SH-301 본드 (영문) (Lem Korea)

Material Safety Data Sheet
Product Name: RB 600(SH-100)
1. Chemical Product and Company Information

a. Product name RB 600(SH-100)
b. Recommended use of the product and Restrictions on use
Recommended use of the product Glue
Restrictions on use None
c. Supplier information
Company Name Gujin Chemical
Address 544-17 Won-dong Osan-City Kyungki-do
Emergency Phone number 031) 374-2525
2. Hazard • Risk
a. Hazard • Risk Classification
Flammable liquids : Division 2
Acute Toxicity(Inhalation: Steam) : Division 4
Skin corrosion/ Skin irritation : Division 2
Eye damage/ Eye irritation : Division 2
Carcinogenic : Division 1B
Reproductive toxicity : Division 1A
Specific target organ toxicity(Exposure once) : Division 3(Acting anesthetic)
Specific target organ toxicity(Exposure once) : Division 1
Specific target organ toxicity(Exposure once) : Division 3(Respiratory stimulus)
Specific target organ toxicity(Repeated exposure) : Division 1
Aspiration Hazard : Division 1
Chronic hazards to the aquatic environment : Division 2
b. Warning signs Items including Precautions
Warning signs
Signs Danger
Hazardous•Risk Statement
H225 Highly flammable liquid and steam
H304 Could be fatal if swallowed and enters airways
H315 Cause skin irritation.
H319 Cause eye irritation.
H332 Harmful by inhalation
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness
H350 May cause cancer
H360 May cause damage to the reproductive capacity or fetus
H370 Causes damage to the body
H372 Prolonged or repeated exposure Causes damage to the body
H411 Long-term toxic effects to aquatic life
Precaution Statement
Prevention P201 Obtain special instructions before use.
P202 Do not handle before read and understand all safety
precautions.
P210 Keep away from Heat, flame, sparks, high temperature – non
smoking
P233 Keep container tightly closed.
P240 Keep bonding or grounding containers and equipment.
P241 Use Explosion-proof electrical, ventilating, lighting equipment.
P242 Use only non-sparking tools.
P243 Take an antistatic device.
P260 Do not inhale dust, fumes, gas, mist, steam and spray.
P261 Avoid inhaling dust, fumes, gas, mist, steam and spray.
P264 Wash thoroughly handling areas after use.
P270 Do not eat, drink or smoke when using this product.
P271 Keep handling only outdoors or in a well-ventilated area .
P273 Do not release to the environment.
P280 Wear protective gloves, safety goggles and face mask.
P281 Wear appropriate personal protective equipment.
countermeasure P301+P310 If swallowed, get medical advice immediately.

P302+P352 If on skin: Wash thoroughly with soap and water.
P303+P361+P353 If on skin: Take off or remove all contaminated
clothing. Wash skin with water.
P304+P340 If inhale: Move to fresh air area and take a rest in a
position comfortable.
P305+P351+P338 If in eyes: Wash gently with water for several
minutes. Remove contact lenses, if possible. Keep washing.
P307+P311 Get medical attention if exposed.
P308+P313 Ask for medical advice if exposed or concerned about
exposure.
P312 Get medical attention if you feel uncomfortable.
P314 Ask for medical advice if you feel uncomfortable.
P321 (...) Keep attention.
P331 Do NOT induce vomiting.
P332+P313 If skin irritation occurs, ask for medical advice.
P337+P313 If eye irritation persists, ask for medical advice.
P362 Take off contaminated clothing and wash before reuse.
P370+P378 In case of fire, use (...) to turn off the fire.
P391 Collect spillage.
Storage P403+P233 Store containers tightly sealed in a well-ventilated area.
P403+P235 Store in a well-ventilated area and Keep cool.
P405 Store in Lockable storage place.
Disposal P501 (depending on the laws and regulations) Dispose the container.
c. Other hazard not included in hazard classification(NFPA)

Light naphtha
Health 1
Fire 2
Reactivity 0
Natural Rubber
Health 1
Fire 1
Reactivity 0
3. Name and Content of Components
Name Official Name CAS no. Content(%)

