Sample Information

Analyzed by : Admin
Analyzed : 10/15/2015 10:10:26 AM
Sample Type : Unknown
Level # :1
Sample Name : A0
Sample ID : A0
IS Amount : [1]=1
Sample Amount :1
Dilution Factor :1
Vial # :4
Injection Volume : 1.00
Data File : C:\GCMSsolution\Data\Project1\Data\2015\Oktober\P'Anton\A0.qgd
Org Data File : C:\GCMSsolution\Data\Project1\Data\2015\Oktober\P'Anton\A0.qgd
Method File : C:\GCMSsolution\Data\Project1\method\028_pinen_AI.qgm
Org Method File : C:\GCMSsolution\Data\Project1\method\028_pinen_AI.qgm
Report File :
Tuning File : C:\GCMSsolution\System\Tune1\13092013.qgt
Modified by : Admin
Modified : 10/15/2015 1:42:04 PM

Chromatogram A0 C:\GCMSsolution\Data\Project1\Data\2015\Oktober\P'Anton\A0.qgd
TIC
3.727

7,000,000
3.826
2.632

3.974
2.974

5.224
2.828

4.567

4.950

5.982
3.910

4.820

3.0 4.0 5.0 6.0 7.0 8.0

min

Peak Report TIC

Peak# R.Time I.Time F.Time Area Area% Height Height% A/H Mark Name
1 2.632 2.605 2.685 298136 1.39 141027 1.96 2.11 Propane, 2,2-dimethoxy- (CAS) 2,2-Dimethoxypropane
2 2.828 2.795 2.875 19358 0.09 8742 0.12 2.21 1-Butanol, 3-methyl- (impure) (CAS) 3-Methyl-1-butanol
3 2.974 2.935 3.030 52646 0.24 22700 0.31 2.32 Benzene, methyl- (CAS) Toluene
4 3.727 3.605 3.785 20317717 94.41 6677710 92.65 3.04 1R-.alpha.-Pinene
5 3.826 3.785 3.880 562453 2.61 253784 3.52 2.22 V Camphene
6 3.910 3.880 3.940 21191 0.10 8067 0.11 2.63 V .gamma.-Terpinene
7 3.974 3.940 4.025 89666 0.42 40773 0.57 2.20 V 2-.BETA.-PINENE
8 4.567 4.530 4.615 24352 0.11 10633 0.15 2.29 .ALPHA.-TERPINOLENE
9 4.820 4.795 4.920 7797 0.04 6191 0.09 1.26 1,7,7-Trimethylbicyclo[2.2.1]hept-5-en-2-ol
10 4.950 4.920 5.005 23994 0.11 10112 0.14 2.37 Verbenol
11 5.224 5.180 5.275 36725 0.17 15481 0.21 2.37 3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl- (CAS) CYCLOHEXEN
12 5.982 5.940 6.085 65665 0.31 12541 0.17 5.24 Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl-, [1S-(1.alpha.,2.beta.,5.alpha.)]-
21519700 100.00 7207761 100.00

Library
<< Target >>
Line#:1 R.Time:2.630(Scan#:7) MassPeaks:117
RawMode:Averaged 2.625-2.635(6-8) BasePeak:73.10(62306)
BG Mode:Calc. from Peak Group 1 - Event 1
100 73

43
89

40 57 98 121 148 160 176 187 197 210 230 245 259 276 290 300

0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:1 Entry:8493 Library:WILEY7.LIB
SI:95 Formula:C5 H12 O2 CAS:77-76-9 MolWeight:104 RetIndex:0
CompName:Propane, 2,2-dimethoxy- (CAS) 2,2-Dimethoxypropane $$ Acetone dimethyl acetal $$ Acetone dimethyl ketal $$ Acetone, dimethyl acetal $$ Me2C(OMe)2 $$
100 73

43
MeO 2 C(Me) 2
15
29 89

13 57

0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:2 Entry:8492 Library:WILEY7.LIB
SI:94 Formula:C5 H12 O2 CAS:77-76-9 MolWeight:104 RetIndex:0
CompName:Propane, 2,2-dimethoxy- (CAS) 2,2-Dimethoxypropane $$ Acetone dimethyl acetal $$ Acetone dimethyl ketal $$ Acetone, dimethyl acetal $$ Me2C(OMe)2 $$
100 73

