec-
precipitation rates to mitigate the release of ommend the design that is protective for each
contaminants to groundwater. The single clay constituent expected in the leachate. If the
liner (Figure 2b) design represents a 3-foot Tier 2 analysis indicates that the no liner/in
thick clay liner with a low hydraulic conduc- situ soils scenario or the user-defined liner is
tivity (1x10-7 cm/sec) beneath a WMU. A not protective, the user can proceed to a full
composite liner design (Figure 2c) consists of site-specific Tier 3 analysis.
7A-21
Protecting Ground Water—Assessing Risk
Figure 2. Three Liner Scenarios Considered in the Tiered Modeling Approach for Industrial
Waste Guidelines
yyy
;;;
;;;
yyy
Waste
Native Soil
Clay Liner
Clay Liner
7A-22
Protecting Ground Water—Assessing Risk
in the IWEM software and in the tables includ- As noted previously in this chapter, one of
ed in the technical background document. the first steps in a ground-water risk assess-
ment is to characterize the waste going into a
The advantages of a Tier 1 screening evalu-
unit. Characterization of the waste includes
ation are that it is fast, and it does not require
identifying the constituents expected in the
site-specific information. The disadvantage of
leachate and estimating leachate concentra-
the Tier 1 screening evaluation is that the
tions for each of these constituents.
analysis does not use site-specific information
Identification of constituents expected in
and might result in a design recommendation
leachate can be based on process knowledge
that is more stringent than is needed for a
or chemical analysis of the waste. Leachate
particular site. For instance, site-specific con-
concentrations can be estimated using
ditions, such as low precipitation and a deep
process knowledge or an analytical leaching
unsaturated zone, might warrant a less strin-
test appropriate to the circumstances, such as
gent design. Before implementing a Tier 1
the Toxicity Characteristic Leaching
recommendation, it is recommended that you
Procedure (TCLP). For more information on
also perform a Tier 2 assessment for at least
identifying waste constituents, estimating
those waste constituents for which Tier 1
waste constituent leachate concentrations,
indicates that a no liner design is not protec-
and selecting appropriate leaching tests, refer
tive. The following sections provide addition-
to Chapter 2 — Characterizing Waste.
al information on how to use the Tier 1
lookup tables. The following example illustrates the Tier
1 process for evaluating a proposed design
for an industrial landfill. The example
1. How Are the Tier 1 Lookup
assumes the expected leachate concentration
Tables Used? for toluene is 1.6 mg/L and styrene is 1.0
The Tier 1 tables provide an easy-to-use
tool to assist waste management decision-
making. Important benefits of the Tier 1
Information Needed to
approach are that it requires minimum data Use Tier 1 Lookup Tables
from the user and provides immediate guid- Waste management Landfill, surface
ance on protective design scenarios. There are unit types: impoundment,
only three data requirements for the Tier 1 waste pile, or land
analysis: WMU type, constituents expected in application unit.
the waste leachate, and the expected leachate
Constituents Constituent names
concentration for each constituent in the
expected and/or CAS numbers.
waste. The Tier 1 tables are able to provide
in the leachate:
immediate guidance because EPACMTP simu-
lations for each constituent, WMU, and Leachate Expected leachate
design combinations were run previously for concentrations: concentration of
a national-scale assessment to generate appro- each constituent or
priate LCTVs for each combination. Because concentration in
the simulations represent a national-scale surface impound-
assessment, the LCTVs in the Tier 1 tables ments or waste to be
represent levels in leachate that are protective applied.
at most sites.
7A-23
Protecting Ground Water—Assessing Risk
mg/L. Both toluene and styrene have three ferences are that the HBN-results present the
LCTVs: one based on an MCL, one based on constituent-specific HBN rather than the
non-cancer ingestion, and one based on non- MCL and include an additional column that
cancer inhalation. Tables 4 and 5 provide identifies the pathway and effect that support
detailed summary information for the no the development of the LCTV. For the con-
liner/in situ soils scenario for MCL-based trolling pathway and effect column, IWEM
LCTVs and the HBN-based LCTVs, respec- would indicate whether the most protective
tively, that is similar to the information that pathway is ingestion of drinking water (indi-
can be found in the actual look-up tables. cated by ingestion) or inhalation during
showering (indicated by inhalation) and
For the Tier 1 MCL-based analysis pre-
whether the adverse effect is a cancer or non-
sented in Table 4, the results provide the
cancer effect. In this example, both styrene
following information: constituent CAS
and toluene have two HBN-based LCTVS:
number, constituent name, constituent-spe-
one for ingestion non-cancer and one for
cific MCL, user-provided leachate concen-
inhalation non-cancer. Only the results for
tration, constituent-specific DAF, the
the controlling HBN exposure pathway and
constituent-specific LCTV, and whether the
effect are shown. In Table 5, only the results
specified design is protective at the target
for the inhalation-during-showering pathway
risk level. To provide a recommendation as
for non-cancer effects are shown because this
to whether a specific design is protective or
is the most protective pathway (that is, the
not, IWEM compares the LCTV with the
LCTV for the inhalation-during-showing
leachate concentration to determine
pathway is lower than the LCTV for ingestion
whether the design is protective. In the
of drinking water) for both of these con-
example presented in Table 4, the no
stituents. As shown in Table 5, comparison of
liner/in situ soils scenario is not protective
the leachate concentration of styrene (1.0
for styrene because the leachate concentra-
mg/L) and toluene (1.6 mg/L) to their respec-
tion provided by the user (1.0 mg/L) is
tive LCTVs (8.0 mg/L and 2.9 mg/L) indi-
greater than the Tier 1 LCTV (0.22 mg/L).
cates that the no liner/in situ soils design is
For toluene, the no liner/in situ soils sce-
protective for the Tier 1 HBN-based LCTVs.
nario is protective because the leachate con-
centration (1.6 mg/L) is less than the Tier 1 Based on the results for the no liner/in situ
LCTV (2.2 mg/L). soils scenario, the user could proceed to the
comparison of the expected leachate concen-
For the health-based number (HBN)-based
tration for styrene with the MCL-based LCTV
results presented in Table 5, the detailed
for a single clay liner to determine whether
results present similar information to that
the single clay liner design is protective. The
presented for the MCL-based results. The dif-
Table 4:
Example of Tier 1 Summary Table for MCL-based LCTVs for Landfills - No Liner/In situ Soils
CAS # Constituent MCL (mg/L) Leachate Concentration (mg/L) DAF LCTV (mg/L) Protective?
7A-24
Protecting Ground Water—Assessing Risk
Table 5:
Example of Tier 1 Summary Table for HBN-based LCTVs for Landfills - No Liner/In situ Soils
CAS # Constituent HBN (mg/L) Leachate DAF LCTV (mg/L) Protective? Controlling
Concentration Pathway &
(mg/L) Effect
user also can proceed to a Tier 2 or Tier 3 Table 7 presents the results of the Tier 1
analysis to determine whether a more site- MCL-based analysis for a composite liner.9 A
specific approach might indicate that the no comparison of the leachate concentration for
liner/in situ soils design is protective for the styrene (1.0 mg/L) to the MCL-based LCTV
site. Table 6 presents the Tier 1 results for the (1000 mg/L) indicates that the composite
single clay liner. As shown, the single clay liner is the recommended liner based on a
liner would not be protective for the MCL- Tier 1 analysis that will be protective for both
based analysis because the expected leachate styrene and toluene.
concentration for styrene (1.0 mg/L) exceeds
the LCTV for styrene (0.61 mg/L). Based on
2. What Do the Results Mean
these results, the user could continue on to
evaluate whether a composite liner is protec- and How Do I Interpret Them?
tive for styrene. For the Tier 1 analysis, IWEM evaluates
the no liner/in situ soils, single clay liner, and
Table 6:
Example of Tier 1 Summary Table for MCL-based LCTVs for Landfills - Single Clay Liner
CAS # Constituent MCL (mg/L) Leachate Concentration (mg/L) DAF LCTV (mg/L) Protective?
Table 7:
Example of Tier 1 Summary Table for MCL-based LCTVs for Landfills - Composite Liner
CAS # Constituent MCL (mg/L) Leachate Concentration (mg/L) DAF LCTV (mg/L) Protective?
9
Table 7 also indicates the effect of the 1000 mg/L cap on the results. The LCTV results from multiply-
ing the RGC with the DAF. In this example, the MCL for styrene (0.1 mg/L) multiplied by the unitless
DAF (5.4 x 104) would result in an LCTV of 5,400 mg/L, but because LCTVs are capped, the LCTV for
styrene in a composite liner is capped at 1,000 mg/L. See Chapter 6 of the Industrial Waste Management 7A-25
Evaluation Model Technical Background Document (U.S. EPA, 2002a) for further information.
Protecting Ground Water—Assessing Risk
composite liner design scenarios, in that stituents whose concentrations exceed a land
order. Generally, if the expected leachate con- application threshold, the recommendation is
centrations for all constituents are lower than that land application might not be appropri-
the no liner LCTVs, the proposed unit does ate. The model does not consider the other
not need a liner to contain this waste. If any design scenarios.
expected constituent concentration is higher
After conducting the Tier 1 evaluation,
than the no liner/in situ soils LCTV, a single
users should consider the following steps:
compacted clay liner or composite liner
would be recommended for containment of • Perform additional evaluations.
the waste using the Tier 1 analysis. If any The Tier 1 evaluation provides a con-
expected concentration is higher than the servative screening assessment whose
single clay liner LCTV, the recommendation values are calculated to be protective
is at least a composite liner. If any expected over a range of conditions and situa-
concentration is higher than the composite tions. Although a user could elect to
liner LCTV, pollution prevention, treatment, install a liner based on the Tier 1
or additional controls should be considered, results, it is appropriate that a user
or a Tier 2 or Tier 3 analysis can be conduct- consider Tier 2 or Tier 3 evaluations
ed to consider site-specific factors before to confirm these recommendations.
making a final judgment. For waste streams • Consider pollution prevention,
with multiple constituents, the most protec- recycling, or treatment. If you do
tive design that is recommended for any one not want to conduct a Tier 2 or Tier
constituent is the overall recommendation. In 3 analysis, and the waste has one or
the example illustrated in Tables 4, 5, 6, and more “problem” constituents that call
7, the recommended design is a composite for a more stringent and costly design
liner because the expected leachate concen- system (or which make land applica-
tration for styrene exceeds the no liner/in situ tion inappropriate), you could con-
soils and clay liner LCTVs in the MCL-based sider pollution prevention, recycling,
analysis, but is lower than the composite and treatment options for those con-
liner LCTV. For the HBN-based analysis, a no stituents. Options that previously
liner/in situ soils design would provide ade- might have appeared economically
quate protection for the site because, as infeasible, might be worthwhile if
shown in Table 5, the leachate concentrations they can reduce the problem con-
for styrene and toluene are lower than their stituent concentration to a level that
respective HBN-based LCTVs. results in a different design recom-
The interpretation for land application is mendation or would make land
similar to the interpretation for landfills. application appropriate. Then, after
However, only the no liner/in situ soils sce- implementing these measures, repeat
nario is evaluated for land application the Tier 1 evaluation. Based on the
because these types of units generally do not results presented in Table 6, pollution
use liner systems. Thus, if all the waste prevention, recycling, or treatment
leachate concentrations are below the no measures could be used to reduce the
liner/in situ soils MCL-based and HBN-based expected leachate concentration for
LCTVs in the Tier 1 lookup tables, land- styrene below 0.61 mg/L so that a
applying waste might be appropriate for the single liner is recommended for the
site. If the waste has one or more con- unit. Consult Chapter 3—Integrating
7A-26
Protecting Ground Water—Assessing Risk
C. Tier 2
Evaluations
The Tier 2 evaluation is Will pollution preven-
designed to provide a tion, recycling, or treat-
Do you have
ment be implemented to
more accurate evaluation site-specific
reduce concentrations of NO
data?
than Tier 1 by allowing problem constituents?
the user to provide site-
specific data. In many YES
cases, a Tier 2 evaluation
might suggest a less strin- NO Consider a Tier 2 evaluation or
gent and less costly design performing a comprehensive Tier
than a Tier 1 evaluation Consider implement- 3 site-specific ground-water fate
ing liner and/or land and transport analysis.
would recommend. This application recom-
section describes the mendation, or obtain-
inputs for the analysis and ing additional data for
a Tier 2 or Tier 3
the process for determin- analysis.
ing a protective recom-
mendation.
7A-27
Protecting Ground Water—Assessing Risk
liner design. As a result, a Tier 2 analysis “optional” parameters that are used unless
provides a protective design recommendation the user provides site-specific data. The
intended only for use at the user’s site, and is default values are derived from a number of
not intended to be applied to other sites. sources, including a survey of industrial
This section discusses the inputs that a user waste management units, a hydrogeologic
can provide and the results from the analysis. database, water-balance modeling, and values
reported in the scientific literature. The selec-
a. Tier 2 Inputs tion of default values is explained in the
IWEM Technical Background Document (U.S.
In addition to the inputs required for the EPA, 2002a). If site-specific data are avail-
Tier 1 analysis, a Tier 2 analysis allows users able, they should be used to derive the most
to provide additional inputs that account for appropriate design scenario for a particular
attributes that are specific to the user’s site. site.10
The Tier 2 inputs that are common to the
Tier 1 evaluation are: In addition to the above parameters, users
can also enter certain constituent specific
• WMU type—waste pile, surface properties, as follows:
impoundment, or land application
unit. • Organic carbon distribution coeffi-
cient (KOC). A function of the nature
• Chemical constituents of concern of a sorbent (the soil and its organic
present in the WMU. carbon content) and the properties of
• Leachate concentration (in mg/L) of a chemical (the leachate constituent).
each constituent. It is equal to the ratio of the solid
and dissolved phase concentrations,
If the user has already performed a Tier 1
measured in milliliters per gram
analysis and continues to a Tier 2 analysis,
(mL/g). The higher the value of the
the Tier 1 inputs are carried forward to the
distribution coefficient, the higher
Tier 2 analysis. In the Tier 2 analysis, howev-
the adsorbed-phase concentration,
er, the user can change these data without
meaning the constituent would be
changing the Tier 1 data.
less mobile. For metals, IWEM pro-
In addition to the Tier 1 inputs, the user vides an option to enter a site-specif-
also provides values for additional parameters ic soil-water partition coefficient (Kd),
including WMU area, WMU depth for land- which overrides the MINTEQA2
fills, ponding depth for surface impound- default sorption isotherms.
ments, and the climate center in the IWEM
• Degradation coefficient. The rate at
database that is nearest to the site. These
which constituents degrade or decay
parameters can have a significant influence
within an aquifer due to biochemical
on the LCTVs generated by the model and
processes, such as hydrolysis or
also are relatively easy to determine. The user
biodegradation (measured in units of
also has the option to provide values for sev-
1/year). The default decay rate in
eral more parameters. Table 8 presents the
IWEM represents degradation from
list of “required” and “optional” parameters.
chemical hydrolysis only, since
Because site-specific data for all of the biodegradation rates are strongly
EPACMTP parameters might not be available, influenced by site-specific factors. In
the model contains default values for the Tier 2, a user can enter an overall
10
A Tier 2 evaluation is not always less conservative than a Tier 1. For example, if a site has a very large
area, a very shallow water table, and/or the aquifer thickness is well below the national average, then
7A-28 the Tier 2 evaluation results can be more stringent than the Tier 1 analysis results.
Protecting Ground Water—Assessing Risk
Table 8.
Input Parameters for Tier 2
WMU area Area covered by the WMU To determine the area for Square meters (m2) All Required
infiltration of leachate
WMU location Geographic location of WMU in terms of To determine local climatic Unitless All Required
the nearest of 102 climate stations conditions that affect infiltration
and aquifer recharge
Total waste Depth of the unit for landfills (average For landfills, used to determine Meters (m) LF Required for
management unit thickness of waste in the landfill, not the landfill depletion rate. For SI landfills and
depth counting the thickness of a liner below the surface impoundments, used surface
waste or the thickness of a final cover on as the hydraulic head to derive impoundments
top of the waste) and surface leakage
impoundments (depth of the free-standing
liquid in the impoundment, not counting
the thickness of any accumulated sediment
layer at the base of the impoundment)
Depth of waste Depth of the base of the unit below the Used together with depth of the Meters (m) LF Optional
management unit ground surface water table to determine SI
below ground distance leachate has to travel WP
surface through unsaturated zone to
reach ground water
Surface Thickness of sediment at the base of Limits infiltration from unit. Meters (m) SI Optional
Impoundment surface impoundment (discounting
sediment layer thickness of engineered liner, if present)
thickness
WMU operational Period of time WMU is in operation. IWEM assumes leachate Years WP Optional
life generation occurs over the same SI
period of time. LAU
WMU infiltration Rate at which leachate flows from the Affected by area’s rainfall Meters per year All Optional
rate bottom of a WMU (including any liner) intensity and design (m/yr)
into unsaturated zone performance. Users either input
infiltration rates directly or
allow IWEM to estimate values
based on the unit’s geographic
location,11 liner design, cover
design and WMU type.
Soil type Predominant soil type in the vicinity of Uses site-specific soil data to sandy loam All Optional
the WMU model leachate migration silt loam
through unsaturated zone and silty clay loam
determine regional recharge rate
Distance to a well The distance from a WMU to a To determine the horizontal Meters (m) All Optional
downgradient well. distance over which dilution
and attenuation occur.
Hydrogeological Information on the hydrogeological setting Determines certain aquifer Varies All Optional
setting of the WMU characteristics (depth to water
table, saturated zone thickness,
saturated zone hydraulic
conductivity, ground-water
hydraulic gradient) when
complete information not
available
11
For surface impoundments IWEM can use either the unit’s geographic location or impoundment characteristics
(such as ponding depth, and thickness of sediment layer) to estimate the infiltration rates.
7A-29
Protecting Ground Water—Assessing Risk
Table 8.
Input Parameters for Tier 2 (con’t)
Depth to the water The depth of the zone between the land Used to predict travel time. Meters (m) All Optional
table surface and the water table
Saturated zone Thickness of the saturated zone of the Delineates the depth over Meters (m) All Optional
thickness aquifer which leachates can mix with
ground waters.
Saturated zone Hydraulic conductivity of the saturated With hydraulic gradient, used Meters per year All Optional
hydraulic zone, or the permeability of the saturated to calculate ground-water flow (m/yr)
conductivity zone in the horizontal direction. rates.
Ground-water Regional horizontal ground-water gradient With hydraulic conductivity, Meters per meter All Optional
hydraulic gradient used to calculate the ground- (m/m)
water flow rate.
Distance to nearest The distance from the unit to the nearest Affects the calculation of Meters (m) SI Optional
surface water body water body ground-water mounding at a site.
degradation rate which overrides the The overall result of a Tier 2 analysis is a
IWEM default. A user can choose to design recommendation similar to the Tier 1
include degradation due to hydroly- analysis. However, the basis for the recom-
sis and biodegradation in the overall mendation differs slightly. To illustrate the
degradation rate. similarities and differences between the
results from the two tiers, the remainder of
b. Tier 2 Results this section continues the example Tier 1
evaluation through a Tier 2 evaluation. In the
After providing site-specific inputs, the Tier 1 example, the disposal of toluene and
user generates design recommendations for styrene in a proposed landfill is evaluated.
each constituent by launching EPACMTP The expected leachate concentration for
from within IWEM. EPACMTP will then sim- toluene is 1.6 mg/L and the expected
ulate the site and determine the 90th per- leachate concentration for styrene is 1.0
centile exposure concentration for each mg/L. In Tier 2, after inputting the site-spe-
design scenario. IWEM determines the mini- cific data summarized in Table 9 and using
mum recommended design at a 90th per- default data for the remaining parameters,
centile exposure concentration by performing the user can then launch the EPACMTP
10,000 Monte Carlo simulations of model simulations.
EPACMTP for each waste constituent and
design. Upon completion of the modeling After completing the EPACMTP model
analyses, IWEM will display the minimum simulations, IWEM produces the results on
design recommendation and the calculated, screen. Table 10 presents the detailed results
location-specific LCTVs based on the 90th of a Tier 2 analysis for the no liner/in situ
percentile exposure concentration. soils scenario. The data presented in this
table are similar to the data presented in the
Tier 1 results, but the Tier 2 analysis expands
7A-30
Protecting Ground Water—Assessing Risk
7A-31
Protecting Ground Water—Assessing Risk
concentration for a design scenario that is ence ground-water concentration (0.1 mg/L).
still protective for a reference ground-water In addition, under the “Protective?” column,
concentration, but the LCTV is not the basis IWEM refers the user to the appropriate liner
for the design recommendation. result if a less stringent design is recom-
mended. In Table 11, the user is referred to
The RGC and 90th percentile exposure
the no liner/in situ soils results for the HBN-
concentration are provided because they are
based ingestion and inhalation results
the point of comparison for the Tier 2 analy-
because, as shown in Table 10, the no
sis. (The LCTV, however, continues to provide
liner/in situ soils scenario is protective. If a
information about a threshold that might be
Tier 2 analysis determines that a single clay
useful for pollution prevention or waste mini-
liner is protective for all constituents, then
mization efforts.) As shown in Table 10, the
IWEM would not continue to an evaluation
no liner/in situ soils scenario is protective for
of a composite liner. For this example of
toluene because all of the 90th percentile
styrene and toluene disposed of in a landfill,
exposure concentrations are less than the
the recommended minimum design is a sin-
three RGCs for toluene, while the no liner/in
gle clay liner, because the 90th percentile
situ soils scenario is not protective for styrene
exposure concentration (0.0723) is less than
for the MCL comparison. For that standard,
the MCL-based RGC (0.1).
the 90th percentile exposure concentration
(0.1201 mg/L) exceeds the RGC (0.1 mg/L).
In this case, IWEM would launch EPACMTP 2. What Do the Results Mean
to evaluate a clay liner to determine whether and How Do I Interpret Them?
that liner design would be protective.
The Tier 2 analysis provides LCTVs and
Table 11 provides the single clay liner recommendations for a minimum protective
results for a Tier 2 analysis. As shown in the design. In the Tier 1 analysis, that recommen-
table, the single clay liner is protective dation is based on a comparison of expected
because the 90th percentile exposure concen- leachate concentrations to LCTVs to determine
tration (0.0723 mg/L) is less than the refer- whether a design scenario is protective. In the
Table 11:
Example of Tier 2 Detailed Summary Table - Single Clay Liner
CAS # Constituent Leachate DAF LCTV Toxicity Ref. 90th Percentile Protective?
Concentration (mg/L) Standard Ground- Exposure
(mg/L) water Concentration
Conc. (mg/L) (mg/L)
7A-32
Protecting Ground Water—Assessing Risk
Tier 2 analysis, LCTVs can be used to help treatment options for those constituents. If,
waste managers determine whether waste min- after conducting the Tier 2 evaluation, the
imization techniques might lower leachate user is not satisfied with the resulting recom-
concentrations and enable them to use less mendations, or if site-specific conditions
costly unit designs, but IWEM does not need seem likely to suggest a different conclusion
to calculate an LCTV to make a design recom- regarding the appropriateness of land applica-
mendation. If the 90th percentile ground- tion of a waste, then the user can conduct a
water concentration does not exceed the more in-depth, site-specific, ground-water
specified RGC, then the evaluated design sce- risk analysis (Tier 3).
nario is protective for that constituent. If the
In addition to the Tier 2 evaluation, other
90th percentile ground-water concentrations
fate and transport models have been devel-
for all constituents under the no liner/in situ
oped that incorporate location-specific consid-
soils scenario are below their respective RGCs ,
erations, such as the American Petroleum
then IWEM will recommend that no liner/in
Institute’s (API’s) Graphical Approach for
situ soils is needed to protect the ground
Determining Site-Specific Dilution-Attenuation
water. If the 90th percentile ground-water con-
Factors.12 API developed its approach to calcu-
centration of any constituent exceeds its RGC,
late facility-specific DAFs quickly using
then a single clay liner is recommended (or, in
graphs rather than computer models. Graphs
the case of land application units, land appli-
visually indicate the sensitivity to various
cation is not recommended). Similarly, if the
parameters. This approach can be used for
90th percentile ground-water concentration of
impacted soils located above or within an
any constituent under the single clay liner sce-
aquifer. This approach accounts for attenua-
nario exceeds its RGC, then a composite liner
tion with distance and time due to
is recommended. As previously noted, howev-
advective/dispersive processes. API’s approach
er, you may decide to conduct a Tier 3 site-
has a preliminary level of analysis that uses a
specific analysis to determine which design
small data set containing only measures of the
scenario is most appropriate. See the ensuing
constituent plume’s geometry. The user can
section on Tier 3 analyses for further informa-
read other necessary factors off graphs provid-
tion. For waste streams with multiple con-
ed as part of the approach. This approach also
stituents, the most protective liner design that
has a second level of analysis in which the
is recommended for any one constituent is the
user can expand the data set to include site-
overall recommendation. As in the Tier 1 eval-
specific measures, such as duration of con-
uation, pollution prevention, recycling, and
stituent leaching, biodegradation of
treatment practices could be considered when
constituents, or site-specific dispersivity val-
the protective standard of a composite liner is
ues. At either level of analysis, the calculation
exceeded if you decide not to undertake a Tier
results in a DAF. This approach is not appro-
3 assessment to reflect site-specific conditions.
priate for all situations; for example, it should
If the Tier 2 analysis found land applica- not be used to estimate constituent concentra-
tion to be appropriate for the constituents of tions in active ground-water supply wells or
concern, then a new land application system to model very complex hydrogeologic set-
may be considered (after evaluating other fac- tings, such as fractured rock. It is recom-
tors). Alternatively, if the waste has one or mended that you consult with the appropriate
more “problem” constituents that make land state agency to discuss the applicability of the
application inappropriate, the user might API approach or any other location-adjusted
consider pollution prevention, recycling, and model prior to use.
12
A copy of API’s user manual, The Technical Background Document and User Manual (API Publication 4659),
can be obtained from the American Petroleum Institute, 1220 L Street, NW, Washington, DC 20005,
202 682-8375. 7A-33
Protecting Ground Water—Assessing Risk
7A-34
Protecting Ground Water—Assessing Risk
• IWEM is not designed for sites with • Incorrect fate and transport modeling
complex hydrogeology, such as frac- can result in a liner system that is not
tured (karst) aquifers. sufficiently protective or an inappro-
priate land application rate.
• The tool is inappropriate for sites
where non-aqueous phase liquid • To avoid incorrect analyses, check to
(NAPL) contaminants are present. see if the professional has sufficient
training and experience at analyzing
• IWEM does not account for all possi- ground-water flow and contaminant
ble fate and transport processes. For fate and transport.
example, colloid transport might be
important at some sites but is not
considered in IWEM. While the user professional experienced in ground-water
can enter a constituent-specific modeling. State officials and appropriate
degradation rate constant to account trade associations might be able to suggest a
for biodegradation, IWEM simulates good consultant to perform the analysis.
biodegradation in a relatively simple
way by assuming the rate is the same 1. How is a Tier 3 Evaluation
in both the unsaturated and the satu- Performed?
rated zones.
A Tier 3 evaluation will generally involve a
more detailed site-specific analysis than Tier
E. Tier 3: A Comprehensive 2. Sites for which a Tier 3 evaluation might
Site-Specific Evaluation be performed typically involve complex and
heterogeneous hydrogeology. Selection and
If the Tier 1 and Tier 2 evaluations do not application of appropriate ground-water
adequately simulate conditions at a proposed models require a thorough understanding of
site, or if you decide that sufficient data are the waste and the physical, chemical, and
available to skip a Tier 1 or Tier 2 analysis, a hydrogeologic characteristics of the site.
site-specific risk assessment could be consid-
ered.13 In situations involving a complex A Tier 3 evaluation should involve the fol-
hydrogeologic setting or other site-specific lowing steps:
factors that are not accounted for in IWEM, a • Developing a conceptual hydrogeo-
detailed site-specific ground-water fate and logical model of the site.
transport analysis might be appropriate for
determining risk to ground water and evalu- • Selecting a flow and transport simu-
ating alternative designs or application rates. lation model.
It is recommended that you consult with the • Applying the model to the site.
appropriate state agency and use a qualified
13
For example, if ground-water flow is subject to seasonal variations, use of the Tier 2 evaluation tool
might not be appropriate because the model is based on steady-state flow conditions.
7A-35
Protecting Ground Water—Assessing Risk
As with all modeling, you should consult • What other contaminant sources are
with the state before investing significant present?
resources in a site-specific analysis. The state
• What fate processes are likely to be
might have a list of preferred models and
significant (e.g. sorption and
might be able to help plan the fate and trans-
biodegradation)?
port analysis.
• Are plume concentrations high
enough to make density effects sig-
a. Developing a Conceptual
nificant?
Hydrogeological Model
The first step in the site-specific Tier 3
evaluation is to develop a conceptual hydro- b. Selecting a Fate and Transport
geological model of the site. The conceptual Simulation Model
model should describe the key features and Numerous computer models exist to simu-
characteristics to be captured in the fate and late ground-water fate and transport.
transport modeling. A complete conceptual Relatively simple models are often based on
hydrogeological model is important to ensure analytical solutions of the mathematical
that the fate and transport model can simu- equations governing ground-water flow and
late the important features of the site. The solute transport equations. However, such
conceptual hydrogeological model should models generally cannot simulate the com-
address questions such as: plexities of real world sites, and for a rigor-
ous Tier 3 evaluation, numerical models
• Does a confined aquifer, an uncon-
based on finite-difference or finite-element
fined aquifer, or both need to be sim-
techniques are recommended. The primary
ulated?
criteria for selecting a particular model
• Does the ground water flow through should be that it is consistent with the char-
porous media, fractures, or a combi- acteristics of the site, as described in the con-
nation of both? ceptual site hydrogeological model, and that
it is able to simulate the significant processes
• Is there single, or are there multiple,
that control contaminant fate and transport.
hydrogeologic layers to be simulated?
In addition to evaluating whether a model
• Is the hydrogeology constant or vari-
will adequately address site characteristics,
able in layer thickness?
the following questions should be answered
• Are there other hydraulic sources or to ensure that the model will provide accu-
sinks (e.g., extraction or injection rate, verifiable results:
wells, lakes, streams, ponds)?
• What is the source of the model?
• What is the location of natural no- How easy is it to obtain and is the
flow boundaries and/or constant model well documented?
head boundaries?
• Are documentation and user’s manu-
• How significant is temporal (season- als available for the model? If yes, are
al) variation in ground-water flow they clearly written and do they pro-
conditions? Does it require a tran- vide sufficient technical background
sient flow model? on the mathematical formulation and
solution techniques?
7A-36
Protecting Ground Water—Assessing Risk
7A-37
Protecting Ground Water—Assessing Risk
Table 12.
Example Site-Specific Ground-Water Fate and Transport Models
MODFLOW MODFLOW is a 3-D, ground-water flow model for steady state and transient simulation of
saturated flow problems in confined and unconfined aquifers. It calculates flow rates and
water balances. The model includes flow towards wells, through riverbeds, and into drains.
MODFLOW is the industry standard for ground-water modeling that was developed and
still maintained by the United States Geological Survey (USGS). MODFLOW-2000 is the
current version. MODFLOW is a public domain model; numerous pre- and post-processing
software packages are available commercially. MODFLOW can simulate ground-water flow
only. In order to simulate contaminant transport, MODFLOW must be used in conjunction
with a compatible solute transport model (MT3DMS, see below).
MODFLOW and other USGS models can be obtained from the USGS Web site at
<water.usgs.gov/nrp/gwsoftware/modflow.html>.
MT3DMS Modular 3-D Transport model (MT3D) is commonly used in contaminant transport model-
ing and remediation assessment studies. Originally developed for EPA, the current version is
known as MT3DMS. MT3DMS has a comprehensive set of options and capabilities for sim-
ulating advection, dispersion/diffusion, and chemical reactions of contaminants in ground-
water flow systems under general hydrogeologic conditions. MT3DMS retains the same
modular structure of the original MT3D code, similar to that implemented in MODFLOW.
The modular structure of the transport model makes it possible to simulate advection, dis-
persion/diffusion, source/sink mixing, and chemical reactions separately without reserving
computer memory space for unused options. New packages involving other transport
processes and reactions can be added to the model readily without having to modify the
existing code.
NOTE: The original version of this model known as MT3D, released in 1991, was based on
a mathematical formulation which could result in mass-balance errors. This version should
be avoided.
BIOPLUME-III BIOPLUME-III is a 2-D, finite difference model for simulating the natural attenuation of
organic contaminants in ground water due to the processes of advection, dispersion, sorp-
tion, and biodegradation. Biotransformation processes are potentially important in the
restoration of aquifers contaminated with organic pollutants. As a result, these processes
require valuation in remedial action planning studies associated with hydrocarbon contami-
nants. The model is based on the USGS solute transport code MOC. It solves the solute
transport equation six times to determine the fate and transport of the hydrocarbons, the
electron acceptors (O2, NO3-, Fe3+, SO42-, and CO2), and the reaction byproducts (Fe2+). A
number of aerobic and anaerobic electron acceptors (e.g., oxygen, nitrate, sulfate, iron (III),
and carbon dioxide) have been considered in this model to simulate the biodegradation of
organic contaminants. Three different kinetic expressions can be used to simulate the aero-
bic and anaerobic biodegradation reactions.
BIOPLUME-III and other EPA supported ground-water modeling software can be obtained
via the EPA Center for Subsurface Modeling Support at the RS Kerr Environmental Research
Lab in Ada, Oklahoma: <www.epa.gov/ada/csmos/models.html>.
7A-38
Protecting Ground Water—Assessing Risk
The American Society for Testing and Materials (ASTM), Section D-18.21.10 concerns
subsurface fluid-flow (ground-water) modeling. The ASTM ground-water modeling section
is one of several task groups funded under a cooperative agreement between USGS and EPA
to develop consensus standards for the environmental industry and keep the modeling
community informed as to the progress being made in development of modeling standards.
The standards being developed by D-18.21.10 are “guides” in ASTM terminology, which
means that the content is analogous to that of EPA guidance documents. The ASTM mod-
eling guides are intended to document the state-of-the-science related to various topics in
subsurface modeling.
The following standards have been developed by D-18.21.10 and passed by ASTM.
They can be purchased from ASTM by calling 610 832-9585. To order or browse for pub-
lications, visit ASTM’s Web site <www.astm.org> .
D-5447 Guide for Application of a Ground-Water Flow Model to a Site-Specific Problem
D-5490 Guide for Comparing Ground-Water Flow Model Simulations to Site-Specific
Information
D-5609 Guide for Defining Boundary Conditions in Ground-Water Flow Modeling
D-5610 Guide for Defining Initial Conditions in Ground-Water Flow Modeling
D-5611 Guide for Conducting a Sensitivity Analysis for a Ground-Water Flow Model
Application
D-5718 Guide for Documenting a Ground-Water Flow Model Application
D-5719 Guide to Simulation of Subsurface Air Flow Using Ground-Water Flow
Modeling Codes
D-5880 Guide for Subsurface Flow and Transport Modeling
D-5981 Guide for Calibrating a Ground-Water Flow Model Application
A compilation of most of the current modeling and aquifer testing standards also can be
purchased. The title of the publication is ASTM Standards on Analysis of Hydrologic
Parameters and Ground Water Modeling, publication number 03-418096-38.
For more information by e-mail, contact service@astm.org.
7A-39
Protecting Ground Water—Assessing Risk
7A-40
Protecting Ground Water—Assessing Risk
Resources
ASTM. 1996. ASTM Standards on Analysis of Hydrologic Parameters and Ground Water Modeling,
Publication Number 03-418096-38.
ASTM. 1993. D-5447 Guide for Application of a Ground-Water Flow Model to a Site-Specific
Problem.
ASTM. 1993. D-5490 Guide for Comparing Ground-Water Flow Model Simulations to Site-specific
Information.
ASTM. 1994. D-5609 Guide for Defining Boundary Conditions in Ground-Water Flow Modeling.
ASTM. 1994. D-5610 Guide for Defining Initial Conditions in Ground-Water Flow Modeling.
ASTM. 1994. D-5611 Guide for Conducting a Sensitivity Analysis for a Ground-Water Flow Model
Application.
ASTM. 1994. D-5718 Guide for Documenting a Ground-Water Flow Model Application.
ASTM. 1994. D-5719 Guide to Simulation of Subsurface Air Flow Using Ground-Water Flow
Modeling Codes.
ASTM. 1995. D-5880 Guide for Subsurface Flow and Transport Modeling.
ASTM. 1996. D-5981 Guide for Calibrating a Ground-Water Flow Model Application.
Berner, E. K. and R. Berner. 1987. The Global Water Cycle: Geochemistry and Environment.
Boulding, R. 1995. Soil, Vadose Zone, and Ground-Water Contamination: Assessment, Prevention,
and Remediation.
Sharma, H., and S. Lewis. 1994. Waste Containment Systems, Waste Stabilization, and Landfills.
Speidel, D., L. Ruedisili, and A. Agnew. 1988. Perspectives on Water: Uses and Abuses.
7A-41
Protecting Ground Water—Assessing Risk
Resources (cont.)
U.S. EPA. 2002a. Industrial Waste Management Evaluation Model (IWEM) Technical
Background Document. EPA530-R-02-012.
U.S. EPA. 2002b. The User’s Guide for the Industrial Waste Management Evaluation Model.
EPA530-R- 02-013.
U.S. EPA. 1997b. Guiding Principles for Monte Carlo Analyses. EPA630-R-97-001.
U.S. EPA. 1994a. A Technical Guide to Ground-Water Model Selection at Sites Contaminated
with Radioactive Substance. EPA 4-2-R-94-012.
U.S. EPA. 1994b. Assessment Framework for Ground-Water Modeling Applications. EPA500-B-
94-003.
U.S. EPA. 1991. Seminar Publication: Site Characterization for Subsurface Remediation.
EPA625-4-91-026.
U.S. EPA. 1988. Selection Criteria For Mathematical Models Used In Exposure Assessments:
Ground-water Models. EPA600-8-88-075.
7A-42
Part IV
Protecting Ground Water
Chapter 7: Section B
Designing and Installing Liners
Resources ....................................................................................................................................................7B-37
Appendix ....................................................................................................................................................7B-43
Figures:
Figure 1. Water Content for Achieving a Specific Density ..........................................................................7B-6
Figure 2: Two Types of Footed Rollers........................................................................................................7B-8
Figure 3: Four Variations of GCL Bonding Methods ................................................................................7B-19
Figure 4: Typical Leachate Collection System ..........................................................................................7B-25
Figure 5: Typical Geonet Configuration....................................................................................................7B-27
Protecting Ground Water—Designing and Installing Liners
O
nce risk has been characterized
and the most appropriate
I. In-Situ Soil
design system is chosen, the Liners
next step is unit design. The For the purpose of the Guide, in-situ soil
Industrial Waste Management refers to simple, excavated areas or impound-
Evaluation Model (IWEM), discussed in ments, without any additional engineering
Chapter 7, Section A—Assessing Risk can be controls. The ability of natural soils to hinder
used to determine appropriate design system transport and reduce the concentration of
recommendations. A critical part of this constituent levels through dilution and atten-
design for new landfills, waste piles, and sur- uation can provide sufficient protection when
face impoundments is the liner system. The the initial constituent levels in the waste
liner system recommendations in the Guide stream are very low, when the wastes are
do not apply to land application units, since inert, or when the hydrogeologic setting
such operations generally do not include a affords sufficient protection.
liner system as part of their design. (For
design of land application units, refer to What are the recommendations
Chapter 7, Section C—Designing a Land for in-situ soils?
Application Program.) You should work with
your state agency to ensure consideration of The soil below and adjacent to a waste
any applicable design system requirements, management unit should be suitable for con-
recommendations, or standard practices the struction. It should provide a firm foundation
state might have. In this chapter, sections I for the waste. Due to the low risk associated
though IV discuss four design options—no with wastes being managed in these units, a
liner/in-situ soils, single liner, composite liner, liner might not be necessary; however, it is
and double liner. Section V covers leachate still helpful to review the recommended loca-
collection and leak detection systems, and tion considerations and operating practices for
section VI discusses construction quality the unit.
assurance and quality control.
7B-1
Protecting Ground Water—Designing and Installing Liners
1
Many industry and trade periodicals, such as Waste Age, MSW Management, Solid Waste Technologies,
and World Wastes, have articles on liner types and their corresponding costs, as well as advertisements
7B-2 and lists of vendors.
Protecting Ground Water—Designing and Installing Liners
2
ASTM D-5084, Standard Test Method for Measurement of Hydraulic Conductivity of Saturated Porous
Materials Using a Flexible Wall Permeameter.
3
ASTM D-698, Test Method for Laboratory Compaction Characteristics of Soil Using Standard Effort
(12,400 ft-lbf/ft3 (600 kN-m/m3)).
ASTM D-1557, Test Method for Laboratory Compaction Characteristics of Soil Using Modified Effort
(56,000 ft-lbf/ft3 (2,700 kN-m/m3)). 7B-3
Protecting Ground Water—Designing and Installing Liners
Assurance and Quality Control for Waste sized particles. Soils with less than 30 percent
Containment Facilities (U.S. EPA, 1993c). fines can be worked to obtain hydraulic con-
ductivities below 1 x 10-7 cm/sec (4 x 10-8
Plasticity characteristics. Plasticity char-
in./sec), but use of these soils requires more
acteristics describe a material’s ability to
careful construction practices.
behave as a plastic or moldable material.
Soils containing clay are generally categorized Gravel is defined as particles unable to
as plastic. Soils that do not contain clay are pass through the openings of a Number 4
non-plastic and typically considered unsuit- sieve, which has an opening size equal to
able materials for compacted clay liners, 4.76 mm (0.2 in.). Although gravel itself has
unless soil amendments such as bentonite a high hydraulic conductivity, relatively large
clay are introduced. amounts of gravel, up to 50 percent by
weight, can be uniformly mixed with clay
Plasticity characteristics are quantified by
materials without significantly increasing the
three parameters: liquid limit, plastic limit,
hydraulic conductivity of the material. Clay
and plasticity index. The liquid limit is
materials fill voids created between gravel
defined as the minimum moisture content (in
particles, thereby creating a gravel-clay mix-
percent of oven-dried weight) at which a soil-
ture with a low hydraulic conductivity. As
water mixture can flow. The plastic limit is
long as the percent gravel in a compacted
the minimum moisture content at which a
clay mixture remains below 50 percent, cre-
soil can be molded. The plasticity index is
ating a uniform mixture of clay and gravel,
defined as the liquid limit minus the plastic
where clay can fill in gaps, is more critical
limit and defines the range of moisture con-
than the actual gravel content of the mixture.
tent over which a soil exhibits plastic behav-
ior. When soils with high plastic limits are You should pay close attention to the per-
too dry during placement, they tend to form cent gravel in cases where a compacted clay
clods, or hardened clumps, that are difficult liner functions as a bottom layer to a geosyn-
to break down during compaction. As a thetic, as gravel can cause puncturing in
result, preferential pathways can form around geosynthetic materials. Controlling the maxi-
these clumps allowing leachate to flow mum particle size and angularity of the grav-
through the material at a higher rate. Soil el should help prevent puncturing, as well as
plasticity indices typically range from 10 per- prevent gravel from creating preferential flow
cent to 30 percent. Soils with a plasticity paths. Similar to gravel, soil particles or rock
index greater than 30 percent are cohesive, fragments also can create preferential flow
sticky, and difficult to work with in the field. paths. To help prevent the development of
Common testing methods for plasticity char- preferential pathways and an increased
acteristics include the methods specified in hydraulic conductivity, it is best to use soil
ASTM D-4318, also known as Atterberg lim- liner materials where the soil particles and
its tests.4 rock fragments are typically small (e.g., 3/4
inch in diameter).
Percent fines and percent gravel. Typical
soil liner materials contain at least 30 percent
fines and can contain up to 50 percent gravel, Interactions With Waste
by weight. Common testing methods for per- Waste placed in a unit can interact with
cent fines and percent gravel are specified in compacted clay liner materials, thereby influ-
ASTM D-422, also referred to as grain size encing soil properties such as hydraulic con-
distribution tests.5 Fines refer to silt and clay-
4
ASTM D-4318, Standard Test Method for Liquid Limit, Plastic Limit, and Plasticity Index of Soils.
5
ASTM D-422, Standard Test Method for Particle-Size Analysis of Soils.
