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Air Quality PDF
Air Quality PDF
Climate is the subject of a great deal of debate, including and perhaps particularly,
policy debate, these days. Are humans changing the climate? If so, is that a bad
thing? Should we try to stop it, and will the consequences to our economy be dire?
Before we can address such questions, it would be helpful to know not only what
climate is, but what factors affect it and in what ways. Only then can we address
what impact humans are having on climate.
Climate includes temperature and precipitation on the surface of the Earth. Climate
is being driven by the Big Energy Input-er, the Sun. The Sun is 93 million miles
away from us, yet its nuclear reactions (2 H -> He + E) have a profound effect on
our small planet. The sun's output of energy(E) comes in many forms, from radio
waves to ultraviolet energy. The most noticeable to us on a sunny day are light and
heat.
When the sun's rays strike the Earth, they make a direct hit at the equator and a
strike a glancing blow at the poles. This means that more energy strikes each
square meter of Earth at the equator than at the poles. This uneven distribution of
heat input drives the atmosphere and ocean to distribute the heat towards the poles
to make the heat more evenly distributed.
Pure air is a mixture of gases, which contain 78% Nitrogen, 20.1% Oxygen, 0.9%
Argon, 0.03% Carbon dioxide, 0.002% Neon, and 0.0005% Helium
If air moves relative to the ground, we feel or see it as wind, just air in
motion. It is set in motion by a series of forces:
Pressure gradient force tending to impel air motion from areas of
high to areas of low pressure.
Gravitation, which tends to accelerate the air downward at a rate
closed to 9.8 m/s/s
Friction acting opposite to the wind direction and proportional roughly
to the square of the wind speed.
The Coriolis force , caused by the rotation of the earth often called the
deflecting force of the earth rotation. It acts at right angles to the wind
direction and is proportional to the wind speed.
Kinds of Wind
1. Global wind caused by the differential warming and cooling of the earth as
it rotates under the sun
2. Local Wind is caused by differential temperature between land and water
masses
Our atmosphere consists of layers which have different densities (densest is closest
to the Earth) and different temperature regimes. These factors allow us to identify
the following layers:
The key layer for us, living on the surface of the Earth, is the troposphere. This is
where all of the weather occurs, and where climate is determined.
The troposphere has its warmest temperatures at the Earth's surface, and cools as
you rise through it.
The ozone layer extends from the top of the stratosphere into the
thermosphere.The Earth's atmosphere is composed of:
Pollutants are those materials (gases, liquid, or solid) that when added to pure air
will cause adverse effects.
Classification of Air Pollutants
1. Primary pollutants are pollutants emitted as such to the
atmosphere
2. Secondary pollutants are pollutants actually produced in the
atmosphere by chemical reactions
MAJOR AIR POLLUTANTS
A. PARTICULATES
1. Dust is defined as solid particles that are entrained by process gases
directly from the material being handled or processed such as ash, coal
and cement
B. GASEOUS POLLUTANTS
1. Sulfur dioxide is a colorless gas, intense chocking odor, highly
soluble in water to form sulfurous acid
2. Sulfur trioxide is highly corrosive soluble in water to form sulfuric
acid
3. Hydrogen Sulfide is a highly poisonous gas with rotten egg odor at
low concentrations, odorless at high concentration.
4. Nitrous oxide is a colorless gas, used as carrier gas in aerosol bottles
5. Nitric oxide is a colorless gas produced during high temperature, high
pressure, and combustion. Oxidizes to Nitrogen dioxide
6. Nitrogen dioxide is a brown to orange gas which is a major
component in the formation of photochemical smog
7. Carbon monoxide is a colorless, odorless, poisonous gas that is a
product of incomplete combustion
8. Carbon dioxide is a colorless, odorless gas formed during complete
combustion.
9. Ozone is a highly reactive gas that is produced mainly during the
formation of photochemical smog
10. Hydrocarbons emitted from automobiles and industries, others
are formed in the atmosphere
11. Methane is a colorless, odorless flammable gaseous hydrocarbon
which a product of decomposition of organic matter.
12. Chlorofluorocarbons is a highly stable compound that is being
used in spray cans as aerosol propellants
The easiest way and also the most economical solution to air pollution is to eliminate
the source of the pollution. Air quality control is often achieved by some form of air
treatment similar in concept to water treatment.
