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Wa0075
Wa0075
doi:10.1016/j.biosystemseng.2004.06.012
PH—Postharvest Technology
(Received 13 November 2003; received in revised form 22 June 2004; published online 20 August 2004)
Abstract
Several physical properties of amaranth seeds (Amaranthus cruentus) were evaluated as a function of moisture
content. When moisture content changed from 77 to 439% d.b., true density decreased from 1390 to 1320 kg
m3, bulk density from 840 to 720 kg m3, specific volume increased from 078 to 110 103 m3 kg1 and
porosity varied from 040 to 045. Shrinkage coefficient was found to be 125. By means of image analysis,
relevant dimensions were measured as a function of moisture content. In the moisture content range of
95–436% d.b., the average length, width and thickness were 142, 129 and 087 mm, respectively. The
geometric mean diameter of seed ranged from 110 to 124 mm, whereas mean sphericity was 082. The average
pycnometric volume and area of one grain were 065 mm3 and 396 mm2, respectively.
r 2004 Silsoe Research Institute. All rights reserved
Published by Elsevier Ltd
Notation
2001; Calzetta Resio et al., 2003; Vizcarra Mendoza The seeds were divided into lots and they were
et al., 2003). Size, surface area and volume are required conditioned to obtain moisture contents in the moisture
in different handling and processing operations and are content range of 7–44% d.b. by adding pre-determined
also needed as input parameters for the prediction of quantities of distilled water and mixing for 30 min. The
transport properties and drying rates of grains through prepared samples were sealed in hermetic flasks and
simulation models. In particular, the estimation of the stored in a refrigerator for 2 days for the moisture to
effective diffusion coefficient of water is affected by the distribute uniformly throughout the sample.
geometry assumed to approximate the grain shape Before the start of each test, the samples were
(Gastón et al., 2002; Kang & Delwiche, 2000). removed from the refrigerator and allowed to equili-
The objective of present work is to measure some brate to room temperature. The moisture content
physical properties, such as true density, bulk density, was determined using the ASAE standard method
specific volume, porosity, shrinkage coefficient, geo- (ASAE 1984). Oven temperature and heating period
metric dimensions, volume and surface area of amar- were set at 901C and 48 h (Lema et al., 2001),
anth seeds. respectively.
A simple parametric model was used to describe the grain porosity is zero, r0 is equal to the density of dry
dependence of physical properties with moisture content solids rs .
(Zogzas et al., 1994). The density of the moist amaranth Bulk density rb or apparent density of a deep-bed of
grains or true density rt in kg m3 is defined as: grains is defined by:
mgrain ms þ mw mgrain
rt ¼ ¼ ð1Þ rb ¼ ð8Þ
V grain V s þ V w þ V a Vb
where mgrain is mass of the sample in g; Vgrain is volume where V b is the bulk volume in mm3 including volume of
of grains in mm3; ms is dry mass in g; mw is mass of void spaces.
water in g; and Vs, Vw and Va, are the volumes in mm3 Deep bed porosity is:
of dry solids, water and air, respectively. It was assumed r
b ¼ 1 b ð9Þ
that the mass of air is negligible. rt
Density of dry solid rs in kg m3 is defined by:
ms 2.3. Geometrical dimensions of amaranth seeds
rs ¼ ð2Þ
Vs
In order to determine the size and shape of the seeds,
and the specific volume n (volume per unit of dry matter)
the images of individual grains were acquired. A 23 inch
in m3 kg1 by:
charge-coupled device (CCD) video camera (XC-711P,
V grain Sony Corp., Japan) was used (Granitto et al., 2002),
n¼ ð3Þ
ms connected to a colour frame grabber (IC-PCI, Imaging
Technology Inc., USA) with 8-bit reference tables per
The volume shrinkage coefficient b is defined by the
colour channel. Illumination was provided by a 150 W
equation:
light source (Fostec Inc., USA) through a quadruple
W fibre optic bundle of 127 mm diameter, with the four
n ¼ n0 1 þ b ð4Þ
100 guides in a symmetric arrangement to produce an even
illumination with good texture enhancement.
