4541/3

Kimia
Tingkatan 5
Kertas 3
2016
1 jam 30 minit

SEKOLAH MENENGAH KEBANGSAAN TELOK KERANG,

82020 PONTIAN, JOHOR DARULTAKZIM

PEPERIKSAAN PERCUBAAN SPM

2016

KIMIA

Kertas 3

Satu jam tiga puluh minit

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. Tuliskan nama dan tingkatan pada ruang Untuk Kegunaan Pemeriksa

yang disediakan.
Bahagian Markah Penuh Markah Diperoleh
2. Kertas soalan ini adalah dalam dwibahasa.
3. Soalan dalam bahasa Inggeris mendahului 1 21
soalan yang sepadan dalam bahasa
Melayu. 2 12
4. Calon dibenarkan menjawab keseluruhan 3 17
atau sebahagian soalan sama ada dalam
bahasa Inggeris atau bahasa Melayu. Jumlah

Kertas soalan ini mengandungi 9 halaman bercetak

1. An experiment is carried out to determine the heat of combustion of four alcohols, methanol
(CH3OH), ethanol (C2H5OH), propanol (C3H7OH) and butanol (C4H9O11). The initial mass of spirit
lamp containing alcohol is measured before burning the alcohol. Then, 200 cm3 of water is heated
with alcohol in the spirit lamp until the temperature of water rises by 30 °C. The final mass of
lamp containing alcohol is measured again after burning. Diagram 1 shows the set up of apparatus
and thermometer reading of water for this experiment.

Satu eksperimen telah dijalankan untuk menentukan haba pembakaran empat jenis alkohol,
metanol (CH3OH), etanol (C2H5OH), propanol (C3H7OH) dan butanol (C4H9OH). Jisim awal
pelita yang mengandungi alkohol diukur sebelum pembakaran alkohol. 200 cm3 air kemudian
dipanaskan dengan alkohol dalam pelita sehingga suhu air meningkat sebanyak 30 °C. Jisim akhir
pelita yang mengandungi alkohol diukur sekali lagi selepas pembakaran. Rajah 1 menunjukkan
susunan radas dan bacaan termometer suhu air bagi eksperimen ini.

Diagram 1/ Rajah 1

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(a) Give one inference based on the observation in Diagram 1.

Berikan satu inferens berdasarkan pemerhatian dalam Rajah 1.

……………………………………………………………………………………………………..

……………………………………………………………………………………………………..

[3 marks]

(b) For this experiment, state:

Bagi eksperimen ini, nyatakan:

(i) The manipulated variable

Pembolehubah dimanipulasi

………………………………………………………………………………………………………

(ii) The responding variable

Pembolehubah bergerak balas

………………………………………………………………………………………………………

(iii) The fixed variable

Pembolehubah dimalarkan

………………………………………………………………………………………………………
[3 marks]
(c) State one hypothesis for this experiment.

Nyatakan satu hipotesis bagi eksperimen ini.

………………………………………………………………………………………………………

………………………………………………………………………………………………………

………………………………………………………………………………………………………
[3 marks]

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(d) Table 2 shows the initial and final readings of the electronic balance for the mass of spirit lamp before
burning and after burning of four types of alcohol.

Jadual 2 menunjukkan bacaan awal dan akhir penimbang elektronik bagi jisim pelita sebelum
pembakaran dan selepas pembakaran bagi empat jenis alkohol.

Table 2
Jadual 2

4
Based on Table 2, state the mass of the alcohols used in space provided into two decimal places.

Berdasarkan Jadual 2, nyatakan jisim alkohol yang digunakan dalam ruangan yang disediakan kepada
dua tempat perpuluhan.

[3 marks]

(e) Calculate the heat of combustion of methanol.

Hitungkan haba pembakaran bagi metanol.

[Heat capasity of water / Muatan haba tentu air = 4.2 J g-1 °C-1]

[Molar mass of methanol / Jisim molar metanol = 32 g mol-1]

[3 marks]

(f) Given the heat of combustion of ethanol and butanol are -1175 kJ mol-1 and -2475 kJ mol-1
respectively. By using the answer obtained in 2(e), plot a graph of heat of combustion against
number of carbon atoms per molecule.

