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 JEE Advance
Paper - I
Sample Test - 3
JEE Advance
Paper – I
Mock Test-3

Instructions:
Section I contains 6 Single answer multiple choice type questions. Each question has 4
choices (A), (B), (C) and (D), out of which only one is correct. For each question you will
be awarded 3 marks if you select the options corresponding to the correct answer ONLY and
zero (0) marks if no option is selected. In all other cases, Minus one (-1) marks will be
awarded in this section.

Section II contains 4 Multiple answer type questions. Each question has 4 choices (A), (B),
(C) and (D), out of which one or more is/are correct. For each question you will be
awarded 4 marks if you select the options corresponding to the correct answer ONLY and
zero (0) marks if no option is selected. In all other cases, Minus one (-1) marks will be
awarded in this section.

Section III contains 4 questions. Each question contains Statement-1 (Assertion) and
Statement-2 (Reason). Each question has 4 choices (A), (B), (C) and (D), out of which only
one is correct. For each question you will be awarded 3 marks if you select the options
corresponding to the correct answer ONLY and zero (0) marks if no option is selected. In all
other cases, Minus one (-1) marks will be awarded in this section.

Section IV contains 3 Linked comprehension type questions. Based upon each paragraph, 3
multiple choice questions have to be answered. Each question has 4 choices (A), (B), (C) and
(D), out of which only one is correct. For each question you will be awarded 4 marks if you
select the options corresponding to the correct answer ONLY and zero (0) marks if no option
is selected. In all other cases, Minus one (-1) marks will be awarded in this section.

SECTION – I – MATHEMATICS

Question 1: ABCD is a square of side 1 unit. A circle passes through vertices A, B of the
square and the remaining two vertices of the square lie outside the circle. The length of the
tangent drawn to the circle from vertex D is 2 units. The radius of the circle is
Options:
(a) 5
1
(b) 10
2
1
(c) 12
3
(d) 8

Question 2: The area bounded by the curves y = 2 -|x -1|, y = sin x; x = 0 and x = 2 is
Options:
(a) 1+ 2cos21

1
 Study Materials
NCERT Solutions for Class 6 to 12 (Math & Science)
Revision Notes for Class 6 to 12 (Math & Science)
RD Sharma Solutions for Class 6 to 12 Mathematics
RS Aggarwal Solutions for Class 6, 7 & 10 Mathematics
Important Questions for Class 6 to 12 (Math & Science)
CBSE Sample Papers for Class 9, 10 & 12 (Math &
Science)
Important Formula for Class 6 to 12 Math
CBSE Syllabus for Class 6 to 12
Lakhmir Singh Solutions for Class 9 & 10
Previous Year Question Paper
CBSE Class 12 Previous Year Question Paper
CBSE Class 10 Previous Year Question Paper
JEE Main & Advanced Question Paper
NEET Previous Year Question Paper

Vedantu Innovations Pvt. Ltd.

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(b) 2 + sin21

(c)
2
(d) 1+ log 2

 /2
sin x
Question 3:  1 + cos x + sin x dx =
0
Options:

(a)
4

(b) + log 2
4

(c) − log 2
4

(d) − log 2
4

Question 4: The equation of circum-circle of a  ABC is x2 + y2 + 3 x + y - 6 = 0. If A = (1,-

2), B = (-3,2) and the vertex C varies then the locus of ortho-centre of  ABC is a
Options:
(a) Straight line
(b) Circle
(c) Parabola
(d) Ellipse

Question 5: ' A' is a 3×3 matrix with entries from the set {-1,0,1}. The probability that 'A' is
neither symmetric nor skew symmetric is
Options:
39 − 36 − 33 + 1
(a)
39
39 − 36 − 33
(b)
39
39 − 1
(c)
310
39 − 33 + 1
(d)
39

2
Question 6: If z1, z2 are complex numbers such that z13 − 3z1z22 = 2 and 3z12 z2 − z23 |= 11
then z12 + z22 =
Options:
(a) 3
(b) 4
(c) 5
(d) 6