where W is moisture content in % d.b. and n0 is specific Grains were chosen at random and exposed to the
volume in m3 kg1 at a moisture content of 0% d.b. camera with two orientations: horizontally and verti-
Other researchers (Saravacos & Maroulis, 2001) cally, as shown in Fig. 1. Images were taken with a
define the volume shrinkage coefficient by the following 768 512 pixel resolution on a blue background, which
relationship, which represents the proportion of initial can be easily subtracted by standard segmentation
specific volume that shrinks as water is removed: routines because of the difference in colour with the
b ðW i W Þ seeds. From the binarised images, length A, width B and
n ¼ ni ð5Þ
rw 100 thickness C, in mm, were determined (Granitto et al.,
2002; Keefe et al., 1986; Yutaka et al., 1982).
where W i is the initial moisture content of the moist Geometric mean diameter Dg in mm and sphericity f
food material in % d.b., ni is the specific volume at values were found using the following expressions
initial moisture content in m3 kg1 and rw is water (Mohsenin, 1970):
density in kg m3. The symbol b is introduced to
1
identify this coefficient from the previous one. The Dg ¼ ðABC Þ3 ð10Þ
shrinkage coefficient b thus defined varies between 0
(no shrinkage) and 1 (full shrinkage). Both coefficients 1
ðABC Þ3
are simply related by: f¼ ð11Þ
A
b
b¼ ð6Þ
n0 rw
2.4. Volume, shape and surface area of amaranth seeds
Combining Eqns (1) and (3), leads to the following
non-linear relationship between the grain density and
If the number of grains N contained in the sample is
moisture content:
known, the pycnometric volume of one grain V g in mm3
r0 ð100 þ W Þ can be determined from the pycnometric volume of the
rt ¼ ð7Þ
ð100 þ bW Þ sample V grain :
where r0 is the density at a moisture content of 0% d.b. V grain
Vg ¼ ð12Þ
If the volume of air pores V a is negligible so that the N
112 R. ABALONE ET AL.
C
e6 ¼ ð19Þ with values for the coefficient of determination R2 of
2 099 and 087, respectively.
The other two semi-axes, e4 and e5, were determined The results for bulk density are in accordance with
so as to make the relative difference between geometric those presented for sunflower (Gupta & Das, 1997),
volume and grain pycnometric volume negligible guna (Aviara et al., 1999), green gram (Nimkar &
(5 104%) in comparison to the relative error (5%) Chattopadhyay, 2001), Turkish mahaleb (Aydin et al.,
involved in the grain pycnometric volume measurement. 2002) and cotton (Özarslan, 2002). Vizcarra Mendoza et
Geometric volume and surface areas of the solid of al. (2003) reported for the variety Amaranthus hipocon-
revolution were calculated by rotation of the area and driacus 860 kg m3 for bulk density, without reference of
the boundary shown in Fig. 2(c) about the Y axis of the moisture range considered. Compared to quinoa
symmetry, respectively. seed, a pseudocereal of similar characteristics, in the
moisture content range of 7–25% d.b., amaranth bulk
density was 15% higher than those reported by Vilche
3. Results and discussion et al. (2003).
Comparing Eqn (20) with Eqn (4) the shrinkage
3.1. Physical properties of amaranth seeds coefficient b and the specific volume n0 were determined,
giving values of 125 and of 071 103 m3 kg1,
Table 1 shows the mean measured values of mass of respectively. b is calculated from Eqn (6), giving a
sample mgrain, dry mass ms and volume of sample Vgrain value of 089. The density r0 (the reciprocal of n0 ) has a
together with the number of grains N contained in each value of 1411 kg m3.
sample. Figure 5 displays true density rt as function of
Applying Eqns (1), (3), (8) and (9) true density rt , moisture content. True density decreased from 1390 to
specific volume n, bulk density rb and porosity b were 1320 kg m3 in the moisture range of 77–439% d.b.
determined for each moisture content. Vizcarra Mendoza et al. (2003) reported for Amaranthus
Figures 3 and 4 display specific volume n and bulk hipocondriacus a value of 1370 kg m3. In order to verify
density rb as function of moisture content. Specific the parametric model presented previously (Section 3.2),
114 R. ABALONE ET AL.
1.2 1420
1400
-1
1.1
Specific volume v, 10-3m kg
1380
1.0
i
1360
0.9 1340
0.8 1320
1300
0.7
10 20 30 40 10 20 30 40
Moisture content W,% d.b. Moisture content W,% d.b.
Fig. 3. Specific volume as function of moisture content. Fig. 5. True density as function of moisture content.
