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Proceedings
of the
Combustion
Institute
Proceedings of the Combustion Institute 34 (2013) 2977–2984
www.elsevier.com/locate/proci

Jet-guided combustion characteristics and local


fuel concentration measurements in a hydrogen
direct-injection spark-ignition engine
Mithun Kanti Roy ⇑, Nobuyuki Kawahara, Eiji Tomita,
Takashi Fujitani
Okayama University, Okayama, Japan

Available online 11 July 2012

Abstract

Spark-ignition (SI) hydrogen engines based on direct injection (DI) promise significant advantages in
terms of thermal efficiency and power output, and present a means of overcoming problems related to
knocking, backfiring, and preignition. A better understanding of the effects of hydrogen jets on the fuel
concentration distribution and mixing process in a DISI engine should provide new and useful insights into
combustion optimization. The objective of the present work was to gain a deeper comprehension of the
characteristics of late-injection hydrogen combustion. An experimental combustion setup was applied to
a fired, jet-guided DISI engine operated at 600 rpm in stratified mode. GDI injector with the jet directed
toward the spark plug was used to develop the stratified combustion concept. A high-speed camera syn-
chronized with the spark was focused on a 52 mm-diameter field of view through a window at the bottom
of the piston crown. A series of single-shot images captured at different intervals was used to study the time
evolution of the flame distribution. Variations in the fuel injection timing relative ignition timing were
found to impact the development of the early flame, as well as the flame propagation. This research also
employed spark-induced breakdown spectroscopy (SIBS) to measure the local fuel–air concentration in the
spark gap at the time of ignition under stratified-charge conditions.
Ó 2012 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

Keywords: Hydrogen direct-injection spark-ignition engine; Flame propagation; Spark-induced breakdown spectros-
copy; Local fuel concentration measurement

1. Introduction reducing the greenhouse gas emissions of conven-


tional internal combustion engines (ICE). The
Hydrogen is regarded as a promising alterna- combustion properties of hydrogen are very differ-
tive fuel for improving the energy efficiency and ent from those of gasoline or diesel since it has a
wide flammability range and high burning veloc-
⇑ Corresponding author. Address: Dept. of Mechanical
ity. Its wide flammability range provides smooth
engine operation at a very lean mixture with a
Engineering, Okayama University, Tsushima-Naka 3,
Kita, Okayama 700-8530, Japan. Fax: +81 86 251 8266.
low NOx level [1]. In addition, its high burning
E-mail address: kawahara@mech.okayama-u.ac.jp velocity may contribute to a relatively high ther-
(M.K. Roy). mal efficiency with a shorter combustion period

1540-7489/$ - see front matter Ó 2012 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
http://dx.doi.org/10.1016/j.proci.2012.06.103
2978 M.K. Roy et al. / Proceedings of the Combustion Institute 34 (2013) 2977–2984

