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Critical Review

Energy Issues in Desalination Processes


RAPHAEL SEMIAT*
Rabin Desalination Laboratory, Grand Water Research Institute, Wolfson Faculty
of Chemical Engineering, TechnionsIsrael Institute of Technology, Technion City,
Haifa 32000, Israel

Received May 14, 2008. Revised manuscript received August 29, 2008. Accepted
September 2, 2008.

Water, energy, and environmental issues are closely related. drinking (Europe and United States) and even in very clean
Newwatertechniquesconsumeenergy,andinnovativerenewable industries such as semiconductor manufacturing plants
energy techniques using biofuels and biodiesel consume an (FABs) in Singapore. Slightly polluted or brackish water is
incredible amount of water. Different desalination techniques relatively easy to treat, yet the main, unlimited water source
comes from the oceans and the seas. Over the years, several
that consume different energy levels from different sources are
desalination techniques have proven to be feasible and are
in use today. Some people, environmentalists, decision serving as appropriate sources. Reverse osmosis (RO) is
makers, and even scientists, mainly in nonscientific publications, currently the fastest growing technique for treating different
consider energy consumption in desalination to be too high types of water. Multistage flash distillation is still the most
and are seeking new ways of reducing it, which often involves common technique, especially where energy is still not an
increasing capital investment. Efforts should be directed at issue. Multieffect distillation has a greater potential as an
reducing not only energy consumption but also total water cost. evaporation technique, while vapor compression may be
A competent grasp of thermodynamics and heat and mass suitable for resort areas or small sites. Other techniques have
transfer theory, as well as a proper understanding of current proven to be inefficient, such as the freezing technique, solar
desalination processes, is essential for ensuring beneficial stills, and more. Other new technologies are trying to pop up
to challenge the existing, already well-established techniques.
improvements in desalination processes. Thermodynamics sets
However, with the continuous energy crisis we are facing,
the absolute minimum limit of the work energy required to the question of how much energy is needed to make water
separate water from a salt solution. Unavoidable irreversibilities is constantly emerging. Unfortunately, significant misun-
augment the actual energy consumption, yet modern derstandings and misinterpretations still prevail, even in the
desalination techniques have succeeded in considerably best published papers. This paper will attempt to make some
narrowing the gap between actual and limiting energy levels. sense of this issue. Prof. Silver, one of the best known
The implication of this smaller gap is that only marginal desalination developers, said the following about 30 years
energy reductions are possible. The current energy consumption ago during a different energy crisis (1): “The production of
of different desalination processes is reviewed in this paper. fresh water from seawater or other contaminated water when
A comparison with other common energy-consuming ventures seen against all the vast and varied industrial activity of the
modern world may seem a small thing. But unless it is
leads to some interesting conclusions.
provided it could prove to be the nail for lack of which the
whole battle of civilization might be lost, even if we solve the
Introduction energy supply situation.”
Modern life has reduced the percentage of people living on
agriculture. Most of the population is concentrated in large
Water, Energy, and the Environment
cities, places that had served in the past as the basis for The future of humankind will be affected by three interrelated
settlements around water sources. Over the centuries, the major endeavorsswater, energy, and environmental protec-
population grew well beyond its ability to supply its water tion. On one hand, energy requires water for cooling
needs. The need for water is therefore essential in many purposes, and on the other hand, water is needed for growing
places, while good-quality water flows into the sea in other biofuels and for biodiesel. Intensified biofuel consumption
places. Conveying water from place to place proved to be has already increased food costs, thus straining living
uneconomical. It is well-known that more than 97% of water conditions of inhabitants in Third World countries. Prob-
on earth has accumulated in the oceans and cannot be used. lematic environmental effects associated with burning oil or
A quarter of the world population uses water melted from biofuel for energy generation are air pollution and global
snow and glaciers. Three quarters of the world consumes warming. Improper water usage through uncontrolled squan-
surface water and aquifer water, altogether less than 0.4% of dering and neglect of wastewater reclamation are intensifying
all of water on earth. water pollution and water shortages. In this paper I will
Many techniques are available for supplying more water. concentrate on issues related to energy needs for medium
The most important is wastewater reuse, especially due to to large water desalination processes. Understanding of real
the necessity for cleaning water to prevent pollution. Treated energy consumption in water desalination processes is
wastewater is used all over the world for irrigation and essential for the scientific community as well as for the
decision makers.
* Corresponding author phone: 972-4-8292009; fax: 972-4- Minimum Energy for Separation. A thermodynamic
8230476; e-mail: cesemiat@tx.technion.ac.il. analysis of the energy requirement of some desalination
10.1021/es801330u CCC: $40.75  2008 American Chemical Society VOL. 42, NO. 22, 2008 / ENVIRONMENTAL SCIENCE & TECHNOLOGY 9 8193
Published on Web 10/22/2008
processes has been described by many researchers (2-6).
Equations for W, the minimum isothermal reversible work
of separation, which is applicable to any desalination process
Wirrev
)
{
1+
∆Tirrev