SECTION – II – MATHEMATICS

x
Question 1: If y = f ( x ) = ( x − t )
6
sin t dt then the true statement among the following
0
are
Options:
(a) y ''+ y = x6
(b) y '( 0) = 0
(c) y ''− y = x6
(d) y ' ( 0) = 1

Question 2: The triangle formed by the lines x + y = 0, 3x + y - 4 = 0 and x + 3 y - 4 = 0 is

Options:
(a) isosceles
(b) scalene
(c) acute angled
(d) obtuse angled

Question 3: If r is a vector satisfying ( )

r  iˆ + ˆj + 2kˆ = iˆ − ˆj then r can be
Options:
(a) 
(b) e
1
(c)
3
1
(d)
5

Question 4: P is a non singular matrix and A, B are two matrices such that B = P−1 AP then
the true statements among the following are
Options:
(a) A is invertible if B is invertible

3
(b) Bn = P−1 An P n  N
(c)   R, B −  I = P
−1
( A −  I ) P (I is the identity matrix)
(d) A, B are both singular matrices

SECTION – III – MATHEMATICS

dP
Question 1: Statement 1: If ‘P’ is a differentiable function of ‘x’ and − 3P  6 x  0
dx
and P(0) = 4 then P  6e − 2x  0
3x

dP d
Statement 2: − 3P − 6 = e3 x ( P + 2) e−3 x 
dx dx
Options:
(a) Statement-1 is True, Statement-2 is True; Statement-2 is a correct Explanation for
Statement-1
(b) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True



Question 2: Statement 1: cot
k =1
−1
2k 2 =
4
1
Statement 2: tan
−1
2
= tan −1 ( 2k + 1) − tan −1 ( 2k − 1) , k  N
2k
Options:
A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct Explanation for
Statement-1
B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1
C) Statement-1 is True, Statement-2 is False
D) Statement-1 is False, Statement-2 is True

Question 3: Statement 1: If ‘Z’ is a complex number then the equation |z2-1| = |z|2-1 has
infinitely many solutions
Statement 2: if Z1, Z2 are complex numbers then Z1 + Z2 = Z1 + Z2 , If Z1, Z2 are the
positive real numbers
Options:
A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct Explanation for
Statement-1
B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1
C) Statement-1 is True, Statement-2 is False

4
D) Statement-1 is False, Statement-2 is True

Question 4: Statement 1: If x, y, z  R, and 3x + 4 y + 5z = 10 2 then the least value of x2

+ y2 + z2 is 4
Options:
(a) Statement-1 is True, Statement-2 is True; Statement-2 is a correct Explanation for
Statement-1
(b) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True

SECTION – IV– MATHEMATICS

Question 1: A curve C which is not a straight line lies in the first quadrant. The tangent at
any point on C meets the positive directions of the coordinate axes at the points A,B. Let 'd '
be the minimum distance of the curve C from the origin O.
If OA + OB =1 then d =
Options:
1
(a)
2 2
1
(b)
2
1
(c)
2
(d) 2

Question 2: A curve C which is not a straight line lies in the first quadrant. The tangent at
any point on C meets the positive directions of the coordinate axes at the points A,B. Let 'd '
be the minimum distance of the curve C from the origin O.
If OA.OB = 4 then d =
Options:
1
(a)
2 2
1
(b)
2
1
(c)
2
(d) 2

5
Question 3: A curve C which is not a straight line lies in the first quadrant. The tangent at
any point on C meets the positive directions of the coordinate axes at the points A,B. Let 'd '
be the minimum distance of the curve C from the origin O.
If AB = 1 then d =
Options:
1
(a)
2 2
1
(b)
2
1
(c)
2
(d) 2

Question 4: Let the equations of two straight lines L1, L2 be respectively be

y − 3 z − 15 x y +1 z + 6
x −5= = and = = . A, B are two distinct points on the x –
5 2 2 5 3
axis such that the two straight lines l1, l2 both perpendicular to the x-axis ( l1 , through A, l2
through B) are drawn so as to intersect both L1, L2 .
Direction ratios of one of the lines l1, l2 are
Options:
(a) 0,3,1)
(b) (0,4,- 3)
(c) (0,5,- 2)
(d) (0,2,3)

Question 5: Let the equations of two straight lines L1, L2 be respectively be

y − 3 z − 15 x y +1 z + 6
x −5= = and = = . A, B are two distinct points on the x –
5 2 2 5 3
axis such that the two straight lines l1, l2 both perpendicular to the x-axis ( l1 , through A, l2
through B) are drawn so as to intersect both L1, L2 .

