STD & SUB : XII – CHEMISTRY ( LESSONS – 2,5,7,8 9,10,17 & 22)

3 MARKS :

1. Mention the disadvantage of Pauling and Mulliken scale.

2. Why EA of fluorine is less than that of chlorine?

3. Calculate the effective nuclear charge experienced by the 4s electron in potassium atom.

4. Define Ionisation energy.

5. Define Electron affinity

6. Define radio activity.

7. What is Q value of a nuclear reaction?

8. Explain the priciple behind the Hydrogen bomb.

9. What is half life period.

10.What is spallation reaction.

11.What is binding energy of Nucleus?

12.Define the terms: i) space lattice ii) unit cell

13.State Bragg’s law.

14.What are superconductors?

15.Sketch the a) simple cubic b) face centred cubic c) body centred cubic lattices

16.What is a vitreous state?

17.Write a short note on molecular crystal

18.How are glasses formed?

19.What is imperfection in solids?

20.What is entropy? What are the units of entropy?

21.What is Gibb’s free energy?

22.Give kelvin statement of second law of thermodynamics.

23.State Trouton’s rule.

24.Which substances are deviating Trouton’s rle?

25.Dissociation of PCl5 decreases in presence of increases in Cl2 why?

26.State LeChatelier’s priciple.

27.What is equilibrium constant?

28.Why do equilibrium reactions referred to as dynamic equilirbium?

29.Define Quotient.

30.Define chemotherapy.

31.What are anaesthetics?

32.In what way antipyrectics are important.

33.What are antibiotics?

34.What are antipasmodics?

35.Give any three characteristics of Dye.

36.What are chromophores? Give two examples.

37.What are artificial sweetening agents? Give two examples.

38.What are antipyretics? Give two examples.

39.What are analgesics? Give two examples.

40.What are antacids? Give examples.

5 marks:

1. Explain briefly on characteristics of rocket proellants.

2. Explain Buna rubbers.

3. Explain Otto Witt theory for colour and strucutre of Dyes

4. Write all posssible isomers with the molecular formula C4H10O and name them.

5. Give any three methods of preparing diethyl ether.

6. Mention the methods of preparation of anisole.

7. How does diethyl ehter react with the following reagents?

i) O2 / long contact ii) HI in excess iii) PCl5 d) dilute H2SO4

8. Give the differences between anisole and an aliphatic ether.

9. Derive the relationship between Kc and Kp

10.Give Kc and Kp for dissociation of PCl5

11.Explain contact process

12.Explain Haber process.

13.Explain the various statement of second law of thermodynamics.

14.Explain the characteristics of free energy

15.Explain the characteristics of entropy.

16.Explain radio carbon dating with its application

17.Give the differences between chemical reaction and nuclear reaction

18.Explain the applications of radio isotopes

19.Give the differences between nuclear fusion and nuclear fission.

20.Explain the nuclear fission reaction with an example

21.Explain the factors affecting ionisation energy.

22.Explain the factors affecting electron affinity.

23.Explain the pauling method to calculate ionic radii.

24.Explain the pauling scale to calculate electro negativity.

25.How electronegativity values help to find out the nature of bond?