Light naphtha Naphtha. Light 64741-46-4 85-90
Natural Rubber NAFKA KRISTALGOM 9006-04-6 10-15
4. First aid measures

a. Eye contact
If in eyes, Wash gently with water for several minutes. Remove contact lenses, if
possible. Keep washing.
If eye irritation persists, ask for medical advice.
b. Skin contact
If on skin, take off or remove all contaminated clothing. Wash skin with water.
If skin irritation occurs, ask for medical advice.
Remove contaminated clothing and shoes and keep away polluted areas .
Prevent the spread of contaminated area when minor skin contact.
If the burn cool the area immediately with cold water as long as possible and do
not remove clothing stuck.
Wash skin with soap and water.
c. Inhalation
Do not induce vomiting.
When exposed to excessive dust or fumes, remove them by clean air and if you
have coughing or other symptoms, ask for medical attention.
d. Ingestion
If swallowed, get medical attention immediately.
Do not induce vomiting.
If you eat or inhale substances, do not use mouth-to-mouth resuscitation, use proper
respiratory medical equipment.
e. Other medical attention
If exposed, contact medical staff and take the special first aid.
Make sure madical staffs are aware of the material and take protection measures.
5. Fire-fighting measures
a. Proper (improper) fire-extinguishing agent
Use alcohol foam, carbon dioxide or water spray associated with this material.
Extinguishing asphyxiation- use dry sand or soil.
b. Specific hazards arising from the chemical
Highly flammable liquid and vapor
Intense polymerization may cause fire and explosion.
Vapor can be moved to the sources of ignited and fire.
While burning, stimulating and highly toxic gases may occurs by thermal
decomposition or combustion.
May form an explosive mixture at flash point or more.
Containers may explode when heated.
Highly flammable: easily ignited by heat, sparks and flames burn.
Water leak has risk for fire/explosion.
Risk for steam explosion indoor, outdoor and drain.
Some may burn but not easily ignited.
Vapors may form explosive mixtures with air.
Non-flammable, substance itself does not burn. When heated and decomposed, may
cause corrosive / toxic fumes.
c. For fire-fighters, protective equipment and precautions
Light naphtha
Rescuers wear appropriate protective equipment.
Keep a safe distance from the fire area and extinguish the fire.
Be careful because most of them are lighter than water.
Because most of the vapor is heavier than air, it could spread along the ground and
can be accumulated in low-lying areas or confined spaces.
If there is no risk, move containers from fire area.
Tank fire-extinguishing, use fire extinguishing equipment at the maximum distance or
use unattended fire-extinguishing system.
Tank fire-extinguishing, cool down the containers with plenty of water after
fire-extinguishing.
Tank fire-extinguishing, stay away immediately when high pressure relief device or
any discoloration of tanks.
Tank fire-extinguishing, stay away make from the tank in flames.
Tank fire-extinguishing, in the case of a large fire extinguishing, use unattended
fire-extinguishing system. If not possible to use that system, just leave it burning.
Natural Rubber
If there is no risk, move containers from fire area.

Some may be transported on a high-temperature.
Leakage may cause water pollution.
In case of contact with skin and eyes may cause burns.
For disposal slaking water, digging ditches and imprison. Do not let material
scattered.
Tank fire-extinguishing, cool down the containers with plenty of water after
fire-extinguishing.
Tank fire-extinguishing, stay away immediately when high pressure relief device or
any discoloration of tanks.
Tank fire-extinguishing, stay away make from the tank in flames.
6. Leakage accident measures

a. Precautions and procedures to protect human
Avoid inhaling dust, fumes, gas, mist, steam and spray.
Due to very fine particles can cause a fire or explosion, eliminate all ignition sources.
Wipe spills immediately then follow precautions.
Keep away the contaminated area.
Do not access if people who do not have protective equipment.
Eliminate all ignition sources.
Keep all equipment in paper folding when handling materials.
If it is not dangerous, stop leaking.
Do not touch damaged containers or spilled material if you don’t have suitable
protective clothing.
To reduce the occurrence of steam, vapor suppressing foam may be used.
Prevent the spread by covering with plastic sheets.
Prevent formation of dust.
Please note that materials and conditions to avoid.
b. Precautions to protect environment
Do not release to the environment.
Prevent entry into waterways, sewers, basements, and confined spaces.
c. Purification or Removal method
Collect spills.
Build dikes to extinguish and keep collecting water.
Absorb inert materials(eg dry sand or soil) and put it into chemical waste container.
Remove dust and wetting with water to prevent scattering.
Absorb liquids and wash contaminated area with rinse and water.
If large spills, make a ditch far from liquid spills.
Using a clean-proof tools, collect absorbed material.
Put spills in clean and dry container with Clean shovel, then move the container
from the spilled area.
If powder spills, cover it with plastic sheet to prevent the spread and keep in a dry
condition.
If small spills, absorb it with sand, non-combustible materials, then insert containers.
7. Handling and Storage