43
MeO 2 C(Me) 2
15 89
29

2 57 101

0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:3 Entry:8494 Library:WILEY7.LIB
SI:93 Formula:C5 H12 O2 CAS:77-76-9 MolWeight:104 RetIndex:0
CompName:Propane, 2,2-dimethoxy- (CAS) 2,2-Dimethoxypropane $$ Acetone dimethyl acetal $$ Acetone dimethyl ketal $$ Acetone, dimethyl acetal $$ Me2C(OMe)2 $$
100 73

43
MeO 2 C(Me) 2
41 89
27
25 57

0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:4 Entry:8497 Library:WILEY7.LIB
SI:93 Formula:C5 H12 O2 CAS:77-76-9 MolWeight:104 RetIndex:0
CompName:Propane, 2,2-dimethoxy- (CAS) 2,2-Dimethoxypropane $$ Acetone dimethyl acetal $$ Acetone dimethyl ketal $$ Acetone, dimethyl acetal $$ Me2C(OMe)2 $$
100 73

43 MeO 2 C(Me) 2
41 89
27
57

0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:5 Entry:8495 Library:WILEY7.LIB
SI:93 Formula:C5 H12 O2 CAS:77-76-9 MolWeight:104 RetIndex:0
CompName:Propane, 2,2-dimethoxy- (CAS) 2,2-Dimethoxypropane $$ Acetone dimethyl acetal $$ Acetone dimethyl ketal $$ Acetone, dimethyl acetal $$ Me2C(OMe)2 $$
100 73

43
MeO 2 C(Me) 2
41 89

14 57 104

0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
<< Target >>
Line#:2 R.Time:2.830(Scan#:47) MassPeaks:136
RawMode:Averaged 2.825-2.835(46-48) BasePeak:55.10(1678)
BG Mode:Calc. from Peak Group 1 - Event 1
100 55
41 70

57

40 97 125 137 149155 174 183 200 215 229 239 257 278 287 299

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:1 Entry:4144 Library:WILEY7.LIB
SI:93 Formula:C5 H12 O CAS:123-51-3 MolWeight:88 RetIndex:0
CompName:1-Butanol, 3-methyl- (impure) (CAS) 3-Methyl-1-butanol $$ Isopentanol $$ 3-Methylbutanol $$ Fusel oil $$ Isoamylol $$ Isoamyl alcohol $$ Isobutyl carbinol $$ Isopentyl alcohol $$ 2-Methyl-4-bu
100 55
41 70

57
HO CH 2CH 2CHMe 2
27

88

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:2 Entry:3822 Library:WILEY7.LIB
SI:93 Formula:C5 H12 O CAS:0-00-0 MolWeight:88 RetIndex:0
CompName:ISOAMYLALCOHOL $$
100 55
70

41

57

40

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:3 Entry:4193 Library:WILEY7.LIB
SI:92 Formula:C5 H12 O CAS:123-51-3 MolWeight:88 RetIndex:0
CompName:ISO AMYL ALCOHOL $$ ISO BUTYL CARBINOL $$ FUSEL AMYL ALCOHOL $$
100 41 55
70

57
HO CH 2CH 2CHMe 2

35 87

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:4 Entry:4140 Library:WILEY7.LIB
SI:91 Formula:C5 H12 O CAS:123-51-3 MolWeight:88 RetIndex:0
CompName:1-Butanol, 3-methyl- (impure) (CAS) 3-Methyl-1-butanol $$ Isopentanol $$ 3-Methylbutanol $$ Fusel oil $$ Isoamylol $$ Isoamyl alcohol $$ Isobutyl carbinol $$ Isopentyl alcohol $$ 2-Methyl-4-bu
100 41 55

70

27 57 HO CH 2CH 2CHMe 2

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:5 Entry:4145 Library:WILEY7.LIB
SI:91 Formula:C5 H12 O CAS:123-51-3 MolWeight:88 RetIndex:0
CompName:1-Butanol, 3-methyl- (impure) (CAS) 3-Methyl-1-butanol $$ Isopentanol $$ 3-Methylbutanol $$ Fusel oil $$ Isoamylol $$ Isoamyl alcohol $$ Isobutyl carbinol $$ Isopentyl alcohol $$ 2-Methyl-4-bu
100 41 55

70

57 HO CH 2CH 2CHMe 2
39

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
<< Target >>
Line#:3 R.Time:2.975(Scan#:76) MassPeaks:125
RawMode:Averaged 2.970-2.980(75-77) BasePeak:91.10(10479)
BG Mode:Calc. from Peak Group 1 - Event 1
100 91

