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2. Hazards identification
Physical state : Liquid. [Clear.]
Odor : Aromatic.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Emergency overview : WARNING!
FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT AND SKIN
IRRITATION. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS AND
CAUSE DAMAGE. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN
DAMAGE. SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY
CAUSE CANCER. DEVELOPMENTAL HAZARD - CONTAINS MATERIAL WHICH
CAN CAUSE ADVERSE DEVELOPMENTAL EFFECTS.
Flammable liquid. May be harmful if swallowed. Irritating to respiratory system and skin.
Aspiration hazard if swallowed. Can enter lungs and cause damage. Keep away from
heat, sparks and flame. Avoid exposure - obtain special instructions before use. Do not
breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing.
Contains material that can cause target organ damage. Contains material which may
cause cancer. Risk of cancer depends on duration and level of exposure. Contains
material which can cause developmental abnormalities. Avoid exposure during
pregnancy. Use only with adequate ventilation. Keep container tightly closed and sealed
until ready for use. Wash thoroughly after handling.
Potential acute health effects
Inhalation : Irritating to respiratory system. Exposure to decomposition products may cause a health
hazard. Serious effects may be delayed following exposure.
Ingestion : Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause
damage.
Skin : Irritating to skin.
Eyes : May cause eye irritation.
Potential chronic health effects
Chronic effects : Contains material that can cause target organ damage.
Carcinogenicity : Contains material which may cause cancer. Risk of cancer depends on duration and
level of exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : Contains material which can cause developmental abnormalities.
Fertility effects : No known significant effects or critical hazards.
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
Date of issue : May 19, 2009 Page: 1/10
Stadis (R) 450 Page: 2/10
2. Hazards identification
Target organs : Contains material which causes damage to the following organs: kidneys, liver, upper
respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.
Over-exposure signs/symptoms
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
Skin : Adverse symptoms may include the following:
irritation
redness
Eyes : No specific data.
Medical conditions : Pre-existing disorders involving any target organs mentioned in this MSDS as being at
aggravated by over- risk may be aggravated by over-exposure to this product.
exposure
See toxicological information (section 11)
3. Composition/information on ingredients
Name CAS number %
toluene 108-88-3 30 - 60
solvent naphtha (petroleum), heavy arom. 64742-94-5 15 - 30
naphthalenesulfonic acid, dinonyl- 25322-17-2 10 - 14.99
isopropanol 67-63-0 1 - 4.99
naphthalene 91-20-3 0.1 - <1
5. Fire-fighting measures
Flammability of the product : May be combustible at high temperature.
Products of combustion : Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
Extinguishing media
Suitable : Use dry chemical, CO2, water spray (fog) or foam.
Not suitable : Do not use water jet.
Special exposure hazards : Flammable liquid. In a fire or if heated, a pressure increase will occur and the container
may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or
explosion hazard.
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
Date of issue : May 19, 2009 Page: 2/10
Stadis (R) 450 Page: 3/10
5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
Date of issue : May 19, 2009 Page: 3/10
Stadis (R) 450 Page: 4/10
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
Date of issue : May 19, 2009 Page: 4/10
Stadis (R) 450 Page: 5/10
11 . Toxicological information
Acute toxicity
Product/ingredient name Result Species Dose Exposure
toluene LD50 Dermal Rabbit 14100 uL/kg -
LD50 Oral Rat 636 mg/kg -
LC50 Inhalation Rat 26700 ppm 1 hours
Vapor
solvent naphtha (petroleum), heavy arom. LD50 Dermal Rabbit >2000 mg/kg -
LD50 Oral Rat >2000 mg/kg -
isopropanol LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5000 mg/kg -
naphthalene LD50 Dermal Rat >2500 mg/kg -
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
Date of issue : May 19, 2009 Page: 5/10
Stadis (R) 450 Page: 6/10
11 . Toxicological information
LD50 Oral Rat 490 mg/kg -
LC50 Inhalation Rat >340 mg/m³ 1 hours
Vapor
Stadis (R) 450 Skin - Primary Rabbit 1.9 4 hours 0.5 ml 21 days
dermal irritation
index (PDII)
Conclusion/Summary
Skin : Slightly irritating to the skin.
Eyes : Severely irritating to eyes.
Respiratory : May cause respiratory irritation.
Sensitizer
Conclusion/Summary
Skin : Sensitizing properties of the product: Not available.
Carcinogenicity
Conclusion/Summary : Not available.
