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EXTRUSION

Winning
with Foam
For Retrofitting. The production costs of
semi-finished extruded products are sig-
nificantly influenced by the cost of raw
materials. This makes technologies very
interesting that reduce raw materials Pipes with foamed cores
(figures: Promix Solutions)
consumption. By means of extrusion
foaming, savings on raw material costs can be achieved without having to accept
compromises in product quality. Retrofit solutions for physical foaming with CO2 or
N2 enable conventional extrusion lines to manufacture foamed products.

CHRISTIAN SCHLUMMER well as for sheet applications in building ing and controlled expansion of the melt
or container construction. with its charge of blowing agent. This re-
oamed semi-finished-products are quires special machines with very long

F used today in numerous areas of ap-


plication. Classic applications utilize
the specific properties of high-expansion
Different Technologies

Heavy foams are relatively high-density


processing units compared to those of
conventional extrusion equipment. The
physical foaming fluid used then is in-
foam to obtain, for instance, insulating foamed articles that ultimately compete jected into the melt under high pressure,
effects, damping properties or a specified with non-foamed products for final ap- then homogenized and cooled in screw
compressibility. In such applications, the plications. These applications have main- mixing and shearing zones. The specified
physical property of foam is the main ly been foamed using chemical foaming goal is a single-phase mixture of melt and
thing. However, foaming is also used in additives. The reason for this lies in the blowing agent with a defined tempera-
cases where the properties of a foamed relatively simple application of chemical ture that undergoes controlled expansion
product scarcely differ from those of non- foaming additives. These additives are due to pressure loss in the shaping die.
foamed products. In such cases, the aim generally dosed gravimetrically into the As a consequence of the ban on CFCs,
is to reduce raw materials consumption raw materials as a masterbatch and devel- aliphatic hydrocarbons such as butane
while largely maintaining the same prop- op their foaming action under the influ- and pentane have become established.
erties. These “heavy” foams are even used ence of warmth. Besides the high costs of Due to their low level of solubility, inert
in cases where they are not even recog- the additives among their disadvantages gases, such as CO2 and nitrogen place
nized as being such: For example, multi- include the limited foaming power of strong demands on processing technol-
layer laminates with a foamed center lay- chemical additives and the retention of ogy, but offer a number of advantages
er are used in adhesive tapes. In the food chemical residues in the melt. Chemical over hydrocarbon-based versions.
industry, dairy products are sold in ther- additives are used in numerous high-den- Among these are unlimited availability
moformed cups with a foam core layer. sity products and achieve weight reduc- and low costs. Since it is obtained from >
Special electrical properties are obtained tions of 10 to 50 %.
in cable applications by means of inter- High-expansion foams are mainly
mediate foamed layers. Multilayer tech- produced on special foam extruders. Sys- i Contact
nical components with a foamed core lay- tems of this type fulfill a number of re-
er are increasingly present in infrastruc- quirements that exceed the capabilities of Promix Solutions AG
ture areas as pressureless sewage pipes as classic extrusion. Besides the process-re- CH-8406 Winterthur
lated specifics of melt conditioning and Switzerland
discharge shaping by the die, foam ex- > www.promix-solutions.com
Translated from Kunststoffe 9/2013, pp. 176–180 truders also have to assume the tasks of
Article as PDF-File at www.kunststoffe- preparing, injecting and homogenizing K show: Hall 9, booth E32
international.com; Document Number: PE111446 the blowing agent, as well as melt cool-

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EXTRUSION

Solutions for
Total Retrofitted Extrusion
costs
Retrofit solutions for foam extrusion us-
ing CO2 and nitrogen appeal both to
processors who would like to replace their
Cost
advantage existing chemical foaming process with
physical foaming, as well as to those who
wish to substitute existing compact arti-
ing
CO2 foam Operating costs of CO2 foaming cles with foamed products.
The Swiss company Promix Solutions
ing specializes in retrofit concepts for phys-
am ical foaming and offers custom solutions
a l fo
mic
Investment

