CONFIDENTIAL EH/APR 2011/CPE591

UNIVERSITI TEKNOLOGI MARA

FINAL EXAMINATION

COURSE PROCESS ENGINEERING I

COURSE CODE CPE591
EXAMINATION APRIL 2011
TIME 3 HOURS

INSTRUCTIONS TO CANDIDATES

1. This question paper consists of five (5) questions.

2. Answer ALL questions in the Answer Booklet. Start each answer on a new page.

3. Do not bring any material into the examination room unless permission is given by the
invigilator.

4. Please check to make sure that this examination pack consists of:

) the Question Paper

) a three - page Appendix 1
in) a one - page Appendix 2
iv) a one - page Appendix 3
v) an Answer Booklet - provided by the Faculty

DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO

This examination paper consists of 4 printed pages
) Hak Cipta Universiti Teknologi MARA CONFIDENTIAL
CONFIDENTIAL 2 EH/APR 2011/CPE591

QUESTION 1

(P02, C01.C2, C3, C1)

a) Describe two of the equipments used for drying with complete labeled diagram.
Explain the drying process and give one example of materials using the equipment
for drying process.
(10 marks)

b) i) Rosalinda is watching the latest weather report when it states that the
temperature is 35°C and the relative humidity is 40%. By using the humidity
chart, estimate the actual humidity H, when the dew point is 20°C. Then,
calculate the humid volume vH, and humid heat cs.
(5 marks)

ii) If the air is having 35°C temperature with pressure of 101.325 kPa and contains
water vapor with a partial pressure pA = 5.3 kPa, calculate the percentage
humidity, HP and percentage relative humidity, HR
(6 marks)

c) Adiabatic saturation temperature, Ts is the temperature of the water being recirculated

until it reaches a steady-state temperature. Whereas, wet bulb temperature is the
steady-state nonequilibrium temperature reached when a small amount of water is
contacted under adiabatic conditions by a continuous stream of gas. Draw a figure of
the method used to measure the wet bulb temperature complete with the label.
(4 marks)

QUESTION 2

(P01.C02, C3, C6)

a) An aqueous slurry at 30°C containing 20 wt % solids is fed to an evaporator in which

enough water is vaporized at 1 atm to produce product slurry containing 35 wt%
solids. Heat is supplied to the evaporator by feeding saturated steam at 1.69 bar
absolute into a coil immersed in the liquid. The steam condenses in the coil, and the
slurry boils at the normal boiling point of pure water. The heat capacity of the solids
may be taken to be half that of liquid water.

i) Draw and label the flow diagram of the evaporator.

(4 marks)

ii) State the datum temperature. Then, calculate the required steam feed rate if
the feed rate is given as 1000 kg/h.
(9 marks)

iii) If the feed rate is cut into half, evaluate the new amount of steam used.
(2 marks)

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CONFIDENTIAL 3 EH/APR 2011/CPE591

b) Fruit juices such as orange juice are biological materials. Their evaporation is
different from the evaporation of inorganic materials. They are heat-sensitive and the
viscosity increases greatly as concentration increases. Explain the problems that
could occur when handling this type of materials. Select a suitable evaporator and
operational strategies which can overcome such problems in handling fruit juices.
Justify your selection.
(10 marks)

QUESTION 3

(P01,C02, C3, C2)

a) 200 kg of an aqueous solution containing 20.0 wt% sodium acetate (NaC2H302)

enters an evaporative crystallizer at 60°C. When the solution is exposed to the low
pressure in the evaporator, 16.9 wt% of the water evaporates, concentrating the
remaining solution and causing crystals of sodium acetate trihydrate
(NaC2H302.3H20) to form. The solubility is 15.4 kg NaC2H3O2/100 kg total water.
The effluents (crystals, solution and water vapor) are all at 20°C.

i) Draw the process flow diagram.

(3 marks)

ii) Calculate the yield (kg) of trihydrate crystals and the mass (kg) of the liquid
solution in which the crystals are suspended.
(5 marks)

iii) Determine the yield of trihydrate crystals and liquid solution if there is no
water evaporates from the process.
(4 marks)

b) In designing and operating a crystallizer, it is important to understand the

mechanisms by which the crystals are formed then grow. Nucleation or nucleus
formation is the basic steps for the overall process of crystallization from a
supersaturated solution. Describe two of the nucleation theories.
(8 marks)

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CONFIDENTIAL 4 EH/APR 2011/CPE591

QUESTION 4

(P02,C01,C3, C2)

a) A membrane separation unit is used to dry (remove water vapor from) a gas mixture
containing 60.0 mole% H20(v) and the balance C0 2 . The gas enters the unit at flow
rate of 2 x 104 cm3 (STP)/s. The desired composition of the reject is x0 = 0.3. The
membrane thickness is 1 mm, the pressure on the feed side is 100 cm Hg, and on
the permeate side it is 20 cm Hg.