at the ignition timing close to top dead center Quantitative measurements of the cycle-to-
(TDC) [2]. Advanced hydrogen engine concepts cycle variations in the mixture strength at or near
based on DI fuel systems have shown that the per- the ignition site are comparatively rare for practi-
formance potential of H2-DI operation is approx- cal hydrogen SI engine. Kawahara et al. [13] used
imately 17% higher than that of gasoline port a spark-induced breakdown spectroscopy (SIBS)
injection [3]. Takagi et al. [4] proposed a plume technique to measure the influence of the Ha/O
ignition combustion concept (PCC) for hydrogen intensity ratio on the hydrogen–air mixture con-
DISI engines in order to reduce NOx emissions centration during fired engine operation. Ando
under high engine-load conditions. and Kuwahara [14] and Fansler et al. [15] reported
Hydrogen DI mixture formation techniques individual measurements of the equivalence ratio
have been grouped in a similar manner as DI gas- at the spark gap using the ratio of cyanogens
oline engines, and include jet-guided, wall-guided, (CN, 388 nm wavelength) and hydroxyl (OH,
and air-guided concepts [5]. Similar to the gasoline 306 nm wavelength) emission intensities from the
direct-injection engine, the injection timing spark that initiates combustion. They determined
strongly influences the ignitability of mixture. A the cycle-resolved local fuel–air ratio in the spark
major challenge to the use of H2-DI is the in-cylin- gap, controlled the large-scale stratification, and
der hydrogen-air mixing. The local equivalence evaluated the utility of SIBS as an engine diagnos-
ratio near the spark plug at the time of the spark tic tool.
discharge is particularly important for successful Very little work has been reported on hydrogen
ignition, since the jet-guided system generates a DISI engines in the late stages of the compression
stratified fuel concentration near the spark plug stroke, especially under stratified charge operating
in a DISI engine. The fuel concentration around conditions. A need exists for high-resolution
the spark plug together with the fluid motion direct-combustion images to measure the fuel dis-
strongly influences the duration of combustion ini- tribution and flame propagation under a range of
tiation. This causes cycle-to-cycle variation, which operating conditions and varying parameters,
can become large in lean-burn engines [6]. A vari- including fuel injection timing, ignition timing,
ety of optical techniques have been used previously and fuel–air equivalence ratio. Therefore, two fea-
to measure the local fuel concentration or the fuel– tures are pertinent to the present study. First,
air ratio in SI engines, including infrared (IR) high-resolution direct images of spark-ignited
absorption, planar laser-induced fluorescence combustion are acquired to investigate the effect
(PLIF), Laser-induced breakdown spectroscopy of fuel-injection timing in terms of the flame prop-
(LIBS) and Raman scattering. LIF measurement agation and combustion rate. Second, the inten-
has been widely used because the LIF signal is sity ratio of the Ha/O atomic emission lines is
strong and provides two-dimensional fuel concen- used to obtain quantitative measurements of the
tration data at a specific time. Tomita et al. [7] local equivalence ratio in the spark gap region.
applied the PLIF method to study the fuel concen-
tration distribution in the transient hydrogen jet.
Results showed that each transient hydrogen jet 2. Experimental apparatus
had different configurations and concentration dis-
tributions. Kaiser and White [8] performed an 2.1. Optical engine
optical study of mixture preparation in a hydro-
gen-fueled engine using a PLIF technique; their A specially designed single-cylinder compres-
report favors increased injection pressure and sion-expansion engine that could only be fired
careful nozzle design. Blotevogel et al. [9] used a once was used for the experiments. This engine
triethylamine (TEA) tracer-based LIF technique can observe only single cycle combustion phenom-
(rather than an acetone tracer) to measure mixture ena in one experimental run. A schematic diagram
formation in H2-ICE under a high-temperature of the engine with the optical diagnostic geometry
and high-pressure environment, and demonstrated is shown in Fig. 1. A summary of engine specifica-
a very good signal-to-noise ratio. tions is provided in Table 1. This engine had only
Ferioli et al. [10] used LIBS on engine exhaust one intake valve. The in-cylinder exhaust gas was
gas to illustrate the ability of this technique to mea- drawn out by a vacuum pump through the inlet
sure the equivalence ratio of SI engines using the valve. A Bowditch elongated piston equipped with
ratios of C/O and C/N atomic peaks derived from a 52 mm-diameter quartz window in the piston
the measured spectra. Phuoc [11] used a laser- crown was used to provide optical access inside
induced spark to measure the ignition and fuel- the combustion chamber. The piston used in this
to-air ratio of CH4–air and H2–air combustible study was flat-topped. The engine was driven by
mixtures simultaneously using the measured spec- an electric motor when the piston was set at
tral peak ratio Ha (656 nm)/O (777 nm). Shudo TDC position. Air was initially introduced into
and Oba [12] measured the mixture formation the cylinder through an inlet valve at a pressure
characteristic with hydrogen jet in nitrogen filled of 101 kPa and a temperature of 300 K. After a
constant volume chamber using LIBS techniques. given amount of time, the valve was closed when
M.K. Roy et al. / Proceedings of the Combustion Institute 34 (2013) 2977–2984 2979

Fig. 1. Schematic view of the optical engine experimental setup.

