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1 AITS-PT-II-PCM-Sol -JEE(Main)/18

FIITJEE JEE(Main)-2018
ANSWERS, HINTS & SOLUTIONS
PART TEST – II
(Main)

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS


1. C 31. B 61. A
ALL INDIA TEST SERIES

2. B 32. C 62. A
3. D 33. B 63. C
4. B 34. B 64. A
5. A 35. B 65. B
6. B 36. D 66. C
7. C 37. D 67. D
8. B 38. C 68. C
9. C 39. C 69. D
10. B 40. A 70. B
11. B 41. A 71. B
12. A 42. D 72. B
13. B 43. A 73. C
14. A 44. B 74. B
15. A 45. C 75. A
16. C 46. A 76. C
17. D 47. B 77. A
18. A 48. D 78. B
19. C 49. C 79. C
20. D 50. D 80. A
21. B 51. C 81. C
22. C 52. A 82. B
23. B 53. C 83. D
24. C 54. B 84. B
25. A 55. C 85. D
26. B 56. D 86. B
27. B 57. C 87. A
28. C 58. C 88. D
29. D 59. B 89. B
30. D 60. C 90. C

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AITS-PT-II-PCM-Sol-JEE(Main)/18 2

Physics PART – I

5R
1. QAB = nCPT = 2   2T0  T0   5RT0
2
In the process BC, PT2 = constant
PP2V2 = constant
PV2 = constant
R 3R R
 molar heat capacity, C = Cv   
1 x 2 1 2
R
C
2
R
 QBC = nCT = 2  (T0  2T0 )  RT0
2
QAB 5RT0
  5
QBC RT0

2. In steady state 3T0 T T + dT T0


Q dT
 kA
t dx
x dx
Q dT
 TA
t dx
 T0
Q
t 
dx  A
0
 TdT
3T0

Q
  4AT02 …(i)
t
Similarly,
 /2 T
Q
t  dx  A  TdT
0 3T0

Q  (9T02 T2 )
 A …(ii)
t 2 2
Dividing (ii) by (i)
9T02  T2  4T02
T2  5T02
T  5T0

3. Given PT3 = constant


T 3
T  constant
V
 V = kT4
The coefficient of thermal expansion is
dV 4kT 3 4
  
VdT kT 4 T

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4. Equilibrium temperature of mixture is 0C.


Total heat released by water = m wSw = 5  1  40 = 200 kcal
Heat taken by ice to increase its temperature from 20C to 0C = 4  0.5  20 = 40 kcal
200  40 160
 mass of ice melted =   2 kg
80 80
 water content in the equilibrium mixture = 5 + 2 = 7 kg

5. Given
C = CV + T2
RT dV
CV   CV  T 2
V dT
T dV
 dT   nk

R V
T 2
 n(kV)
2R
T 2
kV  e 2R
 T 2 

 2R 
 Ve  = constant

6. The net electric potential due to external charge inside the cavity and the induced charge on the
surface of the cavity at any point outside the cavity is zero. If ‘V’ is the electric potential due to
induced charge on the surface of cavity at point ‘P’.
kq
V 0
5a
kq
 V
5a

dT
7. mS  AT 4
dt
4 dT
 R3 S  4R 2 T 4
3 dt
T0 /2 t
dT 3
 
T0
T 4

SR
0
dt
T /2
 1  0 3
 3  t
 3T  T0 SR

 8 1  9t 
  3  
 3 
 T0  SR 
 T0
7SR
 t
9T03
 
8. The electric field due to P1 at the position of P2 is
KP1
E1 
r3
 force of inter action between the dipoles is

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AITS-PT-II-PCM-Sol-JEE(Main)/18 4

dE1
F  P2
dr
3kP1P2
F=
r4

dQ
9. dS 
T
2T0
dT
 dS  nc P 
T0
T

5R 25
S  4  n2  10Rn2  10   0.69
2 3
25  2.3  57.5 J/k

10. The electric flux through the right end plane surface.
q q  4
PS   2(1  cos  )  1  
40 20  5 
q
PS 
100
Hence, the electric flux through the curved surface of the cylinder is
q
CS   PS
20
q q 4q
=  
20 100 100
2q
CS 
50

k(2Q)2 kQ2 k(2Q)Q


11. Ui   
2a 4a 2a
2kQ2 5kQ2
 
a 4a
13kQ2
Ui 
4a
k(3Q)2 9kQ 2
Uf  
4a 4a
 Total heat dissipated, H = Ui  Uf
13kQ2 9kQ2
 