65
40 51 74 99 114 136 152 161 171 192 215 234 248 255 276 292

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:1 Entry:4668 Library:WILEY7.LIB
SI:97 Formula:C7 H8 CAS:108-88-3 MolWeight:92 RetIndex:0
CompName:Benzene, methyl- (CAS) Toluene $$ CP 25 $$ Methylbenzene $$ Toluol $$ Methacide $$ Antisal 1a $$ Methylbenzol $$ Phenylmethane $$
100 91

Me

39 51 65
27 77

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:2 Entry:4672 Library:WILEY7.LIB
SI:97 Formula:C7 H8 CAS:108-88-3 MolWeight:92 RetIndex:0
CompName:Benzene, methyl- (CAS) Toluene $$ CP 25 $$ Methylbenzene $$ Toluol $$ Methacide $$ Antisal 1a $$ Methylbenzol $$ Phenylmethane $$ METHYLBENZENE(TOLUENE) $$ Benzene, methyl $$
100 91

Me

39 65
27 51
74

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:3 Entry:1209 Library:NIST08.LIB
SI:96 Formula:C7H8 CAS:108-88-3 MolWeight:92 RetIndex:794
CompName:Toluene $$ Benzene, methyl $$ Methacide $$ Methylbenzene $$ Methylbenzol $$ Phenylmethane $$ Antisal 1a $$ Toluol $$ Methane, phenyl- $$ NCI-C07272 $$ Tolueen $$ Toluen $$ Toluolo $$ R
100 91

39 65
51
27 74

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:4 Entry:4670 Library:WILEY7.LIB
SI:95 Formula:C7 H8 CAS:108-88-3 MolWeight:92 RetIndex:0
CompName:Benzene, methyl- (CAS) Toluene $$ CP 25 $$ Methylbenzene $$ Toluol $$ Methacide $$ Antisal 1a $$ Methylbenzol $$ Phenylmethane $$ METHYLBENZENE(TOLUENE) $$ Benzene, methyl $$
100 91

Me

39 65
51
27 74

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:5 Entry:4674 Library:WILEY7.LIB
SI:95 Formula:C7 H8 CAS:108-88-3 MolWeight:92 RetIndex:0
CompName:Benzene, methyl- (CAS) Toluene $$ CP 25 $$ Methylbenzene $$ Toluol $$ Methacide $$ Antisal 1a $$ Methylbenzol $$ Phenylmethane $$ METHYLBENZENE(TOLUENE) $$ Benzene, methyl $$
100 91

Me

39 65
27 51
77

20 40 60 80 100 120 140 160 180 200 220 240 260 280
<< Target >>
Line#:4 R.Time:3.725(Scan#:226) MassPeaks:172
RawMode:Averaged 3.720-3.730(225-227) BasePeak:93.15(1928705)
BG Mode:Calc. from Peak Group 1 - Event 1
100 93

77 136
105 121
40 67
143 157 171 185 208 227 248 265 277 287 295

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:1 Entry:9788 Library:NIST08.LIB
SI:95 Formula:C10H16 CAS:7785-70-8 MolWeight:136 RetIndex:948
CompName:1R-.alpha.-Pinene $$ 1R-.alpha.-Pinene $$ Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl-, (1R)- $$ 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene # $$
100 93

77
41 121
27 67 105 136

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:2 Entry:26509 Library:WILEY7.LIB
SI:95 Formula:C10 H16 CAS:508-32-7 MolWeight:136 RetIndex:0
CompName:Tricyclene $$ Tricyclo[2.2.1.0(2,6)]heptane, 1,7,7-trimethyl- (CAS) 1,7,7-Trimethyltricyclo[2.2.1.0(2,6)]heptane $$ Tricyclo[2.2.1.0.(2,6)]heptane, 1,7,7-trimethyl $$ Tricyclo[2.2.1.02,6]heptane, 1,7
100 93
Me

Me
79 121 136
39 105 Me
43 67

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:3 Entry:26451 Library:WILEY7.LIB
SI:95 Formula:C10 H16 CAS:80-56-8 MolWeight:136 RetIndex:0
CompName:.ALPHA.-PINENE, (-)- $$ Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl- (CAS) Pinene $$ 2-Pinene $$ .alpha.-Pinene $$ 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene $$ .alpha.-(+)-Pinene $$ ALPHA-PINEN
100 93

Me
Me Me

39 77 136
105 121
53 65

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:4 Entry:26447 Library:WILEY7.LIB
SI:94 Formula:C10 H16 CAS:80-56-8 MolWeight:136 RetIndex:0
CompName:.ALPHA.-PINENE, (-)- $$ Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl- (CAS) Pinene $$ 2-Pinene $$ .alpha.-Pinene $$ 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene $$ .alpha.-(+)-Pinene $$ ALPHA-PINEN
100 93