If  is the acute angle between the lines l1, l2 and cos  = then  =
5 794
Options:
(a) 42
(b) 53
(c) 61
(d) 64

6
Question 6: Let the equations of two straight lines L1, L2 be respectively be
y − 3 z − 15 x y +1 z + 6
x −5= = and = = . A, B are two distinct points on the x –
5 2 2 5 3
axis such that the two straight lines l1, l2 both perpendicular to the x-axis ( l1 , through A, l2
through B) are drawn so as to intersect both L1, L2 .
Options:
105
(a)
4
127
(b)
5
119
(c)
6
128
(d)
7

Question 7: ABC is a triangle right angled at A with vertices A,B,C in the anti-clockwise
sense in that order. A = (1,2), B = (-3,1) and vertex C lies on the X – axis. BCEF is a square
with vertices B,C,E,F in the clockwise sense in that order. ACD is an equilateral triangle with
vertices A,C,D in the anti-clockwise sense in that order.
Slope of AF is
Options:
7
(a)
10
7
(b)
9
9
(c)
10
11
(d)
10

Question 8: ABC is a triangle right angled at A with vertices A,B,C in the anti-clockwise
sense in that order. A = (1,2), B = (-3,1) and vertex C lies on the X – axis. BCEF is a square
with vertices B,C,E,F in the clockwise sense in that order. ACD is an equilateral triangle with
vertices A,C,D in the anti-clockwise sense in that order.
The Abscissa of centroid of  BCE is
Options:
(a) -1
−1
(b)
2

7
 −1
(c)
3
−2
(d)
3

Question 9: ABC is a triangle right angled at A with vertices A,B,C in the anti-clockwise
sense in that order. A = (1,2), B = (-3,1) and vertex C lies on the X – axis. BCEF is a square
with vertices B,C,E,F in the clockwise sense in that order. ACD is an equilateral triangle with
vertices A,C,D in the anti-clockwise sense in that order.
If D= D = ( ,  ) then ( 4 − 4) =
2

Options:
(a) 2
(b) 3
(c) 4
(d) 5

SECTION – I – PHYSICS

Question 1: Charge is uniformly distributed on a wire such that linear charge density is + λ .
Shape of the wire is shown in the figure, straight section is semi infinitely large. C is the
centre of the semi-circular portion of radius R. Considering all physical quantities in SI units,
 1 
magnitude of electric field at C is:  k = 
 4 0 

Options:
2k
(a)
R
2k 
(b)
R
k
(c)
R
(d) zero

Question 2: A ray incident at an angle 530 on a prism and emerges at an angle of 370 as
shown in figure. If the angle of incidence is made 500 then possible value of the angle of
emergence is

8
Options:
(a) 350
(b) 420
(c) 400
(d) 380

Question 3: A nucleus with mass number 220 initially at rest emits an α -particle. If the Q-
value of the reaction is 5.5MeV, the kinetic energy of the α -particle is
Options:
(a) 4.4MeV
(b) 5.4MeV
(c) 5.6MeV
(d) 6.5MeV

Question 4: The potential energy of a particle of mass m is given by

E , 0  x  1
V ( x) =  0
0 , x 1
1and 2 are the de-Broglie wavelength of the particle, when 0  x  1 and x  1
respectively, If the total energy of particles is 2E0 , then 1 / 2 is
Options:
(a) 2
(b) 2
(c) 1
(d) 4