Che for existing extrusion lines. Experience


in plant

Operating costs of chemical foaming with numerous industrial projects shows


Time
that almost any conventional extruder
© Kunststoffe
can be retrofitted as a foam extruder re-
gardless of its type or size. In order to be
Fig. 1. Comparative cost structures for chemical and physical foams able to offer the optimum solution for
any particular case of application, two as-
pects are of central importance: A
process-relevant evaluation of the exist-
ing plant technology and the specific re-
quirements of the foamed product. In ad-
dition to the physical properties derived
from its raw materials, foam density and
cell size distribution, the surface quality
of the foamed product is an important
quality feature in many instances. In such
cases it is important to consider the in-
Fig. 2. Static retrofit for foaming with CO2 teraction of properties and the limits of
what is possible. Thus falling density is
the surrounding air, CO2 also serves eco- in a position to utilize existing extrusion almost always accompanied by a loss of
political goals, since it does not con- lines for physically foamed products. The mechanical strength. Surface texture is
tribute to global warming. CO2 is non- high investment in a special foaming ex- also a function of the degree of foaming
combustible, odorless and, in process rel- truder becomes superfluous. In addition, whereby individual characteristics can be
evant concentration, non-toxic. Thus a the retrofitted extruder, similarly as with specifically influenced depending on the
trend can be seen toward the use of at- chemical foaming, can be used for both case of application and process variants.
mospheric gases as blowing agents. Spe- foamed and non-foamed products. The Coextruded film and sheet with a foam
cific hardware improvements have made processor can then organize his produc- core layer and compact outer layer com-
it possible to utilize CO2 for many tion capacities flexibly and take the first bine low weight with good surface finish
foamed products that have been manu- step into the market for foamed products (Table 1).
factured by classic hydrocarbons. by combining lower capacities with con- The technological processing require-
ventional products. For a direct compar- ments derive directly from the require-
Chemical and ison of physically and chemically foamed ments for the foamed product whereby
Physical Blowing Agents products, the necessary investment costs existing technology determines the type
for physical foaming equipment are com- and scope of retrofit components. Promix
However, the low solubility of atmospher- pared with the running costs of additives. Solutions offers two fundamentally dif-
ic gases has its advantages. Thus CO2 and As a rule, the bottom line shows a cost ad- ferent concepts that can be divided into
nitrogen can also be used in very low con- vantage for physical foaming in a short static and dynamic solutions. Both con-
centrations for heavy foams that used to time (Fig. 1). cepts pursue the goal of integrating the
be manufacturer exclusively using chem-
ical blowing agents. All in all, the number
Processing characteristics Product-specific characteristics
of high-density foam applications is in-
creasing that are being foamed more for Extruder type Raw material
reason of cost pressures than out of tech- Available space/installation space Foam density
nological necessity. Process engineering
Pressure conditions Cell structure
solutions using atmospheric gases are
thus becoming more important. Solu- Melt cooling Surface structure
tions for retrofitting conventional extru- Drive power Mechanical properties
sion lines for physical foaming offer a low-
Suitability of extruder die Mono-/multilayer application
risk point of entry into this processing
technology. In this way, the processor is Table 1. Features of retrofit solutions for extrusion foaming

108 © Carl Hanser Verlag, Munich Kunststoffe international 9/2013

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EXTRUSION

additional processing steps of blowing


agent injection, homogenizing and cool-
ing in the existing extrusion equipment. Standard Optimized standard New configuration A New configuration B1

Which solution is suitable in a particular 160


instance depends on the concrete circum- 140

Max. amount of CO2 dissolved


stances of the extrusion equipment to be
retrofitted. Thus, in addition to the exist- 120

[in % of base value]


ing floor space, the extruder’s pressure ca- 100
pacity and drive power as well as the melt
cooling requirement are taken into con- 80
sideration.
60

