CH.RAGHAVA RAO, S.D.C P.U COLLEGE, BANGARPET .

ph: 7411224133

2nd PU CHEMISTRY BLUE PRINT AND CHAPTER WISE PREVIOUS QUESTIONS (2023-24)

Name of chapter Marks Part-A Part-B Part-C Part-D Part-E (num)

(MCQ + FIB) (2 marks) (3 marks) (5 marks) (3 marks)
(15 + 5 = 20M) 𝟑 𝟐 𝟑
X 2= 6M X 3=6m X 3 = 9m
𝟔 𝟒 𝟔
Solutions 13 1 16 21 33 44,45
Electro chemistry 14 2,3 34,35 46,47
Chemical kinetics 13 4 17 22 36 48,49
𝟑
X 3=9m
𝟔
d &f-block elements 11 5 18 27,28,29
Co ordination compounds 12 6 23 30,31,32
𝟒
X 5 =20m
𝟕
Halo alkanes 09 7 19 24 37
Alcohols, phenols and ethers 12 8,9 38,39
Aldehydes, ketones & carboxylic 14 10,11 25 40,41
acids
Amines 08 12,13 20 42
Bio molecules 09 14,15 26 43

Solutions (Q.No; 1 (mcq) + 16 (fib) + 21 (2m) +33 (3m) + 44,45 (NP-3m) = 13M)
1. Define binary solutions
2. Give an example for liquid solutions in which solute is gas
3. Ornament gold containing copper is an example for what type of solution
4. In a binary solution mole fraction of one component is 0.68. what is the mole fraction of another component
5. The mole fraction of a solvent in a solutions containing non volatile solute is 0.95. what is the relative lowering
of vapour pressure of the solutions
6. Define molality Write the unit of molality of a solution
7. Define molarity how does molarity vary with temperature
8. how solubility of a gas in liquid varies with i) temperature ii) pressure
9. What happen to the solubility of a gas in a liquid with increase in temperature. Give reason
10. State henrys law write its mathematical equation
11. At constant temperature different gases have different KH value what does this statement suggest
12. At a given temperature oxygen gas is more soluble in water than nitrogen gas. Which one of them has higher
value of kH
13. At a given temperature and pressure nitrogen gas is more soluble in water than helium gas. Which one of them
has highest value of KH
14. Name the law behind CO2 gas in soft drinks under what type of solution
15. State raoult’s law for liquid mixtures. Write its mathematical equation
16. write the difference between ideal and non ideal solution
17. what are non ideal solutions mention the reason for the negative deviation from the raoult’s law
18. 10ml of liq.A is dissolved with 10ml of liquid B resultant solution is 19.9ml. it show which deviation from raoults
law
19. What type of deviation is arise in the solution in which solute-solvent interaction are weaker than solvent-
solvent and solute-solute interactions.
CH.RAGHAVA RAO, S.D.C P.U COLLEGE, BANGARPET . ph: 7411224133
20. What type of deviation from raoult’s law is observed in equal volume of ethanol and Acetone are mixed mention
the reason for it
21. Mention the enthalpy of mixing value for an ideal solution
22. How does the volume change on mixing two volatile liquids to form an ideal solutions
23. What are azeotropes? give example for minimum boiling azeotropes
24. Which type of azeotrope shows a large positive deviation from Raoult’s law?
25. On what factor the value of colligative property depends
26. what is reverse osmosis mention its use or one practical utility of reverse osmosis
27. Define isotonic solution
28. How does the size of the blood cells change when placed in an aqueous solution containing more than 0.9%
(w/v) sodium chloride
29. Sodium chloride solution having concentration greater than 0.9% (W/V) volume is not safe to inject
intravenously – Give reason.
30. Define Vanthoff factor. Give the i value for dimerisation of ethanoic acid in benzene
31. Vanthoff factor is less than one for solution.what is the conclusion drawn from it
32. What is the vanthoff factor for K2SO4
33. The vant hoff factor of NaCl in aq.solution is greter than one explain
34. the V.P of pure benzene at certain temperature is 0.850 bar. a non volatile, non electrolyte solid weighing
0.5grams when added to 39 grams of benzene (molar mass is 78 grams), V.P of the solution then is 0.845 bar.
What is the molar mass of the solid substances
35. v.p of benzene is 200 mm of Hg. When 2g of a non volatile solute dissolved in 78g of benzene. Benzene has v.p
of 195 mm of Hg. Calculate the molar mass of the solute. (molar mass of benzene is 78g/mol)
36. 5.8g of non volatile non electrolyte solute was dissolved in 100g of CS 2. The vapour pressure of the solution
was found to be 190mm of Hg. Calculate molar mass of the solute. Given vapour pressure of pure CS 2 is
195mm of Hg and molar mass of CS 2 is 76g/mole
37. the boiling point of benzene is 353.23K. when 1.80 gm of a non ionisable solute is added to 90g of benzene
the boiling point raised to 354.11K. calculate the molar mass of solute ( K b = 2.53 K.Kg mol-1)
38. On dissolving 3.46g of non volatile solute in 100 grams of water the boiling point of solution was raised to
0.12 K calculate the molar mass of non volatile solute (Kb = 0.51 K Kg mol -1)
39. On dissolving 2.34g of non electrolyte solute in 40g of benzene. The boiling point of solution was higher than
benzene by 0.81K.Kb value for benzene is 2.53K.Kg.mol-1. Calculate the molar mass of solute (molar mass of
benzene is 78 g/mol)
40. when 6.20 gms of non volatile, non ionizing solute is dissolve in 100gms of solvent then boiling point is raised
to 0.474K. Calculate the molar mass of solute? (Kb of water+0.52K.Kg.mol -1)
41. 1.0 g of non electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0.4 K.
find the molar mass of the solute. (Kf= 5.12K.Kg.mol -1)
42. a solution containing 18g of non volatile non electrolyte solute is dissolved in 200gr of water freezes at 272 K.
calculate the molecular mass of solute. Given Kf=1.86 k.kg.mol -1 ( freezing point of water is 273K)
43. 31 g of an unknown material is dissolved in 500g of water. The resulting solution freezes at 271.14K. Calculate
the molar mass of the material. [Given: Kf for water = 1.86 K kg mol-1 Tfo for water = 273 K ]
44. 200cm3 of an aq.solution of a protein contains 1.26g of proteins. The osm. pressure of such a solution at 300K
is found to be 2.57 X 10-3 bar. Calculate the molar mass of protein (R=0.083 l.bar. K-1mol-1)
45. 450cm3 an aqueous solution of a protein contains 1.0g of the protein. The osmotic pressure of such a solution
at 310 is found to be 3.1 X 10-4 bar. Calculate the mola mass of the protein (R=0.083 l.bar. K-1mol-1)
46. 0.3 liters of an aqueous solution contains 1.89 g of the protein. At 300K the osmotic pressure of this solution
was found to be 2.57 x 10 -3 bar. Calculate the molar mass of the protein (R=0.083 l.bar. K-1mol-1)
47. Binary liquid mixture that forms maximum boiling azeotrope at a specific composition is
a) Ethanol + water b) n-hexane + n- heptane c) Benzene + toluene d) Nitric acid + water
48. The value of vant hoff factor for ethanoic acid in benzene is nearly
a) 2 b) 1 c) 0.5 d) 0
49. The ratio of no.of moles of solute in one kg of solvent is called
a) Molarity b) mole fraction c) molality d) mass percentage
CH.RAGHAVA RAO, S.D.C P.U COLLEGE, BANGARPET . ph: 7411224133
50. The liquid solution in which a solute is liquid
a) ethanol dissolved in water b) oxygen dissolved in water c) glucose dissolved in water d) carbondioxide
dissolved in water
51. Which of the following is a coligative property
a) osmosis b) osmotic pressure c) optical activity d) boiling point
52. Which of the following term is dependent on temperature
a) molarity b) mole fraction c) molality d) mass percentage
53. Because of low concentration of O 2 in the blood and tissues of people living at high altitude suffer from a disease
is called Anoxia
54. Low blood oxygen causes climbers to become weak and unable to thnk clearly. Symptoms of a condition known
as Anoxia
55. Azeotropes are constant boiling mixtures having same composition in liquid state and vapor state