Me
Me Me

77
39
53 67 105 121 136
37

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:5 Entry:26441 Library:WILEY7.LIB
SI:94 Formula:C10 H16 CAS:80-56-8 MolWeight:136 RetIndex:0
CompName:.ALPHA.-PINENE, (-)- $$ Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl- (CAS) Pinene $$ 2-Pinene $$ .alpha.-Pinene $$ 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene $$ .alpha.-(+)-Pinene $$
100 93

Me
Me Me

77
27 41
53 105 121 136
67

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
<< Target >>
Line#:5 R.Time:3.825(Scan#:246) MassPeaks:166
RawMode:Averaged 3.820-3.830(245-247) BasePeak:93.10(45623)
BG Mode:Calc. from Peak Group 1 - Event 1
100 93
121

79 107
67
41 136
40 53
150 167 177 185 208 233 248 263 282 295

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:1 Entry:26396 Library:WILEY7.LIB
SI:95 Formula:C10 H16 CAS:79-92-5 MolWeight:136 RetIndex:0
CompName:Camphene $$ Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene- (CAS) 3,3-Dimethyl-2-methylenenorbornane $$ 2,2-Dimethyl-3-methylenenorbornane $$ 3,3-Dimethyl-2-methylenenorcamphane $$ 2
100 93
Me
121 Me
79
67 107
41
53 136
CH 2
27

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:2 Entry:26393 Library:WILEY7.LIB
SI:95 Formula:C10 H16 CAS:79-92-5 MolWeight:136 RetIndex:0
CompName:Camphene $$ Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene- (CAS) 3,3-Dimethyl-2-methylenenorbornane $$ 2,2-Dimethyl-3-methylenenorbornane $$ 3,3-Dimethyl-2-methylenenorcamphane $$ 2
100 93
Me
121
Me
79
39 67 107
53 136 CH 2
38

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:3 Entry:26406 Library:WILEY7.LIB
SI:95 Formula:C10 H16 CAS:79-92-5 MolWeight:136 RetIndex:0
CompName:Camphene $$ Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene- (CAS) 3,3-Dimethyl-2-methylenenorbornane $$ 2,2-Dimethyl-3-methylenenorbornane $$ 3,3-Dimethyl-2-methylenenorcamphane $$ 2
100 93

121 Me
Me
79
67 107
41 136 CH 2
55
27

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:4 Entry:9789 Library:NIST08.LIB
SI:95 Formula:C10H16 CAS:5794-04-7 MolWeight:136 RetIndex:943
CompName:Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1S)- $$ 2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane $$
100 93
121

41 79
67 107
136
53
33

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:5 Entry:26394 Library:WILEY7.LIB
SI:94 Formula:C10 H16 CAS:79-92-5 MolWeight:136 RetIndex:0
CompName:Camphene $$ Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene- (CAS) 3,3-Dimethyl-2-methylenenorbornane $$ 2,2-Dimethyl-3-methylenenorbornane $$ 3,3-Dimethyl-2-methylenenorcamphane $$ 2
100 93 121
Me
Me
136
41 79
67 107
53 CH 2
38

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
<< Target >>
Line#:6 R.Time:3.910(Scan#:263) MassPeaks:158
RawMode:Averaged 3.905-3.915(262-264) BasePeak:93.10(746)
BG Mode:Calc. from Peak Group 1 - Event 1
100 93

119

77 136
65 105
41 144 155 177 183 206 235 247 265 277 284 295

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:1 Entry:26286 Library:WILEY7.LIB
SI:79 Formula:C10 H16 CAS:99-85-4 MolWeight:136 RetIndex:0
CompName:.gamma.-Terpinene $$ 1,4-Cyclohexadiene, 1-methyl-4-(1-methylethyl)- (CAS) 1-ISOPROPYL-4-METHYL-1,4-CYCLOHEXADIENE $$ Moslene $$ Crithmene $$ p-Mentha-1,4-diene $$ .gamma.
100 93

Pr-i

77 119 136
27 39 43
Me
65 105

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:2 Entry:26249 Library:WILEY7.LIB
SI:78 Formula:C10 H16 CAS:99-83-2 MolWeight:136 RetIndex:0
CompName:l-Phellandrene $$ 1,3-Cyclohexadiene, 2-methyl-5-(1-methylethyl)- (CAS) p-Mentha-1,5-diene $$ .alpha.-Fellandrene $$ .alpha.-Phellandrene $$ p-Menthadiene ((-)-) $$ 5-Isopropyl-2-methyl-1,3-cyc
100 93