7B-4
Protecting Ground Water—Designing and Installing Liners
ductivity and permeability. Two ways that next step is to test a representative sample of
waste materials can influence the hydraulic soil to determine material properties such as
conductivity of the liner materials are plasticity characteristics, percent gravel, and
through dissolution of soil minerals and percent fines. To confirm the suitability of the
changes in clay structure. Soil minerals can materials once construction begins, you
be dissolved, or reduced to liquid form, as a should consider requesting that representa-
result of interaction with acids and bases. For tive samples from the materials in the borrow
example, aluminum and iron in the soil can or commercial pit be tested periodically after
be dissolved by acids, and silica can be dis- work has started.
solved by bases. While some plugging of soil
Material selection steps will vary, depend-
pores by dissolved minerals can lower
ing on the origin of the materials for the pro-
hydraulic conductivity in the short term, the
ject. For example, if a commercial pit provides
creation of piping and channels over time can
the materials, locating an appropriate onsite
lead to an increased hydraulic conductivity in
borrow pit is not necessary. In addition to the
the long term. The interaction of waste and
tests performed on the material, it is recom-
clay materials can also cause the creation of
mended that a qualified inspector make visual
positive ions, or cations. The presence of
observations throughout the construction
cations such as sodium, potassium, calcium,
process to ensure that harmful materials, such
and magnesium can change the clay struc-
as stones or other large matter, are not present
ture, thereby influencing the hydraulic con-
in the liner material.
ductivity of the liner. Depending on the
cation type and the clay mineral, an increased What issues should be considered
presence of such cations can cause the clay
minerals to form clusters and increase the in the construction of a liner and
permeability of the clay. Therefore, before the operation of a unit?
selecting a compacted clay liner material, it is
important to develop a good understanding You should develop test pads to demon-
of the composition of the waste that will be strate construction techniques and material
placed in the waste management unit. EPA’s performance on a small scale. During unit con-
Method 9100, in publication SW-846, mea- struction and operation, some additional fac-
sures the hydraulic conductivity of soil sam- tors influencing the performance of the liner
ples before and after exposure to permeants.6 include: preprocessing, subgrade preparation,
method of compaction, and protection against
desiccation and cracking. Each of these steps,
Locating and Testing Material from preprocessing through protection against
Although the selection process for com- desiccation and cracking, should be repeated
pacted clay liner construction materials can for each lift or layer of soil.
vary from project to project, some common
material selection steps include locating and Test Pads
testing materials at a potential borrow or
commercial pit before construction, and Preparing a test pad for the compacted
observing and testing material performance clay liner helps verify that the materials and
throughout construction. First, investigate a methods proposed will yield a liner that
potential borrow or commercial pit to deter- meets the desired hydraulic conductivity. A
mine the volume of materials available. The test pad also provides an opportunity to
6
SW-846, Test Methods for Evaluating Solid Waste: Physical/Chemical Methods.
7B-5
Protecting Ground Water—Designing and Installing Liners
demonstrate the performance of alternative mum tend to have a relatively high hydraulic
materials or methods of construction. A test conductivity. Soils compacted at water con-
pad should be constructed with the soil liner tents greater than optimum tend to have low
materials proposed for a particular project, hydraulic conductivity and low strength.
using the same preprocessing procedures,
Proper soil water content revolves around
compaction equipment, and construction
achieving a minimum dry density, which is
practices proposed for the actual liner. A
expressed as a percentage of the soil’s maxi-
complete discussion of test pads (covering
mum dry density. The minimum dry density
dimensions, materials, and construction) can
typically falls in the range of 90 to 95 percent
be found in Chapter 2 of EPA’s 1993 techni-
of the soil’s maximum dry density value. From
cal guidance document Quality Assurance and
the minimum dry density range, the required
Quality Control for Waste Containment Facilities
water content range can be calculated, as
(U.S. EPA, 1993c). A discussion of commonly
shown in Figure 1. In this example the soil
used methods to measure in-situ hydraulic
has a maximum dry density of 115 lb/cu ft.
conductivity is also contained in that chapter.
Based upon a required minimum dry density
value of 90 percent of maximum dry density,
Preprocessing
Although some liner Figure 1.
materials can be ready Water Content for Achieving a Specific Density
for use in construction
immediately after they
are excavated, many
materials will require
some degree of prepro-
cessing. Preprocessing
methods include: water
content adjustment,
removal of oversized
particles, pulverization
of any clumps, homoge-
nization of the soils, and
introduction of addi-
tives, such as bentonite.
Water content
adjustment. For natural
soils, the degree of satu-
ration of the soil liner at
the time of compaction,
known as molding water
content, influences the
engineering properties of
the compacted material.
Soils compacted at water
contents less than opti- Source: U.S. EPA, 1988.
7B-6
Protecting Ground Water—Designing and Installing Liners
which is equal to 103.5 lb/cu ft, the required mon practice is to blend bentonite with them
water content ranges from 10 to 28 percent. to reduce the hydraulic conductivity. Bentonite
is a clay mineral that expands when it comes
It is less problematic to compact clay soil
into contact with water. Relatively small
at the lower end of the required water con-
amounts of bentonite, on the order of 5 to 10
tent range because it is easier to add water to
percent, can be added to sand or other nonco-
the clay soil than to remove it. Thus, if pre-
hesive soils to increase the cohesion of the
cipitation occurs during construction of a site
material and reduce hydraulic conductivity.
which is being placed at the lower end of the
required water content range, the additional Sodium bentonite is a common additive
water might not result in a soil water content used to amend soils. However, this additive is
greater than the required range. Conversely, if vulnerable to degradation as a result of con-
the site is being placed at the upper end of tact with certain chemicals and waste
the range, for example at 25 percent, any leachates. Calcium bentonite, a more perme-
additional moisture will be excessive, result- able material than sodium bentonite, is anoth-
ing in water content over 28 percent and er common additive used to amend soils.
making the 90 percent maximum dry density Approximately twice as much calcium ben-
unattainable. Under such conditions con- tonite is needed to achieve a hydraulic con-
struction should halt while the soil is aerated ductivity comparable to that of sodium
and excess moisture is allowed to evaporate. bentonite. Amended soil mixtures generally
require mixing in a pug mill, cement mixer, or
Removal of oversized particles.
other mixing equipment that allows water to
Preprocessing clay materials, to remove cob-
be added during the mixing process.
bles or large stones that exceed the maximum
Throughout the mixing and placement
allowable particle size, can improve the soil’s
processes, water content, bentonite content,
compactibility and protect any adjacent
and particle distribution should be controlled.
geomembrane from puncture. Particle size
Other materials that can be used as soil addi-
should be small (e.g., 3/4 inch in diameter)
tives include lime cement and other clay min-
for compaction purposes. If a geomembrane
erals, such as atapulgite. It can be difficult to
will be placed over the compacted clay, only
mix additives thoroughly with cohesive soils,
the upper lift of clay needs to address con-
or clays; the resultant mixture might not
cerns regarding puncture resistance.
achieve the desired level of hydraulic conduc-
Observation by quality assurance and quality
tivity throughout the entire liner.
control personnel is the most effective
method to identify areas where oversized par-
ticles need to be removed. Cobbles and Subgrade Preparation
stones are not the only materials that can It is important to ensure that the subgrade
interfere with compactive efforts. Chunks of on which a compacted clay liner will be con-
dry, hard clay, also known as clods, often structed is properly prepared. When a com-
need to be broken into smaller pieces to be pacted clay liner is the lowest component of a
properly hydrated, remolded, and compact- liner system, the subgrade consists of native
ed. In wet clay, clods are less of a concern soil or rock. Subgrade preparation for these
since wet clods can often be remolded with a systems involves compacting the native soil
reasonable compactive effort. to remove any soft spots and adding water to
Soil amendments. If the soils at a unit do or removing water from the native soil to
not have a sufficient percentage of clay, a com- obtain a specified firmness. Alternatively, in
7B-7
Protecting Ground Water—Designing and Installing Liners
some cases, the compacted clay liner can be ness, and the bonding between the lifts.
placed on top of a geosynthetic material, such Molding water content, described earlier
as a geotextile. In such cases, subgrade prepa- under preprocessing, is another factor influ-
ration involves ensuring the smoothness of encing the effectiveness of compaction.
the geosynthetic on which the clay liner will
Type of equipment. Factors to consider
be placed and the conformity of the geosyn-
when selecting compaction equipment
thetic material to the underlying material.
include: the type and weight of the com-
pactor, the characteristics of any feet on the
Compaction drum, and the weight of the roller per unit
The main purpose of compaction is to length of drummed surface. Heavy com-
densify the clay materials by breaking and pactors, weighing more than 50,000 pounds,
remolding clods of material into a uniform with feet long enough to penetrate a loose lift
mass. Since amended soils usually do not of soil, are often the best types of compactor
develop clumps, the primary objective of for clay liners. For bentonite-soil mixtures, a
compaction for such materials is to increase footed roller might not be appropriate. For
the material’s density. Proper compaction of these mixtures, where densification of the
liner materials is essential to ensure that a material is more important than kneading or
compacted clay liner meets specified remolding it to meet low hydraulic conduc-
hydraulic conductivity standards. Factors tivity specifications, a smooth-drum roller or
influencing the effectiveness of compaction a rubber- tired roller might produce better
efforts include: the type of equipment select- results. Figure 2 depicts two types of footed
ed, the number of passes made over the rollers, a fully penetrating footed roller and a
materials by such equipment, the lift thick- partially-penetrating footed roller.
7B-8
Protecting Ground Water—Designing and Installing Liners
For placement of liners on side slopes, are usually necessary to remold and compact
consider the angle and length of the slope. clay liner materials thoroughly.
Placing continuous lifts on a gradually
An equipment pass can be defined as one
inclined slope will provide better continuity
pass of the compaction equipment or as one
between the bottom and sidewalls of the
pass of a drum over a given area of soil. It is
liner. Since continuous lifts might be impossi-
important to clearly define what is meant by
ble to construct on steeper slopes due to the
a pass in any quality assurance or quality
difficulties of operating heavy compaction
control plans. It does not matter which defin-
equipment on these slopes, materials might
ition is agreed upon, as long as the definition
need to be placed and compacted in horizon-
is used consistently throughout the project.
tal lifts. When sidewalls are compacted hori-
zontally, it is important to avoid creating Lift thickness. You should determine the
seepage planes, by securely connecting the appropriate thickness (as measured before
edges of the horizontal lift with the bottom of compaction) of each of the several lifts that
the liner. Because the lift needs to be wide will make up the clay liner. The initial thick-
enough to accommodate compaction equip- ness of a loose lift will affect the compactive
ment, the thickness of the horizontal lift is effort needed to reach the lower portions of
often greater than the thickness specified in the lift. Thinner lifts allow compactive efforts
the design. In such cases, you should consid- to reach the bottom of a lift and provide
er trimming soil material from the construct- greater assurance that compaction will be suf-
ed side slopes and sealing the trimmed ficient to allow homogenous bonding
surface using a sealed drum roller. between subsequent lifts. Loose lift thickness-
es typically range between 13 and 25 cm (5
It is common for contractors to use several
and 10 in.). Factors influencing lift thickness
different types of compaction equipment dur-
are: soil characteristics, compaction equip-
ing liner construction. Initial lifts might need
ment, firmness of the foundation materials,
the use of a footed roller to fully penetrate a
and the anticipated compaction necessary to
loose lift. Final lifts also might need the use
meet hydraulic conductivity requirements.
of a footed roller for compaction, however,
they might be formed better by using a Bonding between lifts. Since it is
smooth roller after the lift has been compact- inevitable that some zones of higher and
ed to smooth the surface of the lift in prepa- lower hydraulic conductivity, also known as
ration for placement of an overlying preferential pathways, will be present within
geomembrane. each lift, lifts should be joined or bonded in a
way that minimizes extending these zones or
Number of passes. The number of passes
pathways between lifts. If good bonding is
made by a compactor over clay materials can
achieved, the preferential pathways will be
influence the overall hydraulic conductivity
truncated by the bonded zone between the
of the liner. The minimum number of passes
lifts. At least two recommended methods
that is reasonable depends on a variety of
exist for preparing proper bonds. The first
site-specific factors and cannot be general-
method involves kneading, or blending the
ized. In some cases, where a minimum cover-
new lift with the previously compacted lift
age is specified, it might be possible to
using a footed roller. Using a roller with feet
calculate the minimum number of passes to
long enough to fully penetrate through the
meet such a specification. At least 5 to 15
top lift and knead the previous lift improves
passes with a compactor over a given point
the quality of the bond. A second method
7B-9
Protecting Ground Water—Designing and Installing Liners
involves using a disc harrow or similar equip- increase the hydraulic conductivity of a liner.
ment to scarify, or roughen, and wet the top It is important to avoid construction during
inch of the recently placed lift, prior to plac- freezing weather. If freezing does occur and
ing the next lift. the damage affects only a shallow depth, the
liner can be repaired by rerolling the surface.
If deeper freezing occurs, the repairs might
Protection Against Desiccation and
be more complicated. For a general guide to
Cracking frost depths, see Figure 1 of Chapter 11—
You should consider how to protect com- Performing Closure and Post-Closure Care.
pacted clay liners against desiccation and
freezing during and after construction.
Protection against desiccation is important, B. Geomembranes or
because clay soil shrinks as it dries. Depend- Flexible Membrane Liners
ing on the extent of shrinkage, it can crack. Geomembranes or flexible membrane lin-
Deep cracks, extending through more than ers are used to contain or prevent waste con-
one lift, can cause problems. You should stituents and leachate from escaping a waste
measure water content to determine whether management unit. Geomembranes are made
desiccation is occurring. by combining one or more plastic polymers
There are several ways to protect compact- with ingredients such as carbon black, pig-
ed clay liners from desiccation. One preven- ments, fillers, plasticizers, processing aids,
tive measure is to smooth roll the surface with crosslinking chemicals, anti-degradants, and
a steel drummed roller to produce a thin, biocides. A wide range of plastic resins are
dense skin of soil; this layer can help mini- used for geomembranes, including high den-
mize the movement of water into or out of the sity polyethylene (HDPE), linear low density
compacted material. Another option is to wet polyethylene (LLDPE), low density linear
the clay periodically in a uniform manner; polyethlene (LDLPE), very low density poly-
however, it is important to make sure to avoid ethlene (VLDPE), polyvinyl chloride (PVC),
creating areas of excessive wetness. A third flexible polypropylene (fPP), chlorosulfonated
measure involves covering compacted clay polyethylene (CSPE or Hypalon), and ethyl-
liner materials with a sheet of white or clear ene propylene diene termonomer (EPDM).
plastic or tarp to help prevent against desicca- Most manufacturers produce geomembranes
tion and cracking. The cover should be through extrusion or calendering. In the
weighted down with sandbags or other mater- extrusion process, a molten polymer is
ial to minimize exposure of the underlying stretched into a nonreinforced sheet; extrud-
materials to air. Using a light-colored plastic ed geomembranes are usually made of HDPE
will help prevent overheating, which can dry and LLDPE. During the calendering process,
out the clay materials. If the clay liner is not a heated polymeric compound is passed
being covered with a geosynthetic, another through a series of rollers. In this process, a
method to prevent desiccation involves cover- geomembrane can be reinforced with a
ing the clay with a layer of protective cover woven fabric or fibers. Calendered geomem-
soil or intentionally overbuilding the clay liner branes are usually made of PVC and CSPE.
and shaving it down to liner grade.
Protection against freezing is another
important consideration, because freezing can
7B-10
Protecting Ground Water—Designing and Installing Liners
What are the thickness recommen- These stresses include the self-weight of the
geomembrane and any down drag caused by
dations for geomembrane liners? waste settlement on side slope liners.
Geomembranes range in thicknesses from 20 Puncture and tear resistance.
to 120 mil (1 mil = 0.001 in.). A good design Geomembrane liners can be subject to tearing
should include a minimum thickness of 30 mil, during installation due to high winds or han-
except for HDPE liners, which should have a dling. Puncture resistance is also important to
minimum thickness of 60 mil. These recom- consider since geomembranes are often
mended minimum thicknesses ensure that the placed above or below materials that might
liner material will withstand the stress of con- have jagged or angular edges. For example,
struction and the weight load of the waste, and geomembranes might be installed above a
allow adequate seaming to bind separate granular drainage system that includes gravel.
geomembrane panels. Reducing the potential
for tearing or puncture, through proper con- Susceptibility to environmental stress
struction and quality control, is essential for a cracks. Environmental factors can cause
geomembrane to perform effectively. cracks or failures before a liner is stressed to
its manufactured strength. These imperfec-
What issues should be considered tions, referred to as environmental stress
in the design of a geomembrane cracks, often occur in areas where a liner has
been scratched or stressed by fatigue. These
liner? cracks can also result in areas where excess
Several factors to address in the design surface wetting agents have been applied. In
include: determining appropriate material surface impoundments, where the geomem-
properties and testing to ensure these proper- brane liner has greater exposure to the atmos-
ties are met, understanding how the liner will phere and temperature changes, such
interact with the intended waste stream, exposure can increase the potential for envi-
accounting for all stresses imposed by the ronmental stress cracking.
design, and ensuring adequate friction. Ultraviolet resistance. Ultraviolet resis-
tance is another factor to consider in the
Material Properties and Selection design of geomembrane liners, especially in
cases where the liner might be exposed to
When designing a geomembrane liner, you
ultraviolet radiation for prolonged periods of
should examine several properties of the
time. In such cases, which often occur in sur-
geomembrane material in addition to thick-
face impoundments, ultraviolet radiation can
ness, including: tensile behavior, tear resis-
cause degradation and cracking in the
tance, puncture resistance, susceptibility to
geomembrane. Adding carbon black or other
environmental stress cracks, ultraviolet resis-
additives during the manufacturing process
tance, and carbon black content.
can increase a geomembrane’s ultraviolet
Tensile behavior. Tensile behavior refers to resistance. Backfilling over the exposed
the tensile strength of a material and its ability geomembrane also works to prevent degrada-
to elongate under strain. Tensile strength is the tion due to ultraviolet radiation.
ability of a material to resist pulling stresses
without tearing. The tensile properties of a
Interactions With Waste
geomembrane must be sufficient to satisfy the
stresses anticipated during its service life. Since the main purpose of a geomembrane
is to provide a barrier and prevent contami-
7B-11
Protecting Ground Water—Designing and Installing Liners
nants from penetrating through the geomem- Designing for Adequate Friction
brane, chemical resistance is a critical consid- Adequate friction between the geomem-
eration. Testing for chemical resistance might brane liner and the soil subgrade, as well as
be warranted depending on the type, vol- between any geosynthetic components, is
umes, and characteristics of waste managed necessary to prevent extensive slippage or
at a particular unit and the type of geomem- sloughing on the slopes of a unit. Design
brane to be used. An established method for equations for such components should evalu-
testing the chemical resistance of geomem- ate: 1) the ability of a liner to support its own
branes, EPA Method 9090, can be found in weight on side slopes, 2) the ability of a liner
SW-846. ASTM has also adopted standards to withstand down-dragging during and after
for testing the chemical compatibility of vari- waste placement, 3) the best anchorage con-
ous geosynthetics, including geomembranes, figuration for the liner, 4) the stability of soil
with leachates from waste management units. cover on top of a liner, and 5) the stability of
ASTM D-5747 provides a standard for testing other geosynthetic components, such as geot-
the chemical compatibility of extiles or geonets, on top of a liner. An evalu-
geomembranes.7 ation of these issues can affect the choice of
geomembrane material, polymer type, fabric
Stresses Imposed by Liner Design reinforcement, thickness, and texture neces-
A liner design should take into account the sary to achieve the design requirements.
stresses imposed on the liner by the design Interface strengths can be significantly
configuration. These stresses include: the dif- improved by using textured geomembranes.
ferential settlement in foundation soil, strain
requirements at the anchor trench, strain
What issues should be consid-
requirements over long, steep side slopes, ered in the construction of a
stresses resulting from compaction, and seis- geomembrane liner?
mic stresses. Often an anchor trench designed
to secure the geomembrane during construc- When preparing to construct a geomem-
tion is prepared along the perimeter of a unit brane liner, you should plan appropriate
cell. This action can help prevent the shipment and handling procedures, perform
geomembrane from slipping down the interi- testing prior to construction, prepare the
or side slopes. Trench designs should include subgrade, consider temperature effects, and
a depth of burial sufficient to hold the speci- account for wind effects. In addition, you
fied length of liner. If forces larger than the should select a seaming process, determine a
tensile strength of the liner are inadvertently material for and method of backfilling, and
developed, then the liner could tear. For this plan for testing during construction.
reason, the geomembrane liner should be
allowed to slip or give in the trench after con- Shipment, Handling, and Site Storage
struction to prevent such tearing. To help
You should follow quality assurance and
reduce unnecessary stresses in the liner de-
quality control procedures to ensure proper
sign, it is advisable to avoid using horizontal
handling of geomembranes. Different types of
seams. For more information on design stress-
geomembrane liners require different types of
es, consult Geosynthetic Guidance for
packaging for shipment and storage.
Hazardous Waste Landfill Cells and Surface
Typically a geomembrane manufacturer will
Impoundments (U.S. EPA, 1987).
provide specific instructions outlining the
7
ASTM D-5747, Practice for Tests to Evaluate the Chemical Resistance of Geomembranes to Liquids.
7B-12
Protecting Ground Water—Designing and Installing Liners
handling, storage, and construction specifica- Guidance Document: Quality Assurance and
tions for a product. In general, HDPE and Quality Control for Waste Containment Facilities
LLDPE geomembrane liners are packaged in a (U.S. EPA, 1993c).
roll form, while PVC and CSPE-R liners
(CSPE-R refers to a CSPE geomembrane liner
Testing Prior to Construction
reinforced with a fabric layer) are packaged in
panels, accordion-folded in two directions, Before any construction begins, is it recom-
and placed onto pallets. Whether the liner is mended that you test both the geomembrane
shipped in rolls or panels, you should pro- materials from the manufacturer and the
vide for proper storage. The rolls and panels installation procedures. Acceptance and con-
should be packaged so that fork lifts or other formance testing is used to evaluate the per-
equipment can safely transport them. For formance of the manufactured geomembranes.
rolls, this involves preparing the roll to have a Constructing test strips can help evaluate how
sufficient inside diameter so that a fork lift well the intended construction process and
with a long rod, known as a stinger, can be quality control procedures will work.
used for lifting and moving. For accordion Acceptance and conformance testing.
panels, proper packaging involves using a You should perform acceptance and confor-
structurally-sound pallet, wrapping panels in mance testing on the geomembrane liner
treated cardboard or plastic wrapping to pro- received from the manufacturer to determine
tect against ultraviolet exposure, and using whether the materials meet the specifications
banding straps with appropriate cushioning. requested. While the specific ASTM test
Once the liners have been transported to the methods vary depending on geomembrane
site, the rolls or panels can be stored until the type, recommended acceptance and confor-
subgrade or subbase (either natural soils or mance testing for geomembranes includes
another geosynthetic) is prepared. evaluations of thickness, tensile strength and
elongation, and puncture and tear resistance
Subgrade Preparation testing, as appropriate. For most geomem-
brane liner types, the recommended ASTM
Before a geomembrane liner is installed,
method for testing thickness is ASTM D-
you should prepare the subgrade or subbase.
5199.8 For measuring the thickness of tex-
The subgrade material should meet specified
tured geomembranes, you should use ASTM
grading, moisture content, and density
D-5994.9 For tensile strength and elongation,
requirements. In the case of a soil subgrade,
ASTM D-638 is recommended for the HDPE
it is important to prevent construction equip-
and LLDPE sheets, while ASTM D-882 and
ment used to place the liner from deforming
ASTM D-751 are recommended for PVC and
the underlying materials. If the underlying
CSPE geomembranes, respectively.10 Puncture
materials are geosynthetics, such as geonets
resistance testing is typically recommended
or geotextiles, you should remove all folds
for HDPE and LLDPE geomembranes using
and wrinkles before the liner is placed. For
ASTM D-4833.11 To evaluate tear resistance
further information on geomembrane place-
for HDPE, LLDPE, and PVC geomembrane
ment, see Chapter 3 of EPA’s Technical
8
ASTM D-5199, Standard Test Method for Measuring Nominal Thickness of Geotextiles and
Geomembranes.
9
ASTM D-5994, Measuring Core Thickness of Textured Geomembranes.
10
ASTM D-638, Standard Test Method for Tensile Properties of Plastics.
ASTM D-882, Standard Test Methods for Tensile Properties of Thin Plastic Sheeting.
ASTM D-751, Standard Test Methods for Coated Fabrics.
11
ASTM D-4833, Standard Test Method for Index Puncture Resistance of Geotextiles, Geomembranes, 7B-13
and Related Products.
Protecting Ground Water—Designing and Installing Liners
liners, the recommended testing method is potential for tearing as a result of uplift. If
ASTM D-1004, Die C.12 For CSPE-R wind uplift is a potential problem, panels can
geomembranes, ply adhesion is more of a be weighted down with sand bags.
concern than tear or puncture resistance and
can be evaluated using ASTM D-413,
Seaming Processes
Machine Method, Type A.13
Once panels or rolls have been placed,
Test strips. In preparation for liner place- another critical step involves field-seaming
ment and field seaming, you should develop the separate panels or rolls together. The
test strips and trial seams as part of the con- selected seaming process, such as thermal or
struction process. Construction of such sam- chemical seaming, will depend on the chemi-
ples should be performed in a manner that cal composition of the liner. To ensure the
reproduces all aspects of field production. integrity of the seam, you should use the
Providing an opportunity to test seaming seaming method recommended by the manu-
methods and workmanship helps ensure that facturer. Thermal seaming uses heat to bond
the quality of the seams remains constant together the geomembrane panels. Examples
and meets specifications throughout the of thermal seaming processes include extru-
entire seaming process. sion welding and thermal fusion (or melt
bonding). Chemical seaming involves the use
Temperature Effects of solvents, cement, or an adhesive. Chemical
seaming processes include chemical fusion
Liner material properties can be altered by
and adhesive seaming. For more information
extreme temperatures. High temperatures can
on seaming methods, Technical Guidance
cause geomembrane liner surfaces to stick
Document: Inspection Techniques for the
together, a process commonly referred to as
Fabrication of Geomembrane Field Seams (U.S.
blocking. On the other hand, low tempera-
EPA, 1991c), contains a full chapter on each
ture can cause the liner to crack when
of the traditional seaming methods and addi-
unrolled or unfolded. Recommended maxi-
tional discussion of emerging techniques,
mum and minimum allowable sheet tempera-
such as ultrasonic, electrical conduction, and
tures for unrolling or unfolding geomembrane
magnetic energy source methods.
liners are 50°C (122°F) and 0°C (32°F),
respectively. In addition to sticking and crack- Consistent quality in fabricating field
ing, extreme temperatures can cause geomem- seams is paramount to liner performance.
branes to contract or expand. Polyethylene Conditions that could affect seaming should
geomembranes expand when heated and con- be monitored and controlled during installa-
tract when cooled. Other geomembranes can tion. Factors influencing seam construction
contract slightly when heated. Those respon- and performance include: ambient tempera-
sible for placing the liner should take temper- ture, relative humidity, wind uplift, changes
ature effects into account as they place, seam, in geomembrane temperature, subsurface
and backfill in the field. water content, type of supporting surface
used, skill of the seaming crew, quality and
consistency of chemical or welding materials,
Wind Effects
preparation of liner surfaces to be joined,
It is recommended that you take measures moisture at the seam interface, and cleanli-
to protect geomembrane liners from wind ness of the seam interface.
damage. Windy conditions can increase the
12
ASTM D-1004, Standard Test Method for Initial Tear Resistance of Plastic Film and Sheeting.
13
ASTM D-413, Standard Test Methods for Rubber Property-Adhesion to Flexible Substrate.
7B-14
Protecting Ground Water—Designing and Installing Liners
To help control some of these factors, no cover layer is a geosynthetic, it will typically
more than the amount of sheeting that can be be a geonet or geocomposite drain placed
used during a shift or a work day should be directly over the geomembrane. Careful
deployed at one time. To prevent erosion of placement of backfill materials is critical to
the underlying soil surface or washout of the avoid puncturing or tearing the geomem-
geomembrane, proper storm water control brane material.
measures should be employed. Ambient tem-
For soil covers, three considerations deter-
perature can become a concern, if the
mine the amount of slack to be placed in the
geomembrane liner has a high percentage of
underlying geomembrane. These considera-
carbon black. Although the carbon black will
tions include selecting the appropriate type of
help to prevent damage resulting from ultra-
soil, using the proper type of equipment, and
violet radiation, because its dark color
establishing a placement procedure for the
absorbs heat, it can increase the ambient tem-
soil. When selecting a soil for backfilling,
perature of the geomembrane, making instal-
characteristics to consider include particle
lation more complicated. To avoid surface
size, hardness, and angularity, as each of these
moisture or high subsurface water content,
can affect the potential for tearing or punctur-
geomembranes should not be deployed when
ing the liner. To prevent wrinkling, soil covers
the subgrade is wet.
should be placed over the geomembrane in
Regardless of how well a geomembrane such a way that construction vehicles do not
liner is designed, its ability to meet perfor- drive directly on the liner. Care should be
mance standards depends on proper quality taken not to push heavy loads of soil over the
assurance and quality control during installa- geomembrane in a continuous manner.
tion. Geomembrane sheets and seams are Forward pushing can cause localized wrinkles
subject to tearing and puncture during instal- to develop and overturn in the direction of
lation; punctures or tears can result from con- movement. Overturned wrinkles create sharp
tact with jagged edges or underlying materials creases and localized stress in the liner and
or by applying stresses greater than the can lead to premature failure. A recommend-
geomembrane sheet can handle. Proper quali- ed method for placing soil involves continual-
ty assurance and quality control can help ly placing small amounts of soil or drainage
minimize the occurrence of pinhole or seam material and working outward over the toe of
leaks. For example, properly preparing the the previously placed material.
underlying layer and ensuring that the gravel
Another recommended method involves
is of an acceptable size reduces the potential
placing soil over the liner with a large back-
for punctures.
hoe and spreading it with a bulldozer or sim-
ilar equipment. If a predetermined amount of
Protection and Backfilling slack is to be placed in the geomembrane, the
Geomembrane liners that can be damaged temperature of the liner becomes an impor-
by exposure to weather or work activities tant factor, as it will effect the ability of the
should be covered with a layer of soil or a liner to contract and expand. Although the
geosynthetic as soon as possible after quality recommended methods for covering
assurance activities associated with geomem- geomembrane liners with soil can take more
brane testing are completed. If the backfill time than backfilling with larger amounts of
layer is a soil material, it will typically be a soil, these methods are designed to prevent
drainage material like sand or gravel. If the damage caused by covering the liner with too
7B-15
Protecting Ground Water—Designing and Installing Liners
much soil too quickly. In the long run, pre- tive testing should be performed during con-
venting premature liner failure can be faster struction also. For increased quality assur-
and more cost-effective than having to repair ance, it is recommended that peel and shear
a damaged liner. tests on samples from the installed geomem-
brane be performed by an independent labo-
The types of geosynthetics that are often
ratory. Testing methods for shear testing, peel
used as protective covering include geotex-
testing, and tensile testing vary for different
tiles and geonets. Geogrids and drainage geo-
geomembrane liner types.
composites can be used for cover soil
reinforcement on slopes. The appendix at the Determining the number of samples to
end of this chapter provides additional infor- take is a difficult step. Taking too few sam-
mation on geosynthetic materials. For ples results in a poor statistical representation
geosynthetic protective covers, as with soil of the geomembrane quality. On the other
backfilling, to prevent tearing or puncturing, hand, taking too many samples requires
most construction vehicles should not be additional costs and increases the potential
permitted to move directly on the geomem- for defects. Defects can result from the repair
brane. Some possible exceptions include patches used to cover the areas from which
small, 4-wheel, all terrain vehicles or other samples were taken.
types of low ground pressure equipment.
A common sampling strategy is “fixed
Even with these types of vehicles, drivers
increment sampling” where samples are
should take extreme care to avoid move-
taken at a fixed increment along the length of
ments, such as sudden starts, stops, and
the geomembrane. Increments range from 80
turns, which can damage the geomembrane.
to 300 m (250 to 1,000 ft). The type of
Seaming-related equipment should be
welding, such as extrusion or fusion welding,
allowed on the geomembrane liner, as long as
used to connect the seams and the type of
it does not damage the liner. Geosynthetic
geomembrane liner can also help determine
materials are placed directly on the liner and
the appropriate sampling interval. For exam-
are not bonded to it.
ple, extrusion seams on HDPE require grind-
ing prior to welding and if extensive grinding
Testing During Construction occurs, the strength of the HDPE might
Testing during construction enables assess- decrease. In such cases, sampling at closer
ment of the integrity of the seams connecting intervals, such as 90 to 120 m (300 to 400
the geomembrane panels. Tests performed on ft), might provide a more accurate descrip-
the geomembrane seams are categorized as tion of material properties. If the seam is a
either destructive or nondestructive. dual hot edge seam, both the inner and outer
seams might need to be sampled and tested.
Destructive testing. Destructive testing
refers to removing a sample from the liner If test results for the seam or sheet samples
seam or sheet and performing tests on the do not meet the acceptance criteria for the
sample. For liner seams, destructive testing destructive tests, you should continue testing
includes shear testing and peel testing; for the area surrounding the rejected sample to
liner sheets, it involves tensile testing. While determine the limits of the low quality seam.
quality control procedures often require Once the area of low quality has been identi-
destructive testing prior to construction, in fied, then corrective measures, such as seaming
order to ensure that the installed seams and a cap over the length of the seam or reseaming
sheets meet performance standards, destruc- the affected area, might be necessary.
7B-16
Protecting Ground Water—Designing and Installing Liners
7B-17
Protecting Ground Water—Designing and Installing Liners
Type of bonds. Geosynthetic clay liners strength, bentonite clay can be placed
are available with a variety of bonding between geotextiles and stitch bonded or
designs, which include a combination of clay, needle- punched to provide additional stabil-
adhesives, and geomembranes or geotextiles. ity. For example, a GCL with geotextiles sup-
The type of adhesives, geotextiles, and ported by stitch bonding has greater internal
geomembranes used as components of GCLs resistance to shear in the clay layer than a
varies widely. One type of available GCL GCL without any stitching. Needle-punched
design uses a bentonite clay mixed with an GCLs tend to provide greater resistance than
adhesive bound on each side by geotextiles. stitch-bonded GCLs and can also provide
A variation on this design involves stitching increased friction resistance against an
the upper and lower geotextiles together adjoining layer, because they require the use
through the clay layer. Alternatively, another of nonwoven geotextiles. Increased friction is
option is to use a GCL where geotextiles on an important consideration on side slopes.
each side of adhesive or nonadhesive ben-
Mass per unit area. Mass per unit area
tonite clay are connected by needle punch-
refers to the bentonite content of a GCL. It is
ing. A fourth variation uses a clay mixed with
important to distribute bentonite evenly
an adhesive bound to a geomembrane on one
throughout the GCL in order to meet desired
side; the geomembrane can be either the
hydraulic conductivity specifications. All
lower or the upper surface. Figure 3 displays
GCL products available in North America use
cross section sketches of the four variations
a sodium bentonite clay with a mass per unit
of GCL bonds. While these options describe
area ranging from 3.2 to 6.0 kg/m2 (0.66 to
GCLs available at the time of this Guide,
1.2 lb/ft2), as manufactured.
emerging technologies in GCL designs
should also be reviewed and considered.
Interaction With Waste
Thickness. The thickness of the various
available GCL products ranges from 4 to 6 During the selection process for a GCL
mm (160 to 320 mil). Thickness measure- liner, you should evaluate the chemical com-
ments are product dependent. Some GCLs patibility of the liner materials with the types
can be quality controlled for thickness while of waste that are expected to be placed in the
others cannot. unit. Certain chemicals, such as calcium, can
have an adverse effect on GCLs, resulting in a
Moisture content. GCLs are delivered to loss of liner integrity. Specific information on
the job site at moisture contents ranging from GCL compatibilities should be available from
5 to 23 percent, referred to as the “dry” state. the manufacturer.
GCLs are delivered dry to prevent premature
hydration, which can cause unwanted varia- What issues should be consid-
tions in the thickness of the clay component
ered in the construction of a
as a result of uneven swelling.
geosynthetic clay liner?
Stability and shear strength. GCLs
should be manufactured and selected to meet Prior to and during construction, it is rec-
the shear strength requirements specified in ommended that a qualified professional
design plans. In this context, shear strength should prepare construction specifications for
is the ability of two layers to resist forces the GCL. In these specifications, procedures
moving them in opposite directions. Since for shipping and storing materials, as well as
hydrated bentonite clay has low shear performing acceptance testing on delivered
7B-18
Protecting Ground Water—Designing and Installing Liners
Figure 3
Four Variations of GCL Bonding Methods
7B-19
Protecting Ground Water—Designing and Installing Liners
materials, should be identified. The specifica- aged core makes deployment more difficult
tions should also address methods for sub- and can lead to other problems. For example,
grade preparation, joining panels, repairing rolls are sometimes handled by a fork lift
sections, and protective backfilling. with a stinger attached. The stinger is a long
tapered rod that fits inside the core. If the
core is crushed, the stinger can damage the
Shipment, Handling, and Site
liner during deployment.
Storage
GCLs are manufactured in widths of
approximately 2 to 5 m (7 to 17 ft) and
Acceptance and Conformance
lengths of 30 to 60 m (100 to 200 ft). Testing
Directly after manufacturing, GCLs are rolled Acceptance and conformance testing is rec-
around a core and covered with a thin plastic ommended either upon delivery of the GCL
protective covering. This waterproof covering rolls or at the manufacturer’s facility prior to
serves to protect the material from premature delivery. Conformance test samples are used
hydration. GCLs should be stored at the fac- to ensure that the GCL meets the project
tory with these protective coverings. Typical plans and specifications. GCLs should be
storage lengths range from a few days to 6 rewrapped and replaced in dry storage areas
months. To ensure protection of the plastic immediately after test samples are removed.
covering and the rolls themselves during Liner specifications should prescribe sampling
loading and unloading, it is recommended frequencies based on either total area or on
that qualified professionals specify the equip- number of rolls. Since variability in GCLs can
ment needed at the site to lift and deploy the exist between individual rolls, it is important
rolls properly. for acceptance and conformance testing to
account for this. Conformance testing can
To reduce the potential for accidental
include the following.
damage or for GCLs to absorb moisture at
the site, you should try to arrange for “just- Mass per unit area test. The purpose of
in-time-delivery” for GCLs transported from evaluating mass per unit area is to ensure an
the factory to the field. Even with “just-in- even distribution of bentonite throughout the
time-delivery,” it might be necessary to store GCL panel. Although mass per unit area
GCLs for short periods of time at the site. varies from manufacturer to manufacturer, a
Often the rolls can be delivered in trailers, typical minimum value for oven dry weight
which can then serve as temporary storage. is 3.7 kg/m2 (0.75 lb/ft2). Mass per unit area
To help protect the GCLs prior to deploy- should be tested using ASTM D-5993.14 This
ment, you should use wooden pallets to keep test measures the mass of bentonite per unit
the rolls off the ground, placing heavy, water- area of GCL. Sampling frequencies should be
proof tarps over the GCL rolls to protect determined using ASTM D- 4354.15
them from precipitation, and using sandbags
Free swell test. Free swell refers to the
to help keep the tarps in place.
ability of the clay to absorb liquid. Either
Manufacturer specifications should also ASTM D-5890 or GRI-GCL1, a test method
indicate how high rolls of GCLs can be developed by the Geosynthetic Research
stacked horizontally during storage. Over- Institute, can be used to evaluate the free
stacking can cause compression of the core swell of the material.16
around which the GCL is wrapped. A dam-
14
ASTM D-5993, Standard Test Method for Measuring Mass per Unit Area of Geosynthetic Clay Liners.
15
ASTM D-4354, Standard Practice for Sampling of Geosynthetics for Testing.
7B-20
16
ASTM D-5890, Test Method for Swell Index of Clay Mineral Components of Geosynthetic Clay Liners.
GRI-GCL1, Swell Measurement of the Clay Component of Geosynthetic Clay Liners.
Protecting Ground Water—Designing and Installing Liners
Direct shear test. Shear strength of the smooth-wheel roller and maintained in a
GCLs can be evaluated using ASTM D-5321.17 smooth condition prior to deployment.
The sampling frequency for this performance-
oriented test is often based on area, such as
Joining Panels
one test per 10,000 m2 (100,000 ft2).
GCLs are typically joined by overlapping
Hydraulic conductivity test. Either ASTM panels, without sewing or mechanically con-
D-5084 (modified) or GRI-GCL2 will mea- necting pieces together. To ensure proper
sure the ease with which liquids can move joints, you should specify minimum and
through the GCL.18 maximum overlap distances. Typical overlap
Other tests. Testing of any geotextiles or distances range from 150 to 300 mm (6 to 12
geomembranes should be made on the origi- in.). For some GCLs, such as needle punched
nal rolls of the geotextiles or geomembranes GCLs with nonwoven geotextiles, it might be
and before they are fabricated into the GCL necessary to place bentonite on the area of
product. Once these materials have been overlap. If this is necessary, you should take
made part of the GCL product, their proper- steps to prevent fugitive bentonite particles
ties can change as a result of any needling, from coming into contact with the leachate
stitching, or gluing. Additionally, any peel collection system, as they can cause physical
tests performed on needle punched or stitch clogging.
bonded GCLs should use the modified ASTM
D-413 with a recommended sampling fre- Repair of Sections Damaged During
quency of one test per 2,000 m2 (20,000 ft2).19
Liner Placement
During installation, GCLs might incur
Subgrade Preparation some damage to either the clay component or
Because the GCL layer is relatively thin, to any geotextiles or geomembranes. For
the first foot of soil underlying the GCL damage to geotextile or geomembrane com-
should have a hydraulic conductivity of 1 x ponents, repairs include patching using geot-
10-5 cm/sec or less. Proper subgrade prepara- extile or geomembrane materials. If the clay
tion is essential to prevent damage to the component is disturbed, a patch made from
GCL layer as it is installed. This includes the same GCL product should be used to per-
clearing away any roots or large particles that form any repairs.
could potentially puncture the GCL and its
geotextile or geomembrane components. The
Protective Backfilling
soil subgrade should be of the specified grad-
ing, moisture content, and density required As soon as possible after completion of
by the installer and approved by a construc- quality assurance and quality control activi-
tion quality assurance engineer for placement ties, you should cover GCLs with either a soil
of the GCL. Construction equipment deploy- layer or a geosynthetic layer to prevent
ing the rolls should not deform or rut the soil hydration. The soil layer can be a compacted
subgrade excessively. To help ensure this, the clay liner or a layer of coarse drainage materi-
soil subgrade should be smooth rolled with a al. The geosynthetic layer is typically a
17
ASTM D-5321, Standard Test Method for Determining the Coefficient of Soil and Geosynthetic or
Geosynthetic and Geosynthetic Friction by the Direct Shear Method.
18
ASTM D-5084, Standard Test Method for Measurement of Hydraulic Conductivity of Saturated Porous
Materials Using a Flexible Wall Permeameter.
GRI-GCL2, Permeability of Geosynthetic Clay Liners (GCLs).
19
ASTM D-413, Standard Test Methods for Rubber Property-Adhesion to Flexible Substrate. 7B-21
Protecting Ground Water—Designing and Installing Liners
7B-22
Protecting Ground Water—Designing and Installing Liners
ASTM D-5321 provides a test method for To minimize desiccation of the compacted
determining the friction coefficient of soil and clay layer, you should place the geomem-
geomembranes.20 When using bentonite- brane over the clay layer as soon as possible.
amended soils, it is important to account for Additional cover materials should also be
how the percentage of bentonite added and placed over the geomembrane. Exposed
the degree of saturation affect interface fric- geomembranes absorb heat, and high temper-
tion. To provide for stable slopes, it is impor- atures can dry out and crack an underlying
tant to control both the bentonite and compacted clay layer. Daily cyclic changes in
moisture contents. A textured geomembrane temperature can draw water from the clay
can increase the friction with the clay layer layer and cause this water to condense on the
and improve stability. underside of the geomembrane. This with-
drawal of water can lead to desiccation crack-
What issues should be consid- ing and potential interface stability concerns.
ered in the construction of a
composite liner?
To achieve good composite bonding, the
IV. Double Liners
geomembrane and the compacted clay layer (Primary and
should have good hydraulic contact. To
improve good contact, you should smooth- Secondary Lined
roll the surface of the compacted clay layer
using a smooth, steel-drummed roller and
Systems)
remove any stones. In addition, you should In a double-lined waste management unit,
place and backfill the geomembrane so as to there are two distinct liners—one primary
minimize wrinkles. (top) liner and one secondary (bottom) liner.