TREATMENT OF EMISSIONS
Selection of the correct treatment device requires matching characteristics of the
pollutant with features of the control device. It is important to remember that the sizes of air
pollutants range many orders of magnitude, and it is therefore not reasonable to expect one
device to be effective and efficient for all pollutants. In addition, the types of chemicals in
emissions often will dictate the use of some devices.
CONTROL OF PARTICULATES
1. Settling Chambers- the simplest device for controlling particulates consisting of nothing
more than wide places in the exhaust flue where larger particles can settle out, usually with
a baffle to slow the emission stream.
2. Cyclone - the most popular, economical and effective means of controlling particulates
3. Bag (or fabric) Filters - used for controlling particulates, operate like the common
vacuum cleaner. Bag filters are widely used in many industrial applications, but are
sensitive to high temperatures and humidity.
4. Spray Tower or Scrubber- is an effective method for removing large particulates, where
high efficiency scrubbers promote the contact between air and water by violent action in a
narrow throat section into which water is introduced. This method has two major
drawbacks: (a) produce a visible plume (b) the waste is now in liquid form.
5. Electrostatic Precipitator- widely used in power plants, mainly because power is
available. The particulate matter is removed by first charging it by electrons jumping from
one high voltage electrode to the other migrating to the positively charged collecting
electrode.
There are typically three types of ESP units: dry negative corona units, wet negative corona
units and wet positive corona units. Dry negative corona units have inherently better
voltage/current characteristics, are utilized more frequently and will be the main focus of
this website; however, wet negative corona units will be discussed for their applicative
differences. The following is a small list of typical industrial applications for ESPs.
ESP Advantages:
ESPs are very efficient (up to 99% efficiency), even for small particals
They are generally more ecnomical than other particulat control devices:
Operating costs are reduced by low energy consumption, minimal maintanence
requirements and reduced cost on spare parts
Can be designed to handle wet and dry gas compositions for a wide range of gas
temperatures
Can handle large volumes of gas flow with low pressure drop
ESP Disadvantages:
A dry negative corona ESP, is designed to generate and disperse negative electrons
through suspended electrodes (wires). Excess electrons migrate from the corona toward a
positve (grounded) collection plate. Electrons are readily adsorbed onto passing
electronegative gas molecules and particals. As the electrons are accumulated on the dust
particles they are transported and deposited on to the collection plate. Below is a typical dry
gas flow schematic of an ESP. For more detailed and thourough design instruction, consult
the ESP design videos on the Video Instruction page.
As dust particles collect on the grounded plate, they transfer their charge thus completing
the electrical circuit. Particles are retained on the plate by friction and the constant
collection and transfer of particle electrons. As the dust layer increases, electron conduction
is dampened by the resistance. The measure of resistance is known as resistivity.
Resistivity has a strong influence on particle collection efficiency. View video #5 on the
Video Instruction page for more information.
Rapping System
To improve collection efficiency and ensure proper functional use of the precipitator, a
rapping system is applied to the collection plates and electrodes to dislodge the collected
dust layer. A falling weight or fixed rotating hammer raps the collection plates, causing a
vibration that knocks off the dust layer. The dust drops into steeply sloped hoppers, which
are periodically emptied for disposal. The collection plates should be smooth enough to
prevent frictional resistance during rapping removal and have sufficient oscillation behavior
to ensure particle dislocation across the length of the plate. Each plate is rapped
individually to minimize the escape of dust particles from the system. Rapping intervals are
dependent upon gas flow composition, corona voltage, and precipitator size.
ESP Sizing
The volumetric flow rate and gas stream composition are the two important empirical
factors for determining a precipitator design. The velocity component, other wise known as
the migration velocity, is the dominate factor which helps to determine the dust removal
efficiency. The following parameters can also effect the migration velocity component:
The inlet gas stream typically has a high temperature and may require pretreatment. Flue
gas conditioning should be considered to facilitate particle collection. By spraying water into
the flue gas, the fly ash is cooled to an efficient precipitator operating temperature. In
addition, this increases the gas humidity which lowers the dust resistivity. Particle resistivity
is material, temperature and humidity dependent and should be thoroughly understood for
proper ESP design.
Dispersion- is the process of spreading out the emission over a large area and thereby
reducing the concentration of the specific pollutants. The dispersion is dependent on both
the atmospheric stability and the distance from the source...
The effect of atmospheric instability can be as follows:
1. A superadiabatic lapse rate produces atmospheric instability and a looping plume.
2. An adiabatic lapse rate evens out the plume, producing a coning plume.
3. If the plume is emitted into an inversion layer, a fanning plume will result; a highly
descriptive name since from above it can be seen that the plume fans out horizontally
without any vertical dispersion.