Pr-i

77

39
136 Me
51 65
37 105 121

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:3 Entry:26358 Library:WILEY7.LIB
SI:78 Formula:C10 H16 CAS:555-10-2 MolWeight:136 RetIndex:0
CompName:.beta.-Phellandrene $$ Cyclohexene, 3-methylene-6-(1-methylethyl)- (CAS) 3-ISOPROPYL-6-METHYLENE-CYCLOHEXENE, 2-PARA-MENTHADIENE $$ p-Mentha-1(7),2-diene $$ .BETA. PH
100 93

Pr-i
77

H2C
39 65 136
51 121
37 105

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:4 Entry:26552 Library:WILEY7.LIB
SI:78 Formula:C10 H16 CAS:0-00-0 MolWeight:136 RetIndex:0
CompName:BETA-PHELLANDRENE $$
100 93

77 119
136
39 43 65
105

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:5 Entry:26288 Library:WILEY7.LIB
SI:78 Formula:C10 H16 CAS:99-85-4 MolWeight:136 RetIndex:0
CompName:.gamma.-Terpinene $$ 1,4-Cyclohexadiene, 1-methyl-4-(1-methylethyl)- (CAS) 1-ISOPROPYL-4-METHYL-1,4-CYCLOHEXADIENE $$ Moslene $$ Crithmene $$ p-Mentha-1,4-diene $$ .gamma.
100 93

Pr-i

77 119 136
27 39 43
Me
65 105

20 40 60 80 100 120 140 160 180 200 220 240 260 280
<< Target >>
Line#:7 R.Time:3.975(Scan#:276) MassPeaks:148
RawMode:Averaged 3.970-3.980(275-277) BasePeak:93.10(9977)
BG Mode:Calc. from Peak Group 1 - Event 1
100 93

41 69
79
121 136
40 53 107
144 157 174 185 207 215 233 255 270 286

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:1 Entry:26468 Library:WILEY7.LIB
SI:95 Formula:C10 H16 CAS:127-91-3 MolWeight:136 RetIndex:0
CompName:2-.BETA.-PINENE $$ Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene- (CAS) .beta.-Pinene $$ Nopinen $$ Nopinene $$ Pseudopinen $$ Pseudopinene $$ 2(10)-Pinene $$ Terebenthene $$ BETA-P
100 93

Me
Me CH 2

41 69
77 136
53 121
107
36

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:2 Entry:9747 Library:NIST08.LIB
SI:95 Formula:C10H16 CAS:18172-67-3 MolWeight:136 RetIndex:943
CompName:Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene-, (1S)- $$ 2(10)-Pinene, (1S,5S)-(-)- $$ (-)-.beta.-Pinene $$ (-)-2(10)-Pinene $$ L-.beta.-pinene $$ (1S)-(-)-.beta.-Pinene $$ laevo-.beta.-Pinene $$ 6,
100 93

41 69

79
27 53 121 136
107

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:3 Entry:26466 Library:WILEY7.LIB
SI:95 Formula:C10 H16 CAS:127-91-3 MolWeight:136 RetIndex:0
CompName:2-.BETA.-PINENE $$ Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene- (CAS) .beta.-Pinene $$ Nopinen $$ Nopinene $$ Pseudopinen $$ Pseudopinene $$ 2(10)-Pinene $$ Terebenthene $$ BETA-P
100 93

Me
Me CH 2

41 69

79
39 53 121 136
107

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:4 Entry:26462 Library:WILEY7.LIB
SI:95 Formula:C10 H16 CAS:18172-67-3 MolWeight:136 RetIndex:0
CompName:(-)-.beta.-Pinene $$ 6,6-DIMETHYL-2-METHYLENEBICYCLO[3.1.1]-HEPTANE $$ l-.beta.-Pinene $$ Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene-, (1S)- (CAS) .BETA.-PINENE $$ (-)-2(1
100 93

Me
Me CH 2

41 69
77
53 121 136
40 107
200

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:5 Entry:26473 Library:WILEY7.LIB
SI:95 Formula:C10 H16 CAS:127-91-3 MolWeight:136 RetIndex:0
CompName:2-.BETA.-PINENE $$ Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene- (CAS) .beta.-Pinene $$ Nopinen $$ Nopinene $$ Pseudopinen $$ Pseudopinene $$ 2(10)-Pinene $$ Terebenthene $$ BETA-P
100 93

Me
Me CH 2

41 69
79
121 136
27 43 107

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
<< Target >>
Line#:8 R.Time:4.565(Scan#:394) MassPeaks:126
RawMode:Averaged 4.560-4.570(393-395) BasePeak:93.10(1795)
BG Mode:Calc. from Peak Group 1 - Event 1
100 93 121 136