a. Safe handling measures
Do not handle until you read and understand all safety precautions.
Use explosion-proof electrical, ventilating, lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static electricity.
Avoid inhaling dust, fumes, gas, mist, vapors and spray.
Wash thoroughly after use.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Do not expose to pressure, cutting, welding, soldering, bonding, drilling, grinding or
heat exposure, flame, sparks, static electricity or other sources of ignition.
Even after container is emptied, because it may retain product residue, follow all
MSDS/ label precautions.
Pay attention to use/storage.
Open the cap carefully before opening.
Prevent long-term or continuing skin contact.
Keep all equipment grounding when using materials.
Note that materials and conditions to avoid.
Be careful for high temperatures.
Be careful for heat.
Due to there is a risk of oxygen deficiency in low-confined areas, check oxygen
concentration measurements in air and ventilate the air.
b. Safe storage measures
Keep away from heat, flame, sparks and high temperature – non-smoking
Store containers in a well-ventilated area.
Keep cool and in a well-ventilated place.
Properly drain and prevent empty drums, then set it back to the drum regulator
immediately.
Keep away from food and drinks.
8. Exposure controls and personal protection

a. Exposure standards of chemical and biological exposure standards, etc.
National regulations
Light naphtha No data available
Natural Rubber No data available
ACGIH regulations
Natural Rubber Respirable
TWA 0.001 ㎎/㎥
Biological exposure standards

Natural Rubber Not applicable
b. Proper engineering controls

Use isolation process, local exhaust ventilation system or other engineering process
which control air levels below the exposure guidelines.
During operation, if dust, fume or mist occurs, keep the air pollution at below the
exposure limits.
Store this material or install wash facilities and safety shower facilities.
c. Personal protection
Respiratory protection
Light naphtha
Wear respiratory protective equipment which is certified by the Korea Occupational
Safety and Health Agency and meet the exposed gas/liquid physicochemical
characteristic.
If exposure concentration is less than 500ppm, wear respiratory protective equipment
which equipped with the appropriate filter or canister.
If exposure concentration is less than 1250ppm, wear loose-fitting hood/helmet
motorized respirator or continuous-flow-type electric dust mask which equipped with
the appropriate filter or canister.
If exposure concentration is less than 2500ppm, wear front or motorized profile or
air-fed continuous-flow/pressure-demand-type respiratory protective equipment which
equipped with the appropriate filter or canister.
If exposure concentration is less than 50000ppm, front or hood/helmet type,
pressure-demand-type air supplied respirator which equipped with the appropriate
filter or canister.
If exposure concentration is less than 500000ppm, self-contained breathing
apparatus(SCBA) or pressure-demand self-contained breathing apparatus(SCBA) which
equipped with the appropriate filter or canister.
Natural Rubber
Wear respiratory protective equipment which is certified by the Korea Occupational
Safety and Health Agency and meet the exposed gas/liquid physicochemical
characteristic.
9. physicochemical characteristic
a. Appearance
Appearance Liquid
Color Isabelline white
b. Smell
c. Smell threshold value no data available
d. pH no data available
e. Melting point/freezing point no data available
f. Initial boiling point and boiling range 30~150℃
g. Flash point -21℃
h. Evaporation rate no data available
i. Flammability(solid, gas) no data available
j. Upper/ lower range of flammability or explosive no data available
k. Vapor Pressure no data available
l. Solubility Insoluble in water
m. Vapor Density >1.0(air=1)
n. specific gravity 0.7, 15℃
o. n-octanol/ water partition coefficient no data available
p. Autoignition temperature 265℃
q. Decomposition Temperature no data avaiable
r. Viscosity no data avaiable
s. Molecular Weight no data avaiable
Light naphtha
a. Appearance Liquid
Color colorlessness
b. Smell The smell of petrochemical compounds
c. Smell threshold value no data avaiable
d. pH no data materials
e. Melting point/freezing point 155~217℃
f. Initial boiling point and boiling range -20~190 ℃
g. Flash point <38℃
j. Upper/ lower range of flammability or explosive - / -
k. Vapor Pressure 3000 Pa(3-12 hPa at 37.8℃)
l. Solubility no data available
m. Vapor Density (>1)
n. specific gravity no data avaiable
o. n-octanol/ water partition coefficient no data avaiable
p. Autoignition temperature no data avaiable
q. Decomposition Temperature no data avaiable
r. Viscosity no data avaiable
s. Molecular Weight no data avaiable
Natural rubber
a. Appearance Solid
Color colorlessness to yellow
b. Smell odorless
c. Smell threshold value no data available
d. pH (not applicable)
e. Melting point/freezing point (none)
f. Initial boiling point and boiling range (not applicable)
g. Flash point no data available
j. Upper/ lower range of flammability or explosive - / -
k. Vapor Pressure (not applicable)
l. Solubility (water solubility: insolubility.
Solvent solubility: solubility;
Carbon disulfide, pure ether,
chloroform, solid and volatile oil,
petroleum, ether, benzene, tea
Pantin oil. Insoluble: alcohol,
dilute acid, dilute alkali)
m. Vapor Density (not applicable)
n. specific gravity 0.92 (water=1)
o. n-octanol/ water partition coefficient (none)
p. Autoignition temperature no data available
q. Decomposition Temperature 120 ℃
r. Viscosity no data available
s. Molecular Weight no data available
10. Safety and reactivity
a. Chemical safety and possibility of noxious reactivity
Light naphtha
flammable liquid and vapor
Intense polymerization may cause fire and explosion.
May form an explosive mixture at flash point or more.
Highly flammable: easily ignited by heat, sparks and flames burn.
Water leak has risk for fire/explosion.
There is a risk for steam explosion hazard indoor, outdoor and drain.
Steam may form explosive mixtures with air.
Steam may cause dizziness or suffocation without awareness.
If inhalation and contact, may irritate skin and eye or burns.
Natural rubber
Stable at normal temperature and pressure conditions.
Some may burn but not easily ignited.
If fire, irritating and toxic gases may occur.
Inhalation of the substance may be harmful.
Some liquid may cause the steam which induce dizziness and suffocation.
b. Conditions to avoid
Light naphtha
Keep away from heat, flame, sparks and high temperature- non-smoking
Natural rubber
Ignition source-heat, flame, sparks
c. Materials to avoid
Light naphtha no data available
Natural rubber Combustible materials
Irritating and toxic gases
d. Hazardous mateirals during decomposition

