PART I: MULTIPLE CHOICE (2 POINTS EACH, 20 POINTS)

1. Which of the following statements is/are consistent with Dalton' s atomic theory?
F I. The atoms of a given element do not share any common properties.
T II. Matter consists of particles called atoms.
T III. In chemical reactions, atoms rearrange, but are indivisible and indestructible
a. III only.
b. II only.
C. I and III.
d. I only.
✓. II and III.

2. Whic~ of the following have roughly the same mass?

a. A proton and an electron.
b. A neutron and an electron.
,SY. A neutron and a proton.
d. An electron and an alpha particle.
e. None of these options.

3. Uranium exists in nature in the form of several isotopes; the different isotopes have different
$. numbers of neutrons.
b. numbers of protons.
c. atomic numbers.
d. charges.
e. numbers of electrons.

4. Which is an example of a physical change?

a. Sugar, when heated, becomes brown. ll~-fuJ ~ 1 oxiMlev,
b. Milk turns sour over time. ,i~Cl'J t~; CA.C(&.~·caJi""1
JY. Water, when heated, fonns steam.
d. Bleach turns hair yellow . .e,~ eDNY11f-
e. Apples, when exposed to air, tum brown over time ~ ~ ; ox,,,b. fti,,., .
5. Which of the examples below is a chemical change?
a. A bottle of wine completely evaporates in two weeks. ~f\"t.J ~
J✓. Bleach changes the color of the stain on the white shirt.
c. The 'dry ice' (solid CO2) c_!:anges to vae_or. N-n:,J ~~
d. Bubbles form in the water when He gas is blown into the
water. ~ruJ ~

2
 6
· Which response gives the correct numbe) of significant fi~res for all three of the
following measurements? 7.103 cm, 0.00005 inch, and 1.3400 x I o4 dm3
Y.
4, I, and 5
b. 3,I,and3
c. 4, 5, and 5
d. 4, l,and3
e. 3, 5, and 4

7. When the expression, 412.272 + 0.00031 - 1.00797 + 0.000024 + 12.8, is evaluated,

the result should be expressed as
a. 424
b. 424.0
C. 424.06
d. 424.064364
/. 424.1
8. Which element is a halogen?
a. Se
b. Te
C. u
d. 0
✓ I

9. Which of these elements have chemical properties that are similar to silicon?
a. phosphorus
b. aluminum
C. nitrogen

I d. silver
J germanium

10. Which of these pairs of elements would be most likely to -fonn a molecular compound (not
ionic)?
a. Cu and K
b. Al and Rb
c. Kand 0
-sY.P and Br
e. 0 and Zn

3
 PART 11: SHORT ANSWER (7 Parts, 130 points total)

I. NAMING COMPOUNDS: (20 points)

,z_-
Fonnula for the carbonate ion Cc!>$
1-
Fonnula for the phosphate ion poer
Fonnula for ionic compound fonned from sodium and "1a ;t c;: t.- Nt:I,. S'
sulfur I ,z_
i -
Fonnula for ionic compound fonned from calcium ~~~ N01 ~ NCJ'l
and nitrate "2. 7-
..,. ~ 1-
Fonnula and charge for polyatomic ions present in the f\J 1+4
compound, (NH4)3PQ4
Fonnula of iron (III) oxide fe q.,. oz- Fez-01
~ X z..
Name of the compound, N 20 5 N ~ \.fMr lS
~ Dini~~

Name for the compound CuBr2 N<1.\-rrt .lb1 TT

lcn-,n Ccftwl~
Fonnula of compound composed of ammonium and f'J lk,-t ")<. (j,(J'f z - ( N \¼) ~4
sulfate ions I '2. 7-

r-
Fonnula of compound fonned from magnesium and
iodine
. ~ )f--
'2-
'2,t

'
~¾-

II. UNIT CONVERSIONS (20 points)

t I 1,<L ::: lo -c '-

1. What number is needed to complete the following: 1L= Io µL
-et - '. I j.. -:::, /c, ~ ,UL
1 nm = lo m

~ 1Kg= J!:_mg

2. How many micrometers (µm) are there in 3.672 km?

'"1~ 1.,(,fm
::: '3, ~-:t-'2 x lo~><- lo'
1. {,:f fZ 1t-M ::: 1, &1'2 ~ . I~ . 10-' ~ /,41',"'

--=- ~ . 6-+'2 X )l) '1 )Am

4
,..-------------
\6ooooc,
Io'
~ 3. How many cubic inches are in 1.00 dm 3? (1 dm = 10 cm and I in. = 2.54 cm)

