AITS 1718 PT I ADV Paper 1 ANS SOL PDF

1 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18
FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS
PART TEST – I
PAPER-1
ANSWERS KEY
Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS
1. A, B 19. A, C 37. A, B, C, D
ALL INDIA TEST SERIES
2. B, C 20. A, C 38. A, B, C, D
3. A, C 21. A, B, C, D 39. B, C
4. B, C 22. A, B, C, D 40. A, C
5. A, C, D 23. B, C 41. A, C
6. B, C 24. A, B 42. A, B, C
7. A, C 25. A, C, D 43. A, B, D
8. C 26. B 44. C
9. B 27. A 45. D
10. D 28. D 46. A
11. B 29. B 47. B
12. A 30. A 48. C
13. C 31. D 49. C
14. 4 32. 5 50. 4
15. 9 33. 4 51. 0
16. 4 34. 5 52. 9
17. 8 35. 4 53. 1
18. 8 36. 2 54. 5
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AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 2
Physics PART – I
SECTION – A
1. 20  T1 = 2a (for 2 kg block) ….(i)

T2  10 = 1a (for 1 kg block) ….(ii)
2
1 1  1 1 a
T1  T2  (2)   (2) (for the shaft + disc system)
2 2  2  2 1/ 2
So, T1  T2 = 2a ….(iii)
After solving these three equation
2
a = 2 m/s
3R2 R
2. vCM   R2    (from pure rolling)
4 2
1 1 2
mgh  mv 2cm  mR 2 2 (from conservation of energy)
2 25
10gh
 v CM 
13
3. From free body diagram of sand particle

tan  = S = h/R
1 h
work required =  R2hg  .
3 4 h
The system is in unstable equilibrium.

4. For small angle of inclinations, ball rolls without slipping. So there is no work done by friction. At
some critical angle C, the ball starts slipping. For  > C, energy would be lost due to work done
by kinetic friction. But again for ( = /2), friction would be zero.
5. As going up, speed of the particle is decreasing and hence the time taken in crossing the
windows will be t1 < t2 < t3 (If W 1 = W 2 = W 3)
Simultaneously V  t
 V1 < V2 < V3
For unequal windows t1 = t2 = t3 may be if W 3 < W 2 < W1
dU A B
6. F  3 2
dr r 3r
3A
For equilibrium F = 0, r =
B
B2 A B r
  (for r0  )
6A 2r02 3r0 3

7. P  2(iˆ  ˆj)  2( 2iˆ  2ˆj)
= 6iˆ  2ˆj kg-m/s
3 AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18
  1
So, P makes angle tan1   with positive x-axis which is also the direction of normal force
3
  1
exerted on the ball. So the plane surface makes an angle  tan1   with positive x-axis.
2 3
h
8. Center of mass of a triangular uniform plate from its base is  1m
3
2 7 7 5 2
9. Iaxis = MR2  MR2  MR2    9  9 kg-m
5 5 5 7
U 3
10.  MhCM  (2)    2 m
g 3
11. For elevator acceleration 1.5 m/s2, tension in cord 2 and cord 3 is zero
So, T1  150 = (15) (1.5)
 Tension in cord 1, T1 = 172.5 N
12. For elevator acceleration 1 m/s2, tension in cord 2 and cord 3 decreases.
So, 165 + T  2  (7.5  T) 150 = (15) (1)
 T = 5 N
 Tension in cord 2, T2 = 2.5 N
13. For elevator acceleration 2 m/s2, tension in cord 2 and cord 3 is zero.
So, T1  150 = (15) (2)
 Tension in cord 1, T1 = 180 N
So, displacement of block = 15 cm downward.
SECTION – C
2Rdg
 /2 
14.
0


