Revision Date 18.07.2016 Revision no 1.

0
Issue Date 21.05.2015 Form No : 018/ EN

SAFETY DATA SHEET

PETROSOL 95A XILENO
According to Regulation (EU) No 2015/830

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name
Product Code
REACH Registration number
Chemical formula
Product description
Other identification
PETROSOL 95A XILENO
30406
01-2119488216-32-0007
C8 H10
Mixture of xylene isomers (≥ 45%) and ethylbenzene (≤ 55%)
Dimethyl benzenes; Xylene solvent; Xylene mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Organic solvent.

1.3. Details of the supplier of the safety data sheet

Supplier ARKEM Kimya San. ve Tic. A.Ş.

Arkem Center
Valide Sultan Cad.No:10 34473
Bahçeköy - Sarıyer - İstanbul
TURKEY
Tel: +90 212 366 4100
Fax: +90 212 226 3477
arkem@arkem.com.tr
www.arkem.com.tr

1.4. Emergency telephone number

ARKEM: +90 212 366 4100

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)

Physical and Chemical Hazards Flam. Liq. 3 - H226
Human health Acute Tox. 4 - H312; Acute Tox. 4 - H332; Skin Irrit. 2 - H315
Environment Not classified.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

Signal Word Warning

Contains xylene, ethylbenzene

Hazard Statements
H226 Flammable liquid and vapour.
H312 Harmful in contact with skin.
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SAFETY DATA SHEET

PETROSOL 95A XILENO
According to Regulation (EU) No 2015/830

H315 Causes skin irritation.

H332 Harmful if inhaled.

Precautionary Statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P235 Keep cool.
P241 Use explosion-proof electrical, ventilating and lighting equipment.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P501 Dispose of contents/container in accordance with national regulations.

2.3. Other hazards

This product does not contain another predicted danger.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

Classification
Name EC No. CAS No. Content
(EC 1272/2008)
Flam. Liq. 3 - H226
Acute Tox. 4 - H312
xylene 215-535-7 1330-20-7 75 -100 %
Acute Tox. 4 - H332
Skin Irrit. 2 - H315
Flam. Liq. 2 - H225
ethylbenzene 202-849-4 100-41-4 < 25%
Acute Tox. 4 - H332

The Full Text for all Hazard Statements are Displayed in Section 16.

Composition Comments
 The data shown are in accordance with the latest EC Directives.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

General information
Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.

Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the
rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Ingestion
DO NOT INDUCE VOMITING! Never make an unconscious person vomit or drink fluids!
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink.
Stop if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, keep head low so that stomach content
doesn't get into the lungs. Get medical attention immediately! Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband.

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SAFETY DATA SHEET

PETROSOL 95A XILENO
According to Regulation (EU) No 2015/830

Skin contact
Wash skin thoroughly with soap and water or use recognised skin cleanser. Remove contaminated clothing and shoes. Get medical
attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes and get medical attention.

Protection of first-aiders
No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer
should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-
to-mouth resuscitation.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation : Harmful if inhaled. May cause respiratory irritation.
Ingestion : May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.
Skin contact : Harmful in contact with skin. Causes skin irritation.
Eye contact : Causes serious eye irritation.

Over-exposure signs/symptoms
Inhalation : Respiratory tract irritation, coughing.
Ingestion : Nausea or vomiting.
Skin contact : Irritation, redness.
Eye contact : Pain or irritation, watering, redness.

4.3. Indication of any immediate medical attention and special treatment needed
No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media
Fire can be extinguished using: Use dry chemical, CO2, water spray (fog) or foam.
Do not use water jet.

5.2. Special hazards arising from the substance or mixture

Unusual Fire & Explosion Hazards

Air/vapor mixtures may be explosive.

Specific hazards
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a
subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or
explosion hazard. Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).

5.3. Advice for firefighters

Special Fire Fighting Procedures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken
involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Protective equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to
European standard EN 469 will provide a basic level of protection for chemical incidents.

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SAFETY DATA SHEET

PETROSOL 95A XILENO
According to Regulation (EU) No 2015/830

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary
and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. Do not smoke,
use open fire or other sources of ignition. Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Wear protective clothing as described in Section 8 of this safety data
sheet.

6.2. Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if
the product has caused environmental pollution (sewers, waterways, soil or air).

6.3. Methods and material for containment and cleaning up

Small spill: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal
container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal
contractor.
Large Spill: Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or
confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-
proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product.

6.4. Reference to other sections

For personal protection, see section 8.
See section 11 for additional information on health hazards.
For waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions
have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material,
kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-
proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures
against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.

7.2. Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from
direct sunlight in a dry, cool and well ventilated area, away from incompatible materials (see section 10) and food and drink.
Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental contamination.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Name Standart TWA – 8 hours STEL - 15 min Notes

xylene 50 ppm 221 mg/m3 100 ppm 442 mg/m3 INSHT

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SAFETY DATA SHEET

PETROSOL 95A XILENO
According to Regulation (EU) No 2015/830

ethylbenzene 100 ppm 441 mg/m3 200 ppm 884 mg/m3 INSHT

INSHT (Instituto Nacional de Seguridad e Higiene en el Trabajo) - National Institute of Occupational Safety and Health

Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal, workplace atmosphere
or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the
necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the
assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of
hazardous substances.