i) Calculate the ideal separation factor, a* if given the permabilities of P'A = 65 x

10"10 cm3 (STP).cm/(s.cm2.cm Hg) and P'B = 6.5 x 10"10. Then, assuming the
complete mixing model, calculate the fraction permeated, 9, and the
membrane area, Am.
(7 marks)

ii) Determine the minimum reject concentration for xf = 0.6. Then, evaluate the
effect of raising the feed purity to 0.7.
(3 marks)

b) Microfiltration use pressure-driven flow through a membrane to separate micron-size

particles from fluids. There are many different geometries of membranes are used
such as plate and frame, hollow fiber and disposable cartridges. Describe two
membranes with diagrams.
(10 marks)

QUESTION 5

(P05, C02, C6)

Most water is purified for human consumption (drinking water) but water purification may
also be designed for a variety of other purposes, including meeting the requirements of
medical, pharmacology, chemical and industrial applications. Suggest two commercial
adsorbents that can be used to treat the water supply. Compare between these two
adsorbents and justify your selection.
(10 marks)

END OF QUESTION PAPER

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CONFIDENTIAL APPENDIX 1(1) EH/APR 2011/CPE591

Table 1 Vapor Pressure of Water

Temperature Vapor Pressure Temperature Vapor Pressure

e
K kPa JBWt H§ K C kPa mm H$

273.15 0 0.611 4.58 32115 50 12.333 92,5!

28115 10 l.ZZo 9.21 33115 60 19.92 149.4
29115 20 1338 17.54 34115 70 31.16 233.7
298.15 25 1168 23.76 35115 80 47.34 355-1
30115 30* 4.242 31.82 36115 90 70.10, 525.8
31115 40 7.375 55.32 37115 100 101.325 760.0

Sourct: PhysikaHsMechnishe, Rcichsansah, HoJborn, Scbeel, and Heiming, Warmetabcl'

len. Brunswick, Germany: Friedrich Vic wig ai»d Son, 1909.

Table 2 Heat Capacity of Liquid Water at 101.325 kPa (1 Atm)

Tempereiure Hem Capacity^ cp Temperature Heat Capacity, cp

Z
*C K caljg<*C kJjkg-K C K attfg*C Ujkg*K

0 273.15 1.0080 4220 50 32115 0.9992 4 J 83

10 283.15 1.0019 4.195 60 333.15 1.0001 4.187
20 29115 0.9995 4.185 70 34115 1.0013 4.192
25 298.15 0.9989 4.182 80 353.15 L0O29 4.199
30 303.15 0.9987 4.181 90 36115 1.0050 4.208
40 313.15 0.9987 4.181 100 37115 1.0076 4.219

S«ir«? N. S. Osborne, H. F. Slil»son» and D. C. Ginnings, Bur. Standards J. Res.t 23,197

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CONFIDENTIAL APPENDIX 1(2) EH/APR 2011/CPE591

Table 3 Properties of Saturated Steam and Water (Steam Table), SI Units

SpecificVolume Enthalpy Entropy

Temper- Vapor (m3/kg) (kJ/kg) {kJ/kg-K)
oture Pressure
(°C) {kPa) Liquid Sai'd Vapor Liquid Sat 'd Vapor Liquid Sat 'd Vapor

0.01 0.6113 0.0010002 206.136 0.00 2501.4 0.0000 9.1562

3 0.7577 0.0010001 168.132 12.57 2506.9 0.0457 9.0773
6 0.9349 0.0010001 137.734 25.20 2512.4 0.0912 9.0003
9 1.1477 0.0010003 113.386 37.80 2517.9 0.1362 8.9253
12 1.4022 0.0010005 93.784 50.41 2523.4 0.1806 8.8524
15 1.7051 0.0010009 77.926 62.99 2528.9 0,2245 8.7814
18 2.0640 0.0010014 65.038 75.58 2534.4 0.2679 8.7123
21 2.487 0.0010020 54.514 88.14 2539.9 0.3109 8.6450
24 2.985 0.0010027 45.883 100.70 2545.4 0,3534 8.5794
25 3.169 0.0010029 43.360 104.89 25412 0.3674 8.5580
27 3.567 0.0010035 38.774 113.25 2550.8 0.3954 8.5156
30 4.246 0.0010043 32.894 125.79 25563 0.4369 8.4533
33 5.034 0.0010053 28.011 138.33 2561.7 0.4781 8.3927
36 5.947 0.0010063 23.940 150.86 2567.1 0.5188 8.3336
40 7.384 0.0010078 19.523 167.57 2574.3 0.5725 8.2570
45 9.593 0.0010099 15.258 188.45 2583.2 0.6387 8.1648
50 12.349 0.0010121 12032 209.33 2592.1 0.7038 8.0763
55 15.758 0.0010146 9.568 230.23 2600.9 0.7679 7.9913
60 19.940 0.0010172 7.671 251.13 2609.6 0.8312 7.9096
65 25.03 0.0010199 6.197 272.06 2618.3 0.8935 7.8310
70 31.19 0.0010228 5.042 292.98 2626.8 0.9549 7.7553
75 38.58 0.0010259 4.131 313.93 2635.3 1.0155 7.6824
80 47.39 0.0010291 3.407 334.91 2643.7 1.0753 7.6122
"85 57.83 0.0010325 2.828 355.90 265 L9 1.1343 7.5445
90 70.14 0.0010360 Z361* 376.92 2660.1 1.1925 7.4791
95 84.55 0.0010397 1.9819 397.96 2668.1 1.2500 7.4159
100 101.35 0.0010435 1.6729 419.04 2676.1 1.3069 7.3549