Table 1 The injector was located close to the spark plug


Engine specifications. (see Fig. 2) on the central part of the cylinder head
Bore 7.8 cm
based on the narrow-spacing concept. The
Stroke 6.5 cm inclined injector geometry directed the injected
Displacement volume 310.6 cm3 gas toward the spark plug. The distance between
Combustion chamber Pancake shaped the injector nozzle tip and the spark plug was
Compression ratio 9.0 17.4 mm. A time card ensured synchronization
Engine speed 600 rpm of the various trigger signals with the images
Intake valve close(IVC) BDC and the data acquisition system. The in-cylinder
Fuel injection pressure 5 MPa pressure was recorded using a Kistler piezoelectric
transducer installed on the cylinder head. The
heat release rate and the coefficient of variation
the piston was located at bottom dead center (COV) of the indicated mean effective pressure
(BDC). Hydrogen was supplied from a H2 cylin- (IMEP) were calculated from the measured pres-
der and a fuel accumulator was used to maintain sures. Direct photography of the flame combus-
the constant fuel feed pressure to the injector. A tion was acquired through a 45° mirror mounted
solenoid-driven gasoline direct injection (GDI) in the extended piston with a Photron Fastcam
injector used as a fuel injector developed by SA1.1 (12 bit) CMOS camera. The lens was a
Mitsubishi Electric Co. Ltd. A single-hole injector
had an orifice diameter of 1.0 mm.

Fig. 2. Geometric relationship between the single-hole


injector and the spark plug. Fig. 3. Viewable area through the piston window.
2980 M.K. Roy et al. / Proceedings of the Combustion Institute 34 (2013) 2977–2984

1.2
Injection pressure, Pinj = 5 MPa
1.0 Ambient pressure, Pamb= 1.0 MPa

Overall equivalence ratio, φ


0.8

0.6

0.4

0.2

0.0
0 1 2 3 4 5 6 7 8 9
Fig. 4. Developed fiberoptic spark-plug sensor. Injection duration, ms

Fig. 5. Injection duration at various overall equivalence


50 mm, f/1.5 Nikon, and the frame resolution was ratios.
384  320 pixels2 at 40,000 frames per second. An
exemplary photo in Fig. 3 describes the viewable
area through the piston window where injector
is located at the top of the image.

2.2. SIBS method

SIBS is a measurement technique in which


spectrally resolved emissions of plasma generated
by the spark plug. In theory, the air–fuel ratio in
the spark gap can be determined through analysis
of the light emission from the spark, which initi- Fig. 6. Diagrams showing the fuel-injection timing
ates combustion. A commercial spark plug with relative to the ignition timing.
an electrode spacing of 2 mm was used as the SIBS
sensor in a practical SI engine. The fiberoptic
spark plug is shown in Fig. 4. The discharge volt- from 250 to 800 nm with a resolution of 0.3 nm
age and current were supplied from a direct-cur- and a minimum integration time of 1 ms. The
rent power source with an input voltage of 12 V spectrometer converted incoming light into volt-
and input current of 20 A. A spark-charging dura- age across a charge-coupled device (CCD), where
tion of 10 ms was used. Coil ignition systems nor- in each pixel of the CCD represented a pre-cali-
mally have three phases: breakdown, arc, and glow brated wavelength. Data analysis was performed
discharge [13]. Dissociation and ionization occur using the Ocean Optics SpectraSuite software
during the breakdown phase, during which an ion- package.
izing streamer propagates from the ground elec-
trode to the center electrode. After breakdown, 2.3. Operating conditions
the arc phase occurs, and atomic recombination
leads to molecule formation. The breakdown and The fuel injection pressure was maintained
arc phases appear together as a spike in the dis- constantly at 5 MPa in this experiment. The
charge voltage and current. hydrogen quantity was measured in a constant
An optical UV-grade quartz fiber with a core volume vessel at 5 MPa of injection pressure
diameter of 600 lm was housed in the center elec- under different ambient pressure (0.1–1.0 MPa)
trode of the spark plug. The optical fiber had a condition [16]. The relationship between the fuel
numerical aperture (NA) of 0.20, which covered injection duration and the overall equivalence
the area around the ground electrode. The ground ratio are shown in Fig 5. The fuel–air mixture
electrode had a small projection toward the center was ignited at TDC. This experiment was carried
electrode to allow stable initiation of the spark out for four different injection timings after the
discharge. This small projection was the starting intake-valve closing. The relative timings of fuel
point of the ionic streamer during the breakdown injection and spark ignition are illustrated in
and arc phases. Figure 1 shows the measurement Fig. 6 and can be summarized as follows:
system used with our fiber optic spark-plug sensor
in the optical SI engine. Emission spectra from the 1. Tail ignition (TI): Hydrogen is injected during
spark discharge between the ground and center the compression stroke and ignites at the end
electrodes were obtained with the optical fiber of the injection (EOI). Start of injection
coupled to a spectrometer. The spectrometer mea- (SOI) is at a 340.5° crank angle (CA) and the
sured the optical emission spectrum over a range EOI is at TDC.
M.K. Roy et al. / Proceedings of the Combustion Institute 34 (2013) 2977–2984 2981