Question 5: An isosceles triangle is to be cut from one edge of a square lamina of uniform
mass density (as shown in the figure) such that the remaining portion when suspended from
the apex P of the cut will remain in equilibrium in any position. The value of h is

Options:

(a)
(2 − 2 )l
2

(b)
(3 + 3 ) l
2

(c)
( 3 − 3 )l
2

9
(d)
(2 + 2 )l
2

Question 6: A spherical balloon is being inflated so that is volume increases uniformly at the
rate of 40 cm3 /min. How fast is its surface area increasing when the radius is 8 cm ?
Options:
(a) 4 cm2/min
(b) 10 cm2/min
(c) 15cm2 /min
(d) 20cm2 /min

SECTION – II – PHYSICS

Question 1: Voltmeter and ammeter shown in circuit diagram are ideal, then the correct
statements are

Options:
(a) Reading of voltmeter is 4 volt.
(b) Reading of ammeter is 1.0 A.
(c) Current through 1 W resistance is 1.0A.
(d) Current through 1 W resistance is zero.

Question 2: A particle is moving in a circular path of radius 1 m such that its speed is
varying with time as v = 2t m/s, here t is in sec. Given a is the net acceleration and v is the
velocity of the particle.
Options:
1
(a) At t = s angle between velocity and acceleration is 450
2
1
(b) at t = s a.v = 2 2
2
1
(c) At t = s , a.v  0
2
(d) a.v magnitude is independent of radical acceleration.

Question 3: A charged particle is projected in magnetic field B = 10kˆ T from origin in X -

Y plane. The particle moves in a circle and just touches a line y = 5m at x = 5 3m .Then
−5
(mass of particle = 5 10 kg and charge 1μC)

10
Options:
(a) The particle is projected at an angle 60°with X-axis
(b) The radius of circle is 10 m
(c) speed of particle is 2m/s
(d) Work done by magnetic force on the particle is zero.

Question 4: A car moves towards a hill with speed vc . It blows a horn of frequency f which
is heard by an observer following the car with speed v0 .The speed of sound in air is v.
Options:
v
(a) The wavelength of sound reaching the hill is
f
v − vc
(b) The wavelength of sound reaching the hill is
f
v + vc
(c) The wavelength of sound of horn directly reaching the observer is
f
2vc ( v + v0 ) f
(d) The beat frequency observed by the observer is
v2 − vc2

SECTION – III – PHYSICS

Question 1: Statement 1: A force of constant magnitude can provide the variable

acceleration.
Statement 2: A force of constant magnitude can provide constant acceleration only.
Options:
(a) Statement 1 is True, Statement 2 is True; Statement 2 is correct explanation for Statement
1
(b) Statement 1 is True, Statement 2 is True; Statement 2 is NOT a correct explanation for
Statement 1
(c) Statement 1is True, Statement 2 is False,
(d) Statement 1 is False, Statement -2 is True

Question 2: Statement - 1: Magnetic flux (  B.ds ) passing through a closed surface is

zero.
Statement - 2: Magnetic field lines never intersect each other.
Options:
(a) Statement 1 is True, Statement 2 is True; Statement 2 is correct explanation for Statement
1
(b) Statement 1 is True, Statement 2 is True; Statement 2 is NOT a correct explanation for
Statement 1
(c) Statement 1is True, Statement 2 is False,
(d) Statement 1 is False, Statement -2 is True

11
Question 3: Statement - 1: The mass number of a nucleus is equal to the number of nucleons
in the nucleus.
Statement - 2: In a nucleus number of protons are always less than the number of nucleons
Options:
(a) Statement 1 is True, Statement 2 is True; Statement 2 is correct explanation for Statement
1
(b) Statement 1 is True, Statement 2 is True; Statement 2 is NOT a correct explanation for
Statement 1
(c) Statement 1is True, Statement 2 is False,
(d) Statement 1 is False, Statement -2 is True

Question 4: Two wires of same material are hanging as shown in the figure. Breaking stress
is equal for both the wires.