2  (1  2 )Rg cos d   2(1  2 )R g

 d d
 
2( 1   2 )R g  1Rdg
 a 4 O R
2R

15. At vmax
2 km
Av max F (where k is a proportionalty constant)
v max
m
m2/3 v max
2

v max
1/9
 vmax  m
1
16. 1.25 = (10)t 2
2
 t = 0.5 sec
Distance of the cylinder from the truck = 8  0.5 = 4 m
d v2
17. 2T sin  dN  Rd ( is linear mass density of belt)
2 R
2
 Td  dN = v d O
  
  
2 2 2 
T
 so total normal =  dNcos    T cos d   v 2  cos d
d
  
  
2 2 2
 N = 8 newton dN T
18. F  2mA (v 0  v)2  (v 0  v)2 
= 2(1026 )(1025 )(1) (5  2)2  (5  2)2 

= 0.2  40 = 8 N
Chemistry PART – II
SECTION – A
19. Vn
40
PPCl3  PCl2  2   0.8 atm
100
0.8  0.8
KP   1.6 atm
0.40
KP 1.6
KC  n
  0.037
RT  0.0821 520
Increase in pressure increases the number of moles PCl5(g).
20.
1s 1s
  2
r r
1s
4 r 2  2
o
0.53 A
r
21. All the reactions are disproportionation reactions.
22. CaC2  2H2O  Ca  OH2  C2H2

CaC2  N2  Ca NCN  C
Be2 C  4H2 O  2Be  OH 2  CH4
Cyanamide ion [N = C = N]2- is isoelectronic with CO2.


NO  g  NO2  g 
 N2 O3  g
23. 3P 5P 0
3P  x 5P  x  2y x

2NO2  g   N2 O4  g 
5P  x  2y y
PN2 O4 PN2 O4
KP2  2
, 8 2
P NO2
0.5 
PN2O4  2 atm
 y  2 atm
Ptotal  PNO  PNO2  PN2O3  PN2O4
5.5  3P  x  0.5  x  2
3P = 3, P = 1
5P – x – 2y = 0.5
5 × 1 – x – 2 × 2 = 0.5, x = 0.5 atm.
PN2 O3
K P1 
PNO  PNO2 
0.5
  0.4 atm
2.5  0.5
PNO  2.5 atm PNO2  0.5 atm PN2O3  0.5 atm,PN2O4  2atm
24. B – F bond in BF3 is smaller due to P  P back bonding.

B3N3H6  9H2O  3NH3  3H3BO3  3H2
In T I3 oxidation state of T is +1.
25. NH4 OH HCl 

 NH4 Cl H2 O
600.1 6 400.1 4 0
2 0 4
The resulting solution is a basic buffer.
NH4 
pOH  pK b  log
NH4OH
4
pOH  4.74  log  5.04
2
pH  14  5.04  8.96
26. Decomposition of HI on surface of gold is a zero order reaction.
st 2.303 a
27. For a 1 order reaction k  log .
t ax
nd 1 1 1
28. For 2 order reaction k    .
t  a  x a 
Solution for the Q. No. 29 to 31.

F
F F
Br
F F
Hybridisation  sp3 d2
Shape – square pyramidal
Lone pair in central atom = 1

Cl

ICl2  I
Cl
Hybridisation  sp3 d
Shape – Linear
Lone pair in the central atom = 3
XeOF2 Xe O
F
Hybridisation  sp3 d
Shape – T-shaped
Lone pair in the central atom = 2
SECTION – C
 1
32. 2LiNO3   Li2O  2NO2  O2
2
1 mol of LiNO3 will produce NO2 = 1
2Mg  NO3 2  
 2MgO  4NO2  O2
1 mol of Mg NO3  2 will produce NO2 = 2
2Ca NO3 2 

 2CaO  4NO2  O2
1 mol of Ca NO3  2 will produce NO2 = 2

2NaNO3   2NaNO2  O2
Total number of moles of NO2 produced = 5
Z
33. V  2.188  10 6  m / sec.
n
2.188  106  1
n  4
5.47  105
 According to de-Broglie, total number of waves made by an electron in one complete revolution
=n=4
34. The following species are paramagnetic.