Electro chemistry (Q.No; 2,3 (mcq) +34,35 (3m) + 46,47 (NP-3m) = 14M)
1. draw labeled diagram of standard hydrogen electrode. Write its half cell reaction and What is the value of
electrode potential of the following electrode at 298K Pt/H2(0.1M)/H2O write the cell representation
2. Give an example for inert electrode
3. resistance of a conductivity cell filled with 0.02M KCl solution is 520Ω. Calculate the conductivity and molar
conductivity of that solution
4. What is molar conductivity? How is related to the conductivity of a solution whose conc. is mol m-3 Write the SI
unit of molar conductivity
5. What happens to molar conductivity when one mole of KCl dissolved in one litre is diluted to five litres
6. Why does the conductivity of a solution decrease with dilution
7. mention any factors which affects the conductivity of electrolytic solution.
8. define limiting molar conductivity
9. Write the relation b/w molar conductivity, limiting molar conductivity and conc of solutions
10. Write the mathematical expression for limiting molar conductivity of NaCl
11. Draw a graph of ^m vs C1\2 for acetic acid (weak electrolyte) solutions
12. on which factor does the value of conductivity depend is the always relation for the given solvent and
temperature
13. State kohlrausch’s law Mention any two applications of kohlrausch law
0
14. Represent for MgCl2 by using kohlrausch law
˄𝑚
15. Which gas is evolved at cathode during the electrolysis of an aqueous solution of NaCl
16. State faraday’s first law of electrolysis. Write its mathematical form using usual notations
17. State faraday’s second law of electrolysis
18. How many faraday of electricity is required for deposition of one mole Mg
19. For the electrode reaction Zn 2+ + 2e- → Zn. What quantitiy of electricity is required to deposit one mole of zinc
20. How many Faradays of electricity required in the following reactions? MnO4 - → Mn2+ Al 3+ → Al
21. write the overall cell reaction in mercury cell
22. What is a secondary battery
23. Write the equations for the reactions taking place at anode and cathode in the lead storage battery.
24. what are fuel cells
25. Draw a neat diagram of H2-O2 fuel cell. Write the reaction occurs at cathode of the cell
26. Write the equation for the anodic reaction during rusting of iron
27. What is corrosion name the method to prevent it
28. Mention any two methods for prevention of Corrosion
29. calculate the e.m.f of the cell in which the following reaction takes place Ni + 2 Ag +(0.002M) → Ni2+(0.160M) + 2 Ag
given Eo cell = 1.05v
30. For a galvanic cell Mg |Mg2+ (0.130M) || Ag+ (0.00001 M)| Ag Write the overall cell reaction and calculate E cell for the
reaction at 298 K [Given Eo cell = 3.17v]
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31. calculate the EMF of the cell for the reaction Mg + 2 Ag + → Mg2+ + 2 Ag+ given Eo(Mg2+/Mg) = -2.37v and
Eo(Ag+/Ag )= 0.80V [Mg2+]= 0.001M [Ag+]= 0.0001M log105=5
32. for a given data E0(Mg2+/Mg) = -2.37v; E0(Cu2+/Cu) = +0.34v calculate the emf of the cell in which the following
reaction takes place Mg + Cu2+(0.0001M) → Mg2+(0.001M) + Cu
33. For the following electro chemical cell Cu/Cu 2+//Ag+/Ag. (Given E0 (Cu2+/Cu) = 0.30V and E0(Ag+/Ag) = 0.8V)
34. Calculate emf of the cell Mg + Cu 2+(0.0001M) → Mg2+(0.001M) + Cu. Given E0(Mg2+/Mg) = -2.37v E0 (Cu2+/Cu) = +0.34V
35. calculate the ΔG0 at 298K for cell rection 3Mg + 2Al3+ → 3Mg2+ + 2Al E0(Mg2+/Mg) = -2.36v Eo(Al3+/Al) = -1.66v
36. Calculate the values of ΔGo at 298K for the cell reaction Mg + Cu2+ → Mg2+ + Cu given Eo (Mg2+/Mg) = -2.37 V and
Eo (Cu2+/Cu) = + 0.34V and F = 96500 C/mol
37. Calculate the values of ΔGo at 298K for the cell reaction Zn+ Ag+ → Zn2+ + 2Ag given Eo(Zn2+/Zn) = -0.76 V
Eo (Ag+/Ag) = +0.80V and F = 96500 C/mol
38. Calculate the values of ΔGo at 298K for the cell reaction Ni+ Ag+ → Ni2+ + 2Ag given Eo(cell) = 1.05 V and
F = 96500 C/mol
39. calculate ΔGo for the reaction Fe2+(aq) + Ag+(aq) → Fe3+(aq) + Ag(s) (given E ocell= +0.03V, F=96500c)
40. the electrode potential for the Daniel cell given below is 1.1V Zn (s)/Zn2+ || Cu2+/Cu(s) write over all cell reaction
and calculate the standard gibbs energy for the reaction. (F= 96487 c/mol)
41. A solution of Ni(NO3)2 is electrolsed between platinum electrodes using a current of 5 amperes for 20 minutes.
What mass of nickel is deposited at the cathode? (molar mass of ni = 58.7gm/mol)
𝟎
42. Calculate the 𝒇𝒐𝒓 𝑴𝒈𝑪𝒍𝟐 .The limiting molar conductivities of Mg2+ and Cl- ions are 106.0 S cm2 mol-1
˄𝒎
and 76.3 S cm2 mol-1 respectively.
43. ˄mo for NaCl, HCl, NaAc ae 126.4 S cm2 mol-1, 425.9 S cm2 mol-1 and 91.0 Scm2mol-1 calculate ˄mo for
HAc
44. On charging the lead storage battery PbSO4 on cathode is converted to
a) PbO2 b) Pb c) PbO d) No change
45. During the electrolysis of aq. NaCl solution the gas released at anode is
a) H2 b) O2 c) Cl2 d) N2
46. How many coulombs of electricity required to oxidize one mole of Al to Al3+
a) 1F b) 2f c) 3F d) 6F

