Professional Documents
Culture Documents
Anachem
Anachem
10.
(d) 0.075 M
(e) 0.13 M I
Given that a reaction absorbs energy and has an activation energy of 50
k:J/mol, which of the following statements are correct? (Hint: Draw the
potential energy diagram.)
(1) The reverse reaction has an activation energy equal to 50 kJ/mol.
(2) The reverse reaction has an activation energy less than 50 kJ/mol.
(3) The reverse reaction has an activation energy greater than 50 k:J/mol.
( 4) The change in internal energy is less than zero.
(5) The change in internal energy is greater than zero.
(a) (1) and (4)
(b) (2) and (4)
( c) (3) and (4)
(d) (2) and (5)
(e) (3) and (5)
11.
If reaction Ah • .
. . as an act1vat1on energy of 250 kJ and reactionB has an
activation energy of 100 kJ, which of the following statements must be
correct?
(a) If reaction A is exothermic and reaction Bis endothermic then
reaction A is favored kinetically.
•• (b) At the same temperature the rate of reaction B is greater than the rate
of reaction A .
I ( c) The energy of reaction A must be greater than the energy of reaction
B.
( d) The energy of reaction B must be greater than the energy of reaction
>!;;-_,
A.
( e) The rate of reaction A at 25 °C equals the rate of reaction B at
,<<
---- 100 °C.
z: 12.
If the activation energy in the forward direction of an elementary step is
------
;7 52 kJ and the activation energy in the reverse direction is 74 kl, what is
the energy of reaction I>. E for this step?
(a) 22 kJ
(b) -22 kJ
(c) 52 kJ
(d) -52kJ
(e) 126 kJ
13.
Suppose the reaction: A + 2B ~ AB2 occurs by the following
mechanism:
Step 1 A + 8 ~ AB slow
Step 2 AB + 8 ~ AB2 fast
Overall A + 28 ~ AB2
The rate law expression must be Rate = _ _ __
(a) k[A]
(b) k[B]
(c) k[A][B]
(d) k[B]2
(e) k[A][B]2
14.
A possible mechanism for the reaction, 2A + B ~ C + D, is:
(l) A+ A p A2 fast, equilibrium
(2) A2 + A ~ A3 slow
(3) A3 + B ~ A + C + D fast
According to the mechanism, the rate law will be:
(a) Rate= k[A]2
(b) Rate= k[A][B]
(c) Rate= k[A]2[B]
(d) Rate= k[A]
(e) Rate= k[A]3
15.
At 300 K, the following reactio .
k[NOCI]2: n JS found to obey the rate Jaw: Rate =