79 105

40 67
144 164 174 183 208 222 243 257 268 285 296

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:1 Entry:26336 Library:WILEY7.LIB
SI:95 Formula:C10 H16 CAS:586-62-9 MolWeight:136 RetIndex:0
CompName:.ALPHA.-TERPINOLENE $$ Cyclohexene, 1-methyl-4-(1-methylethylidene)- (CAS) 1,4(8)-P-MENTHADIENE $$ 1-METHYLENE-4-ISOPROPYLENECYCLOHEXANE $$ Terpinolene $$ .ALP
100 93 136
121
CMe 2

79
41 105 Me
67
36

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:2 Entry:26339 Library:WILEY7.LIB
SI:94 Formula:C10 H16 CAS:586-62-9 MolWeight:136 RetIndex:0
CompName:.ALPHA.-TERPINOLENE $$ Cyclohexene, 1-methyl-4-(1-methylethylidene)- (CAS) 1,4(8)-P-MENTHADIENE $$ 1-METHYLENE-4-ISOPROPYLENECYCLOHEXANE $$ Terpinolene $$ .ALP
100 93 121
136
CMe 2

79
105
39 Me
53 65
38

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:3 Entry:9801 Library:NIST08.LIB
SI:93 Formula:C10H16 CAS:29050-33-7 MolWeight:136 RetIndex:919
CompName:(+)-4-Carene $$ 4,7,7-Trimethylbicyclo[4.1.0]hept-2-ene # $$
100 93 121

136

79
41 105
67
36

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:4 Entry:25524 Library:WILEY7.LIB
SI:93 Formula:C10 H16 CAS:0-00-0 MolWeight:136 RetIndex:0
CompName:(+)-2-CARENE $$
100 93 121

136

79
41 105
67
38

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:5 Entry:9800 Library:NIST08.LIB
SI:93 Formula:C10H16 CAS:554-61-0 MolWeight:136 RetIndex:948
CompName:Bicyclo[4.1.0]hept-2-ene, 3,7,7-trimethyl- $$ 2-Carene $$ (+)-2-Carene $$ 3,7,7-Trimethylbicyclo[4.1.0]hept-2-ene # $$
100 93 121

136
79
41 105
27 67

20 40 60 80 100 120 140 160 180 200 220 240 260 280
<< Target >>
Line#:9 R.Time:4.820(Scan#:445) MassPeaks:163
RawMode:Averaged 4.815-4.825(444-446) BasePeak:108.10(951)
BG Mode:Calc. from Peak Group 1 - Event 1
100 108
93

67 123
41 77
53 134 151
40 181 191 201 214 225 243 261 275 293

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:1 Entry:16328 Library:NIST08.LIB
SI:79 Formula:C10H16O CAS:0-00-0 MolWeight:152 RetIndex:1120
CompName:1,7,7-Trimethylbicyclo[2.2.1]hept-5-en-2-ol
100 108
93

41 77 OH
27 67 119 137

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:2 Entry:40335 Library:WILEY7.LIB
SI:79 Formula:C10 H16 O CAS:0-00-0 MolWeight:152 RetIndex:0
CompName:1,7,7-TRIMETHYL-BICYCLO[2.2.1]HEPT-5-EN-2-OL $$
100 108
93

41 77
27 67 119 137

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:3 Entry:41010 Library:WILEY7.LIB
SI:77 Formula:C10 H16 O CAS:4501-58-0 MolWeight:152 RetIndex:0
CompName:.ALPHA.-CAMPHOLENE ALDEHYDE $$ 3-Cyclopentene-1-acetaldehyde, 2,2,3-trimethyl- (CAS) .alpha.-Campholenal $$ .alpha.-Campholenic aldehyde $$ 2,2,3-Trimethyl-3-cyclopentacetaldehyd
100 108

CH 2 CHO
93

41 67 Me Me Me
27 55 81 152
119 137

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:4 Entry:16329 Library:NIST08.LIB
SI:77 Formula:C10H16O CAS:4501-58-0 MolWeight:152 RetIndex:1155
CompName:3-Cyclopentene-1-acetaldehyde, 2,2,3-trimethyl- $$ .alpha.-Campholenal $$ .alpha.-Campholenic aldehyde $$ 2,2,3-Trimethyl-3-cyclopentacetaldehyde $$ 3-Cyclopentene-1-acetaldehyde, 2,2,3-trime
100 108