Chemical kinetics (Q.No; 4 (mcq) +17 (fib) +22 (2M) + 36 (3m) + 46,47 (NP-3m) = 13M)
1. Derive the integrated rate equations for the rate constant of a first order reaction
2. Derive the integrated rate equations for the rate constant of a zero order reaction
3. Unit of a rate constant of a reaction is same as that of its rate. What is the order of the reaction
4. A chemical reaction has rate = K [A]2[B]. what is the order of a reaction
5. Identify the reaction order from the rate constant K = 3.2 X 10-5 L mol -1S -1.
6. If the units of rate constant of a reaction is mol-1Lsec-1 then what is the order of a reaction
7. What is the order of reaction which has rate expression Rate = K[A]-1[B]5/3
1
8. The rate equation for the reaction A+B→ P is rate =k|𝐴|2 |𝐵|2 ,what is the order of reaction?
9. Identify the order of the reaction if K = 2.3 X 10 5 L.mol-1.s-1
10. For the reaction 2HI → H2 + I2. Write its molecularity
11. write any two differences between molecularity and order of reaction
12. In a reaction A +B → Products, the reaction is first order in A and second Order in B.
Write the differential rate equation. How is the rate affected on increasing the concentration of B alone by three
times?
13. Give an example of zero order reaction
14. draw the graph for [R] vs time(t) for a zero order reaction. Give the relationship between the rate constant and
the slope of the curve
15. From the following graph identify order of reaction and mention the unit of its rate constant (1 st order graph)
16. Write the formula to calculate half life period of zero order reaction
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17. What happens to the half life period for a first order reaction, if the initial concentration of the reactants is
increased
18. show that the rate of first order reaction is double when concentration of the reactant is doubled
19. Show that half life period of a first order reaction is independent of initial concentration of the reacting species
20. What is pseudo first order reaction give an example
21. In a zero order reaction the time taken to reduce conc of reactant from 100% to 50% is 40 min. what is the time
required to the conc from 25% to 12.5% for same reaction
22. In a zero order reaction the time taken to reduce the conc. of reactant from 50% to 25% is 30 mins. What is the
time required to reduce the concentration from 25% to 12.5%
23. Mention any two factors influence the rate of a reaction
24. Define Activation energy
25. Write the Arrhenius equation explain the terms in it
26. draw the graph showing effect of catalyst on the activation energy of a chemical reaction
27. Define collision frequency
28. What is effective collision write any two factors responsible for effective collision
29. For the reaction R → P the concentration of a reactant changes from 0.03M to 0.02M in 25 minutes. Calculate
the average rate of the reaction.
30. The half life of a first order reaction is 15min. calculate the rate constant of the reaction
31. The rate constant of a first order reaction is 1.15 X 10-3s-1. Calculate its half life of period
32. Calculate the half life period of a first order reaction if the rate constant of the reaction is 6.93 X 10-3 s-1
33. The rate constant of a certain first order reaction is 200s-1. What is its half life period
34. A first order reaction has rate constant K = 5.5 X 10-14s-1. Find the half life of a first order reaction
35. the specific reaction rate of a reaction quadruples when temperature change from 30oC to 50oc. Calculate the
energy of activation of the reaction ( R = 8.314 J K-1 mol-1)
36. the rate constant of a reaction is doubled when the temperature increased from 400K to 410K. calculate the
activation energy (R = 8.314 j K-1.mol-1)
37. the rate of a reaction increases by two times when the temperature of the reaction raised from 300k to 310k.
calculate the energy of activation energy of the reaction (R = 8.314 j K-1.mol-1)
38. in the Arrhenius equation the factor e-Ea/RT represents
a) collision frequency b) proper orientation c) the fraction of molecules with kinetic energy > activation
energy d) threshold energy
39. unit of rate constant of zero order reaction is
a) mol lit-1s-1 b) s-1 c) mol-1lit s-1 d) mol lit-1
40. the reaction order from the rate constant K = 3.2 X 10-5 L mol -1S -1 is
a) 0 b) 1 c) 2 d) 3
41. The temperature dependence of rate of a chemical reaction is explained by Arrhenius equation
42. The criteria for an effective collision of molecules are proper orientation and Activation energy
43. Inversion of cane sugar is an example of pseudo first order reaction

