Professional Documents
Culture Documents
electrolysis plants
Superior membrane process
ThyssenKrupp
A company
of ThyssenKrupp
Technologies
Uhde
2 Table of contents
Page
1. Company profile 3
8. Technical data 15
With its highly specialised their worldwide customers with Uhde was founded in 1921
workforce of more than 4,900 an ever better performance in and is a company in the
employees and an international the fields of planning, design, Technologies segment of the
network of subsidiaries and construction and after-sales ThyssenKrupp Group. The
branch offices, the Dortmund- services for electrolysis plants. company’s activities focus on
based engineering contractor Their common aim is to optimise the engineering and construc-
Uhde has successfully de- the technology and further re- tion of chemical and other
signed and built over 2,000 duce energy consumption. industrial plants in the following
plants throughout the world. fields: fertilisers; electrolysis;
Uhde and Uhdenora can draw gas technologies; oil, coal and
In the field of chlor-alkali elec- on decades of experience in residue gasification; refining
trolysis Uhde offers a proprietary chlor-alkali electrolysis. The technologies; organic inter-
single-element membrane companies have constructed mediates, polymers and
technology, which is marketed more than 200 reference plants synthetic fibres; and also coke
by both Uhde and Uhdenora, around the world. Technological plant and high-pressure tech-
the joint venture company experience and flexible market nologies.
founded in conjunction with De approaches enable Uhde and
Nora. Both Uhde and Uhdenora Uhdenora to effectively meet De Nora has been a world
carry out intensive research a wide range of customer re- leader in the development of
and development to provide quirements. new technologies and industrial
processes, particularly for the
chlor-alkali industry, since 1923.
4 2. Uhde’s remarkably long experience
environment-friendly membrane
Anwil SA
Wloclawek, Poland
Capacity: 216,600 t/year of NaOH
195,000 t/year of Cl2
5
Brine
Brine Brine Chlorine
filtration
Filtration purification and sa
Cl2
tail gas
Brine precipitation
and clarification
Chlorine Chlorine C
compression liquefaction s
Chlorine Hydrogen
treatment treatment
Sulphate
Gypsum
removal
Circulation
Membrane Catholyte
electrolysis cooling
Anolyte
dechlorination
Liquid chlorine
Modern chlor-alkali plants are Once the wet chlorine gas has
equipped with a brine circulation been cooled and filtered, it is
Hydrogen
system specially designed for either fed directly to the con-
membrane technology. Higher sumer plant (e.g. in the case of
sodium chloride depletion in a hydrochloric acid plant) or it
the membrane cells means that is dried and compressed before
the recycle rate and the amount either being fed to the consumer
of equipment needed are plant (e.g. in the case of a VCM
significantly lower than, for ex- plant) or liquefied for storage in
ample, in mercury plants of the tanks.
same capacity. Membrane plants
also have an additional brine The membrane process also
preparation process specially involves a catholyte recirculating
n
adapted to the needs of the system. A part stream of the
plant and to the type and quality product, 32% caustic soda,
of the brine used in order to is diluted with demineralised
ensure that high-quality brine water to a concentration of
Caustic 32 % enters the membrane cells. 30% and recycled to the mem-
The chlorine generated leaves brane cells as catholyte inlet.
the cells with the depleted The remaining caustic soda
brine. If high-purity chlorine is product can be concentrated
required (e.g. for a downstream if necessary.
VCM plant), hydrochloric acid
can be added to the feed brine Hydrogen is a valuable by-
to reduce the oxygen content in product of the process and can
the chlorine produced. be supplied to hydrogen con-
sumers, such as hydrochloric
Caustic 50 % acid plants or hydrogen plants
n
once it has been cooled and
filtered.
All units for the Uhde
membrane process
are provided from a
single source.
8 4. Our latest generation of cells
The best of their kind
Spacer
Anodic channel
Cathodic channel
Anode compartment
Membrane
Cathode
Anode
A single-element stack:
each element can be
replaced individually. Single element
Contact strip
Cell rack
Header
Busbars
Main headers
for product Cl2+H2
Electrolyser
a detailed 3D computer
model.
8. Technical data 15
Service life :
anode coating > 8 years
cathode coating > 8 years
membranes > 4 years
gaskets > 4 years
metal elements > 20 years
Active area per element 2.72 m2
_
3 4 5 6 7 i [kA/m2]
Product quality
Gaseous chlorine
Cl2 > 98 % (vol.)
O2 0.5-1.5 % (vol.)
H2 < 0.05 % (vol.)
Hydrogen
H2 > 99.9 % (vol.)