-1 J.,,r, 'l =- 4.. Jm,., x I lo (#I ) \. I 1... 1Y1 ) '1

t 1~ l-:i •i'7+ c.,,
= .{ ~ 7'- lo~~ ">'-- ,1_ t,,
1
_
7 j;-z ~ -r4f~~
IO ~ 1'1
' :J
- i
(,z, ~'t)
~ 4. The Earth completes its orbit around the Sun roughly in 365 days. If the orbital dista~e is
about 146.6 million kilometers, what is Earth 's orbital speed in miles per hour? (1 m\=
1.609 ·mJ. Express your answer in scientific notation. -
k-W'I
V ;::: d_ J -== l 4c;. C X lo (. 1t-m
c

~ \. I\ )(. )0 b fWI ((A

4
-:::. \, 0 4- X lO fVIJUh. """'"
,-s-«o vtLXM
III. MASS AND MOLES (20 points)

1. Convert moles to grams in each of the following: (30 points)

a. 1.5 moles NH3 c. 0.65 moles H2SO4- - - - - - - -

~~ af N UJ = .\1"9/rr,a1 ~~ 1 U-r~04 == Cl ,g • I fl I(Y1)s'l

It ~ N"°1 o -6~mol Hi,W'f ~ O • G(' ~ & ) ~ ,/H'd~ 1-\i~.
1. ~ ~e,o 6c NIA-1 ;- I. ~ ~IA-7 -,i
I~ -~C14
1~1
= 'l... ~-~Rill> ff Nt-h -= (o ~ , '1- 'f- 1 lh S04

2. Convert the following to moles:

b . 3.01 x 1023 atoms Na

~ 3. How many atoms of oxygen are there in 56.0 grams of oxygen gas (diatomic oxygen)?
-?~ 0 1,1~ ~· s\ @i., _ '> ;: ~I O > ~ ,: ; ~ o ,wrw 1
t ~ Ol, 1., ~ f'llr O _ f~ xl,.c/2?XI01-t ~0
fb~ .,c -.J--
~ l~Z.
i- --
\~01.,
'1- \ A,,A-'t)
'Y"'
- 31
i, 1 _ I~
/0 - ;:- '2 1• o,; X \0 c,vrt.11 l#.l 0
2
,;:-- '2, IO z X 10 • ~ 0

~ 4. You have the balanced equation 4 FeS + 7 0 2 - 2 Fe2O 3 + 4 SO2. If you react 5 moles of 02
how many moles of Fe203will be generated? Use a unit conversion approach to answer this
question based on the mole to mole ratio.
~ Jru. \,oJMl,{U 8l~ ~ ma~ ol 0-i r-eAf.) <,(}l!A ~ ~ 6 r~1' 01 .
~I = ~ ~ cJ{+e,8i
-,:f-

-;;- IA-3 M.C<J-1 cf fe?q

IV. DENSITY (15 points)

1. A sample of zinc metal (density= 7 .14 g/cm 3) is submerged in a graduated cylinder

containing water. The water level in the cylinder rose from 162.5 cm3 to 186.0 cm3 . How
many grams does the sample weigh?
l,\-\L Mtl~ cl,tryw.ul [tu i,-0cJvir . ~ , vo~ 1 · ~ ~ vd--¼mt 1_ ~J.;;i
~ 11 \ai.J, •
\J -= \ q b CN' l - I b 2 ·\ Ct-vi 1 ::, ·'Z 3. <;" C,rvl 1

~ ~t½ d=- -:f·IA-S{c,,v,1

·~ ~ d.-==!!!- => clxv ::~~'V- )> J. x. V -:::'fY\

V "'
==-) (YI== "':f - 14-~ >< 25. s.,. L'."1
~'] Y'

V. ISOTOPES (20 points)

Number of Number of
-
Element Number of Mass Number
Symbol Protons Electrons Neutrons

1 Ne 10 lo 11 <]_ I
Ba ~& ~& 82 ~ I ?,~
27
uAl +3 11 11-~=-I0 14 '2-~

Sc 21 1. I 24 4-5"

6
 1. Calcul~te the average atomic mass of element X which occurs as two isotopes that have the
followmg atomic masses and abundances in nature: 6.017 amu, 7.30% and 7.018 amu,
92.70%.