d &f- block elements (Q.No; 5 (mcq) + 18 (fib) + 27,28,29 (3m) = 11M)

d – block elements:
1. Explain the preparation of K2Cr2O7
2. Explain the preparation of KMnO 4 from MnO2
3. between Ti2+ and V2+ which ion contains more no.of unpaired electrons
4. between Cu+ and Cu2+ which is more stable
5. second ionization enthalpy of Cu is very high. Give reason
6. name one 3d series element that do not show variable oxidation
7. name the metal which show max. Oxidation states
8. 3d series elements exhibit variable oxidation state. Why
9. Write the spin only formula to calculate magnetic moment
10. calculate the spin only magnetic moment of Ti2+ ion (z = 22), Cr3+ ion (Z = 24), Mn2+ ion (Z =25), (Fe2+, Z = 26),
Ferric (Fe3+, Z = 26)
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11. the spin only magnetic moment of Sc3+ is zero. Give reason
12. Zn2+ Salts are colourless – Why?
13. Cu2+ salt is colour.why
14. Sc3+ is colorless where as V3+ ions are colored
15. Tl3+ salts colorless where as Cr3+salts are colour why
16. why Sc3+ is are colorless but Cr3+ are coloured
17. among Zn2+ and Cu2+ which is colorless
18. Why do transition elements form complex compounds
19. transition metals shows catalytical properties give reasons
20. what are interstitial compounds give any two properties
21. Name the transition metal present in Bronze alloy
22. The valence shell electronic configuration of an element with atomic number 24 is
a) 3d44s2 b) 3d54s1 c) 3d64s1 d) 3d44s1
23. Which of the following elements is not regarded as transition element
a) Fe b) Mn c) Sc d) Zn
24. The transition element with stable electronic configuration is
a) Sc b) V c) Cu d) Ti
f – Block elements
25. What is lanthanoid contraction mention the cause for it
26. Give any two consequences of lanthanoid contractions
27. Cerium exhibits +4 oxidation states Give reasons
28. atomic radii of 2nd and 3rd transition elements almost identical (OR) Zr and Hf have almost identical
atomic radii give reason
29. Mention the gas liberated when lanthanolds (Ln) react with acids
30. lanthanoids are less reactive than actinoids give reason
31. Actinoid contraction is greater than lanthanoid contraction why
32. what is the general oxidation state of actinoids
33. Give reasons actinoids show variable oxidation states
34. Give two reasons the chemistry of actinoids are more complicated than lanthanoids
35. Give any two differences between lanthanoids and actinoids
36. What is misch metall

Coordination compounds (Q.No; 6 (mcq) +23 (2m) + 30,31,32 (3m) = 12M)