R } (9)
Wrev η
regardless of the separation mechanism (2), are presented:
where Wirrev is the work (energy) required for separating a
-W ) ∆H - T∆S ) ∆F (1)
unit of water in an actual process, Wrev is the minimum
where ∆H represents the change in enthalpy between the separation energy for a reversible process, and η is the Carnot
final and the initial stages, ∆S represents the change in efficiency of the process. The term ∆Tirrev expresses all
entropy, and ∆F is the change of the free energy. Introducing irreversibilities in a process in terms of the temperature
the free energy relations to the molar concentration of the driving force and R is the boiling point rise (BPR). BPR (R)
salt in water results in is the temperature difference in a minimum energy reversible
separation process. No evaporation can take place when the
∫ ∆F dn ) ∫ RT ln a ∫ p
n2
-W ) dn ) RT ln dn (2) temperature difference is equal to or smaller than the BPR
w n1 p0 value.
Assuming a 50% recovery process of an initial 3.5% NaCl
where n represents the number of water moles in the solution, solution using relations in ref 2, we find that R ) 1 °C and
R is the gas constant, aw is the water activity in the solution, Wrev ) 1.9 (kW h)/m3. Reverse osmosis seawater desalination
1 and 2 represent the initial and final stages of water today consumes about 3.7 (kW he)/m3 of product. Inserting
separation from the solution, respectively, and P is the water these values into eq 9, we find that, with a Carnot efficiency
vapor pressure assumed as an ideal gas. The final expression of 100%, a thermal process aiming to achieve an energy
for the minimal separation energy is given by consumption similar to that of an RO process must operate
with temperature driving forces less than 1 °C (∆Tirrev
0.296T
∫ p
n2
-W ) log dn (3) expresses all irreversibilities, not only the temperature driving
100 - n2 100 p0
force). If we take a Carnot efficiency of 75%, the temperature
Equation 3 directly gives the theoretical minimum separation driving force should be less than 0.75 °C. Thermal desalination
energy in (kW h)/m3 of water product. From eq 1 it is possible usually works under a much lower Carnot efficiency. All
to calculate that the energy needed per cubic meter produced distillation studies consider systems having significantly
from an infinite source of 3.5% salt concentration seawater higher temperature driving forces.
is given by
Actual Energy Demand for Different Desalination
-W ) 0.296T log aw (4) Systems
Evaporation Techniques. The simplest desalination tech-
as a value of 0.79 (kW h)/m3. However, for 50% recovery
nique, single-stage evaporation of seawater, consumes a
based on eq 3, the energy demand is 1.09 (kW h)/m3.
tremendous amount of energy, around 650 (kW ht)/m3 of
On the basis of the chemical potential, µ, the minimum
product, depending slightly on the evaporation temperature.
isothermal reversible energy is given by
The main evaporation techniques, MSF and MED, have
-W ) ∆F ) µc + µp - µf (5) overcome this obstacle by reusing energy consumption
through multiple stages. About 50% of the world desalination
where the letters c, p, and f are concentrate, product, and production is based on the MSF technique in the Persian
feed, respectively. Utilizing thermodynamic relations Gulf. The number of times the heat of evaporation is reused
is represented by the “gained output ratio”, GOR, defined as
F) ∑xµ i i µi ) RT ln ai + µi0 (6) the ratio of the number of tons of water produced per ton
of steam as energy invested.
leads to a different equation: MSF manufacturers provide a GOR design in the range
of 8-12, depending on the steam feed temperature. MED
-W ) 2.18T(nc(xc log asc + (1 - xc) log awc) + 0.01725mf) manufacturers claim a GOR of 10-16 in working units and
(7) up to 30 in designed prototypes. Thermal energy based on
fuel consumption in typical “single-purpose” plants is in the
where c, s, w, and f represent concentrate, salt, water, and range of 55-80 (kW h)/m3 of product for MSF and 40-65
feed, respectively. Introducing values of a into eq 7 yields (kW h)/m3 of product for MED. The work equivalent of these
values similar to those of an integration of eq 3. energy consumptions, based on an efficiency of about 45%
Similar results have been obtained (4) by direct integration in a modern power station, is 24-37 (kW he)/m3 for MSF and
of the third term in eq 3 by using an equation for aw based 18-30 (kW he)/m3 for MED. Pumping energy must be added
on the osmotic constant φ: to this, claimed to be around 1.2-4.5 (kW he)/m3 for both
techniques. Table 1 illustrates the confusion in the literature
ln aw ) -(∑ m /55.51)φ
i (8) regarding real energy consumption in desalination processes.
Estimations are taken from different sources where the real
where mi represents the molality of the different ions. equivalent energy is not always clear.
A value of 1.345 (kW h)/t for seawater at 4.5% was Energy consumption of thermal desalination processes
suggested (5). The values presented are indifferent with may be reduced considerably in “double-purpose” plants by
respect to the separation technique. More information on using heat released by the turbine condensing steam to
energy consumption in desalination processes may be found provide the primary thermal energy required for an MSF or
(6). MED desalination process. High efficiency of electrical energy
Thermal distillation processes suffer from the disadvan- production requires a low steam condensation temperature
tage of a high energy penalty associated with irreversibilities close to the ambient temperature. Back-pressure of the
in the process. Irreversibilties account for energy losses due turbine is therefore increased to provide an adequate heating
to friction, heat losses to the environment, heat losses due steam temperature in the range of 70-120 °C. The cost
to minimal driving forces, losses due to boiling point elevation penalty is reduced electricity production per ton of steam,
(BPE), and more. A simple thermodynamic analysis (2, 3) as explained below. The actual work energy consumption of
based on ideal Carnot cycles leads to the following equation: thermal processes in double-purpose plants is around 4-7