Light naphtha
While burning, highly toxic gases may occur by spread of the fire.
Natural rubber
no data available
11. Toxicity Information

a. Information on routes of exposure
Natural rubber Stimulus
Vomiting, gastroenteric trouble
b. Health hazard information

Acute toxicity
Oral Light naphtha LD50 5000 ㎎/㎏ Rat
Natural rubber no data available
Dermal Light naphtha LD50 3160 ㎎/㎏ Rat

Inhalation Light naphtha no data available

Skin corrosion or irritation

no data available moderate irritant to rabbit
Serious eye damage or irritation

no data available causes eye irritation
Respiratory sensitization
Skin Sensitization Light naphtha no data available

Carcinogenicity
Industrial safety and health act
Notice of Employment and Labor

IARC
OSHA
ACGIH
NTP
EU CLP
Toluene Carc. 1B
Germ cell mutagenicity

Light naphtha In vitro Salmonella typhimurium Ames
test, syster chromated exchanged
assay-negative
Reproduction-toxicity
Specific target organ toxicity (exposure 1 time)

Light naphtha when inhalation, irritating to airway
Aspiration Hazard
12. Impact on the environment

a. Ecotoxicity
Fish Light naphtha no data available
Shellfish Light naphtha LC50 2.6 ㎎/ℓ 96 hr
Birds Light naphtha no data available

b. Persistence and degradability

Persistence Light naphtha log Kow 2.1 ~ 6
Natural rubber (none)
Degradability Light naphtha no data available
c. Bioaccumulative
Condenasability Light naphtha no data available
Biodegradable Light naphtha no data available

d. Mobility in soil
e. Other hazardous effects

Toluene no data available
13. Disposal Considerations

a. Methods of disposal
Light naphtha
1) Seperate the oil and water and incinerate the oil. Dispose remaining water in the
water pollution prevention facilities.
2) Dispose by evaporation and concentration, then incinerate or stabilize remnants.
3) Dispose by coagulation and sedimentation, then incinerate remnants.
4) Purify by the method of separation, distillation, extraction, filtration and pyrolyze.
5) Incinerate or stabilize remnants.
Natural rubber
If specified in the Waste Management Act, follow the regulations and dispose the
container and contents.
b. Disposal Considerations
Light naphtha (According to the regulations) dispose the container contents.
Natural rubber (According to the regulations) dispose the container contents.
14. Transport information