1. With the help of V.B .T account for hybridization, geometry and magnetic property of [Ni(CN) 4]2-
2. With the help of V.B .T account for hybridization, geometry and magnetic property of [Co(NH 3)6]3+
3. With the help of V.B .T account for hybridization, geometry and magnetic property of [Ni(Cl) 4]2-
4. With the help of V.B .T account for hybridization, geometry and magnetic property of [CoF6]3-
5. mention any two postulates of werners theory of coordination compounds
6. How many moles of AgCl will be precipitated when an excess of AgNO3 solution is added to one molar solution
of [CrCl(H2O)5]Cl2
7. what is the coordination number of metal in [FeCl2(en)2]Cl , [Cr(NH3)3(H2O)3]Cl3, [Pt(NH3)3(H2O)Cl2], [Cr
(NH3)3(H2O)3]CI3, [Co(en)2Cl2]
8. what are homoleptic complexes
9. What are heteroleptic complex is give an example
10. what is ambidentate ligand Name the isomerism when ambidentate ligands are present in it
11. explain linkage isomerism with example
12. for a given complex [Co(NH3)5(NO2)]Cl2 write its linkage isomer
13. indicate the type isomerism in the following compounds [Co(NH3)5(SCN)]Cl2 and [Co(NH3)5(NCS)]Cl2
14. write the name of isomerism of [Co(NH3)5Br] SO4 and [Co(NH3)5SO4] Br
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15. for the given complex [Co(NH3)5Br]SO4 write its ionization isomers
16. write the IUPAC name of [Co(NH3)4(H2O)Cl]Cl2, K3[Cr(C2O4)3], K2[Zn(OH)4], [Co(NH3)5(NO2)]Cl2, [Ti(H2O)6]3+,
[Co(NH3)5Br]SO4, [FeCl2(en)2]Cl, [Cr(NH3)3(H2O)3]Cl3, [Pt(NH3)3(H2O)Cl2] and
[Cr (NH3)3(H2O)3]CI3
17. write the formula of tetraamine aquachloridecobalt(iii)chloride
18. write the cis and trans isomeric structures of [Pt(NH3)2Cl2], [Co(NH3)4CI2], [Fe(NH3)2(CN)4]-, [Co(en)2Cl2]
19. write the facial(fac) and meridional(mer) isomer of [Co(NH3)3(NO2)3]
20. which set of d orbitals of a metalion experience more repulsion in octahedral filed created by ligands
21. explain the crystal field splitting of d-orbitals in octahedral complexes
22. If Δ0 < P on the basis of Crystal Field theory write the electronic configuration of d4 ion in octahedral complexes
23. out of the following two coordinate entities cis-[ptCl2(en)2]2- and trans-[ptCl2(en)2]2 which is chial and draw the
structures of its enantiomers
24. draw the figure to show splitting of d-orbitals in an octahedral crystal field.
25. The M – C bond in metal carbonyls possess
a) ionic character b) both σ and π character c) only π character d) ion dipole forces
26. The formua of the complex triamminetriaquachromium(III) chloride is
a) [Cr(H2O)3(NH3)3]Cl3 b) Cr(NH3)3(H2O)3]Cl3 c) [Cr(NH3)3(H2O)3]Cl2 d) [cr(H2O)3(NH3)3]Cl2
27. indicate the complex ion which shows geometrical isomerism
a) [Cr(H2O)4Cl2]+ b) [Pt(NH3)3Cl] c) [Co(NH3)6]3+ d) [Co(CN)5(NC)]3-