N2 , O2 , B 2 , H2 , He 2
35. CH3 COOH NaOH  CH3 COONa  H2 O

60.10.6 x0.1 0
0.6  0.x 0.x
The resulting solution is a buffer solution.
CH3 COO   0.x
pH  pK a  log  0.3  log
0.6  0.x
CH3COOH
0.x
0.x log2  log
pH  pK a  log 0.6  0.x
0.6  0.x
0.x
0.x 2
5.04  4.74  log 0.6  0.x
0.6  0.x x =4
36. 

A  g 
 B  g  C  g 
10 1  10 10 
100 83
D  50, d  41.5
2 2
Dd
 
d  n  1
50  41.5
  0.2
41.5  2  1
 Number of moles of ‘C’ at equilibrium  10   10  0.2  2
Mathematics PART – III
SECTION – A
37. Shown in the figure y-axis
y = {x}
x-axis
0 3  4
 3
x x
2 2
1 1
x x
38. (A) x  x
 2 1
4  x  2  1
 x 

 4  x  1/ x  2  1

1
x
1 x 1
So,   2

8  1  8
4   x    1
 x 
 
 
 x x2  1  
1

0

 4 x 4  x2  1 8 
  
1
So: f  x   2x   x   sin2x injective but not onto
2
(B) f(x) = –x3 cos x + x2 (3 sin x + 2 cos x) + 4x(sin x + 2)
Many one onto
1 n1  r  4 3 2
39. Tn   f   where f(x) = x + x + x + 2, f(x) is an increasing function for  x > 0.
n r 0  n 
1  1  n  1
Tn  f  0   f   .....  f  
n  n
   n 
1
167
x 
4
Tn   x3  x2  2 dx 
0
60
1 n  r  1  1  r   167
Sn   f   > f    .....  f  n   = 60
n r 1  n  n   n  
n
sin t  cos t
40. (A) Let  dt  An
0
t
 2
1 sin t  cos t dt 
An   sin t  cos t dt   .....
  0 

2 

1 1 1 1  
>  1    .....     sin t  cos t dt 
 2 3 
n  0 

2 2 1 1 1
>  1    .....  
  2 3 n
3 sin x  8  3 sin x
(C)
2
 3 sin x 8  3 sin x  
3 1 4
(D) 1  tan x  3 and  
 x 
3 tan x 4 3
So;  
 x 
3
1 y y
41.
2
  
cosec 2 x2  y 2 d x 2  y 2  2   d  
x x

4
1 2 y / x
  cot x 2  y 2 
2
 4

c 0
7/8
42. I  f  f  x   dx ..... (1)
1/8
7/8 7/8
I  f  f 1  x   dx   f 1  f  x   dx ..... (2)
1/8 1/8
3
So, 2I 
4
 2 2 
2  sin2x  x sec 2 x  tan x  cos x   cos x  
43. e
x sec x  tan x
 x tan x 
2 
dx =  e
 2
x sec 2
x  tan 
x    

  2  
2 cos2 x
= e x sec x tan x  c
2
44.-46. (I) f(x) = ||x – 6| – |x – 8|| – |x2 – 4| + 3x – |x – 7|3 is continuous  x  R and not differentiable at
x = –2, 2, 6, 7 & 8
(II) f(x) = (x2 – 9)|x2 + 11x + 24| + sin|x – 7| + cos|x – 4| + (x – 1)3/5 sin(x – 1) is continuous
 x  R and not differentiable at x = –8 & 7
 3 /5 3
 x  1  2 : x  1

 1
 
(III) f  x    x   cos 1 4x 3  3x : 1  x  1 is discontinuous at x = –1 & 1 not differentiable
2

 5/3
 x  1 : 1 x  2

1
at x = –1,  & 1
2
(IV) f(x) = {sin x}{cos x} + (sin3{x})([x]), x  [–1, 2]

