Professional Documents
Culture Documents
COMBUSTION PRINCIPLE
& FLUE GAS ANALYSIS
_______________________________________________________________
Youdhiyan Prasetyo
youdhiyan.prasetyo@gmail.com
+62-811886021
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 1/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 2/42
1
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 3/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 4/42
2
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 5/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 6/42
3
800
O
C
Char
burning Heat
production
Ignition
200-
300
Pyrolysis Heat consumption
105
Volatiles Char
Moisture
80-90 % 10-20 %
evaporation
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 7/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 8/42
4
13 Essentials of Optimum Combustion
Fuel Preparation
Distribution to Burners
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 10/42
5
Furnace Residence Time
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 11/42
What is combustion ?
Combustion, or burning, is the
combination of Oxygen with Fuel,
resulting in the release of Heat
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 12/42
6
What is a Flame ?
Flame Front
Combustion reaction occurs at a
rate the produces visible radiation,
fuel-air mixture and combustion
process.
Flame Envelope
Contour along which the
combustion starts, dividing line
between the fuel-air mixture and
the combustion process.
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 13/42
Every Burner
Needs A
Detector!!!
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 14/42
7
Types of Radiation in Combustion
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 15/42
Background Flame
Target Flame
Field of
View
Detector
DISCRIMINATION :
The ability to distinguish the target flame from all other flames in
the furnace and the Background
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 16/42
8
Applications of the Combustion Equation
• Stoichiometric proportions for finding the correct air
supply rate for a fuel.
• Composition of the combustion products is useful
during the design, commissioning and routine
maintenance of a boiler installation.
• On-site measurements of flue gas composition and
temperature are used as a basis for calculating the
efficiency of the boiler at routine maintenance
intervals.
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 17/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 18/42
9
• If we ignore the components which are present in
the parts per million range, air consists of about
0.9% by volume argon, 78.1% nitrogen and 20.9%
oxygen (ignoring water vapor). Carbon dioxide is
present at 0.038%.
• For the purposes of combustion calculations the
composition of air is approximated as a simple
mixture of oxygen and nitrogen:
oxygen 21%
nitrogen 79%
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 19/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 20/42
10
• The proportion of carbon dioxide in this mixture is
therefore
1
100% 9.51% wet and
10.52
1
100% 11.74% dry
8.52
• The instruments used to measure the composition of flue
gases remove water vapor from the mixture and hence give
a dry reading, so the dry flue gas composition is usually of
greater usefulness.
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 21/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 22/42
11
• The resulting composition of the flue gases,
expressed as percentage by volume, is:
Constituent % vol (dry) % vol (wet)
CO2 9.6 8.1
O2 3.8 3.2
N2 86.6 72.6
H2O – 16.1
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 23/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 24/42
12
• Each constituent is considered separately via its own
combustion equation.
For the carbon:
C + O2 → CO2
12kg 32kg 44kg
or for 1 kg of fuel
32 44
0.86 0.86 0.86 (kg)
12 12
• So each kg of oil requires 2.29 kg oxygen for
combustion of its carbon and produces 3.15 kg CO2
as product.
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 25/42
• Similarly
H2 + ½ O2 → H2O
2kg 16kg 18kg
or per kg of fuel
16 18
0.14 0.14 0.14 (kg)
2 2
• In order to burn the hydrogen content of the oil 1.12
kg oxygen are needed and 1.26 kg water is formed.
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 26/42
13
• The total oxygen requirement is thus (2.29 + 1.12) or
3.41 kg.
A given quantity of air consists of 21% by volume of
oxygen.
• We can simply transform to a mass basis thus:
Component vol fraction(vf) vf × MW Mass fraction
Oxygen 0.21 6.72 6.72
0.233
28.84
Nitrogen 0.79 22.12 22.12
0.767
28.84
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 27/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 28/42
14
Combustion Products : Solid and Liquid Fuels
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 29/42
Calculate:
(a) the volumetric air supply rate required if 500 kg/h
of coal is to be burned at 20% excess air.
(b) the resulting %CO2 (dry) by volume in the
combustion products.
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 30/42
15
• Solution:
Lay out the calculation on a tabular basis using 1 kg coal:
Mass (per kg) O2 Required Products
32 44
Carbon 0.9 0.9 2.4 0.9 3.3
12 12
16 18
Hydrogen 0.03 0.03 0.24 0.03 0.27
2 2
32 64
Sulfur 0.005 0.005 0.005 0.005 0.01
32 32
Oxygen 0.025 -0.025 -
Nitrogen 0.01 - 0.01
Ash 0.03 - -
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 31/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 32/42
16
• (b) To get the %CO2 in the combustion products we need
to know the amounts of oxygen and nitrogen in the flue
gases.
Air supplied = 13.5 kg per kg coal, of which oxygen is
13.5 × 0.233 = 3.14 kg, and nitrogen
13.5 – 3.14 = 10.36 kg.
• The combustion products will thus contain:
3.14 – 2.62 = 0.52 kg O2 and
10.36 + 0.01 = 10.37 kg N2.
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 33/42
• A second tabular procedure can now be used for the volumetric composition of the
flue gases:
Product Mass/kg coal Mol. Wt. kmoles/kg coal %volume
CO2 3.3 44 0.075=(3.3/44) 16.25=(0.075/0.4614)
SO2 0.01 64 0.000156 0.03
O2 0.52 32 0.0162 3.51
N2 10.37 28 0.37 80.20
0.4614
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 34/42
17
COMBUSTION PROBLEM ??
FOULING
SLAGGING
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 35/42
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 36/42
18
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 37/42
H = 19
H H H = 1.5 MM
IT. ST HT FT
6.35 W=H W = 2H
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 38/42
19
1900 - 2200 0F
1038 - 1204 0C
1-2 S
3000 0F
1649 0C
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 39/42
t1 t1
L1 L2
T2’
T2
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 40/42
20
EXCESS AIR REQ. COAL COMPARASION
% MILL TEMP.
C
B
5.1 % A
MOISTURE
FLAMMABILITY LIMITS
PERCENTAGE OF STOICHIOMETRIC AIR
FUEL MINIMUM MAXIMUM
NATURAL GAS 64 % 247 %
OIL 30 % 173 %
COAL 8% 425 %
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 41/42
Thank You……..
Combustion Principle & Flue Gas Analysis Youdhiyan Prasetyo © 2015 42/42
21