Each liner might consist of compacted clay, a
The placement of geomembranes onto a geomembrane, or a composite (consisting of a
compacted clay layer poses a challenge, geomembrane and a compacted clay layer or
because workers cannot drive heavy GCL). Above the primary liner, it is recom-
machines over the clay surface without mended that you construct a leachate collec-
potentially damaging the compacted clay tion and removal system to collect and convey
component. Even inappropriate footwear can liquids out of the waste management unit and
leave imprints in the clay layer. It might be to control the depth of liquids above the pri-
possible to drive some types of low ground mary liner. In addition, you should place a
pressure equipment or small, 4-wheel, all ter- leak detection, collection, and removal system
rain vehicles over the clay surface, but drivers between the primary and secondary liner.
should take extreme care to avoid move- This leak detection system will provide leak
ments, such as sudden starts, stops, and warning, as well as collect and remove any
turns, that could damage the surface. To liquid or leachate that has escaped the prima-
avoid damaging the clay layer, it is recom- ry liner. See section V below for information
mended that you unroll geomembranes by on the design of leachate collection and
lifting the rolls onto jacks at a cell side and removal systems and leak detection, collec-
pulling down on the geomembrane manually. tion, and removal systems.
Also, the entire roll with its core can be
unrolled onto the cell (with auxiliary support
using ropes on embankments).
20
ASTM D-5321, Standard Test Method for Determining the Coefficient of Soil and Geosynthetic or
Geosynthetic and Geosynthetic Friction by the Direct Shear Method.
7B-23
Protecting Ground Water—Designing and Installing Liners
What are the thickness and tion systems serve this purpose. You should
consult with the state agency too determine if
hydraulic conductivity recom- such systems are required. The primary func-
mendations for double liners? tion of a leachate collection and removal sys-
tem is to collect and convey leachate out of a
Each component of the double liner
unit and to control the depth of leachate
should follow the recommendations for
above a liner. The primary function of a leak
geomembranes, compacted clay liners, or
detection system is to detect leachate that has
composite liners described earlier.
escaped the primary liner. A leak detection
Geomembrane liners should have a minimum
system refers to drainage material located
thickness of 30 mil, except for HDPE liners,
below the primary liner and above a sec-
which should have a minimum thickness of
ondary liner (if there is one); it acts as a sec-
60 mil. Similarly, compacted clay liners
ondary leachate collection and removal
should be at least 2 feet thick and are typical-
system. After the leachate has been removed
ly 2 to 5 feet thick. For compacted clay liners
and collected, a leachate treatment system
and geosynthetic clay liners, use materials
might be incorporated to process the leachate
with maximum hydraulic conductivities of 1
and remove harmful constituents.
x 10-7 cm/sec (4 x 10-8 in/sec) and 5 x 10-9
cm/sec (2 x 10-9 in/sec), respectively. The information in this section on leachate
collection and leak detection systems is
What issues should be consid- applicable if the unit is a landfill or a waste
ered in the design and construc- pile. Surface impoundments, which manage
liquid wastes, usually will not have leachate
tion of a double liner? collection and removal systems unless they
Like composite liners, double liners are will be closed in-place as landfills; they might
composed of a combination of single liners. have leak detection systems to detect liquid
When planning to design and construct a wastes that have escaped the primary liner.
double liner, you should consult the sections Leachate collection or leak detection systems
on composite and single liners first. In addi- generally are not used with land application.
tion, you should consult the sections on
leachate collection and removal systems and
leak detection systems. A. Leachate Collection
System
A typical leachate collection system
V. Leachate includes a drainage layer, collection pipes, a
removal system, and a protective filter layer.
Collection and Leachate collection systems are designed to
collect leachate for treatment or alternate dis-
Leak Detection posal and to reduce the buildup of leachate
Systems above the liner system. Figure 4 shows a
cross section of a typical leachate collection
One of the most important functions of a system showing access to pipes for cleaning.
waste management unit is controlling
leachate and preventing contamination of the
underlying ground water. Both leachate col-
lection and removal systems and leak detec-
7B-24
Protecting Ground Water—Designing and Installing Liners
Figure 4
Typical Leachate Collection System
What are the recommendations potential leachate generation, you should use
water balance equations or models. The most
for leachate collection and commonly used method to estimate leachate
removal systems? generation is EPA’s Hydrogeologic Evaluation
of Landfill Performance (HELP) model.21 This
You should design a leachate collection and
model uses weather, soil, and waste manage-
removal system to maintain less than 30 cm
ment unit design data to determine leachate
(12 in.) depth of leachate, or “head,” above
generation rates.
the liner if granular soil or a geosynthetic
material is used. The reason for maintaining What issues should be consid-
this level is to prevent excessive leachate from
building up above the liner, which could ered in the design of a leachate
jeopardize the liner’s performance. This collection and removal system?
should be the underlying factor guiding the
design, construction, and operation of the You should design a leachate collection
leachate collection and removal system. and removal system to include the following
elements: a low-permeability base, a high-
You should design a leachate collection permeability drainage layer, perforated
and removal system capable of controlling the leachate collection pipes, a protective filter
estimated volume of leachate. To determine layer, and a leachate removal system. During
21
Available on the CD-ROM version of the Guide, as well as from the U.S. Army Corps of Engineers Web
site <www.wes.army.mil/el/elmodels/index.html#landfill>
7B-25
Protecting Ground Water—Designing and Installing Liners
design, you should consider the stability of when used in conjunction with a filter layer
the base, the transmissivity of the drainage or geotextile to prevent clogging. Geonets
layers, and the strength of the collection consist of integrally connected parallel sets of
pipes. It is also prudent to consider methods plastic ribs overlying similar sets at various
to minimize physical, biological, and chemi- angles. Geonets are often used on the side
cal clogging within the system. walls of waste management units because of
their ease of installation. Figure 5 depicts a
typical geonet material configuration.
Low-Permeability Base
A leachate collection system is placed over The most critical factor involved with using
the unit’s liner system. The bottom liner geonets in a high-permeability drainage layer
should have a minimum slope of 2 percent to is the material’s ability to transmit fluids
allow the leachate collection system to gravity under load. The flow rate of a geonet can be
flow to a collection sump. This grade is nec- evaluated by ASTM D-4716.22 Several addi-
essary to provide proper leachate drainage tional measures for determining the transmis-
throughout the operation, closure, and post- sivity of geonets are discussed in the Solid
closure of the unit. Estimates of foundation Waste Disposal Facility Criteria: Technical
soil settlement should include this 2 percent Manual (U.S. EPA, 1993b).
grade as a post-settlement design.
Perforated Leachate Collection Pipes
High-Permeability Drainage Layer Whenever the leachate collection system is
A high-permeability drainage layer consists a natural soil, a perforated piping system
of drainage materials placed directly over the should be located within it to rapidly trans-
low-permeability base, at the same minimum mit the leachate to a sump and removal sys-
2 percent grade. The drainage materials can tem. Through the piping system, leachate
be either granular soil or geosynthetic materi- flows gravitationally to a low point where the
als. For soil drainage materials, a maximum of sump and removal system is located. The
12 inches of materials with a hydraulic con- design of perforated leachate collection pipes,
ductivity of at least 1 x 10-2 cm/sec (4 x 10-3 therefore, should consider necessary flow
in/sec) is recommended. For this reason, sand rates, pipe sizing, and pipe structural
and gravel are the most common soil materi- strength. After estimating the amount of
als used. If the drainage layer is going to leachate using the HELP model or a similar
incorporate sand or gravel, it should be water balance model, it is possible to calcu-
demonstrated that the layer will have suffi- late the appropriate pipe diameter and spac-
cient bearing capacity to withstand the waste ing. For the leachate collection system
load of the full unit. Additionally, if the waste design, you should select piping material that
management unit is designed on grades of 15 can withstand the anticipated weight of the
percent or higher, it should be demonstrated waste, construction and operating equipment
that the soil drainage materials will be stable stresses, and foundation settling. Most
on the steepest slope in the design. leachate collection pipes used in modern
waste management units are constructed of
Geosynthetic drainage materials such as HDPE. HDPE pipes provide great structural
geonets can be used in addition to, or in place strength, while allowing significant chemical
of, soil materials. Geonets promote rapid resistance to the many constituents found in
transmission of liquids and are most effective leachate. PVC pipes are also used in waste
22
ASTM D-4716, Standard Test Method for Constant Head Hydraulic Transmissivity (In-Plane Flow) of
Geotextiles and Geotextile Related Products.
7B-26
Protecting Ground Water—Designing and Installing Liners
7B-27
Protecting Ground Water—Designing and Installing Liners
installing a level control, backup pump, and leachate collection and removal systems. To
warning system to ensure proper sump oper- minimize chemical and biological clogging for
ation. Also consider using a backup pump as granular drainage material, the best procedure
an alternate to the primary pump and to is to keep the interstices of the granular
assist it during high flow periods. A warning drainage material as open as possible.
system should be used to indicate pump mal-
The leachate collection pipes are also sus-
function.
ceptible to similar clogging. To prevent this,
Standpipes, vertical pipes extending you should incorporate measures into the
through the waste and cover system, offer design to allow for routine pipe cleaning,
one method of removing leachate from a using either mechanical or hydraulic meth-
sump without puncturing the liner. ods. The cleaning components can include
Alternatively, you can remove leachate from a pipes with a 15 cm (6 in) minimum diameter
sump using pipes that are designed to pene- to facilitate cleaning; access located at major
trate the liner. When installing pipe penetra- pipe intersections or bends to allow for
tions through the liner, you should proceed inspections and cleaning; and valves, ports,
with extreme caution to prevent any liner or other appurtenances to introduce biocides
damage that could result in uncontained and cleaning solutions. Also, you should
leachate. Both of these options rely on gravity check that the design does not include wrap-
to direct leachate to a leachate collection ping perforated leachate collection pipes
pond or to an external pumping station. directly with geotextile filters. If the geotex-
tile becomes clogged, it can block flow into
the pipe.
Minimizing Clogging
Leachate collection and removal systems
are susceptible to physical, biological, and B. Leak Detection System
chemical clogging. Physical clogging can The leak detection system (LDS) is also
occur through the migration of finer-grained known as the secondary leachate collection
materials into coarser-grained materials, thus and removal system. It uses the same
reducing the hydraulic conductivity of the drainage and collection components as the
coarser-grained material. Biological clogging primary leachate collection and removal sys-
can occur through bacterial growth in the tem and identifies, collects, and removes any
system due to the organic and nutrient mate- leakage from the primary system. The LDS
rials in leachate. Chemical clogging can be should be located directly below the primary
caused by chemical precipitates, such as cal- liner and above the secondary liner.
cium carbonates, causing blockage or cemen-
tation of granular drainage material. What are the recommendations
Proper selection of drainage and filter mate- for leak detection systems?
rials is essential to minimize clogging in the
high-permeability drainage layer. Soil and geo- The LDS should be designed to assess the
textile filters can be used to minimize physical adequacy of the primary liner against
clogging of both granular drainage material leachate leakage; it should cover both the
and leachate collection pipes. When placed bottom and side walls of a waste manage-
above granular drainage material, these filters ment unit. The LDS should be designed to
can also double as an operations layer to pre- collect leakage through the primary layer and
vent sharp waste from damaging the liner or transport it to a sump within 24 hours.
7B-28
Protecting Ground Water—Designing and Installing Liners
The LDS should allow for monitoring and treatment techniques, the carbon absorption
collection of leachate escaping the primary process and reverse osmosis are the two most
liner system. You should monitor the LDS on common methods. Carbon absorption uses
a regular basis. If the volume of leachate carbon to remove dissolved organics from
detected by the LDS appears to be increasing leachate and is very expensive. Reverse osmo-
or is significant, you should consider a closer sis involves feeding leachate into a tubular
examination to determine possible remedia- chamber whose wall acts as a synthetic mem-
tion measures. A good rule of thumb is that if brane, allowing water molecules to pass
the LDS indicates a seepage level greater than through but not pollutant molecules, thereby
20 gallons per acre per day, the system might separating clean water from waste constituents.
need closer monitoring or remediation.
What are the recommendations
for leachate treatment systems?
C. Leachate Treatment
System You should review all applicable federal
and state regulations and discharge standards
Once the leachate has been removed from
to determine which treatment system will
the unit and collected, you should consider
ensure long-term compliance and flexibility
taking measures to characterize the leachate
for the unit. Site-specific factors will also play
in order to ensure proper management. There
a fundamental role in determining the proper
are several methods of disposal for leachate,
leachate treatment system. For some facilities,
and the treatment strategy will vary according
onsite storage and treatment might not be an
to the disposal method chosen. Leachate dis-
option due to space constraints. For other
posal options include discharging to or
facilities, having a nearby, publicly owned
pumping and hauling to a publicly owned
treatment works might make pretreatment
treatment works or to an onsite treatment
and discharge to the treatment works an
system; treating and discharging to the envi-
attractive alternative.
ronment; land application; and natural or
mechanical evaporation.
When discharging to or pumping and
hauling leachate to a publicly owned treat-
VI. Construction
ment works, a typical treatment strategy
includes pretreatment. Pretreatment could
Quality
involve equalization, aeration, sedimentation, Assurance and
pH adjustment, or metals removal.23 If the
plan for leachate disposal does not involve a Quality Control
remote treatment facility, pretreatment alone Even the best unit design will not translate
usually is not sufficient. into a structure that is protective of human
health and the environment, if the unit is not
There are two categories of leachate treat-
properly constructed. Manufacturing quality
ment, biological and physical/chemical. The
assurance and manufacturing quality control
most common method of biological treatment
(MQA and MQC) are also important issues
is activated sludge. Activated sludge is a “sus-
for the overall project; however, they are dis-
pended-growth process that uses aerobic
cussed only briefly here since they are pri-
microorganisms to biodegrade organic contam-
marily the responsibility of a manufacturer.
inants in leachate.”24 Among physical/chemical
Nonetheless, it is best to select a manufactur-
23
Arts, Tom. “Alternative Approaches For Leachate Treatment.” World Wastes.
24
Ibid.
7B-29
Protecting Ground Water—Designing and Installing Liners
er who incorporates appropriate quality uct meets project specifications. CQA testing,
assurance and quality control (QA and QC) often referred to as acceptance inspection,
mechanisms as part of the manufacturing provides a measure of the final product quali-
process. The remainder of this section pro- ty and its conformance with project plans
vides a general description of the compo- and specifications. Performing acceptance
nents of a construction quality assurance and inspections routinely, as portions of the pro-
construction quality control (CQA and CQC) ject become complete, allows early detection
program for a project. CQA and CQC are and correction of deficiencies, before they
critical factors for waste management units. become large and costly.
They are not interchangeable, and the dis-
On routine construction projects, CQA is
tinction between them should be kept in
normally the concern of the facility manager
mind when preparing plans. CQA is third
and is usually performed by an independent,
party verification of quality, while CQC con-
third-party testing firm. The independence of
sists of in-process measures taken by the con-
the testing firm is important, particularly
tractor or installer to maintain quality. You
when a facility manager has the capacity to
should establish clear protocols for identify-
perform the CQA activities. Although the
ing and addressing issues of concern
throughout every stage of construction.
MQC, MQA, CQC, and CQA
What is manufacturing quality Manufacturing quality control
assurance? (MQC) is measures taken by the manu-
facturer to ensure compliance with the
The desired characteristics of liner materi-
material and workmanship specifications
als should be specified in the unit’s contract
of the facility manager.
with the manufacturer. The manufacturer
should be responsible for certifying that mate- Manufacturer quality assurance
rials delivered conform to those specifications. (MQA) is measures taken by facility per-
MQC implemented to ensure such confor- sonnel, or by an impartial party brought
mance might take the form of process quality in expressly for the purpose, to deter-
control or computer-aided quality control. If mine if the manufacturer is in compli-
requested, the manufacturer should provide ance with the specifications of the facility
information on the MQC measures used, manager.
allow unit personnel or engineers to visit the Construction quality control (CQC)
manufacturing facility, and provide liner sam- is measures taken by the installer or con-
ples for testing. It is good practice for the tractor to ensure compliance with the
manufacturer to have a dedicated individual installation specifications of the facility
in charge of MQC who would work with unit manager.
personnel in these areas.
Construction quality assurance
What is construction quality (CQA) is measures taken by facility per-
assurance? sonnel, or by an impartial party brought
in expressly for the purpose, to deter-
CQA is a verification tool employed by the mine if the installer or contractor is in
facility manager or regulatory agency, consist- compliance with the installation specifi-
ing of a planned series of observations and cations of the facility manager.
tests designed to ensure that the final prod-
7B-30
Protecting Ground Water—Designing and Installing Liners
7B-31
Protecting Ground Water—Designing and Installing Liners
7B-32
Protecting Ground Water—Designing and Installing Liners
erally the same as the responsibilities for the testing frequencies. When varying testing fre-
construction of a compacted clay liner, with quency, you should establish well-defined
the addition of certain activities including procedures for modifying testing frequency. It
observations of the liner storage area and lin- is also important to evaluate testing methods,
ers in storage, and handling of the liner as the understand the differences among testing
panels are positioned in the cell. methods, and request those methods appro-
Geomembrane CQA staff should also observe priate for the material and seaming method
seam preparation, seam overlap, and materi- be used. Nondestructive testing methods are
als underlying the liner. preferrable when possible to help reduce the
number of holes cut into the geomembrane.
How can implementation of QA
Geomembrane CQA staff also should docu-
and QC be ensured for a ment the results of their observations and pre-
geomembrane liner? pare reports indicating the types of sampling
conducted and sampling results, locations of
Prior to installation, you should work with destructive samples, locations of patches,
the geomembrane manufacturer to ensure the locations of seams constructed, and any prob-
labeling system for the geomembrane rolls is lems encountered. In some cases, they might
clear and logical, allowing easy tracking of the need to prepare drawings of the liner installa-
placement of the rolls within the unit. It is tion. Record drawing preparation is frequently
important to examine the subgrade surface assigned to the contractor, to a representative
with both the subgrade contractor and the liner of the facility manager, or to the engineer. You
installer to ensure it conforms to specifications. should request complete reports from any
Once liner installation is underway, CQA CQA staff and the installers. To ensure com-
staff might be responsible for observations of plete CQA documentation, it is important to
destructive testing conducted on scrap test maintain daily CQA reports and prepare
welds prior to seaming. Geomembrane CQA weekly summaries.
staff might also be responsible for sending
destructive seam sampling to an independent
testing laboratory and reviewing the results for C. Geosynthetic Clay Liner
conformance to specifications. Other observa- Quality Assurance and
tions for which the CQA staff are typically Quality Control
responsible include observations of all seams Construction quality assurance for geosyn-
and panels for defects due to manufacturing thetic clay liners is still a developing area; the
and handling, and placement and observations GCL industry is continuing to establish stan-
of all pipe penetrations through a liner. dardized quality assurance and quality con-
Test methods, test parameters, and testing trol procedures. The CQA recommendation
frequencies should be specified in the CQA for GCLs can serve as a starting point. You
plan to provide context for any data collect- should check with the GCL manufacturer and
ed. It is prudent to allow for testing frequen- installer for more specific information.
cy to change, based on the performance of
the geomembrane installer. If test results indi-
cate poor workmanship, you should increase
testing. If test results indicate high quality
installation work, you can consider reducing
7B-33
Protecting Ground Water—Designing and Installing Liners
7B-34
Protecting Ground Water—Designing and Installing Liners
7B-35
Protecting Ground Water—Designing and Installing Liners
■ Review the recommended location considerations and operating practices for the unit.
■ Select appropriate liner type—single, composite, or double liner—or in-situ soils, based on risk
characterization.
■ Evaluate liner material properties and select appropriate clay, geosynthetic, or combination of mate-
rials; consider interactions of liner and soil material with waste.
■ Develop a construction quality assurance (CQA) plan defining staff roles and responsibilities and
specifying test methods, storage procedures, and construction protocols.
■ Ensure a stable in-situ soil foundation, for nonengineered liners.
■ Prepare and inspect subgrade for engineered liners.
■ Work with manufacturer to ensure protective shipping, handling, and storage of all materials.
■ Construct a test pad for compacted clay liners.
■ Test compacted clay liner material before and during construction.
■ Preprocess clay material to ensure proper water content, remove oversized particles, and add soil
amendments, as applicable.
■ Use proper lift thickness and number of equipment passes to achieve adequate compaction.
■ Protect clay material from drying and cracking.
■ Develop test strips and trial seams to evaluate geomembrane seaming method.
■ Verify integrity of factory and field seams for geomembrane materials before and during construction.
■ Backfill with soil or geosynthetics to protect geomembranes and geosynthetic clay liners during
construction.
■ Place backfill materials carefully to avoid damaging the underlying materials.
■ Install geosynthetic clay liner with proper overlap.
■ Patch any damage that occurs during geomembrane or geosynthetic clay liner installation.
■ Design leachate collection and removal system to allow adequate flow and to minimize clogging;
include leachate treatment and leak detection systems, as appropriate.
■ Document all CQA activities, including meetings, inspections, and repairs.
7B-36
Protecting Ground Water—Designing and Installing Liners
Resources
ASTM D-413. 1993. Standard Test Methods for Rubber Property-Adhesion to Flexible Substrate.
ASTM D-422. 1990. Standard Test Method for Particle-Size Analysis of Soils.
ASTM D-638. 1991. Standard Test Method for Tensile Properties of Plastics.
ASTM D-698. 1991. Test Method for Laboratory Compaction Characteristics of Soil Using Standard
Effort (12,400 ft-lbf/ft3 (600 kN-m/m3)).
ASTM D-882. 1991. Standard Test Methods for Tensile Properties of Thin Plastic Sheeting.
ASTM D-1004. 1990. Standard Test Method for Initial Tear Resistance of Plastic Film and Sheeting.
ASTM D-1557. 1991. Test Method for Laboratory Compaction Characteristics of Soil Using Modified
Effort (56,000 ft-lbf/ft3 (2,700 kN-m/m3)).
ASTM D-4318. 1993. Standard Test Method for Liquid Limit, Plastic Limit, and Plasticity Index of
Soils.
ASTM D-4354. 1989. Standard Practice for Sampling of Geosynthetics for Testing.
ASTM D-4716. 1987. Standard Test Method for Constant Head Hydraulic Transmissivity (In-Plane
Flow) of Geotextiles and Geotextile Related Products.
ASTM D-5084. 1990. Standard Test Method for Measurement of Hydraulic Conductivity of Saturated
Porous Materials Using a Flexible Wall Permeameter.
ASTM D-5199. 1991. Standard Test Method for Measuring Nominal Thickness of Geotextiles and
Geomembranes.
ASTM D-5261. 1992. Standard Test Method for Measuring Mass per Unit Area of Geotextiles.
ASTM D-5321. 1992. Standard Test Method for Determining the Coefficient of Soil and Geosynthetic
or Geosynthetic and Geosynthetic Friction by the Direct Shear Method.
7B-37
Protecting Ground Water—Designing and Installing Liners
Resources (cont.)
Bagchi, A. 1994. Design, Construction, and Monitoring of Landfills.
Berg, R., and L. Well. 1996. A Position Paper on: The Use of Geosynthetic Barriers in Nonhazardous
Industrial Waste Containment.
Borrelli, J. and D. Brosz. 1986. Effects of Soil Salinity on Crop Yields. <hermes.ecn.purdue.edu/cgi/con-
vwqtest?/b-803.wy.ascii>
Boulding, J.R. 1995. Practical Handbook of Soil, Vadose Zone, and Ground Water Contamination:
Assessment, Prevention and Remediation. Lewis Publishers.
Brandt, R.C. and K.S. Martin. 1996. The Food Processing Residual Management Manual. September.
Daniel, D.E., and R.M. Koerner. 1991. Landfill Liners from Top to Bottom. Civil Engineering. December.
Daniel, D.E., and R.M. Koerner. 1993. Technical Guidance Document: Quality Assurance and Quality
Control for Waste Containment Facilities. Prepared for U.S. EPA. EPA600-R-93-182.
Daniel, D.E., and R.M. Koerner. 1995. Waste Containment Facilities: Guidance for Construction, Quality
Assurance and Quality Control of Liner and Cover Systems.
Evanylo, G.K. and W. L. Daniels. 1996. The Value and Suitability of Papermill Sludge and Sludge
Compost as a Soil Amendment and Soilless Media Substitute. Final Report. The Virginia Department of
Agriculture and Consumer Services, P.O. Box 1163, Room 402, Richmond, VA. April.
Federal Test Method Standard 101C. 1980. Puncture Resistance and Elongation Test (1/8 Inch Radius
Probe Method).
Fipps, G. 1995. Managing Irrigation Water Salinity in the Lower Rio Grande Valley. <hermes.ecn.pur-
due.edu/sgml/water_quality/texas/b1667.ascii>
Geosynthetic Research Institute. 1993. GRI-GCL1, Swell Measurement of the Clay Component of GCLs.
Geosynthetic Research Institute. 1993. GRI-GCL2, Permeability of Geosynthetic Clay Liners (GCLs).
7B-38
Protecting Ground Water—Designing and Installing Liners
Resources (cont.)
Idaho Department of Health and Welfare. 1988. Guidelines for Land Application of Municipal and
Industrial Wastewater. March.
McGrath, L., and P. Creamer. 1995. Geosynthetic Clay Liner Applications in Waste Disposal
Facilities.
McGrath, L., and P. Creamer. 1995. Geosynthetic Clay Liner Applications. Waste Age. May.
Michigan Department of Natural Resources, Waste Characterization Unit. 1991. Guidance for Land
Application of Wastewater Sludge in Michigan. March.
Michigan Department of Natural Resources, Waste Characterization Unit. 1991. Guide to Preparing
a Residuals Management Plan. March.
Minnesota Pollution Control Agency. 1993. Land Treatment of Landfill Leachate. February.
Northeast Regional Agricultural Engineering Cooperative Extension. 1996. Animal Agriculture and
the Environment: Nutrients, Pathogens, and Community Relations. NRAES-96. December.
North Carolina Cooperative Extension Service. 1994. Soil facts: Careful Soil Sampling - The Key to
Reliable Soil Test Information. AG-439-30.
Sharma, H., and S. Lewis. 1994. Waste Containment Systems, Waste Stabilization, and Landfills:
Design and Evaluation.
Smith, M.E., S. Purdy, and M. Hlinko. 1996. Some Do’s and Don’ts of Construction Quality
Assurance. Geotechnical Fabrics Report. January/February.
7B-39
Protecting Ground Water—Designing and Installing Liners
Resources (cont.)
Spellman, F. R. 1997. Wastewater Biosolids to Compost.
Texas Water Commission. 1983. Industrial Solid Waste Management Technical Guideline No. 5: Land
Application. December.
Tsinger, L. 1996. Chemical Compatibility Testing: The State of Practice. Geotechnical Fabrics Report.
October/November.
University of Nebraska Cooperative Extension Institute of Agriculture and Natural Resources. 1991.
Guidelines for Soil Sampling. G91-1000-A. February.
U.S. EPA. 2001. Technical Resource Document: Assessment and recommendations for Improving the
Performance of Waste Containment Systems. Draft.
U.S. EPA. 1996b. Report of 1995 Workshop on Geosynthetic Clay Liners. EPA600-R-96-149. June.
U.S. EPA. 1995a. A Guide to the Biosolids Risk Assessments for the EPA Part 503 Rule. EPA832-B-93-
005. September.
U.S. EPA. 1995b. Decision Maker’s Guide to Solid Waste Management. Volume II. EPA530-R-95-023.
U.S. EPA. 1995c. Laboratory Methods for Soil and Foliar Analysis in Long-Term Environmental
Monitoring Programs. EPA600-R-95-077.
U.S. EPA. 1995d. Process Design Manual: Land Application of Sewage Sludge and Domestic Septage.
EPA625-R-95-001. September.
U.S. EPA. 1995e. Process Design Manual: Surface Disposal of Sewage Sludge and Domestic Septage.
EPA625-R-95-002. September.
U.S. EPA. 1994a. A Plain English Guide to the EPA Part 503 Biosolids Rule. EPA832-R-93-003.
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U.S. EPA. 1994b. Biosolids Recycling: Beneficial Technology for a Better Environment. EPA832-R-94-
009. June.
U.S. EPA. 1994c. Guide to Septage Treatment and Disposal. EPA625-R-94-002. September.
7B-40
Protecting Ground Water—Designing and Installing Liners
Resources (cont.)
U.S. EPA. 1994d. Land Application of Sewage Sludge: A Guide for Land Appliers on the Requirements
of the Federal Standards for the Use or Disposal of Sewage Sludge, 40 CFR Part 503. EPA831-B-93-
002b. December.
U.S. EPA. 1994e. Seminar Publication: Design, Operation, and Closure of Municipal Solid Waste
Landfills. EPA625-R-94-008.
U.S. EPA. 1993a. Domestic Septage Regulatory Guidance: A Guide to the EPA 503 Rule. EPA832-B-92-
005. September.
U.S. EPA. 1993b. Solid Waste Disposal Facility Criteria: Technical Manual. EPA530-R-93-017.
U.S. EPA. 1993c. Technical Guidance Document: Quality Assurance and Quality Control for Waste
Containment Facilities. EPA600-R-93-182.
U.S. EPA. 1992. Control of Pathogens and Vector Attraction in Sewage Sludge. EPA625-R-92-013.
December.
U.S. EPA. 1991a. Seminar Publication: Design and Construction of RCRA/CERCLA Final Covers.
EPA625-4-91-025.
U.S. EPA. 1991b. Seminar Publication: Site Characterization for Subsurface Remediation. EPA625-4-91-
026.
U.S. EPA. 1991c. Technical Guidance Document: Inspection Techniques for the Fabrication of
Geomembrane Field Seams. EPA530-SW-91-051.
U.S. EPA. 1990. State Sludge Management Program Guidance Manual. October.
U.S. EPA. 1989a. Seminar Publication: Requirements for Hazardous Waste Landfill Design,
Construction, and Closure. EPA625-4-89-022.
U.S. EPA. 1989b. Seminar Publication: Corrective Action: Technologies and Applications. EPA625-4-89-
020.
U.S. EPA. 1988. Lining of Waste Containment and Other Impoundment Facilities. EPA600-2-88-052.
U.S. EPA. 1987. Geosynthetic Guidance for Hazardous Waste Landfill Cells and Surface Impoundments.
EPA600-2-87-097.
7B-41
Protecting Ground Water—Designing and Installing Liners
Resources (cont.)
U.S. EPA. 1986a. Project Summary: Avoiding Failure of Leachate Collection and Cap Drainage Systems.
EPA600-S2-86-058.
U.S. EPA. 1986b. Test Methods for Evaluating Solid Waste: Physical/Chemical Methods. EPASW-846.
U.S. EPA. 1983. Process Design Manual for Land Application of Municipal Sludge. EPA625-1-83-016.
October.
U.S. EPA, U.S. Army Corps of Engineers, U.S. Department of Interior, and U.S. Department of
Agriculture. 1981. Process Design Manual for Land Treatment of Municipal Wastewater. EPA625-1-81-
013. October.
U.S. EPA. 1979. Methods for Chemical Analysis of Water and Wastes. EPA600-4-79-020.
Viessman Jr., W. and M.J. Hammer. 1985. Water Supply and Pollution Control. 4th ed.
Washington State Department of Ecology. 1993. Guidelines for Preparation of Engineering Reports for
Industrial Wastewater Land Application Systems. Publication #93-36. May.
Webber, M.D. and S.S. Sing. 1995. Contamination of Agricultural Soils. In Action, D.F. and L.J.
Gregorich, eds. The Health of Our Soils.
Wisconsin Department of Natural Resources. 1996. Chapter NR 518: Landspreading of Solid Waste. April.
7B-42
Protecting Ground Water—Designing and Installing Liners
Appendix
Geosynthetic Materials25 application areas, however, they function
almost exclusively as reinforcement materials.
Geotextiles
Geotextiles form one of the two largest Geonets
group of geosynthetics. Their rise in growth Geonets, called geospacers by some, con-
during the past fifteen years has been nothing stitute another specialized segment within the
short of awesome. They are indeed textiles in geosynthetic area. They are usually formed by
the traditional sense, but consist of synthetic a continuous extrusion of parallel sets of
fibers rather than natural ones such as cotton, polymeric ribs at acute angles to one another.
wool, or silk. Thus biodegradation is not a When the ribs are opened, relatively large
problem. These synthetic fibers are made into apertures are formed into a netlike configura-
a flexible, porous fabric by standard weaving tion. Their design function is completely
machinery or are matted together in a ran- within the drainage area where they have
dom, or nonwoven, manner. Some are also been used to convey fluids of all types.
knit. The major point is that they are porous
to water flow across their manufactured plane Geomembranes
and also within their plane, but to a widely
varying degree. There are at least 80 specific Geomembranes represent the other largest
application areas for geotextiles that have been group of geosynthetics and in dollar volume
developed; however, the fabric always per- their sales are probably larger than that of
forms at least one of five discrete functions: geotextiles. Their growth has been stimulated
by governmental regulations originally enact-
1. Separation ed in 1982. The materials themselves are
2. Reinforcement “impervious” thin sheets of rubber or plastic
material used primarily for linings and covers
3. Filtration of liquid- or solid-storage facilities. Thus the
4. Drainage primary function is always as a liquid or
vapor barrier. The range of applications, how-
5. Moisture barrier (when impregnated) ever, is very great, and at least 30 individual
applications in civil engineering have been
Geogrids developed.
Geogrids represent a rapidly growing seg-
ment within the geosynthetics area. Rather Geosynthetic Clay Liners
than being a woven, nonwoven or knit textile Geosynthetic clay liners (or GCLs) are the
(or even a textile-like) fabric, geogrids are newest subset within geosynthetic materials.
plastics formed into a very open, gridlike They are rolls of factory fabricated thin layers
configuration (i.e., they have large apertures). of bentonite clay sandwiched between two
Geogrids are either stretched in one or two geotextiles or bonded to a geomembrane.
directions for improved physical properties or Structural integrity is maintained by needle
made on weaving machinery by unique punching, stitching or physical bonding.
methods. By themselves, there are at least 25 They are seeing use as a composite compo-
25
Created by Geosynthetic Research Institute. Accessed from the Internet on October 16, 2001 at
<www.drexel.edu/gri/gmat.html>.
7B-43
Protecting Ground Water—Designing and Installing Liners
7B-44
Part IV
Protecting Ground Water
Chapter 7: Section C
Designing A Land Application Program
Contents
I. Identifying Waste Constituents for Land Application..............................................................................7C-2
IV. Studying the Interaction of Plants and Microbes with Waste ................................................................7C-14
A. Greenhouse and Field Studies ............................................................................................................7C-15
B. Assessing Plant and Microbial Uptake Rates ........................................................................................7C-16
C. Effects of Waste on Plant and Microbe Growth....................................................................................7C-17
D. Grazing and Harvesting Restrictions....................................................................................................7C-18
VIII.Monitoring ..........................................................................................................................................7C-21
Resources ....................................................................................................................................................7C-24
Tables:
Table 1: Summary of Important Waste Parameters ....................................................................................7C-4
Table 2: Salinity Tolerance of Selected Crops ..........................................................................................7C-10
Table 3: EC and SAR Levels Indicative of Saline, Sodic, and Saline-Sodic Soils ......................................7C-11
Figures:
Figure 1: A Recommended Framework for Evaluating Land Application ..................................................7C-3
Figure 2: The Nitrogen Cycle ....................................................................................................................7C-7
Protecting Ground Water—Designing A Land Application Program
L
Some of the benefits of land application
and application can be a beneficial
include:
and practical method for treating and
disposing of some wastes. Because • Biodegradation of waste. If a waste
land application does not rely on lin- stream contains sufficient organic
ers to contain waste, however, there material, plants and microorganisms
are some associated risks. With proper planning can significantly biodegrade the
and design, a land application program can waste, assimilating its organic compo-
meet waste management and land preservation nents into the soil. After allowing suf-
goals, and avoid negative impacts such as nox- ficient time for assimilation of the
ious odors, long-term damage to soil, and waste, more waste can be applied to a
releases of contaminants to ground water, sur- given site without significantly
face water, or the air. This chapter describes and increasing the total volume of waste at
recommends a framework for addressing a vari- the site. This is in contrast to landfills
ety of waste parameters, in addition to the con- and waste piles, in which waste accu-
stituents outlined in Chapter 7, Section mulates continually and generally
A—Assessing Risk,1 and other factors such as does not biodegrade quickly enough
soil properties and plant and microbial nutrient to reduce its volume significantly.
use2 that can affect the ability of the land to
• Inclusion of liquids. Land applica-
safely assimilate directly applied waste.
tion units can accept bulk, non-con-
Successful land application programs address
tainerized liquid waste. The water
the interactions among all these factors.
1
The constituents incorporated in IWEM, including the heavy metals and synthetic organic chemicals,
typically have little or no agricultural value and can threaten human health and the environment even
in small quantities. The term “waste parameters” as used in this section refers to some additional con-
stituents such as nitrogen and biodegradable organic matter and other site-specific properties such as
pH, that can have considerable agricultural significance and that can significantly impact human health
and the environment.
2
40 CFR Part 503 specifies requirements for land application of sludge from municipal sewage treatment
plants. The Part 503 regulations apply to sewage sludge (now generally referred to as “biosolids”) or
mixtures of sewage sludge and industrial process wastes, not to industrial wastes alone. Some of the
specifications in Part 503, for example those concerning pathogens, might be helpful in evaluating land
application of industrial wastes. For mixtures of sewage sludge and industrial waste, the ground-water
and air risk assessments and the framework laid out in the Guide can help address constituents that are
7C-1
not covered under the Part 503 regulations.
Protecting Ground Water—Designing A Land Application Program
content of some liquid wastes make covered by any permits, MOUs, or other agree-
them desirable at land application ments concerning land application. The Guide
sites in arid climates. When managing does not supersede or modify conditions estab-
liquid waste, land application can lished in regulatory or other binding mecha-
reduce the need for expensive dewa- nisms, such as MOUs or agreements.3
tering processes.
Some wastes might be designated by state
• Improvement of soil. Applying waste or local regulators as essentially equivalent to
directly to land can improve soil qual- a manufactured product or raw material. Such
ity if the waste contains appropriate designations usually are granted only when
levels of biodegradable organic matter use of the designated waste would not present
and nutrients. Nutrients can improve a greater environmental and health risk than
the chemical composition of the soil would use of the manufactured or raw materi-
to the extent that it can better support al it replaces. Equivalence designations are
vegetation, while biodegradable organ- included in the category of “other agreements”
ic matter can improve its physical above. If there are no designated ground-water
properties and increase its water constituents other than those on which the
retention capacity. This potential for designation is based, then the guidelines
chemical and physical improvements described in this chapter can help you to
through land application have led to determine an appropriate application rate.
its use in conditioning soil for agricul-
If the constituent(s) identified in the waste
tural use.
is not currently covered under an agreement,
Figure 1 outlines a framework for evaluat- IWEM or another site-specific model can help
ing land application. This framework incorpo- you determine whether land application of the
rates both the ground-water risk assessment constituent(s) will be protective of ground
methodology recommended in Chapter 7, water. In some cases, pollution prevention or
Section A–Assessing Risk, as well as the other treatment can lower constituents levels so that
waste parameters and factors important to a waste can be land applied. In other cases,
land application. land application might not be feasible. In this
event, you should pursue other waste manage-
ment options. If your modeling results indi-
I. Identifying cate that the constituents can be land applied,
then the guidelines described in this chapter
Waste can once again help you to determine an
appropriate application rate.
Constituents for Your modeling efforts should consider both
Land Application the direct exposure and ecosystem pathways.
These pathways are extremely important in
If a waste leachate contains any of the con-
land application since waste is placed on the
stituents covered in the IWEM ground-water
land and attenuated by the natural environ-
model, you should first check with a federal,
ment rather than contained by an engineered
state, or other regulatory agency to see if the
structure.
waste constituents identified in the waste are
3
EPA has signed agreements with states, industries, and individual sites concerning land application. One
example is EPA’s Memorandum of Understanding (MOU) between the American Forest and Paper
Association (AFPA) and the U.S. EPA Regarding the Implementation of the Land Application Agreements
Among AF&PA Member Pulp and Paper Mills and the U.S. EPA, January 1994. For more information on
this MOU contact either AFPA’s Director of Industrial Waste Programs at 111 19th Street, N.W.,
7C-2 Washington, D.C. 20036 or EPA’s Director of the Office of Pollution Prevention and Toxics.
Protecting Ground Water—Designing A Land Application Program
Calculate agronomic
application rate
Evaluate application
rate. If waste stream
exceeds rate, consider
additional management
measures 7C-3
Protecting Ground Water—Designing A Land Application Program
Table 1
Summary of Important Waste Parameters
Total solids content Indicates ratio of solids to water in waste and influences application
method.
Biodegradable organic matter Influences soil’s water holding capacity, cation exchange, and other
physical and chemical properties, including odor.
Nutrients (nitrogen, phosphorus, Affect plant growth; nitrogen is a major determinant of application rate;
and potassium) can contaminate ground water or cause phytotoxicity if applied in
excess.
Soluble salts Can inhibit plant growth, reduce soil permeability, and contaminate
ground water.
Pathogens Can threaten public health by migrating to ground water or being car-
ried by surface water, wind, or other vectors.
Ground-water constituents Can present public health risk through ground-water contamination,
designated in Chapter 7, Section A– direct contact with waste-soil mix, transport by surface water, and
Risk Assessment including metals accumulation in plants. Metals inhibit plant growth and can be
and organic chemicals phytotoxic at elevated concentrations. Zinc, copper, and nickel are
micronutrients essential to plant growth, but can inhibit growth at high
levels.
7C-4
Protecting Ground Water—Designing A Land Application Program
B. pH
A waste’s pH is a measure of its acidic or
alkaline quality. Most grasses and legumes, as Source: Ag-Chem Equipment Co., Inc.
well as many shrubs and deciduous trees, Reprinted with permission
grow best in soils with a pH range from 5.5 microorganisms and can increase the mobility
to 7.5. If a waste is sufficiently acidic or alka- of zinc, cadmium, and lead.
line5 to move soil pH out of that range, it can
hamper plant growth. Acidic waste promotes Aqueous waste with a pH of 2 or less or a
leaching of metals, because most metals are pH of 12.5 or more meets the definition of
more soluble under acidic conditions than hazardous waste under federal regulations (40
neutral or alkaline conditions. Once in solu- CFR 261.22(a)). If the pH of a waste makes it
tion, the metals would be available for plant too acidic for land application, you can con-
uptake or could migrate to ground water. sider adjusting waste pH before application.
Alkaline conditions inhibit movement of Lime is often used to raise pH, but other
most metals. Extreme alkalinity, where pH is materials are also available. The pH is also
greater than 11, impairs growth of most soil important to consider when developing waste
handling and storage procedures.
4
Some states consider composted materials to no longer be wastes. Consult with the regulatory agency
for applicable definitions.
5
A pH of 7 is neutral. Materials with pH less than 7 are acidic, while those with pH greater than 7 are 7C-5
alkaline.
Protecting Ground Water—Designing A Land Application Program
7C-6
Protecting Ground Water—Designing A Land Application Program
6
U.S. Department of Agriculture, Agricultural Research Service. Agricultural Phosphorus and
Eutrophication, 1999. Washington, DC.
7C-7
Protecting Ground Water—Designing A Land Application Program
amount of any of the plant nutrients. If, how- How can I determine acceptable
ever, waste application rates are based solely
on nitrogen levels, resulting levels of other
metal concentrations?
nutrients such as phosphorus and potassium The Tier I and II ground-water models can
can exceed crop needs or threaten ground help you identify acceptable metals concentra-
water or surface water bodies. You should tions for land application. Also it is important
avoid excessive nutrient levels by monitoring to consult with your local, state, or regional
waste concentrations and soil buildup of agriculture extension center on appropriate
nutrients and reducing the application rate as nutrient concentrations for plant growth. If the
necessary, or by spacing applications to allow risk evaluation indicates that a waste is appro-
plant uptake between applications. Your priate for land application, but subsequent soil
local, state, or regional agricultural extension or plant tissue testing finds excessive levels of
service might have already developed materi- metals, you can consider pretreating the waste
als on or identified software for nutrient with a physical or chemical process, such as
management planning. Consult with them chemical precipitation to remove some metals
about the availability of such information. before application.