2. After tail ignition (ATI): Hydrogen is injected ROHR for HI mode indicates the diffusive phase
during the compression stroke, and the EOI like combustion as well as in CI mode. Figure 7
is at a 5° CA before TDC. The SOI is at a shows that TI mode combustion had faster burn-
335.5° CA and the EOI is at a 355° CA. ing rate compared to the other ignition modes and
3. Center ignition (CI): Hydrogen is injected dur- thereby increases the combustion efficiency.
ing the late part of the compression stroke and Photographs combined with thermodynamic
ignition occurs between the SOI and EOI. The data provide an effective tool for combustion anal-
SOI is at a 350° CA and the EOI is at a 369.5° ysis. Figure 8a–d shows the time-series spark-
CA. ignited combustion images for different ignition
4. Head ignition (HI): Hydrogen is injected dur- timing at an overall equivalence ratio of 0.7. Com-
ing the late part of the compression stroke bustion images of the four different ignition modes
and ignites at TDC, close to the start of injec- are shown for the spark discharge and flame prop-
tion. The SOI is at a 355° CA and the EOI is at agation periods. Some additional luminosity was
a 374.5° CA. observed during flame growth, perhaps due to
combustion of the lubricating oil [17]. For TI tim-
ing mode, the results presented in Fig. 8a show an
3. Experimental results initial early kernel growth after the spark dis-
charge as the rapid flame propagated through the
3.1. Combustion characteristics for different jet combustion chamber. Pictures of the initial com-
ignition modes bustion phase indicate an initial quasi-spherical
and later partially wrinkled flame. When the flame
The results are shown in comparison with the kernel becomes larger than the smallest turbulent
combustion characteristics obtained for four dif- eddies, the flame front will become wrinkled [18].
ferent ignition modes. Typical pressure histories For ATI, the flame travelled a short distance from
and the rate of heat release (ROHR) for different the spark-plug center, as shown in Fig. 8b. Figure
ignition timings at an overall equivalence ratio of 8c shows the CI mode combustion images, in
0.7 are shown in Fig. 7. For TI, where ignition which ignition occurred during the middle of
occurred during the end of the injection period, injection period. It has been known that the hydro-
a rapid increase in pressure just after ignition gen jet injection produced turbulence flow field in
was observed, with a maximum peak ROHR. the surrounding air, which resulted in turbulent
The ATI ignition mode allowed a 5° CA after combustion during the initial phase of CI. Figure
the EOI for the injected gas to mix and settle 8d shows the HI mode combustion images with
before ignition. A medium peak combustion pres- very low flame intensity. The flame propagation
sure was observed compared to the other ignition indicated that the mixture, which was ignited dur-
modes; the heat release rate increased smoothly to ing the fuel injection, behaved quite differently
a maximum and then progressively decreased as from when ignition occurred after the termination
the entire mixture was consumed. For CI, in-cyl- of the injection. Two possible reasons exist to
inder combustion pressure was lower compared explain this phenomenon: the first relates to the
to TI and ATI. The ROHR for CI was faster in degree of charge stratification of the mixture,
the initial stage, but slower burn in the later and the second relates to the decay of the turbu-
stages, indicating diffusive phase combustion. lence generated by the hydrogen jet.
For HI mode, ignition timing at the early stage The COV of IMEP, which is defined as the
of SOI, resulting in reducing the in-cylinder pres- standard deviation of the IMEP divided by the
sure with a low burning rate. The second part of mean IMEP [6], is a good measure of the combus-
tion stability. Cycle variation in a SI engine results
from the change in the mean effective pressure
caused by combustion variation, which is brought
about by variation in the flow of the fuel–air mix-
ture at the time of ignition. The COV of IMEP for
the four ignition modes is shown in Fig. 9, while
that for the TI injection mode was about 7%, indi-
cating that the combustion was relatively stable.
This was attributed to sufficient hydrogen being
in the vicinity of the spark plug to create an ignit-
able mixture, which could burn reliably, as
observed in Fig. 8a. The other three ignition modes
led to the large cycle-by-cycle variations. The ATI
mode showed quite unstable combustion because
at early injection timing, where the in-cylinder
Fig. 7. In-cylinder pressure history and ROHR for pressure is relatively low, the gas jet travels further
different ignition-mode combustion processes. from the spark plug, causing less effective burning.
2982 M.K. Roy et al. / Proceedings of the Combustion Institute 34 (2013) 2977–2984