The Static Solution 40

20
In essence, Promix foam system’s static
solution combines a fluid injection noz- 0
zle for the blowing agent with a down- Throughput 25 % Throughput 50 % Throughput 80 %
Throughput guidance extruder
stream static mixing zone. The system is
installed downstream from the extruder © Kunststoffe
barrel immediately in front of the extru-
sion die. This patented process has the ad- Fig. 3. Maximum soluble amount of CO2 as a function of mixer configuration for polyethylene,
vantage that no alterations are required MFI 4.0, 220°C
for the plasticating unit of the extruder.
All that is required for retrofitting is cor- truder throughput depends on the type With an optimum mixing zone, medi-
responding floor space for installation as and configuration of the mixing zone. um-to-high density microcellular foams
well as reserve pressure from the extrud- The influences of mixing technology on can be produced by the purely static pro-
er, since the static mixing zone is by na- the resulting foam can be illustrated by cessing variant at any throughput. If melt
ture a pressure consumer. The blowing taking the soluble quantity of blowing cooling is also required to further reduce
agent is introduced under high pressure agent at a given point of operation as foam density, the system can be combined
by a mass flow-controlled dosing station. measure of mixture quality. Thus by op- with static melt coolers. An especially ef-
It should be noted thereby that the quan- timizing the mixing zone configuration ficient type of melt cooling can be
tity of blowing agent required by low-to- at a given operating point, up to three achieved with the aid of a Promix bundle
medium foam levels is quite small, so that times higher CO2 concentration could be heat exchanger. The barrel section carry-
precise dosage has to be assured even at dissolved in the melt than with a conven- ing the melt is then fitted with a number
miniscule amounts as small as 1 g/min tional mixing zone. Process-relevant pa- of tempered, bended pipes that function
(Fig. 2). rameters such as pressure and tempera- simultaneously as mixing components.
Especially significant is the configura- ture as well as shear rate and the dwell The pipes are directly tempered by a heat
tion of the static mixing zone. Laborato- time of the polymer-blowing agent sys- transfer medium. The melt flows through
ry experiments at Promix Solutions have tem play a large role in the formation of the cooler and is intensively cooled by
shown that the maximum blowing agent a single-phase solution of polymer and contact with the pipes. At the same time,
concentration soluble at any given ex- foaming fluid (Fig. 3). the special geometry of the pipe bundles >

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EXTRUSION

ly below those of chemical foaming addi- of the cylinder. In this way, it is not nec-
tives (Fig. 4). essary to modify the existing cylinder.
Retrofitting can thus be accomplished in
The Dynamic Solution a short time without long-lasting loss of
production. The static/dynamic cylinder
The dynamic retrofitting variant com- section is equipped with heater bands and
bines static mixing zones with a cooling fan or fluid temperature regu-
dynamic components. The lation. This provides the defined temper-
additional processing steps ature control required to influence the
required for foam ex- melt strength that is so important for
trusion are imple- foaming. Static mixing elements keep the
Fig. 4. The melt cooler mented to begin with melt’s texture and temperature perfectly
enables foam densities dynamically in a pro- homogeneous. The same mass-flow reg-
markedly lower than by chemical cessing section down- ulated dosing station is used for prepar-
foaming processes stream from the con- ing the fluid as in the static solution. The
ventional plastication single-phase solution of blowing fluid
cylinder. Depending on and melt is thus created by the dynamic
ensures that the melt is constantly and peripheral circumstances, the components in the lengthened screw and
thoroughly mixed radially. Despite the plastication cylinder is extended complemented by the static mixing zone.
large heat exchange surface, the resulting to include a tempered section for inject- The advantage of the dynamic solution is
empty volume of approx. 75 % causes on- ing and dissolving the blowing agent. If that it generates almost no additional
ly slight pressure losses. The configura- the plastication screw is suitable, it is pressure loss. The special configuration
tion of the melt cooler is determined by lengthened to include additional func- of the dynamic mixing section mixes and
its cooling task, while taking the materi- tional elements. If not possible, the exist- dissolves the blowing fluid thoroughly
als and processing data of the particular ing screw is replaced by a longer, specifi- and efficiently. Cooling takes place via the
application case into consideration. By cally equipped foaming screw. A static cylinder surface whereby static melt cool-
combining these melt coolers with a mixing zone adjoins this dynamic pro- ers can be included here, too (Fig. 5).
retrofit solution, products can be pro- cessing section. Special injectors inject the If the extruder already has a process-
duced with foam densities that lie clear- foaming fluid into the extended section ing length suitable for foaming applica-
tions, the cylinder may not have to be ex-
tended in certain circumstances. Static
mixers in front of the extrusion die en-
sure a texturally and thermally homoge-
neous melt, a fundamental precondition
for obtaining high-quality foamed prod-
ucts.