Halo alkanes (Q.No; 7 (mcq) +19 (fib) +24 (2m) +37 (5m) = 9M)
1. write the equations for the steps in SN1 mechanism of the conversion of tert. Butyl bromide (2-bromo-2-
methylpropane) into tert butyl alcohol
2. write the mechanism of the reaction b/w aq.KOH and CH 3Cl. What type of nucleophilic sub. Reation (or)
Explain the Sn2 mechanism
3. What is the hybridization of carbon attached to halogen in aryl halides
4. what are benzylic halides? Example
5. C2H5OH + SOCl2 → ____ + SO2 + HCl
6. CH3 – CH = CH2 + HI →
7. CH3-Br + AgF → CH3-F + AgBr. Name the reaction
𝑎𝑐𝑒𝑡𝑜𝑛𝑒
8. CH3Cl + NaI > ___ + ____ Name the reaction
9. Explain Finkelstein reaction and write the equation.
10. Explain swarts reaction with an example
11. Para isomers of dihalobenzene have high melting points that ortho and meta isomers why
𝐴𝑔𝐶𝑁
12. complete the reaction CH3CH2Br 𝑎𝑞.𝑒𝑡ℎ𝑎𝑛𝑜𝑙> ___
13. Give reason in case of optically active alkyl halides SN1 reactions are accompanied by racemisation
14. what is the reagent used in the convertion of alkyl halide into alkene (or) dehydrohalogenation of haloalkanes
15. name the product formed for the reaction of isopropyliodide on alcoholic KOH
𝑎𝑙𝑐 𝐾𝑂𝐻,𝛥
16. 2-bromo pentane > (or) Which gas is liberated when 2-bromopropane is heated with alcoholic potash?
17. haloarenes are less reactive towards nuclophilic substitution reactions than haloalkanes. Why
18. Explain Friedel Craft’s reaction with equation by taking chloro benzene as example.
𝑐𝑜𝑛𝑐 𝐻𝑁𝑂3
19. chloro benzene 𝑐𝑜𝑛𝑐 𝐻2𝑆𝑂4> ____
20. What are Grignard reagent write its general formula
𝑑𝑟𝑦 𝑒𝑡ℎ𝑒𝑟
21. C6H5Br + Mg >
22. Name the organic product formed when chlorobenzene is treated with sodium in dry ether
𝑑𝑟𝑦 𝐸𝑡ℎ𝑒𝑟
23. 2Ph-Cl + 2 Na >
24. explain wurtz fittig reaction (or) Write the general equation for wurtz reaction
25. explain fitting reaction with equation
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26. What is a stereo centre (or) what s the condition to be satisfied for a compound to be chiral (or) asymmetric
carbon atom
27. What is chirality
28. what are enantiomers
29. what is racemic mixture
30. What are freons
31. Give one use of trichloro methane (chloroform).
32. Name the poisonous gas evolved when chloroform is oxidised by air in the presence of light
33. identify the products A,B and C in the following equation
𝑅𝑒𝑑 𝑃 𝑁𝑎𝐼 𝐶6𝐻5𝐼
CH3OH 𝐶𝑙2 > A 𝑑𝑟𝑦 𝑎𝑐𝑒𝑡𝑜𝑛𝑒 > 𝐵 𝑁𝑎 𝑎𝑛𝑑 𝑑𝑟𝑦 𝑒𝑡ℎ𝑒𝑟> C
34. identify the chiral molecule I the following compound
a) 2-bromobutane b) 1-bromobutane c) 2-bromopropane d) 2-bromo-2-methyl propane
35. which of the following has the highest melting point
a) o-dichlrobenzene b) m-dichlrobenzene c) p-dichlrobenzene d) chlrobenzene
36. The reaction CH3Br + NaI → CH3I + NaBr is
a) swarts reaction b) fittig reaction c) wurtz reaction d) finkelstein reaction
37. when chloro benzene is treated with sodium in dry ether diphenyl is formed
38. A equimolarmixture of enantiomers is racemic mixture
39. Alkyl magnesium halides are known as grignard reagent

Alcohols,Phenols and ethers (Q.No; 8,9 (mcq) + 38,39 (5m) = 12M)

Alcohols,Phenols:
1. write the mechanism of acid catalysed dehydration of ehanol to ethene
𝐻+
2. CH3-CH=CH2 + H2O > ----- + ------
3. What happened boiling points of alcohols on increasing number of carbon atoms
4. Explain the preparation of phenol from cumene
5. Explain the preparation of phenol from Aniline
6. How is phenol prepared from benzene sulphonic acid? Write the equation.
7. What is Lucas reagent which alcohol does not produce turbidity with it at room temperature
𝐶𝑢
8. R-CH2-OH 573𝐾 > (or) Identify the product formed when vapours of primary alcohol are passed over heated
copper at 573K.
9. Explain Kolbe’s reaction
ℎ𝑒𝑎𝑡
10. phenol + Zn >
11. Name the product formed when phenol is treated with acidified solution of Na2Cr2O7. Give equation
12. write the name of the product formed by the oxidation of phenol with chromic acid.
𝐶𝑜𝑛𝑐 𝐻𝑁𝑂3
13. Phenol ℎ𝑒𝑎𝑡𝑖𝑛𝑔 > (or) How does phenol react with conc. Nitric acid. Give equation
14. Phenol + 3 Br2 ( water) → _____ + 3HBr. Write the IUPAC name
15. 2C2H5OH + 2 Na → 2 C2H5ONa + _______
16. between phenol and alcohol which is more acidic why
17. what is the effect of the following groups on the acidity of phenol i) –CH3 group ii) –NO2 group
18. what is the effect of i) e- withdrawing group on acidity of phenols ii) e- donating groups on acidity of phenols
19. the most acidic compound among the following is
a) p-nitrophenol b) p-cresol c) phenol d) m-nitrophenol
20. The IUPAC name of wood spirit is
a) methanol b) methanol c) ethanol d) ethanal

Ethers
21. Write the IUPAC name of CH3OC2H5
22. Write the IUPAC name of CH3COCH2CH2CH3.
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23. Explain williamson’s reaction.write the general equation (or) how to prepare Methoxy ethane (or) anisole
24. complete the reaction C6H5-O-CH3 + HI →
25. Write the IUPAC name of the major product formed when anisole react with a mix. Conc.HNO 3 and Conc.H2SO4
26. How anisole is react with bromine in ethanoic acid. Write the reaction
27. how does anisole react with methyl chloride
28. How anisole reacts with acetyl chloride in the presence of anhydrous AlCl3write the chemical equation for the
reaction (or) write the IUPAC name of major product formed in Friedal-craft’s acylation of Anisole
29. When CH3ONa reacts with (CH3)3CBr it gives
a) t-butylmethylether b) 2,2-dimethylpropane c) 2-methylpropene d) 2-methylpropan-2-ol