93
O
41 67
27 55 81 152
119 137

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
Hit#:5 Entry:41009 Library:WILEY7.LIB
SI:77 Formula:C10 H16 O CAS:4501-58-0 MolWeight:152 RetIndex:0
CompName:.ALPHA.-CAMPHOLENE ALDEHYDE $$ 3-Cyclopentene-1-acetaldehyde, 2,2,3-trimethyl- (CAS) .alpha.-Campholenal $$ .alpha.-Campholenic aldehyde $$ 2,2,3-Trimethyl-3-cyclopentacetaldehyd
100 108

CH 2 CHO
93

67
27 39 55 81 Me Me Me
119 137 152

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290
<< Target >>
Line#:10 R.Time:4.950(Scan#:471) MassPeaks:166
RawMode:Averaged 4.945-4.955(470-472) BasePeak:91.10(911)
BG Mode:Calc. from Peak Group 1 - Event 1
100 91
109

119
41 81
55 67
134
40 149 170 186 207 215 229 238 254 275 295

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:1 Entry:41338 Library:WILEY7.LIB
SI:91 Formula:C10 H16 O CAS:473-67-6 MolWeight:152 RetIndex:0
CompName:Verbenol $$ 4,6,6-Trimethylbicyclo-[3.1.1]-hept-3-en-2-ol $$ Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl- $$ d-Verbenol $$ Berbenol $$ 2-Pinen-4-ol $$ (+)-Verbenol $$
100 91
41

59 109 119
79
27 55
134

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:2 Entry:16297 Library:NIST08.LIB
SI:90 Formula:C10H16O CAS:18881-04-4 MolWeight:152 RetIndex:1136
CompName:Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl-, [1S-(1.alpha.,2.beta.,5.alpha.)]- $$ (S)-cis-Verbenol $$ cis-Verbenol $$ 4,6,6-Trimethylbicyclo[3.1.1]hept-3-en-2-ol # $$
100 94 109

59
41
81
55
119

27 137 OH

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:3 Entry:41265 Library:WILEY7.LIB
SI:88 Formula:C10 H16 O CAS:1820-09-3 MolWeight:152 RetIndex:0
CompName:trans-Verbenol $$ Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl-, (1.alpha.,2.alpha.,5.alpha.)- (CAS) 2-Pinen-4-ol, trans- $$
100 109
91
Me
Me OH
119
41
81
39 43 69
134
Me

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:4 Entry:41339 Library:WILEY7.LIB
SI:86 Formula:C10 H16 O CAS:473-67-6 MolWeight:152 RetIndex:0
CompName:Verbenol $$ 4,6,6-Trimethylbicyclo-[3.1.1]-hept-3-en-2-ol $$ Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl- $$ d-Verbenol $$ Berbenol $$ 2-Pinen-4-ol $$ (+)-Verbenol $$
100 41 109
94

81
55 69
27
119
134

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:5 Entry:16333 Library:NIST08.LIB
SI:86 Formula:C10H16O CAS:473-67-6 MolWeight:152 RetIndex:1136
CompName:Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl- $$ d-Verbenol $$ Berbenol $$ 2-Pinen-4-ol $$ Verbenol $$ (+)-Verbenol $$ 4,6,6-Trimethylbicyclo[3.1.1]hept-3-en-2-ol # $$
100 41 109
94 OH
81
55 69
27
119
134
152

20 40 60 80 100 120 140 160 180 200 220 240 260 280
<< Target >>
Line#:11 R.Time:5.225(Scan#:526) MassPeaks:109
RawMode:Averaged 5.220-5.230(525-527) BasePeak:59.10(2711)
BG Mode:Calc. from Peak Group 1 - Event 1
100 59
93
121 136
81
43

40 107
140 162 173 184 203 222 245 256 272 293

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:1 Entry:43777 Library:WILEY7.LIB
SI:95 Formula:C10 H18 O CAS:98-55-5 MolWeight:154 RetIndex:0
CompName:3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl- (CAS) CYCLOHEXENE, 1-METHYL-4-(2-PROPANOL-2-YL)- $$ 4-(1-HYDROXY-1-METHYLETHYL)-1-METHYLCYCLOHEXENE $$
100 59

CMe 2 OH
93
121 136
43 81
Me
41
27 107

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:2 Entry:17343 Library:NIST08.LIB
SI:95 Formula:C10H18O CAS:10482-56-1 MolWeight:154 RetIndex:1143
CompName:3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-, (S)- $$ p-Menth-1-en-8-ol, (S)-(-)- $$ .alpha.-Terpieol $$ .alpha.-Terpineol, (-)- $$ (-)-.alpha.-Terpineol $$ L-.alpha.-terpineol $$ CYCL(-)-.alph
100 59
OH