4a 4a
4kQ2 kQ2
 
4a a

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q  q  40   q  120  q q q  40 40  q
12.    10
5  2   2  C1 = 5F C2 = 2F
6q
 90  = 10 V
5 120  q q  120
q = 75 C
 magnitude of charge flown through the battery C3 = 2F
is
q = 100  75 = 25 C

13. The electric potential of shell B is zero Q+q


q
VB = 0
q
kq kQ C
 0 0
2a 4a B 0
Q A a
 q
2

2a
4a

14. The cell will deliver maximum power to the network if Req = r
3R
 r
2
2r 2
 R = 
3 3

15. The equivalent circuit just after 2 2


closing the switch ‘S’ is
Req = 3 + 2 = 5 
 10
 I0    2A 3
R eq 5

2

 = 10V


16. Since the particle exists the magnetic field region with a velocity v  (3iˆ  3 3ˆj) m/s
3 3
tan  
3

 
3

The angular displacement of the particle in the magnetic field region is  
3
qB
Angular velocity,  =
m
 m
 t 
 3qB

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17. Since B is constant in the region
The net magnetic force experienced by the conducting wire MN is
  

F  I Leff  B 

Where, L eff  6Riˆ

F  I  6Riˆ  B(k)
ˆ 

F  6BIR( j) ˆ
18. The net magnetic moment of the loop is

M  I2 (iˆ  k)
ˆ
The net magnetic torque experienced by the loop is
  
  MB
= I2 (iˆ  k)
ˆ  Bjˆ

  BI2 (kˆ  ˆi)
19. The net magnetic field at the centre ‘O’ of the circular arc is
 I 3 I  I
B0  0  0  0
4 R 8R 8R
0I 3 0I
 
8R 8R
 I  1  3 
B0 =  0 
8R   
20. When r  R 3
r j = r


B2r   0 j2rdr
0 r
B
5 B
 r
Br  0
5 R
B
 r 4
B 0 ,rR
5
when r > R
R


B2r   0 j2rdr
0
R
Br   0 r 3rdr

0

 0 R5
Br 
5
 0  R5
 B ,r>R
5r
R  R 4
at r  , B1  0
2 80
 0 R 4
at r = 2R, B 2 
10
B2
 8
B1

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21. The emf induced between the points ‘A’ and ‘D’ is
  
  B  ( eff  v)
 Ba 2v sin 45
v
= Ba 2  Bva  2Ba2
2

22. When r  R
r B = krt
d
E2r 
dt
B2rdr
0
r E
E
O R
d  ktr 3 
Er   
dt  3  E

kr 2
E , when r  R
3
When r > R
R
d 
 B2rdr 
E2r 
dt 
0
 

R
d 
Er   krtrdr 

dt  
0 
kR3
E , where r > R
3r
R kR 2
 at r  , E1 
2 12
kR2
at r = 2R, E 2 
6
E2
 2
E1

q
23.  Bv   S M
C
q  C(  Bv )
dv B
Now, m  Bi  v
dt
mdv = Bidt
q +q m, 
v q
m dv  B dq
  C N
0 0
mv = Bq
mv
 q …(ii)
B
From (i) and (ii)
mv
 C  CBv
B

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CB
v 
(m  CB 2 2 )

d
24. E2r = (ktr 2 ) B = kt
dt
a E
kr
E ,rR E
2 O R
at r = a q, m
ka E
E
2
To keep the ring stationary
qEa = mga
qka
 mg
2
kqa
 
2mg
kqa
min 
2mg

25. When the current through the inductor is +C/2 C/2


maximum A
di C
VL  L  0
dt imax
Hence capacitors A and B will be in parallel
Now, using conservation of energy +C/2 C/2
1 2 1 2 1 2
C  2  C  Limax C B
2 2 4 2
2
C 1 2
 Limax
4 2
C
imax  
2L

di1 di
26. L1  L2 2
dt dt
i1 i2

 
L1 di1  L 2 di2
0 0
L1i1  L2i2 …(i)
i1  i2  i …(ii)
 L 
i1  1  1   i
 L2 
 L2   L1 
 i1    i and i2   i
 L1  L2   L1  L 2 
1 2
L1i1
U1 L L2 L
  2  1 22  2
U2 1 2 L2L1 L1
L i
2 22

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27. Rms current through resistor ‘R1’ is


50 5
I1(rms)   A
2  10 2 2
 Average power developed in the resistor ‘R1’ is
2
2 5 250
P1  I1(rms)R1    10   62.50 W
2 4