Statement-1: If mass m2 increases then upper wire will break first.

Statement-2: Breaking load of two wires of same material can be different.
Options:
(a) Statement 1 is True, Statement 2 is True; Statement 2 is correct explanation for Statement
1
(b) Statement 1 is True, Statement 2 is True; Statement 2 is NOT a correct explanation for
Statement 1
(c) Statement 1is True, Statement 2 is False,
(d) Statement 1 is False, Statement -2 is True

SECTION – IV – PHYSICS

Question 1: Two blocks of equal mass m are connected by an unstretched spring and the
system is kept at rest on a frictionless horizontal surface. A constant force F is applied on the
second block pulling it away from the other as shown in figure.

The displacement of the centre of mass in time t is

Options:
Ft 2
(a)
2m
Ft 2
(b)
3m

12
 Ft 2
(c)
4m
Ft 2
(d)
m

Question 2: Two blocks of equal mass m are connected by an unstretched spring and the
system is kept at rest on a frictionless horizontal surface. A constant force F is applied on the
second block pulling it away from the other as shown in figure.

If the extension of the spring is x0 at time t, then the displacement of the second block at this
instant is :
Options:
1  Ft 2 
(a)  + x0 
2  2m 
1  Ft 2 
(b) −  + x0 
2  2m 
1  Ft 2 
(c)  − x0 
2 m 
1  Ft 2 
(d)  − x0 
2  2m 

Question 3: Two blocks of equal mass m are connected by an unstretched spring and the
system is kept at rest on a frictionless horizontal surface. A constant force F is applied on the
second block pulling it away from the other as shown in figure.

If the extension of the spring is x0 at time t, then the displacement of the first block at this
instant is :
Options:
 Ft 2 
(a)  − x0 
 2m 
1  Ft 2 
(b)  + x0 
2  2m 
1  2Ft 2 
(c)  − x0 
2 m 

13
 1  2Ft 2 
(d)  − x0 
2  2m 

Question 4: One mole of monoatomic ideal gas of molar mass M undergoes a cyclic process
ABCA as shown in the figure. The line CA, if extended passes through origin of the pressure
(P), density (  ) graph and it makes an angle  with  - axis, BC is perpendicular to  -
axis. Curve AB shows adiabatic process. PA = P0 and PB = 4P0

In the process CA, temperature of the gas

Options:
(a) increases
(b) decreases
(c) remains same
(d) increases then decreases

Question 5: One mole of monoatomic ideal gas of molar mass M undergoes a cyclic process
ABCA as shown in the figure. The line CA, if extended passes through origin of the pressure
(P), density (  ) graph and it makes an angle  with  - axis, BC is perpendicular to  -
axis. Curve AB shows adiabatic process. PA = P0 and PB = 4P0

The possible temperature (T) verses pressure (P) graph for the process ABCA is
Options:
(a)

14
(b)

(c)

(d)

Question 6: One mole of monoatomic ideal gas of molar mass M undergoes a cyclic process
ABCA as shown in the figure. The line CA, if extended passes through origin of the pressure
(P), density (  ) graph and it makes an angle  with  - axis, BC is perpendicular to  -
axis. Curve AB shows adiabatic process. PA = P0 and PB = 4P0

15
The maximum temperature of the gas in the process is
Options:
22/3 M tan 
(a)
R
4 M tan 
2/5
(b)
R
4 M tan 
3/2
(c)
R
2 M tan 
2/5
(d)
R

Question 7: An arrangement is shown in the diagram for a YDSE. Refractive index of the
3 2d 2
glass sheet is 1 = and thickness is t = . In between slits and screen a liquid is filled
2 D
4 5d 2
(refractive index 2 = ) Wavelength of the monochromatic light ray is  = . There
3 D
d 9
are three points on the screen P, Q, R at a distance , d and 3d from C respectively, d is
2 8
the distance between two slits S1 and S2
(D>>d). Source is at equidistance from the slits.