8194 9 ENVIRONMENTAL SCIENCE & TECHNOLOGY / VOL. 42, NO. 22, 2008
TABLE 1. Different Energy Requirements for Industrial Desalination Techniquesa
heat requirements electricity requirements combined energy
ref technique (thermal) [(kW h)/m3] (pumping) [(kW he)/m3] demand [(kW he)/m3]
RO 4-6 4-6
7 MSF 40-120 (thermal) 2.5-5 21-58
MED 30-120 (thermal) 2-2.5 15-58
8 MSF 25-114 (thermal) 4.8 not clear
5 MSF variations 34-102 2-2.2 17-47
9, 10 MED 4-5 (electricity) 1.5 5-6.5
MED 6-12
11 MSF 10-16
RO 3.8
12 RO 3-4
a
Estimations for thermal units depend on the GOR achieved in the plant and on the steam temperature. The far-right
column represents equivalent energies in terms of electrical energy for comparison.

TABLE 2. Energy Consumption for Distillation Techniques Based on Exiting Steam and Heat Losses at Different Temperaturesa
energy consumption including pumping [(kW he)/m3]
electrical power
temperature working potential in the boiling point
range of exiting steam (°C) power station (kW he) elevation range(13) (°C) GOR ) 10 GOR ) 16
70-35, MED 17.0 0.98-0.34 4
100-35, MED 30.7 1.18-0.34 5.6 5
120-35, MSF 38.9 1.31-0.34 8.4 6.9
MED energy losses 13
MSF energy losses 17
a
BPE values of seawater are included. Energy values are calculated from steam tables.