, experimental data; —— , linear fit , experimental data; —— , predicted values with Eqn (22)
800 0.48
840
Bulk density , kgm-3
0.44
800
Porosity b
b
760
0.40
720
0.36
680
10 20 30 40 10 20 30 40
Moisture content W,% d.b. Moisture content W,% d.b.
Fig. 4. Bulk density as function of moisture content. Fig. 6. Deep-bed porosity as function of moisture content.
, experimental data; —— , linear fit , experimental data; —— , linear fit
b and r0 values were introduced in Eqn (7) giving: Deep bed porosity varied from 040 to 045 (Fig. 6),
showing an increasing linear dependence with moisture
1411ð100 þ W Þ
rt ¼ ð22Þ content expressed by:
ð100 þ 125 W Þ
b ¼ ð038 þ 00016 W Þ ð23Þ
True density calculated with Eqn (22) was compared
to measured values in Fig. 5 showing small deviations with a value for the coefficient of determination R2 of
between them. True density bears a non-linear decreas- 075.
ing relationship with moisture content, different from In the moisture content range of 77–439% d.b.,
the linear decreasing trend reported for guna (Aviara et porosity only increased 125% in contrast with the wide
al., 1999), green gram (Nimkar & Chattopadhyay, variation reported for quinoa (Vilche et al., 2003) of
2001), Turkish mahaleb (Aydin, 2002) and cotton about 1258% in the moisture range of 46–258% d.b.
(Özarslan, 2002) and opposite to the increasing linear On average porosity of amaranth was found to be of the
trend reported for quinoa (Vilche et al., 2003) and same order as wheat, shelled corn and sorghum
sunflower (Gupta & Das, 1997). (Brooker et al., 1974).
SOME PHYSICAL PROPERTIES OF AMARANTH SEEDS 115
Table 2
Mean measured dimensions of amaranth grains in the moisture content range of 9 . 5–43 . 6% d.b.
Moisture content Length (A), Width (B), Thickness (C), Geometric Mean Diameter Sphericity
% d.b. mm mm mm (Dg), mm (f)
95 135 122 081 110 081
155 140 126 084 114 082
210 140 127 087 115 083
305 144 129 089 118 082
436 150 137 093 124 083
Table 3
Measured pycnometric volume and calculated geometric area of one grain in the moisture content range of 9 . 5–43 . 6% d.b.
Moisture content % Volume (Vg), Equivalent sphere Oblate spheroid area Solid of revolution
d.b. mm3 area (Ssph), mm2 (Soblate), mm2 area (Ssolid ), mm2
were found to be: to 720 kg m3 and porosity varied from 040 to 045.
e1 ¼ ð0625 þ 000203 W Þ ð31Þ Shrinkage coefficient was found to be 125. If it is
defined as the proportion of initial specific volume
e2 ¼ ð0308 þ 000119 W Þ ð32Þ that shrinks as water is removed, was found to
2 be 089.
with values for the coefficient of determination R of Relevant dimensions of the grain were measured and
096 and 098, respectively. correlations with moisture content were obtained in the
In the solid of revolution case, the semi-axis of the moisture content range of 95–436% d.b. On average,
ellipsoids were found to bear the following relationship length, width and thickness were 142, 129 and 087 mm,
with moisture content: respectively. The geometric mean diameter of seed
e3 ¼ ð0625 þ 000203 W Þ ð33Þ varied from 110 to 124 mm, whereas mean sphericity
was 082. The average pycnometric volume of one grain
e4 ¼ ð0231 þ 000098 W Þ ð34Þ was 065 mm3.
Three different geometries (equivalent sphere, oblate
e5 ¼ ð0481 þ 000157 W Þ ð35Þ spheroid, solid of revolution) having the same pycno-
metric volume as the grain were assumed to approx-
e6 ¼ ð0393 þ 000168 W Þ ð36Þ
imate amaranth shape and calculate the grain surface
2
with values for the coefficient of determination R of area. Based on the solid of revolution shape, the
096, 095, 088 and 091, respectively. estimated surface area was on average 396 mm2, being
Table 3 lists the grain pycnometric volume and this values 10% greater than that of the equivalent
calculated surface areas associated to each representa- sphere.
tion. Results show that the surface area calculated with
the solid of revolution is 10% greater than the surface of
the equivalent sphere. No significant differences (less References
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