Classification
Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA
toluene A4 3 - - - -
isopropanol A4 3 - - - -
naphthalene A4 2B - - Possible -
Mutagenicity
Conclusion/Summary : Not available.
Teratogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Possible risk of harm to the unborn child.
12 . Ecological information
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
toluene - Acute EC50 6 Daphnia - 48 hours
mg/L Daphnia magna
- Acute LC50 5.8 Fish - 96 hours
mg/L Oncorhynchus
mykiss
- Acute LC50 12.6 Fish - Pimephales 96 hours
mg/L promelas
solvent naphtha (petroleum), heavy arom. - Acute EC50 3 to Daphnia 48 hours
10 mg/l
- Acute EC50 1 to Algae 72 hours
3 mg/l
- Acute LC50 2 to 5 Fish 96 hours
mg/l
isopropanol - Acute LC50 6550 Fish - Pimephales 96 hours
mg/L promelas
- Acute LC50 Fish - Fathead 96 hours
10400000 to minnow -
10600000 ug/L Pimephales
Fresh water promelas
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
Date of issue : May 19, 2009 Page: 6/10
Stadis (R) 450 Page: 7/10
12 . Ecological information
- Acute LC50 Fish - Fathead 96 hours
9640000 to minnow -
10000000 ug/L Pimephales
Fresh water promelas
naphthalene - Acute EC50 1.96 Daphnia - Water 48 hours
mg/L Fresh water flea - Daphnia
magna
- Acute LC50 1.8 Fish - 96 hours
mg/L Oncorhynchus
mykiss
Stadis (R) 450 - Acute LC50 12 Fish - Minnows 96 hours
mg/L
Conclusion/Summary : Not available.
Biodegradability
Conclusion/Summary : Not available.
Other adverse effects : No known significant effects or critical hazards.
13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Empty
containers or liners may retain some product residues. This material and its container
must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations. Local
regulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based on
characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the
responsibility of the waste generator to determine the toxicity and physical properties of the material generated to
determine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14 . Transport information
Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
Packaging
instruction
Passenger aircraft
Quantity limitation: 5 L
Cargo aircraft
Quantity limitation: 60
L
Special provisions
IB2, T7, TP1, TP8,
TP28
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
Date of issue : May 19, 2009 Page: 7/10
Stadis (R) 450 Page: 8/10
14 . Transport information
TDG Classification UN1993 FLAMMABLE LIQUID, 3 II Explosive Limit and
N.O.S. (toluene, Limited Quantity
isopropanol) 3 Index
1
Passenger Carrying
Road or Rail Index
5
Special provisions
16
Limited quantity
LQ4
CEFIC Tremcard
30GF1-I+II
15 . Regulatory information
United States
HCS Classification : Flammable liquid
Irritating material
Carcinogen
Target organ effects
U.S. Federal regulations : TSCA 4(a) final test rules: naphthalene
TSCA 8(a) PAIR: naphthalene
United States inventory (TSCA 8b): All components are listed or exempted.
TSCA 12(b) one-time export: naphthalene
Made in the USA
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: toluene; isopropanol
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
toluene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard;
isopropanol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health
hazard
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
Date of issue : May 19, 2009 Page: 8/10
Stadis (R) 450 Page: 9/10
15 . Regulatory information
Clean Water Act (CWA) 307: toluene; naphthalene; benzene
Clean Water Act (CWA) 311: toluene; naphthalene; benzene
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances : No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
SARA 313
Product name CAS number Concentration
Form R - Reporting : toluene 108-88-3 30 - 60
requirements isopropanol 67-63-0 0.99 - 4.99
naphthalene 91-20-3 0.09 - 0.99
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
Date of issue : May 19, 2009 Page: 9/10
Stadis (R) 450 Page: 10/10
16 . Other information
Label requirements : FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT AND SKIN
IRRITATION. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS AND
CAUSE DAMAGE. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN
DAMAGE. SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY
CAUSE CANCER. DEVELOPMENTAL HAZARD - CONTAINS MATERIAL WHICH
CAN CAUSE ADVERSE DEVELOPMENTAL EFFECTS.
Made in the USA
Hazardous Material :
Information System (U.S.A.)
Health * 2
Flammability 3
Physical hazards 0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented
HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection :
Association (U.S.A.)
3 Flammability
Health 2 0 Instability
Special
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
Date of issue : May 19, 2009 Page: 10/10