4. A particularly nasty situation is the fumigation condition, when an inversion cap is
placed on the plume, but a superadiabatic lapse rate under the inversion causes mixing
and high ground level concentrations.
The evaporative losses from the gas tanks have been reduced by the use of gas
tank caps that prevent the vapor from escaping. Losses from carburetors have been
reduced by use of activated-carbon canisters that store the vapors emitted when the
engine is turned off and the hot gasoline in the carburetor vaporizes. The third source of
pollution, the crankcase vent, has been eliminated by closing off the vent to the
atmosphere and recycling the blow-by gases into the intake manifold. Positive Crankcase
Ventilation (PCV) Valve is a small check valve that prevents the build-up of pressure in the
crankcase. Nitrogen oxides from automobile exhausts are controlled by recirculating
exhaust gas, diluting the air to fuel mixture being burned in engine.
Is a comprehensive air quality management policy and program which aims to achieve and
maintain healthy air for all Filipinos.
Guiding Principles
Protect and advance the right of the people to a balanced and healthful ecology in
accord with the rhythm and harmony of nature
Promote and protect the global environment while recognizing the primary
responsibility of local government units to deal with environmental problems
Recognize that the responsibility of cleaning the habitat and environment is primarily
area-based
Recognize that “polluters must pay.”
Recognize that clean and healthy environment is for the good of all and should be the
concern of all.
AIR POLLUTANTS means any matter found in the atmosphere other than oxygen,
Nitrogen, water vapor, carbon dioxide, and the inert gases all in their natural or normal
concentrations, that is detrimental to health or the environment, which includes but not
limited to smoke, dust, soot, cinder, fly ash, solid particles of any kind, gases, fumes,
chemical mists, contaminated stream, and radioactive substances.
OTHER POLLUTANTS
Ozone depleting substances (ODS) such as but not limited to CFC’s, halons and
the like
Greenhouse gases which include carbon dioxide, methane, oxides of nitrogen, and
the like
Persistent Organic Pollutants (POPs) which include but not limited to dioxin, furan,
polychlorinated biphenyls (PCBs), and organochlorine pesticides such as aldrin,
dialdrin, DDT, hexachlotobenzene, lindane, toxaphere, and chlordane.
Radioactive emissions
Allowable chemicals
Within six months after the effectively of this act, unleaded gasoline fuel shall contain
aromatics not exceed 45% by volume and benzene not exceed 4% by volume, provided,
that by year 2003, unleaded gasoline fuel should contain aromatics not exceed to 35% by
volume and benzene not to exceed 2% by volume.
Automotive diesel fuel which contains a concentration of sulfur in excess of 0.20% by
weight with a cetane number of not less than 48. Industrial diesel fuel which contains a
concentration of sulfur in excess of 0.3% by weight.
Penalties
The driver and operator of the apprehended vehicle found to have exceeded the
emission standard shall suffer the following penalties
2 First offense- a fine in the amount of 1,000 pesos
3 Second offense- a fine in the amount of 3,000 pesos
4 Third offense- a fine in the amount of five thousand pesos and the offender
must undergo a seminar on pollution control and management conducted by
DOTC/LTO
In case the third offense was committed within a year from the commission of the first
offense, an additional penalty of suspension of the Motor Vehicle Registration for a
period of one year shall be imposed
Any person who burn municipal waste shall be punished with 2 years and one day to
four years imprisonment
Any person who burns bio-medical waste shall be punished with 4 years and one to
six years imprisonment
Any person who smokes inside a public building or enclosed public place, including
public utility vehicles or other means of public transport or in any enclosed area
outside of his/her private residence, private place of work or any duly designated
smoking area shall be punished with 6 months and one day to one year imprisonment
or a fine of ten thousand pesos
Any person who manufactures, imports, sells, offers for sale, introduces into
commerce, conveys or otherwise disposes of in any manner leaded gasoline shall be
punished with 3 years and one day to 5 years imprisonment and liable for the
appropriate fine.
Any person who manufactures, imports, sells, offers for sale, introduces into
commerce automotive diesel fuel which do not meet the fuel specifications as revised
by the DOE shall be punished with 3 years and one day to 5 years imprisonment and
liable for the appropriate fine.
For stationary sources of pollutants, a fine not exceed of 100,000 pesos for every
owner or operator per day of violation until such time that the standards have been
complied.