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Naming Compounds
Naming Compounds
While there are many thousands of different chemical compounds there is a very definite system
of nomenclature whereby we can name or write chemical formulas for most compounds. We divide the
compounds into two main types – binary compounds and ternary compounds.
Binary Compounds
All true binary compounds contain only two elements. The name of every binary compound ends with
“ide.” Binary compounds come in three types. They are:
For Type I binary compounds the metal present can be found in either Group 1 or Group 2 on the
periodic table. The naming system for this type of compound is quite simple and is found below.
2. A simple cation (obtained from a single atom) takes its name from the name of the element.
3. A simple anion (obtained from a single atom) is named by taking the first part of the element
name (the root) and adding the letters “IDE.”
4. Write the name for the compound by combining the names of the ions.
Examples:
· I is the chemical symbol for iodine, whose root is “iod.” Add the “ide” ending to get iodide.
· O is the symbol for oxygen, whose root is “ox.” Add the “ide” ending to get oxide.
· The chemical symbol of potassium is K. K is in the 1st column of the periodic table, therefore, its
oxidation state is +1.
Pp
· Sulfide is derived from sulfur, whose symbol is S. Its oxidation state is -2.
+1 -2
· So far we have… K S.
· The total positive charge must balance the total negative charge. Therefore, we need 2 K atoms to
give a total positive charge of +2. This balances the -2 charge on the sulfur.
· The chemical symbol of magnesium is Mg. Mg is in the 2nd column of the periodic table, therefore,
its oxidation state is +2.
· Chloride is derived from chlorine, whose symbol is Cl. Its oxidation state is -1.
+2 -1
· So far we have… Mg Cl
· The total positive charge must balance the total negative charge. Therefore, we need 2 chlorine
atoms to give a total negative charge of -2. This balances the charge on the magnesium.
Additional examples
KI à potassium iodide
For Type II binary compounds the metal present is NOT found in either Group 1 or Group 2 on the
periodic table. The naming system for this type of compound is found below.
2. A simple cation (obtained from a single atom) takes its name from the name of the element.
Include a Roman numeral to indicate the oxidation number (charge) on the metal cation.
3. A simple anion (obtained from a single atom) is named by taking the first part of the element
name (the root) and adding the letters “IDE.”
4. Write the name for the compound by combining the names of the ions.
Roman numerals
1......... I 6......... VI
4......... IV 9......... IX
5......... V 10....... X
o Fe is not in the 1st or 2nd column; therefore a Roman numeral is needed in the name. We’ll come
back to that shortly.
· Cl is the chemical symbol for chlorine, whose root is “chlor.” Add the “ide” ending to get chloride.
§ Cl has a -1 charge.
o Multiply times the number of those atoms to get the total negative charge.
§ There are 2 Cl atoms.
§ The total negative charge of -2 must be balanced with a total positive charge of +2.
o Divide the total positive charge by the number of atoms to get Roman numeral.
§ There is only 1 Fe
· Put the pieces together to get the name iron (II) chloride.
· S is sulfur, whose root is “sulf.” Add the “ide” ending to get sulfide.
§ There are 2 sulfur atoms so…. 2 x -2 = -4. <---- total negative charge
· Put the pieces together to get the name lead (IV) sulfide.
· The chemical symbol of nickel is Ni. The oxidation state is +3, as given by the Roman numeral.
· Oxide is derived from oxygen, whose symbol is O. Its oxidation state is -2.
+3 -2
· So far we have Ni O.
· In order to balance the charges we find the least common multiple (LCM) of 3 and 2. The LCM is 6.
We need two Ni atoms (+6 ÷ +3 = 2) and three O atoms (-6 ÷ -2 = 3) to balance the charges.
· Putting it all together we have Ni2O3.
· Nitride is derived from nitrogen, whose symbol is N. Its oxidation state is -3.
+4 -3
· So far we have Pb N.
· The LCM of 4 and 3 is 12. We need three Pb atoms (+12 ÷ +4 = 3) and 4 N atoms (-12 ÷ -3 = 4) to
balance the charges.
· Oxide is derived from oxygen, whose symbol is O. Its oxidation state is -2.
+2 -2
· So far we have Fe O
· Since the charges already balance there is no additional work to be done.
Additional examples
Type III binary compounds contain no metal atoms. There are two different naming systems for
Type III binary compounds: the “old system” and the “new system.” The old system uses prefixes to
indicate the number of each atom present and the new system is identical to that used for naming Type
II compounds.
It is important to note that only one system can be used at a time. NEVER mix prefixes and Roman
numerals.
Rules for naming Type III binary compounds: the OLD SYSTEM
1. The first element in the formula is named first, and the full element name is used.
3. Prefixes are used to denote the numbers of atoms present. (See table below)
4. The prefix mono- is never used for naming the first element.
Prefixes
· N is the chemical symbol of nitrogen. Since there is only one nitrogen atom AND it is the first
element the prefix mono is not used.
· O is the chemical symbol of oxygen, whose root is ox. Add the ide ending to get oxide. There are
two oxygen atoms so we also add the prefix di to get dioxide.
· N is the chemical symbol of nitrogen. Since there are two nitrogen atoms we need to add the prefix
di to get dinitrogen.
· O is the chemical symbol of oxygen, whose root is ox. Add the ide ending to get oxide. There is only
one oxygen atom we add the prefix mono (mono IS used for the second element) to get monoxide.
