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Primary pigments such as titanium dioxide are the most expensive components in
paints. So it is in the interest of the manufacturer to reduce the volume of primary
pigment in the paint. However, this must be done without affecting the quality of
the finished coating.
Figure 1: Pigment spacing improved by reducing the particle size of the filler (black: pigment,
yellow: extender)
As the technology has moved on, it has been found that using a filler of a
particular size, material or shape can improve the aesthetic or mechanical
properties of the coating. These additives are now also known as extender
pigments due to this change in their usage.
Extender Pigments
A wide range of materials are now used as extender pigments. For example;
Chlorite is used to improve barrier properties such as water resistance because
of its plate like shape. Mica, another platy material, can aid corrosion resistance.
Silica is used to improve the rheology of the paint, and to flatten the appearance
of the paint. Wollasonite is used to enhance film strength due to its acicular shape
[2].
The material which will be covered by this application note is Barium Sulphate
or Barytes. Barytes is used as an extender to control the gloss of a coating, and
because it is chemically inert.
The particle size of the extender pigment can affect the coating in one of two
ways. First, the extender can affect the gloss of the coating - a smaller particle
size produces a smoother coating and increases the gloss. In order to achieve
a high gloss the particle size must be smaller than the thickness of the film and
contain no oversized particles. Secondly, the particle size of the extender pigment
can be used to control the spacing of the primary pigment particles within the
paint film. The spacing of the primary pigment particles affects the opacity of the
coating. Too much pigment or extender can cause the particles to crowd together
and reduces the opacity of the coating. Crowding can be avoided by reducing the
particle size of the extender pigment (figure 1) [1].
2 Watching paint dry: relating paint gloss to the particle size of extender pigments
APPLICATION NOTE
The aim of this application note is to show how the particle size of a Barium
Sulphate extender affects the gloss of the coating. In addition to the initial gloss,
the effect of the particle size on the flattening (decrease in gloss) during drying
is also demonstrated. This application note will also cover how laser diffraction
measurements have been used to define and control the production process.
Experimental
Particle size distributions of the extender pigments were obtained using laser
diffraction. This is an extremely well established technique for particle sizing.
The general principles and expected instrument performances are covered by
an ISO standard [3]. The advantages of this technique, and specifically of the
Mastersizer laser diffraction system, include a wide dynamic range (10nm to
3.5mm), and the flexibility to measure a wide range of samples including dry
powders, suspensions and emulsions. The measurements are also fast, which
allows many measurements to be made in a day.
Samples of different particle size were obtained by running the air jet mill at
different speeds. The samples were measured using a dry dispersion unit. The
Barium Sulphate samples of different particle size were then incorporated into
3 Watching paint dry: relating paint gloss to the particle size of extender pigments
APPLICATION NOTE
The 20° gloss of the alkyd gloss paint was measured over 25 days drying time. The
paint system contained a total pigment volume concentration of 21.5%, of which
the primary pigment concentration was 2.5%.
Results
The particle size distributions of the samples obtained by running the air jet
mill at different speeds are shown in Figure 2. As expected, this shows that as
the speed of the mill/classifier is increased then the particle size decreases. In
order to make sure that there are not oversized particles, the mill is controlled
on the Dv97 (which must at least be below 4.5μm). As the size is critical to the
performance of the product, measurements of particle size are taken at regular
intervals during the production process to ensure that the correct size is obtained.
4 Watching paint dry: relating paint gloss to the particle size of extender pigments
APPLICATION NOTE
The 20° gloss was measured for the four paints made up using the extender
pigments of different particle size [Table 1]. Figure 3 shows the gloss as a function
drying time for the four samples. The level of gloss is higher for the sample with
the smallest particle size. This corresponds to smaller particles allowing the paint
to achieve a smoother coating and increasing the amount of light that is reflected.
Figure 3 also shows how the gloss varies over time as the coating dries. In each
case as the coating dries the gloss decreases.
2850 3.58
3550 2.99
4100 2.68
5300 2.5
Figure 3: 20° gloss as a function of drying time for 4 different particle sizes.
5 Watching paint dry: relating paint gloss to the particle size of extender pigments
APPLICATION NOTE
The fact that more gloss is retained by the paint with the smaller extender particle
size is again due to surface roughness. More specifically, it depends on how the
surface roughness changes as the paint dries. When the paint is wet the coating
for each of the samples will have a very smooth surface and consequently a
higher gloss. As the coating dries the surface roughness will become increasingly
dependent on the particle size of the extender. Therefore, in the coatings with the
larger particle size, the surface roughness will increase and the paint will loose
more gloss as it dries.
Conclusions
The particle size of the extender pigment Barium Sulphate has been successfully
measured using laser diffraction. The results of these measurements can be used
to control the production process, by enabling the correct mill speed to be set.
The particle size of an extender pigment is classified on the Dv97. Controlling
the Dv97 allows the proportion of oversized particles within the powder to be
minimized, as these would otherwise affect the opacity and gloss of the coating.
The gloss of a coating can be increased by reducing the particle size. A smaller
particle size produces a smoother coating which allows more light to be reflected
and increases the gloss. Reducing the particle size also aids in the retention of
gloss over time as the coating dries.
6 Watching paint dry: relating paint gloss to the particle size of extender pigments
APPLICATION NOTE
Acknowledgements
Many thanks to Howard Beedle at Viaton Industries, UK for providing the data
presented in the application note.
References
1. Extenders, Clive Hare, Paintings and Coatings Industry, February 2001.
2. The Effect of Fine Particle Size Extenders and Entrapped Air on TiO2 in
Emulsion Paints.
3. ISO 13320:2009 Particle Size Analysis- Laser Diffraction Methods
7 Watching paint dry: relating paint gloss to the particle size of extender pigments
APPLICATION NOTE
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