Industrial Applications

Retrofit concepts of this kind have found


Fig. 5. Dynamic retrofit solution for foaming with CO2 their way into industrial production.
Promix Solutions has retrofitted a large
number of foaming systems for various
areas of application. Among these are ex-
trusion lines with outputs as high as
1,500 kg/h. Substitution of chemical ad-
ditives for foam extrusion as well as the
conversion of conventional extrusion
lines for physical foaming was realized.
One European manufacturer of compos-
ite PP sheet, for instance, has replaced its
previously used chemical foaming
process with a Promix retrofit system for
foaming by CO2. The co-extrusion line
with a total output of 750 kg/h previous-
ly produced PP foamcore sheet with a
density of 600 to 650 kg/m3 and was re-
cently equipped with retrofit concept for
physical foaming (Fig. 6). Annual savings
of over 20 t of chemical masterbatch are
paying for the investment in plant tech-
nology within a few months. Since the line
Fig. 6. Foaming system with melt cooler for foamed sheet extrusion was also equipped with a static melt cool-

110 © Carl Hanser Verlag, Munich Kunststoffe international 9/2013

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EXTRUSION

Fig. 7. Extruded low-density sheet

er, sheet can be produced with markedly


lower density than by a chemical foam-
ing process (Fig. 7). This not only opens up
additional savings potential on the mate-
rials side, but also accesses applications
for the producer that require lower den-
sity PP foam sheet.
One leading manufacturer of plastic
pipe has used the process to realize pro- Fig. 8. Foaming system for extruding PP foamcore pipe
duction of pressureless sewage pipe with
a foamcore layer. To do so, they convert- three extrusion lines have been retrofit- ning stage. In addition to relevant expe-
ed their previous production process for ted with the Promix System (Fig. 8, Title fig- rience, this presumes a holistic approach
single-layer, compact PP sewage pipe in ure). to the extrusion process. Besides the
order to produce multilayer pipe with a choice of raw material and additivizing,
foamcore layer. Their main extruder was Conclusion process control and the ability to judge
retrofitted with a Promix foam system. the suitability of the extrusion die, this in-
Moreover, a new multilayer pipe head and The production of medium-to-high den- volves an understanding of the interac-
ancillary extruder were installed for the sity physically blown foams is being suc- tion among the parameters. If all this is
internal and external pipe layers. Despite cessfully implemented with the aid of given appropriate consideration, the costs
the corresponding investments in an an- retrofit solutions. However, when one of foam extrusion can be significantly re-
cillary extruder, multilayer pipe head and considers the multitude of possible appli- duced and long-term market competi-
foam extrusion system, the investment cations, it becomes clear that the poten- tiveness strengthened. 
paid for itself in short time thanks to a tial for microcellular foamed products is
25–30 % reduction in raw materials con- nowhere near exhausted. Since retrofit so- THE AUTHOR
sumption. Currently three pipe sizes up lutions are by definition always combined CHRISTIAN SCHLUMMER, born 1969, is Director
to DN400 are being produced by this con- with existing plant technology, great sig- of Foam Extrusion and Managing Partner at Promix
cept. These products have passed all tests nificance adheres to the particular sur- Solutions AG of Winterthur, Switzerland;
for the relevant standards. Meanwhile, rounding circumstances right in the plan- c.schlummer@promix-solutions.com

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