If I0 is the intensity of the two interfering waves at point P, then resultant intensity at point P
is
Options:

16
 (a) 4I0
(b) zero
(c) I0
(d) 2I0

Question 8: An arrangement is shown in the diagram for a YDSE. Refractive index of the
3 2d 2
glass sheet is 1 = and thickness is t = . In between slits and screen a liquid is filled
2 D
4 5d 2
(refractive index 2 = ) Wavelength of the monochromatic light ray is  = . There
3 D
d 9
are three points on the screen P, Q, R at a distance , d and 3d from C respectively, d is
2 8
the distance between two slits S1 and S2
(D>>d). Source is at equidistance from the slits.

If I0 is the intensity of the two interfering waves at point P, then resultant intensity at point P is
Options:
d2
(a)
2D
5d 2
(b)
2D
15d 2
(c)
2D
3d 2
(d)
2D

Question 9: An arrangement is shown in the diagram for a YDSE. Refractive index of the
3 2d 2
glass sheet is 1 =and thickness is t = . In between slits and screen a liquid is filled
2 D
4 5d 2
(refractive index 2 = ) Wavelength of the monochromatic light ray is  = . There
3 D

17
 d 9
are three points on the screen P, Q, R at a distance , d and 3d from C respectively, d is
2 8
the distance between two slits S1 and S2
(D>>d). Source is at equidistance from the slits.

Maxima will lie on the point

Options:
(a) O
(b) P
(c) Q
(d) R

SECTION – I – CHEMISTRY

Question 1: The density of the vapour of a substance at 1 atm pressure and 500 K is
0.36 kgm−3 . The vapour effuses through a small hole at a rate of 1.33 times faster than oxygen
under the same condition. The compression factor (Z) of the vapour is
Options:
(a) 1.22
(b) 1.0
(c) 1.5
(d) 0.776

Question 2: 250 ml of x M solution and 500 ml of y M solution of a solute are mixed and
diluted to 2 L to produce a final concentration of 1.6 M. If x : y is 5 : 4 then (x + y) is
Options:
(a) 8.06
(b) 8.86
(c) 9.8
(d) 12.6

−3
Question 3: 2 10 g of green algae absorbs 7 10 moles of CO2 per hour by
−4

photosynthesis as per the following equation:

6nCO2 + 6nH2O ⎯⎯ hv
→(C6 H10O5 )n + 6nO2 If all the carbon of CO2 is converted into
starch, then how long will it take for the algae to increase its mass by 100%
Options:

18
(a) 6.34 hours
(b) 63.4 min
(c) 6.34 min
(d) 126.8 min

Question 4: The empirical formula of sheet silicate & the number of oxygens shared per
tetrahedral are respectively,
Options:
(a) ( SiO3 )n ,2
2 n−

(b) ( Si2O7 )n ,3
6 n−

(c) ( Si2O5 )n ,3
2 n−

(d) ( Si4O11 )n ,4
6 n−

Question 5:

Options:
(a)

(b)

(c)

(d)

Question 6: How are the following compounds related?

19
Options:
(a) Enantiomers
(b) Diastereomers
(c) Epimers
(d) They are identical

SECTION – II – CHEMISTRY

Question 1: Which of the following is/are homopolymers ?

Options:
(a) PVC
(b) Polyacrylonitrile
(c) Buna-S
(d) Nylon 6

Question 2: Which of the following changes will occur when NO2 gas is passed into a dark
red liquid of Cl2O6?
Options:
(a) NO2 gas undergoes disproportionation
(b) ClO2 gas is liberated
(c) It forms nitronium perchlorate salt
(d) Cl2O6 undergoes disproportionation

Question 3: Equal weights of a mixture of CO2 and O2 are enclosed in a vessel at 27oC and 1
atm pressure. Then, which of the following is/are true ?
Options:
(a) O2 molecule will hit the wall with greater momentum than CO2
(b) CO2 molecule will hit the wall with same kinetic energy than O 2
(c) Both O2 and CO2 hit the wall with same momentum
(d) CO2 molecule will hit the wall with greater momentum than O 2