Aldehydes, ketones and Carboxylic acids (Q.No; 10,11 (mcq) + 25 (2M) + 40,41 (5m) = 14M)
Aldehydes, ketones:
1. Explain the machanism of addition of HCN to a carbonyl group in presence of abase
2. What is the hybridization of carbon in carbonyl group of aldehyde and ketone
3. Give the IUPAC name of CH3CHO
4. how is benzoyl chloride converted into benzaldehyde. Write the equation and name of the equation
𝐻2
5. R-COCl 𝑃𝑑,𝐵𝑎𝑆𝑂4> R-CHO. Name the reaction (or) Explain rosenmund reduction of benzoyl chloride
6. how would you prepare acetaldehyde from acetyl chloride. Name the reaction.
7. RCN + SnCl2 + HCl → R-CH=NH → R-CHO Name the reaction
8. P + SnCl2 + HCl → R-CH=NH → Q. what are P and Q Name the reaction
9. Identify the reagent X and Y in the following reaction toulene + _____ + CS2 → complex + ____ →
benzaldehyde
10. name an oxidisnig agent used in the Etard’s reaction
𝐶𝑂,𝐻𝐶𝑙
11. Benzene 𝐴𝑛ℎ𝑦𝑑𝑟𝑜𝑢𝑠 𝐴𝑙𝐶𝑙3>____ Name the reaction (or) how benzene is converted into benzaldehyde by
gatterman-koch reaction. Write reaction.
12. How is ketone is prepared from Grignard reagent and nitrile? Explain with an example
𝐴𝑛ℎ𝑦𝑑𝑟𝑜𝑢𝑠
13. benzene + CH3COCl 𝐴𝑙𝐶𝑙3
14. he lower members of aldehydes and ketones are missible with water why
15. Aldehydes are more reactive than ketones towards nucleophilic addition reaction give one reason
16. Complete the following reaction R2CO + NH2OH → (or) Explain the formation of oxime from carbonyl
compounds (or) (CH3)2CO + NH2OH →
17. Give reason: Acetophenone does not react with saturated sodium bisulphite solution
18. What is the role of dryHCl gas in the addition of alcohols to aldehydes
19. complete and name the following reaction -C=O- + Zn-Hg + HCl → (Or) Explain Clemmenson reduction with
an example.
20. name the reagent used in clemmensen reduction
21. CH3COCH3 + Zn + HCl →
22. what happen when carbonyl compounds are treated with hydrazine. Write the reaction (wolff kishner
reduction)
𝐾𝑀𝑛𝑂4−𝐾𝑂𝐻
23. RCHO 𝐻3𝑂+
24. complete the reaction R – CO - CH3 + NaOX →
25. how does propanone reacts with hydrazine give equation
26. name the reagent used in the convertion of ketone to hydrocarbon. Name the reaction
27. Identify A and B in the following reaction 2 C6H5CHO + Conc.NaOH → A + B
28. Explain aldol condensation (or) What is the action of dil.NaOH on ethanal name the reaction
29. why Ethanal undergo aldol condensation
30. what is crossed aldol condensation give example
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31. identify A,B,C A + conc.NaOH → B + C; B Form turbidity with lucas reagent ofter heating
C + soda lime → benzene
32. Explain cannizaro reaction
33. Formaldehyde undergoes cannizaro reaction why
34. acetaldehyde does not undergo cannizaro reaction.
35. Write the equation for the reaction between and benzaldehyde and conc NaOH solution. Name the reaction
36. How does a formaldehyde reacts with concentrated alkali on heating name this reaction
37. what is formalin solution
38. iodoform reaction with NaOI can be used for the detection of the compound
a) C2H5COC2H5 b) CH3CHO c) CH3CH2CH2OH d) (CH3)3COH
39. Ammonical AgNO3 is
a) etard reagent b) tollens reagent c) fehiling reagent d) jones reagent

carboxylic acids:
𝑎𝑙𝑘.𝐾𝑀𝑛𝑂4
40. RCH2OH 𝐻3𝑂+ >____
41. Benzamide + H3O+ →
42. How are carboxylic acids prepare from nitriles
43. Explain the preparation of carboxylic acids from the Grignard reagent write the reaction
𝑑𝑟𝑦 𝑒𝑡ℎ𝑒𝑟
44. CH3-Mg-Br + CO2 𝐻3𝑂+
45. write equation for the reactions between carboxylic acids and PCl5
46. What is the reagent used in the following equation R-COOH → R-CH2OH
47. What is the action of ammonia on benzoic acid write equation (or) How is benzamide obtained from benzoic
acid?
48. How is benzamide obtained from benzoic acid?
49. How is ehanamide obtained from ethanoic acid
50. explain decarboxylation with example
𝐶𝑎𝑂
51. CH3COONa + NaOH > ____
52. What type of carboxylic acids undergo hvz reaction explain this reaction with example (or) Explain HVZ (Hell-
Volhard-zeilensky reaction with equation.
53. Among formic acid and acetic Acid which is weak acid and why
54. what is the effect of electron with drawing group on the acidity of carboxylic acid
55. What is the effect of electron withdrawing group on the acidity of carboxylic acids?
56. Which of the following is more acidic
a) CH3COOH b) ClCH2COOH ) BrCH2COOH d) FCH2COOH

Amines (Q.No; 12,13 (mcq) +20 (fib) + 42 (5m) = 8M)