Diberi haba pembakaran bagi etanol dan butanol adalah -1175 kJ mol-1 and -2475 kJ mol-1 masing-
masing. Dengan menggunakan jawapan yang diperolehi dalam 2(e), plotkan graf bagi haba
pembakaran melawan bilangan atom karbon per molekul

5
 Heat of combustion against number of carbon atoms per molecule

[3 marks]
(g) Using the plotted graph, predict the heat of combustion of propanol.
Dengan menggunakan graf yang telah diplot, ramalkan haba pembakaran bagi propanol.

………………………………………………………………………………………………………..
[3 marks]

6
2.

Dirty cloth is washed using ceansing Cloth becomes clean

agent X in hard water Pakaian menjadi bersih
Pakaian kotor dicuci dengan agen
pencuci X dalam air liat

Dirty cloth is washed using cleansing The cloth remain dirty and scum
agent Y in hard water is formed
Pakaian kotor dicuci dengan agen Pakaian kekal kotor dan kekat
pencuci Y dalam air liat terbentuk

Diagram 2
Rajah 2

(a) Give one inference based on the observation in Diagram 2.

Berikan satu inferens berdasarkan pemerhatian dalam Rajah 2.

……………………………………………………………………………………………………..

……………………………………………………………………………………………………..

[3 marks]

7
(b) Based on the diagram 2, what is the operational definition of effectiveness of saop and
detergen?
Berdasarkan rajah 2, apakah definisi secara operasi bagi keberkesanan sabun dan
detergen?

………...……………………………………………………………………………………...

……….……………………………………………………………………………………
[3 marks]

(a) State one hypothesis for this experiment.

Nyatakan satu hipotesis bagi eksperimen ini.

…………………………………………………………………………………

…………………………………………………………………………………

…………………………………………………………………………………
[3 marks]

(b) For this experiment, state:

Bagi eksperimen ini, nyatakan:
(i) The manipulated variable
Pembolehubah dimanipulasikan

…………………………………………………………………………

(ii) The responding variable

Pembolehubah bergerak balas

………………………………………………………………………
(iii) The constant variable
Pembolehubah dimalarkan

………………………………………………………………………
[3 marks]

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3.

Ionic compound can conduct electricity in aqueous and molten states but
covalent compound cannot conduct electricity in all states.

Sebatian ion boleh mengkonduksikan elektrik dala mkeadaan leburan dan

larutan akueus tetapi sebatian kovalen tidak boleh mengkonduksikan elektrik
dalam sebarang keadaan.

Using lead (II) bromide as an example of ionic compound and naphthalene as an example
of covalent compound, plan a laboratory experiment to compare the electrical conductivity
of molten ionic and covalent compounds.
Dengan menggunakan plumbum(II) bromida sebagai contoh sebatian ion and naftalena sebagai
contoh sebatian kovalen, rancangkan satu eksperimen untuk membandingkan kekonduksian
elektrik leburan sebatian ion dan sebatian kovalen.

Your planning should include the following aspects:

Perancanganandahendaklahmengandungiaspekberikut:

(a) Problem statement

Pernyataanmasalah

(b) All the variables

Semuapembolehubah

(c) Hypothesis
Hipotesis

(d) List of materials and apparatus

Senaraibahandanradas

(e) Procedure
Prosedur

(f) Tabulation of data

Penjadualan data

[17 marks]

END OF QUESTION PAPER

KERTAS SOALAN TAMAT

9
 Trial phg 2011
No Skema pemarkahan Markah
soalan
2(a) 3
[Able to state the inference correctly ]
Sample answer:
Water absorbed heat energy // Exothermic reaction
[Able to state the inference ] 2
Sample answer:
Water temperature increase/rises.// Methanol releases heat.//Mercury expands.
[Able to state an idea of inference] 1
Sample answer:
Water becomes hot.
[No response given or wrong response] 0
2(b) [Able to state all variables correctly] 3
Sample answer:
Manipulated variable: Types of alcohol
Responding variable: Heat of combustion
Fixed variable: Volume of water // copper can

2(b) [Able to state any 2 variables correctly] 2

[Able to state any 1 variable correctly] 1
[No response given or wrong response] 0
2 [Able to state the relationship between the manipulated variable and the responding variable with 3
(c) direction correctly]
Sample answer:
The higher the number of carbon atoms per molecule, the higher the heat of combustion.//
When the number of carbon atoms per molecule increases, the heat of combustion increases.
Note : RV  MV score 2

[Able to state the relationship between the manipulated variable and the responding variable] 2
Sample answer:
The higher the number of carbon atoms, the higher the heat of combustion.