Question 4: An alkene having M.F ( C16 H16 ) ⎯⎯⎯⎯ →( A) ⎯⎯⎯→( B ) + CHCl3

Re ductive NaOCl
Ozonolysis
The alkene shows geometrical isomerism. Which of the following statements are correct for
the above reaction?
Options:
(a) B is a salt of carboxylic acid
(b) B on decarboxylation gives an aromatic compound
(c) A is a carbonyl compound
(d) A on reduction gives 2°alcohol

SECTION – III – CHEMISTRY

Question 1: Statement 1: For an SN2 isotope exchange, the rate of loss of optical activity is
twice the rate of isotope exchange.

20
Statement 2: SN2 reaction proceeds through inversion.
Options:
(a) Statement 1 is True, Statement 2 is True; Statement 2 is a correct explanation for Statement1
(b) Statement 1 is True, Statement2 is Tue; Statement2 is NOT a correct explanation for
Statement1.
(c) Statement - 1 is True, Statement - 2 is False
(d) Statement - 1 is False, statement - 2 is True.

2+ 2+
Question 2: Statement 1: Cd ( trien ) is more stable than Cd ( en )2  .
2+
Statement 2: If both the complexes are formed from Cd ( H 2O )4  , S  will have a
2+
larger positive value for Cd ( trien ) .
Options:
(a) Statement 1 is True, Statement2 is True; Statement 2 is a correct explanation for Statement1
(b) Statement1 is True, Statement2 is Tue; Statement2 is NOT a correct explanation for
Statement1.
(c) Statement - 1 is True, Statement - 2 is False
(d) Statement - 1 is False, statement - 2 is True.

Question 3: Statement 1: Addition of inert gas at constant volume in Haber’s process for the
synthesis of NH3 produces more amount of NH3.
Statement 2: Increase in pressure favours ammonia formation in Haber’s process.
Options:
(a) Statement1 is True, Statement2 is True; Statement2 is a correct explanation for Statement1
(b) Statement1 is True, Statement2 is Tue; Statement2 is NOT a correct explanation for
Statement1.
(c) Statement - 1 is True, Statement - 2 is False
(d) Statement - 1 is False, statement - 2 is True.

Question 4: Statement 1: The percentage of  - D(+) -glucopyranose is more than  - D(+)

-glucopyranose at equilibrium.
Statement 2: The presence of bulky groups in axial position makes  - D(+) -glucopyranose
more stable.
Options:
(a) Statement 1 is True, Statement 2 is True; Statement2 is a correct explanation for Statement1
(b) Statement 1 is True, Statement 2 is Tue; Statement 2 is NOT a correct explanation for
Statement1.
(c) Statement - 1 is True, Statement - 2 is False
(d) Statement - 1 is False, statement - 2 is True.

SECTION – IV – CHEMISTRY

21
Question 1: 1g of methane diffused in 20 sec. under certain conditions. Under the same
conditions 20 of a hydrocarbon (A) diffused in 40 sec. A 10 mg of sample of (A) took up
8.40 ml of H2 gas measured at 00C and 760 mm pressure.
The number of p bonds present in the compound A is / are
Options:
(a) 2
(b) 1
(c) 3
(d)4

Question 2: 1g of methane diffused in 20 sec. under certain conditions. Under the same
conditions 20 of a hydrocarbon (A) diffused in 40 sec. A 10 mg of sample of (A) took up
8.40 ml of H2 gas measured at 00C and 760 mm pressure.
If one of the open chain isomer of (A) on ozonolysis gives only formaldehyde & glyoxal , then
its monocyclic isomer on ozonolysis gives
Options:
(a) only glyoxal
(b) only methyl glyoxal
(c) formaldehyde & glyoxal
(d) glyoxal & methyl glyoxal

Question 3: 1g of methane diffused in 20 sec. under certain conditions. Under the same
conditions 20 of a hydrocarbon (A) diffused in 40 sec. A 10 mg of sample of (A) took up
8.40 ml of H2 gas measured at 00C and 760 mm pressure.
Identify the incorrect statement.
Options:
(a) One of the isomers of (A) exhibits geometrical isomerism
(b) One of the isomers of (A) gives white precipitate with Tollen s reagent
(c) One of the isomers of (A) is asymmetric
(d) One of the isomers on ozonolysis gives only acetone.