16 9. Solutions through innovations
Single-element technology High material quality Membrane stability Individual sealing system
The single element can be The anode compartment (Ti), The membranes in the single Each single element is sealed
replaced quickly and easily. cathode compartment (Ni), elements are fixed between using a flange, bolting and
Elements are assembled in gaskets (TFM) and tubes two electrodes using spacers. TFM gaskets. All elements are
the electrolyser workshop, (PTFE) are all made from This allows the electrode tested prior to operation to
where leakage tests are then corrosion-resistant material spacing to be adjusted ensure that they are 100%
carried out. This ensures: and guarantee a maximum accurately for optimum leakproof. Costly jackscrew
service life for the single operation. systems, such as those used
highest possible operational elements. The electrolyser in filter-press electrolysers,
reliability headers are long-service-life are not necessary.
easy maintenance components and are made of
pure GRP or titanium on the
cost-optimised membrane
anode side and of PP/GRP on
replacement and electrode
the cathode side.
recoating according to
schedule
no additional investment
needed for back-up
electrolysers
minimal loss of production
17
VESTOLIT GmbH
Marl, Germany
Capacity: 237,000t/year NaOH
210,000t/year Cl2
Our customer services in the Our regular consultancy visits We monitor, analyse and opti-
field of electrolysis do not stop to customers keep them in- mise plant performance during
on plant completion, but also formed about the latest technical the entire lifetime of a plant,
include: developments or revamping applying our integrated per-
activities, and by organising formance analysis system
consultancy visits and supporting technical ex- Uhde IntegratorTM,which con-
technical exchange meetings change meetings and symposia, sists of three different levels:
for example the Chlorine Sym-
Chlorine Symposium
posium held every 3 years at Level 1:
plant performance Uhde’s head office in Germany, Electrolyser interlocking
optimisation we promote active communica- system Uhde GuardTM. This
benchmarking tion between customers, part- mandatory safety device pro-
remembraning/recoating ners and our own specialists. tects the electrolysers should
This enables our customers to malfunctioning occur.
revamps
benefit from the development Element administration pro-
delivery of spare parts of new technologies and the gram Uhde AdministratorTM.
element upgrades. exchange of experience as well This program is used to ad-
as troubleshooting information. ministrate cell components
and to record and analyse
cell assembly data as well as
operating data.
Uhde data acquisition
terminal Uhde ScanTM. This
unit reads information on the
electrolysis cell compart-
ments from a bar code and
transfers this information to
Integrated performance analysis the Uhde AdministratorTM.
system Uhde IntegratorTM It also offers forms for docu-
mentation and administration
purposes.
Level 2:
Level 3: Single-element analyser
Remote data analysis Uhde EvaluatorTM. This sys-
tem monitors cell element
voltages and analyses mem-
brane and coating perform-
ance.
Level 3:
Level 2: Remote data analysis.
Uhde EvaluatorTM Data acquired with the Uhde
EvaluatorTM can be sent
by automatic data transfer
to Uhde to permit further
Level 1: analysis by our specialists
Uhde Guard , Uhde AdministratorTM, Uhde ScanTM
TM in Germany.
21
Uhde offers
optimum solutions
right down to
the last detail.
22
Bayer AG,
Leverkusen/Germany
Capacity:
395,000 t / year NaOH,
350,000 t / year Cl2
12. A full range of services 23
from a single source
Uhde is dedicated to providing Our impressive portfolio of And our services don't stop on
its customers with a wide range services includes: project completion. Partnering
of services and to supporting Feasibility studies/technology is our byword. We promote
them in their efforts to succeed selection active communication between
in their line of business. With customers, partners, operators
Project management
our worldwide network of sub- and our specialists.
sidiaries, associates and experi- Arrangement of financing
enced local representatives, as Financial guidance based on
We like to cultivate our business
well as first-class backing from intimate knowledge of local
relationships and learn more
our head office, Uhde is in an laws, regulations and tax
about the future goals of our
ideal position to achieve this procedures
customers.
goal. Environmental studies
Basic/detail engineering
Uhde stands for tailor-made
We at Uhde place particular im- Utilities/off-sites/ concepts and international
portance on interacting with infrastructure competence – competence
customers at an early stage to
Procurement/inspection/ that is based on more than
combine their ambition and ex-
transportation services 200 plants featuring Uhde
pertise with our experience.
Civil works and erection electrolysis technology world-
Whenever necessary we give
wide.
potential customers the oppor- Commissioning
tunity to visit operating plants Training of operating
and to personally evaluate such personnel For more information contact
matters as process operability, one of the Uhde offices near
Plant operation/maintenance
maintenance and on-stream you or visit our web-site:
Customer services.
time. We aim to build our future www.thyssenkrupp.com/uhde
business on the confidence our
customers place in us. From The policy of the Uhde group is
the initial feasibility study, Further information on this
to ensure utmost quality in the
through financing and project subject can also be found
implementation of our projects.
management to the commis- on the DVD:
Our head office and subsidiaries
sioning of units and grassroots worldwide are certified to the The next generation
plants, Uhde's range of ser- DIN / ISO 9001 / EN29001 which is available in English
vices goes beyond those com- quality standard + SCC. free of charge from:
monly associated with an EPC Ms Klimeck,
contractor.
Public Relations,
info.uhde@thyssenkrupp.com
EL 520/2000e 04/2008 XP/Hi/Printed in Germany
PDF 22.1.2009