Northeast Regional Agricultural Engineering
Services (NRAES) Cooperative Extension, for
example, has compiled information on nutri- F. Carbon-to-Nitrogen Ratio
ent management software programs.7 The carbon-to-nitrogen ratio refers to the
relative quantities of these two elements in a
waste or soil. Carbon is associated with
E. Metals organic matter, and the carbon-to-nitrogen
A number of metals are included in IWEM ratio reflects the level of inorganic nitrogen
for evaluating ground-water risk. Some metals, available. Plants cannot use organic nitrogen,
such as zinc, copper, and manganese, are but they can absorb inorganic nitrogen such
essential soil micronutrients for plant growth. as ammonium. For many wastes, the carbon-
These are often added to inorganic commercial to-nitrogen ratio is computed as the dry
fertilizers. At excessive concentrations, howev- weight content of organic carbon divided by
er, some of these metals can be toxic to the total nitrogen content of waste.
humans, animals, and plants. High concentra-
Some wastes rich in organic materials (car-
tions of copper, nickel, and zinc, for example,
bon) can actually induce nitrogen deficien-
can cause phytotoxicity or inhibit plant
cies. This occurs when wastes provide carbon
growth. Also, the uptake and accumulation of
in quantities that microbes cannot process
metals in plants depends on a variety of plant
without depleting available nitrogen. Soil
and soil factors, including pH, biodegradable
microbes use carbon to build cells and nitro-
organic matter content, and cation exchange
gen to synthesize proteins. Any excess organ-
capacity. Therefore, it is important to evaluate
ic nitrogen is then converted to inorganic
levels of these metals in waste, soil, and plants
nitrogen, which plants can use. The carbon-
from the standpoint of agricultural significance
to-nitrogen ratio tells whether excess organic
as well as health and environmental risk.
nitrogen will be available for this conversion.
When the carbon-to-nitrogen ratio is less
than 20 to 1—indicating a high nitrogen con-
tent—organic nitrogen is mineralized, or con-
7
Nutrient Management Software: Proceedings from the Nutrient Management Software Workshop. To
order, call NRAES at 607 255-7654 and request publication number NRAES-100.
7C-8
Protecting Ground Water—Designing A Land Application Program
7C-9
Protecting Ground Water—Designing A Land Application Program
Table 2:
Salinity Tolerance of Selected Crops
Soil Salinity (mmhos/cm)a that will result in:
Source: Borrelli, J. and D. Brosz. 1986. Effects of Soil Salinity on Crop Yields.
a
A rule of thumb from the irrigation industry holds that soil salinity will be 1½ times the salinity of applied
irrigation water. The effect that waste salinity will have on soil salinity, however, is not as easily predicted
and depends on the waste’s water content and other properties and on the application rate.
b
Reductions are stated as a percentage of maximum expected yield.
waste or soil, determine the Na+, Ca2+, and The third reason soluble salts are impor-
Mg2+ concentrations in milliequivalents per tant is that specific ions can induce plant tox-
liter8 for use in the following equation:9 icities or contaminate ground water. Sodium
and chloride ions, for example, can become
Na+ phytotoxic at high concentrations. To assess
SAR = sodic- or toxic-inducing characteristics, you
½(Ca2+ + Mg2+) should conduct an analysis of specific ions in
addition to measuring EC.
Soils characterized by both high salts What can I do if a waste is either
(excessive TDS as indicated by EC) and
excessive sodium ions (excessive Na+ as indi- saline or sodic?
cated by SAR) are called saline-sodic soils, Saline waste. If a waste is saline, careful
and can be expected to have the negative attention to soil texture, plant selection, and
characteristics of both saline soils and sodic application rate and timing can help. Coarse
soils described above. Table 3 displays EC soils often have a lower clay content and are
and SAR levels indicative of saline, sodic, and less subject to sodium-induced soil structure
saline-sodic soils.
8
The term milliequivalents per liter (meq/l) expresses the concentration of a dissolved substance in
terms of its combining weight. Milliequivalents are calculated for elemental ions such as Na+, Ca2+, and
Mg2+ by multiplying the concentration in mg/l by the valence number (1 for Na+, 2 for Ca2+ or Mg2+)
and dividing by the atomic weight (22.99 for Na+, 40.08 for Ca2+, or 24.31 for Mg2+).
9
If the proper equipment to measure these concentrations is not available, consider sending soil and
waste samples to a soil testing laboratory, such as that of the local extension service (visit <www.reeus-
da.gov/statepartners/usa.htm> for contact information) or nearby university. Such a laboratory will be
7C-10
able to perform the necessary tests and calculate the SAR.
Protecting Ground Water—Designing A Land Application Program
Table 3
EC and SAR Levels Indicative of Saline, Sodic, and Saline-Sodic Soils
Soil Characterization
Source: Fipps, G. Managing Irrigation Water Salinity In the Lower Rio Grande Valley.
a b
In units of mmhos/cm dimensionless
problems. While coarse soils help minimize sum (CaSO4) to irrigation water can also help
soil structural problems associated with salin- to reduce the SAR, by increasing soil calcium
ity, they also have higher infiltration and per- levels. Although this might help address sodi-
meability rates, which allow for more rapid um-induced soil structure problems, if choos-
percolation or flushing of the root zone. This ing to add constituents to alter the SAR, the
can increase the risk of waste constituents EC should also be monitored to ensure salini-
being transported to ground water. ty levels are not increased too much.
Since plants vary in their tolerance to
saline environments, plant selection also is H. Calcium Carbonate
important. Some plant species, such as rye
grass, canary grass, and bromegrass, are only
Equivalent
moderately tolerant and exhibit decreased Calcium carbonate equivalent (CCE) is
growth and yields as salinity increases. Other used to measure a waste’s ability to neutralize
plants, such as barley and bermuda grass, are soil acidity—its buffering capacity—as com-
more saline-tolerant species. pared with pure calcium carbonate. Buffering
capacity refers to how much the pH changes
You should avoid applying high salt con- when a strong acid or base is added to a solu-
tent waste as much as possible. For saline tion. A highly buffered solution will show
wastes, a lower application rate, and thor- only a slight change in pH when strong acids
ough tilling or plowing can help dilute the or bases are added. Conversely, if a solution
overall salt content of the waste by mixing it has a low buffering capacity, its pH will
with a greater soil volume. To avoid the change rapidly when a base or acid is added
inhibited germination associated with saline to it. If a waste has a 50 percent CCE, it
soils, it also can help to time applications of would need to be applied at twice the rate of
high-salt wastes well in advance of seedings. pure calcium carbonate to achieve the same
Sodic waste. SAR alone will not tell how buffering effect.
sodium in a waste will affect soil permeability;
it is important to investigate the EC of a waste
as well. Even if a waste has a high SAR, plants I. Pathogens
might be able to tolerate this level if the waste Potential disease-causing microorganisms
also has an elevated EC. As with saline waste, or pathogens, such as bacteria, viruses, proto-
for sodic waste select a coarser-textured soil to zoa, and the eggs of parasitic worms, might
help address sodium concerns. Adding gyp- be present in certain wastes. Standardized
7C-11
Protecting Ground Water—Designing A Land Application Program
7C-12
Protecting Ground Water—Designing A Land Application Program
How can I evaluate the soil at a types vary considerably, further subdivision of
soil horizons or collection of samples over a
site? greater variety of depths might be appropriate.
To help evaluate the soil properties of a For more information about how to obtain
site, you should consult the U.S. Department representative soil samples and to submit
of Agriculture (USDA) soil survey for the them for analysis, you can consult EPA’s
prospective area. These surveys provide infor- Laboratory Methods for Soil and Foliar Analysis
mation on properties such as soil type and in Long-Term Environmental Monitoring
permeability. USDA has prepared soil surveys Programs (U.S. EPA, 1995d), or state guides,
for most counties in each state. To obtain a such as Nebraska’s Guidelines for Soil Sampling,
copy of the survey for an area, contact the G91-1000.
Natural Resource Conservation Service offices,
the county conservation district, the state agri- Why are chemical and biological
cultural cooperative extension service, or local properties of soil important?
health authorities/planning agency. These soils
surveys will help during site selection; howev- Chemical and biological properties of the
er, conditions they describe can differ from soil, like those of the waste, influence the
the actual soil conditions. attenuation of waste constituents. These
properties include pH, percentage of organic
Several guidance documents on soil sur- matter, and cation exchange capacity. Affected
veys are also available from USDA. These attenuation processes in the soil include
documents include the National Soil Survey absorption, adsorption, microbial degrada-
Handbook and the guide Soil Taxonomy: A tion, biological uptake, and chemical precipi-
Basic System of Soil Classification for Making tation. For example, adsorption—the process
and Interpreting Soil Surveys. The National Soil by which molecules adhere to the surface of
Survey Handbook provides an abundance of other particles, such as clay—increases as the
information including help on interpreting cation exchange capacity and pH of the soil
soil surveys, a primer on soil properties and increase. Cation exchange capacity, in turn, is
soil quality, and guides for predicting the per- dependent on soil composition, increasing as
meability of your soil. Both of these docu- the clay content of the soil increases.
ments are available over the Internet and can Adsorption through cation exchange is an
be obtained from <www.ftw.nrcs.usda.gov/ important means of immobilizing metals in
tech_ref.html>. the soil. Organic chemicals, on the other
For more site-specific data on actual soil hand, are negatively charged and can be
conditions, you can sample and characterize adsorbed through anion exchange, or the
the soil. It might be desirable to have a quali- exchange of negative ions. A soil’s capacity for
fied soil scientist perform this characteriza- anion exchange increases as its pH decreases.
tion, which often includes soil texture,
percentage of organic matter, depth to water Why are physical properties of
table, soil pH, and cation exchange capacity. soil important?
At a minimum, you should characterize sam-
Physical properties of the soil such as tex-
ples from an upper soil layer, 0 to 6 inches,
ture, structure, and pore-size distribution affect
and a deeper soil layer, 18 to 30 inches, and
infiltration rates and the ability of soil to filter
follow established soil sampling procedures to
or entrap waste constituents. Infiltration and
obtain meaningful results. If a detailed charac-
permeability rates decrease as clay content
terization is desired, or if it is suspected soil
7C-13
Protecting Ground Water—Designing A Land Application Program
increases. Sites with soils with permeabilities techniques, and application rates. The agen-
that are too high or too low have lower land cies that regulate land application in a state
application potential. Soils with high perme- can provide specific guidance concerning
ability can allow wastes to move through with- slopes. Soils on concave land and broad flat
out adequate attenuation. Soils with low lands, on the other hand, frequently are
permeability can cause pooling or excessive poorly drained and can be waterlogged dur-
surface runoff during intense rainstorms. ing part of the year. Soils in relatively flat
Excessive runoff conditions can be compensat- areas can have intermediate properties with
ed for somewhat by minimizing surface slope respect to drainage and runoff and could be
during site selection. Soils with low perme- more suitable for land application.
ability are also prone to hydraulic overloading.
The amount of liquid that can be assimi-
lated by a soil system is referred to as its IV. Studying the
hydraulic loading capacity. In addition to a
soil’s permeability, hydraulic loading capacity Interaction of
is dependent on other factors such as cli-
mate, vegetation, site characteristics, and
Plants and
other site-specific soil properties such as soil
type, depth to seasonally high water table,
Microbes with
slope and erodibility, water intake rate, and Waste
underlying geology and hydrogeology. The next step in the design of a land
Exceeding the hydraulic loading capacity of a application unit is to consider the plants and
site, can lead to rapid leaching of waste con- microbes at the site and how they will inter-
stituents into ground water, reduction in bio- act with the waste. This interaction includes
logical activity, sustained anaerobic the uptake and degradation of waste con-
conditions, soil erosion, and possible conta- stituents, the effects of the wastes on plant
mination of surface waters. It can also result and microbial growth, and changes that can
in excessive evaporation, which can cause occur in plants or crops affecting their use as
excessive odor and unwanted airborne emis- food or feed. The uptake of nutrients by
sions. In order to avoid hydraulic overload- plants and microbes on plant roots or in soil
ing at a site, application of liquid or affects the rate of waste assimilation and
semi-liquid waste or wastewater should be biodegradation, usually increasing it.
managed so uncontrolled runoff or prolonged
It might be necessary to conduct green-
saturation of the soil does not occur.
house or field studies or other tests of plants,
An important indicator of soil properties is soil, and microbes to understand and quanti-
its topography, which affects the potential for fy these interactions. You should consult with
soil erosion and contaminated surface-water the state agricultural department, the local
runoff. Soils on ridge tops and steep slopes health department, and other appropriate
are typically well drained, well aerated, and agencies if considering land application of
shallow. Steep slopes, however, increase the wastes containing designated ground-water
likelihood of surface runoff of waste and of constituents or other properties that are
soil erosion into surface waters. State guide- potentially harmful to food or feed crops.
lines, therefore, often specify the maximum Industry groups might also be able to pro-
slopes allowable for land application sites for vide information about plants with which
various waste characteristics, application they have land application experience.
7C-14
Protecting Ground Water—Designing A Land Application Program
10
Based on conversations with Dr. Rufus L. Chaney and Patricia Milner, U.S. Department of Agriculture.
7C-15
Protecting Ground Water—Designing A Land Application Program
11
If a waste contains VOCs, ensure the possibility of VOCs accumulating within the enclosed greenhouse
is addressed.
7C-16
Protecting Ground Water—Designing A Land Application Program
plant type, application rate, and nutrient stituents in the process of using other com-
extraction. From this, you can choose the pounds as an energy source. Aerobic microor-
conditions which result in the desired uptake ganisms require oxygen to metabolize waste
rate while avoiding uptake of designated and produce carbon dioxide and water as end
ground-water constituents at undesirable products. Anaerobic microbes function with-
concentrations. Plant uptake is often mea- out oxygen but produce methane and hydro-
sured as a ratio of the pollutant load found in gen sulfide as end products. These gases can
the plants to the pollutant load applied to the present a safety risk as well as environmental
land as illustrated below: threats, and hydrogen sulfide is malodorous.
For these reasons, it is recommended that
µg pollutant kg pollutant you maintain conditions that favor aerobic
per
hectare
microbes.
g dry plant tissue
For many microorganisms, these condi-
This ratio serves to place pollutant uptake tions include a pH of 6 to 8 and temperatures
in the context of the original amount of pol- of 10°C to 30°C. In addition, microbes might
lutant applied. be unable to transfer oxygen from soil effi-
ciently if the moisture content is near satura-
In choosing plants for a land application
tion, or they might be unable to obtain
unit, you should also consider growing seasons
sufficient water if the soil is too dry. A water
in relation to periods of waste application rate.
content of 25 to 85 percent of the soil’s water
Specific waste application rates associated with
holding capacity is recommended in the liter-
corresponding uptakes of nutrients by plants,
ature. Oxygen generally is available through
as indicated in greenhouse or field studies, are
diffusion from the atmosphere, but this
applicable only during the growing phases cov-
mechanism might provide insufficient oxygen
ered by the study. At other times, waste appli-
if there is too little pore space (less than 10
cation might be infeasible because plants are
percent of soil volume) or if so much organic
not present to help assimilate waste, or because
matter is applied that oxygen is consumed
plants are too large to permit passage of appli-
faster than it is replaced.
cation equipment without sustaining damage.
Microbes. Certain microbes can biode-
grade organic chemicals and other waste con- C. Effects of Waste on
stituents. Some accomplish this by directly Plant and Microbe
using the constituents as a source of carbon Growth
and energy, while others co-metabolize con-
Greenhouse and field studies can tell what
effect the waste will have on plant growth pat-
terns. A typical method of quantifying plant
growth is to state it in terms of biomass pro-
duction, which is the dry weight of the cut
plants (or representative parts of the plants). If
the plants grown with waste applications
show greater mass than the control plants,12
the waste might be providing useful nutrients
or otherwise improving the soil. If the plants
grown with waste applied at a certain rate
12
Trends detected in studies assume that results have been subjected to tests of statistical validity before
finding a trend significant.
7C-17
Protecting Ground Water—Designing A Land Application Program
weigh less than the controls, some con- state to see if there are any restrictions on
stituent(s) in the waste might be excessive at this practice. Growing crops for human con-
the studied application rate. Comparing the sumption on soil amended with waste calls
results from several different application rates for even greater caution. In some states, this
can help find the rate that maximizes growth practice is prohibited or regulated, and in
and avoids detrimental and phytotoxic effects. states where it is allowed, finding food
processors or distributors willing to purchase
Analyzing soil and water after plant growth
such crops can be difficult.
allows for a comparison between the planted
pots or plots against the control to discern the When testing crops before feeding them
differences due to plant action. If water sam- to animals, local agricultural extension ser-
ples show excessive nutrient (especially nitro- vices might be able to help determine what
gen) levels at a certain application rate, this levels are appropriate for animal consump-
might indicate that the plants were unable to tion. If plant tissue samples or findings of a
use all the nutrients in the waste applied at fate and transport model indicate waste con-
that rate, suggesting that the application was stituent levels inappropriate for animal con-
excessive. If soil and water tests show that sumption, it is important that you not use
constituents are consumed, and if other possi- harvested plants as fodder or allow grazing
ble causes can be ruled out, microbes might on the site. Additionally, plants with high
be responsible. Further investigation of constituent levels will probably be inappro-
microbial action might involve sampling of priate for other agricultural use, and thus
microbes in soil, counting their population, would likely necessitate disposal of such
and direct measurement of waste constituents crops as a waste after harvest.
and degradation byproducts.
ment when working onsite. You should limit Climate also determines which plants can
direct exposure to others through steps such grow in a region and the length of the grow-
as access control and vehicle washing to pre- ing season. If the local climate cannot sup-
vent tracking waste and waste amended soil port the plants that might be most helpful in
off site. assimilating the particular constituents in a
given waste, the use of land application might
Access control will also limit exposure of
be limited to other crops at a lower applica-
some animals. If crops will be used for animal
tion rate. If the climate dictates that the part
fodder or grazing, you should test harvested
of the growing cycle during which land appli-
fodder for the designated ground-water con-
cation is appropriate is short, a larger area for
stituents before use and restrict grazing times.
land application might be necessary.
After a site is closed, there might be long-term
access risks to future land uses and the gener- There are also operating considerations
al public. To minimize these risks, long-term associated with climate. Since waste should
access controls or deed restrictions might be not be applied to frozen or very wet soil, the
appropriate. Consult Chapter 11—Performing application times can be limited in cold or
Closure and Post-Closure Care for further rainy climates. In climates where the ground
information. can freeze, winter application poses particular
problems even when the ground is not frozen,
Direct exposure of native animals is often
because if the ground freezes soon after appli-
impossible to control and might be an entry
cation, the waste that remained near the soil
point for the ground-water constituents into
surface can run off into surface waters during
the food chain. Worms, for example, might
subsequent thaw periods. Waste nutrients are
be present in the soil and take in these con-
also more likely to leach through the soil and
stituents. Birds or other animals could then
into the ground water following spring thaw,
consume the worms, bioaccumulate, or be
prior to crop growth and nutrient uptake.
transported off site. Furthermore, animals can
These problems can be partially solved by
ingest plants grown on waste-amended soil.
providing sufficient waste storage capacity for
Therefore, you should also consider pathways
periods of freezing or rainy weather.
such as these in evaluating your plans for
land application.
VII. Calculating An
VI. Accounting for Agronomic
Climate Application Rate
Local climate considerations should also The purpose of a land application unit
enter into your land application planning (i.e., waste disposal versus beneficial use)
process. For example, wastes that are high in helps determine the waste application rate
soluble salts are less appropriate and can have best suited for that unit. When agricultural
deleterious effects in arid climates due to the benefits are to be maximized, the application
osmotic pressure from the salts inhibiting root rate is governed by the agronomic rate. The
uptake of water. On the other hand, the down- objective for determining an agronomic appli-
ward movement of water in the soil is minimal cation rate is to match, as closely as possible,
in arid climates, making the migration of waste the amount of available nutrients in the waste
constituents to ground water less likely. with the amount required by the crop. One
7C-19
Protecting Ground Water—Designing A Land Application Program
14
All of these models are referenced in EPA’s Process Design Manual: Land Application of Sewage Sludge and
Domestic Septage (U.S. EPA, 1995b). According to that source, the NLEAP software, developed by
Shaffer et al., is included in the purchase of Managing Nitrogen for Groundwater Quality and Farm
Profitability by Follet, et al., which also serves as reference for information on parameters required for
nitrogen calculations. Four regional soil and climatic databases (Upper Midwest, Southern,
Northeastern, and Western) also are available on disk for use with NLEAP. These materials can be
obtained from: Soil Science Society of America Attn: Book Order Department, 677 S. Segoe Road,
Madison, WI 53711, 608/273-2021; Book $36.00; Regional Databases $10.00 each. Current updates of
the NLEAP program can be obtained by sending original diskettes to: Mary Brodahl, USDA-ARS-GPSR,
Box E, Fort Collins, CO 80522. Additional information on the DECOMPOSITION model, developed
by Gilmour and Clark, can be obtained from: Mark D. Clark, Predictive Modeling, P.O. Box 610,
7C-20 Fayetteville, AR 72702. The CREAMS and GLEAMS models were developed by USDA.
Protecting Ground Water—Designing A Land Application Program
Management v1.1.15 If assistance is required in should reevaluate your use of land applica-
determining an appropriate agronomic rate for tion. Adjusting the application rate, adding
a waste, you should contact the regional, state, pretreatment, or switching to another means
or county agricultural cooperative extensions, of waste management might be necessary.
or a similar organization. After reevaluation, you should examine
whether corrective action might be necessary
to remediate the contaminated ground water.
VIII. Monitoring You should pay particular attention to ensure
that applications are not exceeding the soil’s
Monitoring ground water can be helpful to assimilative capacity.
verify whether waste constituents have migrat-
ed to ground water. Some state, tribal, or You should also consider testing soil sam-
other regulatory authorities require ground- ples periodically during the active life of a
water monitoring at certain types of land land application unit. For this testing to be
application units; you should consult with the meaningful, it is important that you first
appropriate regulatory agency to determine determine baseline conditions by sampling
whether such a requirement applies to the the soil before waste application begins. This
unit. Even if the unit is not required to moni- might already have been done in preparation
tor ground water, instituting a ground-water for greenhouse/field studies or for site charac-
monitoring program is recommended for terization. Later, when applying waste to the
long-term, multiple application units where unit, you should collect and analyze samples
wastes contain the designated ground-water at regular intervals (such as annually or after
constituents. Such units are more likely to a certain number of applications). Consider
pose a threat to ground water than are single- analyzing samples for macronutrients,
application units or units receiving waste micronutrients, and any of the designated
without these constituents. ground-water constituents reasonably expect-
ed to be present in the waste. The location
In most cases, lysimeters should be suffi- and number of sampling points, frequency of
cient to monitor ground water. A lysimeter is sampling, and constituents to be analyzed
a contained unit of soil, often a box or cylin- will depend on site-specific soil, water, plant,
der in the ground which is filled with soil, and waste characteristics. Local agricultural
open on the top, and closed at the bottom, so extension services, which have experience
that the water that runs through it can be col- with monitoring, especially when coupled
lected. It is usually more simple and econom- with ground-water monitoring, can detect
ical to construct and operate than a contamination problems. Early detection
monitoring well. You can consult with a qual- allows time to change processes to remedy
ified professional to develop an appropriate the problems, and to conduct corrective
ground-water monitoring program for your action if necessary before contamination
land application unit. becomes widespread.
If ground-water results indicate unaccept- Testing soils after the active life of a unit
able constituent levels, you should suspend ends might also be appropriate, especially if
land application until the cause is identified. the waste is likely to have left residues in the
You should then correct the situation that led soil. The duration of monitoring after closure,
to the high readings. If a long-term change in like the location and frequency of monitoring
the industrial process, rather than a one-time during active life, is site-specific and depends
incident, caused the elevated levels, you on similar factors. For further information
15
These models are referenced in the Northeast Regional Agricultural Engineering Cooperative
Extension’s Nutrient Management Software: Proceedings from the Nutrient Management Software
Workshop from December 11, 1996.
7C-21
Protecting Ground Water—Designing A Land Application Program
about testing soil after the active life of a unit location, characteristics, the time and date,
ends, refer to Chapte 11—Performing existing meteorological conditions, suspected
Closure and Post-Closure Care. specific source, information that indicates rel-
ative strength compared to other events, and
when during the day the odors are noticed.
IX. Odor Controls Measuring odors can be accomplished in
Odors are sometimes a common problem two manners: olfactometry and analytical.
at land application facilities and an odor The olfactometry method uses trained indi-
management plan can allow facility managers viduals who determine the strength of an
to respond quickly and effectively to deal odor. Both of these methods have advantages
with odor complaints. A plan should involve and disadvantages. Some of the advantages of
working to prevent odors from occurring, the olfactometry method are that it is accu-
working with neighbors to resolve odor com- rately correlated with human response, it is
plaints, and making changes if odors become fast at providing a general chemical classifica-
an unacceptable condition. The plan should tion, and it is usually cost effective as a field
also identify the chemical odor constituents, screening method. Disadvantages include the
determine the best method for monitoring requirement of highly trained individuals,
odor, and develop acceptable odor thresh- and it does not address the chemistry of the
olds. These odor management plans can be odor problem. Analytical methods use gas
stand-alone plans or part of your company’s chromatographs and mass spectrophotome-
environmental management system. ters to analyze vapor concentrations captured
from a sample. Some of the advantages of the
To effectively deal with odor complaints, it analytical method are that it allows detection
is important to consider creating an odor of odorants at levels near human detection, it
detection and response team to identify the is precise and repetitive, and it provides
source of, and quickly respond to, potential chemical specificity. Disadvantages include a
nuisance odor conditions. Document the very high capital cost which might not accu-
problem as well as how it was or was not rately correlate with human responses. You
resolved, and notify facility managers as soon should contact your state for more informa-
as possible. Odor complaints should be doc- tion on odor management plans and measur-
umented immediately in terms of the odor’s ing odors.
7C-22
Protecting Ground Water—Designing A Land Application Program
7C-23
Protecting Ground Water—Designing A Land Application Program
Resources
Brandt, R.C. and K.S. Martin. 1996. The Food Processing Residual Management Manual. September.
Evanylo, G.K. and W. L. Daniels. 1996. The Value and Suitability of Papermill Sludge and Sludge
Compost as a Soil Amendment and Soilless Media Substitute. Final Report. Virginia Department of
Agriculture and Consumer Services. April.
Fipps, G. 1995. Managing Irrigation Water Salinity in the Lower Rio Grande Valley. <hermes.ecn.pur-
due.edu/sgml/water_quality/texas/b1667.ascii>.
Gage, J. 2000. Operating by Progressive Odor Management Plan. Biocycle Journal of Composting &
Recycling. Vol. 41 No. 6. June.
Idaho Department of Health and Welfare. 1988. Guidelines for Land Application of Municipal and
Industrial Wastewater. March.
Michigan Department of Natural Resources, Waste Characterization Unit. 1991. Guidance for Land
Application of Wastewater Sludge in Michigan. March.
Michigan Department of Natural Resources, Waste Characterization Unit. 1991. Guide to Preparing a
Residuals Management Plan. March.
Minnesota Pollution Control Agency. 1993. Land Treatment of Landfill Leachate. February.
Nagle, S., G. Evanylo, W.L. Daniels, D. Beegle, and V. Groover. Chesapeake Bay Regional Nutrient
Management Training Manual. Virginia Cooperative Extension Service. Crop & Soil Environmental
Sciences. Virginia Polytechnic Institute and State University. Blacksburg, VA. 1997.
Northeast Regional Agricultural Engineering Cooperative Extension. 1996. Animal Agriculture and the
Environment: Nutrients, Pathogens, and Community Relations. NRAES-96. December.
North Carolina Cooperative Extension Service. 1994. Soil facts: Careful Soil Sampling—The Key to
Reliable Soil Test Information. AG-439-30.
7C-24
Protecting Ground Water—Designing A Land Application Program
Resources (cont.)
Oklahoma Department of Environmental Quality. Title 252. Oklahoma Administrative Code, Chapter
647. Sludge and Land Application of Wastewater.
Striebig, B. and R. Giani. 2000. Briefing: The Odor Index and Its Use as a Management Tool for Biosolids
Land Application. Penn State University and Pennsylvania Department of Environmental Protection.
Texas Water Commission. 1983. Industrial Solid Waste Management Technical Guideline No. 5: Land
Application. December.
University of Nebraska Cooperative Extension Institute of Agriculture and Natural Resources. 1991.
Guidelines for Soil Sampling. G91-1000-A. February.
U.S. Department of Agriculture, Natural Resources Conservation Service. 1999. Conservation Practices
Standard: Nutrient Management, Code 590. April.
U.S. Department of Agriculture, Natural Resources Conservation Service. 1999. Core Conservation
Practices, Part 2: Nutrient Management. August.
U.S. Department of Agriculture, Natural Resources Conservation Service. 1999. National Soil Survey
Handbook. September.
U.S. Department of Agriculture, Natural Resources Conservation Service. 1999. Soil Taxonomy: A Basic
System of Soil Classification for Making and Interpreting Soil Surveys. September.
U.S. EPA. 1995a. A Guide to the Biosolids Risk Assessments for the EPA Part 503 Rule. EPA832-B-93-
005. September.
U.S. EPA. 1995b. Process Design Manual: Land Application of Sewage Sludge and Domestic Septage.
EPA625-R-95-001. September.
U.S. EPA. 1995c. Process Design Manual: Surface Disposal of Sewage Sludge and Domestic Septage.
EPA625-R-95-002. September.
U.S. EPA. 1995d. Laboratory Methods for Soil and Foliar Analysis in Long-term Environmental
Monitoring Programs. EPA600-R-95-077.
7C-25
Protecting Ground Water—Designing A Land Application Program
Resources (cont.)
U.S. EPA. 1994a. Land Application of Sewage Sludge: A Guide for Land Appliers on the Requirements
of the Federal Standards for the Use or Disposal of Sewage Sludge, 40 CFR Part 503. EPA831-B-93-
002b. December.
U.S. EPA. 1994b. Guide to Septage Treatment and Disposal. EPA625-R-94-002. September.
U.S. EPA. 1994c. A Plain English Guide to the EPA Part 503 Biosolids Rule. EPA832-R-93-003.
September.
U.S. EPA. 1994d. Biosolids Recycling: Beneficial Technology for a Better Environment. EPA832-R-94-
009. June.
U.S. EPA. 1993. Domestic Septage Regulatory Guidance: A Guide to the EPA 503 Rule. EPA832-B-92-
005. September.
U.S. EPA. 1992. Control of Pathogens and Vector Attraction in Sewage Sludge. EPA625-R-92-013.
December.
U.S. EPA. 1990. State Sludge Management Program Guidance Manual. October.
U.S. EPA. 1983. Process Design Manual for Land Application of Municipal Sludge. EPA625-1-83-016.
October.
U.S. EPA, U.S. Army Corps of Engineers, U.S. Department of Interior, and U.S. Department of
Agriculture. 1981. Process Design Manual for Land Treatment of Municipal Wastewater. EPA625-1-81-
013. October.
U.S. EPA. 1979. Methods for Chemical Analysis of Water and Wastes. EPA600-4-79-020.
Viessman Jr., W. and M.J. Hammer. 1985. Water Supply and Pollution Control. 4th ed.
Washington State Department of Ecology. 1993. Guidelines for Preparation of Engineering Reports for
Industrial Wastewater Land Application Systems. Publication #93-36. May.
Webber, M.D. and S.S. Sing. 1995. Contamination of Agricultural Soils. In Action, D.F. and L.J.
Gregorich, eds. The Health of Our Soils.
Wisconsin Department of Natural Resources. 1996. Chapter NR 518: Landspreading of Solid Waste.
April.
7C-26
Part V
Ensuring Long-Term Protection
Chapter 8
Operating The Waste Management System
Contents
Resources ......................................................................................................................................................8-21
Ensuring Long-Term Protection—Operating the Waste Management System
I
mplementing a waste management sys-
tem that achieves protective environmen-
I. An Effective
tal operations requires incorporating Waste
performance monitoring and measure-
ment of progress towards environmental
Management
goals. An effective waste management system
can help ensure proper operation of the many
System
Having an effective waste management sys-
interrelated systems on which a unit depends
tem requires an understanding of environ-
for waste containment, leachate management,
mental laws and an understanding of how to
and other important functions. If the elements
comply with these laws. An effective waste
of an overall waste management system are not
management system also requires that proce-
regularly inspected, maintained, improved,
dures be in place to monitor performance and
and evaluated for efficiency, even the best-
measure progress towards clearly articulated
designed unit might not operate efficiently.
and well understood environmental goals.
Implementing an effective waste management
Lastly, an effective waste management system
system can also reduce long- and short-term
involves operational procedures that integrate
costs, protect workers and local communities,
continual improvements in waste management
and maintain good community relations.
operations to ensure continued compliance
with environmental laws. In addition to what
is discussed in this chapter, you can consider
This chapter will address the following reviewing and implementing, as appropriate,
questions. the draft voluntary standards for good envi-
ronmental practices developed by the
• What is an effective waste management International Standards Organization (ISO).
system? The ISO 14000 series of standards identify
• What maintenance and operational management system elements that are intend-
aspects should be developed as part of ed to lead to improved performance. These
a waste management system? include: a method to identify significant envi-
ronmental aspects; a policy that includes a
8-1
Ensuring Long-Term Protection—Operating the Waste Management System
commitment to regulatory compliance, the rest are standards that provide optional guid-
prevention of pollution, and continual ance for companies developing and imple-
improvement; environmental objectives and menting management systems and product
targets for all relevant levels and functions in standards. The ISO 14001 specification stan-
the organization; procedures to ensure perfor- dard contains only those requirements that
mance, as well as compliance procedures to can be objectively audited for certification,
monitor and measure performance; and a sys- registration, and self-declaration purposes. For
tematic management review process. more information about EPA’s involvement in
the ISO 14000 and 14001 standards, refer to
The ISO 14000 series of standards include
the ISO 14000 Resource Directory, October
a “specification” standard, ISO 14001. The
1997, (U.S. EPA, 1997). Information on
obtaining the ISO 14000 series of standards is
provided in the text box above. An example of
Additional Information on an integrated EMS can be found at
ISO 14000 <www.epa.gov/dfe/tools/iems.htm>.
The ISO 14000 series of standards are
copyrighted and can be obtained by con-
tacting any of the following organizations: II. Maintenance
American National Standards
Institute (ANSI)
and Operation of
1819 L Street, NW, 6th Floor
Washington, DC 20026
Waste
202 293-8020 Management
<www.ansi.org>
American Society of Testing and
System
Materials (ASTM) Components
100 Bar Harbor Drive All of the time and money invested in plan-
West Conshohocken, PA 19428-2959 ning, designing, and developing a unit will be
610 832-9585 jeopardized if proper operational procedures
<www.astm.org> are not carried out. Effective operation is
American Society for Quality important for environmental protection, and
Control (ASQC) for reasons of economy, efficiency, and aes-
611 East Wisconsin Avenue thetics. Operating control systems, therefore,
P.O. Box 3005 should be developed and maintained by the
Milwaukee, WI 53201 facility operator to ensure efficient and protec-
800 248-1946 tive operation of a waste management system.
<www.asqc.org> These controls consist of the operator con-
ducting frequent inspections, performing rou-
NSF International tine maintenance, reporting inspection results,
P.O. Box 130140 and making necessary improvements to keep
789 N. Dixboro Road the system functioning.
Ann Arbor, MI 48113-0140
800 NSF-MARK or 734 769-8010 Unit inspections can help identify deterio-
<www.nsf.org> ration of or malfunction in control systems.
Surface impoundments should be inspected
8-2
Ensuring Long-Term Protection—Operating the Waste Management System
8-3
Ensuring Long-Term Protection—Operating the Waste Management System
inspection, it is important that all inspection trap for fine sand and silt which bypasses the
reports are reviewed in a timely manner so filter pack and screen and settles out within
that any necessary repairs and improvements the well. This sediment collects within the
can quickly be identified and implemented. sump rather than within the screen, and there-
You should consult with your state agency to fore, does not reduce the functional screened
help determine if improvements are necessary. length of the well and minimizes the need for
periodic cleanouts of the screen. Regardless of
the type of ground-water monitoring well
A. Ground-Water Controls installed, the well should be protected with a
Ground-water protection controls, such as cap or plug at the upper end to prevent con-
ground-water monitoring systems, unit covers, densation, rust, and dirt from entering into the
leachate collection and removal systems, and manhole or protective casing. In addition, it is
leak detection systems should be incorporated important to inspect the outer portion of the
into the design and construction of a unit. wells to ensure that they have not been dam-
aged by trucks or other unit operations, and to
Ground-water monitoring wells require
ensure that the cap or plug is intact.
continued maintenance. A major reason for
maintenance is plugging of the gravel pack or You also should inspect and maintain unit
screen. (See Chapter 9–Monitoring covers to ensure that they are intact. For opti-
Performance for a discussion on the construc- mal performance, covers should be designed
tion of ground-water monitoring wells.) The to minimize permeability, surface ponding,
most common plugging problems are caused and the erosion of cover material. The cover
by precipitation of calcium or magnesium car- should also prevent the buildup of liquids
bonates and iron compounds. Acid is most within the unit. Consult Chapter
commonly used to clean screens clogged with 11–Performing Closure and Post-Closure Care
calcium carbonate. In many instances, howev- for a more detailed discussion on maintaining
er, the cost of attempted restoration of a moni- cover systems.
toring well can be more than the installation of It is essential that all components of a
a new well. Because many wells are installed leachate collection and removal system and a
in unconsolidated sand formations, silt and leak detection system be maintained properly.
clay can be pumped through the system and The main components include the leachate
cause it to fail. Silt and sand grains are abra- collection pipes, manholes, leachate collection
sive and can damage well screens, pumps (if tanks and accessories, and pumps. You should
present), flow meters, and other components. consider cleaning the leachate pipes once a
In some cases, the well can fill with sedi- year to remove any organic growth and visual-
ment and must be cleaned out. The most fre- ly inspecting the manholes, tanks, and pumps
quent method of cleaning is to pull the pump once a year as leachate can corrode metallic
from the well, circulate clean water down the parts. Annual inspections and necessary
well bore through a drop, and flush the sedi- repairs will prevent many future emergency
ment out. If large amounts of sediments are problems such as leachate overflow from the
expected to enter a monitoring well, consider tank due to pump failure. Maintain a record of
incorporating a sediment sump (also called a all repair activities as necessary to assess (or
silt trap or sediment trap) into the monitoring claim) long-term warranties on pumps and
well construction. The sump consists of a other equipment.
blank section of pipe placed below the base of
the screen. Its purpose is to provide a catch-
8-4
Ensuring Long-Term Protection—Operating the Waste Management System
8-5
Ensuring Long-Term Protection—Operating the Waste Management System
8-6
Ensuring Long-Term Protection—Operating the Waste Management System
This section identifies and briefly discusses • Personnel needs and equipment uti-
some of the important operational aspects of lization, including backup.
a waste management system, including devel- • Procedures to address emergencies,
oping an operating plan, performing waste such as medical crises, fires, and spills.
analyses and inspections, installing daily cov-
• Quality control standards.
ers, placing wastes in a unit, removing
sludge, considering climate, implementing • Record keeping protocols.
security and access control measures, provid-
• Means of compliance with local,
ing employee training, addressing nuisance
state, and federal regulations.
concerns, developing emergency response
plans and procedures, and maintaining The daily procedures component of the plan
important records. Consider developing prac- outlines the day-to-day activities necessary to
tices to ensure compliance with applicable place waste, operate environmental controls,
laws and regulations, to train workers how to and inspect and maintain the waste manage-
handle potential problems, and to ensure that ment unit in accordance with its design. Daily
all necessary improvements or changes are procedures should be concise enough to be cir-
made to a waste management system. Proper culated among all employees at the unit and
planning and implementation of these operat- flexible enough to allow for any adjustments
ing practices are important elements in the necessary to accommodate weather variability,
efficient and protective operation of a unit. changing waste volume, and other contingen-
cies. You should revise and update daily proce-
dures as needed to ensure the unit’s continued
A. Operating Plan safe operation within the parameters of the
An operating plan should serve as the pri- overall operating plan.
mary resource document for operating a Since a unit will likely operate for several
waste management unit. It should include the years, it is important that staff periodically
technical details necessary for a unit to oper- review the operating plan to refresh their
ate as designed throughout its intended memories and to ensure long-term conformi-
working life. At a landfill, for example, the ty with the plan. If modifications to the oper-
operating plan should illustrate the chrono- ating plan are necessary, the changes and the
logical sequence for filling the unit, and it date they were made should be noted within
should be detailed enough to allow the facili- the plan itself. Documented operating proce-
ty manager to know what to do at any point dures can be crucial, especially if questions
in the active life of the unit. arise in the future regarding the adequacy of
An operating plan should include: site construction and management.
• A daily procedures component.
8-7
Ensuring Long-Term Protection—Operating the Waste Management System
B. Waste Analysis
To effectively manage waste and ensure
proper handling (e.g., preventing the mixing
of incompatible wastes, use of incompatible
liners or containers), knowledge of the chem-
ical and physical composition of the wastes is
imperative. Determining waste characteristics
can be done by performing a comprehensive
waste analysis or through process knowledge.
To ensure that this information remains accu-
rate, it might be necessary to repeat the An effective waste management system
analysis whenever there is a change in the relies on accurate knowledge of the waste
industrial process generating the waste. For
being handled.
further information, consult Chapter
2–Characterizing Waste. tions, such as checking random loads of waste
on a random day each week or every incom-
ing load on one random day each month.
C. Waste Inspections Base the frequency of random inspections on
The purpose of performing waste inspec- the type and quantity of wastes expected to be
tions is to identify waste that might be inap- received, the accuracy and confidence desired,
propriate for the waste management unit, and and any state inspection requirements.
to prevent problems and accidents before Inspections need to be performed prior to
they happen. Hazardous wastes, PCBs, liq- placement of wastes in a unit.
uids (in landfills and waste piles), and state- Training employees to recognize inappro-
designated wastes are prohibited from priate wastes during routine operations
disposal in units designated solely for indus- increases the chances that inappropriate
trial nonhazardous waste. Some states have waste arriving on non-inspection days will be
developed more stringent screening require- detected. Some indications of inappropriate
ments that require a spotter to be present at a wastes are color, texture, or odor different
unit to detect unauthorized wastes and to from those of the waste a unit normally
weigh and record incoming wastes. receives. Also, laboratory testing can be per-
As part of a waste management system, formed to identify different wastes.
screening procedures should be implemented A waste management system should
to prevent inappropriate wastes from entering include procedures to address suspected
a unit. For units receiving waste exclusively inappropriate waste. The procedures to
from on site, only limited waste screening implement, when inappropriate wastes are
might be necessary. For facilities receiving found, should include the following:
waste from off site, screening procedures typi-
cally call for screening waste as it enters a • Segregate the suspicious wastes.
unit. Ideally, all wastes entering a unit should • Use appropriate personal protective
be screened, but this is not always practical or equipment.
necessary. A decision might be made, there-
fore, to screen a percentage of incoming • Contact the part of the industrial
waste. It might be practical to use spot inspec- facility that generated the waste to
find out more about it.
8-8
Ensuring Long-Term Protection—Operating the Waste Management System
Using alternative daily cover materials can occur. To avoid these problems, it is impor-
save valuable space in a waste management tant to ensure that waste is properly placed
unit. Some types of commercially available and, if possible, compacted to ensure stability
daily cover materials include foam that usual- of the final cover.
ly is sprayed on the working face at the end
To protect liner integrity in lined surface
of the day, and geosynthetic products, such as
impoundments, consider placing an erosion
a tarp or fabric panel that is applied at the
guard or a concrete pad on the liner at the
end of the working day and removed at the
point where waste discharges into the unit.
beginning of the following working day.
Otherwise, pressure from the waste hitting
Some of these materials require specially
the liner can accelerate liner deterioration in
designed application equipment, while others
that area. Inlet pipes can also be arranged so
use equipment generally available at most
that liquid waste being discharged into the
units. Criteria to consider when selecting an
unit is diffused upward or to the side.
alternative daily cover material include avail-
Although inlet pipes can enter the surface
ability and suitability of the material, precipi-
impoundment above the water level, the
tation, chemical compatibility with waste,
point of discharge should be submerged to
equipment requirements, and cost.
avoid generating odor and disturbing the cir-
culation of stratified ponds. Discharging liq-
E. Placing Wastes uid waste straight into the unit without
diffusion is not recommended as this can dis-
To protect the integrity of liner systems, rupt the intended treatment.
the waste management system should pre-
scribe proper waste placement practices. The
primary physical compatibility issue is punc- F. Sludge Removal
ture of the liner by sharp objects in the waste.