(kW he)/m3 of product for steam supply and 1.2-2.5 (kW temperature higher by about 5 °C than the seawater
he)/m3 of product for pumping energy. temperature. This is the same for the concentrate leaving
On a summer day, the seawater cooling system at the end the system, resulting in system losses of 10 °C/m3, totaling
of a multistage evaporation plant may allow the steam to about 11.6 kW h or 5.2 kW he. These values highly depend
work down to 35 °C. Back-pressure turbine steam at 70 °C on the equipment invested for heat recovery. A similar value
can produce up to 17 kW he in the turbine, assuming high may be considered for heat losses through the boundaries
efficiency, since most of the energy of this steam was already of the system, so that total energy consumption is close to
used or dissipated. The MED process working at this range 13 kW he including pumping. In MSF with circulation,
can produce 16 stages according to claims, with a GOR value assuming a higher initial temperature and 40% recovery, the
of 12, due to heat losses. This means almost 2.2 °C/stage, or energy consumption may reach around 17 kW he, including
an average of 1.5 °C as the net average temperature difference the pumping energy. Apparently, the real values lie between
driving force per stage, based on an average of 0.7 °C BPE those values and the values presented in Table 2.
(Table 2). The total energy consumption of this MED process The values estimated above may be reduced on the basis
could theoretically decrease to an equivalent of 1.5 kW he for of equipment expenses. Reducing the temperature difference
the evaporation process, or 4 kW he/m3, including the energy at one or more stages or in the heat recovery between the
for pumping water through the system, control, lighting, etc. exit steam and the feedwater involves a larger heat transfer
Similar calculations may be made for different MED and area and reduces energy consumption. The temperature
MSF conditions. Some results are shown in Table 2, where difference across heat transfer surfaces requires larger heat
the energy consumption is estimated. The calculations transfer surfaces or a greater investment. An extreme case
presented here are based on the assumption that the final of this is the use of solar energy. This energy source may be
vapor condensation at the last stage is operated by the considered as “energy free” since no fuel is used since it is
electricity plant, that the plant also agrees to review the based solely on free sun, yet the cost of this free energy is
problems involved together with the customer, that main- high due to the large area needed. An optimum exists between
tenance problems may also interfere with regular production, the cost of energy used and the cost of the investment.
etc. Hybrid plants apparently work well in the Persian Gulf RO Technique. The specific energy for RO desalination
where power and water supply usually belong to the same has decreased significantly over the past decade and is
management. This method also works in refineries where approaching the theoretical thermodynamic minimum. This
access energy is available and water is required. More was achieved through the development of large pumps having
information on desalination processes may be found in refs an efficiency of approximating 90% using modern efficient
14-17. turbines and other energy recovery devices. The newer
The above estimation appears to be too low since energy devices, known as “turbochargers,” “pressure exchangers”,
losses to the environment may be high. Another way of or “work exchangers”snames adopted by different manufac-
looking at this is through heat losses from the system walls. turerssrepresent efficient ways of recovering the energy
Producing an overall heat balance in an evaporation de- content of the high-pressure concentrate leaving the mem-
salination system, the heat supplied by an external source brane module. Turbines convert the concentrate pressure
is equal to the overall heat leaving the system. Assuming an into the velocity of a jet that spins a wheel. This is used either
MED system with 50% recovery and efficient heat usage, to reduce the power consumption of the motor driving the
every cubic meter of product leaves the system at a pump or to boost the pressure of the feed to a second stage.

VOL. 42, NO. 22, 2008 / ENVIRONMENTAL SCIENCE & TECHNOLOGY 9 8195
TABLE 3. Energy Balance, Large-Scale Plant (51)
energy (kW he)
no. of pumps flow (m3/h) diff head (bar) pump total specific energy [(kW he)/m3 of product)
intake 6 2200 1.0 77 462 0.07
raw water supply 6 2200 2.5 192 1154 0.18
feed booster 12 1042 7.7 281 3368 0.54
high-pressure aggregate
pumps 12 1042 69.3 2381 28567
turbine 12 521 73.0 -980 -11763
motors 12 1444 17323 2.77
auxiliary + lighting 400 400 0.06
total 3.63