a. UN No.
Light naphtha 1268
Natural rubber 1345
b. Proper shipping name

Light naphtha PETROLEUM DISTILLATES, N.O.S. or PETROLEUM
PRODUCTS, N.O.S.
Natural rubber RUBBER SCRAP powdered or granulated, not exceeding
840 microns and rubber content exceeding 45% or
RUBBER SHODDY powdered or granulated, not
exceeding 840 microns and rubber content exceeding
45%
c. Hazard level
Light naphtha 3
Natural rubber 4.1
d. Container grade
Light naphtha I
Natural rubber II
e. Marine pollutants
f. User needs to know in relation to transport or any special safety measures

In case of fire emergency Light naphtha F-E
Natural rubber F-A
In case of spill emergency Light naphtha S-E

Natural rubber S-I
15. Present condition of lawful regulations

a. Occupational Safety and Health Act
Light naphtha Managed hazardous materials
Working environment measurement subject
material (measurement period: 6 months)
Special medical examination subject material
(diagnostic period: 12 months)
Exposure standard substance
no data available
b. Hazardous Chemicals Control Act

c. Safety Control of Dangerous Substances Act

d. Waste Control Act

Toluene specified waste
e. Other domestic and foreign regulation

Domestic regulation
Light naphtha not applicable
Natural rubber not applicable
Foreign regulation
United States Manage Information(OSHA regulation)
United States Manage Information(CERCLA regulation)
United States Manage Information(EPCRA 302 regulation)
United States Manage Information(Rotterdam Agreement Material)
United States Manage Information(Stockholm Agreement Material)
United States Manage Information(Montreal Protocol Material)
EU Classification (Confirm classification result)
Light naphtha Carc. Cat. 2; R45 Muta.Cat.2; R46, Xn; R65
EU Classification (Risk sentence)
Light naphtha R45, R65, R46
EU Classification (Safety sentence)
Light naphtha S53, S45
16. Other information

Light naphtha
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis)(e.
Melting point/freezing point)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis)(k.
Vapor Pressure)
Corporate Solution From Thomson Micromedex(http://csi.micromedex.com)(Oral)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis)(Oral)
Corporate Solution From Thomson Micromedex(http://csi.micromedex.com)(Dermal)
International Uniform ChemicaL Information
Database(IUCLID)(http://ecb.jrc.it/esis)(Dermal)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis)(Skin
corrosion or irritation)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis)(germ
cell mutagenicity)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis)
(Specific Target organ Toxicity (Repeated exposure))
IUCLID(Shellfish)
IUCLID(Persistence)
NATURAL RUBBER
b. First reporting date 2013-06-20

c. Revision and Date of last revision
Revision 0 times
Date of last revision 0
d. Other
∎Written Material Safety Data Sheets (MSDS) is edited and modified by referring to the
Korea Occupational Safety and Health Agency.

SH-301 본드 (영문) (Lem Korea)

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Material Safety Data Sheet

Product Name: RB 600(SH-100)

1. Chemical Product and Company Information

countermeasure P301+P310 If swallowed, get medical advice immediately.

c. Other hazard not included in hazard classification(NFPA)

3. Name and Content of Components

Name Official Name CAS no. Content(%)

4. First aid measures

If there is no risk, move containers from fire area.

6. Leakage accident measures

7. Handling and Storage

8. Exposure controls and personal protection

Biological exposure standards

b. Proper engineering controls

d. Hazardous mateirals during decomposition

11. Toxicity Information

b. Health hazard information

Dermal Light naphtha LD50 3160 ㎎/㎏ Rat

Inhalation Light naphtha no data available

Skin corrosion or irritation

Serious eye damage or irritation

Skin Sensitization Light naphtha no data available

Notice of Employment and Labor

Germ cell mutagenicity

Specific target organ toxicity (exposure 1 time)

12. Impact on the environment

Birds Light naphtha no data available

b. Persistence and degradability

Biodegradable Light naphtha no data available

e. Other hazardous effects

13. Disposal Considerations

14. Transport information

b. Proper shipping name

f. User needs to know in relation to transport or any special safety measures

In case of spill emergency Light naphtha S-E

15. Present condition of lawful regulations

b. Hazardous Chemicals Control Act

c. Safety Control of Dangerous Substances Act

d. Waste Control Act

e. Other domestic and foreign regulation

16. Other information

b. First reporting date 2013-06-20

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