If significant amounts of sludge accumu-
Ensure that the liner is protected from items
late on the bottom of an impoundment, it
angular and sharp enough to puncture it.
might be necessary to remove the sludge and
Similarly, facility employees should be
dispose of it periodically. There are two ways
instructed to keep heavy equipment off the
to remove the sludge: dewater the cell and
liner. Another physical compatibility issue is
remove the sludge after it has dried, or
keeping fine-grained waste materials away
dredge the impoundment. Many different
from drainage layers that could be clogged by
methods exist for dredging an impoundment.
such materials.
Examples include a tanker truck outfitted
Differential settlement of wastes is another with a vacuum hose, manned and remote
problem that can be associated with waste dredges, and submersible pumps on steel
placement. To avoid differential settlement, pontoons used as a floating dredge or
focus on how the waste is placed on the liner dragged on the pond bottom. You should
material or on the protective layer above the work with your state and sludge removal pro-
liner. Uneven placement of waste, or uneven fessionals to choose or create a method that
compaction can result in differential settle- works best at your facility.
ment of succeeding waste layers or of final
There are two main concerns regarding
cover. Differential settlement, in turn, can lead
sludge management: protecting the liner
to ponding and infiltration of water and dam-
while cleaning out sludge from the impound-
age to liners or leachate collection systems. In
ment (if a liner is used) and properly dispos-
extreme cases, failure of waste slopes can
ing of any removed sludge. During dredging,
8-10
Ensuring Long-Term Protection—Operating the Waste Management System
8-11
Ensuring Long-Term Protection—Operating the Waste Management System
move about more freely. In addition, you can ments, and any time a new health or safety
consider imposing onsite speed limits or con- hazard is introduced into the work area. A
structing speed bumps. good training program uses concrete exam-
ples to improve and maintain employee skill,
Access roads should be maintained proper-
safety, and teamwork. Training can be provid-
ly at all times. Adequate drainage of road
ed by in-house trainers, trade associations,
beds is essential for proper operation of a
computer programs, or specialized consul-
unit. Heavy, loaded vehicles traveling to and
tants. In some states, proactive safety and
from a unit deteriorate the roads on which
training programs are required by law.
they travel. Equipment without rubber tires
should be restricted from the paved stretches
of roads as they can damage the roads.
Sufficient funds should be allocated up front
for the maintenance of access roads.
8-12
Ensuring Long-Term Protection—Operating the Waste Management System
8-13
Ensuring Long-Term Protection—Operating the Waste Management System
8-14
Ensuring Long-Term Protection—Operating the Waste Management System
8-15
Ensuring Long-Term Protection—Operating the Waste Management System
• Maintenance and testing log of emer- response to handle public affairs during a
gency equipment. major emergency. These employees should
work with the press to ensure that the public
• Plans to familiarize local authorities,
receives an accurate account of the emergency.
local emergency response organiza-
tions, and neighbors with the charac-
teristics of the unit and appropriate K. Record Keeping
and inappropriate responses to vari-
ous emergency situations. Record keeping is a vital part of cost-effec-
tive, efficient waste management unit opera-
• Information on state emergency tions. Records should be maintained for an
response teams, response contractors, appropriate period of time, but it is a good
and equipment suppliers. idea to keep a set of core records indefinitely.
• Properties of the waste being handled Some facilities have instituted policies that
at the unit, and types of injuries that records are to be maintained for up to 30
could result from fires, explosions, years while other facilities maintain records
releases, or other mishaps. for only 3 years. Some states have record
keeping requirements for certain waste man-
• An evacuation plan for unit person- agement units and associated practices. You
nel (if applicable). should check with state authorities to deter-
• Prominent posting of the above mine what, if any, record keeping is required
information. by law and to determine how long records
should be kept.
The emergency plan should instruct all
employees what to do if an emergency arises, Besides being required by some states,
and all employees should be familiar with the records help evaluate and optimize unit per-
plan and their responsibilities under it. In formance. Over time, these records can serve
order to ensure that everyone knows what to as a valuable almanac of activities, as well as
do in an emergency, EPA recommends con- a source of cost information to help fine tune
ducting periodic drills. These practice re- future expenditures and operating budgets.
sponses could be planned ahead of time or Data on waste volume, for example, can
they could be unannounced. Either way, the allow a prediction of remaining site life, any
drills are treated as real emergencies and special equipment that might be needed, and
serve to hone the skills of the employees who personnel requirements. Furthermore, if a
might have to respond to actual emergencies.
The key to responding effectively to an emer-
gency is knowing in advance what to do.
Communication is vital during an emer-
gency and should be an inherent component
of any emergency response plan. Two-way
radios and bullhorns can prove invaluable in
the event of an emergency, and an alarm sys-
tem can let employees know that an emer-
gency situation is at hand. It is recommended
that you designate one or more employees Keeping accurate records is an essential part
who will not be essential to the emergency of unit operations.
8-16
Ensuring Long-Term Protection—Operating the Waste Management System
facility is ever involved in litigation, accurate, • Personal information and work history
dated records can be invaluable in establish- for each employee, including health
ing a case. information such as illness reports.
8-17
Ensuring Long-Term Protection—Operating the Waste Management System
How can odor be minimized? menting gas controls if odors are associated
with gases generated from a unit.
Increased urbanization has led to industri-
al facilities being situated in close proximity If odors emanate from surface impound-
to residential areas and commercial develop- ments, there are several options available for
ments. This has resulted in numerous com- control, including biological and chemical
plaints about odors from industrial waste treatment. The type of treatment for an
management units and industrial processes impoundment should be determined on a
such as poultry processing, slaughtering and site-specific basis, taking into account the
rendering, tanning, and manufacture of chemistry of the waste.
volatile organics. Some of the major sources Practices to control odor are especially
of odors are hydrogen sulfide and organic important at land application units. If land
compounds generated by anaerobic decom- application is used, it is important to apply
position. The latter can include mercaptans, waste at appropriate rates for site conditions,
indole, skatole, amines, and fatty acids. Odor and design and locate waste storage facilities
might be a concern at a unit, depending on to minimize odor problems. Make it a priority
proximity to neighbors and the nature of the to minimize potential odors by applying
wastes being managed. In addition to causing wastes as soon as possible after delivery and
complaints, odors can be a sign of toxic or incorporating wastes into the soil as soon as
irritating gases or anaerobic conditions in a possible after application. Cleaning trucks,
unit that could have adverse health effects or tanks, and other equipment daily (or more fre-
environmental impacts. Plan to be proactive quently, if necessary) can also help reduce
in minimizing odors, and establish proce- odor. Avoid applying waste when soils are wet
dures to respond to citizen complaints about or frozen or when other soil or slope condi-
odor problems and to correct the problems. tions would cause ponding or poor drainage.
Odors can be seasonal in nature and, Chapter 7 Section C– Designing a Land
therefore, can often be anticipated. Some Application Program presents information
odors at landfills, waste piles, and land appli- concerning an odor management plan for land
cation units arise either from waste being application facilities.
unloaded or from improperly covered in- Other methods of controlling odors
place waste. If odor from waste being include:
unloaded becomes a problem, it might be
necessary to place these loads in a portion of • Covering or enclosing the unit.
the unit where they can be immediately cov- • Adding chemicals such as chlorine,
ered with soil. At land application units, lime, and ferric chloride to reduce
quick incorporation or injection of waste can bacterial activity and oxidize many
help prevent odor. It also might be prudent to products of anaerobic decomposition.
establish a system whereby unit personnel are
• Using biofilters.
notified when odorous wastes are coming to
the unit to allow them to prepare accordingly. • Applying a deep soil cover, whose
Odors from in-place waste can effectively be upper layers consist of silty soils or
minimized by maintaining the integrity of soils containing a large percentage of
cover material over everything but the cur- carbon or humic material.
rently active face. Proper waste compaction
• Applying a layer of relatively imper-
also helps to control odors. Consider imple-
meable soil, so as to reduce gas gen-
8-18
Ensuring Long-Term Protection—Operating the Waste Management System
8-19
Ensuring Long-Term Protection—Operating the Waste Management System
8-20
Ensuring Long-Term Protection—Operating the Waste Management System
Resources
ASTM. 1993. Standard Practice for Maintaining Health and Safety Records at Solid Waste Processing Facilities.
E 1076-85.
Bagchi, A. 1994. Design, Construction, and Monitoring of Landfills. John Wiley & Sons Inc.
Bolton, N. 1995. The Handbook of Landfill Operations: A Practical Guide for Landfill Engineers, Owners, and
Operators. Blue Ridge Solid Waste Consulting.
Robinson, W. 1986. The Solid Waste Handbook: A Practical Guide. John Wiley & Sons Inc.
U.S. EPA/National Response Team. 1996. The National Response Teams Integrated Contingency Plan
Guidance; Notice. (61 FR 28642; June 5, 1996).
U.S. EPA. 1995. Decision-Maker’s Guide to Solid Waste Management, Second Edition. EPA530-R-95-023.
U.S. EPA. 1995. State Requirements for Industrial Nonhazardous Waste Management Facilities.
U.S. EPA. 1994. Seminar Publication: Design, Operation, and Closure of Municipal Solid Waste Landfills.
EPA625-R-94-008.
U.S. EPA. 1993. Solid Waste Disposal Facility Criteria: Technical Manual. EPA530-R-93-017.
U.S. EPA. 1991. Technical Resource Document: Design, Construction, and Operation of Hazardous and
Nonhazardous Waste Surface Impoundments. EPA530-SW-91-054.
U.S. EPA. 1989. Test Methods for Evaluating Solid Waste, Physical/Chemical Methods. SW-846.
U.S. EPA. 1988. Subtitle D of RCRA, “Criteria for Municipal Solid Waste Landfills” (40 CFR Part 258),
Operating Criteria (Subpart C). Draft/Background Document.
8-21
Part V
Ensuring Long-Term Protection
Chapter 9
Monitoring Performance
Contents
V. Sampling and Analytical Protocols and Quality Assurance and Quality Control ..................................9 - 39
A. Data Quality Objectives ......................................................................................................................9 - 41
B. Sample Collection................................................................................................................................9 - 41
C. Sample Preservation and Handling ......................................................................................................9 - 42
D. Quality Assurance and Quality Control ..............................................................................................9 - 42
E. Analytical Protocols ............................................................................................................................9 - 44
VI. Analysis of Monitoring Data, Contingency Planning, and Assessment Monitoring ................................9 - 45
A. Statistical Approaches ..........................................................................................................................9 - 45
B. Contingency Planning..........................................................................................................................9 - 46
C. Assessment Monitoring ........................................................................................................................9 - 46
Resources ..................................................................................................................................................9 - 50
Tables:
Table 1: Factors Affecting Number of Wells Per Location ..........................................................................9 - 9
Table 2: Potential Parameters for Basic Groundwater Monitoring ............................................................9 - 15
Table 3: Recommended Components of a Basic Ground-Water Monitoring Program ..............................9 - 16
Table 4: Comparison of Manual and Automatic Sampling Techniques ....................................................9 - 24
Table 5: Types of QA/QC Samples............................................................................................................9 - 43
Figures:
Figure 1: Cross-Section of a Generic Monitoring Well................................................................................9 - 5
Figure 2: Major Methods for In Situ Monitoring of Soil Moisture or Matrix Potential ..............................9 - 18
Figure 3: Example Methods for Collecting Soil-Pore Samples ..................................................................9 - 19
Figure 4: Soil Gas Sampling Systems........................................................................................................9 - 20
Figure 5: Schematic Diagram of various Types of Sampling Systems ........................................................9 - 36
Figure 6: Sampling Train..........................................................................................................................9 - 38
Ensuring Long-Term Protection—Monitoring Performance
Monitoring Performance
This chapter will help you:
• Carefully design and implement a monitoring program that is essen-
tial to evaluating whether a unit meets performance objectives and
whether there are releases to, and impacts on, the surrounding
environment that need to be corrected.
• Design effective monitoring programs that protect the environment,
improve unit performance, and help reduce long-term costs and lia-
bilities associated with industrial waste management.
M
of the environment caused by the unit. The
onitoring the performance of
detection information obtained from a moni-
a waste management unit is
toring program can be used to ensure that the
an integral part of a compre-
proper types of wastes are being managed in
hensive waste management
the unit, discover and repair any damaged
system. A properly imple-
area(s) of the unit, and determine if an alter-
mented monitoring program provides an
native management approach might be
indication of whether a waste management
appropriate. By implementing a monitoring
unit is functioning in accordance with its
program, facility managers can identify prob-
design, and detects any changes in the quality
lems or releases in a timely fashion and take
the appropriate measures to limit contamina-
This chapter will address the following tion. Continued detection of contamination
questions. in the environment could result in the imple-
mentation of more aggressive corrective
• What site characterizations are needed to
action measures to remediate releases.
develop an effective monitoring program?
This chapter highlights issues associated
• What are the basic elements of a moni-
with establishing a ground-water monitoring
toring program?
program because most industrial waste man-
• How should sampling and analytical pro- agement units need to have such a program.
tocols be used in a monitoring program? The chapter also provides a discussion of air,
surface water, and soil monitoring that might
• What procedures should be used to
be applicable to some units managing industri-
evaluate monitoring data?
al waste. You should consult with qualified
• What elements of the basic monitoring professionals, such as engineers and ground-
program can be modified to address water specialists,1 for technical assistance in
site conditions? making decisions about the design and opera-
tion of a ground-water monitoring program. In
1
For the purpose of this chapter, a qualified “ground-water specialist” refers to a scientist or engineer
who has received a baccalaureate or post-graduate degree in the natural sciences or engineering and has
sufficient training and experience in ground-water hydrology and related fields as demonstrated by
state registration, professional certifications, or completion of accredited university programs that
enable that individual to make sound professional judgements regarding ground-water monitoring,
contaminant fate and transport, and corrective action. 9-1
Ensuring Long-Term Protection—Monitoring Performance
9-2
Ensuring Long-Term Protection—Monitoring Performance
9-3
Ensuring Long-Term Protection—Monitoring Performance
The level of effort one employs to character- depth at a single location, you should install
ize a site sufficiently to design an adequate conventional monitoring wells in clusters or
ground-water monitoring system depends on with multilevel sampling devices.
the geologic and hydrogeologic complexity of
the site. The complexity of a site should not be
2. Direct-Push Ground-Water
assumed; a soil boring program can help
determine the complexity of a site’s hydrogeol- Sampling
ogy. The American Society for Testing and Using the direct-push technique, ground
Materials’ (ASTM) Annual Book of ASTM water is sampled by hydraulically pressing
Standards2 provides more than 80 guides and and/or vibrating a probe to the desired depth
practices related to waste and site characteriza- and retrieving a ground-water sample through
tion and sampling. For additional information the probe. The probe is removed for reuse
on ground-water monitoring, see EPA’s elsewhere after the desired volume of ground
Ground-Water Monitoring: Draft Technical water is extracted. It is important to clean the
Guidance (U.S. EPA, 1993a) and Solid Waste probe with an appropriate decontamination
Disposal Facility Criteria: Technical Manual (U.S. protocol after each use to avoid potential
EPA, 1993b). cross-contamination.
9-4
Ensuring Long-Term Protection—Monitoring Performance
9-5
Ensuring Long-Term Protection—Monitoring Performance
9-6
Ensuring Long-Term Protection—Monitoring Performance
9-7
Ensuring Long-Term Protection—Monitoring Performance
2. Vertical Placement and Screen Well screen lengths are also determined by
Lengths site- and constituent-specific parameters.
These parameters and the importance of tak-
Similar to lateral placement, vertical well ing vertically discrete ground-water samples,
placement in the ground water around a factor into the determination of well screen
waste management unit is determined by size. Highly heterogeneous (complex) geolog-
geologic and hydrogeologic factors, as well as ic sites require shorter well screen lengths to
the chemical and physical characteristics of allow for the sampling of discrete migration
the potential contaminants. The vertical pathway. Screens that span more than a single
placement of each well and its screen lengths contaminant migration pathway can cause
will be determined by the number and spatial cross contamination, possibly increasing the
distribution of potential contaminant migra- extent of contamination. Shorter screen
tion pathways and the depth and thickness of lengths allow for more precise monitoring of
potential migration pathways. Site-specific the aquifer or the portion of the aquifer of
geology, hydrogeology, and constituent char- concern. Excessively large well screens can
acteristics influence the location, size, and lead to the dilution of samples making conta-
geometry of potential contaminant plumes, minant detection more difficult.
which in turn determine monitoring well
depths and screen lengths. The depth or thickness of an aquifer also
influences the length of the well screen. Sites
The chemical and physical characteristics with highly complex geology or relatively
of potential contaminants from a waste man- thick aquifers might require multiple screens
agement unit play a significant role in deter- at varying depths. Conversely, a relatively
mining vertical placement. The specific thin and homogenous aquifer might allow for
properties of a particular contaminant will fewer wells with longer screen lengths. Table
determine what potential migration pathway 1 below summarizes the recommended fac-
it might take in an aquifer. The specific char- tors to consider when determining the num-
acteristics of a contaminant, such as its solu- ber of wells needed per sampling location.
bility, Henry’s law constant, partition
coefficients, specific gravity (density), poten- You should consult with state officials on
tial for natural attenuation and the resulting the lateral and vertical placement of monitor-
reaction or degradation products, and the ing wells including well screening lengths. In
potential for contaminants to degrade confin- the absence of specific state requirements, it
ing layers, will all influence the vertical place- is recommended that the monitoring points
ment and screen lengths of a unit’s be no more than 150 meters downgradient
monitoring wells. A DNAPL, for instance, will from a waste management unit boundary, on
sink to the bottom of an aquifer and migrate facility property, and placed in potential cont-
along geologic gradients (rather than hydro- amination migration pathways. This maxi-
geologic gradients), thus a monitoring well’s mum distance is consistent with the approach
vertical placement should correspond with taken in many states in order to protect
the depth of the appropriate geologic feature. waters of the state.
LNAPLs (light non-aqueous phase liquids),
on the other hand, would move along the top
of an aquifer, and result in placement of wells
and wells screens at the surface of the aquifer.
9-8
Ensuring Long-Term Protection—Monitoring Performance
Table 1
Factors Affecting Number of Wells Per Location (CLUSTER)
One Well per Sampling Location More Than One Well Per Sampling Location
9-9
Ensuring Long-Term Protection—Monitoring Performance
a well intake is controlled by the type of well on top of the filter pack to minimize migra-
intake it is and its opening size. Many types tion of annular seal material (see below) into
of well intakes have been used in monitoring the filter pack.
wells, including: the louvered (shutter-type)
intake, the bridge-slot intake, the machine- Annular Seal
slotted well casing, and the continuous-slot
wire-wound intake. Annular space is the space between the
casing and the borehole wall. Any annular
space that is produced as a result of the
Filter Pack installation of well casing in a borehole pro-
Filter pack is the material placed between vides a channel for vertical movement of
the well screen and the borehole wall that water and/or contaminants unless the space is
allows ground water to flow freely into the sealed. The annular seal in a monitoring well
well while filtering out fine-grained materials. is placed above the filter pack in the annulus
It is important to minimize the distortion of between the borehole and the well casing.
the natural stratigraphic setting during con- The seal serves several purposes: to provide
struction of a monitoring well. Hence, it protection against infiltration of surface water
might be necessary to filter-pack boreholes and potential contaminants from the ground
that are over-sized with regard to the casing surface down the casing/borehole annulus; to
and well intake diameter. The filter pack pre- seal off discrete sampling zones, both
vents formation material from entering the hydraulically and chemically; and to prohibit
well intake and helps stabilize the adjacent vertical migration of water. Such vertical
formation. The filter-pack materials should be movement can cause “cross contamination”
chemically inert to avoid the potential for which can influence the representativeness of
alteration of ground-water sample quality. ground-water samples. The annular seal can
Commonly used filter-pack materials include be comprised of several different types of per-
clean quartz sand, gravel, and glass beads. manent, stable, low-permeability materials
You should check with the state regulatory including pelletized, granular, or powdered
agency to determine if state regulations speci- bentonite; neat cement grout; and combina-
fy filter pack grain size, either in absolute tions of both. The most effective seals are
terms or relative to the grain size of the water obtained by using expanding materials that
bearing zone, or a uniformity coefficient. will not shrink away from either the casing or
the borehole wall after curing or setting.
The filter pack should generally extend
from the bottom of the well intake to approx-
imately two to five feet above the top of the Surface Seal
well intake, provided the interval above the A surface seal is an above-ground seal that
well intake does not result in a hydraulic protects a monitoring well from surface water
connection with an overlying zone. To ensure and contaminant infiltration. Monitoring wells
that filter pack material completely surrounds should have a surface seal of neat cement or
the screen and casing without bridging, the concrete surrounding the well casing and fill-
filter pack can be placed with a tremie pipe (a ing the annular space between the casing and
small diameter pipe that carries the filter the borehole at the surface. The surface seal
pack material directly to the filter screen can be an extension of the annular seal
without creating air pockets within the filter installed above the filter pack, or it can be a
pack). A layer of fine sand can also be placed separate seal placed on top of the annular
9-11
Ensuring Long-Term Protection—Monitoring Performance
seal. The surface seal will generally extend to tive casing and the well casing. This drain
at least three feet away from the well casing at allows trapped water to drain away from the
the surface and taper down to the size of the casing. In high-traffic areas or in areas where
borehole within a few feet of the surface. In heavy equipment might be working, consider
climates with alternating freezing and thawing the installation of additional protection such
conditions, the cement surface should extend as “bumper guards.” Bumper guards are
below the frost depth to prevent potential well brightly-painted posts of wood, steel, or some
damage caused by frost heaving. other durable material set in cement and
located within three or four feet of the well.
Surface Completions
Surface completions are protective casings 2. Well Installation
installed around the well casing. Two types of To ensure collection of representative
surface completions are common for ground- ground-water samples, the well intake, filter
water monitoring wells: above-ground com- pack, and annular seal need to be properly
pletion, and flush-to- ground completion. installed. In cohesive unconsolidated material
The primary purposes of either type of com- or consolidated formations, well intakes
pletion are to prevent surface runoff from should be installed as an integral part of the
entering and infiltrating down the annulus of casing string by lowering the entire unit into
the well and to protect the well from acciden- the open borehole and placing the well intake
tal damage or vandalism. opposite the interval to be monitored.
In an above-ground completion, which is Centralizing devices are typically used to cen-
the preferred alternative, a protective casing is ter the casing and intake in the borehole to
generally installed around the well casing by allow uniform installation of the filter pack
placing the protective casing into the cement material around the well intake. In non-cohe-
surface seal while it is still wet and uncured. sive, unconsolidated materials there are other
The protective casing discourages unautho- standardized techniques to ensure the proper
rized entry into the well, prevents damage by installation of wells, such as the use of a cas-
contact with vehicles, and reduces degrada- ing hammer, a cable tool technique, the dual-
tion caused by direct exposure to sunlight. wall reverse-circulation method, or
The protective casing should be fitted with a installation through the hollow stem of a hol-
locking cap and installed so that there are at low-stem auger.
least one to two inches clearance between the
top of the in-place, inner well, casing cap and 3. Well Development
the bottom of the protective casing locking Monitoring well development is the
cap when in the locked position. removal of fine particulate matter, commonly
Like the inner well casing, the outer pro- clay and silt, from the geologic formation
tective casing should be vented near the top near the well intake. If particulate matter is
to prevent the accumulation and entrapment not removed, as water moves through the for-
of potentially explosive gases and to allow mation into the well, the water sampled will
water levels in the well to respond naturally be turbid, and the viability of the water quali-
to barometric pressure changes. Additionally, ty analyses will be impaired. When pumping
the outer protective casing should have a during well development, the movement of
drain hole installed just above the top of the water is unidirectional toward the well.
cement level in the space between the protec- Therefore, there is a tendency for the particu-
9-12
Ensuring Long-Term Protection—Monitoring Performance
lates moving toward the well to “bridge” monitoring frequency to ensure that samples
together or form blockages that restrict subse- collected are physically and statistically inde-
quent particulate movement. These blockages pendent. For example, in areas with high
can prevent the complete development of the ground-water flow velocity, more frequent
well capacity. This effect potentially impacts monitoring might be necessary to detect a
the quality of the water entering the well. release before it migrates and contaminates
Development techniques should remove such large areas. In areas with low flow velocity,
bridges and encourage the movement of par- less frequent monitoring might be appropri-
ticulates into the well. These particulates can ate. It is important to analyze background
then be removed from the well by bailer or ground-water conditions, such as flow direc-
pump and, in most cases, the water produced tion, velocity, and seasonal fluctuations to
will subsequently be clear and non-turbid. help determine a suitable monitoring fre-
quency for a site. You should consult with the
In most instances, monitoring wells
appropriate state agency to determine an
installed in consolidated formations can be
appropriate monitoring frequency. In the
developed without great difficulty. Monitoring
absence of state requirements, it is recom-
wells also can usually be developed rapidly
mended that semi-annual monitoring be con-
and without great difficulty in sand and grav-
ducted to detect contamination as part of a
el deposits. However, many installations are
basic monitoring program.
made in thin, silty, and/or clayey zones. It is
not uncommon for these zones to be difficult
to develop sufficiently for adequate samples G. Sampling Parameters
to be collected.
Selection of parameters to be monitored in a
ground-water monitoring program should be
F. Duration and Frequency based on the characteristics of waste in the
of Monitoring management unit. Additional sampling and
analysis information can be found in EPA SW-
The duration of ground-water monitoring 846 Test Methods for Evaluating Solid Waste (U.S.
will depend on the length of the active life of EPA, 1986) and in ASTM’s standards. The
the waste management unit and its post-clo- Annual Book of ASTM Standards also identifies
sure care period. Continued monitoring after 18 ASTM guides and practices for performing
a waste management unit has closed is waste characterization and sampling.
important because the potential for contami-
nant releases remains even after a unit has What are sampling parameters?
stopped receiving waste. Monitoring frequen-
cy should be sufficient to allow detection of Analyzing a large number of ground-water
ground-water contamination. This frequency quality parameters in each sampling episode
usually ranges from quarterly to annually. can be costly. To minimize expense, select
only contaminants and geochemical indicators
What site characteristics should that can be reasonably expected to migrate to
the ground water. These are called sampling
be evaluated to determine the parameters. Sampling parameters should pro-
frequency of monitoring? vide an early indication of a release from a
waste management unit. Once contamination
Ground-water flow velocity is important in
is detected, consider expanding the original
establishing an appropriate ground-water
9-13
Ensuring Long-Term Protection—Monitoring Performance
9-14
Ensuring Long-Term Protection—Monitoring Performance
Table 2
Potential Parameters for Basic Ground-Water Monitoring
(Potential Parameters Should be Selected Based on Site-Specific Circumstances)
Minor and Trace Inorganics Initial background sampling of inorganics for which drink-
ing water standards exist (arsenic, barium, cadmium,
chromium, lead, mercury, selenium, silver); ongoing moni-
toring of any constituents showing background near or
above drinking water standards.
9-15
Ensuring Long-Term Protection—Monitoring Performance
Sampling Parameters Metal and organic scans, use of indicators, leachate analysis,
and/or knowledge of the waste. See the categories listed in
Table 2.
mobile contaminant such as cyanide over a can range in thickness from several feet to
permeable sand and gravel aquifer. hundreds of feet. Vadose-zone monitoring
can detect migration of contaminants before
they reach ground water, serving as an early
2. Sampling Parameters
warning system if a waste management unit
The basic recommended ground-water is not functioning as designed. It can also
monitoring program already recommends the reduce the time and cost of remediation, and
use of a parameter list that is tailored to the the extent of subsequent ground-water moni-
waste characteristics and site hydrogeology. toring efforts.
Where the use of the IWEM software indi-
cates no liner is appropriate, it might be pos- If site conditions permit, it might be desir-
sible to reduce the list of parameters able to include vadose-zone monitoring as
routinely analyzed in downgradient wells to part of the overall ground-water program. If
only a few indicator parameters. More com- vadose-zone monitoring is incorporated, the
plete analysis would only be initiated if a sig- recommended number of ground-water mon-
nificant change in the concentration of an itoring wells would be determined by the
indicator parameter had occurred. basic ground-water monitoring program, and
background quality would still need to be
characterized with ground-water monitoring.
3. Vadose-Zone Monitoring The ground-water monitoring program
The vadose zone is the region between the becomes a backup, however, with full use
ground surface and the saturated zone. only being initiated if contaminant migration
Depending on climate, soils, and geology, it is detected in the vadose zone. The sections
4
The actual number of both upgradient and downgradient wells will vary from unit-to-unit and will
depend on the actual site-specific conditions.
5
Discussion of EPA’s rationale for the point of monitoring being out to 150 meters from a unit’s bound-
ary can be found in 40 CFR Part 258 criteria.
6
Ground-water flow rate might dictate that more or less frequent monitoring might be appropriate. More
frequent monitoring might be appropriate at the start of a monitoring program to establish background.
Less frequent and/or reduced in scope monitoring might also be appropriate during the post-closure
9-16 care period.
Ensuring Long-Term Protection—Monitoring Performance
9-17
Ensuring Long-Term Protection—Monitoring Performance
Figure 2. Major Methods for In Situ Monitoring of Soil Moisture or Matrix Potential
(a) Three Types of Porous Cup Tensiometers, (b) Resistance Sensors, and (c) Time Domain Reflectometry
Probes
Sources: (a) Morrison, 1983. (b) U.S. EPA, 1993. (c) Topp and Davis, 1985, by permission.
waste management unit, such as carbon draws soil-gas to the surface, and a syringe
dioxide and methane. Of particular concern used to extract the gas sample, as shown in
are gases associated with the breakdown of Figure 4a. Installing soil-gas probes at multi-
organic materials and toxic organic com- ple levels, as shown in Figure 4b, allows
pounds. Permanent soil-gas monitoring detection of downward or upward migration
installations consist of a probe point placed of soil gases. It is important to note, however,
above the water table, a vacuum pump which that the performance of soil-gas sampling can
9-18
Ensuring Long-Term Protection—Monitoring Performance
be limited by some types of soil, such as tight moisture tension, and hydraulic conductivity
clays or tight, saturated clays. should be measured or estimated.
Unsaturated zone numerical modeling pro-
Vadose Zone Characterization grams, such as HYDRUS 2-D or Seep (2-D)
are designed to characterize the vadose zone.
Just as the design of ground-water moni-
toring systems requires an understanding of
the ground-water flow system, the design of Vadose-Zone Monitoring System Design
vadose zone monitoring systems requires an A vadose zone monitoring system com-
understanding of the vadose zone flow sys- bined with a ground-water monitoring sys-
tem. For example, in ground water systems, tem can reduce the cost of corrective
hydraulic conductivity does not change over measures in the event of a release. Remedial
time at a particular-location, whereas in the action is usually easier and less expensive if
vadose zone, hydraulic conductivity changes employed before contaminants reach the
with soil-water content and soil-moisture ten- ground-water flow system.
sion. To estimate the speed with which water
The design and installation of a vadose-zone
will move through the vadose zone, the rela-
monitoring system are easiest with new waste
tionship between soil-water content, soil-
9-19
Ensuring Long-Term Protection—Monitoring Performance
(a) Gas Sampling Probe and Sample Collection Systems, (b) Typical Installation of Nested Soil Gas Probes
Source: Reprinted with permission from Wilson, et al., Handbook of Vadose Zone Characterization and
Monitoring, 1995. Copyright CRC Press, Boca Raton, Florida.
9-20
Ensuring Long-Term Protection—Monitoring Performance
9-21
Ensuring Long-Term Protection—Monitoring Performance
9-22
Ensuring Long-Term Protection—Monitoring Performance
exposure to hazardous conditions, and its resentative of the runoff, samples might need
low risk of human error. Unfortunately, auto- to be taken at a point further upstream of the
matic sampling is not suitable for all con- discharge pipe or at several locations to best
stituent types. Volatile organic compounds characterize site runoff.
(VOC), for example, can not be sampled
Coordinating with the laboratory. It is
automatically due to the agitation during
important to collect adequate sample vol-
sample collection. This agitation can cause
umes to complete all necessary analyses.
the VOC constituents to completely volatilize
When testing for certain constituents, sam-
from the sample. Other constituents such as
ples might need to be cooled or otherwise
fecal streptococcus, fecal coliform, and chlo-
preserved until analyzed to yield meaningful
rine might also not be amenable to automatic
results. Section 3.5 of EPA’s NPDES Storm
sampling due to their short holding times.
Water Sampling Guidance Document (U.S. EPA,
Since sample temperature and pH need to be
1992) contains information on proper sample
measured immediately, the option for using
handling and preservation procedures.
automatic sampling for these parameters is
Submitting the proper information to the lab-
limited as well. Automatic sampling can also
oratory is important in ensuring proper sam-
be expensive, and does require a certain
ple handling by the laboratory. Proper sample
amount of training. Table 4 presents a com-
documentation guidelines are outlined in
parison of manual and automatic sampling
Section 3.7 of the NPDES Storm Water
techniques.
Sampling Guidance Document. Coordination
Sampling at the outfall point. Storm- with the laboratory that will be performing
water samples should be taken at a storm- the analysis will help ensure that these issues
water point source. A “point source” is are adequately addressed.
defined as any discernible, confined, and dis-
You are required to follow all sampling
crete conveyance. The ideal sampling loca-
and monitoring requirements in an NPDES
tion is often the lowest point in a drainage
permit. If there are no sampling require-
area where a conveyance discharges, such as
ments, analyze runoff for basic constituents,
the discharge at the end of a pipe or ditch.
such as oil and grease, pH, biochemical oxy-
The sample point should be easily accessible
gen demand (BOD), chemical oxygen
on foot and in a location that will not cause
demand (COD), total suspended solids
hazardous sampling conditions. You should
(TSS), phosphorus, and nitrogen, as well as
not sample during dangerous wind, light-
any other constituents known or suspected to
ning, flooding, or other unsafe conditions. If
be present in the waste, such as heavy metals
these conditions are unavoidable during an
or other toxic constituents.
event, then the sampling should be delayed
until a less hazardous event occurs. Additional sampling guidance can be
Preferably, the sampling location will be obtained from EPA’s NPDES Storm Water
located onsite, but if it is not, obtain permis- Sampling Guidance Document (U.S. EPA,
sion from the owner of the property where 1992) and Interim Final RCRA Facility
the discharge is located. Inaccessible dis- Investigation (RFI) Guidance: Volume III (U.S.
charge points, numerous small point dis- EPA, 1989). In addition, state and local envi-
charges, run-on from other properties, and ronmental agencies also have guidance on
infinite other scenarios can cause logistical appropriate sampling methods.
problems with sampling locations. If the dis- There is a national system that provides
charge is inaccessible or not likely to be rep- permitting information for facilities holding
9-23
Ensuring Long-Term Protection—Monitoring Performance
Table 4
Comparison of Manual and Automatic Sampling Techniques
Automatic Grabs • Minimizes labor requirements • Samples not collected for oil and grease, might
• Low risk of human error not be representative
• Reduced personnel exposure to • Automatic samplers generally cannot properly
unsafe conditions collect samples for VOC analysis
• Sampling can be triggered • Costly if numerous sampling sites require the
remotely or initiated according to purchase of equipment
present conditions • Can require equipment installation and
maintenance; can malfunction
• Can require operator training
• Might not be appropriate for pH and temperature
• Might not be appropriate for parameters with
short holding times (e.g., fecal streptococcus,
fecal coliform, chlorine)
• Cross-contamination of aliquot if tubing/bottles
not washed
Automatic Flow- • Minimizes labor requirements • Generally not acceptable for VOC sampling
Weighted • Low risk of human error • Costly if numerous sampling sites require the
Composites • Reduced personnel exposure to purchase of equipment
unsafe conditions • Can require equipment installation and
• Can eliminate the need for maintenance; can malfunction
manual compositing of aliquots • Can require operator training
• Sampling can be triggered remotely • Can require that flow measures be taken during
or initiated according to onsite sampling
conditions • Cross-contamination of aliquot if tubing/bottles
not washed
9-24
Ensuring Long-Term Protection—Monitoring Performance
NPDES permits. This system is called the issued by the local control authority might
Permits Compliance System (PCS) and it require more frequent monitoring (see 40
allows users to retrieve information regarding CFR Section 403.12 (g) and (h)). The local
facilities holding NPDES permits, including municipality will develop and implement
permit limits and actual monitoring data. You standard operating procedures and policies
can specify the desired information by using that specify the sample collection and han-
any combination of facility name, geographic dling protocols in accordance with 40 CFR
location, standard industrial classification Part 136.
(SIC) code, and chemical names. The PCS
Sampling for constituents such as pH,
database can be accessed at <www.epa.gov/
cyanide, oil and grease, flashpoint, and VOCs
enviro/html/water.html#PCS>.
will require manual collection of grab sam-
ples (see 40 CFR Section 403.12 (b)(5)).
B. Monitoring Discharges Similar to composite samples, grab samples
must be representative (see 40 CFR Section
to POTWs 403.12 (g)(4)) of the discharge and must be
As discussed in the Chapter 6–Protecting collected from actively flowing waste streams.
Surface Water, industrial facilities discharging Fluctuations in flow or the nature of the dis-
to a POTW might have to meet “pretreatment charge might require collection and hand-
standards.” If so,, they will be subject to cer- compositing of more than one grab sample to
tain requirements under a local pretreatment accurately access compliance. Flow-weighted
program. The National Pretreatment Program composite samples are preferred over time-
requires certain POTWs in defined circum- weighted composite samples, particularly
stances to develop a local pretreatment pro- where the monitored discharge is intermittent
gram (see 40 CFR Section 403.8(a)). The or variable. The local authorities can waive
actual requirement for a POTW to develop flow-weighted composite sampling if an
and implement a local program is a condition industrial user demonstrates that flow-
of the POTW’s NPDES permit. weighted sampling is not feasible. In these
Sampling is the most common method for cases, time-weighted composite samples can
verifying compliance with pretreatment stan- be collected (see 40 CFR Section 403.12
dards. Monitoring locations are usually desig- (b)(5)(iii)). Refer to EPA’s Industrial User
nated by the local municipality administering Inspection and Sampling Manual for POTWs
the pretreatment program and will be such (U.S. EPA, 1994a) for additional information
that compliance with permitted discharge on sample collection and analysis procedures
limits can be determined. Monitoring loca- for the pretreatment program.
tions should be appropriate for waste stream If you are subject to pretreatment require-
conditions, be representative of the discharge, ments and must conduct sampling to demon-
have no bypass capabilities, and allow for strate compliance, the requirements
unrestricted access at all times (see 40 CFR established for your site by the local control
Section 403.12). authority apply. These include following the
EPA’s General Pretreatment Regulations proper sample collection and handling proto-
require POTWs to monitor each significant cols and being able to prove that you did so
industrial user (SIU) at least annually (see 40 (i.e., by keeping sampling records; noting
CFR Section 403.8 (f)(2)(v)) and each SIU to location, date, and time of sample collection;
self-monitor semi-annually, although permits maintaining chain of custody forms showing
the link between field personnel and the lab-
9-25
Ensuring Long-Term Protection—Monitoring Performance
oratory) (see 40 CFR Section 403.12(o)). seasonal basis (e.g., during periods of intense
Consult EPA’s Introduction to the National rainfall); or on an emergency basis (i.e., an
Pretreatment Program document (U.S. EPA, accidental spill or discharge).
1999) for further information on monitoring
requirements under the National Why is the monitoring taking
Pretreatment Program. place?
You should first determine the purpose of
C. Monitoring Surface establishing a surface-water monitoring pro-
Water Conditions gram. Reasons for monitoring surface water
can include developing baseline characteriza-
In order to determine if runoff from your
tion data prior to a waste management unit
waste management unit is impacting adjacent
being constructed, documenting water quali-
surface waters you might want to consider
ty changes over time, screening for potential
establishing a surface-water quality monitor-
water quality problems, determining the
ing program. Chemical, physical, and biolog-
effectiveness of BMPs, or determining the
ical data can provide information about the
impact of the waste management unit on sur-
effectiveness of BMPs. The data collected will
face waters.
help you to characterize any overall water
quality at the selected monitoring sites, iden- How will the data be used?
tify problem areas, and document any
changes in water quality. The data collected will help you to identify
constituents of concern, the impacts of pollu-
In designing your program, one of the tion and pollution control activities (i.e.,
most important things to consider is what BMPs), and trends in water quality. Note that
types of parameters to monitor (chemical, the data you collect might also be useful to
physical, and/or biological) that will enable regional or local water quality planning
you to determine how your waste manage- offices that might already be collecting simi-
ment unit might be impacting the aquatic lar data in other parts of the watershed.
ecosystem. Determining where you should
set-up a monitoring station is also very What parameters or conditions
important and will depend on relevant
hydrologic, geologic, and meteorologic fac- will be monitored?
tors. For assistance and more information on The basic parameters that are indicators of
establishing water quality sampling stations general water quality health, include dissolved
and a sampling program you should consult oxygen (DO), pH, total suspended solids
with state and local water quality planning (TSS), nitrogen, hardness, temperature, and
agencies. Additional guidance on establishing phosphorous. In addition, you might choose
sampling and monitoring programs can be to monitor parameters that would indicate
obtained from EPA’s Volunteer Stream whether the designated use (e.g., fisheries,
Monitoring Document (U.S. EPA, 1997) and recreation) of the water body is being met (as
Volunteer Lake Monitoring Document (U.S. discussed in Chapter 6–Protecting Surface
EPA, 1991). Monitoring can be conducted at Water). Further, based on the types of con-
regular sites on a continuous basis (“fixed stituents associated with the waste manage-
station” monitoring); at selected sites on an ment unit, you should also sample for
as needed basis or to answer specific ques- contaminants that would indicate whether
tions (“intensive surveys”); on a temporary or your surface-water protection measures are
9-26
Ensuring Long-Term Protection—Monitoring Performance
functioning properly (e.g., heavy metals, pling methods. EPA’s SW-846 also provides
organics, or other materials associated with the guidance on selecting the appropriate sam-
unit). In many cases, a few surrogate con- pling methods.
stituents can be selected instead of analyzing a
complete spectrum of constituents. For exam- When will the monitoring occur?
ple, lead, zinc, or cadmium are often selected You need to establish how frequently mon-
to indicate pollution by toxic metals. Instead itoring will take place, what time of year is
of analyzing for every possible pathogenic best for sampling, and what time of day is
microorganism, total and fecal coliform bacte- best for sampling. Monitoring at the same
ria analyses are commonly used to indicate time of day and at regular intervals helps
bacterial and viral contamination. Chemical ensure comparability of data over time. In
oxygen demand (COD) and total organic car- general, monthly chemical sampling and
bon (TOC) are used in high-frequency grab twice yearly biological sampling are consid-
sampling programs as indicators of pollution ered adequate to identify water quality
by organics. changes over time. If you are conducting bio-
logical sampling, it should be conducted at
Where should the monitoring
the same time each year because of natural
sites/stations be located? seasonal variations in the aquatic ecosystem.
In order to determine if the waste manage- Note that the frequency of sampling should
ment unit is having an impact on surface be increased during the rainy season as this is
water it is important to determine the quality when contamination from waste management
of the water upstream from the unit as well as units is expected to increase due to storm-
downstream. You should also consider the water runoff.
number of sites to establish how accessible,
How can the quality of the data
safe, and convenient potential sites are. In
addition, it is important to determine if poten- collected be ensured?
tial sites are near tributary inflows, dams, You should develop a quality assurance
bridges, or other structures that might affect plan to ensure that quality assurance and
the sampling results. You should also deter- quality control procedures are implemented
mine if you will establish permanent sampling at all times. In addition, the personnel con-
stations (i.e., structures or buildings) or if the ducting the sampling should be properly
stations will simply be designated points with- trained and consider how to manage the data
in the watershed. after the data have been collected.
What sampling methods should Hydrologic and water quality information
be used? is also collected and published regularly by
EPA and the U.S. Geological Survey (USGS).
You must decide how the samples will be Both agencies have computerized systems for
collected, what sampling equipment will be storing and retrieving information on water
used (e.g., automatic samplers or by hand), quality that are available on the Internet.
what equipment preparation methods are Water quantity and flow data in streams is
necessary (e.g., container sterilization, meter also available from USGS which has offices in
calibration), and what protocols will be fol- every state. USGS also operates two national
lowed. Refer to Part II, Section A of this stream water quality networks, the
chapter for a discussion of determining sam- Hydrologic Benchmark Network (HBN) and
9-27
Ensuring Long-Term Protection—Monitoring Performance
9-28
Ensuring Long-Term Protection—Monitoring Performance
migration before they reach ground water. an inaccurate soil characterization which
Characterizing the soil properties at a land could lead to improper application of waste
application site can also help you determine and failure of the unit to properly assimilate
the application rates that will maximize waste the applied waste.
assimilation.