28. Current through the potentiometer wire is


6
I
R5
63
 V
(R  5)
18
2
R5
R+5=9
R=4

29. Let the initial charge on the spherical conductor ‘A’ is Q.


kQ
 V
a
 kQ = Va …(i)
When switch ‘S’ is closed, the total charge ‘Q’ will appear on the outer surface of shell B.
 Final potential of the spherical conductor ‘A’ is
kQ Va V
V   
6a 6a 6

30. Given process is


VT2 = constant
VP2V2 = constant
PV3/2 = constant
 molar heat capacity
R 5R R
C  CV   
1 x 2 3
1
2
 C = R/2
 Heat supplied to the gas is
R
Q = nCT = 2   300  300 R
2
Increase in internal energy of the gas is
5R
 U = nCVT = 2   300  1500R
2
U 1500R
 The ratio  5
Q 300R

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AITS-PT-II-PCM-Sol-JEE(Main)/18 10

Chemistry PART – II

31.
 

N CH2 N CH2 N CH2

 

N CH2 N CH2

32. The carboxylic acid group stabilizes the conjugate base and – I of other groups at closest
distance.

34. Total chiral centres = 3


2n = 23 = 8
O

35. In B all alkyl groups are at equatorial positions so most stable.


Most stable will have least heat of combustion.

37. Glyptal is made from polymerization of ethylene glycol and pthalic acid.

38.
Br


 NH MeI +

excess
 N Me

CH2 Me
CH2
H2 N CH2
Moist Ag2 O

CH2NMe 2
39. Cl

H  
 
 Cl
 

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11 AITS-PT-II-PCM-Sol -JEE(Main)/18

42.
O OCH3 O D O D HO D
D D
D H
  D
  

44. OCH3 O
AlCl 3

 O

OCH3

OH
O

O
46. H

H
O  O

OH OH OH


H
 

47. Cl
Cl

Cl
2

h

1 1

Cl

x  10
2 GI 2 GI
4 OI Cl
4 OI

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AITS-PT-II-PCM-Sol-JEE(Main)/18 12

Cl
Cl
Cl2

h 

1 1
Cl
y4
1 Cl
1
48. CHO
ONa O O
 H3C C O C CH3

CHO O O
O C O C CH3

CH3

CHO CHO
O O
O O
O C CH3 O C CH2
CH3 COO Na H2O
 
 
  

50.
MeOH
 
O O O O OH O
MeO
Re d P
Br2

Br
H2 N
NH3

COOH
O
O ONH4 O
MeO
H 2N

H3 O 

HOOC COOH

NH2
51. Br
MgBr
Mg 
  
Elimination 

Br
Br

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52. Cl

Alc. AgNO
3  AgCl
 

HO
Cl Cl

NaOH
 

Cl
COOH

Oxidation


Cl
53. COOH
CH2 OH
H OH
O H
H Br
HO H
H 2
H O
2
H OH
OH H
OH
OH H OH
CH2OH
H OH
55. + +
Cl Cl Cl Cl Cl Cl
C C  C C  C C
H H H H H H
In cis form attraction between both chlorine leads to stability.
56. H
Tollen's reagent
H 3C C C CH  white ppt.

H2 C CH3

H O HO
O3 /H2O2 LAH

 CO2 
Me C C OH  

Et


H /
 

57. (ii), (vi) will not give Cannizzaro test.

58. Rate of reaction depends upon migration aptitude.

60. Intermolecular aldol reaction.

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AITS-PT-II-PCM-Sol-JEE(Main)/18 14

Mathematics PART – III

p p
61. tan        
1 q q  1
1
1  tan 2
   
 tan 2
      p tan       q

1  p2 p2 
=    q 
p2   q  12 q  1 
1  
 q  12
1
=
2
p   q  1
2 p 2
 p2  q  1  q  q  1
2
q
62. f(x) = (x – 1)(x – cos )(x – sin )
2 + 2 + 2 = 1 + sin2  + cos2  = 2

63. x  2  1  (x + 1)2 = 2
 x4 + 3x3 – 3x2 – 9x + 6 = (x2 + x – 4)(x2 + 2x – 1) + 2 = 2

64. x = r cos , y = r sin 


 r2 sin  cos  r2(cos2  – sin2 ) = r2
4
 r2   4 cosec 4  4
sin 4

   
65. sec 2 cosec 2  sec 2 cosec 2
8 8 8 8
 –a = b  a + b = 0

2ab C C
66. x cos
ab 2 a
1 1 1 b
ra  rb  ab sinC
2 2 2
1 C C r r
2  ab sinC 2ab sin cos A B
 r 2  2 2  x sin C I
ab ab 2
2 abc
r r
ab 4R2  sin A  sinB 