Fig. 8. (a–d) Time-series evolution of the high-speed direct images for different ignition-mode combustion processes.

Fig. 9. COV of IMEP for different ignition-mode Fig. 10. SIBS spectra for different ignition-mode com-
combustion processes. bustion processes.

Further ignition during the midpoint of the injec-


tion period for CI mode, caused the COV of the timing was set closer to the SOI. The results sug-
IMEP to increase by more than 10%. CI mode gest that the TI mode gives the relatively stable
combustion had become unstable, as a heteroge- operation of the ignition modes considered here.
neous fuel–air mixture formed due to short mixing
time. The COV of IMEP for the HI mode was 3.2. Local equivalence ratio measurement
about 24%. The HI mode showed very unstable
combustion due to the shortening of the mixing Spectrally resolved atomic emissions of plasma
time of the hydrogen jet and air since the ignition generated by the spark plug were investigated to
M.K. Roy et al. / Proceedings of the Combustion Institute 34 (2013) 2977–2984 2983

determine the local equivalence ratio. Equivalence 25


φlocal Initial combustion duration
2.0

Mean local equivalence ratio,φlocal


ratio, / is defined as the ratio of the actual fuel-to-

Initial combustion duration, deg.


oxidizer mass, mfuel/mair, over the ratio of the fuel- 20
1.5
to-oxidizer mass at stoichiometric condition,
(mfuel/mair)stoich. The determination of the local 15