To obtain site-specific data on actual soil A. Determining the Quality
conditions, the soil should be sampled and
characterized. The number and location of
of Soil
samples necessary for adequate soil character- Soil quality is an assessment of how well
ization is primarily a function of the variabili- soil performs all of its functions, not just how
ty of the soils at a site. If the soil types occur well it assimilates waste. Measuring crop yield,
in simple patterns, a composite sample of nutrient levels, water quality, or any other sin-
each major soil type can provide an accurate gle outcome alone will not give you a com-
picture of the soil characteristics. The depth plete assessment of a soil’s quality. The
to which the soil profile is sampled, and the minerals and microbes in soil are responsible
extent to which each horizon is vertically for filtering, buffering, degrading, immobiliz-
subdivided, will depend on the parameters to ing, and detoxifying organic and inorganic
be analyzed, the vertical variations in soil materials, including those applied to the land
character, and the objectives of the soil sam- and deposited by the atmosphere. Determining
pling program. You should rely on a qualified the quality of a soil is an assessment of how it
soil scientist to perform this characterization. performs all of these functions in addition to
Poorly conducted soil sampling can result in waste assimilation. For assessing soil quality in
relation to land application units, it will be
9-29
Ensuring Long-Term Protection—Monitoring Performance
important for the soil to be able to filter the soil level and mixed to provide a composite
waste constituents and cycle nutrients such as sample for the area. From the mixed cores a
carbon, nitrogen, and phosphorus. composite subsample should be taken and
analyzed. Each grab sample can be analyzed
Measuring soil quality requires the use of
individually, rather than combined, as part of
physical, chemical, and biological indicators,
a composite sample (discussed below), but
which can be assessed by qualitative or quan-
composite samples generally provide reliable
titative techniques. After measurements are
data for soil characterization.
collected, they can be evaluated by looking
for patterns and comparing results to mea- Soil core grab samples can be collected at
surements taken at a different time or field. random or in a grid pattern. Random collec-
For more information, consult the Guidelines tion generally requires the least amount of
for Soil Quality Assessment prepared by the time, but cores must be collected from the
Soil Quality Institute of the Natural entire area to ensure reliable site characteriza-
Resources Conservation Service (formerly the tion. When performed properly, random
U.S. Soil Conservation Service). sampling will provide an accurate assessment
of average soil nutrient and constituent lev-
els. While the preparation required for col-
B. Sampling Location and lecting core samples in a grid pattern can be
Frequency more costly and time consuming, it does
Prior to sampling, divide the land applica- ensure that the entire area is sampled. An
tion unit into uniform areas, then collect rep- advantage of grid sampling is the ability to
resentative samples from each area. These generate detailed nutrient level maps for a
divisions should be based upon soil type, land application unit. This requires analysis
slope, degree of erosion, cropping history, of each individual grab sample from an area,
known crop growth differences, and any rather than compositing samples. Analyzing
other factors that might influence nutrient each individual grab sample is time consum-
levels in the soil. One recommended ing and expensive, but software and comput-
approach is to divide the unit into areas no erized applicators are becoming available that
larger than 20 acres and to collect at least can use these data to tailor nutrient applica-
one sample from each of these areas. tion to soil needs.
Each sample for a designated area consists You should determine baseline conditions
of a predetermined number of soil cores. A by sampling the soil before waste application
soil core is an individual boring at one spot begins. Subsequent sampling will depend on
in the field. The recommended number of land use and any state or local soil monitor-
cores per sample are 15-20 cores for a sur- ing requirements. After waste is applied to
face soil sample and 6-8 cores for a subsur- the land application unit, you should collect
face sample. If using a soil probe, a single and analyze samples at regular intervals, or
core can be separated into its horizontal lay- after a certain number of applications. You
ers to provide samples for each layer being should sample annually, at a minimum, or
analyzed. For example, a single core could be more frequently, if appropriate.
divided into four predefined layers such as The frequency of sampling, the micronu-
surface soil, subsurface soil, and two deep trients, the macronutrients, and the con-
subsurface soil. For a designated area, all the stituents to be analyzed will depend on
individual cores are combined according to site-specific soil, water, plant, and waste
9-30
Ensuring Long-Term Protection—Monitoring Performance
9-31
Ensuring Long-Term Protection—Monitoring Performance
The exact procedure for drying is not criti- Prior to sampling, all containers and
cal as long as contamination is minimized equipment that are to be used for soil collec-
and excessive temperatures are avoided. The tion (i.e., those that will come in contact
recommended drying procedure for routine with the soil being sampled) should be
soil analysis is to dry the samples overnight, rinsed in warm tap water to remove any
using forced air at ambient temperatures. residual soil particles from previous sampling
Supplemental heating can be used, but it is runs. They should then be rinsed with an
recommended that soil samples to be used aluminum chloride solution. Avoid using
for routine analyses not be dried at greater anhydrous aluminum chloride due to its vio-
than 36°C. Microwave drying can alter the lent reaction with water. A four percent
analytical results and should be avoided. hydrogen chloride solution can also be used
if the soil is not to be analyzed for chlorine.
Because soil is defined as having a particle
The containers and equipment should be
size of less than 2 millimeters, this sieve size
rinsed twice in distilled or deionized water
(# 10 mesh) is recommended for routine soil
and allowed to dry prior to use.
testing. Commercial soil grinders and crush-
ers, such as mortar and pestles, hammer- You should obtain professional assistance
mills, or roller-crushers, are typically long from qualified soil scientists and laboratories
and motorized. The amount of coarse frag- to properly interpret the soil-sample results.
ments common in some samples limits the For more information about how to obtain
use of some of these. In general, it is desir- representative soil samples and submit them
able to get most of the sample to less than 2 for analysis, you can consult various federal
mm with the least amount of grinding. If the manuals, such as EPA’s Laboratory Methods
sample is to be analyzed for micronutrients, for Soil and Foliar Analysis in Long-Term
all contact with metal surfaces should be Environmental Monitoring Programs (U.S. EPA,
avoided during crushing and sieving unless it 1995b), or state guides, such as Nebraska’s
has been clearly demonstrated that the metal Guidelines for Soil Sampling (G91-1000-A).
is not a source of contamination. Cross-cont- The following ASTM methods might also
amination between samples can be avoided prove useful when conducting soil sampling:
by minimizing soil-particle carry over on the D-1452 Practice for Soil Investigation and
crushing and sieving apparatus. For Sampling by Auger Borings; D-1586 Test
macronutrient analysis, removal of particles Method for Penetration Test and Split-Barrel
by brushing or jarring should be adequate. If Sampling of Soils; D-1587 Practice for Thin-
micronutrient or trace element analysis is to Walled Tube Sampling of Soils; and D-3550
be performed, a more thorough cleaning of Practice for Ring-Lined Barrel Sampling of Soils.
the apparatus by brushing or wiping between
samples might be required.
The bulk soil sample should be thorough- IV. Air Monitoring
ly homogenized by mixing with a spatula, The development of appropriate air-moni-
stirring rod, or other implement. As much of toring data can be technically complex and
the sample as possible should be loosened resource intensive. The Industrial Waste Air
and mixed together. No segregation of the (IWAIR) Model on the CD ROM version of
sample by aggregate size should be apparent this Guide provides a simple tool that relies
after mixing. You should dip into the center on waste characterization information, rather
of the mixed sample to obtain a subsample than actual air monitoring data, to evaluate
for analysis.
9-32
Ensuring Long-Term Protection—Monitoring Performance
risks from VOC emissions at a unit. The air- source is an immobile unit from which air
modeling tool uses an emissions model to pollutants are released. Examples include
estimate emissions from a waste management incinerators, boilers, industrial furnaces,
unit based on the waste characterization. You landfills, waste piles, surface impoundments,
should review Chapter 5–Protecting Air and other waste management units. The pur-
Quality, and the supporting background doc- pose of source sampling is to obtain as accu-
ument developed for the IWAIR model to rate a sample as possible of the material
understand the limitations of the model and entering the atmosphere. The major reasons
determine whether it is applicable to a specif- for which source testing is required are to
ic unit. If the model is not appropriate for a demonstrate compliance with regulations or
specific site or if it indicates that there is a permit conditions, to collect engineering data
problem with VOC emissions, use an alterna- (e.g., to evaluate the performance of air pol-
tive (emissions) model that is more appropri- lution control equipment), to support perfor-
ate for the site or consider air monitoring to mance guarantees (e.g., checking to confirm
gather more site-specific data. that the air pollution control equipment is
meeting the guaranteed degree of perfor-
mance), and to provide data for air modeling.
A. Types of Air Emissions
Monitoring 2. Ambient Monitoring
There are generally four different types of
The second type of air monitoring involves
air emissions monitoring: source, ambient,
ambient air monitoring at selected locations
fugitive, and indoor. Source, ambient, and
around the waste management unit or site.
fugitive monitoring can provide data for use
The data are used to monitor dispersion of
in emission and dispersion modeling. In
airborne contaminants to the surrounding
addition, the monitoring of meteorological
areas. Ambient testing usually involves
conditions at sites is generally conducted
“fenceline” testing. Typically, the air is moni-
whenever source emissions or ambient moni-
tored at the four fenceline compass points. At
toring is performed, as discussed below. As
least one additional measuring station is
the vast majority of industrial waste manage-
placed either in the predominant upwind (or
ment units are located outdoors, indoor air
downwind) location or in a direct line
quality and monitoring issues typically will
between your site and a neighboring facility
not apply. Consequently, this guide does not
or property. The resulting data should yield
address this issue. For more information on
information concerning the concentration of
indoor air quality and monitoring visit the
ambient emissions leaving your property
Occupational Safety and Health
(minus the emissions from adjacent facilities).
Administration’s (OSHA) Web site at
<www.osha-slc.gov/SLTC/indoorair In many areas of the country, several facili-
quality/index.html>. ties share property boundaries delineated by a
fenceline. Since each facility is regulated
according to total emissions, it is critical that a
1. Emissions Monitoring neighboring facility’s “drifting” emissions be
Stationary-source emissions monitoring qualified and quantified. Depending on the
involves the direct sampling of an air stream neighboring facility’s production rate, the
in a duct, stack, or pipe that is the end source atmospheric conditions, and the seasonal cli-
of an emission release point. A stationary mate, the neighboring facility’s emissions could
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Ensuring Long-Term Protection—Monitoring Performance
impact the operation of your facility. For be preferred. This is a box that isolates a por-
example, many facilities are required to con- tion of the pond to determine volumetric
tinuously monitor downwind fenceline emis- flow. The box acts as a floating stack in which
sion of hydrocarbons. If a neighboring facility’s emissions are captured into a canister for
emissions of hydrocarbons or adjacent freeway analysis. For material transfer operations or
hydrocarbon emissions drift across your fence- vehicular traffic from unpaved roads, it is
line and combine with your own hydrocarbon obviously not practical to use a handheld ana-
emissions, your total facility hydrocarbon lyzer or to “bag” the source (especially some-
emission limit could be violated. thing as large as a waste pile). In such cases of
particulate matter fugitive emissions, a high-
volume ambient PM10 sampling system is
3. Fugitive Monitoring
used, or the emissions are ducted through a
Fugitive testing is a hybrid of ambient and temporary stack for direct measurement using
source testing and generally involves the a sampling train (see Figure 6).
monitoring of either particulate or gaseous
emissions from sources open to the atmos-
phere. It can involve testing sources such as 4. Meteorological Monitoring
valves, flanges, pumps, and similar equipment Another form of air monitoring measures
and hardware for leaks, and it can include meteorological conditions at a site. Site-spe-
quantifying emissions from open drums, open cific meteorological information can be col-
vats, landfills, waste piles, and surface lected for use in air emission and dispersion
impoundments such as lagoons, pits, and set- modeling. This type of monitoring involves
tling ponds. It is typically conducted using measurement of wind speed, wind direction,
one or more of the following techniques: use temperature, etc., and can be performed
of a handheld organic analyzer; “bagging” sus- when other offsite meteorological informa-
pect sources for subsequent analysis; captur- tion might not adequately characterize the
ing and scrubbing fugitive emissions using a weather conditions at the site. Local wind
floating flux chamber/summa canister; or systems are usually quite significant in terms
measuring particulate matter greater than or of the transport and dispersion of air con-
less than 10 microns in diameter (PM10) fol- stituents. Therefore, local meteorological
lowing promulgated EPA test methods. monitoring will most likely be important for
mountainous or hilly terrain (where solar
Selection of the test method depends on
heating and radiational cooling influence
factors such as the type of emissions, source
how wind moves) or for a site near a large
type, temperature, pressure, constituent con-
body of water (where the differential heating
centration, etc. (test methods are discussed
of land and water can result in thermals and
later in this chapter). For example, a plant
subsidence over water). Also, the initial
operator who suspects that a valve is leaking
direction of transport of constituents from
might use a handheld organic analyzer to ver-
their source is determined by the wind
ify the presence of a leak. If the analyzer is
direction at the source.
not able to quantify the concentration of the
leaking gas, then the bagging technique can To make meteorological measurements,
be employed. To determine the amount and three components are typically needed: a
type of organic emissions escaping from a set- detector or sensor, an encoder or digitizer,
tling pond or wastewater treatment tank, a and a data logger. Most detectors are analog,
floating flux chamber/summa canister might providing a continuous output as a function
9-34
Ensuring Long-Term Protection—Monitoring Performance
9-35
Ensuring Long-Term Protection—Monitoring Performance
B. Air Monitoring and for dissolving gases, a filter surface for col-
lecting particles, or a chamber to contain an
Sampling Equipment aliquot of air for analysis. The flow device
measures the volume of air associated with
1. Ambient Air Monitoring the sampling system. Examples of flow
For ambient air monitoring, the principal devices include mass flow meters and
requirement of a sampling system is to obtain rotameters.
a sample that is representative of the atmos-
phere at a particular place and time. The Gaseous Constituents
major components of most sampling systems
Sampling systems for gaseous constituents
are an inlet manifold, an air mover, a collec-
can take several forms and might not neces-
tion medium, and a flow measurement
sarily have all four components as shown in
device. The inlet manifold transports material
Figure 5. The sampling manifold’s only func-
from the ambient atmosphere to the collec-
tion is to transport the gas from the manifold
tion medium, or analytical device, preferably
inlet to the collection medium. The manifold
in an unaltered condition. The inlet opening
must be made of nonreactive material and no
can be designed for a specific purpose. All
condensation should be allowed to occur in
inlets for ambient sampling must be rain-
the sampling manifold. The volume of the
proof. Inlet manifolds are made out of glass,
manifold and the sampling flow rate deter-
Teflon, stainless steel, or other inert materials
mine the time required for the gas to move
and permit the remaining components of the
from the inlet to the collection medium. This
system to be located at a distance from the
residence time can be minimized to decrease
sample manifold inlet. The air mover (i.e.,
the loss of reactive species in the manifold by
pump) provides the force to create a vacuum
keeping the manifold as short as possible.
or lower pressure at the end of the sampling
system. The collection medium for a sam- The collection medium for gases can be
pling system can be a liquid or solid sorbent liquid or solid sorbents, and evacuated flask,
9-36
Ensuring Long-Term Protection—Monitoring Performance
or a cryogenic trap. Each design is an attempt extracting particles from an airstream are fil-
to optimize gas flow rate and collection effi- tration and impaction.7 All sampling tech-
ciency. Higher flow rates permit shorter sam- niques must be concerned with the behavior
pling times. Liquid collection systems take of particles in a moving airstream. Care must
the form of bubblers which are designed to be taken to move the particles through the
maximize the gas-liquid interface. However, manifold to the collection medium in an
excessive flow rates can result in lower collec- unaltered form. Potential problems arise if
tion efficiency. manifold systems are too long or too twisted.
Gravitational settling in the manifold will
Diagram A is typical of many extractive
remove a fraction of the very large particles.
sampling techniques (e.g., SO2 in liquid sor-
Larger particles are also subject to loss by
bents and polynuclear aromatic hydrocarbons
impaction on walls at bends in a manifold.
on solid sorbents). Diagram B is used for
Particles can also be subject to electrostatic
“open-face” filter collection, in which the fil-
forces which will cause them to migrate to
ter is directly exposed to the atmosphere
the walls of nonconducting manifolds. Other
being sampled. Diagram C is an evacuated
potential problems include condensation or
container used to collect an aliquot of air or
agglomeration during transit time in the man-
gas to be transported to the laboratory for
ifold. These constraints require particulate
chemical analysis, (e.g., polished stainless
sampling manifolds to be as short as possible
steel canisters are used to collect ambient
and to have as few bends as possible.
hydrocarbons for air toxic analysis). Diagram
D is the basis for many of the automated con-
tinuous analyzers, which combine the sam- 2. Source Emissions Monitoring
pling and analytical processes in one piece of For source emissions monitoring, the sam-
equipment (e.g., continuous ambient air pling system is tailored to the unique proper-
monitors for SO2, O3, and NOx). ties of the emissions from a particular
process. It is necessary to take into account
Particulate Constituents the specific process, the nature of the control
devices, the peculiarities of the source, and
Sampling for particulate constituents in the
the use of the data obtained. In source moni-
atmosphere involves a different set of parame-
toring, the sample is obtained from a stack
ters from those used for gases. Particles are
that is discharging to the atmosphere using a
inherently larger than the molecules of N2 and
“sampling train”. A typical sample train is
O2 in the surrounding air and behave differ-
shown in Figure 6. The figure shows the min-
ently with increasing diameter. When sam-
imum number of components, but in some
pling for particulate matter in the atmosphere,
systems the components can be combined.
three pieces of information are of particular
Extreme care must be exercised to assure that
interest: the concentration, the size, and the
no leaks occur in the train and that the com-
chemical composition of the particles. Particle
ponents of the train are identical for both cal-
size is important in determining adverse
ibration and sampling. Standard sampling
effects and atmospheric removal processes.
trains are specified for some tests.
The primary approach is to separate the Continuous emission monitors (CEMs) are
particles from a known volume of air and also available to monitor opacity and certain
subject them to weight determination and gaseous emissions.
chemical analysis. The principle methods for
7
Filtration consists of collecting particles on a filter surface by three processes: direct interception, iner-
tial impaction, and diffusion. Filtration attempts to remove a very high percentage of the mass and
number of particles by these processes. Any size classification is done by a preclassifier, such as an
impactor, before the particle stream reaches the surface of the filter 9-37
Ensuring Long-Term Protection—Monitoring Performance
9-38
Ensuring Long-Term Protection—Monitoring Performance
the atmosphere so that adverse effects do not meters above ground (Boubel, p. 192.), in a
occur. Sampling sites should therefore be place where the results are not influenced by a
selected to measure constituent levels close to nearby source such as a roadway. Sampling
or representative of exposed populations of sites might require electrical power and ade-
people, plants, trees, materials, or structures. quate protection (which can be as simple as a
As a result, ambient air monitoring sites are fence). A shelter, such as a small building,
typically located near ground level, about 3 might be necessary. Permanent sampling sites
(when necessary) will require adequate heat-
ing and air conditioning to provide a stable
EPA Test Methods environment for the sampling and monitoring
EPA test methods are available for a equipment.
variety of compounds and parameters,
including but not limited to the follow-
ing examples: V. Sampling and
• Particulate Matter
• Volatile Organic Compounds (VOC)
Analytical
• Sulfur Dioxide
Protocols and
• Nitrogen Oxide Quality
• Visible Emissions Assurance and
• Carbon Monoxide Quality Control
• Hydrogen Sulfide The best designed monitoring program
• Inorganic Lead will not provide useful data in the absence of
sound sampling and analytical protocols.
• Total Fluoride Sampling and analytical protocols are gener-
• Landfill Gas (gas production flow ally contaminant specific. A correctly
rate) designed and implemented sampling and
analysis protocol helps ensure that sampling
• Nonmethane Organic Compounds results accurately represent media quality and
(NMOC) (in landfill gases) can be compared over time. The accurate
• Hydrogen Chloride representation is demonstrated through statis-
tical analysis.
• Gaseous Organic Compounds
Whether or not an established quality
• Polychlorinated Dibenzo-p-dioxins assurance and quality control (QA/QC) pro-
and Polychlorinated Dibenzofurans gram is required on a federal, state, or local
• Stack Gas Velocity and Volumetric level, it is a good management practice to
Flow Rate develop and strictly implement such a plan.
The sampling protocol should incorporate
• Gas Analysis for Carbon Dioxide,
federal, state, and local QA/QC requirements.
Excess Air, and Dry Molecular Weight
Sampling QA/QC procedures detail steps for
• Moisture Content in Stack Gases collection and handling of samples. Sample
collection, preservation, shipment, storage,
9-39
Ensuring Long-Term Protection—Monitoring Performance
and analysis should be performed in accor- • Description of the methods used for
dance with an approved QA/QC program to sampling and analysis.
ensure data of known quality are generated.
• Sampling manifold and instrument
You should rely on qualified professionals configuration.
who are properly trained to conduct sam-
• Appropriate multipoint calibration
pling. Poorly-conducted sampling can give
procedures.
false evidence of a contamination problem or
can miss early warnings of contaminant • Zero/span checks and record of
leaching. Erring in either direction is an adjustments.
avoidable and costly mistake. • Control specification checks and
their frequency.
• Control limits for zero, span, and
other control limits.
• The corrective actions to be taken
when control limits are exceeded.
• Preventative maintenance.
• Recording and validation of data.
• Documentation of quality assurance
activities.
At a minimum, you should include the
States have developed guidance docu-
following in your sampling protocol:
ments addressing sampling plans, protocols,
• Data quality objectives including lists and reports. You should work with the state
of important tracking parameters, to develop an effective sampling protocol.
such as the date and name of sam-
• You should consult with soil special-
ples.
ists at the state and local environ-
• Sample collection procedures, mental/planning offices, your local
including description of sample col- cooperative extension service office,
lection methods, and lists of neces- or the county conservation district
sary field analyses. office before implementing a soil
• Instructions for sample preservation monitoring program for your unit.
and handling. (For more information, visit the
USDA Cooperative State Research,
• Other QA/QC procedures such as Education, and Extension Service
chain-of-custody. Web site at: <www.reeusda.gov/
• The name of the person who con- 1700/statepartners/usa.htm>).
ducted the sampling. These agencies likely will be able to
provide you with maps showing the
Quality control operations are defined by location and extent of soils, data
operational procedures and might contain the about the physical and chemical
following components for an air monitoring properties of soils, and information
program: derived from the soil data about
9-40
Ensuring Long-Term Protection—Monitoring Performance
potentialities and problems of use for tion. The SOURCE also includes con-
the soils in your area. You can also nections to technical material
consult the Natural Resources through an automatic facsimile link
Conservation Service (NRCS) Web and with technical staff during work-
site at <www.wv.nrcs.usda.gov>. ing hours. For more information con-
The NRCS manages the national cerning the EMC, visit EPA’s Web site
cooperative soil survey program at: <www.epa.gov/ttn/emc>.
which is a partnership of federal land
OAQPS also maintains the Support
management agencies, state agricul-
Center for Regulatory Air Models
tural experiment stations, and state
(SCRAM). The SCRAM Web site
and local agencies that provide soil
<www.epa.gov/scram001> is a source
survey information necessary for
of information on various atmospher-
understanding, managing, conserv-
ic dispersion (air quality) models that
ing, and sustaining soil resources.
support regulatory programs required
The NRCS maintains various on-line
by the Clean Air Act. The computer
databases that can help you to char-
code, data, and technical documents
acterize local soil.
provided by SCRAM deal with math-
• You should consult with air modeling ematical modeling for the dispersion
professionals, state and local air qual- of air constituents. Documentation
ity offices, EPA Regional air program and guidance for these computerized
offices, or EPA’s Office of Air Quality models are a major feature of the
Planning and Standards (OAQPS) in Web site.
Research Triangle Park, North
Carolina, before implementing an air
monitoring program for your unit or A. Data Quality Objectives
choosing alternative emission and In any sampling and analysis plan, it is
dispersion models to evaluate risks important to understand the data needs for a
associated with air emissions. For monitoring program. Tailoring sampling proto-
information concerning emission test col and analytical work to data needs ensures
methods, you can contact the cost-efficient sampling. A sampling and analy-
Emission Measurement Center (EMC) sis plan should specify: 1) clear objective, such
within the Office of Air Quality as what data are needed and how the data are
Planning and Standards. The EMC is to be used, 2) target contaminants, and 3)
EPA’s point of contact for providing level of accuracy requirements for data to be
expert technical assistance for EPA, conclusive. Chapter 1 of EPA SW-846 Test
state, and local officials and industrial Methods for Evaluating Solid Waste (U.S. EPA,
representatives involved in emission 1986) and ASTM Guide D5792 provide guid-
testing. The Center has produced ance on developing data quality objectives for
numerous methods of measuring air waste management activities.
constituents emitted from a multitude
of industries. A 24-hour automated
telephone information hotline known B. Sample Collection
as the “SOURCE” at 919 541-0200, Sample collection techniques should be
provides callers with a variety of carefully designed to ensure sampling quality
technical emission testing informa- and avoid cross-contamination or background
9-41
Ensuring Long-Term Protection—Monitoring Performance
9-42
Ensuring Long-Term Protection—Monitoring Performance
Trip Blank
Used for volatile organic com- Trip blanks provide a quality assur- One trip blank for each cooler
pounds (VOCs) only. Trip blanks ance test for detecting contamination used during a sampling episode
are prepared at the analyzing labo- from improper sample container should be prepared for each
ratory and transported to the field (vial) cleaning prior to shipping to volatile organic method to be used
with the empty vials to be used in the field, the use of contaminated in the field. For example, if 2
the VOC field sampling. They con- water in analyzing the samples in volatile organic methods are to be
sist of a sealed vial filled with ana- the laboratory, VOC contamination used over 2 days with samples
lyte-free water (i.e., de-ionized occurring during sample storage or being sent to the lab at the end of
water). The water should be the transport, and any other environ- each day, then a total of 4 trip
same as the water the laboratory mental conditions that could result blanks would be needed (i.e., Day
will use in analyzing the actual in VOC contamination of samples 1: 1 cooler with samples from 2
samples collected in the field, and during the sampling event. methods = 2 trip blanks; Day 2: 1
include any preservatives or addi- cooler with samples from 2
tives that will be used. They are methods = 2 trip blanks; total trip
handled, stored, and transported blanks = 4).
in the exact same manner as the
field samples. Trip blanks should
never be opened in the field.
Field Blank
A sample collected in the field by Field blanks are used to evaluate the One field blank should be
filling a vial with analyte-free water effects of onsite environmental conta- prepared for each parameter being
and all preservatives or additives minants, the purity of the preserva- sampled and analyzed per day, or
that will be added to actual sam- tives and additives used, and general at a rate of 5 percent of the
ples. Field blanks should be pre- sample collecting and container filling. samples in a parameter group per
pared under the exact same day, whichever is larger. For
conditions in the same location as example if 3 parameter groups
actual samples either in the middle were to be sampled over 2 days
or at the end of each sampling then 6 field blanks would be
episode. They also should be han- required (i.e., 3 parameter groups
dled, stored, and transported in x 2 days = 6 field blanks).
the exact same manner as the actu-
al samples.
Equipment Blank
A sample prepared by pouring Equipment blanks are used to deter- At least one equipment blank
analyte-free water through or over mine the effectiveness of the field should be prepared for each piece
a decontaminated piece of sam- cleaning of sampling equipment. of equipment used in sampling
pling equipment. The blank Generally, they are necessary when that must be field cleaned. Each
should be prepared on site. sampling equipment must be time an equipment blank is
Equipment blanks should be han- cleaned in the field and reused for required, a sample should be
dled, stored, and transported in subsequent sampling. prepared for each parameter group
the exact same manner as the actu- being assessed. For example, if
al samples. samples are taken for 3 parameter
groups, and a piece of sampling
equipment requires cleaning then a
total of 3 equipment blanks will be
required for each required cleaning
(i.e., 1 piece of equipment x 3
parameter groups = 3 equipment
blanks per cleaning).
9-43
Ensuring Long-Term Protection—Monitoring Performance
Duplicates
Samples collected simultaneously Duplicate samples are used to assess (No guidance on frequency
from the same source under identi- the precision of sampling techniques provided)
cal conditions (e.g., same type of and laboratory equipment.
sampling techniques and equip-
ment).
Blinds
A sample prepared prior to a sam- Blinds are used to validate the accu- (No guidance on frequency
pling episode by the laboratory or racy and precision of the analyzing provided)
an independent source. The blind laboratories sample analyses.
contains a specific amount of ana-
lyte known by the preparer, but
that is unknown to the analyst at
the time of analysis.
planning and implementation for waste man- program. Most facility managers use commer-
agement activities. Chapter 1 of SW-846 also cial laboratories to conduct analyses of sam-
provides guidance on QA/QC practices. ples; others might use their own internal
laboratories if they are equipped and qualified
to perform such analyses. In selecting an ana-
E. Analytical Protocols lytical laboratory, check for the following: lab-
Monitoring programs should employ ana- oratory certification by a state or professional
lytical methods that accurately measure the association for the type of analyses needed;
constituents being monitored. SW-846 rec- qualified lab personnel; good quality analyti-
ommends specific analytical methods to test cal equipment with back-up instrumentation;
for various constituents. Similarly, individual a laboratory QA/QC program; proper lab doc-
states might recommend other analytical umentation; and adherence to standard proce-
methods for analysis. dures for data handling, reporting, and record
keeping. Laboratory QA/QC programs should
Ensure the reliability and validity of analyt-
describe chain-of-custody procedures, calibra-
ical laboratory data as part of the monitoring
tion procedures and frequency, analytical
9-44
Ensuring Long-Term Protection—Monitoring Performance
standard operating procedures, and data vali- normal or lognormal). Examples of two statis-
dation and reporting procedures. A good tical approaches include inter-well (upgradient
QA/QC program helps ensure the accuracy of vs. downgradient) or intra-well comparisons.
laboratory data. After consulting with the state agency and sta-
tistical professional and selecting a statistical
approach, continue to use the selected
VI. Analysis of method in all statistical analyses. Do not
switch to a different test when the first
Monitoring Data, method generates unfavorable results.
9-45
Ensuring Long-Term Protection—Monitoring Performance
intervals can be used both for com- tions of contamination. Once a statistically
parison of current monitoring data to significant change has been confirmed for
previous data for the same site. one or more of the sampling parameters, you
should determine whether the change was
• Control charts. These charts use his-
caused by factors unrelated to the unit.
torical data for comparison purposes
Factors unrelated to the unit that might cause
and are, therefore, only appropriate
a change in the detected concentration(s) are:
for initially uncontaminated sites.
• Contaminant sources other than the
There are many different ways to select an
waste management unit being moni-
appropriate statistical method. For more
tored.
detailed guidance on statistical methods for
ground-water contaminant detection moni- • Natural variations in the quality of
toring, consult Addendum to Interim Final the media being monitored.
Guidance Document on Statistical Analysis of
• Analytical errors.
Ground-Water Monitoring Data at RCRA
Facilities (U.S. EPA, 1993); Guidance • Statistical errors.
Document on Statistical Analysis of Ground- • Sampling errors.
Water Monitoring Data at RCRA Facilities-
Interim Final Guidance (U.S. EPA, 1989); and If the change was caused by a factor unre-
ASTM provisional guide PS 64- 96 in the lated to the unit, then additional measures
Annual Book of ASTM Standards. might not be necessary and the original mon-
itoring program can be resumed. If, however,
these factors have been ruled out, you should
B. Contingency Planning begin an assessment monitoring program.
Contingency plans identify the procedures You should consult with the state agency to
to follow if a statistically significant change in determine the type of assessment monitoring
one or more constituents has been detected. to conduct at the unit. Assessment monitor-
A contingency plan should include proce- ing typically involves resampling at all sites,
dures to determine whether a change in sam- and analyzing the samples for a larger list of
ple concentrations was caused by the waste parameters than used during the basic moni-
management unit or by unrelated factors; toring program. More than one sampling
procedures for developing and conducting an event might be necessary and additional
assessment monitoring program; procedures monitoring might need to be performed to
for remediating the waste management unit adequately determine the scope or extent of
to stop the release of contaminants; and a any contamination. It is recommended that
determination of the magnitude of contami- you work with state officials to establish
nation that would require initiation of correc- background concentrations and protection
tive action, such as a statistical exceedance of standards for all additional constituents that
an HBN, an MCL for surface or ground were detected during assessment monitoring.
water, or a site-specific risk-based number. If assessment monitoring results indicate
there is not a statistically significant change
in the concentrations of one or more of the
C. Assessment Monitoring constituents over the established protection
The purpose of assessment monitoring is standards, then you can resume the original
to evaluate the rate, extent, and concentra- monitoring program. If, however, there is a
9-46
Ensuring Long-Term Protection—Monitoring Performance
9-47
Ensuring Long-Term Protection—Monitoring Performance
Ground Water
■ Perform a site characterization, including investigation of the site’s geology, hydrology, and subsur-
face hydrogeology to determine areas for ground-water monitoring; select parameters to be moni-
tored based on the characteristics of the waste managed.
■ Identify qualified engineers and ground-water specialists to assist in designing and operating the
ground-water monitoring program.
■ Consult with qualified professionals to identify necessary program components including the mon-
itoring well design, the number of monitoring wells, the lateral and vertical placement of the wells,
the duration and frequency of monitoring, and the appropriate sampling parameters.
■ Determine the appropriate method(s) of ground-water monitoring, including conventional well
monitoring, direct push sampling, geophysical monitoring, and vadose zone monitoring as possi-
bilities.
■ Use qualified laboratories to analyze samples.
Surface Water
■ Collect and analyze samples according to the requirements of a site’s federal or state storm-water
permit.
■ If not subject to permit requirements, implement a storm-water sampling program to monitor the
quality of runoff and determine the effectiveness of BMPs.
■ If applicable, collect and analyze discharges to POTWs according to any requirements of a local
pretreatment program.
■ Implement a surface-water sampling program to monitor water quality and determine the effec-
tiveness of BMPs.
■ Perform regular inspections and maintenance of surface-water protection measures and BMPs to
reduce the potential for surface-water contamination.
■ Use qualified laboratories to analyze samples.
Soil Monitoring
■ Determine the number and location of samples needed to adequately characterize soil according to
the variability of the soil at a site.
■ Follow established soil-sampling procedures to obtain meaningful results.
■ Use qualified laboratories to analyze samples.
9-48
Ensuring Long-Term Protection—Monitoring Performance
Air Monitoring
■ Use the Industrial Waste Air (IWAIR) Model to evaluate risks from VOC emissions.
■ Use an alternative emissions model if the IWAIR Model indicates a problem with VOC emission or
is not appropriate for your site.
■ If collecting air monitoring data, determine the type of monitoring necessary to evaluate the effec-
tiveness of air pollution control techniques employed on site or for input into air emissions and
dispersion models.
■ Select the proper test methods.
■ Establish guidelines to ensure the quality of the data collected prior to implementing an air moni-
toring program.
■ Consult with air modeling professionals, state and local air quality offices, EPA regional air pro-
gram offices, or EPA’s Office of Air Quality Planning and Standards before implementing an air
monitoring program or choosing an alternative emission model to evaluate risks.
■ Use qualified laboratories to analyze samples.
9-49
Ensuring Long-Term Protection—Monitoring Performance
Resources
Site Characterization
American Society for Testing and Materials. 2001. Annual Book of ASTM Standards. ASTM.
American Society for Testing and Materials. 1994. ASTM Standards on Ground Water and Vadose Zone
Investigations, 2nd Edition. ASTM.
ASTM D-1452. 1980. Practice for Soil Investigation and Sampling by Auger Borings.
ASTM D-1586. 1984. Test Method for Penetration Test and Split-Barrel Sampling of Soils
ASTM D-4220. 1989. Practices for Preserving and Transporting Soil Samples.
ASTM D-5792. 1995. Standard Practice for Generation of Environmental Data Related to Waste Management
Activities: Development of Data Quality Objectives.
Boulding, J.R. 1995. Practical Handbook of Soil, Vadose Zone, and Ground Water Contamination:
Assessment, Prevention and Remediation. Lewis Publishers.
CCME. 1994. Subsurface Assessment Handbook for Contaminated Sites, CCME EPC-NCSRP-48E, Canadian
Council of Ministers of the Environment.
Sara, M.N. 1994. Standard Handbook for Solid and Hazardous Waste Facility Assessments. Lewis Publishers.
Topp, G.C. and J.L. Davis. 1985. “Measurement of Soil Water Using Time-Domain Reflectometry (TDR): A
Field Evaluation,” Soil Science Society of America Journal. 49:19-24.
U.S. EPA. 1993. Subsurface Characterization and Monitoring Techniques: A Desk Reference Guide. Volume I:
Solids and Ground Water, Appendices A and B. EPA625-R-93-003a.
U.S. EPA. 1993. Subsurface Characterization and Monitoring Techniques: A Desk Reference Guide. Volume II:
The Vadose Zone, Field Screening and Analytical Methods, Appendices C and D. EPA625- R-93-003b.
9-50
Ensuring Long-Term Protection—Monitoring Performance
Resources (cont.)
U.S. EPA. 1988. Criteria for Municipal Solid Waste Landfills: Draft background Document. EPA530- SW-
88-042.
U.S. EPA. 1987. DRASTIC: A Standardized System for Evaluating Ground Water Pollution Potential Using
Hydrogeologic Settings. EPA600-2-87-035.
Wilson, L.G., L.G. Everett, and S.J. Cullen (eds.). 1995. Handbook of Vadose Zone Characterization and
Monitoring. Lewis Publishers.
Cullen, S.J., J.K. Kramer, and J.R. Luellen. 1995. A Systematic Approach to Designing a Multiphase
Unsaturated Zone Monitoring Network. Ground Water Monitoring Review 15(3):124-135.
Geoprobe Systems. 1996. Geoprobe Prepacked Screen Monitoring Well: Standard Operating Procedure.
Technical Bulletin No. 96-2000.
Hayes, J.P. and D.C. Tight. 1995. Applying Electrical Resistance Blocks for Unsaturated Zone Monitoring at
Arid Sites. Handbook of Vadose Zone Characterization and Monitoring. L.G. Wilson, L.G. Everett, and S.J.
Cullen (eds.). Lewis Publishers. pp. 387-399.
Kramer, J.H., S.J. Cullen, and L.G. Everett. 1992. Vadose Zone Monitoring with the Neutron Moisture
Probe. Ground Water Monitoring Review 12(3):177-187.
Ohio Environmental Protection Agency. 1995. Technical Guidance Manual for Hydrogeologic
Investigations and Ground Water Monitoring.
Robbins, G.A. and M.M. Gemmell. 1985. Factors Requiring Resolution in Installing Vadose Zone
Monitoring Systems. Ground Water Monitoring Review 5:76-80.
U.S. EPA. 1993b. Solid Waste Disposal Facility Criteria: Technical Manual. Chapter 5. EPA530-R-93- 017.
U.S. EPA. 1991. Handbook: Ground Water. Volume II: Methodology. EPA625-6-90-016b.
9-51
Ensuring Long-Term Protection—Monitoring Performance
Resources (cont.)
U.S. EPA. 1990. Handbook: Ground Water. Volume I: Ground Water and Contamination.
EPA625-6-90- 016a.
U.S. EPA. 1989. Handbook of Suggested Practices for the Design and Installation of Ground-
Water Monitoring Wells. EPA600-4-89-034.
Sample Procedures
ASTM. D-5283. 1997. Standard Practice for Generation of Environmental Data Related to Waste
Management Activities: Quality Assurance and Quality Control Planning and Implementation.
Benson, R.C., R.A. Glaccum, and M.R. Noel. 1984. Geophysical Techniques for Sensing Buried
Wastes and Waste Migration. EPA600-7-84-064.
Bond, W.R. 1995. Case Studies of Vadose Zone Monitoring and Sampling Using Porous Suction
Cup Samplers. Handbook of Vadose Zone Characterization and Monitoring. L.G. Wilson, L.G.
Everett, and S.J. Cullen (eds.). Lewis Publishers. pp. 523-532.
Federal Remediation Technologies Roundtable. 2001. Field Sampling and Analysis Technologies
Matrix. Version 1.0. <www.frtr.gov/site>
Gibbons, R.D. 1990. Estimating the Precision of Ground-Water Elevation Data. Ground Water,
28, 357- 360.
Minnesota Pollution Control Agency. 1995. Ground Water Sampling Guidance: Development of
Sampling Plans, Protocols and Reports.
Thomson, K.A. 1995. Case Studies of Soil Gas Sampling. Handbook of Vadose Zone
Characterization and Monitoring. L.G. Wilson, L.G. Everett, and S.J. Cullen (eds.). Lewis
Publishers. pp. 569-588.
U.S. EPA. 1995b. Laboratory Methods for Soil and Foliar Analysis in Long-term Environmental
Monitoring Program. EPA600-R-95-077
9-52
Ensuring Long-Term Protection—Monitoring Performance
Resources (cont.)
U.S. EPA. 1995c. Low Flow Ground-Water Sampling. EPA540-S-95-504.
U.S. EPA. 1994a. Industrial User Inspection and Sampling Manual for POTWs.
U.S. EPA. 1994b. Region VIII Guidance, Standard Operating Procedures for Field Sampling Activities.
U.S. EPA. 1992. NPDES Storm Water Sampling Guidance Document. EPA833-B-92-001.
U.S. EPA. 1991. Description and Sampling of Contaminated Soils: A Field Pocket Guide. EPA625-12-
91-002
U.S. EPA. 1989. Interim Final RCRA Facility Investigation (RFI) Guidance: Volumes I-III. EPA530- SW-
89-031.
U.S. EPA. 1986. Test Methods for Evaluating Solid Waste—Physical/Chemical Methods. EPA SW-846,
3rd edition. PB88-239-233.
Soil Monitoring
Delaware Cooperative Extension Service. 1995. Recommended Soil Testing Procedures for the
Northeastern United States. 2nd Edition. Northeastern Regional Publication No. 493.
North Carolina Cooperative Extension Service. 1994. Soil facts: Careful Soil Sampling - The Key to
Reliable Soil Test Information. AG-439-30.
Soil Quality Institute of the National Resources Conservation Service, USDA. 2001. Guidelines for Soil
Quality Assessment in Conservation Planning. <www.statlab.iastate.edu/survey/SQI/>
9-53
Ensuring Long-Term Protection—Monitoring Performance
Resources (cont.)
University of Nebraska Cooperative Extension Institute of Agriculture and Natural Resources. 1991.
Guidelines for Soil Sampling. G91-1000-A. February. <www.ianr.unl.edu/pubs/soil/g1000.htm>
U.S. EPA. 1995d. Laboratory Methods for Soil and Foliar Analysis in Long-Term Environmental
Monitoring Programs. EPA600-R-95-077.
U.S. EPA. 1989. RCRA Facility Investigation Guidance: Volume II: Soil, Ground Water and Subsurface
Gas Releases. EPA530-SW-89-031
Air Monitoring
Boubel, R. W., D. L. Fox, D. B. Turner, and A. C. Stern. 1994. Fundamentals of Air Pollution. 3rd
Edition. Academic Press.
Stull, Roland B. 1988. An Introduction to Boundary Layer Meteorology. Kluwer Academic Publishers.
Yoest, H. and R. W. Fitzgerald. February 1996. Chemical Engineering Progress. Stationary Source
Testing: The Fundamentals.
U.S. EPA. 1993. Air/Superfund National Technical Guidance Study Series: Compilation of Information
on Real-time Air Monitoring for Use at Superfund Sites. EPA451-R-93-008.
U.S. EPA. 1993. Air/Superfund National Technical Guidance Study Series: Volume 4: Guidance for
Ambient Air Monitoring at Superfund Sites, Revised. EPA451-R-93-007.
U.S. EPA. 1990. Guidance on Applying the Data Quality Objectives Process for Ambient Air Monitoring
Around Superfund Sites (Stages 1 and 2). EPA450-4-90-005.
U.S. EPA. 1990. Air/Superfund National Technical Guidance Study Series: Contingency Plans at
Superfund Sites Using Air Monitoring. EPA450-1-90-005.
U.S. EPA. 1989. Air/Superfund National Technical Guidance Study Series, Volume 4: Procedures for
Dispersion Modeling and Air Monitoring for Superfund Air Pathway Analysis, Interim Report, Final.