 1
67. cos x = 0 or sin  x    0
 x
 1
 x  or x   n  infinite solution
2 x

68. f x 
 cosec x  1 2

=
cot x 4
 0 ; x  R – n, n  I
 cosec x  1  1  cot x  cot x 1  cot x
2 2

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15 AITS-PT-II-PCM-Sol -JEE(Main)/18

  3 5 199
 x   2n  1  , , , .....,
2 2 2 2 2

Sum = 1  3  5  .....  199   5000
2

69. p = 1, a2 = 4  b = 4 A
p = 2, a3 = 4  c = 4
  is isosceles
  15 4 4
 15 
r1   , r2   15  r3
sa 3 sb
B C
 r2 = r3 = 3r1 2

   
   
70.

tan1  2
4 
  tan 1

1
  tan 1  1  = tan1  r  1   tan1  r  1 
 4r  3   r 2  3    1  1   2  2
 4  1   r  2  r  2  
   
n
 4   1  1
 tan1  4r 2  3   tan1  n  2   tan1  2 
r 1

 4 
  tan1  4r 2  3   tan1 2
r 1

1 1 A
71. A  2x cos   x sin   x2 sin2
2 2
x2
Max  A   x x
2


B C

 3
72. Lines intersect at  3,  which is centre of required circle. Given circle x2 + y2 – 4x – 3y = 0
 2
 3 5
whose centre is  2,  , r 
 2 2
For just sufficient circle d = |r1 – r2|
5 15 9 225
 r  5  r   9 k   k = 45
2 2 4 4

a2  a2  d12
73. If acute angle =   cos      
2a2

 2a2  d12  2a2 cos   d1  2a2  2a2 cos   2acos
2

Similarly, d2  2a2 1  cos    2a sin and d1d2 = a2
2
  1
 4 sin cos  1  sin  
2 2 2

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AITS-PT-II-PCM-Sol-JEE(Main)/18 16

2
74. Let log 3
tan x  t  t 3   1 , t < 0
t
 2 1
 t 2  3    1  3t2 + 2t – 1 = 0  t  1,
 t  3
1 
 log 3 tan x  1  tan x   x
3 6

sin  B  C 
2R sin A a
75. tanB  tanC    
cosB cos C 2R cosB cos C 2RcosB cos C
 2R cos B cos C = k
 Locus of orthocentre is a line parallel to BC

1 3
76. 2 – a = SP =  a   2a = 3
2 2

77. (1, –1) lies on y + x = 0. Hence only one rational point

2
78. x2  y 2  2y  1  x 2   y  1 = distance between (x, y) and (0, –1)
x  2y  3
The distance from (x, y) to x – 2y + 3 = 0 is
5
2 x  2y  3 5
 x 2   y  1  
5 
5 5
 e for hyperbola 1
 
<5

ab
79. a  b  a2  b2 
2
4 a  2
 b for a = 5, a = 6, b = 8
a4
1
   ab  24
2

1 A
80. BD2 = 22 + 52 – 2·2·5· B
2 2
 1
= 32 + x2 – 2·3·x    5 x
 2
 19 = x2 + 3x + 9 3
 x2 + 3x – 10 = 0 C
D
x=2

1 2 2cos   sin 
81.  4  2
2 5 2

PA 10  2 2
82.   AB is a diameter
PB 10  2 2

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83. 2b tan   a2 sec 2   b2 tan2 


1
 e2  1 
3

PA  PB
84.  PA  PB
2
 PA + PB  2PT

 y y 
85. a  x    c   1  0
 2  2 
  = 1,  = –2 and 4( + ) = 2 + 2 –  – 1
=8
++=7

x
86. Equation of tangent is cos   y sin   1
3 3
3 3 1 
S  . It is minimum at  
cos  sin  6

1
87.   
Orthocentre (h, k) = 2a  a t12  t 22  t1t 2 ,  at1t 2  t1  t 2  where t 2    t1
 k = a(t1 + t2)
 k2 
 2
h  2a  a  t1  t 2   t1t 2  2a  a  2  1
a 

ah = 3a2 + k2

88. Sides of squares will be perpendicular tangents to the ellipse. So vertices of square will lie on
diameter circle
 Diameter of circle = 2 a2  3  a  4  2a2  2a2
 a2 + a + 1 = a2
 a = –1
But a2 > 3 and a > –4
a


89. C  , A = 15º, B = 75º
2

1 1 1 1 1 5
90. 2
 2
 2
 2
 1
 OA   OB  a b 4 4

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