I oo
6 , o\-:fy-:f•3o + 1- -olix-y1 . ::(
l~D

2. Element Y has two naturally occurring isotopes: El-10 and El-11. If the average atomic mass 1k)
of element Y is 10.841 atomic mass units, which isotope is the most abundant? V
w
O \ k , . ) ~ ci ),, l3J. ht '){ . ~ { l > ' \ ( 1 o . , k , v ~ 1' ''tJ ts 101J·- )( .

~s, Jo , .f?'l--l -:: x • to +(l.,o-)(') , II ::,:,)) 10. g41 ',( 100 = lo'l4- ,foo· 11 ':If - x · II
loo
ilov --><-
fc,94 . 1 =-
x -= ti oo - Io 4 ~ I
x
= I S"•q _1/. ~ ~ "cJ( '"£.1
VI. EMPIRICAL FORMULA (15 points) ~~ 1'(;1 =: 1c,o-x. : "f?4 • I½
0
, ~ 1'£J ( ~ i~ m~ ~ - ·
1. Glutaric acid contains 45.45% C, 6.10% H, and 48.44% 0 . Determine the empirical formula
of this compound.
'I~ I ~ &.( {~ R.e-n-fo.1,,J,
~~ C ""'1.\-(°•4-(~ ~- ~ e,:( C-= 4(•4-C~ -:: ,g . -:,.~~ Mxl = 1. 1-s- ~
\ 'Z _g (r-1-u1
f'(V.M 1 µ -= "· '" a --4 ~ i /.I : 6-' :J
N\PIAi ef o -= 4 q. tt z,. d' , , ~ /Mlfl
--., ~ 'i' 0
I .: -4 4 ·H1 I -
Ib 1 / tVl<JI
~ C ~ \.-1 ~0 ~ ~ l , '.;Af : ::z ; /
~~ &.b ~ i lt ta ~ -ytt{ "6 1J,..,. JJ.R,(m;& ~ C: 1-\: 0 ::- I, "J..f )( 4 ', '2>' 4- : \ ll 1./
c ~ i➔ : o r c;; •. -i :4
VII. MOLARITY (20 points) l
~ ~ µi o"
1. What is the concentration of a solution that contains 33.4 grams of Ah(S0 4)3 in 0.500 L ?
f'Od\11.rc ~ ~ A l,. ( rl7;,)1 -:::

:. Yl,O • 7 ~ ~ A:\i (.r~'f)1 0 ~

Y-oi-wvvu. EJf A -:i W'1'bv-. V_ 0 .~ L

:J> ~ 1 MWl (J>-1 M= <)
v
-=-

7
 0 1 of a o·250 M solution?
® 2. How many grams of K2CO.1 are needed to make 25 m
\'I'\ -::: {) ?;) -r-, -::; M·V ' M-; 0 · 'J.~O fv1
v 'J V :; 1-s-vn1t- =- 0 ·?-COL-

('no~ ~ of l£1Co1 -; \1~ · 111~

()\'.),'1 l'"IWU/\ °O ~1, LD l n =
o, ~<;,-() M ,._ (). 'J.._fb 1- - D, 0 b2-S"' ~

~ ~ .63 \(.,z.,(1)1 ~ "•ob-Zr~ x: 1~.tzl ,'.2 3 _ ~ ~

,~ • <...4 «- -, Kzl01·

't 3. A patient has a cholesterol count of 206 mg/dL. What is the molarity of cholesterol in this
patient's blood if the molecular mass of cholesterol is 386.64 g/mol?
i clL 6o blow ~ l)_o~ 'i° 1 ~ 1YVM1 <qf <s ~b:. b ¢-- ~ /'fYlfff.
1
~ , V;; 1-JL.::: 10- L
..:,,,...
IY\ :: ·Y),6 6~ :;:. .?-o6 )( l'O-.!.d'
:= ?--() 6 )( 10-1 q 0 . c->-=z X l'O - 3 ~ 't - - _..,
I()
Q
X
s\ rvi,:r1
?5l. 6 tr
;;:
✓
---A
IT"" I
:::-
:> , 1 )( '0
-
IVVV \

4. A laboratory experiment calls for 0.150 M HNOi . What volume of 0.150 M HNO3 can be

Mi::-
V-i, ~ 1
o. i<;;o t-A I
prepared~ 0.350 L of 1.98 M HN03? [ ~owH6tl
M, ::; \,"14
V1 -::o
fv1
o •'1fol,,
fYl.Q-N
1. IS
00,,,ce,0~
~~ ~ 'fvv..tfeJ./~/
I.lo~]

k 1v 1 ::: 1vh Vi.

V,. -:- N.,v, ~ l ,e"-\ i )( v, 1(o

M.2.- o -lrl:>