DNEL
Product

End Use : Workers End Use : Workers

Exposure routes : Inhalation Exposure routes : Skin contact
Exposure time : Short term Exposure time : Long term
Value : 442 mg/m3 Value : 3182 mg/kg bw/day

End Use : Workers End Use : Workers

Exposure routes : Inhalation Exposure routes : Skin contact
Exposure time : Short term Exposure time : Long term
Value : 289 mg/m3 Value : 180 mg/kg bw/day

End Use : Workers End Use : Consumers

Exposure routes : Inhalation Exposure routes : Inhalation
Exposure time : Long term Exposure time : Short term
Value : 180 mg/m3 Value : 260 mg/m³

End Use : Workers End Use : Consumers

Exposure routes : Inhalation Exposure routes : Inhalation
Exposure time : Long term Exposure time : Long term
Value : 77 mg/m3 Value : 65,3 mg/m3

End Use : Workers End Use : Consumers

Exposure routes : Inhalation Exposure routes : Skin contact
Exposure time : Long term Value : 1872 mg/kg bw/day
Value : 221 mg/m3
End Use : Consumers
Exposure routes : Ingestion
Value : 12,5 mg/kg bw/day

The markers evaluated more dangerous these are detailed below:

Workers:
Ethylbenzene ≤% 55 Isomers of xylene ≥% 45
Inhalation DNEL = 77 mg / m3 Inhalation DNEL = 221 mg / m3
Dermal DNEL = 180 mg / kg bw /day Dermal DNEL = 3182 mg / kg bw / day
Oral DNEL = - Oral DNEL = -

General Population:
Ethylbenzene ≤% 55 Isomers of xylene ≥% 45
Inhalation DNEL = 14.8 mg / m3 Inhalation DNEL = 65.3 mg / m3
Dermal DNEL = 108 mg / kg bw / day Dermal DNEL = 1872 mg / kg bw / day
Oral DNEL = 1.60 mg / kg bw / day Oral DNEL = 12.5 mg / kg bw / day

DNEL: Derivired No Effect Concentration

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SAFETY DATA SHEET

PETROSOL 95A XILENO
According to Regulation (EU) No 2015/830

PNEC:
Fresh water 0,327 mg/l
Marine 0,327 mg/l
Fresh water 0,327 mg/l
Fresh water sediment 12,46 mg/kg
Marine water sediment 12,46 mg/kg
Soil 2,31 mg/kg
Sewage Treatment Plant 6,58 mg/l

PNEC: Predicted No-Effect Concentration

8.2. Exposure controls

Protective equipment

Process conditions
Provide eyewash, quick drench

Engineering measures
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep
worker exposure to airborne contaminants below any recommended or statutory limits. Use explosion-proof ventilation
equipment.

Respiratory equipment
If ventilation is inadequate, use respirator that will protect against organic vapor and dust/mist.

Hand protection
Chemical-resistant, impervious gloves complying with an approved standard should be worn.
>8 hours (breakthrough time): nitrile rubber.
The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of
the glove material. Before removing gloves clean them with soap and water.

Eye protection
Safety eyewear complying with an approved standard should be used. Recommended: Tightly fitting safety goggles.

Hygiene measures
DO NOT SMOKE IN WORK AREA!
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and
at the end of the working period. Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if
skin becomes contaminated. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are
close to the workstation location.

Skin protection
Protection suit and suitable protective footwear must be worn.

Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering
modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid
Colour Colourless.
Odour Characteristic.
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SAFETY DATA SHEET

PETROSOL 95A XILENO
According to Regulation (EU) No 2015/830

Solubility Insoluble in the following materials: cold water and hot water.
Initial boiling point and boiling range 130-150°C
Melting/Freezing point -39,3°C
pH Value No data available.
Flash point Closed cup: 27 - 32°C
Evaporation rate 0,77 (butyl acetate = 1)
Auto-Ignition Temperature 488°C
Lower explosion limit 0.8 %(V)
Upper explosion limit 6.7 %(V)
Relative density 0,861
Vapour density 3,7 [Air = 1]
Vapour pressure 0,82 kPa [20°C]
Viscosity Kinematic: 0,0074 cm2/s
Kinematic (40°C): 0,0084 cm2/s
Partition coefficient: noctanol/Water 3.12 - 3.2

9.2. Other information

No data available

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2. Chemical stability

Stable under normal temperature conditions and recommended use. Stable under the prescribed storage conditions.

10.3. Possibility of hazardous reactions

Not expected.

10.4. Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers
to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.

10.5. Incompatible materials

Oxidising substances.