Amines
1. write IUPAC name of CH3CH2NH2
2. write IUPAC name of (CH3)2NH
3. give the IUPAC name for CH3-NH-CH2-CH3
4. mention the IUPAC name of (CH3)3N
5. Give the IUPAC name of (CH3)2NC2H5 (or) (CH3)2N-CH2-CH3
6. Write the IUPAC name of tri methyl amine
7. how is aniline is prepared from nitro benzene
8. Identify the reactant’A’ in the following reaction A+2R-X→ R4N+X-
9. Explain Hoff mann bromamide reaction
10. How is methanamine prepared by Hoffmann’s bromamide degradation reaction? Write the equation.
11. how aniline (benzenamine) is prepared by hofmann bromamide degradation reaction. Give equation
12. write the equations involved in the Gabriel phthalimide synthesis of a primary amine
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13. why are lower members of aliphatic mamines soluble in water
14. what is hinsberg reagent
15. how does primary amine undergoes carbyl amine reaction
16. what is the name of the product formed when methyl amine react with alcoholic KOH and chloroform
17. What is the product formed when aniline is heated with chloroform and ethanolic potassium hydroxide? Give
chemical equation
18. What is the action of bromine water on Benzenamine (aniline)at room temp
19. give the equation for the convertion of aniline to 4-bromoaniline
20. write the basic strength of 10,20,30 basis on hydration effects
21. Which is more basic among aqueous solutions of anline and ammonia? Give one reason
22. The pkb values Ammonia methanamine and Benzenamine (anline) are 4.75, 3.38 & 9.38 respectively Arrange
them in the increasing order of their basic strength
23. arrange the following amines in the order of their increasing basic strength in aq.solutions (CH3)3N, (CH3)2NH,
CH3NH2
24. N,N-dimethylmethanamine is
a) primary amine b) secondary amine c) tertiary amine d) quaternary amine
25. nitration of aniline in the strongly acidic medium at 288K yields
a)2,4,6-trinitroaniline b) o and p-nitroaniline c) m-nitro aniline d) o,m,p-nitroaniline
26. the hybridized state of nitrogen in trimethylamine is
a) sp b) sp2 c) sp3 d) dsp2

Diazonium salts
27. write the general formula of diazonium salt
28. explain Diazotisation (or) how aniline is converted into benzene diazonium chloride. Give equation
𝐵𝑟2,𝑁𝑎𝑂𝐻 𝑁𝑎𝑁𝑂2,𝐻𝐶𝑙
29. CH3CONH2 > P ii) P > Q what are P & Q. name the reaction occourning in first step
0𝐶
30. a)name the major product formed when nitrous acid is treated with i) methylamine b) aniline at low
temperature
𝑁𝑎𝑁𝑂2,𝐻𝐶𝑙
31. Complete the reaction ______ + > [CH3N2Cl] + H2O → CH3OH + ____ + HCl
0𝐶
32. how do you convert a diazonium salt solution into Iodobenzene give eqution
33. Explain the coupling reaction of Benzene diazonium chloride with phenol.Write the equation.
34. Complete the following reaction
benzene diazonium chloride + aniline →

Biomoleues (Q.No; 14,15 (mcq) + 26 (2m) + 43 (5m) = 9M)

Carbohydrates:
1. What are reducing sugars give example
2. How do you show that glucose contains a linear chain of six carbon atoms
3. How do you show that glucose contains five –OH groups
4. write the howorth structure of ᾳ-D(+)Glucose
5. Write Haworth structure for maltose.
6. Write Haworth structure for lactose.
7. What are polysaccharides give an example
8. name the water insoluble component of starch

Proteins & Amino acids:

9. give an example of acidic ᾳ-aminoacid
10. What are essential amino acids?is glyeine an essential amino acid?
11. is lysine an essential or non essential amino acid
12. what are non essential amino acids give example
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13. give an example for naturally occurring optically inactive amino acid
14. Write the general structure of Zwitter ion of ᾳ-aminoacid
15. what is peptide linkage .
16. how many peptide bonds are there in tripeptide
17. How many peptide bonds are present in a tetra peptide?
18. Name the protein present in hair (or) What are fibrous proteins name the protein present in hair
19. give an example for globular proteins
20. mention the two types of secondary structures of proteins
21. Mention any one force which stabilises 2o and 3o structure of proteins.
22. what is denaturation of protein give example
23. which level of structure remains infact during denafuration of proteins?
Vitamins:
24. mention the water soluble vitamin
25. Name any one vitamin that is stored in liver and adipose tissues
26. name the disease caused by the deficiency of vitamin A
27. name the disease caused by the deficiency of vitamin D
28. deficiency of which vitamin causes night blindness
29. Deficiency of which vitamins causes the disease pernicious anaemia
30. Deficiency of which vitamin causes the disease scurvy.
31. Deficiency of which vitamin causes Rickets disease
32. Water soluble vitamin is
a) B b) A c) D d) E
Nucleic acids:
33. name the sugar present in DNA
34. Name the base present only in DNA but not in RNA.
35. name the nitrogenous base present in RNA but not in DNA
36. which nucleic acid contain the base uracil
37. write the two difference betwee DNA & RNA
38. name the nucleic acid which is responsible for genetic information.

Hormones
39. what are harmones give an example
40. Name the harmone which regulate blood sugar level
41. What is the role of hormone glucagon in human blood?
42. Mention two hormones which regulate the Glucose level in the blood
43. The hormone which increases the blood glucose level is
a) gluco corticoids b) glucagon c) progesterone d) thyroxine
44. Which hormone is an iodinated derivative of aminoacid tyrosine
a) insulin b) epinephrine c) thyroxin d) glucagon