Additional methods are available for conveying the con- low temperature), the amount of water collected from 1 m3
centrate stream pressure to the seawater feed steam using of dry air is approximately 1.2 kg.
simple devices (18-50). The amount of dry air needed to produce 1 m3 of water
The above techniques enable considerable reduction in under the above conditions is 700 m3, or 1680 m3 of wet
power consumption used to pressurize the feed. For instance, air/m3 of water produced. The operation of such a process
the pressurizing energy consumption in desalting 3.5% is possible when hot water is passed once through the air,
seawater at a recovery rate of 50% using turbines for or the salted water is heated against the condensing vapor
concentrate energy recovery is as low as 2.7 (kW he)/m3 of from the wet air and a final higher temperature from another
product. Pressure exchangers can reduce energy consump- hot heat source is reached. The first option presents a hot
tion even further to 2.2 (kW he)/m3. Taking into account the source of water; hot and salted spring water may be used this
additional pumping requirements involved in conveying the way. The second option is when the salted water is heated
feed, concentrate, and permeate steam, the overall energy with another source of waste heat. The first option represents
needs are less than 3.7 (kW he)/m3 of product in seawater a case where the energy demand for the water production
desalination. In other desalting applications involving low- is the evaporation heat, namely, around 650 (kW h)/m3. This
salinity raw waters, such as brackish water streams or slightly does not include the pumping expenses of the hot water, the
polluted resources, energy consumption can be as low as 1 air flow, and the cooling water. In fact, in terms of energy,
(kW he)/m3 of product or less, depending on the water salinity this is the highest energy demanding desalination process
and energy recovery availability. that may consume above 800 (kW h)/m3. The second option
Working at a lower pressure may save energy, yet greater uses another source of energy, yet the GOR value is not high
investment in equipment is required. Table 3 presents the and energy demand is still extremely high. In fact, at high
itemized energy consumption for different tasks in a large temperatures, as presented in some reports, it is possible to
RO plant. It is important to note that the energy consumption use the heat source to produce electricity and then run an
for small RO plants may increase due to the lower efficiency RO system. The energy demand will be much lower, and the
of smaller pumps. production efficiency from the source of waste heat will be
much higher. MED operation will produce more water at a
“New” Desalination Processes much higher efficiency and at a lower cost.
The so-called humidification-dehumidification desali-
Recent publications in the scientific literature refer to so- nation process has other problems. First, the heat transfer
called “new” desalination processes. The physics behind these coefficient of the condensing vapor from air is much lower
processes is known. The processes were also mentioned in than for pure water, and hence, the heat transfer area needed
the old literature, as can be seen below. It is important, is enormously high, at least 100-fold, depending on the
however, to analyze the energy needs of these processes. temperature and humidity of the exiting air. All of the
Evaporation-Based Humidification-Dehumidification pollution in the air used for the process is concentrated in
(52). This is one of the oldest desalination processes. Sailors the productsusually dust in remote locations, air pollution
in ancient times used the technique to collect drinking water
during the night after the temperature dropped below the
saturation level (dew point); water could be collected
underneath the sails.
A modern approach based on this “new” technique is
illustrated in Figure 1. Hot seawater or salted water is allowed
to pass through a stream of relatively dry air. The air is heated,
and the water evaporates. The air exits this stage at a higher
temperature, depending on the feedwater, and it contains
more water. The hot wet air is then allowed to pass through
a heat exchanger fed with cooling water. The temperature
drops below the dew point so the water is condensed and
accumulates as a product.
The higher the temperature of the exiting air (the
humidification stage) the higher the air humidity. Take, for
example, saturated air at 80 °C. The air humidity can easily
be found in psychrometric charts; the value is 1.28 kg of
water/kg of dry air. Assuming the air is cooled to 35 °C, the
humidity of the air exiting the system is 0.09 kg of water/kg
of dry air. Assuming all humidity changes are collected (100% FIGURE 1. Schematic of the humidification-dehumidification
saturation at the high temperature and no fog exiting at the process.

8196 9 ENVIRONMENTAL SCIENCE & TECHNOLOGY / VOL. 42, NO. 22, 2008
FIGURE 2. Schematic view of a membrane distillation design based on MED technology.