· Tetrachloride has the prefix tetra which means there are 4 atoms present. Chloride is derived from
chlorine, whose symbol is Cl. Thus, there are 4 Cl atoms in the chemical formula.
· The prefix di means 2. Thus there are 2 N atoms in the chemical formula.
· The prefix penta means 5. Thus, there are 5 O atoms in the chemical formula.
Now let us apply the “new system” to these same compounds. For Type III binary compounds the
“new system” is identical to that used to name Type II binary compounds. The advantage to using the
new system is that you have one less system to learn.
Rules for naming Type III binary compounds: the NEW SYSTEM
2. A simple cation (obtained from a single atom) takes its name from the name of the element.
Include a Roman numeral to indicate the oxidation number (charge) on the metal cation.
3. A simple anion (obtained from a single atom) is named by taking the first part of the element
name (the root) and adding the letters “IDE.”
4. Write the name for the compound by combining the names of the ions.
o Nitrogen is not in the 1st or 2nd column; therefore a Roman numeral is needed in the name.
· O is the symbol for oxygen, whose root is “ox.” Add the “ide” ending to get oxide.
§ The total negative charge of -4 must be balanced with a total positive charge of +4.
o Nitrogen is not in the 1st or 2nd column; therefore a Roman numeral is needed in the name.
· O is the symbol for oxygen, whose root is “ox.” Add the “ide” ending to get oxide.
· Put the pieces together to get the name nitrogen (I) oxide.
+4 -1
· So far we have C Cl
· The LCM of 4 and 1 is 4. We need 1 C atom (+4 ÷ +4 = 1) and 4 Cl atoms (-4 ÷ -1 = 4) to balance the
charges.
· The symbol for nitrogen is N. The Roman numeral indicates a charge of +5.
+5 -2
· So far we have N O
· The LCM of 5 and 2 is 10. Therefore, we need 2 N atoms and 5 O atoms to balance the charges.
· Putting it all together we have N2O5.
Ternary Compounds
A polyatomic ion is a group of atoms with an electric charge. (Even though it is a group of atoms it acts
like it were a single atom.)
The names of nearly all polyatomic ions end with the letters –ate or –ite. Beware three exceptions:
cyanide, hydroxide, and peroxide. These ions end with “ide” which can trick into thinking you have a
binary compound when you actually have a ternary compound.
Follow the naming systems for Type I and Type II binary compounds but…
Examples
There are many atoms that form several different polyatomic ions with oxygen. The naming
system for these ions is based on two things: the most common ion in each series and the number of
oxygen atoms compared to the most common ion. The ones that concern us most are ions of
phosphorus, sulfur, nitrogen, chlorine, and carbon. Memorize these ions!
PO43- = phosphate
SO42- = sulfate
NO3- = nitrate
ClO3- = chlorate
CO32- = carbonate
Examples
PO53- = perphosphate
PO33- = phosphite
PO23- = hypophosphite
SO52- = persulfate
SO32- = sulfite
SO22- = hyposulfite
Note: Some of the ions do not exist in the real world, they are written here to show how to use
the naming system.
Naming Acids
For this class, ALL acids begin with H (hydrogen). The names of ALL acids end with the word “acid.”
There are two types of acids: those that contain oxygen and those that do not.
1. Take the name of the anion, add the prefix “hydro” and change the ending to “ic.”
· We know this is an acid because the chemical formula starts with “H.”
· Take the name of the anion (fluoride) add the prefix “hydro” and change the ending to “ic”:
hydrofluoric
· hydrofluoric acid
· We know this is an acid because the chemical formula starts with “H.”
· Next, take the name of the anion (cyanide) and change the ending to “ic”: hydrocyanic
· hydrocyanic acid
· We know the formula starts with “H” because it is an acid. The charge on hydrogen is +1.
· We also know that the acid does not contain oxygen because of the “hydro” prefix.
· Removing the “hydro” and “ic” leaves us with “brom”, the root of bromine or Br. The charge on
bromine is -1.
+1 -1
· So far we have H Br
· We know the formula starts with “H” because it is an acid. The charge on hydrogen is +1.
· We also know that the acid does not contain oxygen because of the “hydro” prefix.
· Removing the “hydro” and “ic” leaves us with sulfur. The charge on sulfur is -2.
+1 -2
· So far we have H S
· The word acid tells us the first element is H. The charge on H is +1.
· We also know it is a ternary acid because the prefix “hydro” (meaning binary acid) is missing.
· Change “ous” to “ite” to get phophite. The formula for phophite is PO3-3.
Assignment
Formula Name
NH4+ ammonium
C2H3O2- acetate
CO32- carbonate
HCO3- bicarbonate
ClO- hypochlorite
ClO2- chlorite
ClO3- chlorate
ClO4- perchlorate
CrO42- chromate
Cr2O72- dichromate
CN- cyanide
OH- hydroxide
NO2- nitrite
NO3- nitrate
MnO4- permanganate
PO43- phosphate
SO32- sulfite
SO42- sulfate
HSO4- bisulfate
C2O42- oxalate
O22- peroxide
Element Root
Arsenic arsen
Bromine brom
Carbon carb
Chlorine chlor
Fluorine fluor
Hydrogen hydr
Iodine iod
Nitrogen nitr
Oxygen ox
Phosphorus phosph
Selenium selen
Sulfur sulf
Tellurium tellur