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CONFIDENTIAL APPENDIX 1(3) EH/APR 2011/CPE591

Table 3 SI Units, Continued

SpecificVolume Enthalpy Entropy

3
Temper- Vapor " * (m/kg) {kJJkg) (U/kgK)
Pressure
ature (kPa) Liquid Sat'd Vapor Liquid Sat'd Vapor Liquid Sat'd Vapor

105 120.82 0.0010475 1.4194 440.15 2683.8 1.3630 7.2958

110 143.27 0.0010516 1.2102 461.30 2691.5 1.4185 7.2387
115 169.06 0.0010559 1.0366 482.48 2699.0 1.4734 7.1833
120 198.53 0.0010603 0.8919 503.71 2706.3 1.5276 7.1296
125 232.1 0.0010649 0.7706 524.99 2713.5 1.5813 7.0775
130 270.1 0.0010697 0.6685 546.31 2720.5 1.6344 7.0269
135 313.0 0.0010746 0.5822 567.69 2727.3 1.6870 6.9777
140 316.3 0.0010797 0.5089 589.13 2733.9 1.7391 6.9299
145 415.4 0.0010850 0.4463 610.63 2740.3 1.7907 6.8833
150 475?8 0.0010905 0.3928 632.20 2746.5 1.8418 6.8379
155 543.1 0.0010961 0.3468 653.84 2752.4 1.8925 6.7935
160 617.8 0.0011020 0.3071 675.55 2758.1 1.9427 6.7502
165 700.5 0.0011080 0.2727 697.34 2763.5 1.9925 6.7078
170 791.7 0.0011143 0.2428 719.21 2768.7 2.0419 6.6663
175 892.0 0.0011207 0.2168 741.17 2773.6 2.0909 6.6256
180 1002.1 0.0011274 0.19405 763.22 2778.2 2.1396 6.5857
190 1254.4 0.0011414 0.15654 807.62 2786.4 2.2359 6.5079
200 1553.8 0.0011565 0.12736 852.45 2793.2 2.3309 6.4323
225 2548 0.0011992 0.07849 966.78 2803.3 2.5639 6.2503
250 3973 0.0012512 0.05013 1085.36 2801.5 2.7927 6.0730
275 5942 0.0013168 0.03279 1210.07 2785.0 3.0208 5.8938
300 8581 0.0010436 0.02167 1344.0 2749.0 3.2534 5.7045

Source: Abridged from J. H. Keenan. F, G. Kcycs. P. G. Hill, and J. G. Moore, Steam Tables—Metric Units. New
New Yoric: John Wiley & Sons, Inc., 1969. Reprinted by permission of John Wiley & Sons, Inc.

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CONFIDENTIAL APPENDIX 2 EH/APR 2011/CPE591

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Humidity chart for mixtures of air and water vapor at a total pressure
of 101.325 kPa (760 mm Hg)

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CONFIDENTIAL APPENDIX 3 EH/APR 2011/CPE591

LIST OF FORMULAE

1. H 28.97
= ^"x ^
P-p A

2 H = — -^-
28.97 P-pAS

3. cs kJ/kg dry air .K = 1.005 + 1.88 H

4. u H m 3 / k g d r y a i r = f ^ T K ( ^ 4 - ^ H ) = (2.83 *10"3+4.56 x-|0"3 H ) T K

5. hF=cpF(jf-Ti)

6. q=UAAT

7 _xf %
X
'• ° (1-9)
Xf x (1 9)
8 v
y - ' ° '
p e
9
qfy P
9. 1Am=
^j(phx0-P,yp)

-b+Jb
lb 2 -4ac
10. y =—^r
'P 2a

11. a=1-a*

12. b=^(l-x
v 0 )-1+a*^x
J 0 +a*
Pi ° Pi

13.x=-a*^x0
Pi

_ Xf[l+(°'-1)g(1-*f)]
14. xoM= a*(1-xf)+(xf)

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