in cities, and even bacteria and virusessso the water quality bonate is much higher than the concentration of the salt in
produced is poor. the feed. Therefore, the FO process needs higher theoretical
Membrane-Based New Techniques. Recent develop- and actual energies. RO separation is closer to the minimal
ments have brought significant attention to other types of thermodynamic separation energy. Therefore, the aim is to
membrane processes reported mainly in research papers: find a process that consumes lower energy than the RO
forward osmosis (53-55) and membrane distillation (56-59). process.
Forward osmosis (FO) or direct osmosis is defined as the The membrane distillation technique is based on open
water passage from the salt solution or the polluted solution hydrophobic membranes that allow only the passage of water
through a membrane to a solution containing dissolved vapor (59, 64). The product quality is expected to be better
matter of higher osmotic pressure. Loeb (60-62) tried using than that of RO since only water vapor is expected to pass
direct osmosis for energy production from salt and pure through the membrane, yet like in RO membranes, leakage
water. A possible advantage of such a process is that occurs. Vapor condensation is allowed on colder surfaces
separating the water from the higher osmotic pressure adjacent to the membranes or outside the membrane module
solution is easier than through the RO process. Such where vapors are pumped out. Another way is to condense
separations were proposed by using magnetic nanoparticles the vapor in direct contact with a cold water stream.
covered with organic matter and separated by a magnetic The main problem in these techniques is the need to
field (a company called Nanomagnetics published this idea evaporate the water, which involves an energy demand of
in 2004), distillation of the dissolved material like in cases of around 650 (kW h)/m3. This enormous amount of energy
ammonium carbonates (53, 63), or possible simpler separa- may be reduced when energy reuse is possible, similar to the
tion such as crystallization. multieffect distillation desalination process. This may cut
Removal of the nanomagnetic particles against sheer energy demand to about 60 (kW h)/m3 if energy is reused
forces in high flow rate devices involves strong magnetic more than 10 times in the desalination plant. More energy
fields and subsequently high energy consumption. Separating is needed for pumping the water and for the cooling system.
ammonium carbonate from water solution consumes a Heat transfer flux through the membrane is low; therefore,
significant amount of energy, similar to that of water a large transfer area is needed. Developers of this technique
evaporation. It is impossible to separate this salt by evapora- claim that the high energy demand may be supplied by low-
tion without significant water evaporation, so the energy grade, cheap energy, yet this claim also holds for the
demand will be higher than conventional high osmotic multieffect distillation process.
pressure techniques (RO, NF). Care is needed to avoid osmotic The only possible advantage of the MED technique is the
material residuals in product water according to drinking possibility of lower volume and a low plant footprint.
water regulations. Thermodynamics, however, teaches us However, the design is complicated, as shown in Figure 2,
that the minimum separation energy depends on the representing a preliminary membrane distillation design with
concentration. The concentration of the ammonium car- heat recovery, similar, but not identical, to the MED process.

