system prop.

A = 2.25
P1sat = 75 kPa
P2sat = 110 kPa

AT vapor-liq-liq equilibrium
from eqn1 x1 alpha x2 alpha left hand right hand obj func gamma 1 alpha
0.22440543 0.77559457 0.8686454 0.8686454 1.645E-16 3.8708751224

from eqn2 x1 beta x2 beta left hand right hand obj func gamma 1 beta
0.77559457 0.22440543 0.8686454 0.8686454 1.645E-16 1.1199735203

from eqn3 P* = 160.6994 kPa

from eqn4 y* = 0.4054054

AT alpha vapor-liq equilibrium

from eqn5,6 P y1 x1 gamma1 alpha gamma1*x1*psat1
110 0 0 9.4877358364 0
121.570428 0.1135735 0.0213371 8.627953116 13.8071795822
130.901638 0.19223162 0.0426743 7.86217525 25.1634342755
138.377944 0.24906861 0.0640114 7.1790572257 34.4656018687
144.32165 0.291345 0.0853485 6.5687368156 42.0473906717
149.003141 0.32341327 0.1066856 6.0226282869 48.1895932883
152.649296 0.3480436 0.1280228 5.5332463847 53.1286103291
155.450511 0.36708513 0.1493599 5.0940559385 57.0635710918
157.56655 0.38182145 0.170697 4.6993431842 60.162288218
159.131439 0.39317336 0.1920341 4.3441055161 62.5662422601
160.257548 0.40182044 0.2133713 4.0239569012 64.3947583152
161.039007 0.40827692 0.2347084 3.7350466205 65.7485090816
161.554554 0.41294073 0.2560455 3.4739893674 66.7124557822
161.869909 0.41612626 0.2773826 3.2378050359 67.3583194954
162.039761 0.41808664 0.2987198 3.0238667873 67.7466598222
162.109407 0.41902951 0.3200569 2.8298561989 67.9286249095
162.116117 0.41912814 0.341394 2.6537244799 67.9474261624
162.090254 0.41852968 0.3627312 2.4936588904 67.8395821253
162.056184 0.41736123 0.3840683 2.3480536305 67.6359686677
162.033011 0.41573446 0.4054054 2.2154845695 67.3627065039

from eqn7,8 AT beta vapor-liq equilibrium

P y1 x1 gamma1 beta gamma1*x1*psat1
75 1 1 1 75
83.8387742 0.88622228 0.9904611 1.0002047516 74.2997892987
91.9170305 0.80104232 0.9809221 1.000819258 73.6294309453
99.2938292 0.73507187 0.9713832 1.0018442744 72.9881005206
106.023784 0.68262993 0.9618442 1.0032810613 72.3750078889
112.157403 0.64007719 0.9523053 1.0051313869 71.7893955759
117.741402 0.60497443 0.9427664 1.0073975308 71.2305372083
122.818994 0.57562543 0.9332274 1.0100822889 70.6977360122
127.430154 0.55081408 0.9236885 1.0131889787 70.1903233652
131.611869 0.52964568 0.9141495 1.0167214466 69.7076573983
135.39836 0.51144727 0.9046106 1.0206840755 69.2491216433
138.821294 0.49570294 0.8950716 1.0250817939 68.8141237216
141.909975 0.48201047 0.8855327 1.0299200864 68.4020940709
144.691521 0.47005162 0.8759938 1.0352050048 68.0124847055
147.191034 0.45957125 0.8664548 1.0409431809 67.6447680073
149.431744 0.45036238 0.8569159 1.0471418401 67.2984355422
151.435153 0.44225528 0.8473769 1.0538088171 66.9729969
153.221163 0.43510947 0.837838 1.0609525716 66.6679785528
160.386621 0.40666975 0.77968 1.1154044007 65.2243877375
161.629759 0.40160195 0.7615265 1.13650374 64.9108260973
163.212021 0.39486278 0.7233707 1.187889816 64.446352472
163.813817 0.39207057 0.6852149 1.2497601795 64.2265759802
163.819113 0.39206956 0.6470592 1.323495378 64.2284875534
163.504756 0.39404216 0.6089034 1.4107933717 64.4277671115
163.066549 0.39736547 0.5707477 1.5137341649 64.7970162985
162.637683 0.40152785 0.5325919 1.6348618232 65.303559895
162.301261 0.40607595 0.4944361 1.7772876015 65.9066389346
162.098094 0.41057711 0.4562804 1.9448208795 66.5537663698
162.030497 0.4145882 0.4181246 2.1421344398 67.1759313262
162.033011 0.41573446 0.4054054 2.2154845695 67.3627065039