93 121
136
81
43
41 107
27 140

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:3 Entry:43786 Library:WILEY7.LIB
SI:95 Formula:C10 H18 O CAS:10482-56-1 MolWeight:154 RetIndex:0
CompName:3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-, (S)- (CAS) p-Menth-1-en-8-ol, (S)-(-)- $$ ALPHA-TERPINEOL $$ (-)-.alpha.-Terpineol $$ (+)-ALPHA-TERPINEOL (P-MENTH-1-EN-8-OL
100 59

CMe 2 OH
93 121
136
81
43 Me
41 107
27 140

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:4 Entry:43778 Library:WILEY7.LIB
SI:94 Formula:C10 H18 O CAS:98-55-5 MolWeight:154 RetIndex:0
CompName:3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl- (CAS) CYCLOHEXENE, 1-METHYL-4-(2-PROPANOL-2-YL)- $$ 4-(1-HYDROXY-1-METHYLETHYL)-1-METHYLCYCLOHEXENE $$
100 59
136

93
CMe 2 OH
121
43
81
41 Me
107
39 140

20 40 60 80 100 120 140 160 180 200 220 240 260 280
Hit#:5 Entry:43792 Library:WILEY7.LIB
SI:93 Formula:C10 H18 O CAS:10482-56-1 MolWeight:154 RetIndex:0
CompName:3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-, (S)- (CAS) p-Menth-1-en-8-ol, (S)-(-)- $$ ALPHA-TERPINEOL $$ (-)-.alpha.-Terpineol $$ (+)-ALPHA-TERPINEOL (P-MENTH-1-EN-8-OL
100 59

CMe 2 OH
93
121 136
43 81
Me
39 107
148

20 40 60 80 100 120 140 160 180 200 220 240 260 280
<< Target >>
Line#:12 R.Time:5.980(Scan#:677) MassPeaks:176
RawMode:Averaged 5.975-5.985(676-678) BasePeak:43.05(1232)
BG Mode:Calc. from Peak Group 1 - Event 1
100 43

81 91

41 69
109
119
134 150 157
40 177 193 208 218 227 246 256 266 286 297

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:1 Entry:16297 Library:NIST08.LIB
SI:82 Formula:C10H16O CAS:18881-04-4 MolWeight:152 RetIndex:1136
CompName:Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl-, [1S-(1.alpha.,2.beta.,5.alpha.)]- $$ (S)-cis-Verbenol $$ cis-Verbenol $$ 4,6,6-Trimethylbicyclo[3.1.1]hept-3-en-2-ol # $$
100 94 109

59
41
81
55
119

27 137 OH

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:2 Entry:41338 Library:WILEY7.LIB
SI:81 Formula:C10 H16 O CAS:473-67-6 MolWeight:152 RetIndex:0
CompName:Verbenol $$ 4,6,6-Trimethylbicyclo-[3.1.1]-hept-3-en-2-ol $$ Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl- $$ d-Verbenol $$ Berbenol $$ 2-Pinen-4-ol $$ (+)-Verbenol $$
100 91
41

59 109 119
79
27 55
134

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:3 Entry:41339 Library:WILEY7.LIB
SI:81 Formula:C10 H16 O CAS:473-67-6 MolWeight:152 RetIndex:0
CompName:Verbenol $$ 4,6,6-Trimethylbicyclo-[3.1.1]-hept-3-en-2-ol $$ Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl- $$ d-Verbenol $$ Berbenol $$ 2-Pinen-4-ol $$ (+)-Verbenol $$
100 41 109
94

81
55 69
27
119
134

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:4 Entry:16333 Library:NIST08.LIB
SI:81 Formula:C10H16O CAS:473-67-6 MolWeight:152 RetIndex:1136
CompName:Bicyclo[3.1.1]hept-3-en-2-ol, 4,6,6-trimethyl- $$ d-Verbenol $$ Berbenol $$ 2-Pinen-4-ol $$ Verbenol $$ (+)-Verbenol $$ 4,6,6-Trimethylbicyclo[3.1.1]hept-3-en-2-ol # $$
100 41 109
94 OH
81
55 69
27
119
134
152

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300
Hit#:5 Entry:40174 Library:WILEY7.LIB
SI:81 Formula:C10 H16 O CAS:0-00-0 MolWeight:152 RetIndex:0
CompName:p-mentha-E-2,8(9)-dien-1-ol $$
100 43

79 109 134

41
91 119
67
27

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300