EPA450-1-89-004.
U.S. EPA. 1986. Test methods for Evaluating Solid Waste. 3rd Edition. Office of Solid Waste and
Emergency Response. SW-846.
Statistical References
Davis, C.B. and McNichols, R.J. 1987. One-Sided Intervals for at Least p of m Observations from a
Normal Population on Each of r Future Occasions. Technometrics, 29, 359-370.
9-54
Ensuring Long-Term Protection—Monitoring Performance
Resources (cont.)
Gibbons, R.D. 1994. Statistical Methods for Ground-Water Monitoring. John Wiley & Sons.
Gibbons, R.D. 1992. An Overview of Statistical Methods for Ground-Water Detection Monitoring at
Waste Disposal Facilities. In Ground-Water Contamination at Hazardous Waste Sites: Chemical Analysis.
S. Lesge and R.E. Jackson (eds.), New York: Marcel Dekker, Inc.
Gibbons, R.D., Dolan, D., Keough, H., O’Leary, K., and O’Hara, R. 1992. A Comparison of Chemical
Constituents in Leachate from Industrial Hazardous Waste and Municipal Solid Waste Landfills.
Proceedings of the Fifteenth Annual Madison Waste Conference, University of Wisconsin, Madison.
Gibbons, R.D., Gams, N.E., Jarke, F.H., and Stoub, K.P. 1992. Practical Quantitation Limits.
Chemometrics and Intelligent Laboratory Systems, 12, 225-235.
Gibbons, R.D. 1991. Some Additional Nonparametric Prediction Limits for Ground-Water Monitoring at
Waste Disposal Facilities. Ground Water, 29, 729-736.
Gibbons, R.D., Jarke, F.H., and Stoub, K.P. 1991. Detection Limits: For Linear Calibration Curves with
Increasing Variance and Multiple Future Detection Decisions. Waste Testing and Quality Assurance. 3,
ASTM, SPT 1075, 377-390.
Gibbons, R.D. and Baker, J. 1991. The Properties of Various Statistical Prediction Limits. Journal of
Environmental Science and Health. A26-4, 535-553.
Gibbons, R.D. 1991. Statistical Tolerance Limits for Ground-Water Monitoring. Ground Water 29.
Gibbons, R.D. 1990. A General Statistical Procedure for Ground-Water Detection Monitoring at Waste
Disposal Facilities. Ground Water, 28, 235-243.
Gibbons, R.D., Grams, N.E., Jarke, F.H., and Stoub, K.P. 1990. Practical Quantitation Limits.
Proceedings of Sixth Annual U.S. EPA Waste Testing and Quality Assurance Symposium. Vol. 1, 126-
142.
Gibbons, R.D., Jarke, F.H., and Stoub, K.P. 1989. Methods Detection Limits. Proceedings of Fifth Annual
U.S. EPA Waste Testing and Quality Assurance Symposium. Vol. 2, 292-319.
Gibbons, R.D. 1987. Statistical Prediction Intervals for the Evaluation of Ground-Water Quality. Ground
Water, 25, 455-465.
9-55
Ensuring Long-Term Protection—Monitoring Performance
Resources (cont.)
Gibbons, R.D. 1987. Statistical Models for the Analysis of Volatile Organic Compounds in Waste
Disposal Facilities. Ground Water 25, 572-580.
Gilbert, R.O. 1987. Statistical Methods for Environmental Pollution Monitoring. Van Nostrand Reinhold,
New York.
Starks, T.H. 1988. Evaluation of Control Chart Methodologies for RCRA Waste Sites. U.S. EPA Technical
Report CR814342-01-3.
Patil, G.P. and Rao, C.R. eds, Elsevier. 1993. Handbook of Statistics, Vol 12: Environmental Statistics.
U.S. EPA. 1993. Addendum to Interim Final Guidance Document Statistical Analysis of Ground-Water
Monitoring Data at RCRA facilities. EPA530-R-93-003.
U.S. EPA. 1989. Guidance Document on Statistical Analysis of Ground-Water Monitoring Data at RCRA
Facilities–Interim Final Guidance.
9-56
Part V
Ensuring Long-Term Protection
Chapter 10
Taking Corrective Action
Contents
Resources ....................................................................................................................................................10-24
Figures:
Figure 1. Corrective Action Process............................................................................................................10-2
Figure 2. Screening Process for Selecting Appropriate Treatment Technologies ........................................10-17
Tables:
Table 1 Factors To Consider in Conducting a Unit Assessment ..................................................................10-3
Table 2 Chemical Characteristics................................................................................................................10-3
Table 3 Site Characteristics ........................................................................................................................10-4
Table 4 Potential Release Mechanisms for Various Unit Types ....................................................................10-7
Table 5 Examples of Interim Corrective Measures ......................................................................................10-8
Ensuring Long-Term Protection—Taking Corrective Action
E
ffective operation of a waste man-
agement unit involves checking
I. Corrective
the performance of the waste man- Action Process
agement system components. The purpose of a corrective action program
When components are not operat- is to assess the nature and extent of the releas-
ing effectively or when a problem develops, es of waste or constituents from the waste
corrective action might be needed to protect management unit(s); to evaluate unit charac-
human health and the environment. teristics; and to identify, evaluate, and imple-
Corrective action involves identifying expo- ment appropriate corrective measures to
sure pathways of concern, selecting the best protect human health and the environment.
corrective measure to achieve the appropriate The overall goal of any corrective action
cleanup standard, and consulting with state should be to achieve a technically and eco-
and community representatives. nomically feasible cleanup standard at a speci-
fied point on the facility property. For new
This chapter will help address the follow- facilities this point should be on facility prop-
ing questions. erty, no more than 150 meters from the waste
management unit boundary (as established in
• What steps are associated with correc- Chapter 9–Monitoring Performance). Existing
tive action? facilities can either use this same 150 meter
• What information should be collected monitoring point standard or work with their
during investigations? state agencies to determine an alternate set of
acceptable monitoring and cleanup criteria.
• What factors should be considered in Using the ground-water pathway as an exam-
selecting an appropriate corrective mea- ple, the corrective action goal should be to
sure? reduce constituent concentration levels to the
• What is involved in implementing the applicable maximum contaminant levels
selected remedy? (MCLs) or health based numbers at the moni-
10-1
Ensuring Long-Term Protection—Taking Corrective Action
toring point (i.e., for new units, no more than Figure 1 Corrective Action Process
150 meters from the waste management unit).
A corrective action program generally has
the components outlined here and in Figure Unit Assessment
1 (and explained in greater detail below). The
detail required in each of these components
Unit Investigation
varies depending on the unit and its com-
plexity and only those tasks appropriate for
your site should be conducted. We recom- Interim Measures
mend that you coordinate with the state dur-
ing all phases of corrective action.
Corrective Measures
• Perform a unit assessment to locate
Evaluation
the actual or potential source(s) of
the release(s) of contaminants based
on waste management unit monitor-
Corrective Measures
ing information and the use of other
Implementation
existing information.
• Perform a unit investigation to char-
acterize the nature and extent of con-
to ensure that human health and the
tamination from the unit and any
environment are being protected.
contamination that might be migrat-
ing beyond the facility boundary,
identify areas and populations threat- A. Unit Assessment
ened by releases from the unit, and
Often the first activity in the corrective
determine short- and long-term
action process is the unit assessment. A unit
threats of releases from the unit to
assessment identifies potential and actual
human health and the environment.
releases from the unit and makes preliminary
• Identify, evaluate, and implement determinations about release pathways, the
interim measures, if needed. Interim need for corrective action, and interim mea-
measures are short-term actions sures. If appropriate, evaluate the possibility
taken to protect human health and of addressing mul-
the environment while a unit assess- tiple units as the
ment or a unit investigation is being corrective action
performed or before a corrective process proceeds.
measure is selected. Table 1 identifies a
• Identify, evaluate, and implement number of factors
corrective measures to abate the fur- to consider during
ther spread of contaminants, control a unit assessment.
the source of contamination, and to Tables 2 and 3 pre-
remediate releases from the unit. sent some useful
properties and
• Design a program to monitor the parameters that
maintenance and performance of any define chemical
interim or final corrective measures
10-2
Ensuring Long-Term Protection—Taking Corrective Action
Table 1
Factors To Consider in Conducting a Unit Assessment
Table 2
Chemical Characteristics
Property/Parameter Characteristics
Soil sorption parameters Cation exchange capacity, anion exchange capacity, soil/water
partition coefficient (Kd), octanol/water partition coefficient
(Kow)
10-3
Ensuring Long-Term Protection—Taking Corrective Action
Table 3
Site Characteristics
Parameter/Information Characteristics
Contamination parameters Concentration in soil, water, and subsurface gas; depth and
location of contamination
Additional information on performing unit assessments can be found in RCRA Facility Assessment
Guidance (U.S. EPA, 1986).
and site characteristics that you should consid- tion of the appropriate response action. It is
er when characterizing your site and environ- important to tailor unit investigations to spe-
mental setting. cific conditions and circumstances at the unit
and focus on releases and potential pathways.
A beginning step is to review available site
Although each medium will require specific
information regarding unit characteristics,
data and methodologies to investigate a
waste characteristics, contaminant migration
release, a general strategy for this investigation,
pathways, evidence of release, and exposure
consisting of two elements, can be described
potential. Much of this information should
as follows.
have been gathered in the site assessment (see
Chapter 4–Considering the Site) and waste • Collect and review monitoring data,
characterization phases (see Chapter data which can be gathered from out-
2–Characterizing Waste). Conducting a visual side information sources on parame-
site inspection of the unit will re-affirm avail- ters affecting the release, or new
able information and enable you to note any information such as aerial photogra-
visual evidence of releases. If necessary, per- phy or waste characterization.
form sampling to confirm or disprove suspect-
• Formulate and implement field inves-
ed releases before performing an extensive unit
tigations and sampling and analysis or
investigation.
monitoring procedures designed to
verify suspected releases. Evaluate the
B. Unit Investigation nature, extent, and rate of migration of
verified releases. Refer to Chapter
A unit investigation is conducted after a 9–Monitoring Performance to help
release from the operating unit has been con- design a monitoring program.
firmed. The purpose of the investigation is to
gather enough data to fully characterize the Detailed knowledge of source characteristics
nature, extent, and rate of migration of conta- is valuable in identifying constituents for
minants to determine and support the selec- which to monitor, indicator parameters, and
10-4
Ensuring Long-Term Protection—Taking Corrective Action
10-5
Ensuring Long-Term Protection—Taking Corrective Action
structures. It is important to also address the • The waste’s affinity for soil particles.
potential for the transfer of contaminants in
• The waste’s degradability and its
ground water to other environmental media
decomposition products.
through processes such as discharge to surface
water and volatilization to the atmosphere. • Surface features such as topography,
erosion potential, land-use potential,
Use existing ground-water monitoring infor-
and vegetation.
mation, where it exists, to determine the
nature, extent, and rate of contaminant release • Stratigraphic/hydrologic features such
from the unit(s) to the ground water. as soil profile, particle-size distribution,
Investigation of a suspected release might be hydraulic conductivity, pH, porosity,
terminated based on results from an initial and cation exchange capacity.
monitoring phase if these results show that an • Meteorological factors such as temper-
actual release has not, in fact, occurred. If, ature, precipitation, runoff, and evap-
however, contamination is found, you should otranspiration.
characterize the release through subsequent
monitoring to help determine the detailed con- Relevant physical and chemical properties of
stituent composition and concentrations, the the soil should be assessed to help determine
horizontal and vertical extent of the contami- potential mobility of any contaminants in the
nant release, as well as its rate of migration as soil. Also, consider the potential for transfer of
appropriate to assess the risk. This should be contaminants in the soil to other environmental
accomplished through direct sampling and media such as overland runoff to surface water,
analysis and, when appropriate, can be supple- leaching to ground water, and volatilization to
mented by indirect means such as geophysical the atmosphere. In addition, you should estab-
assessment and fate and transport modeling. lish whether a potential release involved a
point source (localized) or a non-point source.
Point sources might include container handling
2. Specific Considerations for Soil and storage areas, tanks, waste piles, and bulk
Investigations chemical transfer areas. Non-point sources
When performing soil investigations, con- might include airborne particulate contamina-
sider the following parameters: tion originating from a land application unit
and widespread leachate seeps from a landfill.
• Ability of the waste to be dissolved by Table 4 presents important mechanisms of con-
infiltrating precipitation. taminant release to soils for various unit types.
This information can be used to identify areas
for initial soil monitoring.
10-6
Ensuring Long-Term Protection—Taking Corrective Action
Table 4
Potential Release Mechanisms for Various Unit Types
Landfill Migration of releases outside the unit’s runoff collection and containment
system
Waste pile Migration of releases outside the unit’s runoff collection and containment
system
• The nature of the source area, such as environmental media such as soil contamina-
point or non-point. tion as a result of flooding of a contaminated
creek on the facility property.
• Waste type and degradability.
During the initial investigation, particular
• Local climate.
attention should be given to sampling runoff
• Hydrologic factors such as stream from contaminated areas, leachate seeps, and
flow conditions. other similar sources of surface-water contami-
• The ability for a contaminant to accu- nation, as these are the primary overland release
mulate in stream bottom sediments. pathways for surface water. Releases to surface
water via ground-water discharge should be
Also, address the potential for the transfer addressed as part of the ground-water investiga-
of contaminants in surface water to other tion for greater efficiency. See Chapter
9–Monitoring Performance, Section II: Surface-
Water Monitoring for information on proper
surface-water monitoring techniques.
10-7
Ensuring Long-Term Protection—Taking Corrective Action
sion modeling to estimate unit-specific emis- might involve a unit in an isolated location,
sion rates, air monitoring to determine con- where an acceptable modeling or monitoring
centrations at a nearby receptor, emission database indicates that the air release can be
monitoring at the source to determine emis- considered insignificant and, therefore, fur-
sion rates, and dispersion modeling to esti- ther studies are not warranted. In many
mate concentrations at a nearby receptor. See cases, however, further release characteriza-
Chapter 9–Monitoring Performance, Section tion might be necessary.
IV: Air Monitoring for more information on
air monitoring and Chapter 5–Protecting Air
for more information on air modeling. C. Interim Measures
As in other media-specific investigations, Many cleanup programs recognize the
the first step is to collect, review, and evaluate need for interim measures while site charac-
available waste, unit, environmental setting, terization is underway or before a final reme-
and release data. Evaluation of these data can dy is selected. Typically, interim measures are
indicate the need for corrective measures or used to control or abate ongoing risks before
that no further action is required. For exam- final remedy selection. Examples of interim
ple, the source might involve a large, active measures for various types of waste manage-
storage surface impoundment containing ment units and various release types are list-
volatile constituents adjacent to residential ed in Table 5. More information is available
housing. Action, therefore, instead of further through the RCRA Corrective Action Interim
studies, might be appropriate. Another case Measures Guidance—Interim Final (U.S. EPA,
Table 5
Examples of Interim Corrective Measures
10-8
Ensuring Long-Term Protection—Taking Corrective Action
Table 5
Examples of Interim Corrective Measures (cont.)
10-9
Ensuring Long-Term Protection—Taking Corrective Action
10-10
Ensuring Long-Term Protection—Taking Corrective Action
10-11
Ensuring Long-Term Protection—Taking Corrective Action
receptors and exposure scenarios based on measures of the fate and transport of contam-
current and projected reasonable land use inants. Where simplified, site-specific mea-
scenarios, and appropriate response actions. sures of the fate and transport are used in the
Site conditions should also be compared to Tier 2 evaluation, much more sophisticated
relevant ecological screening criteria (RESC) models and data will be used in this Tier.
applicable to the site which might include These models might rely on probabilistic
qualitative or quantitative benchmarks, com- approaches and on alternative toxicity and
parison of site conditions to local biological biodegradability data.
and environmental conditions, or considera-
tions related to the exposed habitat areas.
2. Evaluating Treatment
Technologies
RBCA Tier 2 Evaluation
In nearly every phase of the corrective
The user might decide to conduct a Tier 2 action process, some information about treat-
evaluation after selecting and implementing ment technologies is important. Many docu-
the appropriate initial response action to the ments exist that describe candidate
Tier 1 evaluation. The purpose of this tier is technologies in detail and give their respec-
to determine site-specific target levels (SSTLs) tive applicability and limitations. Below are
and appropriate points of compliance when it descriptions and examples of the three major
is determined that Tier 1 RBSLs have been technology categories: containment, extrac-
exceeded. While a Tier 2 evaluation is based tion, and treatment.
on similar screening levels as those used in
the Tier 1 evaluation, some of the generic Containment technologies are used to stop
assumptions used in the earlier evaluation are the further spread or migration of contami-
replaced with site-specific measurements to nants. Some examples of common contain-
develop the SSTLs. The intent of Tier 2 is to ment techniques for constituents in
incorporate the concept that measured levels land-based units include waste stabilization,
of contamination can decline over the dis- solidification, and capping. Capping and
tance from source to receptor. Thus, simple other surface-water diversion techniques, for
environmental fate and transport modeling is instance, can control infiltration of rainwater
used to predict attenuation over that distance. to the contaminated medium. Typical ways to
If site-specific contaminant concentrations are contain contaminated ground-water plumes
above the SSTLs, corrective action is needed include ground-water pumping, subsurface
and further analysis might be required. drains, and barrier or slurry walls. These
ground-water containment technologies con-
trol the migration of contaminants in the
RBCA Tier 3 Evaluation ground-water plume and prevent further dis-
A Tier 3 evaluation involves the same steps solution of contaminants by water entering
as those taken during the Tier 1 and Tier 2 the unit.
evaluations, except that a significant increase
in effort is employed to better define the • Ground-water pumping. Ground-
scope of the contamination. Actual levels of water pumping can be used to
contamination are compared to SSTLs that manipulate and manage ground
are developed for this Tier. The Tier 3 SSTLs water for the purpose of removing,
differ from Tier 2 SSTLs in the level of diverting, and containing a contami-
sophistication used to develop site-specific nated plume or for adjusting ground-
10-12
Ensuring Long-Term Protection—Taking Corrective Action
10-13
Ensuring Long-Term Protection—Taking Corrective Action
10-14
Ensuring Long-Term Protection—Taking Corrective Action
10-15
Ensuring Long-Term Protection—Taking Corrective Action
10-16
Ensuring Long-Term Protection—Taking Corrective Action
10-17
Ensuring Long-Term Protection—Taking Corrective Action
10-18
Ensuring Long-Term Protection—Taking Corrective Action
They are meant to serve as primary reference cient conditions at a waste management unit
sources, and they contain information on site should be quantified in terms of anticipated
background and setting, contaminants and effectiveness according to current and future
media treated, technology, cost and perfor- conditions. This evaluation should determine
mance, and points of contact for the technol- what is technically and financially practicable.
ogy application. Health considerations and the potential for
unacceptable exposure(s) to both workers
EPA has also prepared an overview of
and the public can affect an evaluation.
ground-water cleanup at 28 sites entitled
Groundwater Cleanup: Overview of Operating
Experience at 28 Sites (U.S. EPA, 1999a) that is 5. Evaluating the Ease of
also available from CLU-IN. This overview Implementation
presents a range of the types of cleanups typi-
The ease of implementing the proposed
cally performed at sites with contaminated
corrective measure will affect its schedule. To
ground water and summarizes information
evaluate the ease of implementation of a spe-
about the remediation systems at the 28 sites.
cific corrective measure, it is important to
Summarized information includes design,
operation, and performance of the systems;
capital, operating, and unit costs of the sys- Selecting a Corrective
tems; and factors that potentially affect the cost Action Specialist
and performance of the systems.
Once it has been determined that cor-
EPA’s TIO Web site <www.epa.gov/tio> rective measures are necessary, you should
provides additional information about site determine if in-house expertise is adequate
characterization and treatment technologies or if an outside consultant is necessary.
for remediation. This Web site offers technol-
ogy selection tools and describes programs, If a consultant is needed, determine if
organizations, and available publications. the prospective consultant has the tech-
Some of the available publications include nical competence to do the work need-
Abstracts of Remediation Case Studies, Volumes ed. A poor design for a recovery system,
1-4 (U.S. EPA, 2000a) which summarize 218 unacceptable field procedures, lack of
case studies of site remediation prepared by familiarity with state requirements, or an
federal agencies. Many of these publications inadequate investigation might unneces-
and links are also available through CLU-IN. sarily cost thousands of dollars and still
not complete the cleanup.
10-19
Ensuring Long-Term Protection—Taking Corrective Action
consider the availability of technical expertise any identified contamination and proposed
and equipment, the ability to properly man- remedies. You also should identify any public
age, dispose, or treat wastes generated by the concerns that have been expressed, via writ-
corrective measure, and the likelihood of ten public comments or from public meet-
obtaining local permits and public accep- ings, about the facility’s contamination and
tance for the remedy. Consider also the should address these concerns by the correc-
potential for contamination to transfer from tive measures being evaluated. The best reme-
one media to another as part of the overall dy selected and implemented will be the one
feasibility of the remedy. Cross-media that is agreed upon by the state or local regu-
impacts should be addressed as part of the latory agency, the public, and the facility
implementation phase. Develop a corrective- owner. Review Chapter 1–Understanding Risk
measure schedule identifying the beginning and Building Partnerships before selecting any
and end periods of the permitting, construc- final remedies.
tion, treatment, and source control measures.
E. Implementing
6. Measuring the Degree to
Corrective Measures
Which Community Concerns
The implementation of corrective mea-
are Met sures encompasses all activities necessary to
Prior to selecting the corrective measure(s), initiate and continue remediation. During the
you should hold a public meeting to discuss evaluation and assessment of the nature and
the results of the corrective action assessment extent of the contamination, you should
and to identify proposed remedies. Consider decide whether no further assessment is nec-
notifying adjacent property owners via mail of essary, whether institutional controls are nec-
essary to protect human health and the
environment, whether monitoring and site
Citizen Guides to maintenance are necessary, and whether no
Treatment Technologies further action and closure are appropriate for
EPA’s Technology Innovation Office the unit.
has developed a series of fact sheets that
explain, in basic terms, the operation
1. Institutional Controls
and application of innovative treatment
technologies for remediating sites. The Institutional controls are those controls
fact sheets address issues associated with that can be utilized by responsible parties
innovative treatment technologies as a and regulatory agencies in remedial programs
whole, bioremediation, chemical dehalo- where, as part of the program, certain levels
genation, in situ soil flushing, natural of contamination will remain on site in the
attenuation, phytoremediation, soil soil or ground water. Institutional controls
vapor extraction and air sparging, soil can also be considered in situations where
washing, solvent extraction, thermal des- there is an immediate threat to human
orption, and the use of treatment walls. health. Institutional controls can vary in both
English and Spanish versions of these form and content. Agencies and landowners
fact sheets can be downloaded from can invoke various authorities and enforce-
CLU-IN <clu-in.org/remed1.cfm>. ment mechanisms, both public and private,
to implement one or more of the controls. A
10-20
Ensuring Long-Term Protection—Taking Corrective Action
state could adopt a statutory mandate, for address uses that might disturb a
example, requiring the use of deed restric- containment cap or any unremediat-
tions as a way of enforcing use restrictions ed soils under the surface or below a
and posting signs. Commonly used institu- building. A prohibition on drinking
tional controls include deed restrictions, use onsite or offsite ground water might
restrictions, access controls, notices, registry also be appropriate. Well restriction
act requirements, transfer act requirements, areas can be a form of institutional
and contractual obligations. Additional infor- control by providing notice of the
mation on institutional controls is available at existence of contaminants in ground
EPA’s Office of Solid Waste and Emergency water and by prohibiting or condi-
Response Web site at <www.epa.gov/ tioning the placement and use of any
oerrpage/superfund/action/ or all wells within an area.
postconstruction/ic.htm>.
• Access controls. Access to any par-
• Deed restrictions. These restrictions, ticular site can be controlled by either
also called restrictive covenants, place fencing and gates, security, or posting
limits on the use and conveyance of or warnings. A state might use the
land. They inform prospective following criteria to determine the
owners/tenants of the environmental appropriate level and means of access
status of the property and ensure long- control: whether the site is located in
term compliance with the institutional a residential or mixed-use neighbor-
controls. Typically, there are four hood; proximity to sensitive land-use
requirements for a promise in a deed areas including day care centers,
restriction: the conveyance of land must playgrounds, and schools; and
be documented in writing; it should whether the site is frequently tra-
precisely reflect the parties’ intentions versed by neighbors.
with respect to the scope and duration
• Notices. Controls of this type gener-
of the restrictions; there should be
ally provide notice of specific location
“privity of estate” so that it can be
of contamination on site and disclose
enforced by states; and the promise
any restrictions on access, use, and
“touches and concerns the land.”
development of part or all of the con-
• Use restrictions. Use restrictions are taminated site to preserve the integri-
usually the heart of what is in a deed ty of the remedial action. Types of
restriction. Use restrictions describe notices include record notice (notices
appropriate and inappropriate uses of on land records), actual notice (direct
the property, in an effort to perpetu- notice of environmental information
ate the benefits of the remedial action to other parties to a land transaction),
and ensure property use that is con- and notice to government authorities.
sistent with the applicable cleanup
• Registry act requirements. Some
standard. Such techniques also pro-
states have registry act programs that
hibit any person from making use of
provide for the maintenance of a reg-
the site in a manner that creates an
istry of hazardous waste disposal sites
unacceptable risk of human or envi-
and the restriction of the use and
ronmental exposure to the residual
transfer of listed sites. When a site
contamination. Use restrictions
appears on the registry, the owner
10-21
Ensuring Long-Term Protection—Taking Corrective Action
must comply with regulatory require- and rights of private parties to freely
ments in regard to use and transfer of negotiate these liabilities. Another
the site. The use of a site listed on avenue is for the landowner or
the registry can not be changed with- responsible party to obligate itself to
out permission from the state agency. the state by contract. The state might
require a contractual commitment
• Transfer act requirements. Some
from the party to provide long-term
states have transfer act programs that
monitoring of the site, use restric-
require full evaluation of all environ-
tions, and the means of continued
mental issues before or after the
funding for remediation.
transfer occurs. It might be that,
within such a program, institutional
controls can be established by way of 2. Monitoring and Site
consent order, administrative order, Maintenance
or some other technique that estab-
In many cases, monitoring might need to
lishes implementation and continued
be conducted to demonstrate the effective-
responsibility for institutional con-
ness of the implemented corrective measures.
trols. A typical transfer act imposes
Consult with your state to determine the
obligations and confers rights on par-
amount of time that monitoring should be
ties to a land transaction arising out
conducted. Some corrective measures, such
of the environmental status of the
as capping, hydraulic control, and other
property to be conveyed. Transfer
physical barriers, can require long-term
acts impose information obligations
maintenance to ensure integrity and contin-
on the seller or lessor of a property.
ued performance. Upon completion and veri-
That party must disclose general
fication of cleanup goals, reinstitute your
information about strict liability for
original or modified ground-water monitor-
clean-up costs as well as property-
ing program if the unit is still in active use.
specific information, such as the
presence of hazardous substances,
permitting requirements and status, 3. No Further Action and Site
releases, and enforcement actions Closure
and variances. When the corrective action goals have
• Contractual obligations. One sys- been achieved, and monitoring and site
tem for ensuring future restrictions maintenance are no longer necessary to
on the use of a site, or the obligation ensure that this condition persists, reinstitute
to remediate a site, is to require pri- your original or modified ground-water mon-
vate parties to restrict use by con- itoring program if the unit is still in active
tract. While this method is often use. It might be necessary, however, to ensure
negotiated among private parties, it is that any selected institutional controls remain
difficult, if not impossible, to institu- in place. Refer to Chapter 11–Performing
tionalize control over the process Closure and Post-Closure Care for additional
without interfering with the abilities information on site closures.
10-22
Ensuring Long-Term Protection—Taking Corrective Action
Consider the following when developing a corrective action program for industrial waste management
units:
■ Locate the source(s) of the release(s) of contaminants and determine the extent of the contamina-
tion.
■ Consult with the state, community representatives, and qualified remedial experts when develop-
ing a corrective action program.
■ Identify and evaluate all potential corrective measures including interim measures.
■ Select and implement corrective measures based on the effectiveness and protectiveness of the
remedy, the ease of implementing the remedy, and the degree that the remedy meets local commu-
nity concerns and all applicable state laws.
■ Design a program to monitor the maintenance and performance of corrective measures to ensure
that human health and the environment are being protected.
10-23
Ensuring Long-Term Protection—Taking Corrective Action
Resources
ASTM. 1997. Standard Provisional Guide for Risk-Based Corrective Action (PS104). February.
ASTM. 1994. Emergency Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites.
May.
Louisiana Department of Environmental Quality. 2000. Risk Evaluation/Corrective Action Program (RECAP)
June.
Texas Natural Resource Conservation Commission (TNRCC). 1999. Texas Risk Reduction Program, Title 30
Texas Administrative Code (TAC) Chapter 350.
Texas Natural Resource Conservation Commission (TNRCC). 1995. TNRCC Technical Guidance: Selecting an
Environmental Consultant/Corrective Action Specialist. February.
U.S. EPA. 2002. Draft Superfund Lead-Contaminated Residential Sites Handbook. OSWER 9285.7-50.
U.S. EPA. 2001a. Development of a Data Evaluation: Decision Support System for Remediation of Subsurface
Contamination. EPA600-R-01-044.
U.S. EPA. 2001b. Development of Recommendations and Methods to Support Assessment of Soil Venting
Performance and Closure. EPA600-R-01-070.
U.S. EPA. 2001c. Evaluation of the Protocol for Natural Attenuation of Chlorinated Solvents: Case Study at
the Twin Cities Army Ammunition Plant. EPA600-R-01-025.
U.S. EPA. 2001d.Handbook of Groundwater Protection and Cleanup Policies for RCRA Corrective Action.
EPA530-R-01-015.
U.S. EPA. 2001e. Multispecies Reactive Tracer Test in a Sand and Gravel Aquifer, Cape Cod, Massachusetts.
Parts I-II. EPA600-R-01-007a-b.
U.S. EPA. 2001f. Summary of the Phytoremediation State of the Science Conference, Boston Massachusetts,
May 1-2, 2000. EPA625-R-01-001a.
U.S. EPA. 2000b. Statistical Estimation and Visualization of Ground-Water Contamination Data. EPA600-R-
00-034.
10-24
Ensuring Long-Term Protection—Taking Corrective Action
Resources (cont.)
U.S. EPA. 1999a. Groundwater Cleanup: Overview of Operating Experience at 28 Sites. EPA542-R-99-
006.
U.S. EPA. 1999b. In Situ Permeable Reactive Barrier for the Treatment of Hexavalent Chromium and
Trichloroethylene in Ground Water: Volume 1 Design and Installation. EPA600-R-99-095a.
U.S. EPA. 1999c. In Situ Permeable Reactive Barrier for the Treatment of Hexavalent Chromium and
Trichloroethylene in Ground Water: Volume 2 Performance Monitoring. EPA600-R-99-095b.
U.S. EPA. 1999d. In Situ Permeable Reactive Barrier for the Treatment of Hexavalent Chromium and
Trichloroethylene in Ground Water: Volume 3 Multicomponent Reactive Transport Modeling. EPA600-R-
99-095c.
U.S. EPA. 1999e. Laser Fluorescence EEM Probe for Cone Penetrometer Pollution Analysis. EPA600-R-99-
041.
U.S. EPA. 1998b. Permeable Reactive Barrier Technologies for Contaminant Remediation. EPA600-R-98-
125.
U.S. EPA. 1998c. Technical Protocol for Evaluating natural Attenuation of Chlorinated Solvents in Ground
Water, EPA600-R-98-128.
U.S. EPA. 1996b. Corrective Action for Releases from Solid Waste Management Units at Hazardous Waste
Management Facilities: Advance Notice of Proposed Rulemaking. Fed. Reg. 61(85): 19,431- 19,464. May 1.
U.S. EPA. 1996c. Pump-and-Treat Ground-Water Remediation: A Guide for Decision-Makers and
Practitioners. EPA625-R-95-005.
10-25
Ensuring Long-Term Protection—Taking Corrective Action
Resources (cont.)
U.S. EPA. 1994c. RCRA Corrective Action Plan. EPA520-R-94-004.
U.S. EPA. 1994d. Soil Vapor Extraction Treatment Technology Resource Guide. EPA542-B-94-007.
U.S. EPA. 1992a. A Guide for Conducting Treatability Studies under CERCLA. EPA540-R-92-071.
U.S. EPA. 1992b. RCRA Corrective Action Stabilization Technologies Proceedings. EPA625-R-92-014.
U.S. EPA. 1991b. Handbook: Stabilization Technologies for RCRA Corrective Action. EPA625-6-91- 026.
U.S. EPA. 1989a. RCRA Facility Investigation Guidance: Volume I: Development of an RFI Work Plan and
General Considerations for RCRA Facility Investigations. PB89-200-299.
U.S. EPA. 1989b. RCRA Facility Investigation Guidance: Volume II: Soil, Ground Water, and Subsurface Gas
Releases. PB89-200-299.
U.S. EPA. 1989c. RCRA Facility Investigation Guidance: Volume III: Air and Surface Water Releases. PB89-
200-299.
U.S. EPA. 1989d. RCRA Facility Investigation Guidance: Volume IV: Case Study Examples. PB89-200-299.
U.S. EPA. 1989e. Seminar Publication: Corrective Action: Technologies and Applications. EPA625-4-89-020.
U.S. EPA. 1989f. Practical Guide for Assessing and Remediating Contaminated Sites: Draft.
U.S. EPA. 1988a. Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA.
Interim Final. EPA540-G-89-004.
U.S. EPA. 1988b. RCRA Corrective Action Interim Measures Guidance - Interim Final. EPA530-SW-88-029.
10-26
Part V
Ensuring Long-Term Protection
Chapter 11
Performing Closure and Post-Closure Care
Contents
I. Closure Plans ........................................................................................................................................11- 1
Resources ..................................................................................................................................................11- 35
Tables:
Table 1: Types of Layers in Final Cover Systems........................................................................................11- 9
Table 2: Types of Recommended Final Cover Systems ............................................................................11- 18
Table 3: Example Closure/Post-Closure Cost Estimate Form ..................................................................11- 27
Table 4: Sample Summary Cost Estimating Worksheet ..........................................................................11- 29
Table 5: Estimated Closure and Post-Closure Care Costs ........................................................................11- 31
Figures:
Figure 1: Regional Depth of Frost Penetration in Inches ..........................................................................11 - 6
Figure 2: Drainage Layer Configuration ................................................................................................11 - 11
Contents (cont.)
Figure 3: Geonet with Geotextile Filter Design for Drainage Layer ........................................................11 - 12
Figure 4: Passive Gas Venting System ....................................................................................................11 - 15
Figure 5: Active Gas Venting System ......................................................................................................11 - 15
Figure 6: Example of a Capillary-Break Final Cover System ..................................................................11 - 17
Figure 7: Recommended Final Cover System For a Unit With a Double Liner or a Composite Liner ....11 - 19
Figure 8: Recommended Final Cover System For a Unit With a Single Clay Liner ................................11 - 19
Figure 9: Recommended Final Cover System For a Unit With a Single Clay Liner in an Arid Area ......11 - 20
Figure 10: Recommended Final Cover System For a Unit With a Single Synthetic Liner ......................11 - 20
Figure 11: Recommended Final Cover System For a Unit With a Natural Soil Liner ............................11 - 21
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
T
he overall goal of closure is to
minimize the infiltration of water into a unit
minimize or eliminate potential
by providing maintenance of the final cover.
threats to human health and the
Maintenance should be continued until such
environment and the need for
time as it is determined that care is no longer
future corrective action at the site.
necessary. Also, during post-closure care,
If removing the wastes, containment devices,
closed units should be monitored to verify
and any contaminated subsoils from a unit,
and document that no unacceptable releases
the unit should be returned to an acceptable
are occurring.
risk level so that it is not a current or future
threat. If wastes will be left in place at clo-
sure, the unit should be closed in a manner
that also reduces and controls current or I. Closure Plans
future threats. Steps should also be taken to A well-conceived closure plan is the pri-
avoid future disruptions to final cover sys- mary resource document for the final stage in
tems and monitoring devices. the life of a waste management unit. The pur-
pose of a closure plan is to consider all
This chapter will help address the follow- aspects of the closure scenario. It should be
ing questions. comprehensive so that staff who will imple-
ment it years after its writing will clearly
• How do I develop a closure plan?
understand the activities it specifies. It also
• What factors should I consider when needs to provide enough detail to allow cal-
choosing a closure method? culation of closure and post-closure care costs
• What are the components of a final for determining how much funding needs to
cover? be set aside for those activities.
11-1
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
11-2
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
prior to completing closure. Similarly, other final cover and the proper operation of the gas
site-specific conditions, such as precipitation migration and/or drainage control strategies.
or winter weather, can also cause delay in
If wastes will be removed at closure, the clo-
completing closure. For these situations, you
sure plan should estimate volumes of waste and
should complete closure as soon as feasible.
contaminated subsoil and the extent of contam-
You should also consult with the state agency
inated devices to be removed during closure. It
to determine if any requirements exist for clo-
should further state waste removal procedures,
sure schedules.
establish performance goals, and address any
Even within a waste management unit, state or local requirements for closure by waste
some areas will be closed on different sched- removal. The plan should identify numeric
ules, with certain areas in partial closure, clean-up standards and existing background
while other areas continue to operate. The concentrations of constituents. It also should
schedules and partial closure activities (such discuss the sampling plan for determining the
as intermediate cover) should be considered effectiveness of closure activities. Finally, it
in the closure plan. Although the processes should describe the provisions made for the dis-
for closing such areas might not be different posal of removed wastes and other materials.
than those for closing the unit as a whole, it
The closure plan should also provide a
is still more efficient to integrate partial clo-
detailed description of the monitoring that
sure activities into the closure plan.
will be conducted to assess the unit’s perfor-
If the closure plan calls for the stabiliza- mance throughout the post-closure period.
tion, solidification, or other treatment of These measurements include monitoring
wastes in the unit before the installation of a leachate volume and characteristics to ensure
final cover, the plan should describe those that a cover is minimizing infiltration. It is
activities in detail. Waste stabilization, solidi- important to include appropriate ground-
fication, or other treatment has four goals: water quality standards with which to com-
pare ground-water monitoring reports. You
• Removing liquids, which are ill-suit-
should develop the performance measures
ed to supporting the final cover.
section of the plan prior to completing clo-
• Decreasing the surface area over sure. This section establishes the parameters
which the transfer or escape of conta- that will describe successful closure of the
minants can occur. unit. If limits on these parameters are exceed-
• Limiting the solubility of leachable ed, it will provide an early warning that the
constituents in the waste. final cover system is not functioning as
designed and that measures should be under-
• Reducing toxicity of the waste. taken to identify and correct problems.
For closure strategies that will use engi-
neering controls, such as final covers, the plan
should provide detailed specifications. This
includes descriptions of the cover materials in
II. Selecting a
each layer and their permeability as well as Closure Method
any drainage and/or gas migration control Factors to consider in deciding whether to
measures included in the operation of the perform closure by means of waste removal
final cover. Also the plan should identify mea- or through the use of a final cover include the
sures to verify the continued integrity of the following:
11-3
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
• Feasibility. Is closure by waste This approach is common for landfill units and
removal feasible? For example, if the some surface impoundment units where some
waste volumes are large and underlying waste is left in place. The choice of final cover
soil and ground water are contaminat- materials and design should be the result of a
ed, closure by total waste removal careful review and consideration of all site-spe-
might not be possible. If the unit is cific conditions that will affect the performance
contaminated, consult Chapter of the cover system. If you are not knowledge-
10–Taking Corrective Action to identify able about the engineering properties of cover
activities to address the contamination. materials, you should seek the advice of profes-
In some cases partial removal of the sionals or representatives of state and local
waste might be useful to remove the environmental protection agencies.
source of ground-water contamination.
This section addresses the more important
• Cost-effectiveness. Compare the cost technical issues that should be considered
of removing waste, containment when selecting cover materials and designing a
devices, and contaminated soils, plus cover system. It discusses the various potential
subsequent disposal costs at another components of final cover systems, including
facility, to the cost of installing a final the types of materials that can be used in their
cover and providing post-closure care. design and some of the advantages and disad-
vantages of each. This section also examines
• Long-term protection. Will the final
the interaction between the various compo-
cover control, minimize, or eliminate
nents as they function within the system.
post-closure escape of waste con-
stituents or contaminated runoff to
ground or surface waters to the extent A. Purpose and Goal of
necessary to protect human health and
the environment?
Final Cover Systems
The principal goals of final cover systems
• Availability of alternate site. Is an are to:
alternate site available for final dispos-
al or treatment of removed waste? You • Provide long-term environmental pro-
should consult with the state agency tection of human health and the envi-
to determine whether alternate dispos- ronment by reducing or eliminating
al sites are appropriate. potential risk of contaminant release.
Sections III and V address closure by use of • Minimize infiltration of precipitation
final cover systems and associated post-closure into the waste management unit to
care considerations. Alternatively, Section IV minimize generation of leachates with-
addresses closure by waste removal. in the unit by promoting surface
drainage and maximizing runoff.
• Minimize risk by controlling gas migra-
III. Closure by Use tion (as applicable), and by providing
physical separation between waste and
of Final Cover humans, plants, and animals.
Systems • Minimize long-term maintenance needs.
You might elect to close a waste manage- The final cover should be designed to pro-
ment unit by means of a final cover system. vide long-term protection and minimization of
11-4
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
leachate formation. Final cover systems can How can climate affect a final
be inspected, managed, and repaired to main-
tain long-term protection. For optimal perfor-
cover?
mance, the final cover system should be Freeze and thaw effects can lead to the
designed to minimize infiltration, surface development of microfractures in low perme-
ponding, and the erosion of cover material. ability soil layers. These effects also can cause
To avoid the accumulation of leachate within the realignment of interstitial fines (silts and
a unit, the cover system should be no more clays), thereby increasing the hydraulic con-
permeable than the liner system. For exam- ductivity of the final cover. As a result, you
ple, if a unit’s bottom liner system is com- should determine the maximum depth of
posed of a low-permeability material, such as frost penetration at a site and design covers
compacted clay or a geomembrane, then the accordingly. In other words, barrier layers
cover should also be composed of a low-per- should be below the maximum frost penetra-
meability material unless an evaluation of tion depth. Information regarding the maxi-
site-specific conditions shows an equivalent mum frost penetration depth for a particular
reduction in infiltration. If the cover system is area can be obtained from the Natural
more permeable than the liner, leachate will Resource Conservation Service with the U.S.
accumulate in the unit. This buildup of liq- Department of Agriculture, local utilities,
uids within a unit is often referred to as the construction companies, local universities, or
“bathtub effect.” In addition, since many state agencies. Figure 1 illustrates the regional
units can potentially generate gas, cover sys- depth of frost penetration. You should ensure
tems should be designed to control gas that vegetation layers are thick enough that
migration. Proper quality assurance and qual- low permeability soil layers in the final cover
ity control during construction and installa- are placed below the maximum frost penetra-
tion of the final cover are essential in order to tion depth.
ensure that the final cover performs in accor-
dance with its design. For general informa- How can settlement and subsi-
tion on quality assurance during construction dence affect a final cover?
of the final cover, refer back to the construc-
tion quality assurance section of Chapter 7, When waste decomposes and consolidates,
Section B–Designing and Installing Liners. settlement and subsidence can result.
Recommendations for the type of final cover Excessive settlement and subsidence can sig-
system to use will depend on the type of liner nificantly impair the integrity of the final
and the gas and liquids management strategy cover system by causing ponding of water on
employed in a unit. the surface, fracturing of low permeability
infiltration layers, and failure of geomem-
branes. The degree and rate of waste settle-
B. Technical Considerations ment are difficult to estimate, but they should
for Selecting Cover be considered during design and development
Materials of closure plans. Waste settlement should also
be considered when determining the timing of
Several environmental and engineering con- closure. Steps should be taken to minimize
cerns can affect cover materials and should be the degree of settlement that will occur after
considered in the choice of those materials. the final cover system has been installed.
11-5
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
How can erosion affect the per- • Locally adapted perennial plants that
are resistant to various climatic
formance of a final cover? changes reasonably expected to occur
Erosion can adversely affect the perfor- at the site.
mance of the final cover of a unit by causing • Roots that will not disrupt the low-
rills that require maintenance and repair. permeability layer.
Extreme erosion can lead to the exposure of
the infiltration layer, initiate or contribute to • The ability to thrive in low-nutrient
sliding failures, or expose the waste. soil with minimum nutrient addition.