VOL. 42, NO. 22, 2008 / ENVIRONMENTAL SCIENCE & TECHNOLOGY 9 8197
energy demand with increased feedwater to supply the
original production. It is possible to see how the energy
demand of the RO process increases with the recovery ratio,
while the energy required in the “pumping” line decreases
with recovery. The two lines are summed into a third line
that represents the overall energy required as a function of
recovery. This line clearly has a shallow minimum, around
50% recovery. It is obvious, therefore, that, even with major
changes, the energy consumption of an RO process cannot
be reduced significantly. By improving the RO membranes,
it will be possible, yet extremely difficult, to reduce the actual
RO energy consumption by 10-30%, which may result in an
FIGURE 3. Energy demand in the RO process as a function of overall change on the order of 15%. RO will continue to lead
water recovery. in the near future, in the desalination industry, as the lower
energy consumption technique.
In this design, entering seawater exchanges heat with exiting
hot streams of product and concentrate. External heat must
be added to the feedwater. The water is then allowed to flow Energy-Related Issues
parallel to the membranes where evaporation takes place. The energy cost of an optimized desalination plant is
Vapor leaving the membrane condenses on the heat transfer approximately 30-44% of the total cost of water produced.
wall and transfers the heat condensation to the water in the Current optimal conditions may move toward higher invest-
next stage. In this way, the evaporation energy is reused to ments due to the increased cost of oil. As an extreme example,
heat the concentrating solution. Other designs are possible, fossil energy may be replaced theoretically by solar collectors
yet in terms of energy demand, the technique cannot compete of different types. The problem is that since solar energy is
with RO. As previously mentioned, it is similar to MED but available only 25% of the time, the investment fraction
suffers from low heat transfer properties and will therefore increases by a factor of 4, before taking into account the
need more energy. A report on the construction of a equipment needed for electricity production. The cost of
membrane distillation process pilot plant similar to MSF water produced by solar collectors will be much higher
operation, called Memstill (65), claimed a possible GOR of compared to that of water produced with the use of a regular
30. If this is achievable, taking into account temperature limits energy source. Solar desalination has been investigated over
and the BPR of the evaporating water, the energy consump- the past 50 years, yet no commercial small- or large-scale
tion here will be at least 15 (kW he)/m3 of product. Connecting plant is currently in operation. More information on renew-
such a system to a power station may reduce energy able energy and desalination may be found in refs 68-75.
consumption, as explained earlier, involving the same and The optimization is made during the plant design, yet the
even more problems. energy cost may vary significantly during a project’s lifetime.
For example, during the writing of this paper, the cost of
Energy Reduction in RO Processes natural oil was increasing at a significant rate in comparison
The contention raised in the literature about a potential to its cost at the design stage of the Ashkelon desalination
energy reduction in the RO process by 50% or even 75% is plant. It is difficult to change the optimal design of a plant
unrealistic. However, even with the current low energy once it has been built. However, it is possible to minimize
consumption in the RO process, there is still room for losses by designing for more flexible changes in terms of
improvement. Savings are possible by using better mem- variable energy consumption and equipment costs.
branes having a high permeability without losing rejection A 100 million m3 RO-based seawater desalination plant
capabilities. This would enable a reduction in operating requires an electrical energy supply of less than 50 MW. A
pressure and lead to energy savings. In addition, improved desalination-dedicated power station can work at a much
pretreatment and fouling control measures would facilitate higher efficiency than a regular power station since it operates
operation under more optimal conditions. constantly without the known sine wave, representing
Analyzing the components of RO desalination costs shows day-night and summer-winter changes in consumption.
that the main ones are energy cost and equipment invest- Better efficiency is expected for gas turbines since the high
ment. Itemizing the equipment, membranes, pressure ves- temperature of the gases may also be used. Therefore, the
sels, pumps, tubing, flow devices, and energy recovery units real energy required is lower than for other common uses.
shows that no special item is significantly more expensive Critics among environmentalists are often heard expressing
than the other. However, membranes play the most important concern about energy consumption for water desalination.
role in possible cost reductions. RO membranes cost about Some critics, mainly in nonscientific debates, express
8% of the overall investment. Membranes may still be concern about the environmental impact of energy con-
improved significantly. Permeation may be increased, main- sumption involved in water desalination. Water is an essential
taining similar rejection properties. Increased flux through human need, and energy usage for desalination should take
the membranes will allow a pressure reduction, and hence priority over wasteful modern day energy usages such as
less energy, at the same recovery ratio. A reduction in pressure excessive air-conditioning and high-energy-consuming cars.
may also reduce the costs of expensive metals used with Table 4 analyzes the energy derived from various fuel
high-pressure piping in a highly corrosive environment. This sources (natural gas, gas oil, heavy fuel, and coal) in
will reduce the cost of pumps and flow devices. Larger desalination versus other usages. A large-scale power station
membrane modules will reduce the plant’s footprint. generates electricity from coal or heavy fuel at an efficiency
Figure 3 illustrates an analysis based on the energy of around 45%. If operated effectively, gas turbines may reach
consumption of an RO process and pumping cost as a an efficiency as high as 80%. The magnitude of the energy
function of the recovery ratio. The analysis was made on the consumption in desalination can be more easily appreciated
basis of current RO performance with 50% recovery. The line by referring to the volume of desalted water produced by RO
of the RO process was calculated by increasing energy with from 1 kg of fuel or the mass of fuel required to produce 1
recovery on the basis of pressure changes. The pumping and ton of water. The table shows that 1-2 tons of desalted water
pretreatment line was calculated on the basis of increased can be produced with 1 kg of fuel, making water the cheapest

8198 9 ENVIRONMENTAL SCIENCE & TECHNOLOGY / VOL. 42, NO. 22, 2008
TABLE 4. RO Energy Consumption Compared with Other Alternatives
natural gas gas oil heavy fuel coal
caloric value, kcal/kg of fuel 9000 10750 10000 7700
caloric value, (kW he)/kg of fuel 10.5 12.5 11.6 9
electricity production (45% eff), large power station, (kW he)/kg 4.7 5.6 5.2 4
of fuel
electricity production (80% eff), high-efficiency gas turbine, 8.4
(kW he)/kg fuel
capacity, seawater desalination (50% recovery), m3/kg of fuel 1.3 1.6 1.5 1.2
80% efficiency 2.4
fuel consumption, kg of fuel /m3 of product water 0.7 0.6 0.7 0.9
80% efficiency 0.4
How many km can I drive in the city with 1 m3 of desalinated 2-10a 2-9a
water fuel consumption?
How many hours can I air-condition a single room (2.5 kW 1.4
he)?
a
Depends on the car type, conditions, etc.