10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute Toxicity
Xylene: LC50 5000 ppm, 4 saat (inh.-rat)
LD50 >1700 mg/kg (dermal-rabbit)

Ethylbenzene LD50 >3500 mg/kg (oral-rat)

LD50 >5000 mg/kg (dermal-rabbit)

Human NOAEC Inhalation latter effect 300 mg/m3

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SAFETY DATA SHEET

PETROSOL 95A XILENO
According to Regulation (EU) No 2015/830

Serious eye damage/irritation

xylene: Eyes - Mild irritant– Rabbit.
Eyes - Severe irritant– Rabbit.
Ethylbenzene:
Eyes - Severe irritant– Rabbit.

Skin corrosion/irritation
xylene: Skin - Mild irritant– Rat.
Skin - Moderate irritant– Rabbit.
Ethylbenzene:
Skin - Mild irritant– Rabbit.

Respiratory or skin sensitisation:

Not sensitizing.

Carcinogenicity
Positive - Inhalation - Mouse <75 ppm 103 weeks; 5 days per week
No evidence of carcinogenicity.

Mutagenicity
No data available.

STOT-Single Exposure
Respiratory tract irritation.

STOT-Repeated Exposure
No data available.

Inhalation
In high concentrations, vapours may irritate throat and respiratory system and cause coughing. Harmful if inhaled.

Ingestion
May cause discomfort if swallowed. Gastrointestinal symptoms, including upset stomach.

SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity
Xylene
LC50, 48 hours 8500 ug/L Marine water Crustaceans – Palaemonetes pugio
LC50, 96 hours 3300 - 4093 ug/L Fresh water Fish - Oncorhynchus mykiss - 0,6 g

Ethylbenzene
EC50, 48 hours 2930 to 4400 ug/L Fresh water Daphnia magna - Neonate - <=24 hours
LC50, 48 hours >5200 ug/L Marine water Crustaceans – Americamysis bahia - <24 hours
LC50, 96 hours 4200 ug/L Fresh water Fish - Oncorhynchus mykiss
Chronic NOEC, 48 days 6800 ug/L Fresh water Daphnia magna <=24 hours
Chronic NOEC, 96 days 3300 ug/L Marine water Fish - Menidia menidia

12.2. Persistence and degradability

Readily biodegrability.

12.3. Bioaccumulative potential

LogPow: 3,12 - 3,2
BCF: 29
Potential: Low.

12.4. Mobility in soil

No data available.

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SAFETY DATA SHEET

PETROSOL 95A XILENO
According to Regulation (EU) No 2015/830

12.5. Results of PBT and vPvB assessment

Persistence: Not available.
Bioaccumulation: Not available.
Toxic: Yes.

12.6. Other adverse effects

No data available.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

The generation of waste should be avoided or minimized wherever possible . Significant quantities of waste product residues should
not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation and any regional local authority
requirements.

Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.

Packaging: Please recycle waste pack. Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not
been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create
a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: TRANSPORT INFORMATION

General This substance/mixture may be classified as hazardous. However, it may be dispatched as non-hazardous substance
in cases when the packaging is under limited / exceptional quantity. Please follow the relevant regulations.

14.1. UN number
UN No. (ADR/RID/ADN) 1307
UN No. (IMDG) 1307
UN No. (ICAO) 1307

14.2. UN proper shipping name

Proper Shipping Name XYLENES

14.3. Transport hazard class(es)

ADR/RID/ADN Class 3
ADR/RID/ADN Class Class 3: Flammable liquids.
ADR Label No. 3
IMDG Class 3
ICAO Class/Division 3
Transport Labels

14.4. Packing group

ADR/RID/ADN Packing group III
IMDG Packing group III
ICAO Packing group III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant No.
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SAFETY DATA SHEET

PETROSOL 95A XILENO
According to Regulation (EU) No 2015/830

14.6. Special precautions for user

EMS F-E, S-D
Emergency Action Code •3Y
Hazard No. (ADR) 30
Tunnel Code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Proper shipping name : xylene/ethylbenzene (10% or more) Mixture
Ship type : 2
Pollution category : Y

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Uk Regulatory References
Highly Flammable Liquid Regulations 1972.

Guidance Notes
Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG(108).

EU Legislation
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and
packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation
(EC) No 1907/2006 with amendments. System of specific information relating to Dangerous Preparations. 2001/58/EC.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION

Revision Comments
Revised according to current legislation (CLP).

Issued By
Bülent Özdemir / CRAD Çevre Risk Analiz Denetim ve Eğitim Hizm. A.Ş.
gbf@crad.com.tr Tel: +90 216 335 4600

Issued Note
This SDS is prepared based on the information and documents received from product owner. CRAD or/and SDS author shall not
be responsible for incorrect preapared of SDS and pecuniary loss or intangible damages because of deficient or wrong
information and documents which comes from product owner.

Hazard Statements In Full

H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H332 Harmful if inhaled.

Disclaimer
This information relates only to the specific material designated and may not be valid for such material used in combination with
any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable
as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It
is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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