Anticipated erosion due to surface-water • The ability to survive and function
runoff for a given design criteria can be with little or no maintenance.
approximated using the USDA Universal Soil
Loss Equation1 (U.S. EPA, 1989a). By evaluat- Why are interfacial and internal
ing erosion loss, you might be able to opti-
friction properties for cover com-
mize the final cover design to reduce
maintenance through selection of the best ponents important?
available soil materials. A vegetative cover not Adequate friction between cover compo-
only improves the appearance of a unit, but it nents, such as geomembrane barrier layers
also controls erosion of the final cover. and soil drainage layers, as well as between
The vegetation components of the erosion any geosynthetic components, is needed to
layer should have the following characteristics: prevent extensive slippage or interfacial shear.
Water and ice can affect the potential for
1
USDA Universal Soil Loss Equation: X = RKLSCP where: X = Soil loss (tons/acre/year); R = Rainfall ero-
sion index; K = Soil erodibility index; L = Slope length factor; S = Slope gradient factor; C = Crop man-
11-6
agement factor; P = Erosion control practice. For minimal long-term care X < 2.0 tons/acre/year.
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
cover components to slip. Sudden sliding can can potentially breach the underlying barrier
tear geomembranes or cause sloughing of layer. Strategies for mitigating the effects
earthen materials. Internal shear can also be a described here are discussed below in the
concern for composite or geosynthetic clay context of protection layers composed of
liner materials. Measures to improve stability gravel or cobbles.
include using flatter slopes or textured
geosynthetic membranes, geogrids designed Is it necessary to stabilize wastes?
to resist slipping forces, otherwise reinforcing Before installing a final cover, liquid or
the cover soil, and providing drainage. semi-liquid wastes might need to be stabi-
lized or solidified. Stabilization or solidifica-
Can dry soil materials affect a
tion might be necessary to allow equipment
final cover? on the unit to install the final cover or to
Desiccation, the natural drying of soil ensure adequate support, or bearing capacity,
materials, can have an adverse affect on the for the final cover. With proper bulk cover
soil layers compromising the final cover. technique, it might be feasible to place the
Although this process is most commonly cover over a homogeneous, gel-like, semi-liq-
associated with layers of low permeability uid waste. When selecting a stabilization or
soil, such as clay, it can cause problems with solidification process, it is important to con-
other soil types as well. Desiccation causes sider the effectiveness of the process and its
cracks in the soil surface extending down- compatibility with the wastes. Performance
ward. Cover layers are not very thick, and specifications for stabilization or solidification
therefore these cracks can extend through an processes include leachability, free-liquid con-
entire layer, radically changing its hydraulic tent, physical stability, bearing capacity, reac-
conductivity or permeability. Care should be tivity, ignitability, biodegradability, strength,
taken to detect desiccation at an early stage in permeability, and durability of the stabilized
time to mitigate its damage. Also, the tenden- and solidified waste. You should consider
cy for final covers to become dry makes root seeking professional assistance to properly
penetration even more of a problem in that stabilize or solidify waste prior to closure.
plants respond to drought by extending their Where solidification is not practical, you
root systems downward. should consider reinforcement and construc-
tion of a specialized lighter weight cover sys-
Can plants and animals have an tem over unstable wastes. This involves using
effect on a final cover? combinations of geogrids, geotextiles,
geonets, geosynthetic clay liners, and
When selecting the plant species to geomembranes. For more detail on this prac-
include in the vegetative cover of a waste tice, consult references such as the paper by
management unit, you should consider the Robert P. Grefe, Closure of Papermill Sludge
potential for root systems to grow through Lagoons Using Geosynthetics and Subsequent
surface cover layers and penetrate underlying Performance, and the Geosynthetic Research
drainage and barrier layers. Such penetration Institute proceedings, Landfill Closures:
will form preferential pathways for water Geosynthetics Interface Friction and New
infiltration and compromise the integrity of Developments, cited in the Resources section.
the final cover system. Similarly, the presence
of burrowing animals should be foreseen
when designing the final cover system. Such
animals can burrow in the surface layers and
11-7
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
How can wastes be stabilized? situ mixing and mobile plant mixing. In situ
mixing is the simplest technique, using com-
Many stabilization and solidification mon construction equipment, such as back-
processes require the mixing of waste with hoes, excavators, and dump trucks. In situ
other materials, such as clay, lime, and ash. mixing is most suitable where large amounts
These processes include either sorbents or of materials are added to stabilize or solidify
encapsulating agents. Sorbents are nonreac- the waste. The existing waste management
tive and nonbiodegradable materials that soak area, such as a surface impoundment, can be
up free liquids to form a solid or near-solid used as the mixing area. The in situ mixing
mass. Encapsulating agents enclose wastes to process is open to the atmosphere, so envi-
form an impermeable mass. The following are ronmental and safety issues, such as odor,
examples of some commonly used types of dust, and vapor generation, should be taken
waste stabilization and solidification methods. into consideration. For mobile plant mixing,
• Cement-based techniques. Portland wastes are removed from the unit, mechani-
cement can use moisture from the cally mixed with treatment materials in a
waste (sludge) for cement hydration. portable processing vessel, and deposited
The end product has high strength, back into the unit. Mobile plant mixing is
good durability, and retains waste generally used for treating sludges and other
effectively. wastes with a high liquid content.
• Fly ash or lime techniques. A com-
bination of pozzolanic fly ash, lime, C. Components of a Final
and moisture can form compounds
that have cement-like properties.
Cover
Cover systems can be designed in a variety
• Thermoplastic techniques. Asphalt, of ways to accomplish closure goals. This
tar, polyolefins, and epoxies can be flexibility allows a final cover design system
mixed with waste, forming a semi- to integrate site-specific technical considera-
rigid solid after cooling. tions that can affect performance. This section
• Organic polymer processes. This discusses the potential components or layers
technique involves adding and mixing of a final cover system, their functions, and
monomer with a sludge, followed by appropriate materials for each layer. Since the
adding a polymerizing catalyst. This materials used in cover systems are the same
technique entraps the solid particles. as those used in liner systems, refer to
Chapter 7, Section B–Designing and
After evaluating and selecting a stabilization Installing Liners for a more detailed discus-
or solidification process, you should conduct sion of the engineering properties of the vari-
pilot-scale tests to address issues such as safe- ous materials.
ty, mix ratios, mix times, and pumping prob-
lems. Testing will help assess the potential for Table 1 presents the types of layers and
an increase in waste volume. It will also help typical materials that might exist in a final
to plan the production phase, train operators, cover. The minimum appropriate thicknesses
and devise construction specifications. of each of the five types of layers depends
upon many factors including site drainage,
When conducting full-scale treatment erosion potential, slopes, types of vegetative
operations, options exist for adding and mix- cover, type of soil, and climate.
ing materials. These options might include in
11-8
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
Table 1
Types of Layers in Final Cover Systems
11-9
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
excessively dry the soils. In this case, irrigation intrusion by plant roots or burrowing ani-
will be required to restore the water balance mals. This layer adds depth to the surface
within the soil structure. Topsoil is also vulner- layer, increasing its water storage capacity
able to penetration by burrowing animals. and protecting underlying layers from freez-
ing and erosion. In many cases, the protec-
Geosynthetic erosion control material can
tion layer and the surface layer are combined
be used as a cover above the topsoil to limit
to form a single cover layer.
erosion prior to the establishment of a mature
vegetative cover. The geosynthetic material can What types of materials can be
include embedded seeds to promote plant
growth, and can be anchored or reinforced to used in the protection layer?
add stability on steeply sloped areas. Soil will generally be the most suitable
Geosynthetic material, however, does not material for this layer, except in cases where
enhance the water-holding capacity of the soil. special design requirements exist for the pro-
In arid or semi-arid areas, therefore, the soil tection layer. The advantages and disadvan-
might still be prone to wind and water erosion tages of using soil in the protection layer are
if its water-holding capacity is insufficient. the same as those stated above in the discus-
Cobbles can be a suitable material for the sion of the surface layer topsoil. Factors
surface layer in arid areas or on steep slopes impacting the thickness and type of soil to use
which might hinder the establishment of veg- as a protection layer include freeze and thaw
etation. If they are large enough they will properties and the interaction between the soil
provide protection from wind and water ero- and drainage layers. Other types of materials
sion without washout. Cobbles can also pro- that can be used in the protection layer
tect the underlying barrier layer from include cobbles with a geotextile filter, gravel
intrusion by burrowing animals, but cobbles and rock, and recycled or reused waste.
might not be available locally, and their use Cobbles with a geotextile filter can form
does not protect the underlying barrier layer a good barrier against penetration by plant
from water infiltration. Because cobbles create roots and burrowing animals in arid sites.
a porous surface through which water can The primary disadvantage is that cobbles
percolate, they do not ordinarily support veg- have no water storage capacity and allow
etation. Wind-blown soil material can fill water percolation into underlying layers.
voids between cobbles, and plants can estab-
lish themselves in these materials. This plant Gravel and rock are similar to cobbles
material should be removed, as its roots are since they can form a good barrier against
likely to extend into the underlying barrier penetration by plant roots and burrowing ani-
layer in search of water. mals. Again, this use is usually only consid-
ered for arid sites, because gravel and rocks
What function does the protec- have no water storage capacity and allow
water percolation into underlying layers.
tion or biotic barrier layer serve?
Recycled or reused waste materials such
A protection or biotic barrier layer can be
as fly ash and bottom ash can be used in the
added below the surface layer, but above the
protection layer, when available. Check with
drainage layer, to protect the latter from
the state agency to verify that use of these
11-10
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
materials is allowable. The advantages of drainage layers, the thickness will depend on
using these materials in the protection layer the level of performance being designed and
are that they store water that has infiltrated the properties of available materials. For
past the surface layer, which can then be example, some geonet composites, with a
returned to the surface through evapotrans- thickness of less than 1 inch, have a transmis-
piration, and that they offer protection sivity equal to a much thicker layer of aggre-
against burrowing animals and penetration by gate or sand. The recommended thickness of
roots. If planning to use waste material in the the high permeability soil drainage layer is 12
protection layer, consider its impact on sur- inches with at least a 3 percent slope at the
face runoff at the unit’s perimeter. Design bottom of the layer. Based on standard prac-
controls to ensure runoff does not contribute tice, the drainage layer should have a
to surface-water contamination. Consult hydraulic conductivity in the range of 10-2 to
Chapter 6–Protecting Surface Water for more 10-3 cm/sec. Water infiltration control through
details on designing runoff controls. a drainage layer improves slope stability by
reducing the duration of surface and protec-
What function does the drainage tion layer saturation. In this role, the drainage
layer serve? layer works with vegetation to remove infil-
trating water from the cover and protect the
A drainage layer can be placed below the underlying barrier layer. If this layer drains
surface layer, but above the barrier layer, to the overlying soils too well, it could lead to
direct infiltrating water to drainage systems at the need for irrigation of the surface layer to
the toe of the cover (see Figure 2) or to inter- avoid desiccation.
mittent benches on long steep slopes. For
11-11
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
Another consideration for design of drainage layers. Again, be aware of the possi-
drainage layers is that the water should dis- bility that a gravel drainage layer might drain
charge freely from the toe of the cover or inter- overlying soils so well that irrigation of the
mittent benches. If outlets become plugged or surface layer might become necessary. The
are not of adequate capacity, the toe of the principal advantage to a gravel/geotextile
slope can become saturated and potentially drainage layer is the engineering community’s
unstable. In addition, when designing the considerable body of knowledge regarding
drainage layer, you should consider using flex- their use as drainage materials. Other advan-
ible corrugated piping in conjunction with tages include their ability to protect underly-
either the sand and gravel or the gravel with ing layers from intrusion, puncture,
geotextile filter material to facilitate the move- temperature extremes, and their common
ment of water to the unit perimeter. availability. The geotextile filter provides a
cushion layer between the gravel and the
What materials can be used in overlying protection layer.
the drainage layer?
Figure 3.
Sand and gravel are a common set of Geonet with Geotextile Filter Design
materials used in the drainage layer. The for Drainage Layer
principal consideration in their use is the
hydraulic conductivity required by the overall
design. There can be cases in which the
design requires the drainage of a large
amount of water from the surface layer, and
the hydraulic properties of the sand and grav-
el layer might be insufficient to meet these
requirements. The advantages of using sand
and gravel in the drainage layer include the
ability to protect the underlying barrier layer Source: U.S. EPA, 1991.
from intrusion, puncture, and temperature
extremes. The principal disadvantage to these
materials is that they are subject to intrusions Geonet and geotextile filter materials can
from the overlying protective layer that can be used to form an effective drainage layer
alter their hydraulic conductivity. Similarly, directly above a compacted clay or geomem-
fines in the sand and gravel can migrate brane liner (see Figure 3). They are a suitable
downslope, undermining the stability of the alternative especially in cases where other
cover slope. A graded filter or a geotextile fil- materials, such as sand and gravel, are not
ter can be used to separate and protect the locally available. The principal advantage is
sand and gravel from intrusions by the over- that lightweight equipment can be used
lying protection layer. during installation, reducing the risk of dam-
aging the underlying barrier layer.
Gravel with a geotextile filter is also a
widely-used design, whose applicability can The disadvantages associated with geonet
be limited by the local availability of materi- and geotextile materials are that they provide
als. The gravel promotes drainage of water little protection for the barrier layer against
from the overlying layers, while the geotextile extreme temperature changes, and there can
filter prevents the clogging of granular be slippage between the interfaces between
the geomembrane, geotextile, and low perme-
11-12
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
ability soil barrier materials. The use of tex- producing waste is present). Dry waste mater-
tured materials can be considered to address ial and gas formation within the unit con-
slippage. Furthermore, problems can arise in tribute to drying from below, while a range of
the horizontal seaming of the geotextile climatological conditions, including drought,
drainage layer on long slopes. can affect CCLs from above. Even with
extremely thick surface and protection layers,
Chipped or shredded tires are an addi-
CCLs can still undergo some desiccation.
tional option for drainage layer materials.
Chipped or shredded tires have been used for Clay liners are also vulnerable to subsi-
bottom drainage layers in the past and might dence within the waste unit. This problem
be suitable for cover drainage layers as well. can first manifest itself during liner construc-
One caution concerning the use of chipped tion. As the clay is compacted with machin-
or shredded tires is possible metal contami- ery, the waste might not provide a stable,
nants, or pieces of metal that could damage a even foundation for the compaction process.
geomembrane liner. You should consult with This will make it difficult to create the evenly
the state agency to determine whether this measured lifts comprising the liner. As waste
option is an acceptable practice. settles over time, depressions can form along
the top of the CCL. These depressions put
What function does the barrier differential stresses on the liner, causing
layer serve? cracks which compromise its integrity. For
instance, a depression of only 5 to 11 inches
The barrier layer is the most critical com- across a 6-foot area can be sufficient to crack
ponent of the cover system because it pre- the liner materials.
vents water infiltration into the waste. It also
indirectly promotes the storage and drainage Single geomembrane liners are sheets of
of water from the overlying protection and a plastic polymer combined with other ingre-
surface layers, and it prevents the upward dients to form an effective barrier to water
movement of gases. This layer will be the least infiltration. Such liners are simple and
permeable component of the final cover sys- straightforward to install, but they are rela-
tem. Typically, the hydraulic conductivity of a tively fragile and can be easily punctured
barrier layer is between 10-9 to 10-7 cm/sec. during installation or by movement in surface
layer materials. The principal advantage of a
What types of materials can be geomembrane is that it provides a relatively
impermeable barrier with materials that are
used in the barrier layer? generally available. It is not damaged by tem-
Single compacted clay liners (CCLs) are perature extremes and therefore does not
the most common material used as barrier require a thick surface layer. The geomem-
layers in final cover systems. CCL popularity brane is more flexible than clay and not as
arises largely because of the local availability vulnerable to cracking as a result of subsi-
of materials and the engineering community’s dence within the unit. The principal disad-
extensive experience with their use. Drying vantage is that it provides a point of potential
and subsidence are the primary difficulties slippage at the interface with the cover soils.
posed by CCLs. When the clay dries, cracks Such slippage can tear the geomembrane,
appear and provide preferential pathways even if it is anchored.
along which water can enter the waste, pro- Single geosynthetic clay liners (GCLs)
moting leachate formation, waste decomposi- are composed of bentonite clay supported by
tion, and gas formation (when methane
11-13
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
geotextiles or geomembranes held together some types of GCL and other surface layer
with stitching or adhesives. These liners are materials. The geomembrane is still vulnerable
relatively easy to install and have some self- to puncture, so placement of cover soils is
healing capacity for minor punctures. They important to minimize such damage.
are easily repaired by patching. The main dis-
Textured geomembranes can be used to
advantages include low shear strength, low
increase the stability of cap side slopes.
bearing capacity, vulnerability to puncture
Textured geomembranes are nearly identical
due to relative thinness, and potential for
to standard “smooth” geomembranes differing
slippage at interfaces with under- and overly-
only in the rough or textured surface that has
ing soil materials. When dry, their permeabil-
been added. This textured surface increases
ity to gas makes GCLs unsuitable as a barrier
the friction between the liner and soils and
layer for wastes that produce gas, unless the
other geosynthetics used in the cap, and can
clay will be maintained in a wet state for the
help prevent sliding failures. In general, tex-
entire post-closure period.
tured geomembranes are more expensive than
Geomembrane with compacted clay lin- comparable “smooth” geomembranes.
ers (CCLs) can be used to mitigate the short-
Using textured geomembranes allows cap
comings of each material when used alone. In
designers to employ steeper slopes which can
this composite liner, the geomembrane acts to
increase the available airspace in a waste
protect the clay from desiccation, while pro-
management unit, and therefore increase its
viding increased tolerance to differential set-
capacity. Textured geomembranes also help
tlement within the waste. The clay acts to
keep cover soil in place improving overall
protect the geomembrane from punctures and
liner stability on steep slopes. The degree to
tearing. Both components act as an effective
which textured geomembranes will improve
barrier to water infiltration. The principal dis-
frictional resistance (friction coefficients/fric-
advantage is slippage between the geomem-
tion angles) will vary from site-to-site
brane and surface layer materials.
depending upon the type of soil at the site
Geomembrane with geosynthetic clay lin- and its condition (e.g., moisture content).
ers (GCLs) can also be used as a barrier layer.
Textured geomembranes are manufactured
As with geomembrane and CCL combinations,
by two primary methods. Some textured
each component serves to mitigate the weak-
geomembranes have a friction coating layer
ness of the other. The geosynthetic material is
added to standard “smooth” geomembranes
less vulnerable than its clay counterpart to
through a secondary process. Others are tex-
cracking and has a moderate capacity to self-
tured during the initial production process,
heal. The geomembrane combined with the
meaning textured layers are coextruded as
GCL is a more flexible cover and is less vulner-
part of the liner itself. Textured geomem-
able to differential stresses from waste settle-
branes can be textured on one or both sides.
ment. Neither component is readily affected by
extreme temperature changes, and both work Textured geomembranes are seam-welded
together to form an effective barrier layer. For by the same technologies as standard
more information on the properties of geosyn- geomembranes. Due to their textured surface,
thetic clay liners, including their hydration however, seam welds can be less uniform
after installation, refer to Chapter 7, Section with textured liners than with normal liners.
B–Designing and Installing Liners. The poten- Some textured geomembranes have smooth
tial disadvantage is slippage between the upper edges on the top and bottom of the sheet to
and lower surfaces of the geomembrane and allow for more uniform seam welding.
11-14
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
What function does the gas col- tion of methane rise to dangerous levels. As
with all aspects of a waste containment sys-
lection layer serve? tem, construction quality assurance plays a
The role of the gas collection layer is to critical role in the success of a gas manage-
control the migration of gases to collection ment system.
vents. This collection layer is a permeable Gas extraction wells are an example of
layer that is placed above the foundation active gas control systems. For deep wells,
layer. It is often used in cases where the foun- the number, location, and extent of the pipe
dation layer itself is not the gas collection perforations are important. Also, the depth of
layer. For more information on Clean Air Act the well must be kept safely above the liner
requirements for managing gas from landfills system beneath the waste. For continuous gas
and other waste management units, refer to
Chapter 5–Protecting
Air Quality. Figure 4. Passive Gas Venting System
Gas control systems
generally include mech-
anisms designed to con-
trol gas migration and
to help vent gas emis-
sions into the atmo-
sphere. Systems using
natural pressure and
convection mechanisms
are referred to as passive
gas control systems (see
Figure 4). Examples of
passive gas control sys- Source: Robinson, W., ed. 1986. The Solid Waste Handbook: A Practical
tem elements include Guide. Reprinted by permission of John Wiley & Sons, Inc.
ditches, trenches, vent
walls, perforated pipes
surrounded by coarse Figure 5. Active Gas Venting System
soil, synthetic mem-
branes, and high mois-
ture, fine-grained soil.
Systems using mechani-
cal means to remove gas
from the unit are
referred to as active gas
control systems. Figure
5 illustrates an active
gas system. Gas control
systems can also be
used as part of correc-
tive action measures
Source: Robinson, W., ed. 1986. The Solid Waste Handbook: A Practical
should the concentra-
Guide. Reprinted by permission of John Wiley & Sons, Inc.
11-15
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
collection layers beneath the barrier layer, rier layer. Geotextile and geosynthetic
continuity is important for both soils and drainage composites also can make suitable
geosynthetics. gas collection layers. In many cases, these can
be the most cost-effective alternatives. The
Knowing the rate of gas generation is
same disadvantages exist with these materials
essential to determining the quantity of gas
in the gas collection layer as in other layers,
that can be extracted from the site. Pumping
such as slippage and continuity of flow.
an individual well at a greater vacuum will
give it a wider zone of influence, which is With a geomembrane in the final cover
acceptable, but obviously there are points of barrier system, uplift pressures will be exert-
diminishing marginal returns. Larger suction ed unless the gas is quickly and efficiently
pressures influence a larger region but conveyed to the wells, vents, or collection
involve more energy expended in the pump- trenches. If this is not properly managed,
ing. Pumping at greater vacuum also increas- uplift pressure will either cause bubbles to
es the potential for drawing in atmospheric occur, displacing the cover soil and appear-
air if the pumping rate is set too high. ing at the surface, or decrease the normal
Significant air intrusion into the unit can stress between the geomembrane and its
result in elevated temperatures and even underlying material. This problem has led to
underground fires. You should perform rou- slippage of the geomembrane and all overly-
tine checks of gas generation rates to better ing materials creating high tensile stresses
ensure that optimal pumping rates are used. evidenced by folding at the toe of the slope
and tension cracks near the top.
The performance of gas extraction systems
is affected by the following parameters,
which should be considered when designing D. Capillary-Break Final
and operating gas systems:
Covers
• Daily cover, which inhibits free The capillary-break (CB) approach is an
movement of gas. alternative design for a final cover system
• Sludge or liquid wastes, which affect (see Figure 6). This system relies on the fact
the ease at which gas will move. that for adjacent layers of fine- and coarse-
textured material to be in water-potential
• Shallow depth of unit, which makes
equilibrium, the coarse-grained material
it difficult to extract the gas, because
(such as crushed stone) will tend to have a
atmospheric air will be drawn in
much lower water content than the fine-
during the pumping.
grained material (such as sand). Because the
• Permeability of the final cover, which conductivity of water through a soil decreases
affects the ability of atmospheric air exponentially with its water content, as a soil
to permeate the wastes in the unit. becomes more dry, its tendency to stay dry
increases. Therefore, as long as the strata in a
What types of materials can be capillary break remain unsaturated (remain
used in the gas collection layer? above the water table), the overlying fine-tex-
tured soil will retain nearly all the water and
Sand and gravel are the most common the coarse soil will behave as a barrier to
materials used for gas collection layers. With water percolation due to its dryness. Since
these materials, a filter might be needed to this phenomenon breaks down if the coarse
prevent infiltration of materials from the bar- layer becomes saturated, this alternative
11-16
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
cover system is most appropriate for semiarid Figure 6. Example of a Capillary-Break Final
and desert environments. Cover System
What types of materials are used
in capillary-break covers?
The CB cover system typically consists of
five layers: surface, storage, capillary-break,
barrier, and foundation. The surface, barrier,
and foundation layers play the same role in
the cover system as described above. The
storage layer consists of fine material, such as
silty sand. The capillary-break, or coarse,
layer consists of granular materials, such as
gravel and coarse sand. A fabric filter is often
placed between the coarse and fine layers.
E. The Hydrologic
Evaluation of Landfill
Performance (HELP)
Model Adapted from <www.hanford.gov/eis/hraeis/
The relative performance of various cover eisdoc/graphics/fige-1.gif>
designs can be evaluated with the Hydrologic
Evaluation of Landfill Performance (HELP) defined in terms of soil type, which is related
model, developed by the U.S. Army Corps of to the hydraulic conductivity of each. Users
Engineers Waterway Experiment Station for fill in data collection sheets that request spe-
EPA. The HELP model was designed specifi- cific information on the layers and climate,
cally to support permit writers and engineers and this information is input to the model. In
in evaluating alternative landfill designs, but performing its calculations, the model will
it can also be used to evaluate various final take into account the reported engineering
cover designs. properties of each layer, such as slope,
The HELP model integrates runoff, perco- hydraulic conductivity, and rates of evapo-
lation, and subsurface-water flow actions into transpiration, to estimate the amount of pre-
one model. The model can be used to esti- cipitation that can enter the waste unit
mate the flow of water across and through a through the final cover. To use the HELP
final cover. To achieve this, the HELP model model properly, refer to the HELP Model
uses precipitation and other climatological User’s Guide and documentation (U.S. EPA,
information to partition rainfall and snow 1994b; U.S. EPA, 1994c). The model itself,
melt into surface runoff, evaporation, and the User’s Guide, and supporting documenta-
downward infiltration through the barrier tion can be obtained from the U.S. Army
layer to the waste. Corps of Engineers Web site at
<www.wes.army.mil/el/elmodels>.
The HELP model essentially divides a
waste management unit into layers, each
11-17
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
* Please consult with your state regulatory agency prior to constructing a final cover.
a
The final selection of geomembrane type, thickness, and drainage layer requirements for a final cover
should be design-based and consultation with your state agency is recommended.
b
This recommended thickness is for high permeability soil material with at least a 3 percent slope at the
bottom of the layer. Some geonet composites, with a minimal thickness of less than 1 inch, have a
transmissivity equal to a much thicker layer of aggregate or sand.
c
Thickness might need to be increased to address freeze/thaw conditions.
11-18
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
ed final cover systems based on the unit’s bot- addition, you should consider whether to
tom liner system. While the recommended include a protection layer or a gas collection
minimum final cover systems include closure layer. Figures 7 through 11 display recom-
layer component thicknesses and hydraulic mended minimum final cover systems.
conductivity, the cover systems can be modi-
fied to address site-specific conditions. In
Figure 7. Recommended Final Cover System for a Unit With a Double or Composite Liner
Figure 8. Recommended Final Cover System for a Unit With a Single Clay Liner
11-19
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
Figure 9. Recommended Final Cover System for a Unit With a Single Clay Liner in an Arid Area
Figure 10. Recommended Final Cover System for a Unit With a Single Synthetic Liner
11-20
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
Figure 11. Recommended Final Cover System for a Unit With a Natural Soil Liner
While these recommendations include the decontamination are complete when the con-
use of compacted clay, a facility manager stituent concentrations throughout the unit
might want to consider the use of a geomem- and any areas affected by releases from the
brane barrier layer in addition to, or in place unit do not exceed numeric cleanup levels.
of, a compacted clay barrier layer. Subsidence You should check with the state agency to see
of a final cover constructed with a compacted if it has established any numeric cleanup lev-
clay barrier layer can allow precipitation to els or methods for establishing site-specific
enter the closed unit and increase leachate levels. In the absence of state cleanup levels,
production. The use of a geomembrane in metals and organics should be removed to
place of compacted clay might be more cost either statistically equivalent background lev-
effective. Due to cracking or channeling or els or to maximum contaminant levels
continued subsidence, post-closure care of a (MCLs) or health-based numbers (HBNs)2.
compacted clay barrier layer can be more Metals and organics might have different
expensive to maintain than a geomembrane cleanup levels, but they both should be based
barrier layer. A geomembrane barrier layer on either local background levels or on
can also accommodate more subsidence with- health-based guidelines.
out losing its effectiveness.
Future land use considerations can also be
important in determining the appropriate
level of cleanup. One tool that can be used to
IV. Closure by help evaluate whether waste removal is
appropriate at the site is the risk-based cor-
Waste Removal rective action (RBCA) process described in
Closure by waste removal is a term that Chapter 10–Taking Corrective Action. The
describes the removal and decontamination RBCA process provides guidance on integrat-
of all waste, waste residues, contaminated ing ecological and human health risk-based
ground water, soils, and containment devices. decision-making into the traditional correc-
This approach is common for waste piles and tive action process.
some surface impoundments. Removal and
2
To learn about the regulatory and technical basis for MCLs, access the Integrated Risk Information System
(IRIS), a database of human health effects that can result from exposure to environmental contaminants,
at <www.epa.gov/iris>. Call the EPA Risk Information Hotline at 513 569-7254 for more information. 11-21
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
11-22
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
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Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
11-24
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
11-25
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
that potential exists. Individual post-closure The amount of financial assurance that
care periods can be long or short depending might be necessary is based on site-specific
on the type of waste being managed, the estimates of the costs of closure and post-clo-
waste management unit, and a variety of site- sure care. The estimates should reflect the
specific characteristics. You should contact costs that a third party would incur in con-
the appropriate state agency to determine ducting closure and post-closure activities.
what post-closure period it recommends. In This recommendation ensures adequate funds
the absence of any state guidance on the will be available to hire a third party to carry
appropriate length of the post-closure period, out necessary activities. You should consider
consider a minimum of 30 years. updating the cost estimates annually to
account for inflation and whenever changes
are made to the closure and post-closure
D. Closure and Post-Closure plans. For financial assurance purposes, if a
Cost Considerations state does not have a regulation or guidance
The facility manager of a closed industrial regarding the length of the post-closure care
unit is responsible for that unit. To ensure period, 30 years could be used as a planning
long-term protection of the environment, you tool for developing closure and post-closure
should account for the costs of closure and cost estimates.
post-closure care when making initial plans. Financial assurance mechanisms do not
There are guidance documents available to force anyone to immediately provide full
help plan for the costs associated with closing funding for closure and post-closure care.
a unit. For example, guides produced by the Rather, they help to ensure the future avail-
R.S. Means Co. provide up-to-date cost esti- ability of such funds. For example, trust
mates for most construction-related work, funds can be built up gradually during the
such as moving soil, and material and labor operating life of a waste management unit. By
for installing piping. Table 3 also presents an having an extended “pay-in” period for trust
example of a closure/post-closure cost esti- funds, the burden of funding closure and
mate form. Table 4 presents a sample summa- post-closure care will be spread out over the
ry cost estimating worksheet to assist in economic life of the unit. Alternatively, con-
determining the cost of closure. Also you sider the use of a corporate financial test or
should consider obtaining financial assurance third-party alternative, such as surety bonds,
mechanisms so that the necessary funds will letters of credit, insurance, or guarantees.
be available to complete closure and post-clo-
sure care activities if necessary. Financial What costs can be expected to
assurance planning encourages internalization be associated with the closure of
of the future costs associated with waste man-
agement units and promotes proper design a unit?
and operating practices, because the costs for The cost of constructing a final cover or
closure and post-closure care are often less achieving closure by waste removal will
for units operated in an environmentally pro- depend on site-specific activities. You should
tective manner. You should check with the consider developing written cost estimates
state agency to determine whether financial before closure procedures begin. For closure
assurance is required and what types of by means of a final cover, the cost of con-
financial assurance mechanisms might be structing the final cover will depend on the
acceptable. complexity of the cover profile, final slope
11-26
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
Table 3: Example Closure/Post-Closure Cost Estimate Form* (All Costs Shown in ($000)
ii Final Cover NA
x Ground-water Monitoring NA
TOTAL COSTS
* Developed from New Jersey Department of Environmental Protection, Bureau of Landfill Engineering
Landfill Permits.
11-27
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
ii Final Cover NA
x Ground-water Monitoring
TOTAL COSTS
11-28
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
Activity
Some of the activities listed below are routine. The owner or operator Worksheet Cost
might elect or be required to conduct additional activities. Italic type Number
denotes worksheets for estimating the costs of those additional activities
8 Decontamination DC-1 $
11 Transportation TR-1 $
17 Subtotal (Add engineering expenses and cost of the survey plat, certification of $
closure, and post-closure care to closure costs [Add lines 12 through 16])
Worksheet generated from CostPro©: Closure and Post-Closure Cost Estimating Software. Available from
Steve Jeffords of Tetra Tech EM Inc., 404 225-5514, or 285 Peach Tree Center Avenue, Suite 900,
Atlanta, GA, 30303.
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Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
contours of the cover, whether the entire unit expected. Post-closure care costs should
will be closed (or partial closures), and other include both annual costs, such as monitor-
site-specific factors. For example, the compo- ing, and periodic costs, such as cap or moni-
nents of the final cover system, such as a gas- toring well replacement.
vent layer or a biotic layer, will affect costs. In
For units closed by means of a final cover,
addition, closure-cost estimates would also
you should consider the costs for a mainte-
include final-cover vegetation, run-on and
nance program for the final cover and associ-
runoff control systems, leachate collection
ated vegetation. The more frequent the timing
and removal systems, ground-water monitor-
of the maintenance activities, the greater your
ing wells, gas-monitoring systems and con-
post-closure care costs will be. This program
trols, and access controls, such as fences or
might include repair of damaged or stressed
signs. Closure costs might also include con-
vegetation, and maintenance of side slopes.
struction quality assurance costs, engineering
Costs to maintain the run-on and runoff con-
fees, accounting and banking fees, insurance,
trol systems, leachate collection and removal
permit fees, legal fees, and, where appropri-
systems, and ground-water and gas monitor-
ate, contingencies for cost overruns, reworks,
ing wells should also be expected. In addi-
emergencies, and unforeseen expenses.
tion, sampling, analysis, and reporting costs
For closure by means of waste removal, should be factored into the post-closure cost
closure costs would include the costs of estimates. See Table 5 above for estimates of
removal procedures, decontamination proce- post-closure care costs.
dures, and sampling and analysis. Closure
Post-closure costs should be updated
cost estimates should also consider the costs
annually as a record of actual unit costs is
for equipment to remove all waste, transport
developed. Some costs, such as erosion con-
it to another waste management unit, and
trol and ground-water sampling, might be
properly treat or dispose of it. In addition,
reduced over time as the vegetation on the
fugitive dust emission controls, such as dust
cover matures and a meaningful amount of
suppression practices, might need to be
monitoring data is accumulated. Due to site-
included as a closure cost. Table 5 presents
specific conditions, a shorter or longer post-
example estimates of average closure costs for
closure period might be determined to be
typical closure activities. It also presents esti-
appropriate.
mates of typical post-closure care costs dis-
cussed in more detail below. How can long-term financial
What costs can be expected to be assurance for a unit be obtained?
associated with post-closure care? Different examples of financial assurance
mechanisms include trust funds, surety bond,
After a waste management unit is closed,
insurance, guarantee, corporate guarantees,
you should conduct monitoring and mainte-
and financial tests. Trust funds are a method
nance to ensure that the closed unit remains
whereby cash, liquid assets, certificates of
secure and stable. Consider the costs to con-
deposit, or government securities are deposit-
duct post-closure care and monitoring for
ed into a fund controlled by a trustee, or state
some period of time, such as 30 years (in the
agency. The trust fund amount should be such
absence of a state regulation or guidance). If a
that the principal plus accumulated earnings
unit is successfully closed by means of waste
over the projected life of the waste manage-
removal, no post-closure care costs would be
ment unit would be sufficient to pay closure
11-30
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
Landfill capping
$0.25/gallon 2
Reclamation of area (applying 2.5 feet of top soil and seeding) $10,200/acre 3
$15,000/facility/year 2
Remove perimeter fence (at end of post-closure care period) $2/linear foot 4
1
ICF Incorporated. Memo to Dale Ruhter, September 11, 1996
ICF’s data show that total closure and post-closure care costs are dependent upon the size of the landfill.
The size ranges and corresponding cost estimates were used to calculate the estimated average total costs.
11-31
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
2
Oklahoma Department of Environmental Quality. Table 5.2 Closure Cost Estimate and Table 5.3 Post
Closure Estimate from Chapter 5 of Solid Waste Financial Assurance Program Report. December 2000.
3
Jeffrey H. Heath “Landfill Closures: Balancing Environmental Protection with Cost,” MSW Management.
January/February 1996. pp. 66-70.
4
Wyoming Department of Environmental Quality, Solid and Hazardous Waste Division. Solid Waste
Guideline #12: Participation in the State Trust Account. May 1994.
and post-closure care costs. Surety bond, one or more beneficiaries. The trust
insurance, and guarantee are methods to fund should be dedicated to closure
arrange for a third party to guarantee pay- and post-closure care activities.
ment for closure and post-closure activities if Payments are made annually into the
necessary. A financial test is a standard, such fund so that the full amount for clo-
as an accounting ratio, net worth, bond rat- sure and post-closure care accumu-
ing, or a combination of these standards, that lates before closure and post-closure
measures the financial strength of a firm. By care activities start. A copy of the
passing a financial test, it is determined that trust agreement, which describes
one has the financial strength to pay for clo- how the funds will be used to pay for
sure and post-closure costs. closure and post-closure care activi-
ties, should be placed in the waste
A more detailed explanation of these
management unit’s operating record.
examples and other potential financial assur-
ance mechanisms is provided below. These • Surety bond. A surety bond guaran-
mechanisms can be used individually or in tees performance of an obligation,
combination. This Guide, however, does not such as closure and post-closure
recommend specific, acceptable, financial care. A surety company is an entity
assurance mechanisms. that agrees to answer for the debt or
default of another. Payment or per-
• Trust funds. A trust fund is an
formance surety bonds are acceptable
arrangement in which one party, the
in the event an owner or operator
grantor, transfers cash, liquid assets,
fails to conduct closure and post-clo-
certificates of deposit, or government
sure care activities. If you use a sure-
securities into a fund controlled by a
ty bond or letter of credit, you
special “custodian,” the trustee, who
should establish a standby trust fund
manages the money for the benefit of
(essentially the same as a trust fund).
11-32
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
In most cases, a standby trust fund is that they have the financial resources
established with an initial nominal to pay for closure and post-closure
fee agreed to by the owner or the costs. These tests might require that a
operator and the trustee. Further company meet a specified net worth,
payments into this fund are not a specified ratio of total liabilities to
required until the standby trust is net worth, and a specified net work-
funded by a surety company. The ing capital in the United States.
surety company should be listed as Implicit in using a financial test is a
an acceptable surety in Circular 570 reliance on Generally Accepted
of the U.S. Department of Treasury. Accounting Principles (GAAP) to pro-
vide fairly represented accounting
• Letters of credit. A letter of credit is
data. Your financial statements should
a formalized line of credit from a
be audited by an independent certi-
bank or another institution on behalf
fied public accountant. If the accoun-
of an owner or operator. This agree-
tant gives an adverse opinion or a
ment states that it will make available
disclaimer of opinion of the financial
to a beneficiary, such as a state, a spe-
statements, you should use a different
cific sum of money during a specific
financial assurance mechanism.
time period. The letter of credit
should be irrevocable and issued for • Corporate guarantee. Under a cor-
1 year. The letter of credit should porate guarantee, a parent company
also establish a standby trust fund. guarantees to pay for closure and
post-closure care, if necessary. The
• Insurance. An insurance policy is
parent company should pass a finan-
basically a contract through which
cial test to show that it has adequate
one party guarantees another party
financial strength to provide the
monies, usually a prescribed amount,
guarantee. A financial test is a way
to perform the closure or post-clo-
for guarantors to use financial data to
sure care in return for premiums
show that their resources are ade-
paid. The policy should be issued for
quate to meet closure and post-clo-
a face amount at least equal to the
sure care costs. The guarantee should
current cost estimate for closure and
only be used by firms with adequate
post-closure care. The face amount
financial strength.
refers to the total amount the insurer
is obligated to pay; actual payments • Other financial assurance mecha-
do not change the face amount. nisms. If you consider other financial
assurance mechanisms, you should
• Corporate financial test. Corporate
talk to your state to see if the mecha-
financial tests are a method for an
nism is acceptable.
owner and operator to self-guarantee
11-33
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
11-34
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
Resources
ASTM. D-3987-85. Standard Test Method for Shake Extraction of Solid Waste with Water.
ASTM, APHA, AWWA, & WPCF. Standard Test Methods for Examination of Water and Wastewater.
Bagchi, A. 1994. Design, Construction, and Monitoring of Landfills. John Wiley & Sons Inc.
Florida Department of Environmental Protection. Solid Waste Section. 1995. Municipal Solid Waste Landfill
Alternate Design Closure Guidance.
Geosynthetic Research Institute. 1990. Landfill Closures: Geosynthetics Interface Friction and New
Developments. GRI Proceedings.
Grefe, R. P. 1989. Closure of Papermill Sludge Lagoons Using Geosynthetics and Subsequent Performance.
Presented at the Twelfth Annual Madison Waste Conference. September.
Heath, Jeffrey H. 1996. “Landfill Closures: Balancing Environmental Protection with Cost,” MSW
Management. January/February. pp. 66-70.
ICF Incorporated. 1996. Memorandum to U.S. EPA: Updated Closure and Post-Closure Cost Estimates for
Subtitle C. (Nevin and Brawn to Ruhter, September 11, 1996).
Jesionek, K.S., R.J. Dunn, and D.E. Daniel. 1995. Evaluation of Landfill Final Covers. Proceedings Sardinia
95, Fifth International Landfill Symposium. October.
Koerner, R.M. and D.E. Daniel. 1997. Final Covers for Solid Waste Landfills and Abandoned Dumps.
Oklahoma Department of Environmental Quality. 2000. Chapter 5 of Solid Waste Financial Assurance
Program Report.
New Jersey Department of Environmental Protection and Energy. 1994. Technical Manual for Division of Solid
Waste Management Bureau of Landfill Engineering Landfill Permits.
Texas Natural Resource Conservation Commission. Industrial & Hazardous Waste Division. 1993. Closure
Guidance Documents (Draft). September.
Texas Natural Resource Conservation Commission. Industrial Solid Waste Management. 1984. “Closure and
Post-Closure Estimates.” <ftp://ftp.tnrcc.state.tx.us/pub/bbs1/ihwpslib/tg10.doc>. October.
11-35
Ensuring Long-Term Protection—Performing Closure and Post-Closure Care
Resources (cont.)
U.S. EPA. 1996. Test Methods for Evaluating Solid Waste Physical/Chemical Methods. SW-846.
U.S. EPA. 1995. Decision-Maker’s Guide to Solid Waste Management, Second Edition. EPA530-R-95-023.
U.S. EPA. 1994a. Design, Operation, and Closure of Municipal Solid Waste Landfills. EPA625-R-94-008.
U.S. EPA. 1994b. The Hydrologic Evaluation of Landfill Performance (HELP) Model: Users Guide for
Version 3. EPA600-R-94-168a.
U.S. EPA. 1994c. The Hydrologic Evaluation of Landfill Performance (HELP) Model: Engineering
Documentation for Version 3. EPA600-R-94-168b.
U.S. EPA. 1993. Solid Waste Disposal Facility Criteria: Technical Manual. EPA530-R-93-017.
U.S. EPA. 1991. Seminar Publication: Design and Construction of RCRA/CERCLA Final Covers. EPA625-
4-91-025.
U.S. EPA. 1990. Sites for Our Solid Waste: a Guidebook for Effective Public Involvement. EPA530-SW-90-
019.
U.S. EPA. 1989a. Seminar Publication: Requirements for Hazardous Waste Landfill Design, Construction,
and Closure. EPA625-4-89-022.
U.S. EPA. 1989b. Technical Guidance Document: Final Covers on Hazardous Waste Landfills and Surface
Impoundments. EPA530-SW-89-047.
U.S. EPA. 1988. Guide to Technical Resources for the Design of Land Disposal Facilities. EPA625-6-88-
018.
U.S. EPA. 1979. Method for Chemical Analysis of Water and Wastes. EPA600-4-79-020.
Washington Department of Ecology, Hazardous Waste and Toxics Reduction Program. 1994. Guidance for
Clean Closure of Dangerous Waste Facilities.
Wyoming Department of Environmental Quality, Solid and Hazardous Waste Division. 1994. Solid Waste
Guideline #12: Participation in the State Trust Account.
11-36