equivalence ratio is important in combustion pro- 1.0

cesses, since this ratio strongly affects the combus- 10

tion characteristics. Figure 10 shows the average 0.5


emission spectra with a corrected background 5

obtained from SIBS sensor for the 600–800 nm


regions, corresponding to engine combustion at 0 0.0
Tail Ignition After Tail Center Ignition Head Ignition
different ignition modes. The spectrometer integra- (TI) Ignition (ATI) (CI) (HI)
tion time was used of 1 ms. The spectrometer was
gated shortly after spark breakdown. Each spec- Fig. 12. Local equivalence ratio measured with SIBS
trum corresponds to the average of 10 cycles of and initial combustion duration.
data. A 600 lines/mm grating was used to record
the spectra in the 250–800 nm spectral regions.
The atomic emission spectra from the hydrogen
Ha line at 656 nm, nitrogen N (I) line at 740– (I) intensity ratio showed a clear increasing trend
750 nm, potassium (K) line at 767 nm, and oxygen with increasing overall equivalence ratio, possibly
O (I) triplet line at 777 nm were obtained using the rolling off slightly at higher equivalence ratios. It
developed fiberoptic sensor. The emission at is possible to generate a calibration curve from
767 nm due to potassium (K) is routinely found the global equivalence ratio and the Ha /O (I)
in current research and may have been due to com- ratio. In the present work, the Ha/O (I) intensity
bustion of the lubricating oil [17]. ratio and the overall equivalence ratio data
The calibration measurements presented in this exhibited a linear fit, determined by least squares
experiment were conducted in the same optical to be,
DISI engine (see Fig. 1) for near-homogeneous
/ ¼ ½ðHa =OÞ  1:091 ð1Þ
hydrogen-air mixture combustion at various
2
known equivalence ratios. The overall equivalence with regression coefficients R = 0.92. However,
ratio for near-homogeneous combustion (initial further analysis of the intensity ratios, Ha/N (I),
pressure = 0.1 MPa; initial temperature = 300 K) is required to generate a calibration curve that
was changed from 1.0 to 4.5. The SOI was coinci- they must respond linearly with the overall equiv-
dent with BDC and spark timing was TDC. Fig- alence ratio.
ure 11 illustrates the intensity ratios of Ha/O, Figure 12 shows the measurements of the mean
compared with the global equivalence ratio mea- local equivalence ratio and the initial combustion
sured during near-homogeneous combustion. duration for the four ignition modes at global
The Shirley background correction method [19] equivalence ratio, / = 0.7. The estimated local
was used to subtract the elastic scattering. The equivalence ratio for different ignition modes
Ha and the O (I) peak was integrated over a cer- was obtained using the linear fit (as shown in
tain wavelength range. The error bars shown in Eq. (1)). In this paper, the initial combustion
Fig. 11 correspond to standard deviation deter- duration is defined as the interval of the crank
mined from 10 cycles of data. The data of Ha /O angle from the ignition start to 5% mass fraction
burned. The error bars showed the standard devi-
ation both for the mean local equivalence ratio
5 and the initial combustion duration measure-
ments. The estimated local equivalence ratio at
4 the spark gap just after spark breakdown showed
Overall equivalence ratio,φ

very rich. The standard deviation of the local


3
equivalence ratio measurement shows the bulk
of the variation at each ignition condition. It has
Y=1.091×X been known that the flammability range for
2 2
R =0.917 hydrogen is 4–75%, (/ = 0.1–7.1) by volume in
air at 298 K and 1 atm [20]. But for typical engine
1 operation at high pressure and temperature, the
minimum ignition energies of hydrogen-air mix-
tures is much lower than for other fuel. For HI,
0 1 2 3 4 5
SIBS intensity ratio, Hα/O
the estimated local equivalence ratio was relatively
lower than those in other ignition modes. The
Fig. 11. Correlation of the atomic line intensity ratio, COV of local equivalence ratio for HI was about
Ha/O with the overall equivalence ratio. 40%. The initial combustion duration for HI takes
2984 M.K. Roy et al. / Proceedings of the Combustion Institute 34 (2013) 2977–2984

a large crank angle compared to other ignition were correlated to the global equivalence ratio.
modes. Fajardo and Sick [21] concluded that the For stratified charge operation of the jet injection
increase in shear strain in the spark plug sur- relative to ignition timing, the estimated local
rounding, combined with fuel stratification and equivalence ratio at the spark gap just after spark
extension of plasma channel, could prevent flame breakdown was very rich and varies widely from
kernel development in a DISI engine. cycle-to-cycle. The results presented here confirm
The estimated local equivalence ratio for CI the usefulness of spark-induced breakdown spec-
mode combustion showed very rich compared to troscopy as a diagnostic tool for spark-ignition
other ignition mode. The COV of local equiva- engine. Optimization of the UV-grade optical
lence ratio for CI was about 46%. CI mode com- fiber and the optical gate period in CCD camera
bustion had heterogeneous conditions, in which should be carried out for further measurement.
the ignition occurred while the fuel was in the pro-
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