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  • Equation of State

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    Bruder Einen
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    This document summarizes equations of state models. It discusses virial equations of state, cubic and other equations of state, two-parameter and three-parameter equations of state. Specific equations of state covered include van der Waals, Redlich-Kwong, Soave, and Peng-Robinson equations. It also discusses topics like the principle of corresponding states, mixing rules for binary mixtures, vapor pressure formulas, and comparisons of compressibility factors from different equations of state models.

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    This document summarizes equations of state models. It discusses virial equations of state, cubic and other equations of state, two-parameter and three-parameter equations of state. Specific equations of state covered include van der Waals, Redlich-Kwong, Soave, and Peng-Robinson equations. It also discusses topics like the principle of corresponding states, mixing rules for binary mixtures, vapor pressure formulas, and comparisons of compressibility factors from different equations of state models.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    7 views29 pages

    Equation of State

    Uploaded by

    Bruder Einen
    This document summarizes equations of state models. It discusses virial equations of state, cubic and other equations of state, two-parameter and three-parameter equations of state. Specific equations of state covered include van der Waals, Redlich-Kwong, Soave, and Peng-Robinson equations. It also discusses topics like the principle of corresponding states, mixing rules for binary mixtures, vapor pressure formulas, and comparisons of compressibility factors from different equations of state models.

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    © All Rights Reserved
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    of 29

    EQUATIONS OF STATE

    Dr. Anirban Roy


    Department of Chemical Engineering
    email: anirbanr@goa.bits-pilani.ac.in
    BITS Pilani ph: +91-9830265292
    K K Birla Goa Campus
    TOPICS

     VIRIAL EOS

     CUBIC AND OTHER EOS

     TWO PARAMETER EOS

     THREE PARAMETER EOS

    BITS Pilani, K K Birla Goa Campus


    VIRIAL EQUATIONS OF STATE

    BITS Pilani, K K Birla Goa Campus


    VIRIAL EQUATIONS OF STATE : OTHER FORMS

    Beattie-Bridgeman EOS Benedict-Webb-Rubin EOS

    BITS Pilani, K K Birla Goa Campus


    EQUATIONS OF STATE

    BITS Pilani, K K Birla Goa Campus


    EQUATIONS OF STATE

    BITS Pilani, K K Birla Goa Campus


    EQUATIONS OF STATE

    BITS Pilani, K K Birla Goa Campus


    EQUATIONS OF STATE

    BITS Pilani, K K Birla Goa Campus


    EQUATIONS OF STATE

    BITS Pilani, K K Birla Goa Campus


    EQUATIONS OF STATE

    BITS Pilani, K K Birla Goa Campus


    EQUATIONS OF STATE

    BITS Pilani, K K Birla Goa Campus


    EQUATIONS OF STATE

    BITS Pilani, K K Birla Goa Campus


    EQUATIONS OF STATE

    Rackett Equation – ONLY for


    density of saturated liquids

    BITS Pilani, K K Birla Goa Campus


    EQUATIONS OF STATE

    BITS Pilani, K K Birla Goa Campus


    GIBBS-HELMHOLTZ CONSTRAINED EOS

    BITS Pilani, K K Birla Goa Campus


    PRINCIPLE OF CORRESPONDING STATES
    TWO PARAMETER MODEL

    BITS Pilani, K K Birla Goa Campus


    PRINCIPLE OF CORRESPONDING STATES
    THREE PARAMETER MODEL: LEE
    KESLER COMPRESSIBILITY
    CHARTS

    BITS Pilani, K K Birla Goa Campus


    PRINCIPLE OF CORRESPONDING STATES APPLIED TO VIRIAL EOS

    BITS Pilani, K K Birla Goa Campus


    MIXING RULES

    BITS Pilani, K K Birla Goa Campus


    MIXING RULES

    For Binary Mixtures

    BITS Pilani, K K Birla Goa Campus


    COMPREHENSIVE FORMULAE FOR AN EOS : vDW

    BITS Pilani, K K Birla Goa Campus


    COMPREHENSIVE FORMULAE FOR AN EOS : REDLICH KWONG

    BITS Pilani, K K Birla Goa Campus


    COMPREHENSIVE FORMULAE FOR AN EOS : SOAVE

    BITS Pilani, K K Birla Goa Campus


    COMPREHENSIVE FORMULAE FOR AN EOS : PENG ROBINSON

    BITS Pilani, K K Birla Goa Campus


    SOME VAPOR PRESSURE FORMULAE

    BITS Pilani, K K Birla Goa Campus


    COMPARISON OF Z FROM VARIOUS EOS

    Percentage deviation of calculated compressibilities from the true values


    of ammonia at 200 C

    BITS Pilani, K K Birla Goa Campus


    FORCE FIELDS

    BITS Pilani, K K Birla Goa Campus


    FORCE FIELDS

    BITS Pilani, K K Birla Goa Campus


    THANK YOU

    BITS Pilani, K K Birla Goa Campus

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