Let g  x    sin   x    x   sin2 x


cont. at x  I
g(I+) = g(I–) so differentiable at x = I and for {sin x}{cos x}

 3
Doubtful points for non differentiability are x = 0, , ,
2 2

 {sin x}·{cos x} is discontinuous at x = 0, , 2
2

So not differentiable at x = 2n, 2n +
2
47.-49. (I)
 3  1 3 3
 x 1  x  3  
4
  4  x2    4  x2 
(II) u  sin  ln     cos  ln  
  1 x    1 x 
     
4  x2
 0 
1 x
 4  x2 
  ln  
 1 x 
 
So;  2  u  2
 1  1 
(III) Let |x + 5| = t; g(t)   0,    
 2 4
gt  
 t  2
 t  2  t  2 
(IV)   cos–1 x  
– < ln(cos–1 x)  ln  < 2
SECTION – C
3 2 2
50. Let cot A = a then a + a |a + x| + |a x + 1| = 1
3 2 2 2 2 3
|a + a x| + |a x + 1| = (a x + 1) – (a x + a )
|| + || =  – 
So,   0 and   0
Now take cases: a  –1 and –1 < a  0 & 0 < a  1
 1 1 
Finally we get, a  ( ,  5]   , 
 5 6
51.  0  f(x)  2
and g(3)   2 5,  4    4, 2 5 
4 4
Also  g  x  dx   f   x  dx   f  4   f  0    2, 2   2 5
0 0
Case-I: Let g(x) > 0 and g(x) > 0 S K
4
4
Clearly  g  x  dx  Area MDKS  = 4
0 O M D
Which is a contradiction x=3 x=4
Thus, there is no such C
Similarly case-II: Let g(x) < 0 and g(x) < 0
 x  13  3x
52. f   f  1 7 9 15
 2   2  0 2 3 5 6 8 9
2 2 2 2
f(x) = f(8 – x)
f(x) = –f(8 – x)
 1  15 
f     f     0
2  2
f(2) = –f(6) = 0
f(3) = –f(5) = 0
9 7
f     f     0
2
  2
d
 f   x  f   x  
f(0) = –f(8); h  x  
dx
Clearly: h(x) has minimum 18 zeroes
53. y = 0  x = 2 Y
Let P be the point of inflection
So; P  (2, 2b – a – 16)
Equation of tangent line passing through inflection
P
Point: y = (b – 12)x – a + 8 .....(1)
Let Q  (2 + h, 3h – 1)
Locus of Q: 3x – y = 7 ..... (2)
X
From equation (1) and (2), we get ! x=2
So; a = 15 and b = 15
 k 4
 2k 3  k 2  k  1  1 1
n
n 5 x 4 dx   x 5  
54. lim      
n 
k 1  3n5  n2  n  5k  0
3 3  5 0 15
5
n

AITS 1718 PT I ADV Paper 1 ANS SOL PDF

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AITS 1718 PT I ADV Paper 1 ANS SOL PDF

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1 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

10. D 28. D 46. A

11. B 29. B 47. B

12. A 30. A 48. C

13. C 31. D 49. C

14. 4 32. 5 50. 4

15. 9 33. 4 51. 0

16. 4 34. 5 52. 9

17. 8 35. 4 53. 1

18. 8 36. 2 54. 5

1. 20  T1 = 2a (for 2 kg block) ….(i)

3. From free body diagram of sand particle

18. F  2mA (v 0  v)2  (v 0  v)2 

= 2(1026 )(1025 )(1) (5  2)2  (5  2)2 

21. All the reactions are disproportionation reactions.

22. CaC2  2H2O  Ca  OH2  C2H2

24. B – F bond in BF3 is smaller due to P  P back bonding.

25. NH4 OH HCl 

26. Decomposition of HI on surface of gold is a zero order reaction.

Solution for the Q. No. 29 to 31.

34. The following species are paramagnetic.

35. CH3 COOH NaOH  CH3 COONa  H2 O

Mathematics PART – III

g(I+) = g(I–) so differentiable at x = I and for {sin x}{cos x}

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