Contoh 12.

3 "Optimization of Chemical Processes"

Menentukan konstanta biner pers kesetimbangan Van Laar untuk sistem Water (1)-1,4 Dioxane (2)
A12 = 1.958661
A21 = 1.689446
x1 x2 p1sat p2sat pcalc pexp Pcalc- pexp
0 1 17.47 28.82 28.82 28.00 0.8241
0.1 0.9 17.47 28.82 34.64 34.40 0.2444948108
0.2 0.8 17.47 28.82 36.45 36.70 -0.2470773165
0.3 0.7 17.47 28.82 36.87 36.90 -0.0329289779
0.4 0.6 17.47 28.82 36.87 36.80 0.0737210421
0.5 0.5 17.47 28.82 36.75 36.70 0.0496733839
0.6 0.4 17.47 28.82 36.39 36.50 -0.1094611739
0.7 0.3 17.47 28.82 35.39 35.40 -0.014825107
0.8 0.2 17.47 28.82 32.95 32.90 0.0481369382
0.9 0.1 17.47 28.82 27.73 27.70 0.0295310916
1 0 17.47 28.82 17.47 17.50 -0.03
SSE=

gama1 gama2
2.5

1.5

0.5

0
0 0.2 0.4 0.6 0.8 1 1.2
sistem Water (1)-1,4 Dioxane (2)

(Pcalc- pexp)2 ln γ1 ln γ2 γ1 γ2 y1 y2 x
0.67914081 1.958661 0 7.089829 1 0 1 0
0.0597777125 1.537136 0.022001 4.651252 1.022245 0.234546 0.765454 0.1
0.0610472003 1.177305 0.085307 3.245617 1.089051 0.311091 0.688909 0.2
0.0010843176 0.874167 0.186147 2.396877 1.204599 0.340739 0.659261 0.3
0.0054347921 0.623147 0.321087 1.864787 1.378626 0.353399 0.646601 0.4
0.0024674451 0.420061 0.486999 1.522055 1.627424 0.361776 0.638224 0.5
0.0119817486 0.261076 0.681027 1.298326 1.975906 0.373972 0.626028 0.6
0.0002197838 0.142675 0.900566 1.153355 2.460996 0.398596 0.601404 0.7
0.0023171648 0.061631 1.143236 1.06357 3.136903 0.451147 0.548853 0.8
0.0008720854 0.014981 1.40686 1.015094 4.083113 0.575571 0.424429 0.9
0.0009 0 1.689446 1 5.41648 1 0 1
0.8252430601

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.9 1
0.9 1