commodity manufactured. The fuel consumed to produce household environment. A small family typically consumes
1 m3 of seawater can drive a typical car in a city journey a water at a rate of about 18 m3/month and uses about 1200
distance of only 2-10 km. The same amount of energy may kW he of electricity or other equivalent energy sources per
be used to operate a small room air-conditioner for 1.4 h. month. If the water is obtained from a seawater desalination
Clearly, the energy cost for desalination is rather small plant, the energy consumed for water production (excluding
compared to that in other common energy usages. water transportation) is 140 (kW h)/month (fuel value).
Environmental concern about the CO2 “greenhouse” effect Moderate driving of a family car amounting to about 1500
associated with the use of fossil fuel has led to the goal of km/month consumes 160 L of gas oil/month. Therefore, the
supplying desalination energy from renewable energy sources. energy consumed (expressed in thermal units) for water
Renewable energy sources may soon be compatible and production is 140 (kW ht)/month, for driving the car it is
economical for general electricity production. At that stage, 1500 (kW ht)/month, and for electricity it is 1200/0.45 ) 2667
they will also be suitable for desalination purposes. (kW ht)/month. These figures show that energy for desalinated
No doubt, greater efforts should be devoted toward water is 9.3% of the transportation energy, 5.2% of the
exploiting renewable energy sources. However, the real test electricity energy, and 3.2% of the total family energy
of any new energy source is its acceptance for electricity consumption. Clearly, use of desalinated water is affordable
production or other common energy uses. Savings on CO2 for typical households.
emissions must be made in terms of other energy forms, and
not regarding the very sensitive issue of desalination for Proper Water Usage
freshwater production. The use of nuclear energy, which is
currently still more expensive than fossil energy, is dangerous Desalinated water is considered expensive compared to
in areas where political instability prevails. It is also prob- traditional water sources. The problem starts when these
lematic where the technology is not accessible, and it is sources are not available. Water savings are possible in
necessary to rely on imported, trained, and sophisticated households, yet significant efforts are required. This is also
labor. true for energy consumption. Some more interesting points
A possible method of efficient energy use in a sufficiently are as follows: (1) The cost of water is negligible in regular
large desalination plant involves the design of different types households compared to other utilities payments. (2) The
of hybrid plants consisting of a membrane unit combined cost of water is tolerable for most industries. This was
with a vapor compression unit that uses electrical energy achieved in many places by enforcing strict regulations on
and a multieffect evaporation plant that uses heat energy effluents disposal. (3) The cost of water is significant in
(66, 67). Such an operation is common in the chemical agriculture. Better usage of water in agriculture may be
industry. Energy costs could be minimized by coupling a accomplished by (i) using greenhouses and retreating and
desalination plant with a dedicated power plant generating recirculating water and (ii) using drip irrigation, which saves
electricity and waste heat at optimal economic conditions. 30-90% of water consumption compared to other irrigation
The advantage of the day-night and summer-winter techniques, thus reducing the problem of cost.
electricity production cycle is that desalinated water is This paper was written to increase awareness of the
produced during the night, involving lower power consump- research community about the real information regarding
tion. The main disadvantage is that the desalination equip- energy consumption in salted water desalination. Too much
ment is not used for a large percentage of the time. This is confusion in the literature on this issue exists today, and
a mistake, since, as in any modern plant, production costs even the best researchers are making common mistakes in
are greater if the equipment is not in full use. An efficient this respect. The main conclusions that may be drawn based
desalination plant should therefore be operated 24 h a day, on the analysis made here are as follows: (1) Energy
365 days a year, with exceptions for maintenance only. During consumption for desalination is not very high, especially
this time, a full energy supply is required at the lowest cost. compared to that utilized in other common household
In some cases, it will be possible to combine solar-operated utilities. (2) The current energy consumption for desalination
RO during the day with a low tariff grid operated RO during is close to the minimum energy set by thermodynamics; it
the night, if the energy costs during the day are comparable is impossible to go below this limiting value. (3) Currently,
with that of fossil energy. the lowest energy consumption is achieved by reverse osmosis
Equivalent Energy Usage for an RO Desalination Plant. desalination integrated with energy recovery devices. (4)
It is interesting to compare energy consumption for desali- Distillation techniques consume more energy. Combined
nation with other common energy consumptions in a with electrical power, the energy consumption is higher than

VOL. 42, NO. 22, 2008 / ENVIRONMENTAL SCIENCE & TECHNOLOGY 9 8199
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