Question 4: White crystalline solid (A) reacts with H2 to form a highly associated liquid (B)
and monoatomic colourless gas (C). The liquid (B) is used for etching glass. Compound (A)
undergoes hydrolysis slowly to form (C), (B) and a diatomic gas (D) whereas IE is almost
similar to that of (C). (B) forms an addition compound with KF to form (E) which is
electrolysed in the molten state to form a most reactive gas (F) which combines with (C) in 2
: 1 ratio to produce (A).
The molecular shape, and hybridization state of central atom in the molecule (A) is
Options:
(a) linear, sp
(b) triangular, sp2
(c) linear, sp3d
(d) V-shape, sp3

22
Question 5: White crystalline solid (A) reacts with H2 to form a highly associated liquid (B)
and monoatomic colourless gas (C). The liquid (B) is used for etching glass. Compound (A)
undergoes hydrolysis slowly to form (C), (B) and a diatomic gas (D) whereas IE is almost
similar to that of (C). (B) forms an addition compound with KF to form (E) which is
electrolysed in the molten state to form a most reactive gas (F) which combines with (C) in 2
: 1 ratio to produce (A).
The molecule of compound E contains which of the following types of bonds ?
Options:
(a) ionic bonds
(b) both ionic and covalent bonds
(c) ionic, covalent and metallic bonds
(d) ionic, covalent and H-bonds

Question 6: White crystalline solid (A) reacts with H2 to form a highly associated liquid (B)
and monoatomic colourless gas (C). The liquid (B) is used for etching glass. Compound (A)
undergoes hydrolysis slowly to form (C), (B) and a diatomic gas (D) whereas IE is almost
similar to that of (C). (B) forms an addition compound with KF to form (E) which is
electrolysed in the molten state to form a most reactive gas (F) which combines with (C) in 2
: 1 ratio to produce (A).
According to molecular orbital theory, which of the following is correct about the molecule
(D)?
Options:
(a) Its bond order is 2.0
(b) It has two unpaired electrons in molecular orbital
(c) Its magnetic moment is 1.73BM
(d) All are correct

Question 7:

Identify the incorrect statement regarding the compound C

Options:
(a) It does not give positive Fehling s test
(b) It reacts with (CH3CO)2O in presence of CH3COONa to give an unsaturated acid
(c) It disproportionates with concentrated base
(d) It gives red colouration in Victor-Meyer test

Question 8:

23
The compound E on treatment with a base gives another compound G. Which of the
following is correct regarding G?
Options:
(a) It contains an aldehydic group
(b) It is a salt of keto acid
(c) It is a salt of hydroxy acid
(d) It gives Tollen s test

Question 9:

The final compound F is

Options:
(a)

(b)

(c)

(d)

24
 Answer Key

Mathematics Physics Chemistry

Section – I Section – I Section – I
1. b 1. d 1. a
2. a 2. d 2. b
3. c 3. b 3. c
4. b 4. b 4. b
5. a 5. c 5. c
6. c 6. b 6. b

Section – II Section – II Section – II

1. a, b 1. a, b, d 1. a, b, d
2. a, d 2. a, b, d 2. b, c, d
3. a, b 3. a, b, c, d 3. b, d
4. a, b, c 4. b, c, d 4. a, b, c, d

Section – III Section – III Section – III

1. a 1. c 1. a
2. a 2. b 2. a
3. c 3. c 3. d
4. a 4. a 4. c

Section – IV Section – IV Section – IV

1. a 1. c 1. c
2. d 2. a 2. b
3. b 3. d 3. d
4. b 4. c 4. c
5. c 5. c 5. d
6. b 6. b 6. a
7. d 7. c 7. d
8. c 8. b 8. c
9. b 9. d 9. d

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