[Able to state an idea of hypothesis] 1

Sample answer:
Different alcohols different heat of combustion.//
Type of alcohol affects heat of combustion.

[No response given or wrong response] 0

2(d) [Able to state all the mass of alcohols and round off into two decimal places correctly] 3

10
 Sample answer:
Methanol = 1.54
Ethanol = 1.20
Propanol = 1.10
Butanol = 1.61
[Able to state any three the mass of alcohols and round off into two decimal places correctly] 2
[Able to state all the mass of alcohols in four decimal places correctly.]
[Able to state any two the mass of alcohols and round off into two decimal places correctly] 1
[No response given or wrong response] 0
2(e) Able to calculate the heat of combustion of methanol by fulfill the following criteria : 3
(i) Heat absorbed by water
(ii) Number of mole
(iii) Heat of combustion

Sample answer:
Heat absorbed by water = 200x4.2x30 J // 25200 J
Number of mole = 1.54/32 // 0.048
Heat of combustion = - 25200/ 0.048 J mol-1 // - 525000 J mol-1 // -525 kJ mol-1
Note: without unit, score 2
Able to calculate the heat of combustion of methanol by fulfill any two criteria. 2

Sample answer:
Heat absorbed by water = 100x4.2x30 J // 12600 J …….. X
Number of mole = 1.54/32 // 0.048 ……….
Heat of combustion = - 12600/ 0.048 J mol-1 // - 262500 J mol-1 // -262.5 kJ mol-1 ……

Able to calculate the heat of combustion of methanol by fulfill any one criteria. 1

Sample answer:
Heat absorbed by water = 100x4.2x30 J // 12600 J …….. X
Number of mole = 1.04/32 // 0.0325 ……….X
Heat of combustion = - 12600/ 0.0325 J mol-1 // - 387692 J mol-1 // -387.692 kJ mol-1 ……

[No response given or wrong response] 0

2(f) Able to plot graph accurately. 3

Criteria:
i. Axis with correct label and unit.
ii. Consistent scale
iii. Size of graph: at least half of graph paper
iv. Transfer all points correctly
v. Straight line

Able to plot graph less accurately. 2

Any four criteria

Able to show minimum requirement of plotting graph 1

Criteria:

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 i. Axis with correct label / unit.
ii. Transfer all points
iii. Straight line

[No response given or wrong response] 0

2(g) Able to predict the heat of combustion of propanol correctly. 3

Criteria:
i. Dotted line is drawn on the graph.
ii. Value based on graph.
iii. Negative sign with correct unit.

Able to predict the heat of combustion of propanol incompletely. 2

Any two criteria

Able to give value of the heat of combustion of propanol. 1

Criteria (i)/(ii)

[No response given or wrong response] 0

Joho set 2 2016

Question Explanation Maximum
score
2(a) [Able to state the problem statementcorrectly] 3

Sample answer :
Which compounds conducts electricity in molten state?
Can lead (II) bromide and naphthalene conduct electricity in molten
state?
[Able to state the problem statement less correctly] 2

Sample answer :
Which compounds conducts electricity?
Can lead (II) bromide and naphthalene conduct electricity?
[Able to state the idea of problem statement] 1

Sample answer :
Which compounds conducts electricity in aqueous state?

12
 [Wrong response] 0

Sample answer :
How to compare the electrical conductivity of molten ionic and
covalent compounds?

Question Explanation Maximum

score
2(b) [Able to state the variables correctly] 3

Sample answer :
(a) Manipulated variable : Type of compound
(b) Responding variable : Conductivity of electric
(c) Fixed variable : molten state

1 mistake 2
2 mistakes 1
3 mistakes 0

Question Explanation Maximum

score
2(c) [Able to state the hypothesiscorrectly] 3

Sample answer :
Ionic compound/Lead (II) bromide conducts electricity in molten
state whereas covalent compound/naphthalene cannot conduct
electricity in molten state.