P-X-Y Diagram

190

170

150

P
(kPa) 130

110

90
 P
(kPa) 130

110

90

70
0 0.1 0.2 0.3 0.4 0.5 0.6

x1 , y1
 P* x1 alpha x1 beta
190 0.2244054 0.7755946
160.6994 0.2244054 0.7755946

gamma 1 alpha gamma 2 alpha

3.8708751224 1.1199735203

gamma 1 beta gamma 2 beta

1.1199735203 3.8708751224

gamma2 alpha y2 x2 gamma2*x2*psat2

1 1 1 110
1.001024889 0.8864265 0.9786629 107.7632483683
1.0041058628 0.8077684 0.9573257 105.7382034501
1.0092619061 0.7509314 0.9359886 103.9123424866
1.016524877 0.708655 0.9146515 102.2742596787
1.0259398349 0.6765867 0.8933144 100.8135473747
1.0375655072 0.6519564 0.8719772 99.5206858636
1.0514748998 0.6329149 0.8506401 98.3869401422
1.0677560617 0.6181786 0.829303 97.4042620892
1.0865130144 0.6068266 0.8079659 96.5651965209
1.1078668597 0.5981796 0.7866287 95.8627896084
1.1319570827 0.5917231 0.7652916 95.2904981151
1.1589430692 0.5870593 0.7439545 94.8420978537
1.1890058611 0.5838737 0.7226174 94.5115896738
1.2223501768 0.5819134 0.7012802 94.2931011573
1.2592067276 0.5809705 0.6799431 94.1807820285
1.2998348671 0.5808719 0.658606 94.1686910609
1.3445256163 0.5814703 0.6372688 94.2506719862
1.3936051125 0.5826388 0.6159317 94.4202155698
1.4474385414 0.5842655 0.5945946 94.6703046024

gamma2 beta y2 x2 gamma2*x2*psat2

9.4877358364 0 0 0
 9.0909507471 0.1137777 0.0095389 9.5389848851
8.714326993 0.1989577 0.0190779 18.2875995664
8.356727223 0.2649281 0.0286168 26.3057287034
8.0170838753 0.3173701 0.0381558 33.6487762554
7.6943945999 0.3599228 0.0476947 40.3680076104
7.3877179996 0.3950256 0.0572336 46.5108648992
7.096169665 0.4243746 0.0667726 52.1212576571
6.8189184831 0.4491859 0.0763115 57.2398308187
6.5551831989 0.4703543 0.0858505 61.9042118633
6.3042292128 0.4885527 0.0953894 66.1492387835
6.0653655953 0.5042971 0.1049284 70.0071704056
5.8379423049 0.5179895 0.1144673 73.5078804701
5.6213475941 0.5299484 0.1240062 76.6790367624
5.41500559 0.5404287 0.1335452 79.5462664773
5.2183740372 0.5496376 0.1430841 82.1333089088
5.0309421916 0.5577447 0.1526231 84.4621564617
4.8522288548 0.5648905 0.162162 86.5531849067
3.9266122468 0.5933302 0.22032 95.1622331227
3.6870466442 0.5983981 0.2384735 96.7189331356
3.2457507009 0.6051372 0.2766293 98.7656683089
2.8760531105 0.6079294 0.3147851 99.5872406063
2.565215679 0.6079304 0.3529408 99.5906257728
2.303011389 0.6059578 0.3910966 99.0769891048
2.0811986046 0.6026345 0.4292524 98.2695331026
1.8931114569 0.5984721 0.4674081 97.3341233726
1.7333412821 0.593924 0.5055639 96.3946218314
1.5974864976 0.5894229 0.5437197 95.5443279304
1.4819568179 0.5854118 0.5818754 94.8545654106
1.4474385414 0.5842655 0.5945946 94.6703046024

P-X-Y Diagram
0.4 0.5 0.6 0.7 0.8 0.9 1

x1 , y1
at VLLE
x1alpha * gamma1alpha = x2alpha * gamma2alpha ----eqn1
x1beta * gamma1beta = x2beta * gamma2beta ----eqn2
P* = x1alpha*gamma1alpha*P1sat + x2beta*gamma2beta*P2sat ----eqn3
y* = x1alpha*gamma1alpha*P1sat / P* ----eqn4

at VLE alpha phase and beta phase

P = x1alpha*gamma1alpha*P1sat + x2alpha*gamma2alpha*P2sat ----eqn5

y1alpha = x1alpha*gamma1alpha*P1sat / P ----eqn6
P = x1beta*gamma1beta*P1sat + x2beta*gamma2beta*P2sat ----eqn5
y1beta= x1beta*gamma1beta*P1sat / P ----eqn6