[Able to state the hypothesis less correctly] 2

Sample answer :
Ionic compound/Lead (II) bromide conducts electricity whereas
covalent/naphthalene compound cannot conduct electricity

[Able to state the idea of hypothesis] 1

Sample answer :
Ionic compound/Lead (II) bromide conducts electricity
[Wrong response] 0

13
Question Explanation Maximum
score
2(d) [Able to list the apparatusand materials correctly] 3

Sample answer :
Apparatus :
Crucible, wire gauze, tripod stand, Bunsen burner, connecting wire,
voltmeter /bulb, carbon electrodes, battery, spatula, clay pipe
triangle

Materials :
Lead (II) bromide, naphthalene

1 mistakes 2
More than 2 mistakes 1
[Wrong response] 0

Question Explanation Maximum

score
2(e) [Able to state the procedurecorrectly] 3

Sample answer :

Procedure :
1. Add lead (II) bromide powder to a crucible
2. Place it on a clay pipe triangle
3. Connect the carbon electrode to the battery and voltmeter
4. Dip the carbon electrode into lead (II) bromide
5. Heat it very strongly
6. Record the voltmeter reading
7. Repeat experiment using naphthalene

[Able to state the procedure less correctly] 2

[Able to state the procedure less correctly] 1

[Wrong response] 0

Sample answer :

14
 Wrong procedure of experiment is given

Question Explanation Maximum

score
2(f) [Able to give tabulation of data correctly] 3

Sample answer :

Substance Voltmeter reading / v

Lead (II) bromide
Naphthalene
[Able to give tabulation of data less correctly] 2

[Able to give tabulation of data less correctly] 1

[Wrong response] 0

1. An experiment to determine the heat of combustion of alcohol is conducted in lab as diagram

below. Methanol, ethanol, propanol and butanol are burnt in a spirit lamp and the heat released is
transferred to the can of metal which contained 200 cm3 of distilled water. The temperatures
before combustion and after combustion of distilled water are measured.

The flame of spirit lamp is put off after the temperature of distilled water increase by 300C.

Metal container Thermometer

Clay pipe triangle 200 cm3 of distilled water

Wind shield Spirit lamp

Wooden block Methanol

Diagram 1.1

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 Methanol Ethanol Propanol Butanol
Type of alcohols
CH3OH C2H5OH C3H7OH C4H9OH

Mass of spirit
lamp before
123.56 134.78 112.42 128.73
combustion /
gram

Mass of spirit
lamp after
122.35 133.84 111.65 128.00
combustion /
gram

Mass of alcohol /
1.21 0.94 0.77 0.73
gram

Table 1

Diagram below shows the thermometer before and after the combustion of alcohols.

Type of alcohol Before combustion After combustion

30

60
Methanol

20

Ethanol
30

60
16
20
 30

Propanol 60

20

30

Butanol 60

20

Diagram 1.2

(a) Construct a table to record the temperature for distilled water before and after the combustion
and the increase in temperature.

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 [ 3 marks ]

(b) State the variables for this experiment

(i) Manipulated variable

………………………………………………………………………………………………

(ii) Responding variable

………………………………………………………………………………………………

(iii) Fixed variable

……………………………………………………………………………………………..
[ 3 marks ]

(c) The Heat of Combustion of alcohols is listed as below.

Alcohol Heat of Combustion / kJ mol-1

Methanol, CH3OH - 715
Ethanol, C2H5OH - 1371
Propanol, C3H7OH - 2100
Butanol, C4H9OH - 2673

Base on the table given above; state the inference of this experiment.

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 ………………………………………………………………………………………………..

………………………………………………………………………………………………..

………………………………………………………………………………………………..
[ 3 marks ]

(d) From the table in question (c) above, predict the heat of combustion of pentanol.

………………………………………………………………………………………………..
[ 3 marks ]

(e) From table 1, what is the relationship between the type of alcohol; to the mass of alcohol
burnt to increase the temperature of distilled water by 300C.?

………………………………………………………………………………………………..

………………………………………………………………………………………………..

………………………………………………………………………………………………..
[ 3 marks ]

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